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Interaction of sulfur dioxide and cyanide with cobalt (II) tetrasulfophthalocyanine in aqueous media

  • Authors: Thamae, Mamothibe , Nyokong, Tebello
  • Date: 2002
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/289595 , vital:56652 , xlink:href="https://doi.org/10.1016/S0277-5387(01)00968-8"
  • Description: Kinetic and equilibrium studies for the coordination of cyanide or sulfur dioxide to the cobalt(II) tetrasulfophthalocyanine ([CoTSPc]4−) complex are reported. The equilibrium constant for the coordination of the cyanide under pH 11 conditions and an oxygen atmosphere, and the formation of [(CN−)2Co(III)TSPc]5− species, was found to be 2.1×101 dm3 mol−1 and the rate constant, kf was found to be 7.4 dm3 mol−1 s−1. Similarly, the coordination of SO2 to [CoTSPc]4− occurred with an equilibrium constant of 8.7×101 dm3 mol−1 and a rate constant of 2.1×102 dm3 mol−1 s−1, at pH 11. These rate and equilibrium constants represent the coordination of the second cyanide or sulfur dioxide ligands to the [CoTSPc]4− species. Coordination of the first ligand occurred faster than that of the second ligand in both cases. The coordination is accompanied by the oxidation of the central Co(II) metal with the formation of a Co(III) tetrasulfophthalocyanine species.
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  • Date Issued: 2002

Investigation of the bioconversion of constituents of olive effluents for the production of valuable chemical compounds

  • Authors: Notshe, Thandiwe Loretta
  • Date: 2002
  • Subjects: Phenols , Sewage -- Purification , Effluent quality
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4078 , http://hdl.handle.net/10962/d1007446 , Phenols , Sewage -- Purification , Effluent quality
  • Description: Olive mill wastewater is produced in large quantities during the production of olive oil and olive production effluents are produced during the processing of olives. This project was planned to find a use for constituents found in olive production wastewater. The task was carried out by first characterizing the olive effluents, then screening microorganisms for growth in the effluents and reduction of the pollutant properties of the effluents. An investigation into the biotransformation of aromatic compounds present in the effluents into useful chemicals, was carried out. The olive production effluents were collected from different stages in the process for treating olive wastewater, viz, a fermentation tank (FB), the surface of a digester (LV) and an evaporation pond (SO). The three effluents were characterized by investigating their phenolic composition. Protocatechuic acid, vanillic acid, syringic acid, hydroxyphenyl acetic acid, coumaric acid and ferulic acid were identified in an olive effluent, FB, using thin layer chromatography (TLC) and High perfomance liquid chromatography (HPLC). Hydroxyphenyl acetic acid constitutes almost 60% of the organics in olive effluent FB. Five bacteria, namely RU-LV1; RU-FBI and RU-FB2; RU-SOI and RU-S02, were isolated from the olive effluents LV, FB and SO respectively. These isolates were found to be halotolerant and were able to grow over a broad temperature and pH range, with the maximum temperature and pH for growth being 28°C and pH 7 respectively. A range of microorganisms were evaluated for their ability to grow and reduce the total phenolic content of the olive effluents. Among these Neurospora crassa showed the highest potential for the biological reduction of total phenolics in olive effluents. Approximately 70% of the total phenolic content was removed by N. crassa. Trametes verscilor, Pseudomonas putida strains, RU-KMI and RU-KM3s, and the bacteria isolated from olive effluents could also degrade the total phenolic content of olive effluents, but to a lesser extent. The ability of the five bacterial isolates to grow and degrade aromatic compounds was assessed by growing them in medium with standard aromatic compounds. RU-L V1 degraded 96%, 100%, 73% and 100% of caffeic acid, protocatechuic acid, p-coumaric acid and vanillic acid respectively. The other isolates degraded caffeic acid and protocatechuic acid, but their ability to degraded p-coumaric acid and vanillic acid was found to be lesser than the ability of RU-LV1 to degrade the same aromatic compounds. Whole cells of RU-LV1 degraded vanillic acid but no metabolic products were observed on HPLC analysis. Resting cells, French pressed extract, cell free extracts and cell debris from RU-LV1 cells induced with vanillic acid degraded vanillic acid, ferulic acid and vanillin at rates higher than those obtained from non-induced cultures. No products were observed during the degradation of vanillic acid. Ferulic acid was converted into vanillic acid by French pressed extract, cell free extract and cell debris of RU-LV1. The maximum yield of vanillic acid as a product (0 .23 mM, 50 %yield) was obtained when cell free extracts of RU-LVI, grown in glucose and induced by vanillic acid, were used for the degradation of 0.4 mM ferulic acid. Vanillin was rapidly converted into vanillic acid by resting cells, cell free extracts and French pressed extract of RU-LVI. Using molecular techniques, the similarity ranking of the RU-LVI 16S rRNA gene and its clone showed a high similarity to Corynebacterium glutamicum and Corynebacterium acedopltilum. The rapid degradation of vanillin to vanillic acid suggests that extracts from RU-LV1 degrade ferulic acid into vanillin which is immediately oxidized to vanillic acid. Vanillic acid is also considered as a high value chemical. This project has a potential of producing useful chemicals from cheap substrates that can be found in olive effluents. , KMBT_363
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  • Date Issued: 2002

Iron perchlorophthalocyanine and tetrasulfophthalocyanine catalyzed oxidation of cyclohexane using hydrogen peroxide, chloroperoxybenzoic acid and tert-butylhydroperoxide as oxidants

  • Authors: Grootboom, Natasha , Nyokong, Tebello
  • Date: 2002
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/289606 , vital:56653 , xlink:href="https://doi.org/10.1016/S1381-1169(01)00404-6"
  • Description: Polychlorophthalocyanine (Cl16PcFeII) and tetrasulfophthalocyanine ([FeIITSPc]4−) complexes of iron are employed as catalysts for the oxidation of cyclohexane using tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA) and hydrogen peroxide as oxidants. Catalysis using the Cl16PcFeII was performed in a dimethylformamide:dichloromethane (3:7) solvent mixture. For the [FeIITSPc]4−catalyst, a water:methanol (1:9) mixture was employed. The products of the catalysis are cyclohexanone, cyclohexanol and cyclohexanediol. The relative yields of the products depended on oxidant and the catalyst. TBHP was found to be the best oxidant since minimal destruction of the catalyst and higher selectivity in the products were observed when this oxidant was employed. The mechanism of the oxidation of cyclohexane in the presence of the Cl16PcFeII and [FeIITSPc]4− involves the oxidation of these catalysts, forming an Fe(III) phthalocyanine species as an intermediate. Higher yields were observed when [FeTSPc]4− was employed as a catalyst, which is more soluble than the perchlorinated iron phthalocyanine catalyst.
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  • Date Issued: 2002

Issues in contemporary geographical hydrology

  • Authors: Hughes, Denis A
  • Date: 2002
  • Language: English
  • Type: text , Article
  • Identifier: vital:7083 , http://hdl.handle.net/10962/d1012340
  • Description: Finding solutions to the many water resource utilisation problems that face South Africa has been the driving force behind a large part of the hydrological research that has been undertaken in the country. Any review of the methodology and past or present issues of hydrology in South Africa would find it difficult to distinguish between those that are part of engineering hydrology, and those that are part of geographical hydrology. Both have a great deal to contribute to solving the water resource management problems of South Africa and these contributions should be made in a co-operative framework. As will be demonstrated in the paper, the changing face of South Africa and the requirements of managing water in a transformed, democratic society have made the need for co-operation across various disciplines even more essential.
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  • Date Issued: 2002

John Jolly : the Grahamstown bell founder

  • Authors: Lewis, Colin A
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:6173 , http://hdl.handle.net/10962/d1012364 , http://www.ringingworld.co.uk
  • Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
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  • Date Issued: 2002

Knowledge on Sclerocarya birrea subsp. caffra with emphasis on its importance as a non-timber forest product in South and southern Africa, a summary: Part 1 Taxonomy, ecology and role in rural livelihoods

  • Authors: Shackleton, Sheona E , Shackleton, Charlie M , Cunningham, Tony , Lombard, Cyril , Sullivan, Caroline A , Netshiluvhi, Thiambi
  • Date: 2002
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/182251 , vital:43815 , xlink:href="https://doi.org/10.1080/20702620.2002.10434589"
  • Description: Sclerocarya birrea (marula) is a widespread species throughout the semi-arid, deciduous savannas of much of sub-Saharan Africa. It is widely used by rural populations in most countries in which it is found. It has multiple uses, including the fruits, kernels, oil, bark, wood and leaves. Because of these multiple uses, and its significance in the landscape, several African cultures have specific beliefs and ceremonies associated with this species, and it is often maintained in homestead and arable plots. Because of the widespread occurrence, potentially high fruit production and use of S. birrea it has frequently been identified as a key species to support the development of rural enterprises based on the fruit, beer, oil or nuts and therefore as a species for potential domestication. Localised breeding and cultivation initiatives commenced in the 1970s and some continue. Interest in this species was renewed after the development of a highly successful liqueur using extracts from the fruit. This has developed further in southern Africa over the last 3 to 5 years, especially commercialisation initiatives orientated towards befitting the rural poor. Recently, the UK Department for International Development (DFID) initiated a project to examine the impacts of commercialisation of non-timber forest products, such as marula, on the livelihood capital of the rural poor. As a first phase, the research team compiled a comprehensive literature review of S. birrea, with emphasis on possible commercialisation. This is to be published in two parts. The first part deals with the taxonomy, ecology and its subsistence use and cultural value to rural households. The second part of the review will focus on issues relating to specific properties of the marula, management, intellectual property and its potential commercialisation.
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  • Date Issued: 2002

Language as a ‘resource’ in South Africa: the economic life of language in a globalising society

  • Authors: Wright, Laurence
  • Date: 2002
  • Language: English
  • Type: text , article
  • Identifier: vital:7035 , http://hdl.handle.net/10962/d1007370 , https://doi.org/10.1080/10131750285310031
  • Description: preprint , We need to develop a much more refined and specific understanding of what is meant when people refer to language is a ‘resource’. If something can accurately be described as a resource, then by its very nature it carries with it or attracts, at least in potential, the social motivation associated with the utilization, development or exploitation of that resource. This is strikingly true where language is the resource in question, because language is so intimately bound up with human activity. Where it exists, such social motivation can be augmented and supported so as to realize the ends of language policy. Contrastingly, where it is seen that social motivation informing a particular language situation is at odds with the intent of language policy, then either implementation must retreat and move to other arenas, other points of influence, where intervention can be more effective, or those charged with implementation must resign themselves to costly and messy efforts to force unwanted change through legal authority.
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  • Date Issued: 2002

Leaders' and participants' perceptions of the management of the Life Science Project in Namibia

  • Authors: Kirkegaard, Niels Hugo
  • Date: 2002
  • Subjects: Life Science Project (Namibia) Educational leadership Educational leadership -- Namibia School management and organization School management and organization -- Namibia
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:1662 , http://hdl.handle.net/10962/d1003545
  • Description: After Independence in 1991, Namibia embarked on implementing a new and different educational system. This system was seen as a radical departure from the old apartheid system. The Namibian government approached Ibis, a Danish NGO, to support the change process by establishing and developing a new subject, life science, in Junior Secondary schools in Namibia through the Life Science Project (LSP). In a project of this nature, where a foreign (Danish) educational intervention in a relatively young and new democracy is the issue, cross-cultural aspects are likely to emerge, and these are the focus of this study. This half-thesis is an attempt to illuminate, not to evaluate, managerial as well as cross-cultural features of the project based on perceptions of selected Danish managers and Namibian advisory teachers from the former LSP expressed in the goal of the research: - To explore selected leaders’ and participants’ perception of the management of the Life Science Project. In line with this goal, I elected to conduct the research in the interpretive paradigm, using unstructured interviews as my chief source of data. The findings illuminate what would appear to be an inconsistency in the management of the project. The project seemed to be able to accommodate regional and even personal differences and to be flexible to internal changes. At the same time it appears that in its relationship to the external or task environment it did not show the same openness and flexibility to accommodate diversity. It is suggested that this could be a result of the apparent failure on the part of the project to clarify its own underlying values. The study also reveals interesting and unexpected perceptions of leadership, which may also be interpreted in terms of cultural values and beliefs. These two features of managerial issues could lead one to reflect upon the importance of recognising values in organisations which work across cultures.
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  • Date Issued: 2002

Magma flow inferred from AMS fabrics in a layered mafic sill, Insizwa, South Africa

  • Authors: Ferré, Eric C , Bordarier, Cecile , Marsh, Julian S
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:6733 , http://hdl.handle.net/10962/d1007543
  • Description: The Insizwa sill, is a 25-km-diameter, >1000-m-thick layered mafic intrusion, part of the Karoo Igneous Province in South Africa. The peridotitic and gabbronoritic rocks are undeformed and mineral fabrics demonstrably result from magma flow. A horizontal, centimeter-scale model layering is visible in numerous outcrops. Plagioclase crystals are both tabular and elongated. Their preferred orientation, parallel to the layering, forms a foliation and a NW–SE lineation, respectively interpreted as the magma flow plane and flow direction. Throughout the 78 stations of this study (699 specimens), magnetic susceptibilities (K[subscript m]) range from 750 to 10,000×10[superscript (−6)] SI. The magnetic anisotropy (P[subscript j]) ranges from 1.03 to 1.08. Magnetic ellipsoids are both prolate and oblate (average T[subscript j]≈0). Anisotropy of magnetic susceptibility (AMS) fabrics are dominated by multidomain to pseudo-single domain magnetite. High-field magnetic experiments indicate that the paramagnetic contribution from the mafic silicates is less than 50 percentage for low susceptibility rock types. The anisotropy results from magnetite grain shape solely as shown by no significant increase in P[subscript j] with increasing K[subscript m]. The magnetic lineation (305°, 05°) is consistent throughout the sill at various scales and coincides with the mineral lineation in average. In contrast, the magnetic foliation (125° NE 10°) is generally perpendicular to the mineral foliation and to the layering. Several explanations for this odd configuration are discussed. The variations of magnetic parameters across the layering and field observations point to a multiple injection. The magnetic lineation is consistent with the presence of a single feeder dike situated to the SE of the sill.
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  • Date Issued: 2002

Mandendende

Mandendende vanachiambela

Maybe the courts are not such a Bleak House after all - or please sir, I want some more copyright

  • Authors: Glover, Graham B
  • Date: 2002
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/70841 , vital:29749 , https://heinonline.org/HOL/P?h=hein.journals/soaf119&i=101
  • Description: In our advanced technological age the law of copyright faces tremendous challenges. In particular, the Internet has created serious problems for those who wish to enforce their proprietary rights, and to protect their textual (and other) creations from unregulated and uninhibited reproduction.
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  • Date Issued: 2002

Melatonin protects against copper‐mediated free radical damage

  • Authors: Parmar, Paresh , Limson, Janice L , Nyokong, Tebello , Daya, Santy
  • Date: 2002
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/289617 , vital:56654 , xlink:href=" https://doi.org/10.1034/j.1600-079X.2002.01859.x"
  • Description: Copper is an essential trace element which forms an integral component of many enzymes. While trace amounts of copper are needed to sustain life, excess copper is extremely toxic. Copper has been implicated in various neurodegenerative disorders, such as Wilson's and Alzheimer's diseases. Previous studies showed that melatonin, the principle secretory product of the pineal gland, binds Cupric chloride (Cu2+) and that this may have implications in copper-induced neurodegenerative diseases. In the present study, in vitro copper-mediated lipid peroxidation was induced. Melatonin (5 mM) protected against copper-mediated lipid peroxidation in liver homogenates. Electron micrographs of in vivo administered Cu2+ and melatonin show that melatonin affords some protection to rat hepatocytes in the presence of copper. Electrochemical studies performed show that melatonin, in addition to binding Cu2+, may provide protection against copper-mediated free radical damage by binding Cu1+. The findings of these studies provide further evidence for the neuroprotective role of melatonin.
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  • Date Issued: 2002

Mental illness and the consciousness of freedom: the phenomenology of psychiatric labelling

  • Authors: Bradfield, Bruce
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:6264 , http://hdl.handle.net/10962/d1007882
  • Description: Paradigmatically led by existential phenomenological premises, as formulated by Jean-Paul Sartre and Edmund Husserl specifically, this paper aims at a deconstruction of the value of psychiatric labelling in terms of the implications of such labelling for the labelled individual's experience of freedom as a conscious imperative. This work has as its intention the destabilisation of labelling as a stubborn and inexorable mechanism for social propriety and regularity, which in its unyielding classificatory brandings is.
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  • Date Issued: 2002

Metabolic responses to various combinations of gradient, load and marching speed

  • Authors: Todd, Andrew I , Scott, Patricia A
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:6751 , http://hdl.handle.net/10962/d1009331
  • Description: This study examined the metabolic cost of South African soldiers carrying loads under various conditions of gradient and marching speed. Thirty-two male soldiers participated in the study. Three speed and load combinations, 4, 5 and 6 km.h[superscript (-1)] carrying of 50, 35 and 20 kg respectively, were imposed, on each of three gradients: -10%, 0% and +10%; a total of nine experimental conditions. Subjects wore standardized military uniforms and breathed into a portable ergospirometer (Metamax) for the duration of each condition. Subjects were required to march for six minutes under each condition, and metabolic responses were monitored during the third and sixth minute of each condition. The metabolic responses to the three level marching conditions showed no significant differences. Marching uphill resulted in a significant increase in metabolic demands under all three speed and load onditions. Downhill marching elicited significant decreases only under the two lighter load conditions. Downhill marching with heavy loads appears to show no reduction in metabolic demands placed on soldiers.
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  • Date Issued: 2002

Minding the gaps – an investigation into language policy and practice in four Eastern Cape districts

  • Authors: Probyn, Margie J , Murray, Sarah R , Botha, Liz , Botya, Paula , Brookes, Margie , Westphal, Vivian
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:7024 , http://hdl.handle.net/10962/d1007206
  • Description: South Africa's new Language in Education Policy (LiEP) has been described as one of the most progressive in the world but few schools have implemented it. This article describes research that investigates the gap between the policy goals and what is actually happening in schools in four districts in the Eastern Cape. The research attempts to make explicit community and school language practices and the factors that support or frustrate the formation and enactment of a school language policy in these four linguistically diverse sites. It appears that school governing bodies are not well equipped to make decisions about school language policy which meet the requirements of the national LiEP and economic imperatives to acquire English override considerations of multilingualism and additive bilingualism as expressed in the policy.
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  • Date Issued: 2002

mLAN-The Current Status and Future Directions

  • Authors: Foss, Richard , Fujimori, J I
  • Date: 2002
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/427431 , vital:72438 , https://www.aes.org/e-lib/browse.cfm?elib=11224
  • Description: 'mLAN' describes a network that allows for the transmission and receipt of audio and music control data by audio devices. IEEE 1394 was chosen as the specification upon which to implement mLAN. mLAN has built on IEEE 1394 and related standards, introducing formats, structures, and procedures that enable the deployment of IEEE 1394 within a music studio context. This paper discusses these standards, their implementations, and provides pointers to the future evolution of mLAN.
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  • Date Issued: 2002

Modelling the broiler performance under small-scales and semi commercial management condition

  • Authors: Prince, Siliga Hulisani
  • Date: 2002
  • Subjects: Broilers (Chickens)
  • Language: English
  • Type: Thesis , Masters , MTech (Agricultural Management)
  • Identifier: vital:10963 , http://hdl.handle.net/10948/110 , Broilers (Chickens)
  • Description: Introduction : World poultry meat consumption consists of three major segments: broilers, turkeys, and other poultry which includes spent egg layers, spent breeder hens/males, ducks, geese, guinea-fowl, pheasants, quail, ratites, ostriches and emus. Broilers clearly dominate the world poultry consumption contributing about 70 percent to the world poultry market. Turkeys account for about eight percent while other poultry provides the balance of 22 percent (Roenick, 1998). The world broiler industry has been, and continues to be a very dynamic industry. It has been typified with unprecedented growth in terms of production. In 1961, the world produced 6.5 billion broilers. By 1990, the total annual production was a little over 27 billion broilers and by 1996, total world production had grown to 35.3 billion (Van der Sluis., 1999). This represents a fivefold increase in 35 years, and it has not stopped growing since, with world production surpassed 38 billion in 1998 (Van der Sluis., 1999). In Africa the human population was estimated to be 819.9 million, while the total poultry population of the continent was estimated as 1.133 million chickens, 15 million ducks and seven million turkeys in 1998. Production scale being 1.781701 metric tones (MT) of hen eggs, 2.269000 MT of chickens’ meat, 32.824MT of turkey meat and 52.989MT of duck meat (Gueye, 2000). Commercial poultry products are also imported and exported. For example, 12.000 metric tons of poultry meat was estimated to have been exported from South Africa in 1999, whereas 87.000 and 10.000 metric tons of poultry meat was imported into South Africa and Egypt, respectively (Gueye, 2000). In South Africa poultry production is moving toward the 21st century with the potential for increased development being greater than any other sector of the agricultural industry. The small-scale to medium-scale or semi-commercial farmer is becoming a role-player that needs to be serviced by the poultry industry (Fourie, 2000). The industry will have to take up the challenges that are facing an entrepreneur starting with a poultry venture. The poultry industry has developed from a humble beginning at the turn of the century into a multi-million Rand enterprise where protein is provided through the commercial and small marketing sector (Fourie, 2000). Some of the larger commercial companies market three million birds per week. It is estimated that the commercial company sector is responsible for 75 to 85 percent of production and marketing of white meat in this country whereas the small-scale and medium-scale or semi commercial poultry production enterprises provide 20 to 25 percent of the white meat through the sales of slaughtered and live poultry sale to rural, peri-urban and urban settlements (Fourie., 2000). Small-scale and semi-commercial broiler production is developed by entrepreneurs who buy day-old chicks from the big commercial hatcheries, rear them to the age of five to eight weeks and sell them through a marketing network or small outlets. The small-scale consist of farmers who reared 100 t0 1000 chickens per batch and semi-commercial consist of farmers who reared 1000 to 5000 chickens per batch. These types of farmers acquire very little technical backup in terms of a training and services center where assistance is available every day of the week. The broiler industry requires birds that are of commercial crosses selected for their ability to grow very fast and produce a good quality carcass in the shortest time frame. The small farmers purchase broiler stock, as the day-old chicks from commercial hatcheries and reared them up to six to eight weeks before slaughtered or sold as live chickens. The selling of live chickens through a network outlets system is becoming an industry that is growing at a steady pace, as household food security is becoming important to communities (Fourie, 2000). The price of feed is the single most expensive item on the list of expenses of a farmer because of their financial constraints. The small-scale and semicommercial broiler farmer is faced with the problem of buying small quantities of feed at an inflated price. The problem can be alleviated by groups of small farmers joining co-operative and buying feeds in bulk from suppliers and redistributing to small farmers. The community co-operative can once again play a major role in the distribution of small amounts of feed to its member. The biggest challenge is to provide training with a “hands on” approach. It will be ideal to have a training center where small farmers can be trained in all aspects of poultry production. The training facility will have to operate as a fully operational poultry unit with no risks to bio-security of a commercial enterprise. Training will have to be provided in aspects like hatchery, housing, broilers and record management depending on the farmer’s needs. There is also a need for the research on broiler performance under small-scale and semi commercial farming. Research in this sector of poultry production should look in appropriate feeds, feeding, technology, genotype and performance of genotypes under the system. Emphasis in this study will be on growth patterns and performance of the Ross hybrids as a modern broiler under small-scale and semi commercial management condition. Aspect of the environment such as age, type of feeds and feeding methods, housing, seasons, lighting and genotype will be taken into consideration. The result of the study will provide a realistic database for mathematical modeling of production response and guideline for management planning in small-scale and semi-commercial management condition. Also this result will be important to broiler breeders, to determine the suitability of the modern broiler to small-scale and semi commercial management conditions. The objective of the study was to evaluate the mathematical model that could describe the performance of broilers under the small-scale and semi-commercial management conditions.
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  • Date Issued: 2002

Modelling the distribution and abundance of several demersal fish species on the Agulhas Bank, South Africa

  • Authors: Sampson, Mark Robert
  • Date: 2002
  • Subjects: Fishes -- South Africa -- Geographical distribution , Fishes -- South Africa -- Geographical distribution -- Mathematical models
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5343 , http://hdl.handle.net/10962/d1006207 , Fishes -- South Africa -- Geographical distribution , Fishes -- South Africa -- Geographical distribution -- Mathematical models
  • Description: The Agulhas Bank supports a speciose fish community, many of which are commercially important. Despite substantial research being conducted on aspects of their biology spatial aspects of their distribution and abundance in relation to environment parameters has been ignored. This study, therefore, addressed aspects related to the distribution and abundance of representative species on the Agulhas Bank within a Geographic Information System (GIS). Four candidate species were chosen due to their importance either in numbers or unit mass to the South African demersal trawl fishery. The species also shared morphological and taxonomic similarities. The candidate species chosen were the two Cape hake species, shallow-water hake Meluccius capensis, and deep-water hake Merluccius paradoxus, and the two pleuronectiform species being Agulhas sole Austroglossus pectoralis and redspotted tonguesole Cynoglossus zanzibarensis. The use of a GIS was appropriate and allowed for hidden spatial patterns be exposed and illustrated visually, while also facilitating the quantification of the relationships between distribution/abundance and certain environmental predictors using statistical methods The Department of Marine and Coastal Management, Cape Town, supplied biological data in the form of length frequency and biomass information from spring (AprillMay) and autumn (September/October) cruises conducted between 1986 and 1993 on the R. V. Africana. The Council for National Geoscience, Cape Town, supplied sediment data for the entire southern African coastline. Initial exploratory data analysis highlighted potential relationships between environmental variables and abundance for each specie's life-history stanzas. Variations in spatial distribution were found to be significantly different between each life-history stanzas within species. Fish density as a function of the additive effects of the various environmental parameters, including temperature, depth and sediment type, was assessed using a Poisson Generalized Additive Model (GAM), while distribution was analysed with a logistic GAM. A predictive logistic model was then created, taking into consideration the importance of the predictor variables for each species, allowing for predictive estimates to be made for each species by inputting environmental information within the study area. The importance of certain environmental variables influencing distribution and abundance were noted. General patterns indicated that sediment was the most important to both the distribution and abundance of the two pleuronectiform species and juvenile life-history stanzas, while the adult gadoids' distribution and abundance appeared to be depth dependent.
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  • Date Issued: 2002

Naming students problems: an analysis of language-related discourses at a South African university

  • Authors: Boughey, Chrissie
  • Date: 2002
  • Language: English
  • Type: Article
  • Identifier: vital:6086 , http://hdl.handle.net/10962/d1008484 , http://www.tandfonline.com/doi/pdf/10.1080/13562510220144798
  • Description: This article examines a number of discourses that construct students 'problems' as they engage with tertiary study at a historically black South African university. These dominant discourses are then linked to Street's 'autonomous' model of literacy and Rampton's 'autonomous' model of applied linguistics in order to interrogate their ideological biases. Implications of the discourses for the provision of epistemological access to tertiary study are then explored. The article ends by indicating how a 'literacy across the curriculum' approach to working with students' difficulties could provide an alternative to current 'remedial' programmes.
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  • Date Issued: 2002
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