Career choices of Rhodes University academics : internal and external influences on the decision making process
- Authors: Rippon, Tamsyn
- Date: 2014
- Subjects: Rhodes University -- Vocational guidance , Vocational guidance , Career development -- South Africa -- Grahamstown , College teachers -- Job satisfaction -- South Africa -- Grahamstown , Universities and colleges -- Faculty , Qualitative research
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3229 , http://hdl.handle.net/10962/d1013074
- Description: The career choice process, which emphasises the term ‘choice’, is one which is characterised by an ever changing multi-layered progression (Ozbilgin, Kusku & Erdogmus, 2004). This is due to the choice being a result of the on-going interaction between an individual and their social and organisational contexts. It is then safe to assume that this career decision making process involves an awareness of an individual’s surrounding environment and an ability to acknowledge and understand what they regard as being important to them. In support of this understanding, this research project seeks to draw attention to the career influences of a specific group of professionals rather than researching career choices across a range of professionals within different contexts in efforts to broadly predict career choice behaviour. This study rather focuses on the factors that actively influenced the career choices of ten Rhodes University Academics across a range of disciplines and faculties and their individual career decision making processes. In drawing on “mainstream and heterodox” (Ozbilgin et al., 2004, p. 2) literature, this research aims to apply existing notions presented by past researchers to South African academics, now residing and working at Rhodes University, which is located in the small town of Grahamstown, Eastern Cape. The methods of qualitative inductive research are discussed and the results are explored within the settings and contexts unique to each individual who has been drawn to the specific University context. The purpose of the study is to therefore adopt an inductive thematic analysis approach in seeking to examine the internal and external factors that served to influence the sample of academics into their chosen discipline, their decision to become and academic and their employer of choice, in light of the increasing pressure on higher education institutions to contribute to social and economic transformation within the South Africa (Tettey, 2006).
- Full Text:
- Authors: Rippon, Tamsyn
- Date: 2014
- Subjects: Rhodes University -- Vocational guidance , Vocational guidance , Career development -- South Africa -- Grahamstown , College teachers -- Job satisfaction -- South Africa -- Grahamstown , Universities and colleges -- Faculty , Qualitative research
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3229 , http://hdl.handle.net/10962/d1013074
- Description: The career choice process, which emphasises the term ‘choice’, is one which is characterised by an ever changing multi-layered progression (Ozbilgin, Kusku & Erdogmus, 2004). This is due to the choice being a result of the on-going interaction between an individual and their social and organisational contexts. It is then safe to assume that this career decision making process involves an awareness of an individual’s surrounding environment and an ability to acknowledge and understand what they regard as being important to them. In support of this understanding, this research project seeks to draw attention to the career influences of a specific group of professionals rather than researching career choices across a range of professionals within different contexts in efforts to broadly predict career choice behaviour. This study rather focuses on the factors that actively influenced the career choices of ten Rhodes University Academics across a range of disciplines and faculties and their individual career decision making processes. In drawing on “mainstream and heterodox” (Ozbilgin et al., 2004, p. 2) literature, this research aims to apply existing notions presented by past researchers to South African academics, now residing and working at Rhodes University, which is located in the small town of Grahamstown, Eastern Cape. The methods of qualitative inductive research are discussed and the results are explored within the settings and contexts unique to each individual who has been drawn to the specific University context. The purpose of the study is to therefore adopt an inductive thematic analysis approach in seeking to examine the internal and external factors that served to influence the sample of academics into their chosen discipline, their decision to become and academic and their employer of choice, in light of the increasing pressure on higher education institutions to contribute to social and economic transformation within the South Africa (Tettey, 2006).
- Full Text:
Career success for women academics in higher education: choices and challenges
- Authors: Obers, Nöelle Marie Thérèse
- Date: 2014
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/61346 , vital:28017 , http://0-journals.co.za.wam.seals.ac.za/content/high/28/3/EJC159132
- Description: The aim of the research reported on in this article was to contribute to an understanding of how women academics experience career success; how their choices and challenges impact on their career advancement; and how the playing fields in academia can be levelled. Understanding the constraints and identifying enabling aspects may help women academics to overcome obstacles in their career development and be more represented in academia and ultimately in society. This research was a case study undertaken at one higher education institution (HEI), Rhodes University (RU). The data was collected from institutional documents; questionnaire data from women academics at the HEI; and in-depth interviews with six women academics. The data indicate that mentoring is a strategy to enhance levels of self-esteem and research productivity and ultimately improve the representation of women in leadership and senior positions.
- Full Text:
- Authors: Obers, Nöelle Marie Thérèse
- Date: 2014
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/61346 , vital:28017 , http://0-journals.co.za.wam.seals.ac.za/content/high/28/3/EJC159132
- Description: The aim of the research reported on in this article was to contribute to an understanding of how women academics experience career success; how their choices and challenges impact on their career advancement; and how the playing fields in academia can be levelled. Understanding the constraints and identifying enabling aspects may help women academics to overcome obstacles in their career development and be more represented in academia and ultimately in society. This research was a case study undertaken at one higher education institution (HEI), Rhodes University (RU). The data was collected from institutional documents; questionnaire data from women academics at the HEI; and in-depth interviews with six women academics. The data indicate that mentoring is a strategy to enhance levels of self-esteem and research productivity and ultimately improve the representation of women in leadership and senior positions.
- Full Text:
Challenging desire : performing whiteness in post-apartheid South Africa
- Authors: Smit, Sonja
- Date: 2014
- Subjects: Performance art -- South Africa , Bailey, Brett, 1967- , Cohen, Steven, 1962- , Antwoord (Musical group) , MacGarry, Michael , Eurocentrism -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2164 , http://hdl.handle.net/10962/d1016358
- Description: The central argument of this thesis asserts that in the process of challenging dominant subject positions, such as whiteness, performance creates the possibilities for new or alternative arrangements of desire. It examines how the creative process of desire is forestalled (reified) by habitual representations of whiteness as a privileged position, and proposes that performance can be a valid form of resistance to static conceptions of race and subjectivity. The discussion takes into account how the privilege of whiteness finds representation through forms of neo-liberalism and neo-colonialism in the post apartheid context. The analysis focuses on the work of white South African artists whose work offers a critique from within the privileged “centre” of whiteness. The research is situated within the inter-disciplinary field of performance studies entailing a reading and application of critical texts to the analysis. Alongside this qualitative methodology surfaces a subjective dialogue with the information presented on whiteness. Part Two includes an analysis of Steven Cohen’s The Cradle of Humankind (2011), Brett Bailey’s Exhibit A (2011) and Michael MacGarry’s LHR-JNB (2010). Each section examines the way in which the respective works engage in a questioning of whiteness through performance. Part Three investigates South African rap-rave duo, Die Antwoord and how their appropriation of Zef interrogates desires for an essential authenticity. Part Four focuses on my own performance practice and the proposed value of engaging with a form of practice-led research. This is particularly relevant in relation to critical race studies that require a level of self-reflexivity from the researcher. It presents an analysis of the work entitled Villain (2012) as a disturbance of theatrical desire through a process of ‘becoming’. This notion of meaning and identity as ‘becoming’ is argued as a strategy to challenge prevailing modes of perception which can possibly restore the production of desire to the viewer. The thesis concludes with the notion that performance can offer a mode of immanent ethics which is significant in creating both vulnerable and critical forms of whiteness.
- Full Text:
- Authors: Smit, Sonja
- Date: 2014
- Subjects: Performance art -- South Africa , Bailey, Brett, 1967- , Cohen, Steven, 1962- , Antwoord (Musical group) , MacGarry, Michael , Eurocentrism -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2164 , http://hdl.handle.net/10962/d1016358
- Description: The central argument of this thesis asserts that in the process of challenging dominant subject positions, such as whiteness, performance creates the possibilities for new or alternative arrangements of desire. It examines how the creative process of desire is forestalled (reified) by habitual representations of whiteness as a privileged position, and proposes that performance can be a valid form of resistance to static conceptions of race and subjectivity. The discussion takes into account how the privilege of whiteness finds representation through forms of neo-liberalism and neo-colonialism in the post apartheid context. The analysis focuses on the work of white South African artists whose work offers a critique from within the privileged “centre” of whiteness. The research is situated within the inter-disciplinary field of performance studies entailing a reading and application of critical texts to the analysis. Alongside this qualitative methodology surfaces a subjective dialogue with the information presented on whiteness. Part Two includes an analysis of Steven Cohen’s The Cradle of Humankind (2011), Brett Bailey’s Exhibit A (2011) and Michael MacGarry’s LHR-JNB (2010). Each section examines the way in which the respective works engage in a questioning of whiteness through performance. Part Three investigates South African rap-rave duo, Die Antwoord and how their appropriation of Zef interrogates desires for an essential authenticity. Part Four focuses on my own performance practice and the proposed value of engaging with a form of practice-led research. This is particularly relevant in relation to critical race studies that require a level of self-reflexivity from the researcher. It presents an analysis of the work entitled Villain (2012) as a disturbance of theatrical desire through a process of ‘becoming’. This notion of meaning and identity as ‘becoming’ is argued as a strategy to challenge prevailing modes of perception which can possibly restore the production of desire to the viewer. The thesis concludes with the notion that performance can offer a mode of immanent ethics which is significant in creating both vulnerable and critical forms of whiteness.
- Full Text:
Challenging hegemony? : a provincial perspective on the limits of policy challenge in the South African state
- Authors: Reynolds, John
- Date: 2014 , 2014-06-24
- Subjects: Community development -- South Africa -- Eastern Cape , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3372 , http://hdl.handle.net/10962/d1013031
- Description: This thesis provides a provincial perspective on the limits of policy challenge within the post-apartheid South African state. This perspective is located in the Eastern Cape Province of South Africa, which is one of the poorest of the nine provinces into which the national territory was divided during the constitutional negotiations prior to the landmark democratic elections of 1994. The empirical foundation for this perspective is an analysis of the process of developing the Eastern Cape Provincial Growth and Development Plan 2004-2014 (PGDP), which took place in 2002-2004. Starting with a broader theoretical discussion, followed by a brief contextual analysis of the South African economy, the structure of the post-apartheid South African state, and key growth and development policies, the more detailed engagement with the PGDP process is undertaken. Drawing on Jessop’s (2008) strategic-relational approach, this thesis argues that the PGDP process arose within a particular spatio-temporal context where new opportunities for policy challenge were possible, but that such challenge had to be negotiated on a strategically selective terrain on which that challenge was neutralised. The PGDP process unfolded as a complex dialectic of agency and a range of path-dependent institutional processes with varying temporal and spatial horizons (cf. Pierson, 2004, 2005) in which no particular outcomes were guaranteed, but in terms of which some outcomes were more likely than others. Although the organisation of state power was expressed in the content of the PGDP, that power had to be understood as fractured across a range of state and non-state institutions, but with the state as the primary site of the contingent organisation of power. The provincial sphere of government faces particular constraints with the South African state, which has implications for its policy scope and the possibilities of policy challenge, even where wider social support is achieved.
- Full Text:
- Authors: Reynolds, John
- Date: 2014 , 2014-06-24
- Subjects: Community development -- South Africa -- Eastern Cape , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3372 , http://hdl.handle.net/10962/d1013031
- Description: This thesis provides a provincial perspective on the limits of policy challenge within the post-apartheid South African state. This perspective is located in the Eastern Cape Province of South Africa, which is one of the poorest of the nine provinces into which the national territory was divided during the constitutional negotiations prior to the landmark democratic elections of 1994. The empirical foundation for this perspective is an analysis of the process of developing the Eastern Cape Provincial Growth and Development Plan 2004-2014 (PGDP), which took place in 2002-2004. Starting with a broader theoretical discussion, followed by a brief contextual analysis of the South African economy, the structure of the post-apartheid South African state, and key growth and development policies, the more detailed engagement with the PGDP process is undertaken. Drawing on Jessop’s (2008) strategic-relational approach, this thesis argues that the PGDP process arose within a particular spatio-temporal context where new opportunities for policy challenge were possible, but that such challenge had to be negotiated on a strategically selective terrain on which that challenge was neutralised. The PGDP process unfolded as a complex dialectic of agency and a range of path-dependent institutional processes with varying temporal and spatial horizons (cf. Pierson, 2004, 2005) in which no particular outcomes were guaranteed, but in terms of which some outcomes were more likely than others. Although the organisation of state power was expressed in the content of the PGDP, that power had to be understood as fractured across a range of state and non-state institutions, but with the state as the primary site of the contingent organisation of power. The provincial sphere of government faces particular constraints with the South African state, which has implications for its policy scope and the possibilities of policy challenge, even where wider social support is achieved.
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Change in narrative therapy : a pragmatic hermeneutic case study
- Authors: McLean, Neville Terence
- Date: 2014
- Subjects: Narrative therapy
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3235 , http://hdl.handle.net/10962/d1013164
- Description: The client of this case study was a twenty two year old female in her first year at university. The client had come into therapy because she had felt depressed, lonely and riddled with selfdoubt. The author used a Narrative Therapy approach with the client and was focussed on helping the client generate new meanings and stories that were more useful and empowering for the client. In this case study, the author was interested in exploring the process of change that the client underwent during the therapy process and he would rely on identifying innovative moments to track these changes. This interest informed the research question; what is the process of change in narrative therapy as tracked through the therapeutic dialogue? How does the change process in this case study track with the heuristic model of change put forward by Gonçalves and his colleagues? The author chose to use a pragmatic hermeneutic case study method in order to analyse the data and the results were organised into a coherent narrative. The data was collected from twenty two therapy sessions and these were grouped together into themes, namely a quick start, the beginning of change, thickening the innovative moments and lighting the fire. The results of this study reveal that despite being considered a good outcome case by the author, the process of change differed somewhat to that proposed by the heuristic model of change.
- Full Text:
- Authors: McLean, Neville Terence
- Date: 2014
- Subjects: Narrative therapy
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3235 , http://hdl.handle.net/10962/d1013164
- Description: The client of this case study was a twenty two year old female in her first year at university. The client had come into therapy because she had felt depressed, lonely and riddled with selfdoubt. The author used a Narrative Therapy approach with the client and was focussed on helping the client generate new meanings and stories that were more useful and empowering for the client. In this case study, the author was interested in exploring the process of change that the client underwent during the therapy process and he would rely on identifying innovative moments to track these changes. This interest informed the research question; what is the process of change in narrative therapy as tracked through the therapeutic dialogue? How does the change process in this case study track with the heuristic model of change put forward by Gonçalves and his colleagues? The author chose to use a pragmatic hermeneutic case study method in order to analyse the data and the results were organised into a coherent narrative. The data was collected from twenty two therapy sessions and these were grouped together into themes, namely a quick start, the beginning of change, thickening the innovative moments and lighting the fire. The results of this study reveal that despite being considered a good outcome case by the author, the process of change differed somewhat to that proposed by the heuristic model of change.
- Full Text:
Changes and continuities in the labour process on commercial farms in post-Apartheid South Africa : studies from Eastern Cape and KwaZulu-Natal Provinces
- Authors: Kheswa, Nomzamo Sybil
- Date: 2014
- Subjects: Agricultural laborers -- South Africa -- Eastern Cape , Agricultural laborers -- South Africa -- KwaZulu-Natal , Agricultural wages -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- KwaZulu-Natal , Eastern Cape (South Africa) -- Rural conditions , KwaZulu-Natal (South Africa) -- Rural conditions , Agricultural laborers -- South Africa -- Eastern Cape -- Social conditions , Agricultural laborers -- South Africa -- KwaZulu-Natal -- Social conditions , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- KwaZulu-Natal , Apartheid -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3366 , http://hdl.handle.net/10962/d1011978 , Agricultural laborers -- South Africa -- Eastern Cape , Agricultural laborers -- South Africa -- KwaZulu-Natal , Agricultural wages -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- KwaZulu-Natal , Eastern Cape (South Africa) -- Rural conditions , KwaZulu-Natal (South Africa) -- Rural conditions , Agricultural laborers -- South Africa -- Eastern Cape -- Social conditions , Agricultural laborers -- South Africa -- KwaZulu-Natal -- Social conditions , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- KwaZulu-Natal , Apartheid -- South Africa
- Description: This thesis examines the agricultural labour process on commercial farms in post-apartheid South Africa with a particular focus on systems of labour control on these farms. Considerable literature exists about the labour process in capitalist society but the capitalist labour process does not exist in any pure form. Rather, different labour processes exist and the specific form they take depends on spatial and temporal conditions. Additionally, labour processes are often economic sector-specific. Because of variation in capitalist labour processes, differences in systems of labour control (or labour control regimes) also arise. Historically, up until the end of apartheid in 1994, the labour control regime on commercial farms in South Africa was marked by a paternalistic despotism of a racialised kind. This in part reflected the fact that commercial farms were simultaneously sites of both economic production and social reproduction and, further, they were very privatised agrarian spaces largely unregulated (specifically with regard to labour) by the state. Since the end of apartheid, commercial farms have been subjected to multiple pressures. Notably, the South African state has strongly intervened in labour relations on commercial farms, and commercial farms have been subjected to ongoing neo-liberal restructuring. This has led to the prospects of changes in the prevailing labour control system on commercial farms. In this context, the thesis pursues the following key objective: to understand changes and continuities in the labour process on commercial farms – and particularly labour control systems – subsequent to the end of apartheid in South Africa. It does so with reference to four farms in Eastern Cape and KwaZulu-Natal Provinces.
- Full Text:
- Authors: Kheswa, Nomzamo Sybil
- Date: 2014
- Subjects: Agricultural laborers -- South Africa -- Eastern Cape , Agricultural laborers -- South Africa -- KwaZulu-Natal , Agricultural wages -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- KwaZulu-Natal , Eastern Cape (South Africa) -- Rural conditions , KwaZulu-Natal (South Africa) -- Rural conditions , Agricultural laborers -- South Africa -- Eastern Cape -- Social conditions , Agricultural laborers -- South Africa -- KwaZulu-Natal -- Social conditions , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- KwaZulu-Natal , Apartheid -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3366 , http://hdl.handle.net/10962/d1011978 , Agricultural laborers -- South Africa -- Eastern Cape , Agricultural laborers -- South Africa -- KwaZulu-Natal , Agricultural wages -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- KwaZulu-Natal , Eastern Cape (South Africa) -- Rural conditions , KwaZulu-Natal (South Africa) -- Rural conditions , Agricultural laborers -- South Africa -- Eastern Cape -- Social conditions , Agricultural laborers -- South Africa -- KwaZulu-Natal -- Social conditions , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa -- KwaZulu-Natal , Apartheid -- South Africa
- Description: This thesis examines the agricultural labour process on commercial farms in post-apartheid South Africa with a particular focus on systems of labour control on these farms. Considerable literature exists about the labour process in capitalist society but the capitalist labour process does not exist in any pure form. Rather, different labour processes exist and the specific form they take depends on spatial and temporal conditions. Additionally, labour processes are often economic sector-specific. Because of variation in capitalist labour processes, differences in systems of labour control (or labour control regimes) also arise. Historically, up until the end of apartheid in 1994, the labour control regime on commercial farms in South Africa was marked by a paternalistic despotism of a racialised kind. This in part reflected the fact that commercial farms were simultaneously sites of both economic production and social reproduction and, further, they were very privatised agrarian spaces largely unregulated (specifically with regard to labour) by the state. Since the end of apartheid, commercial farms have been subjected to multiple pressures. Notably, the South African state has strongly intervened in labour relations on commercial farms, and commercial farms have been subjected to ongoing neo-liberal restructuring. This has led to the prospects of changes in the prevailing labour control system on commercial farms. In this context, the thesis pursues the following key objective: to understand changes and continuities in the labour process on commercial farms – and particularly labour control systems – subsequent to the end of apartheid in South Africa. It does so with reference to four farms in Eastern Cape and KwaZulu-Natal Provinces.
- Full Text:
Characterization and application of phthalocyanine-magnetic nanoparticle conjugates anchored to electrospun polyamide nanofibers
- Authors: Ledwaba, Mpho
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54610 , vital:26593
- Description: This work presents the syntheses, photophysical and photochemical characterization of zinc tetracarboxyphenoxy phthalocyanine (ZnTCPPc, 3) and its gadolinium oxide nanoparticle conjugate (4). By means of spectroscopic and microscopic characterization, the conjugation of the ZnTCPPc to the silica coated gadolinium oxide nanoparticles (Si-Gd2O3 NPs, 2) through an amide bond was confirmed. The thermal stability, morphology, nanoparticle sizes and their conjugates with the Pc were studied using ThermoGravimetric Analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and powder X-ray diffractometry (XRD). Conjugation of ZnTCPPc to the magnetic nanoparticles, proved to have a negligible effect on the photophysical parameters of the phthalocyanine, where a slight decrease in fluorescence and triplet quantum yields and lifetimes was observed. The singlet oxygen quantum yield, however, increased slightly upon conjugation, suggesting that the overall efficiency of the ZnTCPPc as a photosensitizer had improved. Physical mixing of the ZnTCPPc and the silica-coated gadolinium nanoparticles also showed an improvement in the singlet oxygen quantum yield and triplet lifetime, also showing an enhanced efficiency for the photosensitizer and therefore photocatalysis. ZnTCPPc (3) alone and the Pc-gadolinium oxide nanoparticle conjugate (4) were therefore electrospun into nanofibers to create a solid support. The fibers were characterized and their diameter sizes and composition was studied confirming the incorporation of the phthalocyanine and gadolinium oxide nanoparticle. Increased singlet oxygen generation resulted in increased Photodegradation of the environmental pollutant Orange G and the fibers were found to be more efficient as photocatalysts compared to the photosensitizer in solution. The nanomaterial may therefore be applied to the photodegradation of Orange G.
- Full Text:
- Authors: Ledwaba, Mpho
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54610 , vital:26593
- Description: This work presents the syntheses, photophysical and photochemical characterization of zinc tetracarboxyphenoxy phthalocyanine (ZnTCPPc, 3) and its gadolinium oxide nanoparticle conjugate (4). By means of spectroscopic and microscopic characterization, the conjugation of the ZnTCPPc to the silica coated gadolinium oxide nanoparticles (Si-Gd2O3 NPs, 2) through an amide bond was confirmed. The thermal stability, morphology, nanoparticle sizes and their conjugates with the Pc were studied using ThermoGravimetric Analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and powder X-ray diffractometry (XRD). Conjugation of ZnTCPPc to the magnetic nanoparticles, proved to have a negligible effect on the photophysical parameters of the phthalocyanine, where a slight decrease in fluorescence and triplet quantum yields and lifetimes was observed. The singlet oxygen quantum yield, however, increased slightly upon conjugation, suggesting that the overall efficiency of the ZnTCPPc as a photosensitizer had improved. Physical mixing of the ZnTCPPc and the silica-coated gadolinium nanoparticles also showed an improvement in the singlet oxygen quantum yield and triplet lifetime, also showing an enhanced efficiency for the photosensitizer and therefore photocatalysis. ZnTCPPc (3) alone and the Pc-gadolinium oxide nanoparticle conjugate (4) were therefore electrospun into nanofibers to create a solid support. The fibers were characterized and their diameter sizes and composition was studied confirming the incorporation of the phthalocyanine and gadolinium oxide nanoparticle. Increased singlet oxygen generation resulted in increased Photodegradation of the environmental pollutant Orange G and the fibers were found to be more efficient as photocatalysts compared to the photosensitizer in solution. The nanomaterial may therefore be applied to the photodegradation of Orange G.
- Full Text:
Characterization of electrodes modified by one pot or step by step electro-click reaction and axial ligation of iron tetracarboxyphthalocyanine
- Maringa, Audacity, Mashazi, Philani N, Nyokong, Tebello
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193892 , vital:45403 , xlink:href="https://doi.org/10.1016/j.electacta.2014.09.011"
- Description: The modification of the glassy carbon electrode (GCE) was carried out using two methods. The first method is simultaneous electropolymerization and electro-click followed by immersion into a solution of dimethyl formamide (DMF) containing FeTCPc. The second method is step by step whereby electropolymerization is carried out first followed by electro-click and then immersion into a DMF solution containing FeTCPc. From the electrochemical characterization, it was observed that the second route (step by step method) was the best as indicated by the ferricyanide studies (cyclic voltammetry and scanning electrochemical microscopy). In the electrooxidation of hydrazine, we obtained a potential of 0.26 V. Of interest were the detection limit of 6.4 μM and the catalytic rate constant of 2.1 × 109 cm3 mol−1 s−1. This shows that the sensor can be used for the electrooxidation of hydrazine.
- Full Text:
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193892 , vital:45403 , xlink:href="https://doi.org/10.1016/j.electacta.2014.09.011"
- Description: The modification of the glassy carbon electrode (GCE) was carried out using two methods. The first method is simultaneous electropolymerization and electro-click followed by immersion into a solution of dimethyl formamide (DMF) containing FeTCPc. The second method is step by step whereby electropolymerization is carried out first followed by electro-click and then immersion into a DMF solution containing FeTCPc. From the electrochemical characterization, it was observed that the second route (step by step method) was the best as indicated by the ferricyanide studies (cyclic voltammetry and scanning electrochemical microscopy). In the electrooxidation of hydrazine, we obtained a potential of 0.26 V. Of interest were the detection limit of 6.4 μM and the catalytic rate constant of 2.1 × 109 cm3 mol−1 s−1. This shows that the sensor can be used for the electrooxidation of hydrazine.
- Full Text:
Characterization of the Hsp40 partner proteins of Plasmodium falciparum Hsp70
- Authors: Njunge, James Mwangi
- Date: 2014
- Subjects: Plasmodium falciparum , Heat shock proteins , Malaria -- Chemotherapy , Protein-protein interactions , Erythrocytes -- Biotechnology , Molecular chaperones , Host-parasite relationships , Mitochondria
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4117 , http://hdl.handle.net/10962/d1013186
- Description: Human malaria is an economically important disease caused by single-celled parasites of the Plasmodium genus whose biology displays great evolutionary adaptation to both its mammalian host and transmitting vectors. This thesis details the 70 kDa heat shock protein (Hsp70) and J protein chaperone complements in malaria parasites affecting humans, primates and rodents. Heat shock proteins comprise a family of evolutionary conserved and structurally related proteins that play a crucial role in maintaining the structural integrity of proteins during normal and stress conditions. They are considered future therapeutic targets in various cellular systems including Plasmodium falciparum. J proteins (Hsp40) canonically partner with Hsp70s during protein synthesis and folding, trafficking or targeting of proteins for degradation. However, in P. falciparum, these classes of proteins have also been implicated in aiding the active transport of parasite proteins to the erythrocyte cytosol following erythrocyte entry by the parasite. This host-parasite “cross-talk” results in tremendous modifications of the infected erythrocyte, imparting properties that allow it to adhere to the endothelium, preventing splenic clearance. The genome of P. falciparum encodes six Hsp70 homologues and a large number of J proteins that localize to the various intracellular compartments or are exported to the infected erythrocyte cytosol. Understanding the Hsp70-J protein interactions and/or partnerships is an essential step for drug target validation and illumination of parasite biology. A review of these chaperone complements across the Plasmodium species shows that P. falciparum possesses an expanded Hsp70-J protein complement compared to the rodent and primate infecting species. It further highlights how unique the P. falciparum chaperone complement is compared to the other Plasmodium species included in the analysis. In silico analysis showed that the genome of P. falciparum encodes approximately 49 J proteins, 19 of which contain a PEXEL motif that has been implicated in routing proteins to the infected erythrocyte. Most of these PEXEL containing J proteins are unique with no homologues in the human system and are considered as attractive drug targets. Very few of the predicted J proteins in P. falciparum have been experimentally characterized. To this end, cell biological and biochemical approaches were employed to characterize PFB0595w and PFD0462w (Pfj1) J proteins. The uniqueness of Pfj1 and the controversy in literature regarding its localization formed the basis for the experimental work. This is the first study showing that Pfj1 localizes to the mitochondrion in the intraerythrocytic stage of development of P. falciparum and has further proposed PfHsp70-3 as a potential Hsp70 partner. Indeed, attempts to heterologously express and purify Pfj1 for its characterization are described. It is also the first study that details the successful expression and purification of PfHsp70-3. Further, research findings have described for the first time the expression and localization of PFB0595w in the intraerythrocytic stages of P. falciparum development. Based on the cytosolic localization of both PFB0595w and PfHsp70-1, a chaperone – cochaperone partnership was proposed that formed the basis for the in vitro experiments. PFB0595w was shown for the first time to stimulate the ATPase activity of PfHsp70-1 pointing to a functional interaction. Preliminary surface plasmon spectroscopy analysis has revealed a potential interaction between PFB0595w and PfHsp70-1 but highlights the need for further related experiments to support the findings. Gel filtration analysis showed that PFB0595w exists as a dimer thereby confirming in silico predictions. Based on these observations, we conclude that PFB0595w may regulate the chaperone activity of PfHsp70-1 in the cytosol while Pfj1 may play a co-chaperoning role for PfHsp70-3 in the mitochondrion. Overall, this data is expected to increase the knowledge of the Hsp70-J protein partnerships in the erythrocytic stage of P. falciparum development, thereby enhancing the understanding of parasite biology.
- Full Text:
- Authors: Njunge, James Mwangi
- Date: 2014
- Subjects: Plasmodium falciparum , Heat shock proteins , Malaria -- Chemotherapy , Protein-protein interactions , Erythrocytes -- Biotechnology , Molecular chaperones , Host-parasite relationships , Mitochondria
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4117 , http://hdl.handle.net/10962/d1013186
- Description: Human malaria is an economically important disease caused by single-celled parasites of the Plasmodium genus whose biology displays great evolutionary adaptation to both its mammalian host and transmitting vectors. This thesis details the 70 kDa heat shock protein (Hsp70) and J protein chaperone complements in malaria parasites affecting humans, primates and rodents. Heat shock proteins comprise a family of evolutionary conserved and structurally related proteins that play a crucial role in maintaining the structural integrity of proteins during normal and stress conditions. They are considered future therapeutic targets in various cellular systems including Plasmodium falciparum. J proteins (Hsp40) canonically partner with Hsp70s during protein synthesis and folding, trafficking or targeting of proteins for degradation. However, in P. falciparum, these classes of proteins have also been implicated in aiding the active transport of parasite proteins to the erythrocyte cytosol following erythrocyte entry by the parasite. This host-parasite “cross-talk” results in tremendous modifications of the infected erythrocyte, imparting properties that allow it to adhere to the endothelium, preventing splenic clearance. The genome of P. falciparum encodes six Hsp70 homologues and a large number of J proteins that localize to the various intracellular compartments or are exported to the infected erythrocyte cytosol. Understanding the Hsp70-J protein interactions and/or partnerships is an essential step for drug target validation and illumination of parasite biology. A review of these chaperone complements across the Plasmodium species shows that P. falciparum possesses an expanded Hsp70-J protein complement compared to the rodent and primate infecting species. It further highlights how unique the P. falciparum chaperone complement is compared to the other Plasmodium species included in the analysis. In silico analysis showed that the genome of P. falciparum encodes approximately 49 J proteins, 19 of which contain a PEXEL motif that has been implicated in routing proteins to the infected erythrocyte. Most of these PEXEL containing J proteins are unique with no homologues in the human system and are considered as attractive drug targets. Very few of the predicted J proteins in P. falciparum have been experimentally characterized. To this end, cell biological and biochemical approaches were employed to characterize PFB0595w and PFD0462w (Pfj1) J proteins. The uniqueness of Pfj1 and the controversy in literature regarding its localization formed the basis for the experimental work. This is the first study showing that Pfj1 localizes to the mitochondrion in the intraerythrocytic stage of development of P. falciparum and has further proposed PfHsp70-3 as a potential Hsp70 partner. Indeed, attempts to heterologously express and purify Pfj1 for its characterization are described. It is also the first study that details the successful expression and purification of PfHsp70-3. Further, research findings have described for the first time the expression and localization of PFB0595w in the intraerythrocytic stages of P. falciparum development. Based on the cytosolic localization of both PFB0595w and PfHsp70-1, a chaperone – cochaperone partnership was proposed that formed the basis for the in vitro experiments. PFB0595w was shown for the first time to stimulate the ATPase activity of PfHsp70-1 pointing to a functional interaction. Preliminary surface plasmon spectroscopy analysis has revealed a potential interaction between PFB0595w and PfHsp70-1 but highlights the need for further related experiments to support the findings. Gel filtration analysis showed that PFB0595w exists as a dimer thereby confirming in silico predictions. Based on these observations, we conclude that PFB0595w may regulate the chaperone activity of PfHsp70-1 in the cytosol while Pfj1 may play a co-chaperoning role for PfHsp70-3 in the mitochondrion. Overall, this data is expected to increase the knowledge of the Hsp70-J protein partnerships in the erythrocytic stage of P. falciparum development, thereby enhancing the understanding of parasite biology.
- Full Text:
Citizenship rights : still a long road to travel - Graduation Ceremonies address 2014
- Authors: Badat, Saleem
- Date: 2014
- Language: English
- Type: Text
- Identifier: vital:7872 , http://hdl.handle.net/10962/d1016421
- Description: The 20th anniversary of our democracy is a good time to reflect on the progress that we have made with respect to citizenship in post-1994 South Africa. 1994 was a revolutionary breakthrough. From being a racially exclusive authoritarian society in which millions were downtrodden subjects, we became a democracy in which for the first time almost all inhabitants became citizens. Critical here was a commendable Constitution, including a Bill of Rights, which held out the promise of an extensive range of human, social and economic rights that did not exist for all or at all prior to 1994. During the past 20 years there have been significant economic and social gains and achievements. At the same time, there continue to be many challenges, and key institutions of our democracy have come under strain as a result of too many in power seeking to use the state as their private piggy bank. Still, a relatively independent judiciary, free media, autonomous universities and the like remain intact. Witness in this regard the magnificent performance of the Public Protector’s office under Thuli Madonsela. However, a number of contemporary realities, compromise the ideal of full and substantive citizenship rights for all that the Constitution promises. Indeed, they condemn large numbers of people to conditions that are associated with subjecthood and being subjects.
- Full Text:
- Authors: Badat, Saleem
- Date: 2014
- Language: English
- Type: Text
- Identifier: vital:7872 , http://hdl.handle.net/10962/d1016421
- Description: The 20th anniversary of our democracy is a good time to reflect on the progress that we have made with respect to citizenship in post-1994 South Africa. 1994 was a revolutionary breakthrough. From being a racially exclusive authoritarian society in which millions were downtrodden subjects, we became a democracy in which for the first time almost all inhabitants became citizens. Critical here was a commendable Constitution, including a Bill of Rights, which held out the promise of an extensive range of human, social and economic rights that did not exist for all or at all prior to 1994. During the past 20 years there have been significant economic and social gains and achievements. At the same time, there continue to be many challenges, and key institutions of our democracy have come under strain as a result of too many in power seeking to use the state as their private piggy bank. Still, a relatively independent judiciary, free media, autonomous universities and the like remain intact. Witness in this regard the magnificent performance of the Public Protector’s office under Thuli Madonsela. However, a number of contemporary realities, compromise the ideal of full and substantive citizenship rights for all that the Constitution promises. Indeed, they condemn large numbers of people to conditions that are associated with subjecthood and being subjects.
- Full Text:
Classification of the difficulty in accelerating problems using GPUs
- Authors: Tristram, Uvedale Roy
- Date: 2014
- Subjects: Graphics processing units , Computer algorithms , Computer programming , Problem solving -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4699 , http://hdl.handle.net/10962/d1012978
- Description: Scientists continually require additional processing power, as this enables them to compute larger problem sizes, use more complex models and algorithms, and solve problems previously thought computationally impractical. General-purpose computation on graphics processing units (GPGPU) can help in this regard, as there is great potential in using graphics processors to accelerate many scientific models and algorithms. However, some problems are considerably harder to accelerate than others, and it may be challenging for those new to GPGPU to ascertain the difficulty of accelerating a particular problem or seek appropriate optimisation guidance. Through what was learned in the acceleration of a hydrological uncertainty ensemble model, large numbers of k-difference string comparisons, and a radix sort, problem attributes have been identified that can assist in the evaluation of the difficulty in accelerating a problem using GPUs. The identified attributes are inherent parallelism, branch divergence, problem size, required computational parallelism, memory access pattern regularity, data transfer overhead, and thread cooperation. Using these attributes as difficulty indicators, an initial problem difficulty classification framework has been created that aids in GPU acceleration difficulty evaluation. This framework further facilitates directed guidance on suggested optimisations and required knowledge based on problem classification, which has been demonstrated for the aforementioned accelerated problems. It is anticipated that this framework, or a derivative thereof, will prove to be a useful resource for new or novice GPGPU developers in the evaluation of potential problems for GPU acceleration.
- Full Text:
- Authors: Tristram, Uvedale Roy
- Date: 2014
- Subjects: Graphics processing units , Computer algorithms , Computer programming , Problem solving -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4699 , http://hdl.handle.net/10962/d1012978
- Description: Scientists continually require additional processing power, as this enables them to compute larger problem sizes, use more complex models and algorithms, and solve problems previously thought computationally impractical. General-purpose computation on graphics processing units (GPGPU) can help in this regard, as there is great potential in using graphics processors to accelerate many scientific models and algorithms. However, some problems are considerably harder to accelerate than others, and it may be challenging for those new to GPGPU to ascertain the difficulty of accelerating a particular problem or seek appropriate optimisation guidance. Through what was learned in the acceleration of a hydrological uncertainty ensemble model, large numbers of k-difference string comparisons, and a radix sort, problem attributes have been identified that can assist in the evaluation of the difficulty in accelerating a problem using GPUs. The identified attributes are inherent parallelism, branch divergence, problem size, required computational parallelism, memory access pattern regularity, data transfer overhead, and thread cooperation. Using these attributes as difficulty indicators, an initial problem difficulty classification framework has been created that aids in GPU acceleration difficulty evaluation. This framework further facilitates directed guidance on suggested optimisations and required knowledge based on problem classification, which has been demonstrated for the aforementioned accelerated problems. It is anticipated that this framework, or a derivative thereof, will prove to be a useful resource for new or novice GPGPU developers in the evaluation of potential problems for GPU acceleration.
- Full Text:
Climate Change and Environmental Challenges in Southern African Development Community (SADC): Responses in the Age of Globalisation
- Chikunda, Charles, Mandikonza, Caleb
- Authors: Chikunda, Charles , Mandikonza, Caleb
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437249 , vital:73363 , ISBN 9789462098367 , https://brill.com/display/book/9789462098367/BP000009.xml
- Description: There is evidence that one of the greatest controversies facing Africa today is how to make sense of the two leading global intentions of the 21st century: sustainable development and globalisation. These two paradigms appear to have some op-posing tendencies within them, some of which are contestable. Globalisation advocates for liberalisation; reduction or elimina-tion of state regulations on the market, free reign, and a high degree of rights to the large corporations that dominate the market. Globalisation also entails the cross flow of knowledge and knowledge forms.
- Full Text:
- Authors: Chikunda, Charles , Mandikonza, Caleb
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437249 , vital:73363 , ISBN 9789462098367 , https://brill.com/display/book/9789462098367/BP000009.xml
- Description: There is evidence that one of the greatest controversies facing Africa today is how to make sense of the two leading global intentions of the 21st century: sustainable development and globalisation. These two paradigms appear to have some op-posing tendencies within them, some of which are contestable. Globalisation advocates for liberalisation; reduction or elimina-tion of state regulations on the market, free reign, and a high degree of rights to the large corporations that dominate the market. Globalisation also entails the cross flow of knowledge and knowledge forms.
- Full Text:
Cloud information security : a higher education perspective
- Authors: Van der Schyff, Karl Izak
- Date: 2014
- Subjects: Cloud computing -- Security measures , Information technology -- Security measures , Data protection , Internet in higher education , Education, Higher -- Technological innovations
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4692 , http://hdl.handle.net/10962/d1011607 , Cloud computing -- Security measures , Information technology -- Security measures , Data protection , Internet in higher education , Education, Higher -- Technological innovations
- Description: In recent years higher education institutions have come under increasing financial pressure. This has not only prompted universities to investigate more cost effective means of delivering course content and maintaining research output, but also to investigate the administrative functions that accompany them. As such, many South African universities have either adopted or are in the process of adopting some form of cloud computing given the recent drop in bandwidth costs. However, this adoption process has raised concerns about the security of cloud-based information and this has, in some cases, had a negative impact on the adoption process. In an effort to study these concerns many researchers have employed a positivist approach with little, if any, focus on the operational context of these universities. Moreover, there has been very little research, specifically within the South African context. This study addresses some of these concerns by investigating the threats and security incident response life cycle within a higher education cloud. This was done by initially conducting a small scale survey and a detailed thematic analysis of twelve interviews from three South African universities. The identified themes and their corresponding analyses and interpretation contribute on both a practical and theoretical level with the practical contributions relating to a set of security driven criteria for selecting cloud providers as well as recommendations for universities who have or are in the process of adopting cloud computing. Theoretically several conceptual frameworks are offered allowing the researcher to convey his understanding of how the aforementioned practical concepts relate to each other as well as the concepts that constitute the research questions of this study.
- Full Text:
- Authors: Van der Schyff, Karl Izak
- Date: 2014
- Subjects: Cloud computing -- Security measures , Information technology -- Security measures , Data protection , Internet in higher education , Education, Higher -- Technological innovations
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4692 , http://hdl.handle.net/10962/d1011607 , Cloud computing -- Security measures , Information technology -- Security measures , Data protection , Internet in higher education , Education, Higher -- Technological innovations
- Description: In recent years higher education institutions have come under increasing financial pressure. This has not only prompted universities to investigate more cost effective means of delivering course content and maintaining research output, but also to investigate the administrative functions that accompany them. As such, many South African universities have either adopted or are in the process of adopting some form of cloud computing given the recent drop in bandwidth costs. However, this adoption process has raised concerns about the security of cloud-based information and this has, in some cases, had a negative impact on the adoption process. In an effort to study these concerns many researchers have employed a positivist approach with little, if any, focus on the operational context of these universities. Moreover, there has been very little research, specifically within the South African context. This study addresses some of these concerns by investigating the threats and security incident response life cycle within a higher education cloud. This was done by initially conducting a small scale survey and a detailed thematic analysis of twelve interviews from three South African universities. The identified themes and their corresponding analyses and interpretation contribute on both a practical and theoretical level with the practical contributions relating to a set of security driven criteria for selecting cloud providers as well as recommendations for universities who have or are in the process of adopting cloud computing. Theoretically several conceptual frameworks are offered allowing the researcher to convey his understanding of how the aforementioned practical concepts relate to each other as well as the concepts that constitute the research questions of this study.
- Full Text:
Collection of urban tree products by households in poorer residential areas of three South African towns
- Kaoma, Humphrey, Shackleton, Charlie M
- Authors: Kaoma, Humphrey , Shackleton, Charlie M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180980 , vital:43678 , xlink:href="https://doi.org/10.1016/j.ufug.2014.02.002"
- Description: The high rates of urban in-migration and poverty common in many developing country towns potentially increases the reliance of urban populations on the direct benefits provided by trees. Yet understanding of the extent of such use and the sources of these tree products is limited. Here we report on the extent of use of urban tree products by 450 households in the poorer areas of three towns along a rainfall gradient based on household questionnaires. We considered the proportion of households making use of each of several tree products and the collection or purchasing frequency which we disaggregated by source of the product, including trees in homesteads, urban spaces, edges of towns and via purchase from traders. Most households (91%) used firewood, which was most frequently collected from the urban fringe or purchased, although one-third at times also collected firewood from trees on their home plot. All households used fruits, most commonly sourced through purchase (98%), but nearly half of whom also supplemented by harvesting fruits from their home plot. Other products used included wood for building, fencing and utensils, herbal medicines, planting material and mulch. Collection of products from urban homestead trees was highest amongst households in the informal settlements and least in the more established townships. Residents of new low-cost housing areas made extensive use of urban tree products harvested in urban spaces because they had fewer homestead trees than residents of informal areas or townships. Overall, urban residents made use of a wide array of tangible products from trees which they sourced from a variety of places, including their homestead plot. This urges that planning agencies ensure that homestead plot sizes or other urban spaces that provide tree products are large enough to support the direct needs of poorer urban residents.
- Full Text:
- Authors: Kaoma, Humphrey , Shackleton, Charlie M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180980 , vital:43678 , xlink:href="https://doi.org/10.1016/j.ufug.2014.02.002"
- Description: The high rates of urban in-migration and poverty common in many developing country towns potentially increases the reliance of urban populations on the direct benefits provided by trees. Yet understanding of the extent of such use and the sources of these tree products is limited. Here we report on the extent of use of urban tree products by 450 households in the poorer areas of three towns along a rainfall gradient based on household questionnaires. We considered the proportion of households making use of each of several tree products and the collection or purchasing frequency which we disaggregated by source of the product, including trees in homesteads, urban spaces, edges of towns and via purchase from traders. Most households (91%) used firewood, which was most frequently collected from the urban fringe or purchased, although one-third at times also collected firewood from trees on their home plot. All households used fruits, most commonly sourced through purchase (98%), but nearly half of whom also supplemented by harvesting fruits from their home plot. Other products used included wood for building, fencing and utensils, herbal medicines, planting material and mulch. Collection of products from urban homestead trees was highest amongst households in the informal settlements and least in the more established townships. Residents of new low-cost housing areas made extensive use of urban tree products harvested in urban spaces because they had fewer homestead trees than residents of informal areas or townships. Overall, urban residents made use of a wide array of tangible products from trees which they sourced from a variety of places, including their homestead plot. This urges that planning agencies ensure that homestead plot sizes or other urban spaces that provide tree products are large enough to support the direct needs of poorer urban residents.
- Full Text:
Colonisation and community structure of benthic diatoms on artificial substrates following a major flood event: a case of the Kowie River (Eastern Cape, South Africa)
- Dalu, Tatenda, Froneman, P William, Chari, Lenin D, Richoux, Nicole B
- Authors: Dalu, Tatenda , Froneman, P William , Chari, Lenin D , Richoux, Nicole B
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143357 , vital:38239 , http://dx.doi.org/10.4314/wsa.v40i3.10
- Description: A major flooding event that occurred during October–November 2012 caused major changes in the Kowie River hydromorphology and aquatic communities. The aim of our study was to identify the environmental variables that structure riverine benthic diatom communities at upstream and downstream locations 25 km apart on the Kowie River, South Africa. This was undertaken using tiles as artificial substrates so that we could study how the communities developed after the flood disturbance. The diatom community structure was assessed over a 28-day period following a flood event in October 2012. The Mann Whitney test indicated that there was a statistically significant difference (p 0.05) in total dissolved solids, salinity, pH and oxygen reduction potential between the two sites. In total, 58 diatom species belonging to 30 genera were identified over the 28-day study.
- Full Text:
- Authors: Dalu, Tatenda , Froneman, P William , Chari, Lenin D , Richoux, Nicole B
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143357 , vital:38239 , http://dx.doi.org/10.4314/wsa.v40i3.10
- Description: A major flooding event that occurred during October–November 2012 caused major changes in the Kowie River hydromorphology and aquatic communities. The aim of our study was to identify the environmental variables that structure riverine benthic diatom communities at upstream and downstream locations 25 km apart on the Kowie River, South Africa. This was undertaken using tiles as artificial substrates so that we could study how the communities developed after the flood disturbance. The diatom community structure was assessed over a 28-day period following a flood event in October 2012. The Mann Whitney test indicated that there was a statistically significant difference (p 0.05) in total dissolved solids, salinity, pH and oxygen reduction potential between the two sites. In total, 58 diatom species belonging to 30 genera were identified over the 28-day study.
- Full Text:
Combating corruption while respecting human rights : a critical study of the non-conviction based assets recovery mechanism in Kenya and South Africa
- Authors: Obura, Ken Otieno
- Date: 2014
- Subjects: Human rights -- Kenya , Human rights -- South Africa , Corruption -- Kenya , Corruption -- South Africa , Reparation (Criminal justice) -- Kenya , Reparation (Criminal justice) -- South Africa , Political corruption -- Kenya , Political corruption -- South Africa , Corruption investigation -- Kenya , Corruption investigation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3719 , http://hdl.handle.net/10962/d1013159
- Description: The thesis contributes to the search for sound anti-corruption laws and practices that are effective and fair. It argues for the respect for human rights in the crafting and implementation of anti-corruption laws as a requisite for successful control of corruption. The basis for this argument is threefold: First, human rights provide a framework for checking against abuse of state’s police power, an abuse which if allowed to take root, would make the fight against corruption lose its legitimacy in the eye of the people. Second, human rights ensure that the interest of individuals is catered for in the crafting of anti-corruption laws and practices thereby denying perpetrators of corruption legal excuses that can be exploited to delay or frustrate corruption cases in the courts of law. Third, human rights provide a useful framework for balancing competing interests in the area of corruption control – it enables society to craft measures that fulfils the public interest in the eradication of corruption while concomitantly assuring the competing public interest in the protection of individual members’ liberties – a condition that is necessary if the support of the holders of these competing interests is to be enlisted and fostered in the fight against corruption. The thesis focuses on the study of the non-conviction based assets recovery mechanism, a mechanism that allows the state to apply a procedure lacking in criminal law safeguards to address criminal behaviour. The mechanism is thus beset with avenues for abuse, which if unchecked could have debilitating effects not only to individual liberties but also to the long term legitimacy of the fight against corruption. In this regard, the thesis examines how the human rights framework has been used in Kenya and South Africa to check on the potential dangers of the non-conviction based mechanism and to provide for a proportional balance between the imperative of corruption control and the guarantee against arbitrary deprivation of property. The aim is to unravel the benefits of respecting human rights in the fight against corruption in general and in the non-conviction based assets recovery in particular. Kenya and South Africa are chosen for study because they provide two models of non-conviction based mechanisms with different levels of safeguards, for comparative consideration.
- Full Text:
- Authors: Obura, Ken Otieno
- Date: 2014
- Subjects: Human rights -- Kenya , Human rights -- South Africa , Corruption -- Kenya , Corruption -- South Africa , Reparation (Criminal justice) -- Kenya , Reparation (Criminal justice) -- South Africa , Political corruption -- Kenya , Political corruption -- South Africa , Corruption investigation -- Kenya , Corruption investigation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3719 , http://hdl.handle.net/10962/d1013159
- Description: The thesis contributes to the search for sound anti-corruption laws and practices that are effective and fair. It argues for the respect for human rights in the crafting and implementation of anti-corruption laws as a requisite for successful control of corruption. The basis for this argument is threefold: First, human rights provide a framework for checking against abuse of state’s police power, an abuse which if allowed to take root, would make the fight against corruption lose its legitimacy in the eye of the people. Second, human rights ensure that the interest of individuals is catered for in the crafting of anti-corruption laws and practices thereby denying perpetrators of corruption legal excuses that can be exploited to delay or frustrate corruption cases in the courts of law. Third, human rights provide a useful framework for balancing competing interests in the area of corruption control – it enables society to craft measures that fulfils the public interest in the eradication of corruption while concomitantly assuring the competing public interest in the protection of individual members’ liberties – a condition that is necessary if the support of the holders of these competing interests is to be enlisted and fostered in the fight against corruption. The thesis focuses on the study of the non-conviction based assets recovery mechanism, a mechanism that allows the state to apply a procedure lacking in criminal law safeguards to address criminal behaviour. The mechanism is thus beset with avenues for abuse, which if unchecked could have debilitating effects not only to individual liberties but also to the long term legitimacy of the fight against corruption. In this regard, the thesis examines how the human rights framework has been used in Kenya and South Africa to check on the potential dangers of the non-conviction based mechanism and to provide for a proportional balance between the imperative of corruption control and the guarantee against arbitrary deprivation of property. The aim is to unravel the benefits of respecting human rights in the fight against corruption in general and in the non-conviction based assets recovery in particular. Kenya and South Africa are chosen for study because they provide two models of non-conviction based mechanisms with different levels of safeguards, for comparative consideration.
- Full Text:
Comparative phylogeography of five swallowtail butterfly species (Lepidoptera: Papilionidae) in South Africa : ecological and taxonomic implications.
- Authors: Neef, Götz-Georg
- Date: 2014
- Subjects: Swallowtail butterflies , Papilionidae -- South Africa , Phylogeography -- South Africa , Swallowtail butterflies -- Effect of habitat modification on , Biodiversity -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4266 , http://hdl.handle.net/10962/d1013574
- Description: With current biota under constant threat of extinction, it is important to ascertain where and how biological diversity is generated and partitioned. Phylogeographic studies can assist in the identification of places and processes that indicate the origin and maintenance of biodiversity. Forest fragmentation has a big effect on local extinction and loss of genetic diversity of forest-restricted taxa, along with divergence and speciation of forest biota. This study aims to understand the effects of these processes on a number of forest-dwelling butterflies using a comparative phylogeographic approach. Mitochondrial DNA of five different Papilio species with different degrees of forest specificity was analysed using phylogenetic methods. In addition, the subspecific taxonomy of P. ophidicephalus was investigated using morphometrics of discal spots on the wings and nuclear DNA analysis along with mitochondrial DNA analysis. The results show that the forest-restricted species (P. ophidicephalus and P. echerioides) have more genetic structure and less genetic diversity than the more generalist species (P. dardanus, P. demodocus and P. nireus). This could be due to inbreeding depression and bottlenecks caused by forest fragmentation. As forest patches become smaller, the population size is affected and that causes a loss in genetic diversity, and increasing habitat fragmentation disrupts gene flow. The intraspecific taxonomy of P. ophidicephalus is far from revealed. However, this study shows there is evidence for the different subspecies when comparing morphological results and genetic results. From the evidence provided here it is suggested that P. ophidicephalus should be divided into two separate species rather than five subspecies.
- Full Text:
- Authors: Neef, Götz-Georg
- Date: 2014
- Subjects: Swallowtail butterflies , Papilionidae -- South Africa , Phylogeography -- South Africa , Swallowtail butterflies -- Effect of habitat modification on , Biodiversity -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4266 , http://hdl.handle.net/10962/d1013574
- Description: With current biota under constant threat of extinction, it is important to ascertain where and how biological diversity is generated and partitioned. Phylogeographic studies can assist in the identification of places and processes that indicate the origin and maintenance of biodiversity. Forest fragmentation has a big effect on local extinction and loss of genetic diversity of forest-restricted taxa, along with divergence and speciation of forest biota. This study aims to understand the effects of these processes on a number of forest-dwelling butterflies using a comparative phylogeographic approach. Mitochondrial DNA of five different Papilio species with different degrees of forest specificity was analysed using phylogenetic methods. In addition, the subspecific taxonomy of P. ophidicephalus was investigated using morphometrics of discal spots on the wings and nuclear DNA analysis along with mitochondrial DNA analysis. The results show that the forest-restricted species (P. ophidicephalus and P. echerioides) have more genetic structure and less genetic diversity than the more generalist species (P. dardanus, P. demodocus and P. nireus). This could be due to inbreeding depression and bottlenecks caused by forest fragmentation. As forest patches become smaller, the population size is affected and that causes a loss in genetic diversity, and increasing habitat fragmentation disrupts gene flow. The intraspecific taxonomy of P. ophidicephalus is far from revealed. However, this study shows there is evidence for the different subspecies when comparing morphological results and genetic results. From the evidence provided here it is suggested that P. ophidicephalus should be divided into two separate species rather than five subspecies.
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Comparison between base metals and platinum group metals in nitrogen, M codoped TiO 2 (M= Fe, Cu, Pd, Os) for photocatalytic removal of an organic dye in water
- Kuvarega, Alex T, Mamba, Bhekie B, Krause, Rui W M
- Authors: Kuvarega, Alex T , Mamba, Bhekie B , Krause, Rui W M
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125129 , vital:35734 , https://doi.org/10.1155/2014/962102
- Description: The photocatalytic performance of a number of nonmetal and metal codoped TiO2 for the degradation of eosin yellow under simulated solar radiation was investigated. The synthesised materials were characterised by FTIR, Raman spectroscopy, XRD, DRUV-Vis, SEM, and TEM.The N, metal codoped TiO2 containing 0.5 wt.% of the metal consisted mainly of the anatase phase, with a particle size range of 15–28 nm. The particles were largely spherical and shifted the absorption edge well into the visible region. Band gap reduction was more pronounced for the N, PGM codoped TiO2 compared to N, base metal codoped samples. Codoping led to an enhancement in the photocatalytic activity of the materials for the degradation of eosin yellow. N, Pd codoped TiO2 was the most effective photocatalyst (99.9% dye removal) while N, Cu codoped TiO2 showed the least activity (25.5% removal). The mechanism for the photocatalytic enhancement was proposed on the basis of formation of an electron deficient Schottky barrier at the semiconductor-metal interface, which acts as an electron sink and thus retards electron-hole recombination. It was shown that the ability of the photocatalyst to degrade the dye depends on the nature and type of the metal dopant in the codoped TiO2 system.
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- Authors: Kuvarega, Alex T , Mamba, Bhekie B , Krause, Rui W M
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125129 , vital:35734 , https://doi.org/10.1155/2014/962102
- Description: The photocatalytic performance of a number of nonmetal and metal codoped TiO2 for the degradation of eosin yellow under simulated solar radiation was investigated. The synthesised materials were characterised by FTIR, Raman spectroscopy, XRD, DRUV-Vis, SEM, and TEM.The N, metal codoped TiO2 containing 0.5 wt.% of the metal consisted mainly of the anatase phase, with a particle size range of 15–28 nm. The particles were largely spherical and shifted the absorption edge well into the visible region. Band gap reduction was more pronounced for the N, PGM codoped TiO2 compared to N, base metal codoped samples. Codoping led to an enhancement in the photocatalytic activity of the materials for the degradation of eosin yellow. N, Pd codoped TiO2 was the most effective photocatalyst (99.9% dye removal) while N, Cu codoped TiO2 showed the least activity (25.5% removal). The mechanism for the photocatalytic enhancement was proposed on the basis of formation of an electron deficient Schottky barrier at the semiconductor-metal interface, which acts as an electron sink and thus retards electron-hole recombination. It was shown that the ability of the photocatalyst to degrade the dye depends on the nature and type of the metal dopant in the codoped TiO2 system.
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Comparison of fluorophore and peroxidase labeled aptamer assays for MUC1 detection in cancer cells
- Flanagan, Shane, Limson, Janice, Fogel, Ronen
- Authors: Flanagan, Shane , Limson, Janice , Fogel, Ronen
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431076 , vital:72742 , xlink:href="10.1109/BioCAS.2014.6981720"
- Description: Aptamers hold great promise for cancer diagnosis and therapy. Several biosensors incorporate aptamers as biorecognition elements for tumor markers although few evaluate their detection in a native conformation and cellular micro-environment. In this study, fluorophore and peroxidase labeled aptamer configurations were compared for the detection of MCF7 breast and SW620 colon cancer cell lines expressing the tumor marker MUC1. Fluorescence based detection showed selective binding to the cell lines relative to a nonbinding control sequence with sequence specific binding differences between MUC1 aptamers accredited to variation in the glycosylation state of expressed MUC1. The peroxidase labeled assay showed high detection sensitivity although low binding specificity was observed for the MUC1 aptamers to the cell lines. Results suggest that aptamers susceptible to non specific binding to cells may limit the applicability of enzymatic amplification to improve aptasensor sensitivity.
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- Authors: Flanagan, Shane , Limson, Janice , Fogel, Ronen
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431076 , vital:72742 , xlink:href="10.1109/BioCAS.2014.6981720"
- Description: Aptamers hold great promise for cancer diagnosis and therapy. Several biosensors incorporate aptamers as biorecognition elements for tumor markers although few evaluate their detection in a native conformation and cellular micro-environment. In this study, fluorophore and peroxidase labeled aptamer configurations were compared for the detection of MCF7 breast and SW620 colon cancer cell lines expressing the tumor marker MUC1. Fluorescence based detection showed selective binding to the cell lines relative to a nonbinding control sequence with sequence specific binding differences between MUC1 aptamers accredited to variation in the glycosylation state of expressed MUC1. The peroxidase labeled assay showed high detection sensitivity although low binding specificity was observed for the MUC1 aptamers to the cell lines. Results suggest that aptamers susceptible to non specific binding to cells may limit the applicability of enzymatic amplification to improve aptasensor sensitivity.
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Comparison of the biology of geographically distinct populations of the citrus pest, Thaumatotibia leucotreta (Meyrick)(Lepidoptera: Tortricidae)
- Opoku-Debrah, John K, Hill, Martin P, Knox, Caroline M, Moore, Sean D
- Authors: Opoku-Debrah, John K , Hill, Martin P , Knox, Caroline M , Moore, Sean D
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405769 , vital:70204 , xlink:href="https://hdl.handle.net/10520/EJC160246"
- Description: Baculovirus biopesticides are an important component of integrated pest management programmes worldwide. One such example is the Cryptophlebia leucotreta granulovirus (CrleGV) which is used for the control of false codling moth, Thaumatotibia (= Cryptophlebia) leucotreta (Meyrick) (Lepidoptera: Tortricidae), a pest of citrus and other crops in South Africa. A potential problem associated with constant application of viral biopesticides is the differing susceptibility to the virus observed between different geographic populations of the insect host. This could be related to a number of factors, including biological performance and fitness of the target insect population. This study compared a variety of phenotypic traits between geographically distinct T. leucotreta populations collected from the Addo, Marble Hall, Citrusdal and Nelspruit regions of South Africa, and reared under laboratory conditions for several generations. Traits including pupal mass, female fecundity, egg hatch, pupal survival, adult eclosion and developmental time were used as parameters to measure biological performance and fitness. Insects from the Citrusdal region of the Western Cape exhibited significantly lower pupal mass, female fecundity, egg hatch, pupal survival, adult eclosion and the longest duration in larval and pupal development compared to the other colonies investigated. This is the first study to report differences in the performance of laboratory reared T. leucotreta from different geographic locations, and the findings may have important implications for the application of viral biopesticides for the control of this pest in South Africa.
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- Authors: Opoku-Debrah, John K , Hill, Martin P , Knox, Caroline M , Moore, Sean D
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405769 , vital:70204 , xlink:href="https://hdl.handle.net/10520/EJC160246"
- Description: Baculovirus biopesticides are an important component of integrated pest management programmes worldwide. One such example is the Cryptophlebia leucotreta granulovirus (CrleGV) which is used for the control of false codling moth, Thaumatotibia (= Cryptophlebia) leucotreta (Meyrick) (Lepidoptera: Tortricidae), a pest of citrus and other crops in South Africa. A potential problem associated with constant application of viral biopesticides is the differing susceptibility to the virus observed between different geographic populations of the insect host. This could be related to a number of factors, including biological performance and fitness of the target insect population. This study compared a variety of phenotypic traits between geographically distinct T. leucotreta populations collected from the Addo, Marble Hall, Citrusdal and Nelspruit regions of South Africa, and reared under laboratory conditions for several generations. Traits including pupal mass, female fecundity, egg hatch, pupal survival, adult eclosion and developmental time were used as parameters to measure biological performance and fitness. Insects from the Citrusdal region of the Western Cape exhibited significantly lower pupal mass, female fecundity, egg hatch, pupal survival, adult eclosion and the longest duration in larval and pupal development compared to the other colonies investigated. This is the first study to report differences in the performance of laboratory reared T. leucotreta from different geographic locations, and the findings may have important implications for the application of viral biopesticides for the control of this pest in South Africa.
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