Assessment of bioflocculant production by two marine bacteria isolated from the bottom sediment of marine Algoa Bay
- Authors: Ntozonke, Ncedo
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11298 , http://hdl.handle.net/10353/d1021290
- Description: Bioflocculants are polymers, mostly, of microbial origin which floc out suspended particles from liquid medium. The ability of these biopolymers to remove suspended particles from solutions is termed bioflocculation, and the efficiency of flocculation activities depends on the characteristics of the flocculants. In comparison with conventionally used flocculants, bioflocculants have the advantage of being safe (no toxic effects known), biodegradable and harmlessness to the environment. The study assessed production of bioflocculant by two marine bacteria from the bottom sediment of marine environment. The 16S rDNA was used for identification, and the two bacteria species were identified as Enterococcus hirae and Bacillus thuringiensis. Factors affecting the production and activity of the bioflocculants produced by these two organisms were studied. The bacteria optimally produced bioflocculant with fructose (91.7%) and urea (91%) as sole carbon and nitrogen sources respectively. Mg2+ (87%) and Ca2+ (86%), likewise, served as best cation sources on the production of the bioflocculant at pH 5(93%). Additionally, the flocculating activity of the bioflocculant increased with the addition of Mg2+ (81%) and Na+ (81%), and the highest flocculating activity was at pH 5 of the kaolin clay. The Fourier transform infrared spectroscopy (FTIR) shows that the bioflocculant is a glycoprotein. The second bacterium (Bacillus thuringiensis) produced bioflocculant optimally when the media had mixed nitrogen sources (Urea, ammonium chloride and tryptone (67%)) and glucose (85.65%) as a sole carbon source, also Ca2+ (74.6%) was the best cation that induced the production of bioflocculant. After purification, the bioflocculant flocculated optimally in alkaline pH 12 (81%) in the presence of Mn2+ (73%) and Ca2+ (72.8%). Chemical analysis of the bioflocculant revealed it to be a polysaccharide. Both bioflocculants flocculate efficiently and can be used to replace synthetic flocculants in water treatment, wastewater, in downstream processing, and processing of food and chemicals and other industrial uses of flocculants. Challenges though (i) are to develop conditions for large scale production of the bioflocculant, (ii) to do further characterization of the both bioflocculants (iii) to assess the bioflocculants for treatments of water/wastewater, and to apply it in various industrial processes.
- Full Text:
- Date Issued: 2015
- Authors: Ntozonke, Ncedo
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11298 , http://hdl.handle.net/10353/d1021290
- Description: Bioflocculants are polymers, mostly, of microbial origin which floc out suspended particles from liquid medium. The ability of these biopolymers to remove suspended particles from solutions is termed bioflocculation, and the efficiency of flocculation activities depends on the characteristics of the flocculants. In comparison with conventionally used flocculants, bioflocculants have the advantage of being safe (no toxic effects known), biodegradable and harmlessness to the environment. The study assessed production of bioflocculant by two marine bacteria from the bottom sediment of marine environment. The 16S rDNA was used for identification, and the two bacteria species were identified as Enterococcus hirae and Bacillus thuringiensis. Factors affecting the production and activity of the bioflocculants produced by these two organisms were studied. The bacteria optimally produced bioflocculant with fructose (91.7%) and urea (91%) as sole carbon and nitrogen sources respectively. Mg2+ (87%) and Ca2+ (86%), likewise, served as best cation sources on the production of the bioflocculant at pH 5(93%). Additionally, the flocculating activity of the bioflocculant increased with the addition of Mg2+ (81%) and Na+ (81%), and the highest flocculating activity was at pH 5 of the kaolin clay. The Fourier transform infrared spectroscopy (FTIR) shows that the bioflocculant is a glycoprotein. The second bacterium (Bacillus thuringiensis) produced bioflocculant optimally when the media had mixed nitrogen sources (Urea, ammonium chloride and tryptone (67%)) and glucose (85.65%) as a sole carbon source, also Ca2+ (74.6%) was the best cation that induced the production of bioflocculant. After purification, the bioflocculant flocculated optimally in alkaline pH 12 (81%) in the presence of Mn2+ (73%) and Ca2+ (72.8%). Chemical analysis of the bioflocculant revealed it to be a polysaccharide. Both bioflocculants flocculate efficiently and can be used to replace synthetic flocculants in water treatment, wastewater, in downstream processing, and processing of food and chemicals and other industrial uses of flocculants. Challenges though (i) are to develop conditions for large scale production of the bioflocculant, (ii) to do further characterization of the both bioflocculants (iii) to assess the bioflocculants for treatments of water/wastewater, and to apply it in various industrial processes.
- Full Text:
- Date Issued: 2015
Assessment of the effects of stream channel incision on soil water levels, soil morphology and vegetation in a wetland in the Hogsback area, Eastern Cape, South Africa
- Authors: Omar, Mohamed Yussuf
- Date: 2015
- Subjects: Hydrology Wetland Soil Formation
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/3132 , vital:28264
- Description: Wetland degradation in the form of channel incisioning can significantly alter the hydrological functioning of a wetland. In this study in a small headwater wetland in the Hogsback area, Eastern Cape Province, the impact of channel incisioning on soil water levels and soil morphology was examined. A good correlation (R2 = 0.89) exists between the depth of channel incisioning and average water table depths in most of the 21 installed piezometers. In localised cases the upslope supply of water was in equilibrium with drainage from the piezometers. Although all the studied soils show hydromorphic characteristics, those continuously saturated close to the surface exhibit redox accumulations in oxygen supplying macropores, whereas gleyic colour patterns occur deeper in soils where the water table has been lowered by channel incision. The nature and occurrence of different hydromorphic soil indicators observed confirm the contribution of soil morphology as a valuable indicator of long-term average soil water conditions. The study evaluates the effects of hydrological processes on plant species composition and distribution in a Hogsback wetland. Twenty-four circular plots with a radius of 2 m were established between March and August 2013. Within each sample plot, the habitat information and species present were recorded including Braun-Blanquet cover-abundance value for each and every species present in the plot. Plant species were identified in the field and the unknown plant species were collected, pressed, oven-dried and identified at the National Herbarium, South African Biodiversity Institute (SANBI), Pretoria and Schonland Herbarium, Rhodes University, Grahamstown. A total of 39 taxa belonging to 19 families and 34 genera were recorded from the Hogsback wetland. Of the documented taxa, three were exotic and three endemic to South Africa, indicating diversity and dynamic nature of Hogsback wetland flora. Plant families with the highest number of species were: Poaceae (11 species), Asteraceae (5 species), Onagraceae and Cyperaceae with 3 taxa each. The low number of exotic plant species in Hogsback wetland (three taxa in total) indicates limited anthropogenic influence. Unique species recorded in Hogsback wetlands are three species that are endemic to South Africa, namely, Alchemilla capensis, Helichrysum rosum and Lysimachia nutans. Five main floristic associations were identified from the Hierarchical Cluster Analysis whilst Detrenched .Correspondence Analysis (DCA) identified four groups. The Canonical Correspondence Analysis (CCA) indicates that edaphic factors, particularly in an area covered with water, erosion category, organic matter content and water table depth were the most important environmental variables measured accounting for the vegetation pattern present in the Hogsback wetland.
- Full Text:
- Date Issued: 2015
- Authors: Omar, Mohamed Yussuf
- Date: 2015
- Subjects: Hydrology Wetland Soil Formation
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/3132 , vital:28264
- Description: Wetland degradation in the form of channel incisioning can significantly alter the hydrological functioning of a wetland. In this study in a small headwater wetland in the Hogsback area, Eastern Cape Province, the impact of channel incisioning on soil water levels and soil morphology was examined. A good correlation (R2 = 0.89) exists between the depth of channel incisioning and average water table depths in most of the 21 installed piezometers. In localised cases the upslope supply of water was in equilibrium with drainage from the piezometers. Although all the studied soils show hydromorphic characteristics, those continuously saturated close to the surface exhibit redox accumulations in oxygen supplying macropores, whereas gleyic colour patterns occur deeper in soils where the water table has been lowered by channel incision. The nature and occurrence of different hydromorphic soil indicators observed confirm the contribution of soil morphology as a valuable indicator of long-term average soil water conditions. The study evaluates the effects of hydrological processes on plant species composition and distribution in a Hogsback wetland. Twenty-four circular plots with a radius of 2 m were established between March and August 2013. Within each sample plot, the habitat information and species present were recorded including Braun-Blanquet cover-abundance value for each and every species present in the plot. Plant species were identified in the field and the unknown plant species were collected, pressed, oven-dried and identified at the National Herbarium, South African Biodiversity Institute (SANBI), Pretoria and Schonland Herbarium, Rhodes University, Grahamstown. A total of 39 taxa belonging to 19 families and 34 genera were recorded from the Hogsback wetland. Of the documented taxa, three were exotic and three endemic to South Africa, indicating diversity and dynamic nature of Hogsback wetland flora. Plant families with the highest number of species were: Poaceae (11 species), Asteraceae (5 species), Onagraceae and Cyperaceae with 3 taxa each. The low number of exotic plant species in Hogsback wetland (three taxa in total) indicates limited anthropogenic influence. Unique species recorded in Hogsback wetlands are three species that are endemic to South Africa, namely, Alchemilla capensis, Helichrysum rosum and Lysimachia nutans. Five main floristic associations were identified from the Hierarchical Cluster Analysis whilst Detrenched .Correspondence Analysis (DCA) identified four groups. The Canonical Correspondence Analysis (CCA) indicates that edaphic factors, particularly in an area covered with water, erosion category, organic matter content and water table depth were the most important environmental variables measured accounting for the vegetation pattern present in the Hogsback wetland.
- Full Text:
- Date Issued: 2015
Assessment of the quality indices and prevalence of Escherichia coli pathotypes in selected rivers of Osun state, Southwestern Nigeria
- Authors: Titilawo, Osuolale Yinka
- Date: 2015
- Language: English
- Type: Thesis , Doctoral , PhD (Microbiology)
- Identifier: vital:11295 , http://hdl.handle.net/10353/d1021274
- Description: Surface waters are important freshwater sources used for domestic, industrial, agricultural and recreational activities, and the availability of good quality freshwater is indispensable for preventing water-borne diseases and improving quality of life especially in communities that lack pipe-borne water. Water samples were collected from ten rivers at different locations in Osun State, Southwestern Nigeria. A total of 12 physicochemical parameters, counts of total coliforms (TC) and Escherichia coli isolates were determined using standard analytical procedures. Confirmed Escherichia coli isolates (n=300) were assessed for the presence of 10 virulence genes (VGs) associated with Escherichia coli strains causing intestinal and extra-intestinal infections. The recovered Escherichia coli isolates were elucidated for their antibiogram profiling by disk diffusion method and the resistant isolates were further profiled for their genotypic antimicrobial resistance by polymerase chain reaction technique. The physicochemical qualities ranged as follows: pH (6.9 - 7.6), temperature (26 – 29 ºC), turbidity (2.28 – 9.46 NTU), electrical conductivity (229 – 581 μS/cm), nitrate (0.03 – 0.05 mg/L), nitrite (0.00 – 0.01 mg/L), sulphate (3.33 – 20.33 mg/L), chloride ions (7.83 – 27.33 mg/L), dissolved oxygen (4.23 – 5.57 mg/L), total dissolved solids (56 – 184 mg/L), total hardness (78 – 519 mg/L) and alkalinity (50.67 – 146.67 mg/L). Statistical analysis showed that pH, temperature, electrical conductivities, nitrates, nitrites, chloride, dissolved oxygen, total dissolved solid, total hardness and alkalinity were significantly different (P < 0.05), whereas turbidity and sulphate were not significantly different (P ˃ 0.05) from each parameter with respect to sampling sites. While the VG lt for enterotoxigenic E. coli had the highest prevalence of 45%, the enteropathogenic E. coli genes eae and bfp were detected in 6% and 4% of the isolates respectively. The VGs stx1 and stx2 specific for the enterohemorrhagic E. coli pathotypes were equally detected in 7% and 1% of the isolates respectively. Also, the VG eagg harboured by enteroaggregative pathotype and diffusely-adherent E. coli VG daaE were detected in 2% and 4% of the isolates respectively and enteroinvasive E. coli VG ipaH was not detected. In addition, the VGs papC for uropathogenic and ibeA for neonatal meningitis were frequently detected in 19% and 3% of isolates respectively. While all the isolates tested were susceptible to imipenem, meropenem, amikacin and gatilofloxacin, others were variously susceptible, and resistant as follows; ciprofloxacin (96%), kanamycin (95%), neomycin (92%), streptomycin (84%), chloramphenicol (73%), nalidixic acid (66%), nitrofuratoin (64%), gentamycin (63%), doxycycline (58%), cefepime (57%), tetracycline (49%) and cephalothin (42%). Conversely, all the isolates were resistant to sulphamethoxazole, and high levels of resistance were equally observed against amoxycillin (59%), ampicilin (57%) and cefuroxime (40%). Cefepime, cephalothin, cefuroxime, nalidixic acid, nitrofuratoin, chloramphenicol and tetracycline were not significantly different in their effect against the isolates from all locations (P > 0.05), whereas the resistance profile of the isolates against gentamycin, ciprofloxacin, sulphamethoxazole, ampicillin and amoxicillin were significantly different (P < 0.05). Amikacin, kanamycin, streptomycin, meropenem, imipenem and gatilofloxacin were statistically excluded from the analysis since all tested isolates showed total susceptibility to these antimicrobials. The multiple antibiotic resistance indexing ranged from 0.50 to 0.80 for all the sampling locations and exceeded the threshold value of 0.2. Prevalence and distributions of the 19 resistance determinants assessed were obtained as follows; [sulfonamides (sulI (8%), sulII (41%)], [beta-lactams; (ampC 22%; blaTEM, (21%), blaZ (18%),], [tetracyclines (tetA (24%), tetB (23%), tetC (18%), tetD (78%), tetK (15%), tetM, (10%)], [phenicols; (catI (37%), catII (28%), cmlA1 (19%)] and [aminoglycosides; (aacC2 (8%), aphA1 (80%), aphA2 (80%), aadA (79%) and strA (38%)]. The Pearson chi square exact test revealed many strong significant associations among ampC, blaTEM, blaZ and tetA genes with some determinants screened. In the same vein, a grand total of 366 resistance gene fingerprints were spotted across the sampling locations and among the resistant pathotypes, the modal prevalent gene prints were found among the ETEC strains in 148 (40%), being the predominant pathotype observed, followed by UPEC strains 80 (22%) while the lowest was the least occurring EAEC pathotype 14 (4%). While some physicochemical parameters exceeded prescribed standards for drinking water, some fell within. The total coliforms obtained in all the sampling sites were above the acceptable limits. Findings reveal the presence of diarrhoeagenic and non-diarrhoeagenic E. coli in the selected rivers and suggest a potential public health risk as the rivers are important resources for domestic, recreational and livelihood usage by their host communities. The multiple drug resistance indexing signifies isolates and pathotypes of high antimicrobial usage origin. An increase in the antimicrobial resistance signatures towards conventionally used antibiotics as observed in this study necessitates for safe water supply, adequate sanitation facilities and proper surveillance programs towards the monitoring of antimicrobial resistance determinants in water-bodies. Generally, results from this study indicate that the river waters are not suitable for consumption, domestic or recreational use and re-echo the importance of safeguarding the freshwater resources of Southwestern Nigeria.
- Full Text:
- Date Issued: 2015
- Authors: Titilawo, Osuolale Yinka
- Date: 2015
- Language: English
- Type: Thesis , Doctoral , PhD (Microbiology)
- Identifier: vital:11295 , http://hdl.handle.net/10353/d1021274
- Description: Surface waters are important freshwater sources used for domestic, industrial, agricultural and recreational activities, and the availability of good quality freshwater is indispensable for preventing water-borne diseases and improving quality of life especially in communities that lack pipe-borne water. Water samples were collected from ten rivers at different locations in Osun State, Southwestern Nigeria. A total of 12 physicochemical parameters, counts of total coliforms (TC) and Escherichia coli isolates were determined using standard analytical procedures. Confirmed Escherichia coli isolates (n=300) were assessed for the presence of 10 virulence genes (VGs) associated with Escherichia coli strains causing intestinal and extra-intestinal infections. The recovered Escherichia coli isolates were elucidated for their antibiogram profiling by disk diffusion method and the resistant isolates were further profiled for their genotypic antimicrobial resistance by polymerase chain reaction technique. The physicochemical qualities ranged as follows: pH (6.9 - 7.6), temperature (26 – 29 ºC), turbidity (2.28 – 9.46 NTU), electrical conductivity (229 – 581 μS/cm), nitrate (0.03 – 0.05 mg/L), nitrite (0.00 – 0.01 mg/L), sulphate (3.33 – 20.33 mg/L), chloride ions (7.83 – 27.33 mg/L), dissolved oxygen (4.23 – 5.57 mg/L), total dissolved solids (56 – 184 mg/L), total hardness (78 – 519 mg/L) and alkalinity (50.67 – 146.67 mg/L). Statistical analysis showed that pH, temperature, electrical conductivities, nitrates, nitrites, chloride, dissolved oxygen, total dissolved solid, total hardness and alkalinity were significantly different (P < 0.05), whereas turbidity and sulphate were not significantly different (P ˃ 0.05) from each parameter with respect to sampling sites. While the VG lt for enterotoxigenic E. coli had the highest prevalence of 45%, the enteropathogenic E. coli genes eae and bfp were detected in 6% and 4% of the isolates respectively. The VGs stx1 and stx2 specific for the enterohemorrhagic E. coli pathotypes were equally detected in 7% and 1% of the isolates respectively. Also, the VG eagg harboured by enteroaggregative pathotype and diffusely-adherent E. coli VG daaE were detected in 2% and 4% of the isolates respectively and enteroinvasive E. coli VG ipaH was not detected. In addition, the VGs papC for uropathogenic and ibeA for neonatal meningitis were frequently detected in 19% and 3% of isolates respectively. While all the isolates tested were susceptible to imipenem, meropenem, amikacin and gatilofloxacin, others were variously susceptible, and resistant as follows; ciprofloxacin (96%), kanamycin (95%), neomycin (92%), streptomycin (84%), chloramphenicol (73%), nalidixic acid (66%), nitrofuratoin (64%), gentamycin (63%), doxycycline (58%), cefepime (57%), tetracycline (49%) and cephalothin (42%). Conversely, all the isolates were resistant to sulphamethoxazole, and high levels of resistance were equally observed against amoxycillin (59%), ampicilin (57%) and cefuroxime (40%). Cefepime, cephalothin, cefuroxime, nalidixic acid, nitrofuratoin, chloramphenicol and tetracycline were not significantly different in their effect against the isolates from all locations (P > 0.05), whereas the resistance profile of the isolates against gentamycin, ciprofloxacin, sulphamethoxazole, ampicillin and amoxicillin were significantly different (P < 0.05). Amikacin, kanamycin, streptomycin, meropenem, imipenem and gatilofloxacin were statistically excluded from the analysis since all tested isolates showed total susceptibility to these antimicrobials. The multiple antibiotic resistance indexing ranged from 0.50 to 0.80 for all the sampling locations and exceeded the threshold value of 0.2. Prevalence and distributions of the 19 resistance determinants assessed were obtained as follows; [sulfonamides (sulI (8%), sulII (41%)], [beta-lactams; (ampC 22%; blaTEM, (21%), blaZ (18%),], [tetracyclines (tetA (24%), tetB (23%), tetC (18%), tetD (78%), tetK (15%), tetM, (10%)], [phenicols; (catI (37%), catII (28%), cmlA1 (19%)] and [aminoglycosides; (aacC2 (8%), aphA1 (80%), aphA2 (80%), aadA (79%) and strA (38%)]. The Pearson chi square exact test revealed many strong significant associations among ampC, blaTEM, blaZ and tetA genes with some determinants screened. In the same vein, a grand total of 366 resistance gene fingerprints were spotted across the sampling locations and among the resistant pathotypes, the modal prevalent gene prints were found among the ETEC strains in 148 (40%), being the predominant pathotype observed, followed by UPEC strains 80 (22%) while the lowest was the least occurring EAEC pathotype 14 (4%). While some physicochemical parameters exceeded prescribed standards for drinking water, some fell within. The total coliforms obtained in all the sampling sites were above the acceptable limits. Findings reveal the presence of diarrhoeagenic and non-diarrhoeagenic E. coli in the selected rivers and suggest a potential public health risk as the rivers are important resources for domestic, recreational and livelihood usage by their host communities. The multiple drug resistance indexing signifies isolates and pathotypes of high antimicrobial usage origin. An increase in the antimicrobial resistance signatures towards conventionally used antibiotics as observed in this study necessitates for safe water supply, adequate sanitation facilities and proper surveillance programs towards the monitoring of antimicrobial resistance determinants in water-bodies. Generally, results from this study indicate that the river waters are not suitable for consumption, domestic or recreational use and re-echo the importance of safeguarding the freshwater resources of Southwestern Nigeria.
- Full Text:
- Date Issued: 2015
Assessment of the spatial and temporal variations in periphyton communities along a small temperate river system: A multimetric and stable isotope analysis approach
- Dalu, Tatenda, Bere, Taurai, Richoux, Nicole B, Froneman, P William
- Authors: Dalu, Tatenda , Bere, Taurai , Richoux, Nicole B , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124249 , vital:35580 , https://doi.org/10.1016/j.sajb.2015.05.028
- Description: Periphyton community structure and stable isotope values have been identified as potential indicators of anthropogenic nitrogen pollution, an increasingly important challenge in aquatic systems. The aim of the study was to assess the spatio-temporal changes in periphyton characteristics to identify potential anthropogenic nitrogen pollution sources such as agricultural and sewage discharge within the Kowie River catchment, South Africa. Periphyton was collected once a season from five sites between September 2012 and May 2013. Diversity indices, multimetric and stable isotope analyses were employed for describing the spatial and temporal dynamics of periphyton community assemblages. Water depth, salinity, resistivity, oxygen reduction potential, nitrates, water velocity and conductivity were the major factors affecting periphyton community structure. Eighty-seven periphyton taxa belonging to 43 genera were recorded throughout the study sites and periods. Periphyton species richness, abundance and stable isotope signatures differed significantly among sites but not among seasons. The lower sections of the Kowie River were polluted by anthropogenic sources as indicated by the high periphytic isotopic nitrogen values (7.9–15.2‰) compared to the pristine upstream sites (4–8‰). We recommend that researchers use a combination of community structure and stable isotope measurements to monitor the periphyton in lotic systems.
- Full Text:
- Date Issued: 2015
- Authors: Dalu, Tatenda , Bere, Taurai , Richoux, Nicole B , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124249 , vital:35580 , https://doi.org/10.1016/j.sajb.2015.05.028
- Description: Periphyton community structure and stable isotope values have been identified as potential indicators of anthropogenic nitrogen pollution, an increasingly important challenge in aquatic systems. The aim of the study was to assess the spatio-temporal changes in periphyton characteristics to identify potential anthropogenic nitrogen pollution sources such as agricultural and sewage discharge within the Kowie River catchment, South Africa. Periphyton was collected once a season from five sites between September 2012 and May 2013. Diversity indices, multimetric and stable isotope analyses were employed for describing the spatial and temporal dynamics of periphyton community assemblages. Water depth, salinity, resistivity, oxygen reduction potential, nitrates, water velocity and conductivity were the major factors affecting periphyton community structure. Eighty-seven periphyton taxa belonging to 43 genera were recorded throughout the study sites and periods. Periphyton species richness, abundance and stable isotope signatures differed significantly among sites but not among seasons. The lower sections of the Kowie River were polluted by anthropogenic sources as indicated by the high periphytic isotopic nitrogen values (7.9–15.2‰) compared to the pristine upstream sites (4–8‰). We recommend that researchers use a combination of community structure and stable isotope measurements to monitor the periphyton in lotic systems.
- Full Text:
- Date Issued: 2015
Assignment of spin and parity to states in the nucleus ¹⁹⁶T1
- Authors: Uwitonze, Pierre Celestin
- Date: 2015
- Subjects: Nuclear spin , Particles (Nuclear physics) -- Chirality
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5558 , http://hdl.handle.net/10962/d1017903
- Description: This work presents a study of high-spin states in the nucleus ¹⁹⁶Tl via γ-spectroscopy. ¹⁹⁶Tl was produced via the ¹⁹⁷Au(⁴He,5n) ¹⁹⁶Tl reaction at a beam energy of 63 MeV. The γ-γ coincidence measurements were performed using the AFRODITE γ-spectrometer array at iThemba LABS. The previous level scheme of ¹⁹⁶Tl has been extended up to an excitation of 4071 keV including 24 new γ-ray transitions. The spin and parity assignment to levels was made from the directional correlation of oriented nuclei (DCO) and linear polarization anisotropy ratios. An analysis of the B(M1)/B(E2) ratios was found to be consistent with the configuration of πh₉/₂♁vi₁₃/₂ for the ground state band. Although no chiral band was found in ¹⁹⁶TI and ¹⁹⁸TI.
- Full Text:
- Date Issued: 2015
- Authors: Uwitonze, Pierre Celestin
- Date: 2015
- Subjects: Nuclear spin , Particles (Nuclear physics) -- Chirality
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5558 , http://hdl.handle.net/10962/d1017903
- Description: This work presents a study of high-spin states in the nucleus ¹⁹⁶Tl via γ-spectroscopy. ¹⁹⁶Tl was produced via the ¹⁹⁷Au(⁴He,5n) ¹⁹⁶Tl reaction at a beam energy of 63 MeV. The γ-γ coincidence measurements were performed using the AFRODITE γ-spectrometer array at iThemba LABS. The previous level scheme of ¹⁹⁶Tl has been extended up to an excitation of 4071 keV including 24 new γ-ray transitions. The spin and parity assignment to levels was made from the directional correlation of oriented nuclei (DCO) and linear polarization anisotropy ratios. An analysis of the B(M1)/B(E2) ratios was found to be consistent with the configuration of πh₉/₂♁vi₁₃/₂ for the ground state band. Although no chiral band was found in ¹⁹⁶TI and ¹⁹⁸TI.
- Full Text:
- Date Issued: 2015
Assisting in-service grade R teachers to nurture the holistic development of the five to seven year old child through music : a participatory approach
- Authors: Cloete, Erna Petronella
- Date: 2015
- Subjects: School music -- Instruction and study -- South Africa , Early childhood education , Music -- Instruction and study
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:8530 , http://hdl.handle.net/10948/d1021177
- Description: Music’s significant contribution to the holistic development of the young learner is uncontested and confirmed by views of seminal scholars, such as Nzewi 2003, Reimer 2003, Nussbaum 2001, Elliot 1994 and Merriam 1964, amongst others. As such, music education supports basic values of self-growth, self-knowledge and enjoyment. This study argues for the vital importance of music education in Grade R in the South African schooling system where teachers can successfully implement the curriculum. In post-apartheid multicultural and multi-musical South Africa music education in Grade R is the sole responsibility of the generalist Grade R teacher. However, due to inadequate training and minimal, unproductive in-service initiatives, the vast majority of Reception Year teachers assumingly do not have the required competences to teach music in a way that maximally enhances the holistic development of their learners. Findings revealed that teachers exhibited limited, if any, musical knowledge and per se, they are insufficiently skilled in the effective delivery of the curriculum in terms of music. This study acknowledges the need to equip in-service Grade R teachers with the required competences to effectively implement the national school and teach music with confidence. The lack of successful and effective continuing professional teacher development initiatives from the Department of Education and Department of Basic Education to assist Grade R teachers in teaching music, was a serious concern to me. This concern reinforced the motivation to embark on this project. In this thesis, I report on an intervention strategy aimed at enabling three Grade R practitioners at one peri- urban township school in the Eastern Cape to improve their music education competencies. These three Coloured ladies only held a Certificate in Early Childhood Development, rating at an NQF level 4 and 5. None of these practitioners had any prior music experience in music training, music making or music teaching. I utilised a Participatory Action Learning and Action Research (PALAR). PALAR combines research with development and is thus highly suitable when addressing multifaceted problems in rapidly changing environments, such as South Africa. In my study, the participants were thus actively involved in identifying problems and creating solutions. A number of collaborative interactions and qualitative data generation strategies such as Focus Group Interviews, Observations, Drawing, Interviews, Narrative Inquiry, Case Study and Reflective Journals were implemented. Findings indicated that the practitioners experienced transformation on both a professional and personal level as they discovered and tapped into their own innate musical competences. This enabled them to explore ways to teach music that enhanced the holistic development of their learners, developing them physically, cognitively emotionally, socially, and musically. Learners likewise benefitted from the intervention as they experienced social cohesion in a multicultural classroom and gained the fruits of music’s remedial impact and therapeutic value in their lives.
- Full Text:
- Date Issued: 2015
- Authors: Cloete, Erna Petronella
- Date: 2015
- Subjects: School music -- Instruction and study -- South Africa , Early childhood education , Music -- Instruction and study
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:8530 , http://hdl.handle.net/10948/d1021177
- Description: Music’s significant contribution to the holistic development of the young learner is uncontested and confirmed by views of seminal scholars, such as Nzewi 2003, Reimer 2003, Nussbaum 2001, Elliot 1994 and Merriam 1964, amongst others. As such, music education supports basic values of self-growth, self-knowledge and enjoyment. This study argues for the vital importance of music education in Grade R in the South African schooling system where teachers can successfully implement the curriculum. In post-apartheid multicultural and multi-musical South Africa music education in Grade R is the sole responsibility of the generalist Grade R teacher. However, due to inadequate training and minimal, unproductive in-service initiatives, the vast majority of Reception Year teachers assumingly do not have the required competences to teach music in a way that maximally enhances the holistic development of their learners. Findings revealed that teachers exhibited limited, if any, musical knowledge and per se, they are insufficiently skilled in the effective delivery of the curriculum in terms of music. This study acknowledges the need to equip in-service Grade R teachers with the required competences to effectively implement the national school and teach music with confidence. The lack of successful and effective continuing professional teacher development initiatives from the Department of Education and Department of Basic Education to assist Grade R teachers in teaching music, was a serious concern to me. This concern reinforced the motivation to embark on this project. In this thesis, I report on an intervention strategy aimed at enabling three Grade R practitioners at one peri- urban township school in the Eastern Cape to improve their music education competencies. These three Coloured ladies only held a Certificate in Early Childhood Development, rating at an NQF level 4 and 5. None of these practitioners had any prior music experience in music training, music making or music teaching. I utilised a Participatory Action Learning and Action Research (PALAR). PALAR combines research with development and is thus highly suitable when addressing multifaceted problems in rapidly changing environments, such as South Africa. In my study, the participants were thus actively involved in identifying problems and creating solutions. A number of collaborative interactions and qualitative data generation strategies such as Focus Group Interviews, Observations, Drawing, Interviews, Narrative Inquiry, Case Study and Reflective Journals were implemented. Findings indicated that the practitioners experienced transformation on both a professional and personal level as they discovered and tapped into their own innate musical competences. This enabled them to explore ways to teach music that enhanced the holistic development of their learners, developing them physically, cognitively emotionally, socially, and musically. Learners likewise benefitted from the intervention as they experienced social cohesion in a multicultural classroom and gained the fruits of music’s remedial impact and therapeutic value in their lives.
- Full Text:
- Date Issued: 2015
Audit committee effectiveness in an Eastern Cape provincial department
- Authors: Koranteng, Isaac
- Date: 2015
- Subjects: Audit committees -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/4045 , vital:20507
- Description: The discussion on the extent to which audit committees perform the oversight function of financial governance is important. This is particularly so in the Eastern Cape where the implementation of the Public Finance Management Act (PFMA) of 1999 has not significantly improved financial management. The deteriorating financial management environment of provincial departments impacts negatively on service delivery and is therefore a matter of great concern to the political administrators at both national and provincial levels. The objective of this study is to determine how effective audit committees are in Eastern Cape provincial departments and how this translates into good financial governance and, ultimately, improved service delivery. To achieve this objective, a literature review of the link between audit committee effectiveness, accountability and corporate governance in the public sector was conducted. It was found that audit committees in the public sector have similar responsibilities to that of the private sector and lack of accountability in the public sector impacts negatively on service delivery. A second literature review was conducted to highlight the current state of public financial management in South Africa and how this has had an impact on financial management in Eastern Cape provincial departments. A qualitative research methodology was applied because the researcher is of the opinion that the research question asked is more interpretive than predictive. An interview survey was conducted in which senior management officials were selected from provincial departments and interviewed using semi-structured questions. The research study concluded, that provincial departments in the Eastern Cape have all established audit committees in line with the Public Finance Management Act (PFMA) National Treasury regulations. These committees are however ineffective. Ineffectiveness is as a result of, among other factors, lack of stability in accounting officer and chief financial officer positions. Secondly, senior management have not been made to account for the persistent negative audit outcomes in their departments. The research recommends that the political leadership of the province should ensure stability in leadership, particularly in the position of accounting officer and the chief financial officer.
- Full Text:
- Date Issued: 2015
- Authors: Koranteng, Isaac
- Date: 2015
- Subjects: Audit committees -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/4045 , vital:20507
- Description: The discussion on the extent to which audit committees perform the oversight function of financial governance is important. This is particularly so in the Eastern Cape where the implementation of the Public Finance Management Act (PFMA) of 1999 has not significantly improved financial management. The deteriorating financial management environment of provincial departments impacts negatively on service delivery and is therefore a matter of great concern to the political administrators at both national and provincial levels. The objective of this study is to determine how effective audit committees are in Eastern Cape provincial departments and how this translates into good financial governance and, ultimately, improved service delivery. To achieve this objective, a literature review of the link between audit committee effectiveness, accountability and corporate governance in the public sector was conducted. It was found that audit committees in the public sector have similar responsibilities to that of the private sector and lack of accountability in the public sector impacts negatively on service delivery. A second literature review was conducted to highlight the current state of public financial management in South Africa and how this has had an impact on financial management in Eastern Cape provincial departments. A qualitative research methodology was applied because the researcher is of the opinion that the research question asked is more interpretive than predictive. An interview survey was conducted in which senior management officials were selected from provincial departments and interviewed using semi-structured questions. The research study concluded, that provincial departments in the Eastern Cape have all established audit committees in line with the Public Finance Management Act (PFMA) National Treasury regulations. These committees are however ineffective. Ineffectiveness is as a result of, among other factors, lack of stability in accounting officer and chief financial officer positions. Secondly, senior management have not been made to account for the persistent negative audit outcomes in their departments. The research recommends that the political leadership of the province should ensure stability in leadership, particularly in the position of accounting officer and the chief financial officer.
- Full Text:
- Date Issued: 2015
Automated statistical audit system for a government regulatory authority
- Authors: Xozwa, Thandolwethu
- Date: 2015
- Subjects: Auditing -- Statistical methods -- Data processing , Mathematica (Computer program language)
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/6061 , vital:21035
- Description: Governments all over the world are faced with numerous challenges while running their countries on a daily basis. The predominant challenges which arise are those which involve statistical methodologies. Official statistics to South Africa’s infrastructure are very important and because of this it is important that an effort is made to reduce the challenges that occur during the development of official statistics. For official statistics to be developed successfully quality standards need to be built into an organisational framework and form a system of architecture (Statistics New Zealand 2009:1). Therefore, this study seeks to develop a statistical methodology that is appropriate and scientifically correct using an automated statistical system for audits in government regulatory authorities. The study makes use of Mathematica to provide guidelines on how to develop and use an automated statistical audit system. A comprehensive literature study was conducted using existing secondary sources. A quantitative research paradigm was adopted for this study, to empirically assess the demographic characteristics of tenants of Social Housing Estates and their perceptions towards the rental units they inhabit. More specifically a descriptive study was undertaken. Furthermore, a sample size was selected by means of convenience sampling for a case study on SHRA to assess the respondent’s biographical information. From this sample, a pilot study was conducted investigating the general perceptions of the respondents regarding the physical conditions and quality of their units. The technical development of an automated statistical audit system was discussed. This process involved the development and use of a questionnaire design tool, statistical analysis and reporting and how Mathematica software served as a platform for developing the system. The findings of this study provide insights on how government regulatory authorities can best utilise automated statistical audits for regulation purposes and achieved this by developing an automated statistical audit system for government regulatory authorities. It is hoped that the findings of this study will provide government regulatory authorities with practical suggestions or solutions regarding the generating of official statistics for regulatory purposes, and that the suggestions for future research will inspire future researchers to further investigate automated statistical audit systems, statistical analysis, automated questionnaire development, and government regulatory authorities individually.
- Full Text:
- Date Issued: 2015
- Authors: Xozwa, Thandolwethu
- Date: 2015
- Subjects: Auditing -- Statistical methods -- Data processing , Mathematica (Computer program language)
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/6061 , vital:21035
- Description: Governments all over the world are faced with numerous challenges while running their countries on a daily basis. The predominant challenges which arise are those which involve statistical methodologies. Official statistics to South Africa’s infrastructure are very important and because of this it is important that an effort is made to reduce the challenges that occur during the development of official statistics. For official statistics to be developed successfully quality standards need to be built into an organisational framework and form a system of architecture (Statistics New Zealand 2009:1). Therefore, this study seeks to develop a statistical methodology that is appropriate and scientifically correct using an automated statistical system for audits in government regulatory authorities. The study makes use of Mathematica to provide guidelines on how to develop and use an automated statistical audit system. A comprehensive literature study was conducted using existing secondary sources. A quantitative research paradigm was adopted for this study, to empirically assess the demographic characteristics of tenants of Social Housing Estates and their perceptions towards the rental units they inhabit. More specifically a descriptive study was undertaken. Furthermore, a sample size was selected by means of convenience sampling for a case study on SHRA to assess the respondent’s biographical information. From this sample, a pilot study was conducted investigating the general perceptions of the respondents regarding the physical conditions and quality of their units. The technical development of an automated statistical audit system was discussed. This process involved the development and use of a questionnaire design tool, statistical analysis and reporting and how Mathematica software served as a platform for developing the system. The findings of this study provide insights on how government regulatory authorities can best utilise automated statistical audits for regulation purposes and achieved this by developing an automated statistical audit system for government regulatory authorities. It is hoped that the findings of this study will provide government regulatory authorities with practical suggestions or solutions regarding the generating of official statistics for regulatory purposes, and that the suggestions for future research will inspire future researchers to further investigate automated statistical audit systems, statistical analysis, automated questionnaire development, and government regulatory authorities individually.
- Full Text:
- Date Issued: 2015
Azawan: precolonial musical culture and Saharawi nationalism in the refugee camps of the Hamada Desert in Algeria
- Authors: Amoros, Luis Gimenez
- Date: 2015
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59710 , vital:27641 , http://dx.doi.org/10.21504/amj.v10i1.1225
- Description: This article analyses Saharawi music as performed for the refugee community in the camps. I argue that the construction and evolution of Saharawi music in the camps is divided into two main areas: nationalism in relation to the decolonisation of Western Sahara, and maintenance of cultural values in Saharawi music found in the historical retention of the Haul modal system originating in precolonial Saharawi culture. Local audiences use the term Azawan to define the combination of nationalist sentiments and retention of their precolonial musical culture in Saharawi music.
- Full Text:
- Date Issued: 2015
- Authors: Amoros, Luis Gimenez
- Date: 2015
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59710 , vital:27641 , http://dx.doi.org/10.21504/amj.v10i1.1225
- Description: This article analyses Saharawi music as performed for the refugee community in the camps. I argue that the construction and evolution of Saharawi music in the camps is divided into two main areas: nationalism in relation to the decolonisation of Western Sahara, and maintenance of cultural values in Saharawi music found in the historical retention of the Haul modal system originating in precolonial Saharawi culture. Local audiences use the term Azawan to define the combination of nationalist sentiments and retention of their precolonial musical culture in Saharawi music.
- Full Text:
- Date Issued: 2015
Bacterial degradation of fossil fuel waste in aqueous and solid media
- Authors: Edeki, Oghenekume Gerald
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/54565 , vital:26588
- Description: The generation of environmental pollutants worldwide is mainly due to over reliance on fossil fuels as a source of energy. As a result of the negative impacts of these pollutants on the health of humans, animals, plants and microorganisms, global attention has been directed towards ways of containing this problem. Biodegradation of fossil fuel is one of the most effective methods used to remediate contaminated systems. However with regard to coal waste, much of what is known is based on the ability of fungal species to biosolubilize this material under enrichment conditions in a laboratory setting. For effective biodegradation as a remediation technique, there is an immediate need to source, isolate, enrich and incorporate other microorganisms such as bacteria into bioremediation technologies. The goal of this dissertation was to isolate bacteria from fossil fuel contaminated environments and to demonstrate competence for petroleum hydrocarbon degradation which was achieved using a combination of analytical methods such as spectrophotometry, FT-IR, SEM and GC-MS. Screening for biodegradation of coal and petroleum hydrocarbon waste resulted in the isolation of 75 bacterial strains of which 15 showed good potential for use in developing remedial biotechnologies. Spectrophotometric analysis of bacteria both in coal and petroleum hydrocarbons (all in aqueous media) revealed a high proliferation of bacteria in these media suggesting that these microbes can effectively utilize the various substrates as a source of carbon. The isolated bacteria effectively degraded and converted waste coal to humic and fulvic acids; products required to enrich coal mine dumps to support re-vegetation. Scanning electron microscopy showed the attachment of bacteria to waste coal surfaces and the disintegration of coal structures while FT-IR analysis of extracted humic-like substances from biodegraded waste coal revealed these to have the same functional groups as commercial humic acid. Specific consortia which were established using the isolated bacterial strains, showed greater potential to biodegrade coal than did individual isolates. This was evident in experiments carried out on coal and hydrocarbons where the efficient colonization and utilization of these substrates by each bacterial consortium was observed due to the effect of added nutrients such as algae. The biodegradation of liquid petroleum hydrocarbons (diesel and BTEX) was also achieved using the 15 bacterial isolates. GC-MS analysis of extracted residual PHC from aqueous and solid media revealed rapid breakdown of these contaminants by bacteria. Different bacterial consortia established from the individual isolates were shown to be more efficient than single isolates indicating that formulated consortia are the biocatalysts of choice for fossil fuel biodegradation. This study represents one of the most detailed screenings for bacteria from fossil fuel contaminated sites and the isolation of strains with potential to biodegrade coal and petroleum hydrocarbon wastes. Several consortia have been developed and these show potential for further development as biocatalysts for use in bioremediation technology development. An evaluation of efficiency of each established bacterial consortium for biodegradation in a commercial and/or industrial setting at pilot scale is now needed.
- Full Text:
- Date Issued: 2015
- Authors: Edeki, Oghenekume Gerald
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/54565 , vital:26588
- Description: The generation of environmental pollutants worldwide is mainly due to over reliance on fossil fuels as a source of energy. As a result of the negative impacts of these pollutants on the health of humans, animals, plants and microorganisms, global attention has been directed towards ways of containing this problem. Biodegradation of fossil fuel is one of the most effective methods used to remediate contaminated systems. However with regard to coal waste, much of what is known is based on the ability of fungal species to biosolubilize this material under enrichment conditions in a laboratory setting. For effective biodegradation as a remediation technique, there is an immediate need to source, isolate, enrich and incorporate other microorganisms such as bacteria into bioremediation technologies. The goal of this dissertation was to isolate bacteria from fossil fuel contaminated environments and to demonstrate competence for petroleum hydrocarbon degradation which was achieved using a combination of analytical methods such as spectrophotometry, FT-IR, SEM and GC-MS. Screening for biodegradation of coal and petroleum hydrocarbon waste resulted in the isolation of 75 bacterial strains of which 15 showed good potential for use in developing remedial biotechnologies. Spectrophotometric analysis of bacteria both in coal and petroleum hydrocarbons (all in aqueous media) revealed a high proliferation of bacteria in these media suggesting that these microbes can effectively utilize the various substrates as a source of carbon. The isolated bacteria effectively degraded and converted waste coal to humic and fulvic acids; products required to enrich coal mine dumps to support re-vegetation. Scanning electron microscopy showed the attachment of bacteria to waste coal surfaces and the disintegration of coal structures while FT-IR analysis of extracted humic-like substances from biodegraded waste coal revealed these to have the same functional groups as commercial humic acid. Specific consortia which were established using the isolated bacterial strains, showed greater potential to biodegrade coal than did individual isolates. This was evident in experiments carried out on coal and hydrocarbons where the efficient colonization and utilization of these substrates by each bacterial consortium was observed due to the effect of added nutrients such as algae. The biodegradation of liquid petroleum hydrocarbons (diesel and BTEX) was also achieved using the 15 bacterial isolates. GC-MS analysis of extracted residual PHC from aqueous and solid media revealed rapid breakdown of these contaminants by bacteria. Different bacterial consortia established from the individual isolates were shown to be more efficient than single isolates indicating that formulated consortia are the biocatalysts of choice for fossil fuel biodegradation. This study represents one of the most detailed screenings for bacteria from fossil fuel contaminated sites and the isolation of strains with potential to biodegrade coal and petroleum hydrocarbon wastes. Several consortia have been developed and these show potential for further development as biocatalysts for use in bioremediation technology development. An evaluation of efficiency of each established bacterial consortium for biodegradation in a commercial and/or industrial setting at pilot scale is now needed.
- Full Text:
- Date Issued: 2015
Baculovirus-based strategies for the management of insect pests: a focus on development and application in South Africa
- Knox, Caroline M, Moore, Sean D, Luke, Garry, Hill, Martin P
- Authors: Knox, Caroline M , Moore, Sean D , Luke, Garry , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416829 , vital:71389 , xlink:href="https://doi.org/10.1080/09583157.2014.949222"
- Description: There is growing concern among governments, scientists, agricultural practitioners and the general public regarding the negative implications of widespread synthetic chemical pesticide application for the control of crop pests. As a result, baculovirus biopesticides are gaining popularity as components of integrated pest management (IPM) programmes in many countries despite several disadvantages related to slow speed of kill, limited host range and complex large scale production. In South Africa, baculoviruses are incorporated into IPM programmes for the control of crop pests in the field, and recent bioprospecting has led to the characterisation of several novel isolates with the potential to be formulated as commercial products. This contribution will provide an overview of the use of baculoviruses against insect pests in South Africa, as well as research and development efforts aimed at broadening their application as biocontrol agents. Challenges faced by researchers in developmental projects as well as potential users of baculoviruses as biopesticides in the field are also discussed.
- Full Text:
- Date Issued: 2015
- Authors: Knox, Caroline M , Moore, Sean D , Luke, Garry , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416829 , vital:71389 , xlink:href="https://doi.org/10.1080/09583157.2014.949222"
- Description: There is growing concern among governments, scientists, agricultural practitioners and the general public regarding the negative implications of widespread synthetic chemical pesticide application for the control of crop pests. As a result, baculovirus biopesticides are gaining popularity as components of integrated pest management (IPM) programmes in many countries despite several disadvantages related to slow speed of kill, limited host range and complex large scale production. In South Africa, baculoviruses are incorporated into IPM programmes for the control of crop pests in the field, and recent bioprospecting has led to the characterisation of several novel isolates with the potential to be formulated as commercial products. This contribution will provide an overview of the use of baculoviruses against insect pests in South Africa, as well as research and development efforts aimed at broadening their application as biocontrol agents. Challenges faced by researchers in developmental projects as well as potential users of baculoviruses as biopesticides in the field are also discussed.
- Full Text:
- Date Issued: 2015
Barriers to and enablers of climate change adaptation in four South African municipalities, and implications for community based adaptation
- Authors: Spires, Meggan Hazel
- Date: 2015
- Subjects: Climatic changes -- South Africa , Climatic changes -- Risk management -- South Africa , Climatic changes -- Social aspects -- South Africa , Climate change mitigation -- South Africa , Climatic changes -- Government policy -- South Africa , Municipal government -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4787 , http://hdl.handle.net/10962/d1018913
- Description: The focus of this study is on understanding the multiple and interacting factors that hinder or enable municipal planned climate change adaptation, here called barriers and enablers respectively, and their implications for community based adaptation. To do this I developed a conceptual framework of barriers to and enablers of planned climate change adaptation, which informed a systematic literature review of barriers to planned community based adaptation in developing countries. In this framework barriers were grouped into resource, social and physical barriers. I then conducted empirical case study analysis using qualitative research methods in four South African municipalities to understand what barriers and enablers manifested in these contexts. In light of the reflexive nature of my methodology, my framework was adjusted based on my empirical findings, where contextual barriers were found to better represent the empirical results and subsumed physical barriers. I found my framework useful for analysis, but in the empirical cases, barriers and enablers overlaid and interacted so significantly that in reality it was often difficult to separate them. A key finding was that enablers tended to be more about the way things are done, as opposed to direct opposites of barriers. Comparison of barriers and enablers across the case studies revealed a number of key themes. Municipalities struggle to implement climate change adaptation and community based adaptation within contexts of significant social, economic and ecological challenges. These contextual barriers, when combined with certain cognitive barriers, lead to reactive responses. Existing municipal systems and structures make it difficult to enable climate change adaptation, which is inherently cross‐sectoral and messy, and especially community based adaptation that is bottom‐up and participatory. Lack of locally applicable knowledge, funding and human resources were found to be significant resource barriers, and were often underlain by social barriers relating to perceptions, norms, discourses and governance challenges. Enablers of engaged officials, operating within enabling organisational environments and drawing on partnerships and networks, were able to overcome or circumvent these barriers. When these enablers coincided with windows of opportunity that increased the prioritisation of climate change within the municipality, projects with ancillary benefits were often implemented. Analysis of the barriers and enablers identified in the literature and case studies, informed discussion on whether municipalities are able to implement community based adaptation as defined in the literature, as well as the development of recommendations for how municipal planned climate change adaptation and community based adaptation can be further understood and enabled in the future. These recommendations for practice and research include: (a) To acknowledge and understand the conceptual framings of municipal climate change work, as these framings inform the climate change agenda that is pursued, and hence what municipal climate change adaptation work is done and how it was done. (b) The need for further research into the social barriers that influence the vital enablers of engaged officials, enabling organisational environments, and partnerships and networks. (c) To learn from pilot community‐level interventions that have been implemented by municipalities, as well as from other disciplines and municipalities. (d) To develop top‐down/bottom‐up approaches to enable municipal planned climate change adaptation and community based adaptation, that benefits from high level support and guidance, as well as local level flexibility and learning‐by‐doing. (e) To develop viable mechanisms for municipalities to better engage with the communities they serve.
- Full Text:
- Date Issued: 2015
- Authors: Spires, Meggan Hazel
- Date: 2015
- Subjects: Climatic changes -- South Africa , Climatic changes -- Risk management -- South Africa , Climatic changes -- Social aspects -- South Africa , Climate change mitigation -- South Africa , Climatic changes -- Government policy -- South Africa , Municipal government -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4787 , http://hdl.handle.net/10962/d1018913
- Description: The focus of this study is on understanding the multiple and interacting factors that hinder or enable municipal planned climate change adaptation, here called barriers and enablers respectively, and their implications for community based adaptation. To do this I developed a conceptual framework of barriers to and enablers of planned climate change adaptation, which informed a systematic literature review of barriers to planned community based adaptation in developing countries. In this framework barriers were grouped into resource, social and physical barriers. I then conducted empirical case study analysis using qualitative research methods in four South African municipalities to understand what barriers and enablers manifested in these contexts. In light of the reflexive nature of my methodology, my framework was adjusted based on my empirical findings, where contextual barriers were found to better represent the empirical results and subsumed physical barriers. I found my framework useful for analysis, but in the empirical cases, barriers and enablers overlaid and interacted so significantly that in reality it was often difficult to separate them. A key finding was that enablers tended to be more about the way things are done, as opposed to direct opposites of barriers. Comparison of barriers and enablers across the case studies revealed a number of key themes. Municipalities struggle to implement climate change adaptation and community based adaptation within contexts of significant social, economic and ecological challenges. These contextual barriers, when combined with certain cognitive barriers, lead to reactive responses. Existing municipal systems and structures make it difficult to enable climate change adaptation, which is inherently cross‐sectoral and messy, and especially community based adaptation that is bottom‐up and participatory. Lack of locally applicable knowledge, funding and human resources were found to be significant resource barriers, and were often underlain by social barriers relating to perceptions, norms, discourses and governance challenges. Enablers of engaged officials, operating within enabling organisational environments and drawing on partnerships and networks, were able to overcome or circumvent these barriers. When these enablers coincided with windows of opportunity that increased the prioritisation of climate change within the municipality, projects with ancillary benefits were often implemented. Analysis of the barriers and enablers identified in the literature and case studies, informed discussion on whether municipalities are able to implement community based adaptation as defined in the literature, as well as the development of recommendations for how municipal planned climate change adaptation and community based adaptation can be further understood and enabled in the future. These recommendations for practice and research include: (a) To acknowledge and understand the conceptual framings of municipal climate change work, as these framings inform the climate change agenda that is pursued, and hence what municipal climate change adaptation work is done and how it was done. (b) The need for further research into the social barriers that influence the vital enablers of engaged officials, enabling organisational environments, and partnerships and networks. (c) To learn from pilot community‐level interventions that have been implemented by municipalities, as well as from other disciplines and municipalities. (d) To develop top‐down/bottom‐up approaches to enable municipal planned climate change adaptation and community based adaptation, that benefits from high level support and guidance, as well as local level flexibility and learning‐by‐doing. (e) To develop viable mechanisms for municipalities to better engage with the communities they serve.
- Full Text:
- Date Issued: 2015
Base erosion and profit shifting by multinational corporations and weaknesses revealed in South African income tax legislation
- Authors: Peerbhai, Aneesa
- Date: 2015
- Subjects: International business enterprises -- Law and legislation -- South Africa , Corporations -- Taxation -- Law and legislation -- South Africa , Tax planning -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:917 , http://hdl.handle.net/10962/d1017540
- Description: This research examined the concept of base erosion and profit shifting in the context of tax schemes employed by multinational corporations. The objective of this thesis was to identify weaknesses within South Africa’s income tax legislation, based on these schemes, and further to propose recommendations to counter the occurrence of base erosion and profit shifting by multinational companies. The research also comprised of a limited review of current global and South African initiatives to address the problem of base erosion and profit shifting. It was concluded that there are a number of weaknesses in the definitions and provisions of the South African income tax legislation that need to be addressed in order to reduce base erosion and profit shifting. Brief recommendations were proposed in relation to each of the weaknesses, in order to address them.
- Full Text:
- Date Issued: 2015
- Authors: Peerbhai, Aneesa
- Date: 2015
- Subjects: International business enterprises -- Law and legislation -- South Africa , Corporations -- Taxation -- Law and legislation -- South Africa , Tax planning -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:917 , http://hdl.handle.net/10962/d1017540
- Description: This research examined the concept of base erosion and profit shifting in the context of tax schemes employed by multinational corporations. The objective of this thesis was to identify weaknesses within South Africa’s income tax legislation, based on these schemes, and further to propose recommendations to counter the occurrence of base erosion and profit shifting by multinational companies. The research also comprised of a limited review of current global and South African initiatives to address the problem of base erosion and profit shifting. It was concluded that there are a number of weaknesses in the definitions and provisions of the South African income tax legislation that need to be addressed in order to reduce base erosion and profit shifting. Brief recommendations were proposed in relation to each of the weaknesses, in order to address them.
- Full Text:
- Date Issued: 2015
Beauveria and Metarhizium against false codling moth (Lepidoptera: Tortricidae): a step towards selecting isolates for potential development of a mycoinsecticide
- Coombes, Candice A, Hill, Martin P, Moore, Sean D, Dames, Joanna F, Fullard, T
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405757 , vital:70203 , xlink:href="https://hdl.handle.net/10520/EJC167505"
- Description: False codling moth, Thaumatotibia leucotreta Meyrick (1912) (Lepidoptera: Tortricidae), can cause both pre- and post-harvest damage to citrus fruit. Not only can this result in reduced crop yield, but more importantly because of the moth's endemism to sub-Saharan Africa, it is classified as a phytosanitary pest by many export markets. An entire consignment of citrus may be rejected in the presence of a single moth (Moore 2012). Since the bulk of citrus fruit production in South Africa is exported, the control of T. leucotreta is critical (Citrus Growers Association, South Africa 2012). Traditionally, control has been achieved through the use of chemical insecticides; however, residue restrictions, resistance development and concerns about environmental pollution have substantially reduced the dependence on chemical pesticides in citrus. Research on T. leucotreta control has therefore focused on the use of biological organisms (e.g. parasitoids and viruses), which are used as control agents within an integrated pest management (IPM) programme in citrus. These biological control agents, however, only targeted the aboveground life stages of the pest, not the soil-dwelling life stages (late fifth instars, prepupae, pupae), which is the subject of this contribution (Moore 2012).
- Full Text:
- Date Issued: 2015
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405757 , vital:70203 , xlink:href="https://hdl.handle.net/10520/EJC167505"
- Description: False codling moth, Thaumatotibia leucotreta Meyrick (1912) (Lepidoptera: Tortricidae), can cause both pre- and post-harvest damage to citrus fruit. Not only can this result in reduced crop yield, but more importantly because of the moth's endemism to sub-Saharan Africa, it is classified as a phytosanitary pest by many export markets. An entire consignment of citrus may be rejected in the presence of a single moth (Moore 2012). Since the bulk of citrus fruit production in South Africa is exported, the control of T. leucotreta is critical (Citrus Growers Association, South Africa 2012). Traditionally, control has been achieved through the use of chemical insecticides; however, residue restrictions, resistance development and concerns about environmental pollution have substantially reduced the dependence on chemical pesticides in citrus. Research on T. leucotreta control has therefore focused on the use of biological organisms (e.g. parasitoids and viruses), which are used as control agents within an integrated pest management (IPM) programme in citrus. These biological control agents, however, only targeted the aboveground life stages of the pest, not the soil-dwelling life stages (late fifth instars, prepupae, pupae), which is the subject of this contribution (Moore 2012).
- Full Text:
- Date Issued: 2015
Before before & after after
- Authors: Musavengana, Shelter K
- Date: 2015
- Subjects: South African fiction (English) -- 21st century , Short stories, South African -- 21st century , Creative writing (Higher education)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:5991 , http://hdl.handle.net/10962/d1017775
- Description: The stories in this collection explore the fantastical, the power of memory, and the human capacity to love. Moving between the surreal, the absurd, the allegorical, and the metafictional, they elaborate on life's ordinary madness and the mysteries of the spirit. By challenging the either/or boundaries of the binary of realism and fantasy, the stories provoke the reader to engage actively with the text. Influenced by experimental US author Stacey Levine, the mid‐century British novelist Barbara Comyns, and the adventurous Chinese writer Can Xue, in most cases, they create a playful, experimental world that exists at a slight angle to the world as we know it.
- Full Text:
- Date Issued: 2015
- Authors: Musavengana, Shelter K
- Date: 2015
- Subjects: South African fiction (English) -- 21st century , Short stories, South African -- 21st century , Creative writing (Higher education)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:5991 , http://hdl.handle.net/10962/d1017775
- Description: The stories in this collection explore the fantastical, the power of memory, and the human capacity to love. Moving between the surreal, the absurd, the allegorical, and the metafictional, they elaborate on life's ordinary madness and the mysteries of the spirit. By challenging the either/or boundaries of the binary of realism and fantasy, the stories provoke the reader to engage actively with the text. Influenced by experimental US author Stacey Levine, the mid‐century British novelist Barbara Comyns, and the adventurous Chinese writer Can Xue, in most cases, they create a playful, experimental world that exists at a slight angle to the world as we know it.
- Full Text:
- Date Issued: 2015
Being a Born Free: the misunderstandings and missed opportunities facing young South Africans
- Authors: Malila, Vanessa
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158680 , vital:40220 , https://hdl.handle.net/10520/EJC175765
- Description: Young South Africans are often referred to as the Born Frees - a term which sometimes means people born after 1994, sometimes people born after 1990, or young people who came of age politically after 1994. I've come to really dislike the term Born Frees and particularly the way it is used by the media and the politicians. By calling young people Born Frees, society is using apartheid as a reference point to identify a post-apartheid generation. This reference point (the transition to a 'free' society) unfortunately does not resonate with many of the young people that I've encountered in my research and many feel insulted by the implications of this term, which does not apply to them in any way. Should South African society really be using the transition from apartheid to define its young people and how does it relate to the lives of real young people in South Africa today? Are they really Born Free, free from what, free to do what, free individuals or free as a collective? I will look at some of the stereotypes being used in the mainstream media of Born Frees, and then look at the reaction to this term by some real young South Africans.
- Full Text:
- Date Issued: 2015
- Authors: Malila, Vanessa
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158680 , vital:40220 , https://hdl.handle.net/10520/EJC175765
- Description: Young South Africans are often referred to as the Born Frees - a term which sometimes means people born after 1994, sometimes people born after 1990, or young people who came of age politically after 1994. I've come to really dislike the term Born Frees and particularly the way it is used by the media and the politicians. By calling young people Born Frees, society is using apartheid as a reference point to identify a post-apartheid generation. This reference point (the transition to a 'free' society) unfortunately does not resonate with many of the young people that I've encountered in my research and many feel insulted by the implications of this term, which does not apply to them in any way. Should South African society really be using the transition from apartheid to define its young people and how does it relate to the lives of real young people in South Africa today? Are they really Born Free, free from what, free to do what, free individuals or free as a collective? I will look at some of the stereotypes being used in the mainstream media of Born Frees, and then look at the reaction to this term by some real young South Africans.
- Full Text:
- Date Issued: 2015
Being at Home: Race, Institutional Culture and Transformation at South African Higher Education Institutions
- Tabensky, Pedro, Matthews, Sally
- Authors: Tabensky, Pedro , Matthews, Sally
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/142084 , vital:38048 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
- Authors: Tabensky, Pedro , Matthews, Sally
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/142084 , vital:38048 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
Being for others : critical reflections on the stranger, the estranged and the self in participatory art
- Authors: Munro, Samantha Fawn
- Date: 2015
- Subjects: Self , Identity (Philosophical concept) in art , Alienation (Philosophy) , Interactive art , Art appreciation , Art exhibition audiences , Interactive art -- Themes, motives , Social interaction
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2507 , http://hdl.handle.net/10962/d1017771
- Description: By referring to established concepts and theories which contemplate our experiences in relation to others and space, this thesis examines the interactions and responses of an audience during various participatory artworks. I draw upon Jean-Paul Sartre’s Being and Nothingness and Elizabeth Grosz’ Architecture From The Outside: Essays on Virtual and Real Space in order to understand our interactions with other people, our interactions inside an environment, and the objects and ceremonies we use during these interactions. I align these experiences with the methods which are employed to anticipate and create the interactions between an audience and a participatory artwork. Our daily interactions can be considered a frame that an artist shapes for their represented situation to allow, provide and guide an audience towards their possibilities for movements and actions within a participatory artwork. The interactions that occur in participatory art are done in relation to others and include groups of people interacting with each other rather than an individual disembodied experience. I refer to Claire Bishop in her book, Artificial Hells, and Nicolas Bourriaud in Relational Aesthetics in order to define participatory art. In defining participatory art I focus on the idea that participation is a social activity without which the artwork does not function or exist. I unravel Brett Bailey’s Exhibit A, Anthea Moys Anthea Moys vs The City of Grahamstown and Christian Boltanski’s Personnes in terms of the frame they use to construct participation and interaction. I refer to my own exhibition Ineffaceable as an exploration of these frames which encourage participation. The inside and the outside are a constant theme throughout this thesis and my exhibition. This thematic re-emerges in relation to a number of opposing and fluctuating dynamics: the self and the other; the object and the subject; familiarity and strangeness; the participator and the spectator; the immersive and the disembodied; and the artwork and the audience. Participatory art has not been sufficiently explored particularly in South Africa with South African case studies and particularly from a practical standpoint that includes methodologies for creating participation. This thesis hopes to enrich and contribute to the contemplations on participatory art by focusing on our interactions with others.
- Full Text:
- Date Issued: 2015
- Authors: Munro, Samantha Fawn
- Date: 2015
- Subjects: Self , Identity (Philosophical concept) in art , Alienation (Philosophy) , Interactive art , Art appreciation , Art exhibition audiences , Interactive art -- Themes, motives , Social interaction
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2507 , http://hdl.handle.net/10962/d1017771
- Description: By referring to established concepts and theories which contemplate our experiences in relation to others and space, this thesis examines the interactions and responses of an audience during various participatory artworks. I draw upon Jean-Paul Sartre’s Being and Nothingness and Elizabeth Grosz’ Architecture From The Outside: Essays on Virtual and Real Space in order to understand our interactions with other people, our interactions inside an environment, and the objects and ceremonies we use during these interactions. I align these experiences with the methods which are employed to anticipate and create the interactions between an audience and a participatory artwork. Our daily interactions can be considered a frame that an artist shapes for their represented situation to allow, provide and guide an audience towards their possibilities for movements and actions within a participatory artwork. The interactions that occur in participatory art are done in relation to others and include groups of people interacting with each other rather than an individual disembodied experience. I refer to Claire Bishop in her book, Artificial Hells, and Nicolas Bourriaud in Relational Aesthetics in order to define participatory art. In defining participatory art I focus on the idea that participation is a social activity without which the artwork does not function or exist. I unravel Brett Bailey’s Exhibit A, Anthea Moys Anthea Moys vs The City of Grahamstown and Christian Boltanski’s Personnes in terms of the frame they use to construct participation and interaction. I refer to my own exhibition Ineffaceable as an exploration of these frames which encourage participation. The inside and the outside are a constant theme throughout this thesis and my exhibition. This thematic re-emerges in relation to a number of opposing and fluctuating dynamics: the self and the other; the object and the subject; familiarity and strangeness; the participator and the spectator; the immersive and the disembodied; and the artwork and the audience. Participatory art has not been sufficiently explored particularly in South Africa with South African case studies and particularly from a practical standpoint that includes methodologies for creating participation. This thesis hopes to enrich and contribute to the contemplations on participatory art by focusing on our interactions with others.
- Full Text:
- Date Issued: 2015
Beneficiary perceptions of a low income housing scheme: Mdantsane township
- Authors: Bandile, Unathi Cordelia
- Date: 2015
- Subjects: Low-income housing -- South Africa -- Eastern Cape , Public housing -- South Africa -- Eastern Cape , Housing development -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9719 , http://hdl.handle.net/10948/d1021137
- Description: The aim of this study was to investigate the socio-economic perceptions of the beneficiaries of the low income housing scheme in Unit P, of Mdantsane Township, under Buffalo City Metropolitan Municipality. Both quantitative and qualitative approaches were utilised in this study. For instance, questionnaires on the perceptions were administered amongst twenty (20) beneficiaries of this low housing scheme. Semi structured interviews were conducted amongst five (5) respondents who participated in the survey design. The study found that the intervention of providing poor people with houses was not appropriately done as these houses are too small and therefore fail to consider the families of the beneficiaries although the South African government seems to have succeeded to some extent in providing low income housing for the unemployed and those that belong to the low income category. The study also found that the location of Unit P poses a threat because it is located away from all the amenities compelling the beneficiaries to travel more than 5km to the amenities and essential services. The study therefore recommends that the government employs competent contractors that would do a proper job. State officials, tasked with overseeing the various state funded housing projects, have to ascertain the success of these projects by making sure that the contractors do not lack skills such as the ability to facilitate projects of a high magnitude as that could lead to flawed projects. They should be constantly monitored and post evaluated. This will help to minimize the wasting of state resources.
- Full Text:
- Date Issued: 2015
- Authors: Bandile, Unathi Cordelia
- Date: 2015
- Subjects: Low-income housing -- South Africa -- Eastern Cape , Public housing -- South Africa -- Eastern Cape , Housing development -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9719 , http://hdl.handle.net/10948/d1021137
- Description: The aim of this study was to investigate the socio-economic perceptions of the beneficiaries of the low income housing scheme in Unit P, of Mdantsane Township, under Buffalo City Metropolitan Municipality. Both quantitative and qualitative approaches were utilised in this study. For instance, questionnaires on the perceptions were administered amongst twenty (20) beneficiaries of this low housing scheme. Semi structured interviews were conducted amongst five (5) respondents who participated in the survey design. The study found that the intervention of providing poor people with houses was not appropriately done as these houses are too small and therefore fail to consider the families of the beneficiaries although the South African government seems to have succeeded to some extent in providing low income housing for the unemployed and those that belong to the low income category. The study also found that the location of Unit P poses a threat because it is located away from all the amenities compelling the beneficiaries to travel more than 5km to the amenities and essential services. The study therefore recommends that the government employs competent contractors that would do a proper job. State officials, tasked with overseeing the various state funded housing projects, have to ascertain the success of these projects by making sure that the contractors do not lack skills such as the ability to facilitate projects of a high magnitude as that could lead to flawed projects. They should be constantly monitored and post evaluated. This will help to minimize the wasting of state resources.
- Full Text:
- Date Issued: 2015
Benzimidazole or Diamide From a Reaction of Diamines and Carboxylic Acids or Acid Chlorides: Crystal Structures and Theoretical Studies
- Odame, Felix, Hosten, Eric C, Betz, Richard, Lobb, Kevin A, Tshentu, Zenixole R
- Authors: Odame, Felix , Hosten, Eric C , Betz, Richard , Lobb, Kevin A , Tshentu, Zenixole R
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447938 , vital:74685 , xlink:href="https://pdfs.semanticscholar.org/bf5a/ce94c9436f40059793eb988e08da8ef09886.pdf"
- Description: A reaction of an acid chloride with a diamine yielded a diamide. m-Toluic acid was chlorinated to m-toluoyl chloride and subsequently reacted with 4-methyl-o-phenylenediamine in pyridine to obtain 3-methyl-N-[2-(3-methylbenzamido)phenylbenzamide (I). 2-(3-Methylphenyl)-1H-benzimidazole (II) has been obtained upon reacting o-phenylenediamine with m-toluic acid in polyphosphoric acid and toluene. The compounds have been characterized by IR, NMR, microanalyses and GC-MS. The crystal structures of the compounds have been discussed. DFT calculations of the frontier orbitals of the precursor compounds have been carried out to ascertain the groups that contribute to the HOMO and LUMO, and to study their contribution to the reactivity in the formation of the diamides and benzimidazoles. The synthesis of the amide from a diamine was seen to be favoured in the presence of a good leaving group attached to the carbonyl as in the case of acid chloride. However, the synthesis of benzimidazoles was found to be favoured in the presence of an excess of a protonating agent and high temperature.
- Full Text:
- Date Issued: 2015
- Authors: Odame, Felix , Hosten, Eric C , Betz, Richard , Lobb, Kevin A , Tshentu, Zenixole R
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447938 , vital:74685 , xlink:href="https://pdfs.semanticscholar.org/bf5a/ce94c9436f40059793eb988e08da8ef09886.pdf"
- Description: A reaction of an acid chloride with a diamine yielded a diamide. m-Toluic acid was chlorinated to m-toluoyl chloride and subsequently reacted with 4-methyl-o-phenylenediamine in pyridine to obtain 3-methyl-N-[2-(3-methylbenzamido)phenylbenzamide (I). 2-(3-Methylphenyl)-1H-benzimidazole (II) has been obtained upon reacting o-phenylenediamine with m-toluic acid in polyphosphoric acid and toluene. The compounds have been characterized by IR, NMR, microanalyses and GC-MS. The crystal structures of the compounds have been discussed. DFT calculations of the frontier orbitals of the precursor compounds have been carried out to ascertain the groups that contribute to the HOMO and LUMO, and to study their contribution to the reactivity in the formation of the diamides and benzimidazoles. The synthesis of the amide from a diamine was seen to be favoured in the presence of a good leaving group attached to the carbonyl as in the case of acid chloride. However, the synthesis of benzimidazoles was found to be favoured in the presence of an excess of a protonating agent and high temperature.
- Full Text:
- Date Issued: 2015