Hard choices ahead
- Authors: Pithouse, Richard, 1970-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:6204 , http://hdl.handle.net/10962/d1008573 , http://sacsis.org.za/site/article/334.1
- Description: preprint , From Introduction: In recent weeks people have been willing to risk arrest, violence and in some cases death at the hands of our habitually brutal police force to assert a whole range of demands. These demands have included an insistence on the right to the cities, the right to an income, the right to a decent education and the right to a living wage.
- Full Text:
- Authors: Pithouse, Richard, 1970-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:6204 , http://hdl.handle.net/10962/d1008573 , http://sacsis.org.za/site/article/334.1
- Description: preprint , From Introduction: In recent weeks people have been willing to risk arrest, violence and in some cases death at the hands of our habitually brutal police force to assert a whole range of demands. These demands have included an insistence on the right to the cities, the right to an income, the right to a decent education and the right to a living wage.
- Full Text:
Health literacy assessment: relexicalising a US test for a South African population
- Hunt, Sally, Dowse, Roslind, La Rose, Christopher M
- Authors: Hunt, Sally , Dowse, Roslind , La Rose, Christopher M
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/139131 , vital:37708 , DOI: 10.2989/SALALS.2008.26.2.7.571
- Description: The problems of illiteracy in health contexts have been well documented in the literature and include such serious repercussions as medication non-compliance and failure to seek medical help during the course of an illness. The Rapid Estimate of Adult Literacy in Medicine (REALM) is a standardised health literacy test developed in the United States that has been previously administered and researched in South Africa (Lecoko, 2000). It is an objective vocabulary test, designed as a screening instrument to identify the health literacy levels of patients in clinics, which uses item recognition of 66 health-related words. Lecoko found that, in a South African setting, only 8 out of the 66 words in the US-developed test could be deemed acceptable. Therefore, the current study focused on the principled relexicalisation of the REALM, using words gathered from health information and promotional texts in local clinics, hypothesising that this would improve its applicability. After administration to a statistically similar group of respondents, the number of acceptable words on the test increased from eight to 38. Thus it is concluded that principled relexicalisation may be one way of improving the applicability of standardised health literacy tests to local populations and settings. However, the limitations of standardised tests may prove to be a significant barrier overshadowing the value of relexicalisation.
- Full Text:
- Authors: Hunt, Sally , Dowse, Roslind , La Rose, Christopher M
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/139131 , vital:37708 , DOI: 10.2989/SALALS.2008.26.2.7.571
- Description: The problems of illiteracy in health contexts have been well documented in the literature and include such serious repercussions as medication non-compliance and failure to seek medical help during the course of an illness. The Rapid Estimate of Adult Literacy in Medicine (REALM) is a standardised health literacy test developed in the United States that has been previously administered and researched in South Africa (Lecoko, 2000). It is an objective vocabulary test, designed as a screening instrument to identify the health literacy levels of patients in clinics, which uses item recognition of 66 health-related words. Lecoko found that, in a South African setting, only 8 out of the 66 words in the US-developed test could be deemed acceptable. Therefore, the current study focused on the principled relexicalisation of the REALM, using words gathered from health information and promotional texts in local clinics, hypothesising that this would improve its applicability. After administration to a statistically similar group of respondents, the number of acceptable words on the test increased from eight to 38. Thus it is concluded that principled relexicalisation may be one way of improving the applicability of standardised health literacy tests to local populations and settings. However, the limitations of standardised tests may prove to be a significant barrier overshadowing the value of relexicalisation.
- Full Text:
How many declarations do we need?: Inside the drafting of the Bonn Declaration on education for sustainable development
- Authors: Lotz-Sisitka, Heila
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182522 , vital:43837 , xlink:href="https://doi.org/10.1177/097340820900300217"
- Description: The Bonn Declaration, approved by the 900 participants at the UNESCO World Conference on Sustainable Development, differs from other conference declarations in that it is the first declaration to deal exclusively with education for sustainable development. It received input from official State representatives and, perhaps because of that, it is somewhat less provocative than some nongovernmental or university-sponsored declarations. Also, it actually sets out, with some authority, an agenda for UNESCO, the manager of the UN Decade of Education for Sustainable Development. Though some may question the usefulness of conference declarations, history shows that such declarations do have at least some guiding power in that they provide common starting points for deliberation on possible changes at national and international levels.
- Full Text:
- Authors: Lotz-Sisitka, Heila
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182522 , vital:43837 , xlink:href="https://doi.org/10.1177/097340820900300217"
- Description: The Bonn Declaration, approved by the 900 participants at the UNESCO World Conference on Sustainable Development, differs from other conference declarations in that it is the first declaration to deal exclusively with education for sustainable development. It received input from official State representatives and, perhaps because of that, it is somewhat less provocative than some nongovernmental or university-sponsored declarations. Also, it actually sets out, with some authority, an agenda for UNESCO, the manager of the UN Decade of Education for Sustainable Development. Though some may question the usefulness of conference declarations, history shows that such declarations do have at least some guiding power in that they provide common starting points for deliberation on possible changes at national and international levels.
- Full Text:
Interaction of water-soluble CdTe quantum dots with octacarboxy metallophthalocyanines
- Idowu, Mopelola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264197 , vital:53708 , xlink:href="https://doi.org/10.1016/j.jlumin.2008.11.005"
- Description: Water-soluble CdTe quantum dots capped with L-cysteine (QD-CYS) were found to improve the photophysical and photochemical properties of octacarboxy metallophthalocyanine (MOCPc, M=Zn(II), Al(III)(OH), Ge(IV)(OH)2 and Si(IV)(OH)2) complexes. Increased diffusional interactions between the molecules and the ground-state molecular oxygen were established resulting from the increase in the triplet-state quantum yield and lifetimes of the MOCPcs in the presence of QD-CYS. Energy transfer occurred from QD-CYS to the MOCPcs upon excitation of QD-CYS. It was found that an efficient energy transfer process, which is not directly related to the amount of spectral overlap between the donor (QD-CYS) and the acceptor (MOCPc) can occur. Singlet oxygen via fluorescence resonance energy transfer (FRET) mechanism was produced in the QD-MPc mixture.
- Full Text:
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264197 , vital:53708 , xlink:href="https://doi.org/10.1016/j.jlumin.2008.11.005"
- Description: Water-soluble CdTe quantum dots capped with L-cysteine (QD-CYS) were found to improve the photophysical and photochemical properties of octacarboxy metallophthalocyanine (MOCPc, M=Zn(II), Al(III)(OH), Ge(IV)(OH)2 and Si(IV)(OH)2) complexes. Increased diffusional interactions between the molecules and the ground-state molecular oxygen were established resulting from the increase in the triplet-state quantum yield and lifetimes of the MOCPcs in the presence of QD-CYS. Energy transfer occurred from QD-CYS to the MOCPcs upon excitation of QD-CYS. It was found that an efficient energy transfer process, which is not directly related to the amount of spectral overlap between the donor (QD-CYS) and the acceptor (MOCPc) can occur. Singlet oxygen via fluorescence resonance energy transfer (FRET) mechanism was produced in the QD-MPc mixture.
- Full Text:
Investigating the effect of Genetic Algorithms on Filter Optimisation Within Fast Packet Classifiers
- Nottingham, Alastair, Irwin, Barry V W
- Authors: Nottingham, Alastair , Irwin, Barry V W
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428674 , vital:72528 , https://www.researchgate.net/profile/Marijke-Coet-zee/publication/220803190_A_Framework_for_Web_Services_Security_Policy_Negotiation/links/0fcfd50f7d806aafc8000000/A-Framework-for-Web-Services-Security-Policy-Negotiation.pdf#page=119
- Description: Packet demultiplexing and analysis is a core concern for network secu-rity, and has hence inspired numerous optimisation attempts since their conception in early packet demultiplexing filters such as CSPF and BPF. These optimisations have generally, but not exclusively, focused on improving the speed of packet classification. Despite these im-provements however, packet filters require further optimisation in order to be effectively applied within next generation networks. One identified optimisation is that of reducing the average path length of the global filter by selecting an optimum filter permutation. Since redundant code generation does not change the order of computation, the initial filter order before filter optimisation affects the average path length of the resultant control-flow graph, thus selection of an optimum permutation of filters could provide significant performance improvements. Unfortu-nately, this problem is NP-Complete. In this paper, we consider using Genetic Algorithms to’breed’an optimum filter permutation prior to re-dundant code elimination. Specifically, we aim to evaluate the effec-tiveness of such an optimisation in reducing filter control flow graphs.
- Full Text:
Investigating the effect of Genetic Algorithms on Filter Optimisation Within Fast Packet Classifiers
- Authors: Nottingham, Alastair , Irwin, Barry V W
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428674 , vital:72528 , https://www.researchgate.net/profile/Marijke-Coet-zee/publication/220803190_A_Framework_for_Web_Services_Security_Policy_Negotiation/links/0fcfd50f7d806aafc8000000/A-Framework-for-Web-Services-Security-Policy-Negotiation.pdf#page=119
- Description: Packet demultiplexing and analysis is a core concern for network secu-rity, and has hence inspired numerous optimisation attempts since their conception in early packet demultiplexing filters such as CSPF and BPF. These optimisations have generally, but not exclusively, focused on improving the speed of packet classification. Despite these im-provements however, packet filters require further optimisation in order to be effectively applied within next generation networks. One identified optimisation is that of reducing the average path length of the global filter by selecting an optimum filter permutation. Since redundant code generation does not change the order of computation, the initial filter order before filter optimisation affects the average path length of the resultant control-flow graph, thus selection of an optimum permutation of filters could provide significant performance improvements. Unfortu-nately, this problem is NP-Complete. In this paper, we consider using Genetic Algorithms to’breed’an optimum filter permutation prior to re-dundant code elimination. Specifically, we aim to evaluate the effec-tiveness of such an optimisation in reducing filter control flow graphs.
- Full Text:
Language shift in Grahamstown: A case study of selected Xhosa-speakers
- Authors: De Klerk, Vivian A
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158106 , vital:40149 , https://0-doi.org.wam.seals.ac.za/10.1515/ijsl.2000.146.87
- Description: A number of scholars (Fasold 1984; Aitchison 1991; Denison 1977; Dorian 1980; Gal 1979) have examined the issue of language maintenance and shift, trying to discover why certain languages (or language variants) sometimes replace each other among some Speakers, particularly in certain domains of linguistic behaviour under some conditions or intergroup contact. This article provides an overview of the main factors that have been identified as playing an important role in influencing language shift and then reports on the relative importance of these factors in a survey that examined the experiences and attitudes of Xhosa-speaking parents who have recently chosen to send their children to English-medium schools in Grahamstown (Eastern Cape, South Africa). The research was carried out during 1998, and the project was a multifaceted quantitative and qualitative longitudinal study involving responses to a postal questionnaire sent to all non-English parents at English-medium schools in the town, and follow-up Interviews with 26 parents.
- Full Text:
- Authors: De Klerk, Vivian A
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158106 , vital:40149 , https://0-doi.org.wam.seals.ac.za/10.1515/ijsl.2000.146.87
- Description: A number of scholars (Fasold 1984; Aitchison 1991; Denison 1977; Dorian 1980; Gal 1979) have examined the issue of language maintenance and shift, trying to discover why certain languages (or language variants) sometimes replace each other among some Speakers, particularly in certain domains of linguistic behaviour under some conditions or intergroup contact. This article provides an overview of the main factors that have been identified as playing an important role in influencing language shift and then reports on the relative importance of these factors in a survey that examined the experiences and attitudes of Xhosa-speaking parents who have recently chosen to send their children to English-medium schools in Grahamstown (Eastern Cape, South Africa). The research was carried out during 1998, and the project was a multifaceted quantitative and qualitative longitudinal study involving responses to a postal questionnaire sent to all non-English parents at English-medium schools in the town, and follow-up Interviews with 26 parents.
- Full Text:
Local Knowledge as a Source of Community Resilience: IKS community Development and Resilience
- Shava, Soul, Zazu, Clayton, Tidball, Keith, O'Donoghue, Rob B
- Authors: Shava, Soul , Zazu, Clayton , Tidball, Keith , O'Donoghue, Rob B
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433052 , vital:72928 , xlink:href="https://hdl.handle.net/10520/EJC61567"
- Description: Local knowledge can serve a source of local community resilience that provides an enabling capacity for people to sustain their livelihoods and adapt to environmental changes or new environments. This knowledge was evidenced as capable of resurfacing when contingent opportunities arise. This contribution draws upon case studies of emerging self-mobilised social learning processes in the recollection and application of agricultural knowledge as revealed in immigrant gardeners' narratives in New York City, United States and narratives from relocated farming communities in Sebakwe, Zimbabwe. In these narratives the communities draw upon their reserves of local knowledge to respond to changes within their local environments. Such knowledge can serve as a source of community resilience through enabling people to sustain their livelihoods and community wellbeing, and thus adapt to environmental changes and displacement.
- Full Text:
- Authors: Shava, Soul , Zazu, Clayton , Tidball, Keith , O'Donoghue, Rob B
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433052 , vital:72928 , xlink:href="https://hdl.handle.net/10520/EJC61567"
- Description: Local knowledge can serve a source of local community resilience that provides an enabling capacity for people to sustain their livelihoods and adapt to environmental changes or new environments. This knowledge was evidenced as capable of resurfacing when contingent opportunities arise. This contribution draws upon case studies of emerging self-mobilised social learning processes in the recollection and application of agricultural knowledge as revealed in immigrant gardeners' narratives in New York City, United States and narratives from relocated farming communities in Sebakwe, Zimbabwe. In these narratives the communities draw upon their reserves of local knowledge to respond to changes within their local environments. Such knowledge can serve as a source of community resilience through enabling people to sustain their livelihoods and community wellbeing, and thus adapt to environmental changes and displacement.
- Full Text:
Management, Processing and Analysis of Cryptographic Network Protocols
- Cowie, Bradley, Irwin, Barry V W, Barnett, Richard J
- Authors: Cowie, Bradley , Irwin, Barry V W , Barnett, Richard J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428687 , vital:72529 , https://d1wqtxts1xzle7.cloudfront.net/30968790/ISSA2009Proceedings-libre.pdf?1393060231=andresponse-content-disposi-tion=inline%3B+filename%3DAN_ANALYSIS_OF_AUTHENTICATION_FOR_PASSIV.pdfandExpires=1714732172andSignature=Ei8RhR2pCSUNGCNE40DugEyFamcyTxPuuRq9gslD~WGlNqPEgG3FL7VFRQCKXhZBWyAfGRjMtBmNDJ7Sjsgex12WxW9Fj8XdpB7Bfz23FuLc-t2YRM-2joKOHJQLxWJlfZiOzxDvVGZeM3zCHj~f3NUeY1~n6PtVtLzNdL8glIg5dzDTTIE6ms2YlxmnO6JvlzQwOWdHaUbHsZzMGOV19UPtBk-UJzHSq3NRyPe4-XNZQLNK-mEEcMGsLk6nkyXIsW2QJ7gtKW1nNkr6EMkAGSOnDai~pSqzb2imspMnlPRigAPPISrNHO79rP51H9bu1WvbRZv1KVkGvM~sRmfl28A__andKey-Pair-Id=APKAJLOHF5GGSLRBV4ZA#page=499
- Description: The use of cryptographic protocols as a means to provide security to web servers and services at the transport layer, by providing both en-cryption and authentication to data transfer, has become increasingly popular. However, we note that it is rather difficult to perform legitimate analysis, intrusion detection and debugging on cryptographic protocols, as the data that passes through is encrypted. In this paper we assume that we have legitimate access to the data and that we have the private key used in transactions and thus we will be able decrypt the data. The objective is to produce a suitable application framework that allows for easy recovery and secure storage of cryptographic keys; including ap-propriate tools to decapsulate traffic and to decrypt live packet streams or precaptured traffic contained in PCAP files. The resultant processing will then be able to provide a clear-text stream which can be used for further analysis.
- Full Text:
- Authors: Cowie, Bradley , Irwin, Barry V W , Barnett, Richard J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428687 , vital:72529 , https://d1wqtxts1xzle7.cloudfront.net/30968790/ISSA2009Proceedings-libre.pdf?1393060231=andresponse-content-disposi-tion=inline%3B+filename%3DAN_ANALYSIS_OF_AUTHENTICATION_FOR_PASSIV.pdfandExpires=1714732172andSignature=Ei8RhR2pCSUNGCNE40DugEyFamcyTxPuuRq9gslD~WGlNqPEgG3FL7VFRQCKXhZBWyAfGRjMtBmNDJ7Sjsgex12WxW9Fj8XdpB7Bfz23FuLc-t2YRM-2joKOHJQLxWJlfZiOzxDvVGZeM3zCHj~f3NUeY1~n6PtVtLzNdL8glIg5dzDTTIE6ms2YlxmnO6JvlzQwOWdHaUbHsZzMGOV19UPtBk-UJzHSq3NRyPe4-XNZQLNK-mEEcMGsLk6nkyXIsW2QJ7gtKW1nNkr6EMkAGSOnDai~pSqzb2imspMnlPRigAPPISrNHO79rP51H9bu1WvbRZv1KVkGvM~sRmfl28A__andKey-Pair-Id=APKAJLOHF5GGSLRBV4ZA#page=499
- Description: The use of cryptographic protocols as a means to provide security to web servers and services at the transport layer, by providing both en-cryption and authentication to data transfer, has become increasingly popular. However, we note that it is rather difficult to perform legitimate analysis, intrusion detection and debugging on cryptographic protocols, as the data that passes through is encrypted. In this paper we assume that we have legitimate access to the data and that we have the private key used in transactions and thus we will be able decrypt the data. The objective is to produce a suitable application framework that allows for easy recovery and secure storage of cryptographic keys; including ap-propriate tools to decapsulate traffic and to decrypt live packet streams or precaptured traffic contained in PCAP files. The resultant processing will then be able to provide a clear-text stream which can be used for further analysis.
- Full Text:
Meeting democracy’s challenge developments:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
Metal (Co, Fe) tribenzotetraazachlorin–fullerene conjugates
- Ozoemena, Kenneth I, Mamuru, Solomon A, Fukuda, Takamitsu, Kobayashi, Nagao, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
Metallophthalocyanine Based Carbon Paste Electrodes for the Determination of 2′, 3′‐Dideoxyinosine
- Ozoemena, Kenneth I, Stefan-van Staden, Raluca-Ioana, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
Mobile monitors: protecting the will of the people
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Tandlich, Roman, Zuma, Bongumusa M, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
Mulch tower treatment system Part I: Overall performance in greywater treatment
- Zuma, Bongumusa M, Tandlich, Roman, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
Nathaniel Merriman’s lecture: “Shakspeare, as Bearing on English History”
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
NGOs and rural movements in contemporary South Africa
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
- Full Text:
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
- Full Text:
Nine Notes on Lisbon
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229807 , vital:49712 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229807 , vital:49712 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
Of fences and peace between neighbours
- Authors: Krüger, Rósaan
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68909 , vital:29338 , https://hdl.handle.net/10520/EJC85309
- Description: Publisher version , The speaker in the poem "Mending Wall" by American poet Robert Frost questions the wisdom of the saying that "Good Fences Make Good Neighbo[u]rs" (1914 North of Boston lines 27 and 45). The walls or fences referred to in the poem represent more than just physical barriers separating adjacent premises; the speaker sees them as representing obstacles to communication and friendship between individuals. Seen from the perspective of the speaker, a fence or wall is a "bad" thing. But the speaker is but one of the parties to the neighbourly relationship. For the speaker's neighbour, a wall or a fence is "a protector of privacy" (Watson "Frost's Wall : The View from the Other Side" 1971 44 The New England Quarterly 653 655). Thus there are two views on walls or fences: they can be seen negatively as obstructing good relations, or positively as dividers that secure good relations between neighbours by separating them and protecting their privacy rights.
- Full Text: false
- Authors: Krüger, Rósaan
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68909 , vital:29338 , https://hdl.handle.net/10520/EJC85309
- Description: Publisher version , The speaker in the poem "Mending Wall" by American poet Robert Frost questions the wisdom of the saying that "Good Fences Make Good Neighbo[u]rs" (1914 North of Boston lines 27 and 45). The walls or fences referred to in the poem represent more than just physical barriers separating adjacent premises; the speaker sees them as representing obstacles to communication and friendship between individuals. Seen from the perspective of the speaker, a fence or wall is a "bad" thing. But the speaker is but one of the parties to the neighbourly relationship. For the speaker's neighbour, a wall or a fence is "a protector of privacy" (Watson "Frost's Wall : The View from the Other Side" 1971 44 The New England Quarterly 653 655). Thus there are two views on walls or fences: they can be seen negatively as obstructing good relations, or positively as dividers that secure good relations between neighbours by separating them and protecting their privacy rights.
- Full Text: false
On location: Narratives of the South African city of the late 1940s and 1950s in film and literature
- Authors: Baines, Gary F
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125397 , vital:35779 , https://doi.10.1080/02582470308671922
- Description: This article is about narratives, about the forms and meanings constructed by South African storytellers, especially writers and filmmakers. It examines the relationships between examples of these two different narrative forms of literature (fiction and non-fiction) and feature film. Following Turner, the point of departure is that the study of narrative has the potential to provide a framework within which such a two pronged approach can be undertaken. This is not to say that the production of meaning takes place within an exclusive literary or cinematic context. Rather, this approach will allow us to obtain a fuller picture of the narrative of the South African city than is possible by concentrating on one medium. It is based on the premise that narratives are ultimately produced by culture; thus these cultural constructions generate meanings, take on a significance, and assume forms that are articufations of the values, beliefs -the ideology - of the culture.' Literature and film offer specific forms for such narratives. By adopting an interdisciplinary approach which borrows insights from literary and film studies, this article attempts to make a contribution to the fledgling field of South African cultural studies.
- Full Text:
On location: Narratives of the South African city of the late 1940s and 1950s in film and literature
- Authors: Baines, Gary F
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125397 , vital:35779 , https://doi.10.1080/02582470308671922
- Description: This article is about narratives, about the forms and meanings constructed by South African storytellers, especially writers and filmmakers. It examines the relationships between examples of these two different narrative forms of literature (fiction and non-fiction) and feature film. Following Turner, the point of departure is that the study of narrative has the potential to provide a framework within which such a two pronged approach can be undertaken. This is not to say that the production of meaning takes place within an exclusive literary or cinematic context. Rather, this approach will allow us to obtain a fuller picture of the narrative of the South African city than is possible by concentrating on one medium. It is based on the premise that narratives are ultimately produced by culture; thus these cultural constructions generate meanings, take on a significance, and assume forms that are articufations of the values, beliefs -the ideology - of the culture.' Literature and film offer specific forms for such narratives. By adopting an interdisciplinary approach which borrows insights from literary and film studies, this article attempts to make a contribution to the fledgling field of South African cultural studies.
- Full Text:
On Moving House
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229785 , vital:49710 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229785 , vital:49710 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text: