Whither state, private or public service broadcasting? : an analysis of the construction of news on ZBC TV during the 2002 presidential election campaign in Zimbabwe
- Authors: Dlamini, Tula
- Date: 2013-07-16
- Subjects: Zimbabwe Broadcasting Corporation Journalism -- Political aspects -- Zimbabwe Mass media -- Political aspects -- Zimbabwe Political campaigns -- Zimbabwe Elections -- Zimbabwe Television and politics -- Zimbabwe Zimbabwe -- Politics and government -- 1980-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3520 , http://hdl.handle.net/10962/d1008257
- Description: The study sets out to examine the television coverage of the 2002 presidential campaign in Zimbabwe by examining the extent to which the Zimbabwe Broadcasting Corporation fulfilled the mandate of public service broadcasting. The primary objective of this study is to assess how ZBC television newscasts mediated pluralistic politics in the coverage of the country's presidential election campaign, in line with the normative public sphere principles. The thesis comprises seven chapters organized, first, with an introductory chapter, which provides the general background of the study. The chapter offers the rationale for the focus on TV rather than other media fomls . There are two theoretical and contextual chapters in which the use of both qualitative and quantitative methods is explained and findings are presented. Finally, the conclusion offers recommendations about the form broadcasting might take to fulfil a public service mandate and these include the strengthening of the public service broadcasting model along normative public sphere principles. The findings of the analysed election newscasts confirm that ZBC television election news was constructed in favour of ZANU PF at the expense of voices from other social and political constituencies. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Authors: Dlamini, Tula
- Date: 2013-07-16
- Subjects: Zimbabwe Broadcasting Corporation Journalism -- Political aspects -- Zimbabwe Mass media -- Political aspects -- Zimbabwe Political campaigns -- Zimbabwe Elections -- Zimbabwe Television and politics -- Zimbabwe Zimbabwe -- Politics and government -- 1980-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3520 , http://hdl.handle.net/10962/d1008257
- Description: The study sets out to examine the television coverage of the 2002 presidential campaign in Zimbabwe by examining the extent to which the Zimbabwe Broadcasting Corporation fulfilled the mandate of public service broadcasting. The primary objective of this study is to assess how ZBC television newscasts mediated pluralistic politics in the coverage of the country's presidential election campaign, in line with the normative public sphere principles. The thesis comprises seven chapters organized, first, with an introductory chapter, which provides the general background of the study. The chapter offers the rationale for the focus on TV rather than other media fomls . There are two theoretical and contextual chapters in which the use of both qualitative and quantitative methods is explained and findings are presented. Finally, the conclusion offers recommendations about the form broadcasting might take to fulfil a public service mandate and these include the strengthening of the public service broadcasting model along normative public sphere principles. The findings of the analysed election newscasts confirm that ZBC television election news was constructed in favour of ZANU PF at the expense of voices from other social and political constituencies. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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A psychoanalytic hermeneutic investigation of destructive narcissism
- Authors: De Wit, Estelle
- Date: 2013-06-04 , 2004
- Subjects: Narcissism Narcissism -- Treatment Psychoanalysis Death instinct Ego (Psychology) Self psychology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3180 , http://hdl.handle.net/10962/d1008055
- Description: The purpose of this research was to investigate the clinical phenomenon of destructive narcissism. Contemporary Kleinian and neo-Kleinian theoretical perspectives provided the interpretative perspective on the complexities of inaccessible personalities and subtle forms of internal destructiveness. Four research questions were formulated to interrogate the individual and collective experiences of three male patients whose internal worlds seem to be governed by rigid intrapychic structures organized around the dictatorship of a constellation of seemingly impenetrable defensive strategies. These questions were as follows: 1. What emotional states, actions and experiences of self and others characterize the clinical phenomenon designed as destructive narcissism and distinguish it from other forms of character pathology? 2. What early developmental experiences and relationships may have pre-disposed individuals to the development of this type of character pathology? 3. How are the psychodynamic processes of destructive narcissism structured and configured in the psychotherapeutic process and progress? 4. What are the transference/countertransference psychotherapeutic manifestations of the psychodynamics of destructive narcissism? The illustrative-didactic case study method was utilized to discuss pertinent aspects of each patient. This included their early developmental histories, inter- and intrapersonal relationships, their current mental state, defensive strategies and their stated reasons for commencing psychotherapy. In addition, the structure of the psychotherapeutic process with these patients was reviewed in depth. Various psychic and personality features, as unveiled through this process were discussed, as well as the implications of these for the therapeutic endeavor. The features chosen for discussion were: Firstly, the constellation of the internal object world, the capacity for symbolic thought and defensive organizations. Secondly, therapeutic ambivalence, which made psychotherapy untenable, was explored in conjunction with transference/countertransference issues. Thirdly, the shadow sides of psychotherapeutic change with these patients were considered and the issues of therapeutic failure and other treatment possibilities were examined. It was concluded that there need be an important shift with regard to the psychotherapeutic goals for those patients whose condition may be chronic, and for whom it appears that psychotherapy is of little benefit. In essence, the intent of psychotherapy with these patients is to reach the healthy sane patient of the patient within the pathological organization. Attempts to unravel the perverse gratification and protection derived from the domination of the narcissistic structure may not be enough, and the patient's collusion with the internal destructive gang should also be exposed. If this can be achieved, the patient may come to accept the existence of a part of himself as truly destructive. This, in turn, cannot be disowned, therefore the patient has to live with it. Thus, in destructive narcissism, the challenge for the therapist is the extremely difficult task of disentangling the patient's pain from the idealization of internal destructiveness. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Authors: De Wit, Estelle
- Date: 2013-06-04 , 2004
- Subjects: Narcissism Narcissism -- Treatment Psychoanalysis Death instinct Ego (Psychology) Self psychology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3180 , http://hdl.handle.net/10962/d1008055
- Description: The purpose of this research was to investigate the clinical phenomenon of destructive narcissism. Contemporary Kleinian and neo-Kleinian theoretical perspectives provided the interpretative perspective on the complexities of inaccessible personalities and subtle forms of internal destructiveness. Four research questions were formulated to interrogate the individual and collective experiences of three male patients whose internal worlds seem to be governed by rigid intrapychic structures organized around the dictatorship of a constellation of seemingly impenetrable defensive strategies. These questions were as follows: 1. What emotional states, actions and experiences of self and others characterize the clinical phenomenon designed as destructive narcissism and distinguish it from other forms of character pathology? 2. What early developmental experiences and relationships may have pre-disposed individuals to the development of this type of character pathology? 3. How are the psychodynamic processes of destructive narcissism structured and configured in the psychotherapeutic process and progress? 4. What are the transference/countertransference psychotherapeutic manifestations of the psychodynamics of destructive narcissism? The illustrative-didactic case study method was utilized to discuss pertinent aspects of each patient. This included their early developmental histories, inter- and intrapersonal relationships, their current mental state, defensive strategies and their stated reasons for commencing psychotherapy. In addition, the structure of the psychotherapeutic process with these patients was reviewed in depth. Various psychic and personality features, as unveiled through this process were discussed, as well as the implications of these for the therapeutic endeavor. The features chosen for discussion were: Firstly, the constellation of the internal object world, the capacity for symbolic thought and defensive organizations. Secondly, therapeutic ambivalence, which made psychotherapy untenable, was explored in conjunction with transference/countertransference issues. Thirdly, the shadow sides of psychotherapeutic change with these patients were considered and the issues of therapeutic failure and other treatment possibilities were examined. It was concluded that there need be an important shift with regard to the psychotherapeutic goals for those patients whose condition may be chronic, and for whom it appears that psychotherapy is of little benefit. In essence, the intent of psychotherapy with these patients is to reach the healthy sane patient of the patient within the pathological organization. Attempts to unravel the perverse gratification and protection derived from the domination of the narcissistic structure may not be enough, and the patient's collusion with the internal destructive gang should also be exposed. If this can be achieved, the patient may come to accept the existence of a part of himself as truly destructive. This, in turn, cannot be disowned, therefore the patient has to live with it. Thus, in destructive narcissism, the challenge for the therapist is the extremely difficult task of disentangling the patient's pain from the idealization of internal destructiveness. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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Getting "layed" : new professional positions in South African psychology
- Authors: Henderson, Jill
- Date: 2013-06-04
- Subjects: Psychology -- Study and teaching -- South Africa Psychologists -- Training of -- South Africa Psychologists -- Selection and appointment -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3179 , http://hdl.handle.net/10962/d1007953
- Description: KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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- Authors: Henderson, Jill
- Date: 2013-06-04
- Subjects: Psychology -- Study and teaching -- South Africa Psychologists -- Training of -- South Africa Psychologists -- Selection and appointment -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3179 , http://hdl.handle.net/10962/d1007953
- Description: KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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Employees' experience of job satisfaction within a successful organisation
- Authors: Milne, Claire
- Date: 2013-06-03
- Subjects: Employee motivation Job satisfaction Employees -- Rating of Performance standards Management -- Employee participation Organizational effectiveness Organizational behavior Employees -- Psychology Wages -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3159 , http://hdl.handle.net/10962/d1007639
- Description: In the present organisational climate characterised by intense competition, the success of an organisation is increasingly dependent on its employees' expertise and knowledge (Carrel, Elbert, Hatfield, Grobler, Marx & Van der Schyf, 1997). Employees need to be motivated to contribute to the organisation's goals, for their knowledge and expertise to benefit an organisation (Lawler III, 1994). Organisations need to foster a situation in which employees have a positive attitude towards work and are able to benefit personally through directing their effort towards organisational goals. (Robbins, 2000) This study focuses on an organisation that has managed to link job satisfaction with organisational gain, and explores the link between these two subjects. A case study of a South African mining operation is reported on, and examined in-depth. The mine, a successful operation in terms of productivity, is recognised by its holding company as exemplary and is competing with the best base metal producers in the world. The research was conducted in two stages. The first stage consisted of 20 semi-structured individual interviews. Ten employees were selected from both the lower employee-levels and the higher employee-levels. The individual interviews focused on the experience of working at the mine with particular reference to interpersonal dynamics, job satisfaction, leadership style, and reward systems. During the second stage of the research, focus groups were conducted with two groups of seven employees each, one group from the lower-levels and one from the higher-levels. The focus groups aimed at obtaining a deeper understanding of the issues that emerged from the individual interviews. Grounded theory analysis was used during both the first, and second phase of the study. The results indicated that the mine's employees experience a high level fulfilment of higher-order needs, and that this experience is a reaction to the mine's performance enhancing culture. It is further shown that the same factors that create job satisfaction, when applied in excess, or in certain circumstances may lead to dissatisfaction within the same context.
- Full Text:
- Authors: Milne, Claire
- Date: 2013-06-03
- Subjects: Employee motivation Job satisfaction Employees -- Rating of Performance standards Management -- Employee participation Organizational effectiveness Organizational behavior Employees -- Psychology Wages -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3159 , http://hdl.handle.net/10962/d1007639
- Description: In the present organisational climate characterised by intense competition, the success of an organisation is increasingly dependent on its employees' expertise and knowledge (Carrel, Elbert, Hatfield, Grobler, Marx & Van der Schyf, 1997). Employees need to be motivated to contribute to the organisation's goals, for their knowledge and expertise to benefit an organisation (Lawler III, 1994). Organisations need to foster a situation in which employees have a positive attitude towards work and are able to benefit personally through directing their effort towards organisational goals. (Robbins, 2000) This study focuses on an organisation that has managed to link job satisfaction with organisational gain, and explores the link between these two subjects. A case study of a South African mining operation is reported on, and examined in-depth. The mine, a successful operation in terms of productivity, is recognised by its holding company as exemplary and is competing with the best base metal producers in the world. The research was conducted in two stages. The first stage consisted of 20 semi-structured individual interviews. Ten employees were selected from both the lower employee-levels and the higher employee-levels. The individual interviews focused on the experience of working at the mine with particular reference to interpersonal dynamics, job satisfaction, leadership style, and reward systems. During the second stage of the research, focus groups were conducted with two groups of seven employees each, one group from the lower-levels and one from the higher-levels. The focus groups aimed at obtaining a deeper understanding of the issues that emerged from the individual interviews. Grounded theory analysis was used during both the first, and second phase of the study. The results indicated that the mine's employees experience a high level fulfilment of higher-order needs, and that this experience is a reaction to the mine's performance enhancing culture. It is further shown that the same factors that create job satisfaction, when applied in excess, or in certain circumstances may lead to dissatisfaction within the same context.
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Acquiring academic reading practices in History I : an ethnographic study of a group of foundation year students at Rhodes University
- Authors: Niven, Penelope Mary
- Date: 2013-05-29
- Subjects: Compensatory education -- South Africa English language -- Study and teaching (Higher) -- Foreign speakers History -- Study and teaching (Higher) -- Foreign speakers College students, Black -- South Africa Black people -- Education (Higher) -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2380 , http://hdl.handle.net/10962/d1007860
- Description: This thesis reports on a critical, ethnographic investigation into the reading practices of a group of 14 foundation year students at Rhodes University in 2002. The university had identified all the student-participants as 'underprepared' for university learning: they were from poor, socio-economic backgrounds, used English as an additional language, and had been educated in township or rural schools. Using the Socio-cultural model of literacy (Heath, 1984; Gee, 1990 & Street, 1993), the study explores the culturally-shaped attitudes and assumptions about reading that the students brought with them into a tertiary learning context from their homes, communities and schools. It reports on their subsequent efforts to become academic readers in the disciplinary context of History. Framing Theory (Reid and MacLachlan, 1994) was employed to analyse the kinds of matches and mismatches that arose between the students' frames about the nature and purpose of reading, and those implicitly accepted as normative by teachers in the History department. It accounts for the students' difficulties in achieving epistemological access in terms of a conflict of frames: both the students and their teachers usually failed to recognise each others' constructions about the nature and purpose of 'reading for a degree'. The study'S critical purpose required that its potential for generating emancipatory consequences needed to be investigated. Thus the study reports on how both sets of participants began to reframe their understanding of academic reading, by describing the ways in which they reflected on the findings in the final stages of the research process. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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- Authors: Niven, Penelope Mary
- Date: 2013-05-29
- Subjects: Compensatory education -- South Africa English language -- Study and teaching (Higher) -- Foreign speakers History -- Study and teaching (Higher) -- Foreign speakers College students, Black -- South Africa Black people -- Education (Higher) -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2380 , http://hdl.handle.net/10962/d1007860
- Description: This thesis reports on a critical, ethnographic investigation into the reading practices of a group of 14 foundation year students at Rhodes University in 2002. The university had identified all the student-participants as 'underprepared' for university learning: they were from poor, socio-economic backgrounds, used English as an additional language, and had been educated in township or rural schools. Using the Socio-cultural model of literacy (Heath, 1984; Gee, 1990 & Street, 1993), the study explores the culturally-shaped attitudes and assumptions about reading that the students brought with them into a tertiary learning context from their homes, communities and schools. It reports on their subsequent efforts to become academic readers in the disciplinary context of History. Framing Theory (Reid and MacLachlan, 1994) was employed to analyse the kinds of matches and mismatches that arose between the students' frames about the nature and purpose of reading, and those implicitly accepted as normative by teachers in the History department. It accounts for the students' difficulties in achieving epistemological access in terms of a conflict of frames: both the students and their teachers usually failed to recognise each others' constructions about the nature and purpose of 'reading for a degree'. The study'S critical purpose required that its potential for generating emancipatory consequences needed to be investigated. Thus the study reports on how both sets of participants began to reframe their understanding of academic reading, by describing the ways in which they reflected on the findings in the final stages of the research process. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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The hydrogeomorphology of the Featherstone Kloof Catchment
- Authors: Ntakumba, Stanley Sixolile
- Date: 2013-05-29
- Subjects: Wetlands -- South Africa , Wetland restoration -- South Africa -- Featherstone Kloof Catchment , Wetland conservation -- South Africa -- Featherstone Kloof Catchment , Wetland management -- South Africa -- Featherstone Kloof Catchment , Wetland ecology -- South Africa -- Featherstone Kloof Catchment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4870 , http://hdl.handle.net/10962/d1007862 , Wetlands -- South Africa , Wetland restoration -- South Africa -- Featherstone Kloof Catchment , Wetland conservation -- South Africa -- Featherstone Kloof Catchment , Wetland management -- South Africa -- Featherstone Kloof Catchment , Wetland ecology -- South Africa -- Featherstone Kloof Catchment
- Description: Wetlands are an important part of the landscape as hydrogeomorphological ecosystems. Over the centuries their importance has not received relevant attention; instead they have been treated as wastelands impeding development for maximum economic benefits. Research evidence from different parts of the world has influenced the change of such negative perceptions to an extent that the issue of wetlands' rehabilitation/restoration, conservation and management is firmly on the global agenda and local agendas of various countries, as evidenced by the adoption of the Ramsar Convention in 1971, and the Working for Water and Working for Wetlands programmes of the South African government. The aim of this research was to investigate the hydrological and geomorphological functions of a headwater wetland located in the Featherstone Kloof Catchment near Grahamstown, South Africa. The research was based on the hypotheses that wetlands store sediments, attenuate floods, store water and prolong downstream flows. A literature survey was conducted to gauge the state of knowledge about wetlands, particularly their hydrogeomorphology. An attempt was made to locate the study area within the broad historical and spatial context using a number of methods, including the radiocarbon dating of wetland sediments, the review of relevant literature and the analysis of historical hydroclimatic data. The results revealed that the wetland has existed for approximately 2000 years - as the oldest radiocarbon date obtained was 1850±50 BP. An analysis of more than a century (+120 years) long Grahamstown rainfall series indicated a steady fluctuation of rainfall around the mean, with regular decada1 cycles of wet and dry spells. Years with more rain below average were more common than those with higher rainfall, and storms events were quite common in the III area over the period. The distribution of seasons in the area over a calendar year period was demonstrated through the use of evaporation data. An intensive monitoring of hydrological and geomorphological variables was carried out using a combination of methods. The topography of the instrumented site was determined using a Total Station from reference benchmarks. Hydrological measurements included a nest of forty-eight piezometers for water table monitoring, and streamflow gauges at the upstream and downstream limits of the study site. Soil stratigraphic analysis was carried out through field techniques and laboratory measurements. A survey of wetland sediments was carried out after the main floods events. Data generated were used to analyse relationships between various variables and their role on the functioning of the wetland. The water balance of the wetland was quantified. The results indicated that the wetland was able to perform the cited hydrogeomorphological functions to some extent. For example, one of the key findings of this research is that the wetland was important in sustaining base flows under normal circumstances. However, the wetland did little to attenuate large floods. The results also revealed some important questions that require further research, including the role played by extreme flood events in altering wetland characteristics, the contribution of each water balance component in the hydrological functioning of wetlands, and importance of quantifying sediment budgets of headwater wetlands. The study demonstrated the complex nature of the wetland hydro geomorphology and that certain questions about wetlands require direct field monitoring to be better understood. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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- Authors: Ntakumba, Stanley Sixolile
- Date: 2013-05-29
- Subjects: Wetlands -- South Africa , Wetland restoration -- South Africa -- Featherstone Kloof Catchment , Wetland conservation -- South Africa -- Featherstone Kloof Catchment , Wetland management -- South Africa -- Featherstone Kloof Catchment , Wetland ecology -- South Africa -- Featherstone Kloof Catchment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4870 , http://hdl.handle.net/10962/d1007862 , Wetlands -- South Africa , Wetland restoration -- South Africa -- Featherstone Kloof Catchment , Wetland conservation -- South Africa -- Featherstone Kloof Catchment , Wetland management -- South Africa -- Featherstone Kloof Catchment , Wetland ecology -- South Africa -- Featherstone Kloof Catchment
- Description: Wetlands are an important part of the landscape as hydrogeomorphological ecosystems. Over the centuries their importance has not received relevant attention; instead they have been treated as wastelands impeding development for maximum economic benefits. Research evidence from different parts of the world has influenced the change of such negative perceptions to an extent that the issue of wetlands' rehabilitation/restoration, conservation and management is firmly on the global agenda and local agendas of various countries, as evidenced by the adoption of the Ramsar Convention in 1971, and the Working for Water and Working for Wetlands programmes of the South African government. The aim of this research was to investigate the hydrological and geomorphological functions of a headwater wetland located in the Featherstone Kloof Catchment near Grahamstown, South Africa. The research was based on the hypotheses that wetlands store sediments, attenuate floods, store water and prolong downstream flows. A literature survey was conducted to gauge the state of knowledge about wetlands, particularly their hydrogeomorphology. An attempt was made to locate the study area within the broad historical and spatial context using a number of methods, including the radiocarbon dating of wetland sediments, the review of relevant literature and the analysis of historical hydroclimatic data. The results revealed that the wetland has existed for approximately 2000 years - as the oldest radiocarbon date obtained was 1850±50 BP. An analysis of more than a century (+120 years) long Grahamstown rainfall series indicated a steady fluctuation of rainfall around the mean, with regular decada1 cycles of wet and dry spells. Years with more rain below average were more common than those with higher rainfall, and storms events were quite common in the III area over the period. The distribution of seasons in the area over a calendar year period was demonstrated through the use of evaporation data. An intensive monitoring of hydrological and geomorphological variables was carried out using a combination of methods. The topography of the instrumented site was determined using a Total Station from reference benchmarks. Hydrological measurements included a nest of forty-eight piezometers for water table monitoring, and streamflow gauges at the upstream and downstream limits of the study site. Soil stratigraphic analysis was carried out through field techniques and laboratory measurements. A survey of wetland sediments was carried out after the main floods events. Data generated were used to analyse relationships between various variables and their role on the functioning of the wetland. The water balance of the wetland was quantified. The results indicated that the wetland was able to perform the cited hydrogeomorphological functions to some extent. For example, one of the key findings of this research is that the wetland was important in sustaining base flows under normal circumstances. However, the wetland did little to attenuate large floods. The results also revealed some important questions that require further research, including the role played by extreme flood events in altering wetland characteristics, the contribution of each water balance component in the hydrological functioning of wetlands, and importance of quantifying sediment budgets of headwater wetlands. The study demonstrated the complex nature of the wetland hydro geomorphology and that certain questions about wetlands require direct field monitoring to be better understood. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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Synthesis and evaluation of PGM-selective ligands
- Gxoyiya, Babalwa Siliziwe Blossom
- Authors: Gxoyiya, Babalwa Siliziwe Blossom
- Date: 2013-05-28
- Subjects: Platinum group , Ligands , Ligands -- Evaluation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4450 , http://hdl.handle.net/10962/d1007849 , Platinum group , Ligands , Ligands -- Evaluation
- Description: A series of polydentate POM-selective, sulfur-containing amide ligands have been synthesized from ro-dibromoalkanes and mercaptoacetanilide, The resulting 3,6- dithiaoctanediamides and 3,7-dithianonanediamides, some of which contain a polymerisable group, were all characterized by high-resolution MS, IR, I Hand I3C NMR spectroscopic methods. Various approaches to the polymerisable ligands were explored, the most efficient proving to be the incorporation of an allyl ether moiety in the mercaptoacetanilide. The corresponding Pd(U) and Pt(II) complexes were also prepared from the metal chloride salts and characterized by elemental analysis and spectroscopic methods. The NMR data indicates that both the cis- and transcomplexes were formed, while the IR data indicates cis- coordination of the chlorine . ligands. Molecularly imprinted polymers (MIP's), prepared using platinum(II) mercaptoacetanilide and 3,6-dithiadiamide complexes, showed high selectivity for , , palladium(II) [in the presence of Pt(II), CoCII), Cu(II) and Ni(II)] as determined by . ICP-MS analysis. The more kinetically inert Pt(II) ions however, slowly displaced Pd(II), confirming the Pt(II) selectivity of the MIP's. Solvent extraction studies were conducted to explore the selectivity of the 3,6- dithiaoctanediamides and 3,7-dithianonanediamides for Pd(U) over CoCII), Cu(U) and Ni(II). The ICP-MS data indicate that, in general, equilibration was achieved within ten minutes and that the longer-chain amides were less selective than the shorter-chain analogues. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Authors: Gxoyiya, Babalwa Siliziwe Blossom
- Date: 2013-05-28
- Subjects: Platinum group , Ligands , Ligands -- Evaluation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4450 , http://hdl.handle.net/10962/d1007849 , Platinum group , Ligands , Ligands -- Evaluation
- Description: A series of polydentate POM-selective, sulfur-containing amide ligands have been synthesized from ro-dibromoalkanes and mercaptoacetanilide, The resulting 3,6- dithiaoctanediamides and 3,7-dithianonanediamides, some of which contain a polymerisable group, were all characterized by high-resolution MS, IR, I Hand I3C NMR spectroscopic methods. Various approaches to the polymerisable ligands were explored, the most efficient proving to be the incorporation of an allyl ether moiety in the mercaptoacetanilide. The corresponding Pd(U) and Pt(II) complexes were also prepared from the metal chloride salts and characterized by elemental analysis and spectroscopic methods. The NMR data indicates that both the cis- and transcomplexes were formed, while the IR data indicates cis- coordination of the chlorine . ligands. Molecularly imprinted polymers (MIP's), prepared using platinum(II) mercaptoacetanilide and 3,6-dithiadiamide complexes, showed high selectivity for , , palladium(II) [in the presence of Pt(II), CoCII), Cu(II) and Ni(II)] as determined by . ICP-MS analysis. The more kinetically inert Pt(II) ions however, slowly displaced Pd(II), confirming the Pt(II) selectivity of the MIP's. Solvent extraction studies were conducted to explore the selectivity of the 3,6- dithiaoctanediamides and 3,7-dithianonanediamides for Pd(U) over CoCII), Cu(U) and Ni(II). The ICP-MS data indicate that, in general, equilibration was achieved within ten minutes and that the longer-chain amides were less selective than the shorter-chain analogues. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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A histological description of ovarian recrudescence in two Labeo victorianus populations
- Booth, Anthony J, Hecht, Thomas
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123564 , vital:35455 , https://doi.org/10.2989/16085910409503813
- Description: The ovaries of Labeo victorianus are paired organs situated in the peritoneal cavity and suspended on either side of the midline by a mesovarium. A capsule, composed of dense, regularly-arranged collagen and elastic fibres mixed with a few smooth muscle cells, enclosed the ovaries and gave off connective tissue septa, forming the ovigerous lamellae, which contained germ and follicle cells. Eight discrete stages of recrudescence were identified: oogonia, chromatin nucleolar oocytes, perinucleolar oocytes, primary yolk vesicle oocytes, secondary yolk vesicle oocytes, tertiary yolk vesicle oocytes, post-ovulatory follicles and atretic oocytes. Ovulation seemed to be synchronised with the onset of rainfall, with some deviations in the Sio River population. Gonadosomatic index variation followed a bimodal pattern, with maxima between January–February and between September–October for both populations. The same pattern was exhibited for both rainfall and water levels at the two study sites. Successful ovulation was followed by the formation of post-ovulatory follicles and Type I atresia, while failed spawning was characterised by Type II atresia. Clearance of post-ovulatory follicles was by phagocytosis and formation of melanomacrophage centres. There were variations in post-ovulatory changes between the two populations. Reproductive patterns in the Kagera River population conformed to the ‘norm’ in African labeines of the synchronisation of spawning with rainfall. Slight deviations from this pattern were, however, observed in the Sio River population where spawning occurred prior to the onset of rainfall.
- Full Text:
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123564 , vital:35455 , https://doi.org/10.2989/16085910409503813
- Description: The ovaries of Labeo victorianus are paired organs situated in the peritoneal cavity and suspended on either side of the midline by a mesovarium. A capsule, composed of dense, regularly-arranged collagen and elastic fibres mixed with a few smooth muscle cells, enclosed the ovaries and gave off connective tissue septa, forming the ovigerous lamellae, which contained germ and follicle cells. Eight discrete stages of recrudescence were identified: oogonia, chromatin nucleolar oocytes, perinucleolar oocytes, primary yolk vesicle oocytes, secondary yolk vesicle oocytes, tertiary yolk vesicle oocytes, post-ovulatory follicles and atretic oocytes. Ovulation seemed to be synchronised with the onset of rainfall, with some deviations in the Sio River population. Gonadosomatic index variation followed a bimodal pattern, with maxima between January–February and between September–October for both populations. The same pattern was exhibited for both rainfall and water levels at the two study sites. Successful ovulation was followed by the formation of post-ovulatory follicles and Type I atresia, while failed spawning was characterised by Type II atresia. Clearance of post-ovulatory follicles was by phagocytosis and formation of melanomacrophage centres. There were variations in post-ovulatory changes between the two populations. Reproductive patterns in the Kagera River population conformed to the ‘norm’ in African labeines of the synchronisation of spawning with rainfall. Slight deviations from this pattern were, however, observed in the Sio River population where spawning occurred prior to the onset of rainfall.
- Full Text:
An assessment of a light-attraction fishery in southern Lake Malawi
- Weyl, Olaf L F, Kazembe, Jacqueline, Booth, Anthony J, Mandere, D S
- Authors: Weyl, Olaf L F , Kazembe, Jacqueline , Booth, Anthony J , Mandere, D S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123683 , vital:35472 , https://doi.org/10.2989/16085910409503787
- Description: This study provides the first quantitative assessment of the light-attraction component of a small-scale purse seine, locally known as a chilimira net, fishery in two areas of southern Lake Malawi. For monitoring purposes the shoreline of Lake Malawi is divided into a number of statistical strata. Two strata (‘2.1’ in the southeast arm and ‘3.1’ in the southwest arm of the lake) were selected for this study. Catch per unit effort in stratum 2.1 was generally lower than that recorded in stratum 3.1 but nets in stratum 2.1 fished more frequently, leading to similar annual catches in the two strata. Annual catch was estimated as 19.4 (CI = 15.9–23.5) tons net–1 year–1 in stratum 2.1 and 23.5 (CI = 19.5–28.1) tons net–1 year–1 in stratum 3.1 respectively. A total of 62 species from 28 cichlid genera, and 13 species from nine non-cichlid genera, were identified from the samples. Of the 37 genera identified, only five; Copadichromis, Dimidiochromis, Engraulicypris, Oreochromis and Rhamphochromis, contributed more than 5% to the total annual catch in either stratum. Their combined contribution to the annual catch was in excess of 85% in both strata. Comparisons showed that catch-composition was dependent on area. Length-frequency distributions of major target species in the catch showed that the fishery targeted juveniles in stratum 2.1, while in stratum 3.1 most individuals were harvested after reaching their lengthat-maturity. The dependence of catch-composition and size-selection on area indicates that management interventions for this fishery need to be area-specific. Since the fishery targets a diverse species assemblage, effort limitation or area closure may be the only viable management options, until such time as additional biological and fisheries data are available for the application of stock assessment models.
- Full Text:
- Authors: Weyl, Olaf L F , Kazembe, Jacqueline , Booth, Anthony J , Mandere, D S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123683 , vital:35472 , https://doi.org/10.2989/16085910409503787
- Description: This study provides the first quantitative assessment of the light-attraction component of a small-scale purse seine, locally known as a chilimira net, fishery in two areas of southern Lake Malawi. For monitoring purposes the shoreline of Lake Malawi is divided into a number of statistical strata. Two strata (‘2.1’ in the southeast arm and ‘3.1’ in the southwest arm of the lake) were selected for this study. Catch per unit effort in stratum 2.1 was generally lower than that recorded in stratum 3.1 but nets in stratum 2.1 fished more frequently, leading to similar annual catches in the two strata. Annual catch was estimated as 19.4 (CI = 15.9–23.5) tons net–1 year–1 in stratum 2.1 and 23.5 (CI = 19.5–28.1) tons net–1 year–1 in stratum 3.1 respectively. A total of 62 species from 28 cichlid genera, and 13 species from nine non-cichlid genera, were identified from the samples. Of the 37 genera identified, only five; Copadichromis, Dimidiochromis, Engraulicypris, Oreochromis and Rhamphochromis, contributed more than 5% to the total annual catch in either stratum. Their combined contribution to the annual catch was in excess of 85% in both strata. Comparisons showed that catch-composition was dependent on area. Length-frequency distributions of major target species in the catch showed that the fishery targeted juveniles in stratum 2.1, while in stratum 3.1 most individuals were harvested after reaching their lengthat-maturity. The dependence of catch-composition and size-selection on area indicates that management interventions for this fishery need to be area-specific. Since the fishery targets a diverse species assemblage, effort limitation or area closure may be the only viable management options, until such time as additional biological and fisheries data are available for the application of stock assessment models.
- Full Text:
More media for Southern Africa?: the place of politics, economics and convergence in developing media density
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147825 , vital:38676 , https://0-doi.org.wam.seals.ac.za/10.1080/02560240485310041
- Description: In line with global trends, media in Southern Africa in the past decade has been moving slowly towards mergers, partnerships and multi-platform publishing. Driven by politics and facilitated by technology, the process has had to confront the difficulty of establishing viable economic models, the lack of regional integration within Southern African countries, and what is sometimes a difficult political environment. Markets remain largely national or local and economically weak. Print media faces huge hurdles. Broadcast media density is improving, partly through noncommercial mechanisms. News websites are understaffed, lacking in viable survival strategies and skills, and are incompletely integrated with parent media platforms. Economic pressures, however, are likely to force Southern African media operations into greater synergies in search of survival. The various convergences entailed may increase media density.
- Full Text:
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147825 , vital:38676 , https://0-doi.org.wam.seals.ac.za/10.1080/02560240485310041
- Description: In line with global trends, media in Southern Africa in the past decade has been moving slowly towards mergers, partnerships and multi-platform publishing. Driven by politics and facilitated by technology, the process has had to confront the difficulty of establishing viable economic models, the lack of regional integration within Southern African countries, and what is sometimes a difficult political environment. Markets remain largely national or local and economically weak. Print media faces huge hurdles. Broadcast media density is improving, partly through noncommercial mechanisms. News websites are understaffed, lacking in viable survival strategies and skills, and are incompletely integrated with parent media platforms. Economic pressures, however, are likely to force Southern African media operations into greater synergies in search of survival. The various convergences entailed may increase media density.
- Full Text:
Transforming the media: a cultural approach
- Authors: Steenveld, Lynette N
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147891 , vital:38682 , DOI: 10.1080/02560240485310061
- Description: The change from an Apartheid state to a liberal democratic one has wrought many changes at all levels of South African society: the economic, social, political, cultural. This paper explores the impacts of these changes on the South African print media industry, with a view to assessing their contribution to the development of a democratic citizenship. While acknowledging the constraining effects of economic structures of ownership, the paper locates these within the broader social and political context of post-apartheid South Africa. It thus attempts to synthesise elements of both a political economy and cultural approach to the analysis of cultural production.
- Full Text:
- Authors: Steenveld, Lynette N
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147891 , vital:38682 , DOI: 10.1080/02560240485310061
- Description: The change from an Apartheid state to a liberal democratic one has wrought many changes at all levels of South African society: the economic, social, political, cultural. This paper explores the impacts of these changes on the South African print media industry, with a view to assessing their contribution to the development of a democratic citizenship. While acknowledging the constraining effects of economic structures of ownership, the paper locates these within the broader social and political context of post-apartheid South Africa. It thus attempts to synthesise elements of both a political economy and cultural approach to the analysis of cultural production.
- Full Text:
"It was a brilliant time" : an investigation into the experiences of the founder group of the Directorate of Special Operations
- Geyer-van Rensburg, Karen Helen
- Authors: Geyer-van Rensburg, Karen Helen
- Date: 2004
- Subjects: National Prosecuting Authority of South Africa. Directorate of Special Operations Crime -- South Africa Crime -- Prevention -- South Africa Criminal Justice, Administration of -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:815 , http://hdl.handle.net/10962/d1007919
- Description: The President, Thabo Mbeki, established the Directorate of Special Operations (DSO) in 1999 shortly after the general elections. The DSO was intended to supplement the efforts of the South African Police Services in combating crime. The unit would concentrate on national priority crimes and police corruption and would report to the National Director of Public Prosecutions (NDPP). The founder members of the DSO were identified in my research and open-ended interviews were conducted with them. The goal of my research was to understand the founder group's experience of the creation of the organisational culture of the DSO and what that experience meant to them . In particular, I wanted to establish what role the founder members of the DSO believed their values and beliefs played in creating the organisation's culture, and their perception of how those values influenced the leadership, management and organisation processes of the DSO. The public sector environment seldom offers opportunities to create something new and this was a unique experience. The founder members received no personal gain except the satisfaction of creating something that would be there for their descendants, something that would change the face of law enforcement forever and in fact, pioneer the troika methodology for the first time in the world within a permanent structure. The values of the founder members influenced their decision to join and they believed that the DSO would make a difference in the lives of ordinary South Africans. They were dedicated, committed, loyal and passionate. Their leadership inspired the members of the organisation and ensured the success of the DSO, despite the lack of resources, staff and legislation. This was an exciting time in the history of the organisation and many personal sacrifices were made. The founder members are proud of the achievements of the DSO and of having been a part thereof. It certainly was "a brilliant time".
- Full Text:
- Authors: Geyer-van Rensburg, Karen Helen
- Date: 2004
- Subjects: National Prosecuting Authority of South Africa. Directorate of Special Operations Crime -- South Africa Crime -- Prevention -- South Africa Criminal Justice, Administration of -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:815 , http://hdl.handle.net/10962/d1007919
- Description: The President, Thabo Mbeki, established the Directorate of Special Operations (DSO) in 1999 shortly after the general elections. The DSO was intended to supplement the efforts of the South African Police Services in combating crime. The unit would concentrate on national priority crimes and police corruption and would report to the National Director of Public Prosecutions (NDPP). The founder members of the DSO were identified in my research and open-ended interviews were conducted with them. The goal of my research was to understand the founder group's experience of the creation of the organisational culture of the DSO and what that experience meant to them . In particular, I wanted to establish what role the founder members of the DSO believed their values and beliefs played in creating the organisation's culture, and their perception of how those values influenced the leadership, management and organisation processes of the DSO. The public sector environment seldom offers opportunities to create something new and this was a unique experience. The founder members received no personal gain except the satisfaction of creating something that would be there for their descendants, something that would change the face of law enforcement forever and in fact, pioneer the troika methodology for the first time in the world within a permanent structure. The values of the founder members influenced their decision to join and they believed that the DSO would make a difference in the lives of ordinary South Africans. They were dedicated, committed, loyal and passionate. Their leadership inspired the members of the organisation and ensured the success of the DSO, despite the lack of resources, staff and legislation. This was an exciting time in the history of the organisation and many personal sacrifices were made. The founder members are proud of the achievements of the DSO and of having been a part thereof. It certainly was "a brilliant time".
- Full Text:
"My novel, Hill of Fools"
- Peteni, R L, Wright, Laurence
- Authors: Peteni, R L , Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7038 , http://hdl.handle.net/10962/d1007376 , http://hdl.handle.net/10520/EJC47869
- Description: preprint , R.L. Peteni - 'There is a tendency in human beings to pay no heed to events in small remote areas. They would rather concern themselves only with those events which make headlines, with political upheavals and industrial conflicts centred in large metropolitan regions. Yet there is always drama and human conflict in the humblest rural village. In selecting a pastoral theme and small fictitious villages in an obscure corner of Keiskammahoek as the setting of the novel, I had an ironic intention. Themes illustrated in these obscure villages would, I believed, have more universal application than they would if I had selected a larger centre, identifiable personages and known political trends. I did not want anybody to sit back, complacent, feeling that the spotlight was on Lennox Sebe’s Ciskei alone, or Kaiser Matanzima’s Transkei, or John Vorster’s apartheid South Africa. The spotlight is on the Ciskei, yes, on Transkei, on South Africa, on any other country where public life and personal relationships are bedevilled by tribalism or racialism or any form of sectionalism.
- Full Text:
- Authors: Peteni, R L , Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7038 , http://hdl.handle.net/10962/d1007376 , http://hdl.handle.net/10520/EJC47869
- Description: preprint , R.L. Peteni - 'There is a tendency in human beings to pay no heed to events in small remote areas. They would rather concern themselves only with those events which make headlines, with political upheavals and industrial conflicts centred in large metropolitan regions. Yet there is always drama and human conflict in the humblest rural village. In selecting a pastoral theme and small fictitious villages in an obscure corner of Keiskammahoek as the setting of the novel, I had an ironic intention. Themes illustrated in these obscure villages would, I believed, have more universal application than they would if I had selected a larger centre, identifiable personages and known political trends. I did not want anybody to sit back, complacent, feeling that the spotlight was on Lennox Sebe’s Ciskei alone, or Kaiser Matanzima’s Transkei, or John Vorster’s apartheid South Africa. The spotlight is on the Ciskei, yes, on Transkei, on South Africa, on any other country where public life and personal relationships are bedevilled by tribalism or racialism or any form of sectionalism.
- Full Text:
'Counterfeiting' Shakespeare; Evidence, Authorship, and John Ford's Funerall Elegye, Brian Vickers book review
- Authors: Birkinshaw, Catherine
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457498 , vital:75643 , https://hdl.handle.net/10520/EJC48033
- Description: 'Counterfeiting'Shakespeare; Evidence, Authorship, and John Ford's Funerall Elegye. Cambridge University Press, 2002. 568 pp. Reviewed by CATHARINE BIRKINSHAW' Counterfeiting' Shakespeare is Brian Vickers's magisterial summing up of the debates over two dubious Shakespearean attributions. The first is the notorious" Shall I die?", Gary Taylor's discovery, that he and Stanley Wells included in the Oxford Complete Works (1986).
- Full Text:
- Authors: Birkinshaw, Catherine
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457498 , vital:75643 , https://hdl.handle.net/10520/EJC48033
- Description: 'Counterfeiting'Shakespeare; Evidence, Authorship, and John Ford's Funerall Elegye. Cambridge University Press, 2002. 568 pp. Reviewed by CATHARINE BIRKINSHAW' Counterfeiting' Shakespeare is Brian Vickers's magisterial summing up of the debates over two dubious Shakespearean attributions. The first is the notorious" Shall I die?", Gary Taylor's discovery, that he and Stanley Wells included in the Oxford Complete Works (1986).
- Full Text:
'Environmental policy to community action': methodology and approaches in community-based environmental education programmes in Uganda
- Authors: Babikwa, Daniel J
- Date: 2004
- Subjects: Environmental education -- Uganda -- Case studies Education and state -- Uganda Community development -- Uganda -- Case studies Sustainable development -- Uganda -- Case studies Environmental policy -- Uganda -- Case studies
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1518 , http://hdl.handle.net/10962/d1003400
- Description: This research was conducted in Luwero, a rural district in central Uganda, over a period of three years, half of which entailed fulltime engagement in a participatory action research process with VEDCO, an indigenous NGO. The study focuses on the educational processes involved in the translation of Uganda's environmental policy into action at community level. It looks at community-based education and development activities run by VEDCO among smallholder farmers. The study addressed four objectives. For the first objective I developed a conceptual framework through a review of theories informing education in general and environmental education, adult education, community education, and community development in particular. The second objective was to conduct a situational analysis to identify contextual issues related to policy implementation at community level. The third objective was to engage in a participatory action research process with the NGO in the farming community in response to the identified contextual issues, and the fourth was to explore and comment on environmental education methods used within a community context. PRA techniques, interviews, and other participatory data collection methods were used to generate the data. The study reveals contradictions that limit NGO capacity to make appropriate use of participatory education processes in implementing policy-related training at community level. Elements in the National Plan for the Modernisation of Agriculture, for example, conflicted with the principle of sustainable development underlying the policy. VEDCO itself was changing from a social-welfare-oriented organisation into a commercial enterprise pursuing economic goals, which conflicted with its social goals. The capitalist development ideology of the donor was being adopted by VEDCO, which contradicted the goals of people-centred development. This was exacerbated by VEDCO's dependency on donor funds for its activities. Contextual issues like people's history; poverty, gender and inconsistent land policies further complicated the policy implementation processes. There were also inconsistencies in the epistemological assumptions and didactic approaches evident in the implementation. The study shows that the intended emancipatory education processes are more often supplanted by technicist methodologies. Thus, it exposes the underlying historical, ideological and epistemological tensions and contradictions within the field of education, particularly in relation to the `paradigmatic' orientations (neo-classical, liberal and socially critical/emancipatory) outlined in the literature. Conclusions are made at two levels: in relation to the study goals, of examining policy implementation at community level and in terms of the study's contribution to the understanding of current education theory in the context of sustainable development among communities.
- Full Text:
- Authors: Babikwa, Daniel J
- Date: 2004
- Subjects: Environmental education -- Uganda -- Case studies Education and state -- Uganda Community development -- Uganda -- Case studies Sustainable development -- Uganda -- Case studies Environmental policy -- Uganda -- Case studies
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1518 , http://hdl.handle.net/10962/d1003400
- Description: This research was conducted in Luwero, a rural district in central Uganda, over a period of three years, half of which entailed fulltime engagement in a participatory action research process with VEDCO, an indigenous NGO. The study focuses on the educational processes involved in the translation of Uganda's environmental policy into action at community level. It looks at community-based education and development activities run by VEDCO among smallholder farmers. The study addressed four objectives. For the first objective I developed a conceptual framework through a review of theories informing education in general and environmental education, adult education, community education, and community development in particular. The second objective was to conduct a situational analysis to identify contextual issues related to policy implementation at community level. The third objective was to engage in a participatory action research process with the NGO in the farming community in response to the identified contextual issues, and the fourth was to explore and comment on environmental education methods used within a community context. PRA techniques, interviews, and other participatory data collection methods were used to generate the data. The study reveals contradictions that limit NGO capacity to make appropriate use of participatory education processes in implementing policy-related training at community level. Elements in the National Plan for the Modernisation of Agriculture, for example, conflicted with the principle of sustainable development underlying the policy. VEDCO itself was changing from a social-welfare-oriented organisation into a commercial enterprise pursuing economic goals, which conflicted with its social goals. The capitalist development ideology of the donor was being adopted by VEDCO, which contradicted the goals of people-centred development. This was exacerbated by VEDCO's dependency on donor funds for its activities. Contextual issues like people's history; poverty, gender and inconsistent land policies further complicated the policy implementation processes. There were also inconsistencies in the epistemological assumptions and didactic approaches evident in the implementation. The study shows that the intended emancipatory education processes are more often supplanted by technicist methodologies. Thus, it exposes the underlying historical, ideological and epistemological tensions and contradictions within the field of education, particularly in relation to the `paradigmatic' orientations (neo-classical, liberal and socially critical/emancipatory) outlined in the literature. Conclusions are made at two levels: in relation to the study goals, of examining policy implementation at community level and in terms of the study's contribution to the understanding of current education theory in the context of sustainable development among communities.
- Full Text:
100 years of chemistry at Rhodes University
- Brown, Michael E, Eve, Desmond John, Kaye, Perry T, Rivett, Douglas E A, Watkins, Gareth M
- Authors: Brown, Michael E , Eve, Desmond John , Kaye, Perry T , Rivett, Douglas E A , Watkins, Gareth M
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6564 , http://hdl.handle.net/10962/d1004123
- Description: The history of Grahamstown is well documented and two books deal with the history of Rhodes University.1,2 Although the Chemistry Department was one of the founding departments, coverage in the official histories is minimal and sometimes inaccurate or misleading. The Rhodes University Centenary is an appropriate time to look back on some of the achievements of the department and some of its graduates over the past 100 years.
- Full Text:
- Authors: Brown, Michael E , Eve, Desmond John , Kaye, Perry T , Rivett, Douglas E A , Watkins, Gareth M
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6564 , http://hdl.handle.net/10962/d1004123
- Description: The history of Grahamstown is well documented and two books deal with the history of Rhodes University.1,2 Although the Chemistry Department was one of the founding departments, coverage in the official histories is minimal and sometimes inaccurate or misleading. The Rhodes University Centenary is an appropriate time to look back on some of the achievements of the department and some of its graduates over the past 100 years.
- Full Text:
A capillary zone electrophoresis (CZE) method for the determination of cyclizine hydrochloride in tablets and suppositories
- Mohammadi, I, Kanfer, Isadore, Walker, Roderick B
- Authors: Mohammadi, I , Kanfer, Isadore , Walker, Roderick B
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6406 , http://hdl.handle.net/10962/d1006479
- Description: Current compendial methods of assay for the analysis of cyclizine tablets involve the use of UV spectrophotometry. Since this is a non-selective technique its application to more complex dosage forms, such as suppositories, is unlikely to be appropriate. There is therefore a need for the development of a highly specific quantitative analytical method, such as high performance liquid chromatography (HPLC) or capillary electrophoresis (CE). The latter technique was chosen in view of some specific advantages over HPLC, such as the use of relatively non-toxic aqueous buffers, as opposed to organic solvents, which obviates the use of expensive HPLC grade solvents making CE more cost effective. Cyclizine was analyzed in 50 mM phosphate buffer (pH 2.3) and run at an applied voltage 25 kV. Detection sensitivity was enhanced by using a wavelength of 200 nm and samples were loaded hydrodynamically onto an uncoated fused-silica capillary (60 cm×50 mm i.d.). Chlorcyclizine was used as the internal standard and resolution of both compounds was achieved in less than 7 min. Stress testing was undertaken in order to investigate the appearance of breakdown products. The method has the requisite accuracy, selectivity, sensitivity and precision to assay cyclizine in tablets and suppositories. Degradation products resulting from the stress studies did not interfere with the detection of cyclizine and the assay is thus stability-indicating.
- Full Text:
- Authors: Mohammadi, I , Kanfer, Isadore , Walker, Roderick B
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6406 , http://hdl.handle.net/10962/d1006479
- Description: Current compendial methods of assay for the analysis of cyclizine tablets involve the use of UV spectrophotometry. Since this is a non-selective technique its application to more complex dosage forms, such as suppositories, is unlikely to be appropriate. There is therefore a need for the development of a highly specific quantitative analytical method, such as high performance liquid chromatography (HPLC) or capillary electrophoresis (CE). The latter technique was chosen in view of some specific advantages over HPLC, such as the use of relatively non-toxic aqueous buffers, as opposed to organic solvents, which obviates the use of expensive HPLC grade solvents making CE more cost effective. Cyclizine was analyzed in 50 mM phosphate buffer (pH 2.3) and run at an applied voltage 25 kV. Detection sensitivity was enhanced by using a wavelength of 200 nm and samples were loaded hydrodynamically onto an uncoated fused-silica capillary (60 cm×50 mm i.d.). Chlorcyclizine was used as the internal standard and resolution of both compounds was achieved in less than 7 min. Stress testing was undertaken in order to investigate the appearance of breakdown products. The method has the requisite accuracy, selectivity, sensitivity and precision to assay cyclizine in tablets and suppositories. Degradation products resulting from the stress studies did not interfere with the detection of cyclizine and the assay is thus stability-indicating.
- Full Text:
A case study of the strategic nature of DaimlerChrysler South Africa's corporate social investment programmes in the local communities of the Border-Kei region in the Eastern Cape Province
- Authors: Mak'ochieng, Alice Atieno
- Date: 2004
- Subjects: DaimlerChrysler , Automobile industry and trade -- South Africa , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Industries -- Social aspects -- South Africa -- Eastern Cape , Social responsibility of business -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1165 , http://hdl.handle.net/10962/d1002781 , DaimlerChrysler , Automobile industry and trade -- South Africa , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Industries -- Social aspects -- South Africa -- Eastern Cape , Social responsibility of business -- South Africa -- Eastern Cape
- Description: Corporate social responsibility has become the business issue of the 21st century. Heightened expectations of the business sector, globalisation and increased media attention on the role of business in society are casting an intense spotlight on this issue. As a result, pressure has built on business to play a larger role in bringing about socio-economic development to many local communities where they operate. While for a long time companies have been involved in the community on a philanthropy basis, many companies today are reassessing the manner in which they conduct their corporate social responsibility programmes. Many companies are including corporate social responsibility issues into their strategic planning process and overall corporate strategy. Emphasis is given to certain strategic indicators that must be present in order for a company to be said to have taken a strategic approach to corporate social responsibility. This study adopted a critical-realist approach using a case study method to evaluate DaimlerChrysler South Africa’s corporate social investment programmes in the local community of the Border-Kei region against these strategic indicators. This new form of engagement is even challenging for a multinational corporation, which may feel that it is only obliged to assist the local community where its corporate headquarters is located. But as companies derive an everlarger share of revenue and profits from international operations, multinational companies are being called upon to redefine “community”, by looking beyond local, domestic and geographical communities to include those in regions where they have factories or factories operated by key suppliers. This study found that DCSA was strategically involved and had a good relationship with its local community. However, the company needs to be more connected with the rural communities to make local projects more successful especially after handover.
- Full Text:
- Authors: Mak'ochieng, Alice Atieno
- Date: 2004
- Subjects: DaimlerChrysler , Automobile industry and trade -- South Africa , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Industries -- Social aspects -- South Africa -- Eastern Cape , Social responsibility of business -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1165 , http://hdl.handle.net/10962/d1002781 , DaimlerChrysler , Automobile industry and trade -- South Africa , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Industries -- Social aspects -- South Africa -- Eastern Cape , Social responsibility of business -- South Africa -- Eastern Cape
- Description: Corporate social responsibility has become the business issue of the 21st century. Heightened expectations of the business sector, globalisation and increased media attention on the role of business in society are casting an intense spotlight on this issue. As a result, pressure has built on business to play a larger role in bringing about socio-economic development to many local communities where they operate. While for a long time companies have been involved in the community on a philanthropy basis, many companies today are reassessing the manner in which they conduct their corporate social responsibility programmes. Many companies are including corporate social responsibility issues into their strategic planning process and overall corporate strategy. Emphasis is given to certain strategic indicators that must be present in order for a company to be said to have taken a strategic approach to corporate social responsibility. This study adopted a critical-realist approach using a case study method to evaluate DaimlerChrysler South Africa’s corporate social investment programmes in the local community of the Border-Kei region against these strategic indicators. This new form of engagement is even challenging for a multinational corporation, which may feel that it is only obliged to assist the local community where its corporate headquarters is located. But as companies derive an everlarger share of revenue and profits from international operations, multinational companies are being called upon to redefine “community”, by looking beyond local, domestic and geographical communities to include those in regions where they have factories or factories operated by key suppliers. This study found that DCSA was strategically involved and had a good relationship with its local community. However, the company needs to be more connected with the rural communities to make local projects more successful especially after handover.
- Full Text:
A comparative case study of the strategies used by grade one teachers who teach through the medium of English
- Authors: Jackson, Gail
- Date: 2004
- Subjects: Native language and education -- South Africa Language policy -- South Africa Language and education -- South Africa English language -- Study and teaching (Elementary) -- South Africa Multilingualism -- South Africa Education, Bilingual -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1941 , http://hdl.handle.net/10962/d1007855
- Description: This research project begins by exploring the problems surrounding the implementation of the 1997 Language in Education Policy (LiEP), and offers insight into why some schools, despite the promotion of additive bilingualism, choose English as the primary medium of instruction. It is a comparative case study of two Grade 1 classes in different situational contexts, which highlights the teaching strategies and language practices of teachers who teach predominantly non-English speakers through the medium of English. Research carried out through this case study illustrates the use of a wide range of teaching strategies, which assist young learners when learning through an additional language. In School A, thematic linking between different learning areas to maximise vocabulary development in both the mother tongue and the additional language, as well as repetition, recycling, scaffolding and contextualisation of content were found to be important. In addition, the use of questioning to elicit understanding, as well as classroom organisation and code-switching were strategies which assisted both the teacher and learners in this multilingual environment. In School B, class size, group work and the inclusion into the timetable of a wide range of diverse activities over and above the main learning areas, which provided opportunities for language development, were important considerations. In addition, routine, predictability and an attention to detail, in keeping with a form-focussed approach, aided the children in understanding the mechanics of literacy and guiding them towards becoming phonologically aware.
- Full Text:
- Authors: Jackson, Gail
- Date: 2004
- Subjects: Native language and education -- South Africa Language policy -- South Africa Language and education -- South Africa English language -- Study and teaching (Elementary) -- South Africa Multilingualism -- South Africa Education, Bilingual -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1941 , http://hdl.handle.net/10962/d1007855
- Description: This research project begins by exploring the problems surrounding the implementation of the 1997 Language in Education Policy (LiEP), and offers insight into why some schools, despite the promotion of additive bilingualism, choose English as the primary medium of instruction. It is a comparative case study of two Grade 1 classes in different situational contexts, which highlights the teaching strategies and language practices of teachers who teach predominantly non-English speakers through the medium of English. Research carried out through this case study illustrates the use of a wide range of teaching strategies, which assist young learners when learning through an additional language. In School A, thematic linking between different learning areas to maximise vocabulary development in both the mother tongue and the additional language, as well as repetition, recycling, scaffolding and contextualisation of content were found to be important. In addition, the use of questioning to elicit understanding, as well as classroom organisation and code-switching were strategies which assisted both the teacher and learners in this multilingual environment. In School B, class size, group work and the inclusion into the timetable of a wide range of diverse activities over and above the main learning areas, which provided opportunities for language development, were important considerations. In addition, routine, predictability and an attention to detail, in keeping with a form-focussed approach, aided the children in understanding the mechanics of literacy and guiding them towards becoming phonologically aware.
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A comparative study of egg development in two species of Siphonariid limpets with contrasting developmental modes
- Authors: Pal, Purba
- Date: 2004
- Subjects: Siphonariidae -- Eggs Siphonariidae -- Spawning Limpets
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5826 , http://hdl.handle.net/10962/d1007663
- Description: The family Siphonariidae is considered primitive amongst the basommatophorans although the ancestry and evolutionary relationships of these marine pulmonates are far from settled. This thesis investigates and compares different aspects of egg development and the female reproductive system in two sympatric species of Siphonaria with different developmental mode (S. capensis, a planktonic developer and S. serrata, a direct developer). The study on the seasonality of gametogenesis and spawning shows that they are both spring/summer spawners with continuous sperm production. The egg production is highest in spring and summer with a brief interruption in winter months. The gametogenic cycle when examinated, reveals that both species are simultaneous hermaphrodites once sexually mature. Amongst various factors that are investigated, density of animals has a positive effect on the number of spawn only during peak spawning. Larger individuals of S. capensis and S. serrata contains more mature oocytes in the gonad indicating that the shell length and fecundity of these two limpets are positively correlated. By contrast, parasitism by trematodes has a drastic effect on the reproductive output of these limpets leaving them completely castrated. Egg development in S. capensis and S. serrata shows that both produce yolk auto synthetically (with the help of organelles like RER, Golgi bodies) but S. serrata also incorporates some high molecular weight precursors via endocytotis. The structure as well as the biochemical composition of the egg ribbons is also different between these two species with higher carbohydrate and protein content of collar shaped spawn of S. serrata. S. capensis produces egg ribbons of less fibrous nature containing thinner egg capsules compared to the direct developer. A comparison of both the glandular complex and spermatheca between these two limpets shows no inter specific difference in the structure although the glandular complex of the siphonariids shows fine structural and histochemical similarities with the albumen gland and membrane gland of the opisthobranchs. The structure of the spermatheca suggests that in both species the organ most possibly receives sperm (for degradation only?) and may transport them via the spermathecal duct (for fertilization?). Finally, it is suggested that S. capensis and S. serrata exhibit primitive features (e.g., an autosynthetic mode of vitellogenesis in S. capensis and a single glandular complex composed of an albumen and a mucous gland) compared to other basommatophorans, which should be considered in future phylogenetic investigations.
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- Authors: Pal, Purba
- Date: 2004
- Subjects: Siphonariidae -- Eggs Siphonariidae -- Spawning Limpets
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5826 , http://hdl.handle.net/10962/d1007663
- Description: The family Siphonariidae is considered primitive amongst the basommatophorans although the ancestry and evolutionary relationships of these marine pulmonates are far from settled. This thesis investigates and compares different aspects of egg development and the female reproductive system in two sympatric species of Siphonaria with different developmental mode (S. capensis, a planktonic developer and S. serrata, a direct developer). The study on the seasonality of gametogenesis and spawning shows that they are both spring/summer spawners with continuous sperm production. The egg production is highest in spring and summer with a brief interruption in winter months. The gametogenic cycle when examinated, reveals that both species are simultaneous hermaphrodites once sexually mature. Amongst various factors that are investigated, density of animals has a positive effect on the number of spawn only during peak spawning. Larger individuals of S. capensis and S. serrata contains more mature oocytes in the gonad indicating that the shell length and fecundity of these two limpets are positively correlated. By contrast, parasitism by trematodes has a drastic effect on the reproductive output of these limpets leaving them completely castrated. Egg development in S. capensis and S. serrata shows that both produce yolk auto synthetically (with the help of organelles like RER, Golgi bodies) but S. serrata also incorporates some high molecular weight precursors via endocytotis. The structure as well as the biochemical composition of the egg ribbons is also different between these two species with higher carbohydrate and protein content of collar shaped spawn of S. serrata. S. capensis produces egg ribbons of less fibrous nature containing thinner egg capsules compared to the direct developer. A comparison of both the glandular complex and spermatheca between these two limpets shows no inter specific difference in the structure although the glandular complex of the siphonariids shows fine structural and histochemical similarities with the albumen gland and membrane gland of the opisthobranchs. The structure of the spermatheca suggests that in both species the organ most possibly receives sperm (for degradation only?) and may transport them via the spermathecal duct (for fertilization?). Finally, it is suggested that S. capensis and S. serrata exhibit primitive features (e.g., an autosynthetic mode of vitellogenesis in S. capensis and a single glandular complex composed of an albumen and a mucous gland) compared to other basommatophorans, which should be considered in future phylogenetic investigations.
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