Ethics of climate change: a normative account
- Authors: Afolabi, Abiodun Paul
- Date: 2021-10-29
- Subjects: Climatic changes Senegal Saint-Louis , Climatic changes Moral and ethical aspects , Cultural property Senegal Saint-Louis , Ethics Senegal Saint-Louis , Applied ethics , Environmental justice Senegal Saint-Louis , Philosophy, African , Normativity (Ethics)
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/192864 , vital:45272 , 10.21504/10962/192864
- Description: Consider, for instance, you and your family have lived around a place where you enjoyed the flora and fauna of the land as well as the natural environment. Fishing and farming were pleasant activities for your family, and anyone in the community not only to survive but thrive. Your neighbours and the people in the community pride themselves so much in their farming abilities and fishing techniques. Suddenly things start taking a different turn because of rising sea level and changing weather pattern. First, your land began to give way because of sweeping erosion, and later the riverbank serving the community starts drying up. Your neighbour could not hold their own in this grim condition as they started relocating. You even witnessed some of your family and friends leaving the community and you later heard that they have become climate refugees. To put it all together, you were told that what you are experiencing is one of climate change effects. You were told that the loss of the place that you once cherished is not an act of God but the result of the reckless flaring of greenhouse gasses harmful to the environment by some powerful but polluting nations. What will you do? This might sound like a fairy tale. In reality, this is the story of the people of Saint Louis Atlantic Coasts in Senegal, captured by the Global Climate Change Alliance Plus Initiative.1 Their situation has been described as ‘living on the edge’ because for centuries, Saint Louis Atlantic Coasts, home to around 230,000 inhabitants, also known as the ‘Venice of Africa’ has been protected from the pounding Atlantic waves by the ‘Langue de Barbarie,’ a narrow, 30 km peninsula at the mouth of the Senegal river. However, the low-lying sandy spit of land along this World Heritage site is itself rapidly disappearing in the present. This is the consequence of a changing climate and other man-made problems such as illegal sand-mining and over-development. Today, the southern part of the Langue de Barbarie is an island, and the village of Doune Baba Dieye is under more than a metre of water. The villagers have become climate refugees, forced to live in temporary camps on the mainland. Not only have they lost their homes, but they have also lost significant cultural heritage like the farming and fishing culture tied to this place. The ethical considerations that emerge from climate change impacts on the world’s cultural heritage are varied. However, it seems not as self-evident in the way that research on climate change ethics has been framed around economic interest and direct threats to human life and other species. Even when they mention climate impacts on heritage sites around the world, those of Africans have been side-lined. For instance, the impact of climate change on small island nations like Tuvalu, Kiribati2 have gained much traction in climate change discourse, but we do not get to see stories of Africans whose cherished cultural heritage are affected by climate despoliation. How do we respond to this intractable challenge? This is a question of justice and, to be more precise, climate justice. Many principles and proposals for climate justice have been put forward, but the insufficient attention to the vulnerabilities or loss of cultural heritage values of Africans, which is a critical aspect of their social realities, make these theories less persuasive on a global level. This thesis, then, fills this gap in the literature by suggesting that the failure to take cognizance of the injustice in neglecting cultural heritage values when dealing with the burden of climate change is the effect of three problems. One, the value of culture is less understood in this environmental age. Hence, cultural values are excluded or made to be secondary in consideration of principles of climate justice. Second, the idea of Personhood has been neglected in climate ethics and climate justice discourse. Yet, this idea of Personhood can be an enabler of climate justice in that a realization of the significance of cultural heritage to the wellness of the human persons in Africa, makes it loss morally reprehensible. Third, those whose cultural heritage is significantly affected do not get represented in the debate about sharing the burden of climate change. This dissertation thereby builds upon the general findings of the past about anthropogenic climate change, its causes and consequences. Adopting a discursive normative framework, I also address the significance of cultural heritage in this contemporary environmental age and discuss the global justice implications of cultural heritage loss to climate change. This dissertation further provides a critique of mainstream climate justice theories, especially their marginalization of the cultural dimension of climate change. In this regard, the metaphor - ‘cultural storm’ was deployed to argue that climate justice discourses have neither factored the deep socio-cultural impact of climate change nor do they draw on the cultural understanding of justice in putting forward their theories. Given the nature of the indirect, cumulative, and interconnected invisible losses to cultural heritage from climate change, it seems unlikely that they can be addressed by simple tweaks of the climate justice status quo. This dissertation proposes that the idea of personhood in African philosophy, can be conceived to ensure climate justice live up to its expectations in a world of diverse persons dealing with a complex phenomenon like climate change. It argues that a cultural dimension of climate ethics has implications for how mitigation, adaptation and compensation plans should be furthered for global climate justice. At the foundation of my argument, I suggest that what is needed in climate justice discourse is a commitment to explore new and innovative alternatives that will produce an inclusive global climate treaty that is sensitive to the cultural heritage assets that is destroyed by climate change in Africa. This will require a multi-dimensional framework that allows fundamentally different kinds of values and benefits to be given equal visibility and standing in global climate negotiations. The dissertation proceeds in six chapters. In the first chapter, I discuss how climate change denies, damage and destroys cultural heritage values in Africa and argue that it is unjust to ignore this dimension of climate change impact, particularly on the African continent. In the second chapter, I critically discuss the normative value of cultural heritage in an environmentally sustainable and morally appropriate way for this global age. I argue that what is lost when climate change affects cultural heritage is a significant cultural asset that ought to be seriously considered in climate ethics. The third chapter addresses the global justice implications of the destruction of Africa's cultural heritage by climate change that must be paid attention to. In chapter four, I evaluate the plausibility of some of the mainstream climate justice proposals. I offered a different possible critique of current approaches to climate justice to show how they have furthered cultural injustice. The critique of current climate justice theories that I offer, stems from an uninspiring approach that belies logic permitting the sacrificing of that which is connected to others wellbeing as well as the implicit assumptions and the limitation of the idea of justice that undergird these climate justice theories. I offer, in chapter five, a plausible climate ethics theory that recognizes culturally embedded ideas of justice and empower all stakeholders to build by themselves, lives that are, in the light of these ideas, deemed to be adversely impacted by climate change. This theory advances a socio-cultural perspective to climate change which could provide a nuanced basis for understanding and addressing global climate duties that will be sensitive to the loss of cultural heritage. Specifically, I apply the African conception of personhood, to provide a normative basis for a different but intuitive understanding of the cultural dimension of climate ethics. In the final chapter, I discuss how this theory can be applied to rethink current global responses in the form of mitigation, adaptation and compensation in such a way that it takes seriously the impacts of climate change on Africa’s cultural heritage and values. , Thesis (PhD) -- Faculty of Humanities, Philosophy, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Afolabi, Abiodun Paul
- Date: 2021-10-29
- Subjects: Climatic changes Senegal Saint-Louis , Climatic changes Moral and ethical aspects , Cultural property Senegal Saint-Louis , Ethics Senegal Saint-Louis , Applied ethics , Environmental justice Senegal Saint-Louis , Philosophy, African , Normativity (Ethics)
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/192864 , vital:45272 , 10.21504/10962/192864
- Description: Consider, for instance, you and your family have lived around a place where you enjoyed the flora and fauna of the land as well as the natural environment. Fishing and farming were pleasant activities for your family, and anyone in the community not only to survive but thrive. Your neighbours and the people in the community pride themselves so much in their farming abilities and fishing techniques. Suddenly things start taking a different turn because of rising sea level and changing weather pattern. First, your land began to give way because of sweeping erosion, and later the riverbank serving the community starts drying up. Your neighbour could not hold their own in this grim condition as they started relocating. You even witnessed some of your family and friends leaving the community and you later heard that they have become climate refugees. To put it all together, you were told that what you are experiencing is one of climate change effects. You were told that the loss of the place that you once cherished is not an act of God but the result of the reckless flaring of greenhouse gasses harmful to the environment by some powerful but polluting nations. What will you do? This might sound like a fairy tale. In reality, this is the story of the people of Saint Louis Atlantic Coasts in Senegal, captured by the Global Climate Change Alliance Plus Initiative.1 Their situation has been described as ‘living on the edge’ because for centuries, Saint Louis Atlantic Coasts, home to around 230,000 inhabitants, also known as the ‘Venice of Africa’ has been protected from the pounding Atlantic waves by the ‘Langue de Barbarie,’ a narrow, 30 km peninsula at the mouth of the Senegal river. However, the low-lying sandy spit of land along this World Heritage site is itself rapidly disappearing in the present. This is the consequence of a changing climate and other man-made problems such as illegal sand-mining and over-development. Today, the southern part of the Langue de Barbarie is an island, and the village of Doune Baba Dieye is under more than a metre of water. The villagers have become climate refugees, forced to live in temporary camps on the mainland. Not only have they lost their homes, but they have also lost significant cultural heritage like the farming and fishing culture tied to this place. The ethical considerations that emerge from climate change impacts on the world’s cultural heritage are varied. However, it seems not as self-evident in the way that research on climate change ethics has been framed around economic interest and direct threats to human life and other species. Even when they mention climate impacts on heritage sites around the world, those of Africans have been side-lined. For instance, the impact of climate change on small island nations like Tuvalu, Kiribati2 have gained much traction in climate change discourse, but we do not get to see stories of Africans whose cherished cultural heritage are affected by climate despoliation. How do we respond to this intractable challenge? This is a question of justice and, to be more precise, climate justice. Many principles and proposals for climate justice have been put forward, but the insufficient attention to the vulnerabilities or loss of cultural heritage values of Africans, which is a critical aspect of their social realities, make these theories less persuasive on a global level. This thesis, then, fills this gap in the literature by suggesting that the failure to take cognizance of the injustice in neglecting cultural heritage values when dealing with the burden of climate change is the effect of three problems. One, the value of culture is less understood in this environmental age. Hence, cultural values are excluded or made to be secondary in consideration of principles of climate justice. Second, the idea of Personhood has been neglected in climate ethics and climate justice discourse. Yet, this idea of Personhood can be an enabler of climate justice in that a realization of the significance of cultural heritage to the wellness of the human persons in Africa, makes it loss morally reprehensible. Third, those whose cultural heritage is significantly affected do not get represented in the debate about sharing the burden of climate change. This dissertation thereby builds upon the general findings of the past about anthropogenic climate change, its causes and consequences. Adopting a discursive normative framework, I also address the significance of cultural heritage in this contemporary environmental age and discuss the global justice implications of cultural heritage loss to climate change. This dissertation further provides a critique of mainstream climate justice theories, especially their marginalization of the cultural dimension of climate change. In this regard, the metaphor - ‘cultural storm’ was deployed to argue that climate justice discourses have neither factored the deep socio-cultural impact of climate change nor do they draw on the cultural understanding of justice in putting forward their theories. Given the nature of the indirect, cumulative, and interconnected invisible losses to cultural heritage from climate change, it seems unlikely that they can be addressed by simple tweaks of the climate justice status quo. This dissertation proposes that the idea of personhood in African philosophy, can be conceived to ensure climate justice live up to its expectations in a world of diverse persons dealing with a complex phenomenon like climate change. It argues that a cultural dimension of climate ethics has implications for how mitigation, adaptation and compensation plans should be furthered for global climate justice. At the foundation of my argument, I suggest that what is needed in climate justice discourse is a commitment to explore new and innovative alternatives that will produce an inclusive global climate treaty that is sensitive to the cultural heritage assets that is destroyed by climate change in Africa. This will require a multi-dimensional framework that allows fundamentally different kinds of values and benefits to be given equal visibility and standing in global climate negotiations. The dissertation proceeds in six chapters. In the first chapter, I discuss how climate change denies, damage and destroys cultural heritage values in Africa and argue that it is unjust to ignore this dimension of climate change impact, particularly on the African continent. In the second chapter, I critically discuss the normative value of cultural heritage in an environmentally sustainable and morally appropriate way for this global age. I argue that what is lost when climate change affects cultural heritage is a significant cultural asset that ought to be seriously considered in climate ethics. The third chapter addresses the global justice implications of the destruction of Africa's cultural heritage by climate change that must be paid attention to. In chapter four, I evaluate the plausibility of some of the mainstream climate justice proposals. I offered a different possible critique of current approaches to climate justice to show how they have furthered cultural injustice. The critique of current climate justice theories that I offer, stems from an uninspiring approach that belies logic permitting the sacrificing of that which is connected to others wellbeing as well as the implicit assumptions and the limitation of the idea of justice that undergird these climate justice theories. I offer, in chapter five, a plausible climate ethics theory that recognizes culturally embedded ideas of justice and empower all stakeholders to build by themselves, lives that are, in the light of these ideas, deemed to be adversely impacted by climate change. This theory advances a socio-cultural perspective to climate change which could provide a nuanced basis for understanding and addressing global climate duties that will be sensitive to the loss of cultural heritage. Specifically, I apply the African conception of personhood, to provide a normative basis for a different but intuitive understanding of the cultural dimension of climate ethics. In the final chapter, I discuss how this theory can be applied to rethink current global responses in the form of mitigation, adaptation and compensation in such a way that it takes seriously the impacts of climate change on Africa’s cultural heritage and values. , Thesis (PhD) -- Faculty of Humanities, Philosophy, 2021
- Full Text:
- Date Issued: 2021-10-29
The design, synthesis and antiplasmodial activity of a series of halogenated fosmidomycin analogues and hybrid drugs
- Authors: Afolayan, Anthonia Folake
- Date: 2012
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64370 , vital:28538
- Description: Malaria continues to be a devastating disease and a major cause of death in sub-Saharan Africa. With resistance against most of the available antimalarial drugs, there is a need for ongoing research and development of antimalarial agents. Fosmidomycin and its acetyl analogue FR900098 have been identified as potent inhibitors of Plasmodium falciparum, the causative agent of the most deadly form of malaria. Clinical trials of these agents have revealed poor absorption due to their high hydrophilicity. In the present studies the effect of halogenation of the acyl chain as well as the biological effect of extending the acyl sidechain was explored. This provided the basis on which fosmidomycin hybrids were designed to investigate the feasibility of hybrid extending into NADPH binding pocket. Synthesis of a series of halogenated FR900098 analogues was carried out in three stages. This included i) The introduction of the phosphonate group by reaction with 1,3dibromopropane in an Arbuzov reaction, ii) The introduction of a hydroxamate group by reaction of the propyl phosphonate by means of a nucleophilic substitution reaction with BocNHOBn and iii) The introduction of a halogenated acyl side chain on a protected fosmidomycin backbone. The synthesis of fosmidomycin-hybrids for which chloroquinefosmidomycin hybrids were used as the prototype, involved convergence of the two separately constructed moieties i.e. fosmidomycin and the quinoline moieties in a covalent linkage. The quinoline moiety was easily synthesized from the reaction of 4,7dichloroquinoline with 1,2-diamino ethane. The aminoquinoline so formed resulted in chloroquine-fosmidomycin hybrids 3.8 and 3.9 when reacted with halogenated FR900098 analogues. Antiplasmodial assays were conducted on the chloroquine-fosmidomycin hybrids and the halogenated fosmidomycin derivatives against the chloroquine resistant Gambian FCR-3 strain of P. falciparum. The most potent iodoacetyl fosmidomycin analogues 2.21 gave an IC50 value of 5.54 µM which is eight times more potent than the known antiplasmodial FR900098 which gave an IC50 value of 41.67 µM. All the halogenated FR900098 analogues showed better antiplasmodial activity than their non-halogenated derivatives. This indicated that the presence of halogens in the FR900098 analogues contributes to their biological Chapter 1 Literature review activity. The acetyl and propyl linked hybrids 3.8 and 3.9 showed potent antiplasmodial activity with IC50 values of 0.18 and 0.82 µM respectively. These were by far the most potent hybrids synthesized and provided leads for a new class of promising antimalarial agents. Preliminary E. coli DXR enzyme inhibition assays were carried out on the halogenated fosmidomycin analogues. The results showed good inhibition of the enzyme by the phosphonic acids of the chloroacetyl and chloropropyl analogues 2.1 and 2.2 respectively. Molecular modelling of the compounds on E. coli (PDB code: 2EGH) and P. falciparum (PDB code: 3AUA) DXR showed strong binding of the halogenated fosmidomycin analogues while the hybrids in the absence of docked NADPH showed minimum binding to the enzymes.
- Full Text:
- Date Issued: 2012
- Authors: Afolayan, Anthonia Folake
- Date: 2012
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64370 , vital:28538
- Description: Malaria continues to be a devastating disease and a major cause of death in sub-Saharan Africa. With resistance against most of the available antimalarial drugs, there is a need for ongoing research and development of antimalarial agents. Fosmidomycin and its acetyl analogue FR900098 have been identified as potent inhibitors of Plasmodium falciparum, the causative agent of the most deadly form of malaria. Clinical trials of these agents have revealed poor absorption due to their high hydrophilicity. In the present studies the effect of halogenation of the acyl chain as well as the biological effect of extending the acyl sidechain was explored. This provided the basis on which fosmidomycin hybrids were designed to investigate the feasibility of hybrid extending into NADPH binding pocket. Synthesis of a series of halogenated FR900098 analogues was carried out in three stages. This included i) The introduction of the phosphonate group by reaction with 1,3dibromopropane in an Arbuzov reaction, ii) The introduction of a hydroxamate group by reaction of the propyl phosphonate by means of a nucleophilic substitution reaction with BocNHOBn and iii) The introduction of a halogenated acyl side chain on a protected fosmidomycin backbone. The synthesis of fosmidomycin-hybrids for which chloroquinefosmidomycin hybrids were used as the prototype, involved convergence of the two separately constructed moieties i.e. fosmidomycin and the quinoline moieties in a covalent linkage. The quinoline moiety was easily synthesized from the reaction of 4,7dichloroquinoline with 1,2-diamino ethane. The aminoquinoline so formed resulted in chloroquine-fosmidomycin hybrids 3.8 and 3.9 when reacted with halogenated FR900098 analogues. Antiplasmodial assays were conducted on the chloroquine-fosmidomycin hybrids and the halogenated fosmidomycin derivatives against the chloroquine resistant Gambian FCR-3 strain of P. falciparum. The most potent iodoacetyl fosmidomycin analogues 2.21 gave an IC50 value of 5.54 µM which is eight times more potent than the known antiplasmodial FR900098 which gave an IC50 value of 41.67 µM. All the halogenated FR900098 analogues showed better antiplasmodial activity than their non-halogenated derivatives. This indicated that the presence of halogens in the FR900098 analogues contributes to their biological Chapter 1 Literature review activity. The acetyl and propyl linked hybrids 3.8 and 3.9 showed potent antiplasmodial activity with IC50 values of 0.18 and 0.82 µM respectively. These were by far the most potent hybrids synthesized and provided leads for a new class of promising antimalarial agents. Preliminary E. coli DXR enzyme inhibition assays were carried out on the halogenated fosmidomycin analogues. The results showed good inhibition of the enzyme by the phosphonic acids of the chloroacetyl and chloropropyl analogues 2.1 and 2.2 respectively. Molecular modelling of the compounds on E. coli (PDB code: 2EGH) and P. falciparum (PDB code: 3AUA) DXR showed strong binding of the halogenated fosmidomycin analogues while the hybrids in the absence of docked NADPH showed minimum binding to the enzymes.
- Full Text:
- Date Issued: 2012
AIA's Southern Africa Chronicle - Volume VIII No.3
- Africa Information Afrique (AIA)
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169401 , vital:41746
- Description: Machipanda, February 3,1995 (AIA/Brian Latham)—Many Zimbabwean peasants have quietly found the solution to land shortages by crossing into neighbouring Mozambique where it is plentiful. For as little as US$ 10 a field, they are acquiring land and a place to live — probably illegally — from chiefs and headmen across the border. Information on how to get land is easily accessible in Machipanda, the Mozambique border town at the head of the Beira Corridor from Zimbabwe to the Indian Ocean. Confusion reigns in Mozambique in the aftermath of the devastating civil war. And in a country reputed to be the poorest on earth, the government can do little to control the flood of border jumpers in both directions: Mozambicans enter Zimbabwe to sell everything from guns to clothes donated by aid agencies and Zimbabweans enter Mozambique in search of land to till.
- Full Text:
- Date Issued: 1995
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169401 , vital:41746
- Description: Machipanda, February 3,1995 (AIA/Brian Latham)—Many Zimbabwean peasants have quietly found the solution to land shortages by crossing into neighbouring Mozambique where it is plentiful. For as little as US$ 10 a field, they are acquiring land and a place to live — probably illegally — from chiefs and headmen across the border. Information on how to get land is easily accessible in Machipanda, the Mozambique border town at the head of the Beira Corridor from Zimbabwe to the Indian Ocean. Confusion reigns in Mozambique in the aftermath of the devastating civil war. And in a country reputed to be the poorest on earth, the government can do little to control the flood of border jumpers in both directions: Mozambicans enter Zimbabwe to sell everything from guns to clothes donated by aid agencies and Zimbabweans enter Mozambique in search of land to till.
- Full Text:
- Date Issued: 1995
AIA's Southern Africa Chronicle - Volume VIII No.1
- Africa Information Afrique (AIA)
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169377 , vital:41744
- Description: Sowa, January 3, 1994 (AIA/Caitlin Davies) — Mercy Manakedi Theetso is 29 and has four children. She breast-fed her first child for 18 months, her second for eight months, and she didn’t breast-feed her third child at all. “I was working and the baby stayed with my mother so we used a bottle for the first four months, then we used a cup,” explains Theetso. “Myself, I like to breast-feed but I don’t have the time.” In the 1960s Botswana’s medical practitioners began giving new-born babies the bottle. Now, 30 years later, there is a concerted effort by the Botswana government to promote a return to breast-feeding. But as women have gone out of the home to work, reversing the trend is not an easy task. However, breast-feeding does remain popular in Botswana. “It’s a culturally acceptable norm,” says Virkloti Morewane of UNICEF, and boys and girls are fed for the same amount of time.
- Full Text:
- Date Issued: 1995
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169377 , vital:41744
- Description: Sowa, January 3, 1994 (AIA/Caitlin Davies) — Mercy Manakedi Theetso is 29 and has four children. She breast-fed her first child for 18 months, her second for eight months, and she didn’t breast-feed her third child at all. “I was working and the baby stayed with my mother so we used a bottle for the first four months, then we used a cup,” explains Theetso. “Myself, I like to breast-feed but I don’t have the time.” In the 1960s Botswana’s medical practitioners began giving new-born babies the bottle. Now, 30 years later, there is a concerted effort by the Botswana government to promote a return to breast-feeding. But as women have gone out of the home to work, reversing the trend is not an easy task. However, breast-feeding does remain popular in Botswana. “It’s a culturally acceptable norm,” says Virkloti Morewane of UNICEF, and boys and girls are fed for the same amount of time.
- Full Text:
- Date Issued: 1995
AIA's Southern Africa Chronicle - Volume VIII No.2
- Africa Information Afrique (AIA)
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169389 , vital:41745
- Description: Windhoek, January 16,1995 (AIA/Joshua Amupadhi) — Many impoverished Namibians are demanding swifter change to better their lives following elections which restored the ruling SWAPO party to power for another five years. SWAPO, the former guerrilla organisation which fought for the independence of Namibia from apartheid South African rulers, won an easy victory in the first post independence elections in December. Those interviewed say five years were enough for the former liberation movement to have made a good start on improving the standards of living of many previously disadvantaged Namibians and dismantle apartheid structures established during 75 years of South African colonialism. One SWAPO supporter says independence has created only a black elite to join whites in the rich suburban areas but has not narrowed the gap between the rich and poor.
- Full Text:
- Date Issued: 1995
- Authors: Africa Information Afrique (AIA)
- Date: 1995
- Subjects: AIA
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/169389 , vital:41745
- Description: Windhoek, January 16,1995 (AIA/Joshua Amupadhi) — Many impoverished Namibians are demanding swifter change to better their lives following elections which restored the ruling SWAPO party to power for another five years. SWAPO, the former guerrilla organisation which fought for the independence of Namibia from apartheid South African rulers, won an easy victory in the first post independence elections in December. Those interviewed say five years were enough for the former liberation movement to have made a good start on improving the standards of living of many previously disadvantaged Namibians and dismantle apartheid structures established during 75 years of South African colonialism. One SWAPO supporter says independence has created only a black elite to join whites in the rich suburban areas but has not narrowed the gap between the rich and poor.
- Full Text:
- Date Issued: 1995
Trade unions in Africa
- African Labour Researchers Network (ALRN)
- Authors: African Labour Researchers Network (ALRN)
- Date: 2003-12
- Subjects: Labour unions -- Africa
- Language: English
- Type: text , pamphlet
- Identifier: http://hdl.handle.net/10962/111142 , vital:33390
- Description: In March 2001, a group of African trade union-based researchers met in Johannesburg, South Africa, to form the African Labour Researchers Network (ALRN). The network initially covered Ghana, Nigeria, Namibia, South Africa, Zimbabwe and Zambia but has since grown and now includes Kenya, Tanzania, Malawi and Angola. One of the network's objectives is to address policy issues that affect African workers and their trade unions by providing relevant research and education materials. The first research project undertaken by the network covered the labour movement in the countries of the founding members. The researchers looked at the legal, economic and political environment in which trade unions operate and identified some of the key challenges that unions face today. This booklet is based on the country case studies that were undertaken by Austin Muneku (Zambia), Anthony yaw Baah (Ghana), Godfrey Kanyenze and Blessing Chiripanhura (Zimbabwe), Salihu Lukman (Nigeria), Herbert Jauch and Barney Karuuombe (Namibia) as well as Ravi Naidoo, Claire Horton, Thobile Yanta, Samuel Denga, Lebo Modise and Wolfe Braude (South Africa). This booklet was compiled by Herbert Jauch and Kishi-Silas Shakumu with assistance from Anthony yaw Baah. We wish to thank the Ford Foundation, the Netherlands Trade Union Federation (FNV), the Finnish Trade Union Solidarity Centre (SASK), and the Belgian Fund for Development Co-operation (FOS) for their support (direct and indirect) of the network's activities, which made the publication of this booklet possible.
- Full Text:
- Date Issued: 2003-12
- Authors: African Labour Researchers Network (ALRN)
- Date: 2003-12
- Subjects: Labour unions -- Africa
- Language: English
- Type: text , pamphlet
- Identifier: http://hdl.handle.net/10962/111142 , vital:33390
- Description: In March 2001, a group of African trade union-based researchers met in Johannesburg, South Africa, to form the African Labour Researchers Network (ALRN). The network initially covered Ghana, Nigeria, Namibia, South Africa, Zimbabwe and Zambia but has since grown and now includes Kenya, Tanzania, Malawi and Angola. One of the network's objectives is to address policy issues that affect African workers and their trade unions by providing relevant research and education materials. The first research project undertaken by the network covered the labour movement in the countries of the founding members. The researchers looked at the legal, economic and political environment in which trade unions operate and identified some of the key challenges that unions face today. This booklet is based on the country case studies that were undertaken by Austin Muneku (Zambia), Anthony yaw Baah (Ghana), Godfrey Kanyenze and Blessing Chiripanhura (Zimbabwe), Salihu Lukman (Nigeria), Herbert Jauch and Barney Karuuombe (Namibia) as well as Ravi Naidoo, Claire Horton, Thobile Yanta, Samuel Denga, Lebo Modise and Wolfe Braude (South Africa). This booklet was compiled by Herbert Jauch and Kishi-Silas Shakumu with assistance from Anthony yaw Baah. We wish to thank the Ford Foundation, the Netherlands Trade Union Federation (FNV), the Finnish Trade Union Solidarity Centre (SASK), and the Belgian Fund for Development Co-operation (FOS) for their support (direct and indirect) of the network's activities, which made the publication of this booklet possible.
- Full Text:
- Date Issued: 2003-12
A basic guide to the Reconstruction and Development Programme
- Authors: African National Congress
- Date: 1994
- Subjects: Reconstruction and development programme (South Africa) , South Africa -- Economic policy , South Africa -- Social policy , African National Congress
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/75927 , vital:30483 , 1874902062
- Description: The RDP is a plan to address the many social and economic problems facing our country — problems such as...violence, lack of housing, lack of jobs, inadequate education and health care, lack of democracy, a failing economy. The RDP recognises that all of these problems are connected. For example, we cannot successfully build the economy while millions do not have homes or jobs. And we cannot provide homes and jobs without rebuilding the economy. We need policies and strategies to address all of the problems together. The RDP aims to do this. The RDP is a programme to mobilise all our people and all our resources to finally get rid of apartheid and build a democratic, non racial and non sexist future. The RDP was drawn up by the ANC-led alliance in consultation with other key mass organisations and assisted by a wide range of nongovernmental organisations (NGOs) and research organisations. This inclusive approach to developing and implementing policy — involving as many organisations as possible — is unique in South Africa’s political history. The ANC — because it is a liberation movement and based on the traditions of the Freedom Charter — is the only political organisation which can bring together such a wide range of social movements, community-based organisations and numerous other sectors and formations. This widespread and broad-based support throughout South Africa will allow the ANC within a Government of National Unity successfully to implement the RDP.
- Full Text:
- Date Issued: 1994
- Authors: African National Congress
- Date: 1994
- Subjects: Reconstruction and development programme (South Africa) , South Africa -- Economic policy , South Africa -- Social policy , African National Congress
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/75927 , vital:30483 , 1874902062
- Description: The RDP is a plan to address the many social and economic problems facing our country — problems such as...violence, lack of housing, lack of jobs, inadequate education and health care, lack of democracy, a failing economy. The RDP recognises that all of these problems are connected. For example, we cannot successfully build the economy while millions do not have homes or jobs. And we cannot provide homes and jobs without rebuilding the economy. We need policies and strategies to address all of the problems together. The RDP aims to do this. The RDP is a programme to mobilise all our people and all our resources to finally get rid of apartheid and build a democratic, non racial and non sexist future. The RDP was drawn up by the ANC-led alliance in consultation with other key mass organisations and assisted by a wide range of nongovernmental organisations (NGOs) and research organisations. This inclusive approach to developing and implementing policy — involving as many organisations as possible — is unique in South Africa’s political history. The ANC — because it is a liberation movement and based on the traditions of the Freedom Charter — is the only political organisation which can bring together such a wide range of social movements, community-based organisations and numerous other sectors and formations. This widespread and broad-based support throughout South Africa will allow the ANC within a Government of National Unity successfully to implement the RDP.
- Full Text:
- Date Issued: 1994
Gender paper to be presented to the ANC Policy Conference 2012: discussion document
- African National Congress (ANC)
- Authors: African National Congress (ANC)
- Date: 2012-02-01
- Subjects: South Africa -- Politics and government -- 1994- , Social planning -- South Africa
- Language: English
- Type: book , text
- Identifier: http://hdl.handle.net/10962/68675 , vital:29304
- Description: This document is informed by the struggles of women in the fight against colonialism and apartheid which were also encapsulated in the Women’s Charter of 1954. The discussion is also premised on the charter that women drew up in 1993, prior to the 1994 elections. Our Constitution, in its quest to protect and promote gender equality in South Africa, drew largely from these documents.
- Full Text:
- Date Issued: 2012-02-01
- Authors: African National Congress (ANC)
- Date: 2012-02-01
- Subjects: South Africa -- Politics and government -- 1994- , Social planning -- South Africa
- Language: English
- Type: book , text
- Identifier: http://hdl.handle.net/10962/68675 , vital:29304
- Description: This document is informed by the struggles of women in the fight against colonialism and apartheid which were also encapsulated in the Women’s Charter of 1954. The discussion is also premised on the charter that women drew up in 1993, prior to the 1994 elections. Our Constitution, in its quest to protect and promote gender equality in South Africa, drew largely from these documents.
- Full Text:
- Date Issued: 2012-02-01
Discussion document : nationalisation
- African National Congress, Department of Economic Policy
- Authors: African National Congress, Department of Economic Policy
- Date: 1991?
- Subjects: Government ownership -- South Africa , Industrial policy -- South Africa , Socialism -- South Africa , South Africa -- Economic policy
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66044 , vital:28887
- Description: Nationalisation involves putting any section of the economy under the control and ownership of a government. Nationalisation is not new to South Africa. The governments of the past and especially the Nationalist Party have nationalised a number of industries in the South African economy. Today almost 54% of the productive assets in the country are in the hands of the government. Transport, electricity, post office, are a few examples. Nationalisation in the past has been used to benefit only the whites, by providing them with jobs and services.
- Full Text:
- Date Issued: 1991?
- Authors: African National Congress, Department of Economic Policy
- Date: 1991?
- Subjects: Government ownership -- South Africa , Industrial policy -- South Africa , Socialism -- South Africa , South Africa -- Economic policy
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66044 , vital:28887
- Description: Nationalisation involves putting any section of the economy under the control and ownership of a government. Nationalisation is not new to South Africa. The governments of the past and especially the Nationalist Party have nationalised a number of industries in the South African economy. Today almost 54% of the productive assets in the country are in the hands of the government. Transport, electricity, post office, are a few examples. Nationalisation in the past has been used to benefit only the whites, by providing them with jobs and services.
- Full Text:
- Date Issued: 1991?
The Apdusan: African People's Democratic Union of Southern Africa
- African People's Democratic Union of Southern Africa
- Authors: African People's Democratic Union of Southern Africa
- Date: 1999-10
- Subjects: APDUSA -- Periodicals , South Africa -- Politics and government -- 1994- -- Periodicals , South Africa -- Economic conditions -- 1991- -- Periodicals , South Africa -- Social conditions
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/76095 , vital:30503
- Description: After many deadlocks, accusations of negotiating in bad faith, marches and lunch-time pickets, more than 600,000 Public Sector Workers went on strike on 24 August 1999. The government then unilaterally implemented a 6.3% increase for public servants against their original demand of 10-15% increase. "The dispute goes back to January 1999, to a workshop dealing with the budgetary process. At this meeting the Department of Finance outlined its Medium-Term Expenditure Framework, for the first time to the public sector workers. In the MTEF the parameters for wage cuts, and 'non-negotiability’ were already set. All unions in the public service bargaining council presented their wage demands - 10% to 15%” [COSATU paper on Public Sector Workers Fight for a Living Wage.] Thereafter COSATU and government officials met over the next few months until May 1999, when a dispute was declared. On the 29th March 1999, COSATU commented ‘To the Unions it is clear, government is not prepared to negotiate - it has already made up its mind’ [COSATU document - Public Sector Workers Fight for a Living Wage] During the period May-June COSATU Unions decided to “throw their weight behind the ANC election campaign.’’[ibid.]. By the August 1999 the unions compromised their demand from 10% to 7.3% increase. Towards the end of August the government unilaterally implemented ei 6.3% increase for public sector workers, and 4% increase for itself. It then went on an ideological media campaign against the workers claiming that the 4% increase for members of parliament is much less than what has been granted to the public sector workers. , Vol. 5 no. 3
- Full Text:
- Date Issued: 1999-10
- Authors: African People's Democratic Union of Southern Africa
- Date: 1999-10
- Subjects: APDUSA -- Periodicals , South Africa -- Politics and government -- 1994- -- Periodicals , South Africa -- Economic conditions -- 1991- -- Periodicals , South Africa -- Social conditions
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/76095 , vital:30503
- Description: After many deadlocks, accusations of negotiating in bad faith, marches and lunch-time pickets, more than 600,000 Public Sector Workers went on strike on 24 August 1999. The government then unilaterally implemented a 6.3% increase for public servants against their original demand of 10-15% increase. "The dispute goes back to January 1999, to a workshop dealing with the budgetary process. At this meeting the Department of Finance outlined its Medium-Term Expenditure Framework, for the first time to the public sector workers. In the MTEF the parameters for wage cuts, and 'non-negotiability’ were already set. All unions in the public service bargaining council presented their wage demands - 10% to 15%” [COSATU paper on Public Sector Workers Fight for a Living Wage.] Thereafter COSATU and government officials met over the next few months until May 1999, when a dispute was declared. On the 29th March 1999, COSATU commented ‘To the Unions it is clear, government is not prepared to negotiate - it has already made up its mind’ [COSATU document - Public Sector Workers Fight for a Living Wage] During the period May-June COSATU Unions decided to “throw their weight behind the ANC election campaign.’’[ibid.]. By the August 1999 the unions compromised their demand from 10% to 7.3% increase. Towards the end of August the government unilaterally implemented ei 6.3% increase for public sector workers, and 4% increase for itself. It then went on an ideological media campaign against the workers claiming that the 4% increase for members of parliament is much less than what has been granted to the public sector workers. , Vol. 5 no. 3
- Full Text:
- Date Issued: 1999-10
Drifting towards death: a South African patient safety incident through an HFE Systems lens
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
Mainstreaming education for sustainable development: Elaborating the role of position-practice systems using seven laminations of scale
- Agbedahin, Adesuwa V, Lotz-Sisitka, Heila
- Authors: Agbedahin, Adesuwa V , Lotz-Sisitka, Heila
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182428 , vital:43829 , xlink:href="https://doi.org/10.1080/14767430.2019.1602975"
- Description: The United Nations Sustainable Development Goal 4.7 proposes that Education for Sustainable Development (ESD) should be included at all levels of education, known as ‘mainstreaming’. However, there is little guidance as to how to achieve this. ESD mainstreaming demands more than simply a technical policy transfer; it also requires attention to the position-practice systems of involved agents. This article critically assesses the mainstreaming of ESD in the case of university educators in Africa who have participated in the International Training Programme on ESD in higher education. It clarifies their position-practice systems in terms of Bhaskar’s seven laminations of scale. This article therefore provides a detailed description of the ways in which agents' position-practice systems enable and constrain ESD mainstreaming. It also demonstrates that a critical realist perspective can contribute towards the understanding and achievement of transformation towards sustainability and can help to ensure the flourishing of both current and future generations.
- Full Text:
- Date Issued: 2019
- Authors: Agbedahin, Adesuwa V , Lotz-Sisitka, Heila
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182428 , vital:43829 , xlink:href="https://doi.org/10.1080/14767430.2019.1602975"
- Description: The United Nations Sustainable Development Goal 4.7 proposes that Education for Sustainable Development (ESD) should be included at all levels of education, known as ‘mainstreaming’. However, there is little guidance as to how to achieve this. ESD mainstreaming demands more than simply a technical policy transfer; it also requires attention to the position-practice systems of involved agents. This article critically assesses the mainstreaming of ESD in the case of university educators in Africa who have participated in the International Training Programme on ESD in higher education. It clarifies their position-practice systems in terms of Bhaskar’s seven laminations of scale. This article therefore provides a detailed description of the ways in which agents' position-practice systems enable and constrain ESD mainstreaming. It also demonstrates that a critical realist perspective can contribute towards the understanding and achievement of transformation towards sustainability and can help to ensure the flourishing of both current and future generations.
- Full Text:
- Date Issued: 2019
Voltammetric characterisation of the self-assembled monolayers (SAMs) of benzyl-and dodecyl-mercapto tetra substituted metallophthalocyanines complexes
- Agboola, Bolade, Westbroek, Philippe, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Agboola, Bolade , Westbroek, Philippe , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281414 , vital:55723 , xlink:href="https://doi.org/10.1016/j.elecom.2006.08.047"
- Description: Voltammetric characterisations of cobalt, iron, manganese, nickel and zinc phthalocyanine complexes tetra substituted with benzyl- and dodecyl-mercapto ring substituents and immobilisation on gold electrodes via the self-assembling technique are presented. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, under potential deposition of copper and solution redox chemistry of [Fe(H2O)6 3+ ]/[Fe(H2O)6 2+ ]. The solution chemistry of [Fe(CN)6]−3/[Fe(CN)6]−4 redox process was used to study the orientation of the CoPcs-SAMs and this revealed a possible deviation from flat orientation of the complexes on the gold electrodes when the SAM formation times were greater than 24 h. For SAM formation time at 24 and 48 h, CoTDMPc-SAM showed more inhibition of the [Fe(CN)6]−3/[Fe(CN)6]−4 redox process than the CoTBMPc-SAM counterpart, indicating more blocking characteristics of the dodecylmercapto ring substituents compared to the benzylmercapto counterpart. To avoid SAM desorption, the potential application should be limited to −0.2 to +0.8 V vs. Ag∣AgCl (NaCl, sat’d) in acidic and neutral pH.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Westbroek, Philippe , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281414 , vital:55723 , xlink:href="https://doi.org/10.1016/j.elecom.2006.08.047"
- Description: Voltammetric characterisations of cobalt, iron, manganese, nickel and zinc phthalocyanine complexes tetra substituted with benzyl- and dodecyl-mercapto ring substituents and immobilisation on gold electrodes via the self-assembling technique are presented. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, under potential deposition of copper and solution redox chemistry of [Fe(H2O)6 3+ ]/[Fe(H2O)6 2+ ]. The solution chemistry of [Fe(CN)6]−3/[Fe(CN)6]−4 redox process was used to study the orientation of the CoPcs-SAMs and this revealed a possible deviation from flat orientation of the complexes on the gold electrodes when the SAM formation times were greater than 24 h. For SAM formation time at 24 and 48 h, CoTDMPc-SAM showed more inhibition of the [Fe(CN)6]−3/[Fe(CN)6]−4 redox process than the CoTBMPc-SAM counterpart, indicating more blocking characteristics of the dodecylmercapto ring substituents compared to the benzylmercapto counterpart. To avoid SAM desorption, the potential application should be limited to −0.2 to +0.8 V vs. Ag∣AgCl (NaCl, sat’d) in acidic and neutral pH.
- Full Text:
- Date Issued: 2007
Comparative electrooxidation of nitrite by electrodeposited Co (II), Fe (II) and Mn (III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281212 , vital:55702 , xlink:href="https://doi.org/10.1016/j.aca.2007.01.031"
- Description: This work reports on the electrooxidation of nitrite using Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines electrodeposited onto a gold electrode. Good catalytic activity (in terms of lowering overpotential) was obtained for these molecules when compared to previously reported MPc catalysts. The catalytic current was found to vary linearly with nitrite concentration in the range employed in this work (0.1–1 mM) and high sensitivities ranging from 6.9 to 9.9 μA mM−1 were observed for all the modified electrodes.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281212 , vital:55702 , xlink:href="https://doi.org/10.1016/j.aca.2007.01.031"
- Description: This work reports on the electrooxidation of nitrite using Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines electrodeposited onto a gold electrode. Good catalytic activity (in terms of lowering overpotential) was obtained for these molecules when compared to previously reported MPc catalysts. The catalytic current was found to vary linearly with nitrite concentration in the range employed in this work (0.1–1 mM) and high sensitivities ranging from 6.9 to 9.9 μA mM−1 were observed for all the modified electrodes.
- Full Text:
- Date Issued: 2007
Comparative efficiency of immobilized non-transition metal phthalocyanine photosensitizers for the visible light transformation of chlorophenols
- Agboola, Bolade, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/286043 , vital:56233 , xlink:href="https://doi.org/10.1016/j.molcata.2005.12.009"
- Description: Photolysis of aqueous solutions of chlorophenols (4-chlorophenol, 2,4-dichlorophenol, 2,4,5-trichlorophenol and pentachlorophenol) in the presence of immobilized non-transition metal phthalocyanine photosensitizers onto Amberlite® is presented. The photosensitizers studied are: Al (AlOCPc) and Zn (ZnOCPc) octacarboxyphthalocyanines; Al (AlPcS4) and Zn (ZnPcS4) tetrasulfophthalocyanines; sulfonated phthalocyanine complexes (containing mixtures of differently substituted derivatives) of Al (AlPcSmix), Zn (ZnPcSmix), Ge (GePcSmix), Si (SiPcSmix) and Sn (SnPcSmix). Photolysis of the chlorophenols resulted mainly in the formation of chlorobenzoquinone derivatives. The complexes showed order of activity towards the transformation of pentachlorophenol as follows: ZnOCPc > SiPcSmix > SnPcSmix > ZnPcSmix > GePcSmix > ZnPcS4 > AlPcSmix > AlOCPc > AlPcS4. The generation of singlet oxygen (1O2) by these immobilized MPc photosensitizers was found to play a major role in their photoactivities towards the transformation of these chlorophenols. Langmuir–Hinshelwood (L–H) kinetic model studies showed that the ZnOCPc, GePcSmix and ZnPcSmix photocatalysis occurred on the catalysts surface. © 2005 Elsevier B.V. All rights reserved.
- Full Text:
- Date Issued: 2006
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/286043 , vital:56233 , xlink:href="https://doi.org/10.1016/j.molcata.2005.12.009"
- Description: Photolysis of aqueous solutions of chlorophenols (4-chlorophenol, 2,4-dichlorophenol, 2,4,5-trichlorophenol and pentachlorophenol) in the presence of immobilized non-transition metal phthalocyanine photosensitizers onto Amberlite® is presented. The photosensitizers studied are: Al (AlOCPc) and Zn (ZnOCPc) octacarboxyphthalocyanines; Al (AlPcS4) and Zn (ZnPcS4) tetrasulfophthalocyanines; sulfonated phthalocyanine complexes (containing mixtures of differently substituted derivatives) of Al (AlPcSmix), Zn (ZnPcSmix), Ge (GePcSmix), Si (SiPcSmix) and Sn (SnPcSmix). Photolysis of the chlorophenols resulted mainly in the formation of chlorobenzoquinone derivatives. The complexes showed order of activity towards the transformation of pentachlorophenol as follows: ZnOCPc > SiPcSmix > SnPcSmix > ZnPcSmix > GePcSmix > ZnPcS4 > AlPcSmix > AlOCPc > AlPcS4. The generation of singlet oxygen (1O2) by these immobilized MPc photosensitizers was found to play a major role in their photoactivities towards the transformation of these chlorophenols. Langmuir–Hinshelwood (L–H) kinetic model studies showed that the ZnOCPc, GePcSmix and ZnPcSmix photocatalysis occurred on the catalysts surface. © 2005 Elsevier B.V. All rights reserved.
- Full Text:
- Date Issued: 2006
Hydrogen peroxide oxidation of 2-chlorophenol and 2, 4, 5-trichlorophenol catalyzed by monomeric and aggregated cobalt tetrasulfophthalocyanine
- Agboola, Bolade, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289249 , vital:56612 , xlink:href="https://doi.org/10.1016/j.molcata.2004.10.041"
- Description: Cobalt tetrasulfophthalocyanine (CoTSPc) was used to catalyze the oxidation of 2-chlorophenol (2-CP) and 2,4,5-trichlorophenol (TCP) using hydrogen peroxide (H2O2) as the oxidant. This CoTSPc catalyzed hydrogen peroxide oxidation of chlorophenols resulted in the formation of different types of oxidation products depending on the solvent conditions. In water/methanol conditions (where CoTSPc is mainly monomeric, and unionized forms of the phenols), phenol and hydroquinone were the main oxidation products, while in phosphate buffer solutions (pH 7 and 10 for TCP and 2-CP, respectively, where CoTSPc is mainly aggregated, and ionized forms of the phenols), benzoquinone was the main product. In contrast to CoTSPc, other MTSPc complexes studied (AlTSPc, CuTSPc and NiTSPc) exhibited no detectable catalytic effect on the oxidation of chlorophenols under the experimental conditions employed, thus proving the effect of the central metal ions on efficient catalysis of chlorophenol. Reaction pathways are proposed based on the relative time of oxidation products formation.
- Full Text:
- Date Issued: 2005
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289249 , vital:56612 , xlink:href="https://doi.org/10.1016/j.molcata.2004.10.041"
- Description: Cobalt tetrasulfophthalocyanine (CoTSPc) was used to catalyze the oxidation of 2-chlorophenol (2-CP) and 2,4,5-trichlorophenol (TCP) using hydrogen peroxide (H2O2) as the oxidant. This CoTSPc catalyzed hydrogen peroxide oxidation of chlorophenols resulted in the formation of different types of oxidation products depending on the solvent conditions. In water/methanol conditions (where CoTSPc is mainly monomeric, and unionized forms of the phenols), phenol and hydroquinone were the main oxidation products, while in phosphate buffer solutions (pH 7 and 10 for TCP and 2-CP, respectively, where CoTSPc is mainly aggregated, and ionized forms of the phenols), benzoquinone was the main product. In contrast to CoTSPc, other MTSPc complexes studied (AlTSPc, CuTSPc and NiTSPc) exhibited no detectable catalytic effect on the oxidation of chlorophenols under the experimental conditions employed, thus proving the effect of the central metal ions on efficient catalysis of chlorophenol. Reaction pathways are proposed based on the relative time of oxidation products formation.
- Full Text:
- Date Issued: 2005
Comparative electrooxidation of sulphite by self-assembled monolayers (SAMs) of Co (II), Fe (II), Ni (II) and Mn (III) tetrakis benzylmercapto and dodecylmercapto metallophthalocyanines complexes on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281223 , vital:55703 , xlink:href="https://doi.org/10.1016/j.talanta.2006.11.042"
- Description: This work reports on the use of Co(II), Fe(II), Mn(III) and Ni(II) tetrakis benzylmercapto and dodecylmercapto phthalocyanine complexes for gold electrode modification for electrooxidation of sulphite ions. The complexes were successfully used to modify gold electrodes by self-assembled monolayer (SAM) technique. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, underpotential deposition (UPD) of copper and solution redox chemistry of [Fe(H2O)63+]/[Fe(H2O)62+]. All the modified electrodes showed improved catalytic activities than the unmodified gold electrode towards sulphite ion electrooxidation with all the modified electrodes exhibiting high resistance to electrode surface passivation. Better catalytic performance were obtained for the CoPcs, FePcs and MnPcs which have metal based redox processes within the range of the sulphite electrooxidation peak, while the NiPcs which did not show metal based redox reaction performed less. The catalytic current was found to be linear with sulphite ion concentration in the concentration range employed in this work (0.1–1 mM) and sensitivities ranging from 1.68 to 2.96 μA/mM were observed for all the modified electrodes. Mechanisms of the catalytic oxidation of sulphite ions are proposed.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281223 , vital:55703 , xlink:href="https://doi.org/10.1016/j.talanta.2006.11.042"
- Description: This work reports on the use of Co(II), Fe(II), Mn(III) and Ni(II) tetrakis benzylmercapto and dodecylmercapto phthalocyanine complexes for gold electrode modification for electrooxidation of sulphite ions. The complexes were successfully used to modify gold electrodes by self-assembled monolayer (SAM) technique. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, underpotential deposition (UPD) of copper and solution redox chemistry of [Fe(H2O)63+]/[Fe(H2O)62+]. All the modified electrodes showed improved catalytic activities than the unmodified gold electrode towards sulphite ion electrooxidation with all the modified electrodes exhibiting high resistance to electrode surface passivation. Better catalytic performance were obtained for the CoPcs, FePcs and MnPcs which have metal based redox processes within the range of the sulphite electrooxidation peak, while the NiPcs which did not show metal based redox reaction performed less. The catalytic current was found to be linear with sulphite ion concentration in the concentration range employed in this work (0.1–1 mM) and sensitivities ranging from 1.68 to 2.96 μA/mM were observed for all the modified electrodes. Mechanisms of the catalytic oxidation of sulphite ions are proposed.
- Full Text:
- Date Issued: 2007
Synthesis and electrochemical properties of benzyl-mercapto and dodecyl-mercapto tetrasubstituted manganese phthalocyanine complexes
- Agboola, Bolade, Ozoemena, Kenneth I, Westbroek, Philippe, Nyokong, Tebello
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Westbroek, Philippe , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281321 , vital:55713 , xlink:href="https://doi.org/10.1016/j.electacta.2006.09.002"
- Description: Manganese tetrakis (benzyl-mercapto) phthalocyanine (MnTBMPc) and manganese tetrakis (dodecyl-mercapto) phthalocyanine (MnTDMPc) complexes were synthesized and their spectral and electrochemical properties are reported. Cyclic voltammetric data showed three reversible to quasi-reversible and two irreversible redox processes for both complexes. Ring substituents influenced the positions of both oxidation and reduction redox couples. Spectroelectrochemistry confirmed the first two reductions to be due to MnIIIPc2−/MnIIPc2− and MnIIPc3−/MnIIPc2− processes. The first example of a formation of self-assembled monolayers (SAMs) using thiol substituted MnPc complexes is presented, the SAMs were found to show blocking characteristics towards some faradaic reactions.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Ozoemena, Kenneth I , Westbroek, Philippe , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281321 , vital:55713 , xlink:href="https://doi.org/10.1016/j.electacta.2006.09.002"
- Description: Manganese tetrakis (benzyl-mercapto) phthalocyanine (MnTBMPc) and manganese tetrakis (dodecyl-mercapto) phthalocyanine (MnTDMPc) complexes were synthesized and their spectral and electrochemical properties are reported. Cyclic voltammetric data showed three reversible to quasi-reversible and two irreversible redox processes for both complexes. Ring substituents influenced the positions of both oxidation and reduction redox couples. Spectroelectrochemistry confirmed the first two reductions to be due to MnIIIPc2−/MnIIPc2− and MnIIPc3−/MnIIPc2− processes. The first example of a formation of self-assembled monolayers (SAMs) using thiol substituted MnPc complexes is presented, the SAMs were found to show blocking characteristics towards some faradaic reactions.
- Full Text:
- Date Issued: 2007
Electrocatalytic oxidation of chlorophenols by electropolymerised nickel (II) tetrakis benzylmercapto and dodecylmercapto metallophthalocyanines complexes on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281247 , vital:55705 , xlink:href="https://doi.org/10.1016/j.electacta.2007.02.017"
- Description: This work reports on the use of nickel(II) tetrakis benzylmercapto (NiTBMPc) and dodecylmercapto (NiTDMPc) metallophthalocyanine complexes films on gold electrodes for the electrochemical oxidation of 4-chlorophenol (4-CP) and 2,4,5-trichlorophenol (TCP). Both NiTBMPc and NiTDMPc complexes were successfully deposited on gold electrodes by electropolymerisation. The films were electro-transformed in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridged form. For both complexes, films with different thickness were prepared and characterised by electrochemical impedance and UV–vis (on indium tin oxide) spectroscopies and the results showed typical behaviour for modified electrodes with increasing charge transfer resistance values (Rp) with polymer thickness. The poly-Ni(OH)NiPcs showed better catalytic activity than their poly-NiPcs counterparts.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281247 , vital:55705 , xlink:href="https://doi.org/10.1016/j.electacta.2007.02.017"
- Description: This work reports on the use of nickel(II) tetrakis benzylmercapto (NiTBMPc) and dodecylmercapto (NiTDMPc) metallophthalocyanine complexes films on gold electrodes for the electrochemical oxidation of 4-chlorophenol (4-CP) and 2,4,5-trichlorophenol (TCP). Both NiTBMPc and NiTDMPc complexes were successfully deposited on gold electrodes by electropolymerisation. The films were electro-transformed in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridged form. For both complexes, films with different thickness were prepared and characterised by electrochemical impedance and UV–vis (on indium tin oxide) spectroscopies and the results showed typical behaviour for modified electrodes with increasing charge transfer resistance values (Rp) with polymer thickness. The poly-Ni(OH)NiPcs showed better catalytic activity than their poly-NiPcs counterparts.
- Full Text:
- Date Issued: 2007
Tuning the physico-electrochemical properties of novel cobalt (II) octa [(3, 5-biscarboxylate)-phenoxy] phthalocyanine complex using phenylamine-functionalised SWCNTs
- Agboola, Bolade O, Ozoemena, Kenneth I, Nyokong, Tebello, Fukuda, Takamitsu, Kobayashi, Nagao
- Authors: Agboola, Bolade O , Ozoemena, Kenneth I , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261692 , vital:53435 , xlink:href="https://doi.org/10.1016/j.carbon.2009.10.023"
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode.
- Full Text:
- Date Issued: 2010
- Authors: Agboola, Bolade O , Ozoemena, Kenneth I , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261692 , vital:53435 , xlink:href="https://doi.org/10.1016/j.carbon.2009.10.023"
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode.
- Full Text:
- Date Issued: 2010