The development of platinum and palladium-selective polymeric materials
- Authors: Fayemi, Omolola Esther
- Date: 2013 , 2013-05-03
- Subjects: Polymers , Platinum , Palladium , Adsorption , Sorbents , Nanofibers , Amines , Nanoparticles
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4287 , http://hdl.handle.net/10962/d1002964 , Polymers , Platinum , Palladium , Adsorption , Sorbents , Nanofibers , Amines , Nanoparticles
- Description: The adsorption and separation of platinum(IV) and palladium(II) chlorido species (PtCl₆²⁻ and PdCl₄²⁻) on polystyrene-based beads and nanofibers as well as silica microparticles functionalized with polyamine centres derived from ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetriamine (TETA) and tris-(2-aminoethyl)amine (TAEA) is described. The functionalized sorbent materials were characterized by using microanalysis, SEM, XPS, BET and FTIR. The nanofiber sorbent material functionalized with ethylenediamine (F-EDA) had the highest loading capacity which was attributed to its high nitrogen content (10.83%) and larger surface area (241.3m²/g). The adsorption and loading capacities of the sorption materials were investigated using both the batch and column studies in 1 M HCI. The adsorption studies for both PtCl₆²⁻ and PdCl₄²⁻ on the polystyrene-based sorbent materials fit the Langmuir isotherm while the silica-based sorbents fitted the Freundlich isotherm with R² values > 0.99. In the column experiment the highest loading capacity of Pt and Pd were 7.4 mg/g and 4.3 mg/g respectively on the nanofiber sorbent material based on ethylenediamine (EDA). The polystyrene and silica-based resins with triethylenetetramine (TETA) functionality (M-TETA and S-TETA) showed selectivity for platinum and palladium, respectively. Metal chlorido complexes loaded on the sorbent materials were recovered by using 3% m/v thiourea solution as teh eluting agent with quantitative desorption efficiency under the selected experimental conditions. The separation of platinum from palladium was partially achieved by selective stripping of PtCl₆²⁻ with 0.5 M of NaClO₄ in 1.0 M HCI with PdCl₄²⁻ was eluted with 0.5 M thiourea in 1.0 M HCI. The selectivity of the M-TETA and S-TETA sorbent materials was proved by column separation of platinum(IV) and palladium(II), respectively, from synthetic solutions containing iridium(IV) and rhodium(III). The loading capacity for platinum on M-TETA was 0.09 mg/g while it was 0.27 mg/g for palladium on S-TETA. , Acrobat PDFMaker 10.1 for Word , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Authors: Fayemi, Omolola Esther
- Date: 2013 , 2013-05-03
- Subjects: Polymers , Platinum , Palladium , Adsorption , Sorbents , Nanofibers , Amines , Nanoparticles
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4287 , http://hdl.handle.net/10962/d1002964 , Polymers , Platinum , Palladium , Adsorption , Sorbents , Nanofibers , Amines , Nanoparticles
- Description: The adsorption and separation of platinum(IV) and palladium(II) chlorido species (PtCl₆²⁻ and PdCl₄²⁻) on polystyrene-based beads and nanofibers as well as silica microparticles functionalized with polyamine centres derived from ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetriamine (TETA) and tris-(2-aminoethyl)amine (TAEA) is described. The functionalized sorbent materials were characterized by using microanalysis, SEM, XPS, BET and FTIR. The nanofiber sorbent material functionalized with ethylenediamine (F-EDA) had the highest loading capacity which was attributed to its high nitrogen content (10.83%) and larger surface area (241.3m²/g). The adsorption and loading capacities of the sorption materials were investigated using both the batch and column studies in 1 M HCI. The adsorption studies for both PtCl₆²⁻ and PdCl₄²⁻ on the polystyrene-based sorbent materials fit the Langmuir isotherm while the silica-based sorbents fitted the Freundlich isotherm with R² values > 0.99. In the column experiment the highest loading capacity of Pt and Pd were 7.4 mg/g and 4.3 mg/g respectively on the nanofiber sorbent material based on ethylenediamine (EDA). The polystyrene and silica-based resins with triethylenetetramine (TETA) functionality (M-TETA and S-TETA) showed selectivity for platinum and palladium, respectively. Metal chlorido complexes loaded on the sorbent materials were recovered by using 3% m/v thiourea solution as teh eluting agent with quantitative desorption efficiency under the selected experimental conditions. The separation of platinum from palladium was partially achieved by selective stripping of PtCl₆²⁻ with 0.5 M of NaClO₄ in 1.0 M HCI with PdCl₄²⁻ was eluted with 0.5 M thiourea in 1.0 M HCI. The selectivity of the M-TETA and S-TETA sorbent materials was proved by column separation of platinum(IV) and palladium(II), respectively, from synthetic solutions containing iridium(IV) and rhodium(III). The loading capacity for platinum on M-TETA was 0.09 mg/g while it was 0.27 mg/g for palladium on S-TETA. , Acrobat PDFMaker 10.1 for Word , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
Academic freedom and the enclosure of knowledge in the global university
- Authors: Federici, Sylvia
- Date: 2013
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/773 , vital:19989
- Description: A discussion of 'academic freedom' is timely as everywhere, across the planet, this long fought-for principle is under siege. Trends, already emerging in Africa in the 1980s, are extending to every part of the world, contributing to what we can call 'a global enclosure of knowledge. ' This is the restriction of access to education to the 'happy few,' as knowledge and education are becoming commodified and profitability is becoming the sole logic by which the university is structured. Here I examine the most salient ways in which academic freedom is affected by these developments (with special reference to the United States) and, most important, how we can resist them. First, however, I consider what we mean by 'academic freedom,' since it is a concept that has been evolving, taking on new meanings, and is presently used with different connotations.
- Full Text:
- Authors: Federici, Sylvia
- Date: 2013
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/773 , vital:19989
- Description: A discussion of 'academic freedom' is timely as everywhere, across the planet, this long fought-for principle is under siege. Trends, already emerging in Africa in the 1980s, are extending to every part of the world, contributing to what we can call 'a global enclosure of knowledge. ' This is the restriction of access to education to the 'happy few,' as knowledge and education are becoming commodified and profitability is becoming the sole logic by which the university is structured. Here I examine the most salient ways in which academic freedom is affected by these developments (with special reference to the United States) and, most important, how we can resist them. First, however, I consider what we mean by 'academic freedom,' since it is a concept that has been evolving, taking on new meanings, and is presently used with different connotations.
- Full Text:
When does a nation-level analysis make sense? ESD and educational governance in Brazil, South Africa, and the USA
- Feinstein, Noah W, Jacobi, Pedro R, Lotz-Sisitka, Heila
- Authors: Feinstein, Noah W , Jacobi, Pedro R , Lotz-Sisitka, Heila
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/131645 , vital:36707 , http://dx.doi.org/10.1080/13504622.2013.767321
- Description: International policy analysis tends to simplify the nation state, portraying countries as coherent units that can be described by one statistic or placed into one category. As scholars from Brazil, South Africa, and the USA, we find the nation-centric research perspective particularly challenging. In each of our home countries, the effective influence of the national government on education is quite limited, particularly in fringe and emerging areas of education such as Education for Sustainable Development (ESD) and Climate Change Education (CCE). This essay explores how nation-level comparisons are and are not useful for international research on ESD and CCE. We consider several layers of decentralized governance, but ultimately come to the conclusion that ESD governance in our respective countries is polycentric rather than decentralized. We discuss the implications of this idea for cross-national policy research on ESD and CCE.
- Full Text:
- Authors: Feinstein, Noah W , Jacobi, Pedro R , Lotz-Sisitka, Heila
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/131645 , vital:36707 , http://dx.doi.org/10.1080/13504622.2013.767321
- Description: International policy analysis tends to simplify the nation state, portraying countries as coherent units that can be described by one statistic or placed into one category. As scholars from Brazil, South Africa, and the USA, we find the nation-centric research perspective particularly challenging. In each of our home countries, the effective influence of the national government on education is quite limited, particularly in fringe and emerging areas of education such as Education for Sustainable Development (ESD) and Climate Change Education (CCE). This essay explores how nation-level comparisons are and are not useful for international research on ESD and CCE. We consider several layers of decentralized governance, but ultimately come to the conclusion that ESD governance in our respective countries is polycentric rather than decentralized. We discuss the implications of this idea for cross-national policy research on ESD and CCE.
- Full Text:
The restoration of an alien-invaded riparian zone in grassy fynbos, South Africa
- Authors: Fourie, Saskia
- Date: 2013
- Subjects: Fynbos ecology -- South Africa Riparian ecology -- South Africa Riparian restoration -- South Africa Alien plants -- South Africa Invasive plants -- South Africa Endemic plants -- South Africa Plants -- Effect of fires on -- South Africa Soil seed banks -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4733 , http://hdl.handle.net/10962/d1003840
- Description: The most recent surveys in South Africa estimate that invasions are still increasing, despite substantial clearing efforts. Riparian systems in South Africa are particularly vulnerable to invasion by woody IAPs. This thesis addresses the restoration of alien‐invaded riparian systems, by investigating the factors that facilitate or constrain spontaneous recovery and influence the trajectories of succession. These factors include invasion history and management history, especially the use of fire. A seedling emergence approach was used to test the presence of a viable pre‐fire seedbank, and the effect of fire on the seed bank. The efficacy of some active restoration interventions was also tested, with the aim to return invasion‐resistant, indigenous vegetation with a structure and function representative of uninvaded sites. The findings of this study indicated the presence of a viable and persistent riparian soil seed bank, even after 30 years of intermtittent invasion as well as two fire cycles under invasion. It shows that the management practice of fell‐and‐burn resulted in high soil temperatures, and that this reduced the indigenous soil seed bank density, especially in the upper soil layer. Clear germination sequences and patterns of emergence over time for different species were observed during this study, with many species exhibiting delayed emergence relative to the timing of the fire event. It is proposed that manipulation of the season of fire could be used to selectively optimise the order of arrival and therefore superior recruitment of some species over others in the Eastern Cape fynbos, and thus alter the trajectories of recovery of vegetation towards a more desired state. Active restoration in the form of indigenous seed and plant additions resulted in a significantly higher indigenous cover after seven months, compared to a control (passive restoration) or restoring with grass. Indigenous cover and composition was also strongly influenced by lateral zonation, and some key guilds and species were missing or present in much lower densities compared to reference sites. Grass restoration significantly suppressed the regeneration of A. longifolia, as well as the regeneration of indigenous species. Biotic resistance can thus be achieved through restoration, and it could be a powerful tool in the management of IAPs, although the deliberate introduction of grass after clearing in fynbos also reduces biodiversity and could have unforeseen consequences to riparian function.
- Full Text:
- Authors: Fourie, Saskia
- Date: 2013
- Subjects: Fynbos ecology -- South Africa Riparian ecology -- South Africa Riparian restoration -- South Africa Alien plants -- South Africa Invasive plants -- South Africa Endemic plants -- South Africa Plants -- Effect of fires on -- South Africa Soil seed banks -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4733 , http://hdl.handle.net/10962/d1003840
- Description: The most recent surveys in South Africa estimate that invasions are still increasing, despite substantial clearing efforts. Riparian systems in South Africa are particularly vulnerable to invasion by woody IAPs. This thesis addresses the restoration of alien‐invaded riparian systems, by investigating the factors that facilitate or constrain spontaneous recovery and influence the trajectories of succession. These factors include invasion history and management history, especially the use of fire. A seedling emergence approach was used to test the presence of a viable pre‐fire seedbank, and the effect of fire on the seed bank. The efficacy of some active restoration interventions was also tested, with the aim to return invasion‐resistant, indigenous vegetation with a structure and function representative of uninvaded sites. The findings of this study indicated the presence of a viable and persistent riparian soil seed bank, even after 30 years of intermtittent invasion as well as two fire cycles under invasion. It shows that the management practice of fell‐and‐burn resulted in high soil temperatures, and that this reduced the indigenous soil seed bank density, especially in the upper soil layer. Clear germination sequences and patterns of emergence over time for different species were observed during this study, with many species exhibiting delayed emergence relative to the timing of the fire event. It is proposed that manipulation of the season of fire could be used to selectively optimise the order of arrival and therefore superior recruitment of some species over others in the Eastern Cape fynbos, and thus alter the trajectories of recovery of vegetation towards a more desired state. Active restoration in the form of indigenous seed and plant additions resulted in a significantly higher indigenous cover after seven months, compared to a control (passive restoration) or restoring with grass. Indigenous cover and composition was also strongly influenced by lateral zonation, and some key guilds and species were missing or present in much lower densities compared to reference sites. Grass restoration significantly suppressed the regeneration of A. longifolia, as well as the regeneration of indigenous species. Biotic resistance can thus be achieved through restoration, and it could be a powerful tool in the management of IAPs, although the deliberate introduction of grass after clearing in fynbos also reduces biodiversity and could have unforeseen consequences to riparian function.
- Full Text:
Extreme weather events in the Sneeuberg, Karoo, South Africa: a case study of the floods of 9 and 12 February 2011
- Fox, Roddy C, Rowntree, Kate M
- Authors: Fox, Roddy C , Rowntree, Kate M
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6672 , http://hdl.handle.net/10962/d1004468
- Description: Two destructive flood events occurred in rapid succession in the semi-arid Sneeuberg Mountains of the Karoo, South Africa in February 2011. The temporal and spatial characteristics of these two extreme events are examined in this paper through analysis of data from an unusually dense, and reliable, network of farm rain gauges. These analyses add to our understanding derived from existing rain gauge information. Comparisons are then made with patterns from a range of modeled products derived from remote sensed information: the Modern-Era Retrospective Analysis for Research and Applications (MERRA), the Tropical Rainfall Measuring Mission (TRMM) and the Global Land Data Assimilation System (GLDAS). We found that the first flood event was widespread and precipitation was related strongly to altitude. The second was highly localised, with no relationship to altitude. Both had very sharply peaked rainfall intensities. These findings are of significance to the studies of flooding and landscape change in the area as such events have become more pronounced over the past 50 yr and it is likely that this trend will accelerate. The modeled patterns are derived largely from remote sensing and we found that they are reliable for drawing out monthly and annual variations but they make noticeable underestimates. They are poor estimates, however, both for the spatial distribution of precipitation, and the short term trends as they struggle to estimate the impact of topography and other local forcing factors. This finding corroborates information derived from other analyses at broader spatial scales using more widely spread, established rain gauge stations. Ten percent of southern Africa has been classified as mountainous and these areas provide much of our water resources so our findings are significant to water managers throughout this and similar mountainous regions.
- Full Text:
- Authors: Fox, Roddy C , Rowntree, Kate M
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6672 , http://hdl.handle.net/10962/d1004468
- Description: Two destructive flood events occurred in rapid succession in the semi-arid Sneeuberg Mountains of the Karoo, South Africa in February 2011. The temporal and spatial characteristics of these two extreme events are examined in this paper through analysis of data from an unusually dense, and reliable, network of farm rain gauges. These analyses add to our understanding derived from existing rain gauge information. Comparisons are then made with patterns from a range of modeled products derived from remote sensed information: the Modern-Era Retrospective Analysis for Research and Applications (MERRA), the Tropical Rainfall Measuring Mission (TRMM) and the Global Land Data Assimilation System (GLDAS). We found that the first flood event was widespread and precipitation was related strongly to altitude. The second was highly localised, with no relationship to altitude. Both had very sharply peaked rainfall intensities. These findings are of significance to the studies of flooding and landscape change in the area as such events have become more pronounced over the past 50 yr and it is likely that this trend will accelerate. The modeled patterns are derived largely from remote sensing and we found that they are reliable for drawing out monthly and annual variations but they make noticeable underestimates. They are poor estimates, however, both for the spatial distribution of precipitation, and the short term trends as they struggle to estimate the impact of topography and other local forcing factors. This finding corroborates information derived from other analyses at broader spatial scales using more widely spread, established rain gauge stations. Ten percent of southern Africa has been classified as mountainous and these areas provide much of our water resources so our findings are significant to water managers throughout this and similar mountainous regions.
- Full Text:
Perceived usefulness of agricultural information sought on-line and broadcast in rural Mozambique: a case study of two Community Multimedia Centres (CMCs)
- Authors: Fuel, Isaias Carlos
- Date: 2013
- Subjects: Radio in community development -- Mozambique Radio broadcasting -- Mozambique Radio stations -- Mozambique Digital media -- Mozambique Rural development -- Mozambique Agriculture -- Mozambique
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3505 , http://hdl.handle.net/10962/d1007240
- Description: The wealth of information available on the Internet holds the potential to aid development in Africa. In order to be effective, such information needs to be contextualised to respond to local needs and practices. The combination of old and new media can support uptake and improve acceptance of new technologies in developing countries. The purpose of this qualitative study was to investigate the perceived usefulness of agricultural information sought on-line and broadcast via community radio in the two Community Multimedia Centres (CMCs) of Namaacha and Murrombene, in rural Mozambique. The data was generated from focus group discussion, individual interview, document analysis, and observation involving farmers and radio presenters. The study has shown that on-line agricultural information responds to the needs of the farmers because it contributes to eliminate pests and help farmers to make decisions about their activities. The study has also shown that there is a communication gap between farmers, extension workers, and volunteer reporters working at the community radios of the two CMCs. Volunteers have no agricultural knowledge. The problem this creates manifests itself primarily when they try to translate on-line agricultural information from Portuguese into local languages. Farmers have difficulties expressing their problems. Extension workers are not available to act as experts and mediators between volunteers and farmers. A collaborative website focusing on locally relevant content was suggested as a possible improvement.
- Full Text:
- Authors: Fuel, Isaias Carlos
- Date: 2013
- Subjects: Radio in community development -- Mozambique Radio broadcasting -- Mozambique Radio stations -- Mozambique Digital media -- Mozambique Rural development -- Mozambique Agriculture -- Mozambique
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3505 , http://hdl.handle.net/10962/d1007240
- Description: The wealth of information available on the Internet holds the potential to aid development in Africa. In order to be effective, such information needs to be contextualised to respond to local needs and practices. The combination of old and new media can support uptake and improve acceptance of new technologies in developing countries. The purpose of this qualitative study was to investigate the perceived usefulness of agricultural information sought on-line and broadcast via community radio in the two Community Multimedia Centres (CMCs) of Namaacha and Murrombene, in rural Mozambique. The data was generated from focus group discussion, individual interview, document analysis, and observation involving farmers and radio presenters. The study has shown that on-line agricultural information responds to the needs of the farmers because it contributes to eliminate pests and help farmers to make decisions about their activities. The study has also shown that there is a communication gap between farmers, extension workers, and volunteer reporters working at the community radios of the two CMCs. Volunteers have no agricultural knowledge. The problem this creates manifests itself primarily when they try to translate on-line agricultural information from Portuguese into local languages. Farmers have difficulties expressing their problems. Extension workers are not available to act as experts and mediators between volunteers and farmers. A collaborative website focusing on locally relevant content was suggested as a possible improvement.
- Full Text:
Impact of insecticides on the reproductive potential of false codling moth, Thaumatotibia leucotreta (Meyrick, 1913)(Lepidoptera: Tortricidae)
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
Exploring the possibility of an Ubuntu-based political philosophy
- Authors: Furman, Katherine Elizabeth
- Date: 2013
- Subjects: Ubuntu , Political philosophy , Ethical theories , Law , South Africa , Ubuntu (Philosophy) -- Research -- South Africa , Political science -- Philosophy -- Research , Philosophy, African -- Research , Social values -- Research South Africa , Ethics -- Research -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:2756 , http://hdl.handle.net/10962/d1002003
- Description: It is typically said that there are two questions that political philosophy seeks to address: ‘who gets what?’ and ‘who decides on who gets what?’ South Africa, along with much of the rest of the world, has answered the second question badly and currently ranks as one of the world’s most unequal societies. Counter-intuitively, South Africa maintains a social-political order that (re)produces this inequality along with great enthusiasm for ubuntu, an African ethic that at a minimum requires that we treat each other humanely. However, due to the view that ubuntu has been co-opted in support of South Africa’s unjust system, ubuntu has largely been ignored by radical thinkers. The aim of this thesis is therefore to explore the possibility of an ubuntu-based political philosophy, with the core assumption that political philosophy is rooted in ethical theory. Three tasks are therefore undertaken in this thesis. Firstly, ubuntu is articulated as an ethic. Secondly, it is compared to similar Western ethical theories in order to determine if there are distinguishing characteristics that make ubuntu a more appropriate founding ethic for South African political philosophy. Finally, whether ubuntu can find real-world applicability will be assessed by looking at the way ubuntu has been used in the law
- Full Text:
- Authors: Furman, Katherine Elizabeth
- Date: 2013
- Subjects: Ubuntu , Political philosophy , Ethical theories , Law , South Africa , Ubuntu (Philosophy) -- Research -- South Africa , Political science -- Philosophy -- Research , Philosophy, African -- Research , Social values -- Research South Africa , Ethics -- Research -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:2756 , http://hdl.handle.net/10962/d1002003
- Description: It is typically said that there are two questions that political philosophy seeks to address: ‘who gets what?’ and ‘who decides on who gets what?’ South Africa, along with much of the rest of the world, has answered the second question badly and currently ranks as one of the world’s most unequal societies. Counter-intuitively, South Africa maintains a social-political order that (re)produces this inequality along with great enthusiasm for ubuntu, an African ethic that at a minimum requires that we treat each other humanely. However, due to the view that ubuntu has been co-opted in support of South Africa’s unjust system, ubuntu has largely been ignored by radical thinkers. The aim of this thesis is therefore to explore the possibility of an ubuntu-based political philosophy, with the core assumption that political philosophy is rooted in ethical theory. Three tasks are therefore undertaken in this thesis. Firstly, ubuntu is articulated as an ethic. Secondly, it is compared to similar Western ethical theories in order to determine if there are distinguishing characteristics that make ubuntu a more appropriate founding ethic for South African political philosophy. Finally, whether ubuntu can find real-world applicability will be assessed by looking at the way ubuntu has been used in the law
- Full Text:
Editorial:
- Authors: Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158840 , vital:40233 , https://hdl.handle.net/10520/EJC141608
- Description: If you've been a Rhodes Journalism Review reader for a while, you'll be surprised by the smaller magazine you are holding in your hands right now. RJR started off life as an A4 but has been big since no 9, December 1994, and the size I inherited when I started as editor in 1997. It's a format I've always loved; it stands (er, stood) out among the wash of pamphlets at international conferences, it gave designers and photographers a fantastic sweep of canvas, and it was distinctive in the world of magazines, a true original.
- Full Text:
- Authors: Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158840 , vital:40233 , https://hdl.handle.net/10520/EJC141608
- Description: If you've been a Rhodes Journalism Review reader for a while, you'll be surprised by the smaller magazine you are holding in your hands right now. RJR started off life as an A4 but has been big since no 9, December 1994, and the size I inherited when I started as editor in 1997. It's a format I've always loved; it stands (er, stood) out among the wash of pamphlets at international conferences, it gave designers and photographers a fantastic sweep of canvas, and it was distinctive in the world of magazines, a true original.
- Full Text:
Editorial:
- Authors: Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158851 , vital:40234 , https://hdl.handle.net/10520/EJC141608
- Description: If you've been a Rhodes Journalism Review reader for a while, you'll be surprised by the smaller magazine you are holding in your hands right now. RJR started off life as an A4 but has been big since no 9, December 1994, and the size I inherited when I started as editor in 1997. It's a format I've always loved; it stands (er, stood) out among the wash of pamphlets at international conferences, it gave designers and photographers a fantastic sweep of canvas, and it was distinctive in the world of magazines, a true original.
- Full Text:
- Authors: Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158851 , vital:40234 , https://hdl.handle.net/10520/EJC141608
- Description: If you've been a Rhodes Journalism Review reader for a while, you'll be surprised by the smaller magazine you are holding in your hands right now. RJR started off life as an A4 but has been big since no 9, December 1994, and the size I inherited when I started as editor in 1997. It's a format I've always loved; it stands (er, stood) out among the wash of pamphlets at international conferences, it gave designers and photographers a fantastic sweep of canvas, and it was distinctive in the world of magazines, a true original.
- Full Text:
The new Africans: a textual analysis of the construction of 'African-ness' in Chaz Maviyane-Davies' 1996 poster depictions of the Universal Declaration of Human Rights
- Authors: Garman, Brian Donald
- Date: 2013
- Subjects: Human rights , Posters , African perspective , Stereotypes , Black men , Maviyane-Davies, Chaz -- Criticism and interpretation , Universal Declaration of Human Rights -- Posters -- Research , Ethnicity -- Research -- Africa , Human rights -- Africa , Pan-Africanism
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3413 , http://hdl.handle.net/10962/d1001844
- Description: In 1996, Zimbabwean graphic designer Chaz Maviyane-Davies created a set of human rights posters which represent several articles of the Universal Declaration of Human Rights, from what he calls an “African perspective”. In this study I investigate how Maviyane-Davies has constructed ‘African-ness’ and probe what he refers to as the “alternative aesthetic” that he is trying to create. I use a visual social semiotic approach to examine the discourses he draws on to re-image and re-imagine Africa and Africans in a manner that contests the stereotypical representations found in political, news and economic discourses about Africa, paying particular attention to the ways he uses images of the body. My analysis of the posters shows how complex and difficult it can be to contest regimes of representation that work to fix racialised and derogatory meanings. In response to the pejorative stereotypes of the black body, Maviyane-Davies uses images of strong, healthy, and magnificent people (mostly men) to construct a more affirmative representation of Africa and Africans. Significantly, he draws on sports, touristic, traditional and hegemonic discourses of masculinity in an attempt to expand the complexity and range of possible representations of African-ness. In so doing he runs the risk of reproducing many of the stereotypes that sustain not only the racialised and gendered (masculinist) representations of Africa, but also a sentimentalisation and romanticisation of a place, a people and their traditions. Apart from women in prominent positions, other conspicuous absences from these images include white people and hegemonic references to Western modernity. I do not believe he is discarding whites and modernity as un-African, but is rejecting the naturalisation of whiteness as standing in for humanity, and particular icons of Western modernity as significations of ‘modernity’ itself
- Full Text:
- Authors: Garman, Brian Donald
- Date: 2013
- Subjects: Human rights , Posters , African perspective , Stereotypes , Black men , Maviyane-Davies, Chaz -- Criticism and interpretation , Universal Declaration of Human Rights -- Posters -- Research , Ethnicity -- Research -- Africa , Human rights -- Africa , Pan-Africanism
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3413 , http://hdl.handle.net/10962/d1001844
- Description: In 1996, Zimbabwean graphic designer Chaz Maviyane-Davies created a set of human rights posters which represent several articles of the Universal Declaration of Human Rights, from what he calls an “African perspective”. In this study I investigate how Maviyane-Davies has constructed ‘African-ness’ and probe what he refers to as the “alternative aesthetic” that he is trying to create. I use a visual social semiotic approach to examine the discourses he draws on to re-image and re-imagine Africa and Africans in a manner that contests the stereotypical representations found in political, news and economic discourses about Africa, paying particular attention to the ways he uses images of the body. My analysis of the posters shows how complex and difficult it can be to contest regimes of representation that work to fix racialised and derogatory meanings. In response to the pejorative stereotypes of the black body, Maviyane-Davies uses images of strong, healthy, and magnificent people (mostly men) to construct a more affirmative representation of Africa and Africans. Significantly, he draws on sports, touristic, traditional and hegemonic discourses of masculinity in an attempt to expand the complexity and range of possible representations of African-ness. In so doing he runs the risk of reproducing many of the stereotypes that sustain not only the racialised and gendered (masculinist) representations of Africa, but also a sentimentalisation and romanticisation of a place, a people and their traditions. Apart from women in prominent positions, other conspicuous absences from these images include white people and hegemonic references to Western modernity. I do not believe he is discarding whites and modernity as un-African, but is rejecting the naturalisation of whiteness as standing in for humanity, and particular icons of Western modernity as significations of ‘modernity’ itself
- Full Text:
Who knew
- Authors: Gaunt, Hailey Kathryn
- Date: 2013
- Subjects: Poetry , Memory , Nature , Marriage , Faith , Death , Meaning , English language -- Writing , South African poetry (English) -- 21st century , Creative writing (Higher education)
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:5962 , http://hdl.handle.net/10962/d1001812
- Description: This book of poems ranges in style from narrative to condensed lyric moment, and shifts in perspective from observation to introspection. Thematically, these poems explore everyday life through its many manifestations – memory, nature, marriage, faith and death – with an emphasis on finding meaning in absolutely ordinary things. Though their tone is often vulnerable and tender, even when it is more distant the poems are always searching.
- Full Text:
- Authors: Gaunt, Hailey Kathryn
- Date: 2013
- Subjects: Poetry , Memory , Nature , Marriage , Faith , Death , Meaning , English language -- Writing , South African poetry (English) -- 21st century , Creative writing (Higher education)
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:5962 , http://hdl.handle.net/10962/d1001812
- Description: This book of poems ranges in style from narrative to condensed lyric moment, and shifts in perspective from observation to introspection. Thematically, these poems explore everyday life through its many manifestations – memory, nature, marriage, faith and death – with an emphasis on finding meaning in absolutely ordinary things. Though their tone is often vulnerable and tender, even when it is more distant the poems are always searching.
- Full Text:
'Leaders like children playing with a grenade?' : an analysis of how the Arab Spring was received in South Africa
- Authors: Gevers, Tristan Ronald
- Date: 2013
- Subjects: Arab Spring, 2010- Revolutions -- Theory Arab countries -- Social conditions -- 21st century South Africa -- Social condtions -- 21st century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2846 , http://hdl.handle.net/10962/d1006031
- Description: When the Arab Spring took place, it took the world by surprise and sparked renewed interest in the idea of revolution. With differing opinions on what caused such a revolutionary wave throughout the North African and Middle Eastern region, many began looking at their own countries, and South Africa was no different. A debate was sparked in South Africa, as to whether there would be a revolution or not. What I originally set out to accomplish is to find out which side of the debate would be correct through the philosophical context of revolutionary theory. Initially, we attempted to define and consider the history of revolutionary theory. We found that revolutionary theory has gone through four generation and that even finding a theoretically informed definition is difficult. Following this, we considered some social-psychological theories of revolution as well as theories of moral indignation. We found that these theories were incredibly informative and that they provide some insight into the reasoning for revolutionary fear in the South African debate. Through the use of opinion pieces, we then considered the South African debate, and – using socialpsychological theories and the theories of moral indignation - found that both sides of the argument had valuable points, however, they often lacked some foresight. With tentative agreement, we found that the side arguing that there would a revolution in South Africa had a more valuable argument, despite its limitations. However, far more research is required before one can – with more accuracy – predict a revolutionary occurrence in such a way as was done in South Africa.
- Full Text:
- Authors: Gevers, Tristan Ronald
- Date: 2013
- Subjects: Arab Spring, 2010- Revolutions -- Theory Arab countries -- Social conditions -- 21st century South Africa -- Social condtions -- 21st century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2846 , http://hdl.handle.net/10962/d1006031
- Description: When the Arab Spring took place, it took the world by surprise and sparked renewed interest in the idea of revolution. With differing opinions on what caused such a revolutionary wave throughout the North African and Middle Eastern region, many began looking at their own countries, and South Africa was no different. A debate was sparked in South Africa, as to whether there would be a revolution or not. What I originally set out to accomplish is to find out which side of the debate would be correct through the philosophical context of revolutionary theory. Initially, we attempted to define and consider the history of revolutionary theory. We found that revolutionary theory has gone through four generation and that even finding a theoretically informed definition is difficult. Following this, we considered some social-psychological theories of revolution as well as theories of moral indignation. We found that these theories were incredibly informative and that they provide some insight into the reasoning for revolutionary fear in the South African debate. Through the use of opinion pieces, we then considered the South African debate, and – using socialpsychological theories and the theories of moral indignation - found that both sides of the argument had valuable points, however, they often lacked some foresight. With tentative agreement, we found that the side arguing that there would a revolution in South Africa had a more valuable argument, despite its limitations. However, far more research is required before one can – with more accuracy – predict a revolutionary occurrence in such a way as was done in South Africa.
- Full Text:
The implementation of a service-learning component in an organic chemistry laboratory course
- Glover, Sarah R, Sewry, Joyce D, Bromley, Candice L, Davies-Coleman, Michael T, Hlengwa, Amanda I
- Authors: Glover, Sarah R , Sewry, Joyce D , Bromley, Candice L , Davies-Coleman, Michael T , Hlengwa, Amanda I
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70699 , vital:29690 , https://doi.org/10.1021/ed2008153
- Description: Education institutions globally are increasingly expected to explore avenues for the implementation of service-learning into their curricula. A second-year undergraduate organic chemistry laboratory experiment, in which the undergraduate students make azo dyes, can provide a vehicle for a service-learning module in which university undergraduate students then teach students from resource-limited secondary schools how to make azo dyes. Evidence is provided to show how the theory is reinforced for both sets of students through a shared practical experience. The practical application of chemistry is conveyed through the use of the synthetic azo dyes to dye tshirts. The results of this study show that the service-learning experience clearly assists undergraduate students to appreciate the role of chemists in the broader society while at the same time increasing awareness of the inequalities in school education systems.
- Full Text:
- Authors: Glover, Sarah R , Sewry, Joyce D , Bromley, Candice L , Davies-Coleman, Michael T , Hlengwa, Amanda I
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70699 , vital:29690 , https://doi.org/10.1021/ed2008153
- Description: Education institutions globally are increasingly expected to explore avenues for the implementation of service-learning into their curricula. A second-year undergraduate organic chemistry laboratory experiment, in which the undergraduate students make azo dyes, can provide a vehicle for a service-learning module in which university undergraduate students then teach students from resource-limited secondary schools how to make azo dyes. Evidence is provided to show how the theory is reinforced for both sets of students through a shared practical experience. The practical application of chemistry is conveyed through the use of the synthetic azo dyes to dye tshirts. The results of this study show that the service-learning experience clearly assists undergraduate students to appreciate the role of chemists in the broader society while at the same time increasing awareness of the inequalities in school education systems.
- Full Text:
The impact of low to moderate alcohol consumption on different types of human performance
- Authors: Goble, David
- Date: 2013
- Subjects: Alcohol -- Physiological effect Temperance Human information processing -- Effect of drugs on Visual perception -- Effect of drugs on Cognition -- Effect of drugs on Caffeine -- Physiological effect
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5136 , http://hdl.handle.net/10962/d1006042
- Description: Despite extensive research into the effects of alcohol consumption, there is no clear understanding into the mechanisms underlying human information processing impairment. The acute consumption of alcohol was investigated to determine the implications for human information processing capabilities, and to identify the extent to which these implications were stage-specific. Further aims included the investigation and quantification of caffeine-induced antagonism of alcohol impairment. Moreover, the aforementioned relationships were investigated in morning versus evening conditions. A test battery of six resource-specific tasks was utilised to measure visual perceptual, cognitive and sensory-motor performance, fashioned to return both simple and complex measures of each task. The tasks implemented were: visual perceptual performance (accommodation, visual detection, visual pattern recognition); cognition (memory recall- digit span); and motor output (modified Fitts‟ and a driving simulated line-tracking). Performance measures were recorded by the respective computer based tasks. Physiological variables measured included heart rate frequency, heart rate variability (RMSSD, High and Low Frequency Power) and body temperature. Saccade speed, saccade amplitude, pupil size and fixation duration were the oculomotor parameters measured. Three groups of participants (alcohol, caffeine+alcohol and control) n=36 were studied, split evenly between sexes in a mixed repeated/non-repeated measures design. The control group performed all test batteries under no influence. The alcohol group performed test batteries one and two sober, and three and four under the influence of a 0.4 g/kg dose of alcohol. Group caffeine+alcohol conducted test battery one sober, two under the effect of caffeine only (4 mg/kg), and three and four under the influence of both caffeine and alcohol (0.4 g/kg). The third test battery demonstrated the effects of alcohol during the inclining phase of the blood alcohol curve, and the fourth represented the declining phase. Morning experimentation occurred between 10:00 - 12: 45 and 10:30 -13:15 with evening experimentation between 19:00 - 21:30 and 19:30 - 22:00. Acute alcohol consumption at a dose of approximately 0.4 g/kg body weight effected an average peak breath alcohol concentration of 0.062 % and 0.059 % for the alcohol and caffeine+alcohol groups respectively. Task-related visual perceptual performance demonstrated significant decrements for simple reaction time, choice reaction time and error rate. Cognitive performance demonstrated no significant performance decrements, while motor performance indicated significant decrements in target accuracy only. Physiological parameters in response to alcohol consumption showed significantly decreased heart rate variability (RMSSD) in the modified Fitts‟ task only. A significant decrease in saccade amplitude in the memory task was the only change in oculomotor parameters. Prior caffeine consumption demonstrated limited antagonism to task-related alcohol impairment, significantly improving performance only in reduced error rate while reading. Caffeine consumption showed stimulating effects on physiological parameters, significantly increasing heart rate and heart rate variability when compared to alcohol alone. The design of the tasks allows for comparison between complex and simple task performance, indicating resource utilisation and depletion. Complex tasks demonstrated higher resource utilisation, however with no statistical performance differences to simple tasks. Physiological parameters showed greater change in response to alcohol consumption, than did the performance measures. Alcohol consumption imposed significant changes in physiological and oculomotor parameters for cognitive tasks only, significantly increasing heart rate frequency and decreasing heart rate variability, skin temperature and saccade amplitude. Caffeine consumption showed no antagonism of alcohol-induced performance measures. Physiological measures showed that caffeine consumption imposed stimulating effects in only the neural reflex and memory tasks, significantly increasing heart rate frequency and heart rate variability. Prior caffeine consumption significantly decreased fixation duration in the memory task only. The time of day at which alcohol was consumed demonstrated significant performance and physiological implications. Results indicated that morning consumption of alcohol imposes greater decrements in performance and larger fluctuations in physiological parameters than the decrements in evening experimental sessions. It can be concluded that alcohol consumption at a dose of 0.4 g/kg affects all stages in the information processing chain. Task performance indicates that alcohol has a greater severity on the early stages of information processing. Conversely, under the influence of alcohol an increased task complexity induces greater effects on central stage information processing. In addition, caffeine consumption at a dose of 4 mg/kg prior to alcohol does not antagonise the alcohol-induced performance decrements.
- Full Text:
- Authors: Goble, David
- Date: 2013
- Subjects: Alcohol -- Physiological effect Temperance Human information processing -- Effect of drugs on Visual perception -- Effect of drugs on Cognition -- Effect of drugs on Caffeine -- Physiological effect
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5136 , http://hdl.handle.net/10962/d1006042
- Description: Despite extensive research into the effects of alcohol consumption, there is no clear understanding into the mechanisms underlying human information processing impairment. The acute consumption of alcohol was investigated to determine the implications for human information processing capabilities, and to identify the extent to which these implications were stage-specific. Further aims included the investigation and quantification of caffeine-induced antagonism of alcohol impairment. Moreover, the aforementioned relationships were investigated in morning versus evening conditions. A test battery of six resource-specific tasks was utilised to measure visual perceptual, cognitive and sensory-motor performance, fashioned to return both simple and complex measures of each task. The tasks implemented were: visual perceptual performance (accommodation, visual detection, visual pattern recognition); cognition (memory recall- digit span); and motor output (modified Fitts‟ and a driving simulated line-tracking). Performance measures were recorded by the respective computer based tasks. Physiological variables measured included heart rate frequency, heart rate variability (RMSSD, High and Low Frequency Power) and body temperature. Saccade speed, saccade amplitude, pupil size and fixation duration were the oculomotor parameters measured. Three groups of participants (alcohol, caffeine+alcohol and control) n=36 were studied, split evenly between sexes in a mixed repeated/non-repeated measures design. The control group performed all test batteries under no influence. The alcohol group performed test batteries one and two sober, and three and four under the influence of a 0.4 g/kg dose of alcohol. Group caffeine+alcohol conducted test battery one sober, two under the effect of caffeine only (4 mg/kg), and three and four under the influence of both caffeine and alcohol (0.4 g/kg). The third test battery demonstrated the effects of alcohol during the inclining phase of the blood alcohol curve, and the fourth represented the declining phase. Morning experimentation occurred between 10:00 - 12: 45 and 10:30 -13:15 with evening experimentation between 19:00 - 21:30 and 19:30 - 22:00. Acute alcohol consumption at a dose of approximately 0.4 g/kg body weight effected an average peak breath alcohol concentration of 0.062 % and 0.059 % for the alcohol and caffeine+alcohol groups respectively. Task-related visual perceptual performance demonstrated significant decrements for simple reaction time, choice reaction time and error rate. Cognitive performance demonstrated no significant performance decrements, while motor performance indicated significant decrements in target accuracy only. Physiological parameters in response to alcohol consumption showed significantly decreased heart rate variability (RMSSD) in the modified Fitts‟ task only. A significant decrease in saccade amplitude in the memory task was the only change in oculomotor parameters. Prior caffeine consumption demonstrated limited antagonism to task-related alcohol impairment, significantly improving performance only in reduced error rate while reading. Caffeine consumption showed stimulating effects on physiological parameters, significantly increasing heart rate and heart rate variability when compared to alcohol alone. The design of the tasks allows for comparison between complex and simple task performance, indicating resource utilisation and depletion. Complex tasks demonstrated higher resource utilisation, however with no statistical performance differences to simple tasks. Physiological parameters showed greater change in response to alcohol consumption, than did the performance measures. Alcohol consumption imposed significant changes in physiological and oculomotor parameters for cognitive tasks only, significantly increasing heart rate frequency and decreasing heart rate variability, skin temperature and saccade amplitude. Caffeine consumption showed no antagonism of alcohol-induced performance measures. Physiological measures showed that caffeine consumption imposed stimulating effects in only the neural reflex and memory tasks, significantly increasing heart rate frequency and heart rate variability. Prior caffeine consumption significantly decreased fixation duration in the memory task only. The time of day at which alcohol was consumed demonstrated significant performance and physiological implications. Results indicated that morning consumption of alcohol imposes greater decrements in performance and larger fluctuations in physiological parameters than the decrements in evening experimental sessions. It can be concluded that alcohol consumption at a dose of 0.4 g/kg affects all stages in the information processing chain. Task performance indicates that alcohol has a greater severity on the early stages of information processing. Conversely, under the influence of alcohol an increased task complexity induces greater effects on central stage information processing. In addition, caffeine consumption at a dose of 4 mg/kg prior to alcohol does not antagonise the alcohol-induced performance decrements.
- Full Text:
Towards the development of a mycoinsecticide to control white grubs (Coleoptera: Scarabaeidae) in South African sugarcane
- Authors: Goble, Tarryn Anne
- Date: 2013
- Subjects: Insecticides -- Environmental aspects Insecticides -- Toxicology Beetles -- South Africa -- KwaZulu-Natal Beetles -- Control -- South Africa -- KwaZulu-Natal Coleophoridae -- South Africa -- KwaZulu-Natal Scarabaeidae -- South Africa -- KwaZulu-Natal Sugarcane -- Diseases and pests -- South Africa -- KwaZulu-Natal Sugarcane -- Diseases and pests -- Control -- South Africa -- KwaZulu-Natal , Insecticides
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5586 , http://hdl.handle.net/10962/d1001748
- Description: In the KwaZulu-Natal (KZN) Midlands North region of South Africa, the importance and increased prevalence of endemic scarabaeids, particularly Hypopholis sommeri Burmeister and Schizonycha affinis Boheman (Coleoptera: Melolonthinae), as soil pests of sugarcane, and a need for their control was established. The development of a mycoinsecticide offers an environmentally friendly alternative to chemical insecticides. The identification of a diversity of white grub species, in two Scarabaeidae subfamilies, representing seven genera were collected in sugarcane as a pest complex. Hypopholis sommeri and S. affinis were the most prevalent species. The increased seasonal abundances, diversity and highly aggregated nature of these scarabaeid species in summer months, suggested that targeting and control strategies for these pests should be considered in this season. Increased rainfall, relative humidity and soil temperatures were linked to the increased occurrence of scarab adults and neonate grubs. Beauveria brongniartii (Saccardo) Petch epizootics were recorded at two sites in the KZN Midlands North on H. sommeri. Seventeen different fluorescently-labelled microsatellite PCR primers were used to target 78 isolates of Beauveria sp. DNA. Microsatellite data resolved two distinct clusters of Beauveria isolates which represented the Beauveria bassiana senso stricto (Balsamo) Vuillemin and B. brongniartii species groups. These groupings were supported by two gene regions, the nuclear ribosomal Internal Transcribed Spacer (ITS) and the nuclear B locus (Bloc) gene of which 23 exemplar Beauveria isolates were represented and sequenced. When microsatellite data were analysed, 26 haplotypes among 58 isolates of B. brongniartii were distinguished. Relatively low levels of genetic diversity were detected in B. brongniartii and isolates were shown to be closely related. There was no genetic differentiation between the two sites, Harden Heights and Canema in the KZN Midlands North. High gene flow from swarming H. sommeri beetles is the proposed mechanism for this lack of genetic differentiation between populations. Microsatellite analyses also showed that B. brongniartii conidia were being cycled from arboreal to subterranean habitats in the environment by H. sommeri beetles. This was the first record of this species of fungus causing epizootics on the larvae and adults of H. sommeri in South Africa. The virulence of 21 isolates of Beauveria brongniartii and two isolates of B. bassiana were evaluated against the adults and larvae of S. affinis and the adults of H. sommeri and Tenebrio molitor Linnaeus (Coleoptera: Tenebrionidae). Despite being closely-related, B. brongniartii isolates varied significantly in their virulence towards different hosts and highlighted the host specific nature of B. brongniartii towards S. affinis when compared to B. bassiana. Adults of S. affinis were significantly more susceptible to B. brongniartii isolates than the second (L2) or third instar (L3) grubs. The median lethal time (LT₅₀) of the most virulent B. brongniartii isolate (C13) against S. affinis adults was 7.8 days and probit analysis estimated a median lethal concentration (LC₅₀) of 4.4×10⁷ conidia/ml⁻¹. When L2 grubs were treated with a concentration of 1.0×10⁸ conidia/ml⁻¹, B. brongniartii isolates HHWG1, HHB39A and C17 caused mortality in L2 grubs within 18.4-19.8 days (LT₅₀). Beauveria brongniartii isolate HHWG1 was tested against the L3 grubs of S. affinis at four different concentrations. At the lowest concentration (1×10⁶ conidia/ml⁻¹), the LT₅₀ was 25.8 days, and at the highest concentration (1×10⁹ conidia/ml⁻¹) the LT₅₀ dropped to 15.1 days. The persistence of B. bassiana isolate 4222 formulated on rice and wheat bran and buried at eight field sites in the KZN Midlands North was evaluated by plating out a suspension of treated soil onto a selective medium. All eight field sites showed a significant decline in B. bassiana CFUs per gram of soil over time, with few conidia still present in the samples after a year. Greater declines in CFUs were observed at some sites but there were no significant differences observed in the persistence of conidia formulated on rice or wheat bran as carriers. Overall, poor persistence of B. bassiana isolate 4222 was attributed to suboptimum temperatures, rainfall, which rapidly degraded the nutritive carriers, attenuated fungal genotype and the action of antagonistic soil microbes. Growers’ perceptions of white grubs as pests and the feasibility of a mycoinsecticide market were evaluated by means of a semi-structured questionnaire. The study showed that the reduced feasibility of application, general lack of potential demand for a product, high cost factors and most importantly, the lack of pest perception, were factors which would negatively affect the adoption of a granular mycoinsecticide. Growers however exhibited a positive attitude towards mycoinsecticides, and showed all the relevant attributes for successful technology adoption. It is recommended that because B. brongniartii epizootics were recorded on target pests which indicated good host specificity, dispersal ability and persistence of the fungus in the intended environment of application; that a mycoinsecticide based on this fungal species be developed. What will likely increase adoption and success of a mycoinsecticide is collaboration between various industries partners to increases market potential in other crops such as Acacia mearnsii De Wild (Fabales: Fabaceae).
- Full Text:
- Authors: Goble, Tarryn Anne
- Date: 2013
- Subjects: Insecticides -- Environmental aspects Insecticides -- Toxicology Beetles -- South Africa -- KwaZulu-Natal Beetles -- Control -- South Africa -- KwaZulu-Natal Coleophoridae -- South Africa -- KwaZulu-Natal Scarabaeidae -- South Africa -- KwaZulu-Natal Sugarcane -- Diseases and pests -- South Africa -- KwaZulu-Natal Sugarcane -- Diseases and pests -- Control -- South Africa -- KwaZulu-Natal , Insecticides
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5586 , http://hdl.handle.net/10962/d1001748
- Description: In the KwaZulu-Natal (KZN) Midlands North region of South Africa, the importance and increased prevalence of endemic scarabaeids, particularly Hypopholis sommeri Burmeister and Schizonycha affinis Boheman (Coleoptera: Melolonthinae), as soil pests of sugarcane, and a need for their control was established. The development of a mycoinsecticide offers an environmentally friendly alternative to chemical insecticides. The identification of a diversity of white grub species, in two Scarabaeidae subfamilies, representing seven genera were collected in sugarcane as a pest complex. Hypopholis sommeri and S. affinis were the most prevalent species. The increased seasonal abundances, diversity and highly aggregated nature of these scarabaeid species in summer months, suggested that targeting and control strategies for these pests should be considered in this season. Increased rainfall, relative humidity and soil temperatures were linked to the increased occurrence of scarab adults and neonate grubs. Beauveria brongniartii (Saccardo) Petch epizootics were recorded at two sites in the KZN Midlands North on H. sommeri. Seventeen different fluorescently-labelled microsatellite PCR primers were used to target 78 isolates of Beauveria sp. DNA. Microsatellite data resolved two distinct clusters of Beauveria isolates which represented the Beauveria bassiana senso stricto (Balsamo) Vuillemin and B. brongniartii species groups. These groupings were supported by two gene regions, the nuclear ribosomal Internal Transcribed Spacer (ITS) and the nuclear B locus (Bloc) gene of which 23 exemplar Beauveria isolates were represented and sequenced. When microsatellite data were analysed, 26 haplotypes among 58 isolates of B. brongniartii were distinguished. Relatively low levels of genetic diversity were detected in B. brongniartii and isolates were shown to be closely related. There was no genetic differentiation between the two sites, Harden Heights and Canema in the KZN Midlands North. High gene flow from swarming H. sommeri beetles is the proposed mechanism for this lack of genetic differentiation between populations. Microsatellite analyses also showed that B. brongniartii conidia were being cycled from arboreal to subterranean habitats in the environment by H. sommeri beetles. This was the first record of this species of fungus causing epizootics on the larvae and adults of H. sommeri in South Africa. The virulence of 21 isolates of Beauveria brongniartii and two isolates of B. bassiana were evaluated against the adults and larvae of S. affinis and the adults of H. sommeri and Tenebrio molitor Linnaeus (Coleoptera: Tenebrionidae). Despite being closely-related, B. brongniartii isolates varied significantly in their virulence towards different hosts and highlighted the host specific nature of B. brongniartii towards S. affinis when compared to B. bassiana. Adults of S. affinis were significantly more susceptible to B. brongniartii isolates than the second (L2) or third instar (L3) grubs. The median lethal time (LT₅₀) of the most virulent B. brongniartii isolate (C13) against S. affinis adults was 7.8 days and probit analysis estimated a median lethal concentration (LC₅₀) of 4.4×10⁷ conidia/ml⁻¹. When L2 grubs were treated with a concentration of 1.0×10⁸ conidia/ml⁻¹, B. brongniartii isolates HHWG1, HHB39A and C17 caused mortality in L2 grubs within 18.4-19.8 days (LT₅₀). Beauveria brongniartii isolate HHWG1 was tested against the L3 grubs of S. affinis at four different concentrations. At the lowest concentration (1×10⁶ conidia/ml⁻¹), the LT₅₀ was 25.8 days, and at the highest concentration (1×10⁹ conidia/ml⁻¹) the LT₅₀ dropped to 15.1 days. The persistence of B. bassiana isolate 4222 formulated on rice and wheat bran and buried at eight field sites in the KZN Midlands North was evaluated by plating out a suspension of treated soil onto a selective medium. All eight field sites showed a significant decline in B. bassiana CFUs per gram of soil over time, with few conidia still present in the samples after a year. Greater declines in CFUs were observed at some sites but there were no significant differences observed in the persistence of conidia formulated on rice or wheat bran as carriers. Overall, poor persistence of B. bassiana isolate 4222 was attributed to suboptimum temperatures, rainfall, which rapidly degraded the nutritive carriers, attenuated fungal genotype and the action of antagonistic soil microbes. Growers’ perceptions of white grubs as pests and the feasibility of a mycoinsecticide market were evaluated by means of a semi-structured questionnaire. The study showed that the reduced feasibility of application, general lack of potential demand for a product, high cost factors and most importantly, the lack of pest perception, were factors which would negatively affect the adoption of a granular mycoinsecticide. Growers however exhibited a positive attitude towards mycoinsecticides, and showed all the relevant attributes for successful technology adoption. It is recommended that because B. brongniartii epizootics were recorded on target pests which indicated good host specificity, dispersal ability and persistence of the fungus in the intended environment of application; that a mycoinsecticide based on this fungal species be developed. What will likely increase adoption and success of a mycoinsecticide is collaboration between various industries partners to increases market potential in other crops such as Acacia mearnsii De Wild (Fabales: Fabaceae).
- Full Text:
Towards an exceptional undergraduate personal learning experience: the Personal Librarian Programme, a pilot project at Rhodes University Library
- Authors: Gontshi, V
- Date: 2013
- Language: English
- Type: Conference paper
- Identifier: vital:6978 , http://hdl.handle.net/10962/d1007916
- Description: This paper is a record of a unique intervention for enhancing the Undergraduate learning experience at Rhodes University. It will focus on the establishment of the project, the experiences encountered and lessons learned thus far. In April 2013, a vibrant team of 13 librarians embarked on a Personal Librarian Pilot Project at the Rhodes University Library. The Personal Librarian Programme is primarily directed at undergraduate students at Rhodes University. In an attempt to bridge the information literacy skills gap that exists between Senior School and University in South Africa, the idea behind this programme is that each incoming first year student is assigned a Personal Librarian who will remain that individual’s contact in the library throughout his/her academic career at Rhodes University. The project came about as a result of research exploring the perceptions of both students and lecturers in the Commerce Faculty at Rhodes University with regard to Information Literacy practices and needs (Gontshi, 2011). The study revealed and recorded a shortcoming in the Information Literacy ability of students between Senior School Level and University Level. It became clear that new University students were not aware of the important link between their academic studies and the Library which in turn suggested the need to make Rhodes University librarians and the role that they play in the academic world more obvious to these new students (Gontshi, 2011). The Personal Librarian Programme was devised to fill this need. The Librarians involved in this programme include staff from all sections of the Library: circulation, faculty liaison and bibliographic/technical services. The training needs of staff who did not work directly with students were identified and the relevant training provided. The staff from Circulation and Bibliographic/Technical services sections identified a need to advance their knowledge on the use of library from a users’ perspective. The training focused on the following: “Brainstorming a research topic with a student”; “Identifying relevant databases to conduct a research topic” and “Conducting a search on relevant databases for the research topic” – this included ‘different ways of devising an effective search technique’. The training ensured a good foundation for these librarians to develop their confidence to work with users. The project, modeled on a similar programme at the Yale University Library in America, was also a direct result of Rhodes University Library’s involvement in the Carnegie Research Libraries Consortium (2009 – 2011) and a ten-week internship in the United States, seven weeks of which were spent at Yale University.
- Full Text:
- Authors: Gontshi, V
- Date: 2013
- Language: English
- Type: Conference paper
- Identifier: vital:6978 , http://hdl.handle.net/10962/d1007916
- Description: This paper is a record of a unique intervention for enhancing the Undergraduate learning experience at Rhodes University. It will focus on the establishment of the project, the experiences encountered and lessons learned thus far. In April 2013, a vibrant team of 13 librarians embarked on a Personal Librarian Pilot Project at the Rhodes University Library. The Personal Librarian Programme is primarily directed at undergraduate students at Rhodes University. In an attempt to bridge the information literacy skills gap that exists between Senior School and University in South Africa, the idea behind this programme is that each incoming first year student is assigned a Personal Librarian who will remain that individual’s contact in the library throughout his/her academic career at Rhodes University. The project came about as a result of research exploring the perceptions of both students and lecturers in the Commerce Faculty at Rhodes University with regard to Information Literacy practices and needs (Gontshi, 2011). The study revealed and recorded a shortcoming in the Information Literacy ability of students between Senior School Level and University Level. It became clear that new University students were not aware of the important link between their academic studies and the Library which in turn suggested the need to make Rhodes University librarians and the role that they play in the academic world more obvious to these new students (Gontshi, 2011). The Personal Librarian Programme was devised to fill this need. The Librarians involved in this programme include staff from all sections of the Library: circulation, faculty liaison and bibliographic/technical services. The training needs of staff who did not work directly with students were identified and the relevant training provided. The staff from Circulation and Bibliographic/Technical services sections identified a need to advance their knowledge on the use of library from a users’ perspective. The training focused on the following: “Brainstorming a research topic with a student”; “Identifying relevant databases to conduct a research topic” and “Conducting a search on relevant databases for the research topic” – this included ‘different ways of devising an effective search technique’. The training ensured a good foundation for these librarians to develop their confidence to work with users. The project, modeled on a similar programme at the Yale University Library in America, was also a direct result of Rhodes University Library’s involvement in the Carnegie Research Libraries Consortium (2009 – 2011) and a ten-week internship in the United States, seven weeks of which were spent at Yale University.
- Full Text:
Towards an exceptional Undergraduate Personal Learning Experience: the Personal Librarian Programme, a pilot project at Rhodes University Library
- Authors: Gontshi, V
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6985 , http://hdl.handle.net/10962/d1007918
- Description: This paper is a record of a unique intervention for enhancing the undergraduate learning experience at Rhodes University. It focuses on the establishment of the project, the experiences encountered and lessons learned thus far. In April 2013, a team of 13 librarians embarked on a Personal Librarian Pilot Project at the Rhodes University Library. The Personal Librarian Programme is primarily directed at undergraduate students at Rhodes University. In an attempt to bridge the information literacy skills gap that exists between Senior School and University in South Africa, the idea behind this programme is that each incoming first year student is assigned a Personal Librarian who will remain that individual’s contact in the library throughout his/her academic career at Rhodes University. The project came about as a result of research exploring the perceptions of both students and lecturers in the Commerce Faculty at Rhodes University with regard to Information Literacy practices and needs (Gontshi, 2011). The study revealed and recorded a shortcoming in the Information Literacy ability of students between Senior School Level and University Level. It became clear that new University students were not aware of the important link between their academic studies and the Library which in turn suggested the need to make Rhodes University librarians and the role that they play in the academic world more obvious to these new students (Gontshi, 2011). The Personal Librarian Programme was devised to fill this need. The Librarians involved in this programme include staff from all sections of the Library: circulation, faculty liaison and bibliographic/technical services. The training needs of staff who did not work directly with students were identified and the relevant training provided. The staff from circulation and bibliographic/technical services sections identified a need to advance their knowledge in the use of the library from a users’ perspective. The training focused on the following: “Brainstorming a research topic with a student”; “Identifying relevant databases to conduct a research topic” and “Conducting a search on relevant databases for the research topic” – this included different ways of devising an effective search technique. The training ensured a good foundation for these librarians to develop their confidence to work with users. The project, modeled on a similar programme at the Yale University Library in the United States of America, was also a direct result of Rhodes University Library’s involvement in the Carnegie Research Libraries Consortium (2009 – 2011) and the author’s ten-week internship in the United States, seven weeks of which were spent at Yale University.
- Full Text:
- Authors: Gontshi, V
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6985 , http://hdl.handle.net/10962/d1007918
- Description: This paper is a record of a unique intervention for enhancing the undergraduate learning experience at Rhodes University. It focuses on the establishment of the project, the experiences encountered and lessons learned thus far. In April 2013, a team of 13 librarians embarked on a Personal Librarian Pilot Project at the Rhodes University Library. The Personal Librarian Programme is primarily directed at undergraduate students at Rhodes University. In an attempt to bridge the information literacy skills gap that exists between Senior School and University in South Africa, the idea behind this programme is that each incoming first year student is assigned a Personal Librarian who will remain that individual’s contact in the library throughout his/her academic career at Rhodes University. The project came about as a result of research exploring the perceptions of both students and lecturers in the Commerce Faculty at Rhodes University with regard to Information Literacy practices and needs (Gontshi, 2011). The study revealed and recorded a shortcoming in the Information Literacy ability of students between Senior School Level and University Level. It became clear that new University students were not aware of the important link between their academic studies and the Library which in turn suggested the need to make Rhodes University librarians and the role that they play in the academic world more obvious to these new students (Gontshi, 2011). The Personal Librarian Programme was devised to fill this need. The Librarians involved in this programme include staff from all sections of the Library: circulation, faculty liaison and bibliographic/technical services. The training needs of staff who did not work directly with students were identified and the relevant training provided. The staff from circulation and bibliographic/technical services sections identified a need to advance their knowledge in the use of the library from a users’ perspective. The training focused on the following: “Brainstorming a research topic with a student”; “Identifying relevant databases to conduct a research topic” and “Conducting a search on relevant databases for the research topic” – this included different ways of devising an effective search technique. The training ensured a good foundation for these librarians to develop their confidence to work with users. The project, modeled on a similar programme at the Yale University Library in the United States of America, was also a direct result of Rhodes University Library’s involvement in the Carnegie Research Libraries Consortium (2009 – 2011) and the author’s ten-week internship in the United States, seven weeks of which were spent at Yale University.
- Full Text:
The Rotterdam Rules : a South African perspective
- Authors: Gordon, Goscelin Lucy
- Date: 2013
- Subjects: Rotterdam Rules (2008) , Contracts, Maritime , Maritime law , Maritime law -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3662 , http://hdl.handle.net/10962/d1001865 , Rotterdam Rules (2008) , Contracts, Maritime , Maritime law , Maritime law -- South Africa
- Description: The objective of this paper is to investigate the Rotterdam Rules, and to ascertain whether South Africa should accede to or ratify them. In order to accomplish this, South Africa's current maritime transport regime will be examined, and existing "problem areas" will be identified. This will be followed by a comparative analysis between the Rotterdam Rules and the Hague-Visby Rules, which South Africa applies as part of national law to regulate the carriage of goods by sea. As a new maritime Convention, the Rotterdam Rules have attracted widespread criticism and support, and whether such is justified will also be considered. Finally potential considerations South Africa should take into account in electing whether or not to accede or ratify the Rules have been assessed from a political, economic, social, technological, legal and environmental standpoint as at 31 December 2011
- Full Text:
- Authors: Gordon, Goscelin Lucy
- Date: 2013
- Subjects: Rotterdam Rules (2008) , Contracts, Maritime , Maritime law , Maritime law -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3662 , http://hdl.handle.net/10962/d1001865 , Rotterdam Rules (2008) , Contracts, Maritime , Maritime law , Maritime law -- South Africa
- Description: The objective of this paper is to investigate the Rotterdam Rules, and to ascertain whether South Africa should accede to or ratify them. In order to accomplish this, South Africa's current maritime transport regime will be examined, and existing "problem areas" will be identified. This will be followed by a comparative analysis between the Rotterdam Rules and the Hague-Visby Rules, which South Africa applies as part of national law to regulate the carriage of goods by sea. As a new maritime Convention, the Rotterdam Rules have attracted widespread criticism and support, and whether such is justified will also be considered. Finally potential considerations South Africa should take into account in electing whether or not to accede or ratify the Rules have been assessed from a political, economic, social, technological, legal and environmental standpoint as at 31 December 2011
- Full Text:
An empirical analysis of financial stress within South Africa and its apparent co-movement with financial stress emanating from advanced and emerging economies
- Authors: Graham, Brydone
- Date: 2013
- Subjects: Financial crises -- South Africa Financial crises -- Developing countries Globalization -- Economic aspects -- South Africa International economic relations South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1053 , http://hdl.handle.net/10962/d1006795
- Description: The identification of financial stress, and an understanding of financial contagion on a global scale, is of critical importance to a South African economy that is becoming increasingly integrated into the global economy. The last decade has been characterised by periods of high economic growth, but also periods of significant financial instability culminating in global economic crises. This study examines the extent to which the South African financial system is exposed to distress abroad by identifying and measuring the co-movement of financial stress originating from within and outside South Africa. The study can be separated into two sections: the identification of financial stress and the measurement of financial contagion. Using monthly data for the period 2000 to 2012, three indices were constructed for the emerging markets, advanced economies and South Africa using varianceequal weighting. The indices were tested for contagion using the Johansen and Jesulius (1990) multivariate cointegration approach supplemented with basic OLS architecture and Impulse Response analysis. The results indicate the three constructed indices were highly accurate at identifying the intensity and timing of financial stress over the three regions respectively. It was found that the South African financial sector is highly susceptible to financial stress originating from advanced economies. The results obtained for financial stress emanating from emerging markets were not as conclusive and found to be insignificant. Overall, it is clear that the methods employed to identify financial stress are highly accurate and that South Africa is highly susceptible to financial stress originating from abroad. It is clear that advanced economies have a greater ability to affect financial stress in South Africa via contagion. It must be noted that this does not conclude that South Africa is not affected by emerging market crises, but that these crises tend to affect South Africa through advanced economy channels as defined within this thesis.
- Full Text:
- Authors: Graham, Brydone
- Date: 2013
- Subjects: Financial crises -- South Africa Financial crises -- Developing countries Globalization -- Economic aspects -- South Africa International economic relations South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1053 , http://hdl.handle.net/10962/d1006795
- Description: The identification of financial stress, and an understanding of financial contagion on a global scale, is of critical importance to a South African economy that is becoming increasingly integrated into the global economy. The last decade has been characterised by periods of high economic growth, but also periods of significant financial instability culminating in global economic crises. This study examines the extent to which the South African financial system is exposed to distress abroad by identifying and measuring the co-movement of financial stress originating from within and outside South Africa. The study can be separated into two sections: the identification of financial stress and the measurement of financial contagion. Using monthly data for the period 2000 to 2012, three indices were constructed for the emerging markets, advanced economies and South Africa using varianceequal weighting. The indices were tested for contagion using the Johansen and Jesulius (1990) multivariate cointegration approach supplemented with basic OLS architecture and Impulse Response analysis. The results indicate the three constructed indices were highly accurate at identifying the intensity and timing of financial stress over the three regions respectively. It was found that the South African financial sector is highly susceptible to financial stress originating from advanced economies. The results obtained for financial stress emanating from emerging markets were not as conclusive and found to be insignificant. Overall, it is clear that the methods employed to identify financial stress are highly accurate and that South Africa is highly susceptible to financial stress originating from abroad. It is clear that advanced economies have a greater ability to affect financial stress in South Africa via contagion. It must be noted that this does not conclude that South Africa is not affected by emerging market crises, but that these crises tend to affect South Africa through advanced economy channels as defined within this thesis.
- Full Text: