The sorption of Hydrochloric Acid and Potassium Hydroxide by mohair and wool
- Bamford, Graeme Reginald Ernest
- Authors: Bamford, Graeme Reginald Ernest
- Date: 1959
- Subjects: Hydrochloric acid -- Absorption and adsorption , Hydroxides -- Absorption and adsorption , Wool , Mohair
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4452 , http://hdl.handle.net/10962/d1009503
- Description: The main object of the present investigation has been to establish a titration curve for mohair keratin and to compare it with similar data for wool, to determine whether the differences in physical and chemical properties could be attributed in any way to the acidic and basic character of these fibres. As shown in subsequent discussion such measurements provide extremely useful information regarding the chemical structure of proteins in general, and in the technical fields involving processes such as wool scouring, carbonizing and dyeing. The study has been extended to include certain modified wools, i.e. photochemically damaged, and oxidized keratin. The most successful contribution to the titration data of wool keratin is the work of Steinhardt and Harris and subsequent authors have tended to adopt their procedures without modification. In the present study attempts have been made to obtain a clearer understanding of the fundamental processes. New techniques and analytical methods have been introduced to improve the accuracy of the measurements.
- Full Text:
- Date Issued: 1959
- Authors: Bamford, Graeme Reginald Ernest
- Date: 1959
- Subjects: Hydrochloric acid -- Absorption and adsorption , Hydroxides -- Absorption and adsorption , Wool , Mohair
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4452 , http://hdl.handle.net/10962/d1009503
- Description: The main object of the present investigation has been to establish a titration curve for mohair keratin and to compare it with similar data for wool, to determine whether the differences in physical and chemical properties could be attributed in any way to the acidic and basic character of these fibres. As shown in subsequent discussion such measurements provide extremely useful information regarding the chemical structure of proteins in general, and in the technical fields involving processes such as wool scouring, carbonizing and dyeing. The study has been extended to include certain modified wools, i.e. photochemically damaged, and oxidized keratin. The most successful contribution to the titration data of wool keratin is the work of Steinhardt and Harris and subsequent authors have tended to adopt their procedures without modification. In the present study attempts have been made to obtain a clearer understanding of the fundamental processes. New techniques and analytical methods have been introduced to improve the accuracy of the measurements.
- Full Text:
- Date Issued: 1959
The thermal decomposition of irradiated silver permanganate
- Authors: Sole, Michael John
- Date: 1959
- Subjects: Decomposition (Chemistry) , Irradiation , Permanganates , Silver compounds , Metals -- Thermal properties
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4502 , http://hdl.handle.net/10962/d1013265
- Description: The thermal decomposition of silver permanganate, pre-irradiated in BEPO and in a ⁶°C₀ Ϫ 'hot spot' has been investigated in the temperature range 100 - 125°C. The results are similar to those for irradiated KMn0₄ and the mechanism proposed for the latter is again suggested. The activation energy for the migration of point defects over the induction period is 1.03 ev. The decompositions of unirradiated and irradiated crystals differ in that the latter undergo physical disintegration over the acceleratory period. X-ray studies immediately prior to disintegration show strain and fragmentation in the irradiated crystal. An explanation involving the annealing of point defects at dislocation is advanced to explain the changes produced in the p/t plots with increased dosage, and fixed decomposition temperature. Summary, p. 94.
- Full Text:
- Date Issued: 1959
- Authors: Sole, Michael John
- Date: 1959
- Subjects: Decomposition (Chemistry) , Irradiation , Permanganates , Silver compounds , Metals -- Thermal properties
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4502 , http://hdl.handle.net/10962/d1013265
- Description: The thermal decomposition of silver permanganate, pre-irradiated in BEPO and in a ⁶°C₀ Ϫ 'hot spot' has been investigated in the temperature range 100 - 125°C. The results are similar to those for irradiated KMn0₄ and the mechanism proposed for the latter is again suggested. The activation energy for the migration of point defects over the induction period is 1.03 ev. The decompositions of unirradiated and irradiated crystals differ in that the latter undergo physical disintegration over the acceleratory period. X-ray studies immediately prior to disintegration show strain and fragmentation in the irradiated crystal. An explanation involving the annealing of point defects at dislocation is advanced to explain the changes produced in the p/t plots with increased dosage, and fixed decomposition temperature. Summary, p. 94.
- Full Text:
- Date Issued: 1959
The transport system of the Border : a study of transport and communications in the Border region of the Cape Province with special reference to the effect of transport on the economic and commercial development of the region
- Authors: Smith, Hugh Hamilton
- Date: 1959
- Subjects: Transportation -- South Africa -- Eastern Cape , Harbors -- South Africa -- East London , Railroads -- South Africa -- Eastern Cape , Transportation, Automotive -- South Africa -- Eastern Cape , Communication and traffic -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1122 , http://hdl.handle.net/10962/d1018721
- Description: Transport undoubtedly occupies a most important place in the economic and commercial life of all countries. In this respect South Africa is no exception, and very briefly, the principal economic functions of transport are enumerated below. 1. Transport establishes communication between consumers and the producers of goods or services. 2. Transport facilitates the movement of persons between the place where they live and the place where they work - usually this is a daily procedure, but in South Africa it also entails the movement of large numbers of Natives from the Native Reserves to work for some months at a time either in the gold mines or in the several urban areas of the Union. 3. Transport makes geographical specialization possible, for agricultural or mineral resources will only be exploited, or specialized industries established, in a particular area, if the commodities produced can be transported to other parts of a country, or the world; and other capital and consumer goods brought to the producers living in the area of specialized production. 4. Transport faciitates industrial production because, of raw materials which come from many sources. Furthermore, transport enables the finished products of industry to be distributed to the markets in which they are sold. In all these cases, the efficiency of transport has to be measured not only in terms of its cost, but also in terms of its efficiency, which includes, inter alia, the time taken, the frequency of services, the safety of goods and passengers while in transit and the provision of various special services, such as the provision by railway undertakings of private siding facilities. This thesis will be divided into five parts, the first dealing with the technical and commercial development of the Buffalo Harbour. It has been decided to deal with the Harbour first because, not only has it been the focal point of the transport system of the Border Region since the latter part of the nineteenth century, but it has dominated the economic and commercial development of East London, as well as that of the Border Region as a whole. The second part deals with the evolution of the railway system from the 166 mile long East London and Queenstown Railway, to the present 1,110 miles of the Cape Eastern System. This historical chapter is followed by an analysis of the traffic of the Cape Eastern System. Part Three deals with the theory, practice, and economic consequences, of railway rating policy. Part Four is a detailed analysis of the goods traffic forwarded from, and received at East London in the period from 1st April, 1953 to 31st March, 1956. Part Five deals with roads and road transport. Finally, certain conclusions are offered, based on the significant points revealed by the investigation on which this thesis is based. In this thesis the theory of transport will not be dealt with in detail for it is essentially a factual account of the development of the transport system of the Border Region and an analysis of the present situation. It has unfortunately not been possible to make in this thesis a study of railway finance or railway economics with regard to the Cape Eastern System, for the data upon which to base such an investigation are not available for the Cape Eastern System in isolation. No attempt will be made to assess either the technical or the operating efficiency of the railway system for not only would this require more data than are available, but also a technical knowledge not possessed by the writer.
- Full Text:
- Date Issued: 1959
- Authors: Smith, Hugh Hamilton
- Date: 1959
- Subjects: Transportation -- South Africa -- Eastern Cape , Harbors -- South Africa -- East London , Railroads -- South Africa -- Eastern Cape , Transportation, Automotive -- South Africa -- Eastern Cape , Communication and traffic -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1122 , http://hdl.handle.net/10962/d1018721
- Description: Transport undoubtedly occupies a most important place in the economic and commercial life of all countries. In this respect South Africa is no exception, and very briefly, the principal economic functions of transport are enumerated below. 1. Transport establishes communication between consumers and the producers of goods or services. 2. Transport facilitates the movement of persons between the place where they live and the place where they work - usually this is a daily procedure, but in South Africa it also entails the movement of large numbers of Natives from the Native Reserves to work for some months at a time either in the gold mines or in the several urban areas of the Union. 3. Transport makes geographical specialization possible, for agricultural or mineral resources will only be exploited, or specialized industries established, in a particular area, if the commodities produced can be transported to other parts of a country, or the world; and other capital and consumer goods brought to the producers living in the area of specialized production. 4. Transport faciitates industrial production because, of raw materials which come from many sources. Furthermore, transport enables the finished products of industry to be distributed to the markets in which they are sold. In all these cases, the efficiency of transport has to be measured not only in terms of its cost, but also in terms of its efficiency, which includes, inter alia, the time taken, the frequency of services, the safety of goods and passengers while in transit and the provision of various special services, such as the provision by railway undertakings of private siding facilities. This thesis will be divided into five parts, the first dealing with the technical and commercial development of the Buffalo Harbour. It has been decided to deal with the Harbour first because, not only has it been the focal point of the transport system of the Border Region since the latter part of the nineteenth century, but it has dominated the economic and commercial development of East London, as well as that of the Border Region as a whole. The second part deals with the evolution of the railway system from the 166 mile long East London and Queenstown Railway, to the present 1,110 miles of the Cape Eastern System. This historical chapter is followed by an analysis of the traffic of the Cape Eastern System. Part Three deals with the theory, practice, and economic consequences, of railway rating policy. Part Four is a detailed analysis of the goods traffic forwarded from, and received at East London in the period from 1st April, 1953 to 31st March, 1956. Part Five deals with roads and road transport. Finally, certain conclusions are offered, based on the significant points revealed by the investigation on which this thesis is based. In this thesis the theory of transport will not be dealt with in detail for it is essentially a factual account of the development of the transport system of the Border Region and an analysis of the present situation. It has unfortunately not been possible to make in this thesis a study of railway finance or railway economics with regard to the Cape Eastern System, for the data upon which to base such an investigation are not available for the Cape Eastern System in isolation. No attempt will be made to assess either the technical or the operating efficiency of the railway system for not only would this require more data than are available, but also a technical knowledge not possessed by the writer.
- Full Text:
- Date Issued: 1959
A critical study of the curcumin method for the determination of boron in plant material
- Authors: Davidson, R J
- Date: 1958
- Subjects: Plants -- Nutrition , Boron , Turmeric
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4458 , http://hdl.handle.net/10962/d1011003
- Description: Methods for the determination of boron are reviewed. A thorough investigation of the curcumin method was undertaken. Factors such as spectral absorption, boron volatilisation and the effects of pH, the stability of reagents and colour solutions, the drying of reaction products and the interference from certain elements, were investigated. A study of the efficiency of extracting boron from plant material using an ashing procedure is presented. The modified curcumin method for the determination of boron in plant material is described. The statistical accuracy and precision of the modified method is presented. The modified method was used to determine the boron content in citrus and pineapple leaf samples obtained from various parts of the Eastern Cape.
- Full Text:
- Date Issued: 1958
- Authors: Davidson, R J
- Date: 1958
- Subjects: Plants -- Nutrition , Boron , Turmeric
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4458 , http://hdl.handle.net/10962/d1011003
- Description: Methods for the determination of boron are reviewed. A thorough investigation of the curcumin method was undertaken. Factors such as spectral absorption, boron volatilisation and the effects of pH, the stability of reagents and colour solutions, the drying of reaction products and the interference from certain elements, were investigated. A study of the efficiency of extracting boron from plant material using an ashing procedure is presented. The modified curcumin method for the determination of boron in plant material is described. The statistical accuracy and precision of the modified method is presented. The modified method was used to determine the boron content in citrus and pineapple leaf samples obtained from various parts of the Eastern Cape.
- Full Text:
- Date Issued: 1958
A statistical study of the errors involved in the sampling and chemical analysis of soils and plants, with particular reference to citrus and pineapples
- Steyn, Willem Johannes Abraham
- Authors: Steyn, Willem Johannes Abraham
- Date: 1958
- Subjects: Soil chemistry , Plants -- Analysis , Soils -- Analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4506 , http://hdl.handle.net/10962/d1013291
- Description: 1. Accurate and reproducible methods for the determination of N and acid- extractable P in soils are described. The variations in N, P, and K found by intensive sampling of three different soil types are presented. 3. Suggestions for the adequate sampling of soils for various purposes arc given. 4. A study is presented of the preparative stages in leaf analysis (washing, drying, grinding and storage) as applied to citrus and pineapple leaf material. Likely errors are pointed out and procedures whereby these may be minimised are described. 5. A reliable wet-ashing procedure for obtaining leaf solutions is described. 6. Accurate and reproducible methods for the determination of total N, P,. K, Ca, Mg, Na, Fe, Mn, Zn and Cu in citrus and pineapple leaves are presented. 7. It is shown that diurnal variations in nutrient concentrations occur in citrus and pineapple leaves. 8. The variations in N, P, K, Ca, Mg, Na, Fe, Mn, Zn and Cu, occurring from tree to tree in 3 different Navel orange blocks are presented. It is shown that if all these elements are to be represented . to within 10% of the mean values on a 19 : 1 probability level, all the trees in the blocks would have to be sampled. Reasonable sampling procedures for various purposes are suggested. 9. The variations in N, P, K, Ca, Mg, Fe, Mn, Zn and Cu, occurring in 3 different Cayenne pineapple plantations are presented and described. Suitable sampling procedures are suggested.
- Full Text:
- Date Issued: 1958
- Authors: Steyn, Willem Johannes Abraham
- Date: 1958
- Subjects: Soil chemistry , Plants -- Analysis , Soils -- Analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4506 , http://hdl.handle.net/10962/d1013291
- Description: 1. Accurate and reproducible methods for the determination of N and acid- extractable P in soils are described. The variations in N, P, and K found by intensive sampling of three different soil types are presented. 3. Suggestions for the adequate sampling of soils for various purposes arc given. 4. A study is presented of the preparative stages in leaf analysis (washing, drying, grinding and storage) as applied to citrus and pineapple leaf material. Likely errors are pointed out and procedures whereby these may be minimised are described. 5. A reliable wet-ashing procedure for obtaining leaf solutions is described. 6. Accurate and reproducible methods for the determination of total N, P,. K, Ca, Mg, Na, Fe, Mn, Zn and Cu in citrus and pineapple leaves are presented. 7. It is shown that diurnal variations in nutrient concentrations occur in citrus and pineapple leaves. 8. The variations in N, P, K, Ca, Mg, Na, Fe, Mn, Zn and Cu, occurring from tree to tree in 3 different Navel orange blocks are presented. It is shown that if all these elements are to be represented . to within 10% of the mean values on a 19 : 1 probability level, all the trees in the blocks would have to be sampled. Reasonable sampling procedures for various purposes are suggested. 9. The variations in N, P, K, Ca, Mg, Fe, Mn, Zn and Cu, occurring in 3 different Cayenne pineapple plantations are presented and described. Suitable sampling procedures are suggested.
- Full Text:
- Date Issued: 1958
An investigation of isolated bursts of solar radio noise
- Shuter, William Leslie Hazlewood
- Authors: Shuter, William Leslie Hazlewood
- Date: 1958
- Subjects: Solar physics -- Research , Solar radio emission
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5539 , http://hdl.handle.net/10962/d1013216
- Description: The literature on isolated bursts and possible mechanisms of origin has been critically reviewed, and observations point to a mechanism involving omission of electromagnetc radiation from plasma oscillations in the solar corona excited by outward travelling disturbances. Solar noise observations on 125 Mc./s. recorded at Rhodes University during the period November 26 1957 - February 6 1958 have been analysed by the author for isolated bursts, and these observations show the same general features reported by previous investigators. In interpretation of these records particular attention has been devoted to two aspects of isolated bursts; namely the preponderance on single frequency records of double-humped bursts, and the shape of isolated burst profiles. The authors suggests that a probable explanation of double-humped bursts observed on any frequency f is that the first hump represents omission at or near the level of zero refractive index for f radiation, and that the second hump corresponds to harmonic omission at the f/2 level. Source velocities may be calculated from the time delay between the peaks and an average value of 2 x 10⁴ km./sec. was obtained from an analysis of 21 double-humped bursts. This value is in very good agreement with that deduced by Wild (1950b) from the rate of frequency drift of peak intensity of isolated bursts. Simple isolated bursts had decay profiles which are approximatley exponential in shape, and this is usually interpreted in terms of the natural decay of plasma oscillations in the medium of origin. The author has verified that the exponential function is a good fit to the observed decay profiles, but shows that a relation of the form I - ¹/n (superscript) ⋉ t (where I is intensity and t is time) fits just as well. An alternative model is suggested which would lead to an exponential-like decay profile which is not determined by the natural decay of plasma oscillations. The work concludes with some suggestions for further research.
- Full Text:
- Date Issued: 1958
- Authors: Shuter, William Leslie Hazlewood
- Date: 1958
- Subjects: Solar physics -- Research , Solar radio emission
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5539 , http://hdl.handle.net/10962/d1013216
- Description: The literature on isolated bursts and possible mechanisms of origin has been critically reviewed, and observations point to a mechanism involving omission of electromagnetc radiation from plasma oscillations in the solar corona excited by outward travelling disturbances. Solar noise observations on 125 Mc./s. recorded at Rhodes University during the period November 26 1957 - February 6 1958 have been analysed by the author for isolated bursts, and these observations show the same general features reported by previous investigators. In interpretation of these records particular attention has been devoted to two aspects of isolated bursts; namely the preponderance on single frequency records of double-humped bursts, and the shape of isolated burst profiles. The authors suggests that a probable explanation of double-humped bursts observed on any frequency f is that the first hump represents omission at or near the level of zero refractive index for f radiation, and that the second hump corresponds to harmonic omission at the f/2 level. Source velocities may be calculated from the time delay between the peaks and an average value of 2 x 10⁴ km./sec. was obtained from an analysis of 21 double-humped bursts. This value is in very good agreement with that deduced by Wild (1950b) from the rate of frequency drift of peak intensity of isolated bursts. Simple isolated bursts had decay profiles which are approximatley exponential in shape, and this is usually interpreted in terms of the natural decay of plasma oscillations in the medium of origin. The author has verified that the exponential function is a good fit to the observed decay profiles, but shows that a relation of the form I - ¹/n (superscript) ⋉ t (where I is intensity and t is time) fits just as well. An alternative model is suggested which would lead to an exponential-like decay profile which is not determined by the natural decay of plasma oscillations. The work concludes with some suggestions for further research.
- Full Text:
- Date Issued: 1958
Contributions to the biology, anatomy and physiology of Opisthophthalmus Latimanus & other scorpions
- Authors: Alexander, Anne Joy
- Date: 1958
- Subjects: Scorpions -- South Africa , Scorpions -- Anatomy , Scorpions -- Physiology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5891 , http://hdl.handle.net/10962/d1013375
- Description: [From Introduction] For many years the problem of interrelationships within the Arthropoda and, indeed, the origin of the Phylum itself have been of interest to many zoologists. It was felt, for reasons which will be given later, that one of the studies which might throw some light on this matter is that of the neuromuscular physiology of arachnid appendages. Consequently it was proposed that the work which is reported here should be primarily concerned with this problem. As in so many cases involving live animals, both the experimental subjects and the experimenter gradually managed to change the direction in which work was proceeding and the result is that only a preliminary attack has been made on the original problem, while most of the material submitted here deals either with functional anatomy or with biological-cum-behavioural characteristics of the experimental animal. Thus it was found that to develop experimental preparations for neuro-muscular studies, it was necessary to work out the anatomy of the muscles and nerves of the appendages used; but this it is not enough. For these nerves and muscles are part of a functional complex which operates as a unit and have therefore to be studied in relation to the structures that they move. Considerations at this level, in fact, carried the study to the plane of functional anatomy. Furthermore it was recognised that even the comprehension of a limb as a functional complex cannot be acquired in isolation. All structures have an evolutionary history and in any consideration of functional anatomy this history must be taken into account - even if the consideration requires extension to the problem of the origin of the group immediately under study.
- Full Text:
- Date Issued: 1958
Contributions to the biology, anatomy and physiology of Opisthophthalmus Latimanus & other scorpions
- Authors: Alexander, Anne Joy
- Date: 1958
- Subjects: Scorpions -- South Africa , Scorpions -- Anatomy , Scorpions -- Physiology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5891 , http://hdl.handle.net/10962/d1013375
- Description: [From Introduction] For many years the problem of interrelationships within the Arthropoda and, indeed, the origin of the Phylum itself have been of interest to many zoologists. It was felt, for reasons which will be given later, that one of the studies which might throw some light on this matter is that of the neuromuscular physiology of arachnid appendages. Consequently it was proposed that the work which is reported here should be primarily concerned with this problem. As in so many cases involving live animals, both the experimental subjects and the experimenter gradually managed to change the direction in which work was proceeding and the result is that only a preliminary attack has been made on the original problem, while most of the material submitted here deals either with functional anatomy or with biological-cum-behavioural characteristics of the experimental animal. Thus it was found that to develop experimental preparations for neuro-muscular studies, it was necessary to work out the anatomy of the muscles and nerves of the appendages used; but this it is not enough. For these nerves and muscles are part of a functional complex which operates as a unit and have therefore to be studied in relation to the structures that they move. Considerations at this level, in fact, carried the study to the plane of functional anatomy. Furthermore it was recognised that even the comprehension of a limb as a functional complex cannot be acquired in isolation. All structures have an evolutionary history and in any consideration of functional anatomy this history must be taken into account - even if the consideration requires extension to the problem of the origin of the group immediately under study.
- Full Text:
- Date Issued: 1958
Correlation of the feeding habits, jaw musculature and type of teeth of some South African golden moles
- Authors: Thelejane, Thomas Sohl
- Date: 1958
- Subjects: Moles (Animals) -- Food , Insectivores (Mammals)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5892 , http://hdl.handle.net/10962/d1013385
- Description: The jaw musculature and its innervation in the Chrysochloridae studied is typicaly mammalian except that the m. temporalis occupies the whole of the orbito-temporal fossa. The antemolar teeth are specialized, while the molars are simple and primitive. Normally the diet of Golden Moles consists of earthworms, insects in all stages of development and millipedes. The firm implantation of the antemolar teeth can be correlated with their function of catching the prey, while the molars are adapted for a worm-like diet. The available evidence indicates that the genera Bematiscus and Chrysospalax are more primitive than the other Golden Moles. Since Golden Moles feed on insects in all stares of development and millipedes, they can be considered as being of economic importance.
- Full Text:
- Date Issued: 1958
- Authors: Thelejane, Thomas Sohl
- Date: 1958
- Subjects: Moles (Animals) -- Food , Insectivores (Mammals)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5892 , http://hdl.handle.net/10962/d1013385
- Description: The jaw musculature and its innervation in the Chrysochloridae studied is typicaly mammalian except that the m. temporalis occupies the whole of the orbito-temporal fossa. The antemolar teeth are specialized, while the molars are simple and primitive. Normally the diet of Golden Moles consists of earthworms, insects in all stages of development and millipedes. The firm implantation of the antemolar teeth can be correlated with their function of catching the prey, while the molars are adapted for a worm-like diet. The available evidence indicates that the genera Bematiscus and Chrysospalax are more primitive than the other Golden Moles. Since Golden Moles feed on insects in all stares of development and millipedes, they can be considered as being of economic importance.
- Full Text:
- Date Issued: 1958
Freedom in the thought of John Locke and John Stuart Mill
- Authors: Omer-Cooper, John David
- Date: 1958
- Subjects: Locke, John, 1632-1704 , Mill, John Stuart, 1806-1873 , Liberty , Ethics , Free thought , Autonomy (Psychology)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2746 , http://hdl.handle.net/10962/d1012989
- Description: Recent history has abundantly justified J. S. Mlll's theory that the power of soclety over the indivldual is llkely to increase without limlt If lt was not prevented. One of the most obvlous phenomena of our times has been the rise of the so-called totalltarlan systems of government; states that treat the lndlvldual as a being wlth no other end but the servlce of the state and which are prepared to use the advanced technlques which modern scientific research has made available to them to mould the individual as the perfect tool of the system.
- Full Text:
- Date Issued: 1958
- Authors: Omer-Cooper, John David
- Date: 1958
- Subjects: Locke, John, 1632-1704 , Mill, John Stuart, 1806-1873 , Liberty , Ethics , Free thought , Autonomy (Psychology)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2746 , http://hdl.handle.net/10962/d1012989
- Description: Recent history has abundantly justified J. S. Mlll's theory that the power of soclety over the indivldual is llkely to increase without limlt If lt was not prevented. One of the most obvlous phenomena of our times has been the rise of the so-called totalltarlan systems of government; states that treat the lndlvldual as a being wlth no other end but the servlce of the state and which are prepared to use the advanced technlques which modern scientific research has made available to them to mould the individual as the perfect tool of the system.
- Full Text:
- Date Issued: 1958
Grahamstown: a socio-ecological study of a small South African Town
- Authors: Watts, Hilstan Lett
- Date: 1958
- Subjects: Grahamstown (South Africa) -- Buildings , Grahamstown (South Africa) -- History , Grahamstown (South Africa) -- Social conditions , Grahamstown (South Africa) -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3386 , http://hdl.handle.net/10962/d1013424
- Description: Little is known at present about the development, structure, and functions of small towns in the Union of South Africa, and there is a need to fill this gap in our knowledge. A study has been made of Grahamstown, a small South African town. This study is monographic and intensive in character, and heuristic in aim. Ad hoc hypotheses have been formulated on the basis of the findings of the study, and these must be tested by subsequent studies of other small towns. Grahamstown, the subject of the study, was chosen largely for reasons of convenience, and also because of its interesting development. It is suggested that in many ways the town is possibly a typical small town, but at this stage we cannot know if this is so. Only the white population of the town was investigated, as it was necessary to limit research to manageable proportions, and in addition several studies have already been made of the non-white populations of the town. The analysis has been described as socio-ecological, as basically the methodological approach used is an attempt to wed the methods of the urban demographer and the social ecologist. Time and space are used as the two co-ordinates for the analysis, so that both a social historical and an ecological-demographic analysis of the town have been made. The historical analysis of the development and functions of Grahamstown relies heavily on material collected from the early newspapers of the town. Grahamstown, once the most important town in the Eastern Cape Province, known as the ''Emporium" and ''Metropolis" of the Eastern Cape, and the most progressive town in the Colony, is to-day a small static town with, on the whole, relatively restricted influence. This fundamental change in the historical development of the town, hitherto unexplained, is the result of the changes in the socioecological make-up of the region around the town. Founded in 1812 as a strategic outpost on the frontier of the Colony, Grahamstown dominated a wide region; as the gateway to and the supply centre for, the frontier, the town flourished and reigned supreme. From the mid 19th Century onwards the region began to change to a developed one, with the frontier more and more inland. Grahamstown, no longer a strategic outpost in a frontier region, lost its dominant ecological position to Port Elizabeth, the natural supply base for, and gateway to, the new settled region. As one town among many in the new settled region, Grahamstown gradually lost many of its former functions, and began to stagnate. The town is to-day mainly known for its important educational function. This function, a relic from the days of the town's zenith, has saved the town from complete stagnation. The town is what it is to-day largely because of the socio-ecological regional influences which have operated on it since its foundation. To-day Grahamstown is located within the Port Elizabeth metropolitan district. The town is the centre of a wide variety of regional services of an ad hoc type, and the modal region served seems to be that settled by the 1820 Settlers - basically the town is mainly a supply centre for its surrounding rural areas. The demographic structure of the town reveals a static population. Growth of the white population has been practically static since about 1880, and the age structure is that of a stationary population. Particularly noticeable is the under-representation of the young working group in the population, and it is suggested that due to the lack of economic opportunities in the town, the young workers of the town, especially the unmarried males, migrate to larger urban areas to seek employment, and advancement. The sex-ratio of the population shows an excess of females, and this may be due to migration out of an excess of young males, and possibly migration in of older spinsters. Retired persons definitely migrate to the town to settle. The town, a predominantly English speaking one, has practically no industries, and so the population contains a majority of workers engaged in professional, administrative, and commercial activities. This stresses the service and supply functions of the town. The ecological analysis delineated various natural areas and zones in the town. The pattern approximates to patterns revealed by studies of American towns. Although the areas involved were relatively small, ecological differentiation was marked. The spatial distribution of demographic and other social phenomena was studied in detail. The results of the study have allowed several ad hoc hypotheses concerning the development, functions, and structures of small towns in South Africa to be formulated. These may be tested by subsequent studies, and so ultimately knowledge and theories about our small towns may be built up.
- Full Text:
- Date Issued: 1958
- Authors: Watts, Hilstan Lett
- Date: 1958
- Subjects: Grahamstown (South Africa) -- Buildings , Grahamstown (South Africa) -- History , Grahamstown (South Africa) -- Social conditions , Grahamstown (South Africa) -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3386 , http://hdl.handle.net/10962/d1013424
- Description: Little is known at present about the development, structure, and functions of small towns in the Union of South Africa, and there is a need to fill this gap in our knowledge. A study has been made of Grahamstown, a small South African town. This study is monographic and intensive in character, and heuristic in aim. Ad hoc hypotheses have been formulated on the basis of the findings of the study, and these must be tested by subsequent studies of other small towns. Grahamstown, the subject of the study, was chosen largely for reasons of convenience, and also because of its interesting development. It is suggested that in many ways the town is possibly a typical small town, but at this stage we cannot know if this is so. Only the white population of the town was investigated, as it was necessary to limit research to manageable proportions, and in addition several studies have already been made of the non-white populations of the town. The analysis has been described as socio-ecological, as basically the methodological approach used is an attempt to wed the methods of the urban demographer and the social ecologist. Time and space are used as the two co-ordinates for the analysis, so that both a social historical and an ecological-demographic analysis of the town have been made. The historical analysis of the development and functions of Grahamstown relies heavily on material collected from the early newspapers of the town. Grahamstown, once the most important town in the Eastern Cape Province, known as the ''Emporium" and ''Metropolis" of the Eastern Cape, and the most progressive town in the Colony, is to-day a small static town with, on the whole, relatively restricted influence. This fundamental change in the historical development of the town, hitherto unexplained, is the result of the changes in the socioecological make-up of the region around the town. Founded in 1812 as a strategic outpost on the frontier of the Colony, Grahamstown dominated a wide region; as the gateway to and the supply centre for, the frontier, the town flourished and reigned supreme. From the mid 19th Century onwards the region began to change to a developed one, with the frontier more and more inland. Grahamstown, no longer a strategic outpost in a frontier region, lost its dominant ecological position to Port Elizabeth, the natural supply base for, and gateway to, the new settled region. As one town among many in the new settled region, Grahamstown gradually lost many of its former functions, and began to stagnate. The town is to-day mainly known for its important educational function. This function, a relic from the days of the town's zenith, has saved the town from complete stagnation. The town is what it is to-day largely because of the socio-ecological regional influences which have operated on it since its foundation. To-day Grahamstown is located within the Port Elizabeth metropolitan district. The town is the centre of a wide variety of regional services of an ad hoc type, and the modal region served seems to be that settled by the 1820 Settlers - basically the town is mainly a supply centre for its surrounding rural areas. The demographic structure of the town reveals a static population. Growth of the white population has been practically static since about 1880, and the age structure is that of a stationary population. Particularly noticeable is the under-representation of the young working group in the population, and it is suggested that due to the lack of economic opportunities in the town, the young workers of the town, especially the unmarried males, migrate to larger urban areas to seek employment, and advancement. The sex-ratio of the population shows an excess of females, and this may be due to migration out of an excess of young males, and possibly migration in of older spinsters. Retired persons definitely migrate to the town to settle. The town, a predominantly English speaking one, has practically no industries, and so the population contains a majority of workers engaged in professional, administrative, and commercial activities. This stresses the service and supply functions of the town. The ecological analysis delineated various natural areas and zones in the town. The pattern approximates to patterns revealed by studies of American towns. Although the areas involved were relatively small, ecological differentiation was marked. The spatial distribution of demographic and other social phenomena was studied in detail. The results of the study have allowed several ad hoc hypotheses concerning the development, functions, and structures of small towns in South Africa to be formulated. These may be tested by subsequent studies, and so ultimately knowledge and theories about our small towns may be built up.
- Full Text:
- Date Issued: 1958
Synthetic ion exchange resins, incorporating asymmetric groups, as resolving agents
- Authors: O'Sullivan, Diarmid John
- Date: 1958
- Subjects: Ion exchange resins -- Synthesis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4485 , http://hdl.handle.net/10962/d1012991
- Description: The object of this research is to further investigate the possiblitiy of resolving racemic bases on an optically active cation exchange resin. Any success in this direction would help to explain the reason for Bunnett and Mark's failure, since the general assumption that selective adsorption of one enantimorph of a racemic compound on an active exchanger should occur has been verified by Grubhofer and Schleith. The work can be conveniently divided into two sections. a) The preparation of optically active cation exchange resins and, b) the use of these as resolving agents. P. 8
- Full Text:
- Date Issued: 1958
- Authors: O'Sullivan, Diarmid John
- Date: 1958
- Subjects: Ion exchange resins -- Synthesis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4485 , http://hdl.handle.net/10962/d1012991
- Description: The object of this research is to further investigate the possiblitiy of resolving racemic bases on an optically active cation exchange resin. Any success in this direction would help to explain the reason for Bunnett and Mark's failure, since the general assumption that selective adsorption of one enantimorph of a racemic compound on an active exchanger should occur has been verified by Grubhofer and Schleith. The work can be conveniently divided into two sections. a) The preparation of optically active cation exchange resins and, b) the use of these as resolving agents. P. 8
- Full Text:
- Date Issued: 1958
The atonement : a brief discussion
- Authors: Hay, Thomas Alexander
- Date: 1958
- Subjects: Atonement , Satisfaction for sin
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1258 , http://hdl.handle.net/10962/d1012233 , Atonement , Satisfaction for sin
- Description: This first section endeavours briefly to set out the problem, seeing it ln its proper context against the need it fulfils and its historical setting. It attempts to show something of the nature of sin and the need which sin creates; and asks the question Why Atonement? This question can only be answered by an appreciation of the meaning and power of sinfulness. Atonement is necessarily from God's side, and it is costly to God. An important factor in this section is the attempt to see the wholeness of Christ's work; to set the atonement in its true context within the life of Christ. An attempt is made to relate the atonement to the incarnation, The Word made flesh and dwelling among us; to the resurrection, which is not to be misunderstood as a mere evidential appendage to the cross, but to be seen as an essential factor in the salvation of men; and also to the ascension, to the problem of time and eternity, in that while Christ's work was once-for-all, it is nevertheless continued - it was in history, but is not bound within history. When this conception of the unity of Christ's work is grasped then we can turn to a consideration of the cross, always regarded by Faith as the very centre of the atonement. A brief survey is made of the Biblical teaching concerning salvation and the cross; and the centrality of the cross is interpreted sacrificially. Summary, p. x-xi.
- Full Text:
- Date Issued: 1958
- Authors: Hay, Thomas Alexander
- Date: 1958
- Subjects: Atonement , Satisfaction for sin
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1258 , http://hdl.handle.net/10962/d1012233 , Atonement , Satisfaction for sin
- Description: This first section endeavours briefly to set out the problem, seeing it ln its proper context against the need it fulfils and its historical setting. It attempts to show something of the nature of sin and the need which sin creates; and asks the question Why Atonement? This question can only be answered by an appreciation of the meaning and power of sinfulness. Atonement is necessarily from God's side, and it is costly to God. An important factor in this section is the attempt to see the wholeness of Christ's work; to set the atonement in its true context within the life of Christ. An attempt is made to relate the atonement to the incarnation, The Word made flesh and dwelling among us; to the resurrection, which is not to be misunderstood as a mere evidential appendage to the cross, but to be seen as an essential factor in the salvation of men; and also to the ascension, to the problem of time and eternity, in that while Christ's work was once-for-all, it is nevertheless continued - it was in history, but is not bound within history. When this conception of the unity of Christ's work is grasped then we can turn to a consideration of the cross, always regarded by Faith as the very centre of the atonement. A brief survey is made of the Biblical teaching concerning salvation and the cross; and the centrality of the cross is interpreted sacrificially. Summary, p. x-xi.
- Full Text:
- Date Issued: 1958
The development of the secretaryship to the government at the Cape of Good Hope under John Montagu, 1843-1852
- Authors: Breitenbach, J J
- Date: 1958
- Subjects: Montagu, John, 1797-1853 , Montagu family , Cape of Good Hope (Colony) -- Parliament -- Legislative Council , Cape of Good Hope (South Africa) -- History , Cape of Good Hope (South Africa) -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2620 , http://hdl.handle.net/10962/d1014603
- Description: The development of the Cape Colony during the 'forties and early 'fifties last century is, indeed, a fascinating study. And as one aspect of it, a critical study analysis of the public career of John Montagu, while he was Colonial Secretary at the Cape, is of particular interest. For, by tracing the influence of his office in relation to the changing political, social and economic structures of the colony, it is hoped some contribution will be made to the knowledge of the period. Thus, the present thesis is, in part, an examination of the duties and responsibilities of the Colonial Office; but more particularly, it is an examination of how Montagu, who virtually dominated the Cape scene for almost a decade interpreted these duties and responsibilities. By concentrating, then, on his role in the civil administration and political management of colonial affairs, other aspects are revealed. The authority of the Colonial Office, which had through the years become a sort of government 'archives', was developed to such an extent, that every memorandum issued by it seems to set the tone for government policy. More. The very fact that Montagu was, time and again, left in charge of civil affairs at the Cape, while it reveals the dominant native problem and the vital question of defence, accounts also for the patenalism in government. The most important primary sources for this study have been the British Parliamentary Papers on Cape Affairs, the Cape of Good Hope Blue Books, Government House Records and the relevant minutes of the Executive and Legislative Councils. The Annual Almanacs of the Cape proved to be invaluable; they contain a wealth of information on the institutions of government, central and local, as well as the most indispensable returns for all the many services at the Cape.
- Full Text:
- Date Issued: 1958
- Authors: Breitenbach, J J
- Date: 1958
- Subjects: Montagu, John, 1797-1853 , Montagu family , Cape of Good Hope (Colony) -- Parliament -- Legislative Council , Cape of Good Hope (South Africa) -- History , Cape of Good Hope (South Africa) -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2620 , http://hdl.handle.net/10962/d1014603
- Description: The development of the Cape Colony during the 'forties and early 'fifties last century is, indeed, a fascinating study. And as one aspect of it, a critical study analysis of the public career of John Montagu, while he was Colonial Secretary at the Cape, is of particular interest. For, by tracing the influence of his office in relation to the changing political, social and economic structures of the colony, it is hoped some contribution will be made to the knowledge of the period. Thus, the present thesis is, in part, an examination of the duties and responsibilities of the Colonial Office; but more particularly, it is an examination of how Montagu, who virtually dominated the Cape scene for almost a decade interpreted these duties and responsibilities. By concentrating, then, on his role in the civil administration and political management of colonial affairs, other aspects are revealed. The authority of the Colonial Office, which had through the years become a sort of government 'archives', was developed to such an extent, that every memorandum issued by it seems to set the tone for government policy. More. The very fact that Montagu was, time and again, left in charge of civil affairs at the Cape, while it reveals the dominant native problem and the vital question of defence, accounts also for the patenalism in government. The most important primary sources for this study have been the British Parliamentary Papers on Cape Affairs, the Cape of Good Hope Blue Books, Government House Records and the relevant minutes of the Executive and Legislative Councils. The Annual Almanacs of the Cape proved to be invaluable; they contain a wealth of information on the institutions of government, central and local, as well as the most indispensable returns for all the many services at the Cape.
- Full Text:
- Date Issued: 1958
The doctrine of the dominical sacraments in St. Thomas Aquinas, John Calvin and the early Scottish reformers
- Authors: Moore, Michael
- Date: 1958
- Subjects: Thomas, Aquinas, Saint, 1225?-1274 , Calvin, Jean, 1509-1564 , Sacraments
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1263 , http://hdl.handle.net/10962/d1012877
- Description: The subject of the sacraments was chosen for this thesis because it was believed that the sacraments should be fully understood and should be placed at the centre of the work and worship of the Church, if the Church is to fulfil its role as the body of Christ in the world today. From studying the work of the reformers it became obvious that the word and the sacraments do not hold the place in the reformed Churches which they were intended to by Calvin and the early Scottish reformers. Pref., p. 1.
- Full Text:
- Date Issued: 1958
- Authors: Moore, Michael
- Date: 1958
- Subjects: Thomas, Aquinas, Saint, 1225?-1274 , Calvin, Jean, 1509-1564 , Sacraments
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1263 , http://hdl.handle.net/10962/d1012877
- Description: The subject of the sacraments was chosen for this thesis because it was believed that the sacraments should be fully understood and should be placed at the centre of the work and worship of the Church, if the Church is to fulfil its role as the body of Christ in the world today. From studying the work of the reformers it became obvious that the word and the sacraments do not hold the place in the reformed Churches which they were intended to by Calvin and the early Scottish reformers. Pref., p. 1.
- Full Text:
- Date Issued: 1958
The expanding horizon : a geographical commentary upon routes, records, observations & opinions contained in selected documents concerning travel at the Cape, 1750-1800
- Forbes, Vernon S (Vernon Siegfried)
- Authors: Forbes, Vernon S (Vernon Siegfried)
- Date: 1958
- Subjects: Travelers -- South Africa , South Africa -- Description and travel -- Early works to 1800
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4886 , http://hdl.handle.net/10962/d1014908
- Description: This study seeks to provide a geographical commentary upon documents relating to travel in the Cape during the second half of the eighteenth century. These documents include not only books of travel, but also travel journals, letters and maps both published and unpublished. They have been examined in the first place to ascertain what light they throw on the evolution of geographical ideas concerning the phenomena now capable of classification under the broad heading of physical geography. Secondly the have been viewed as part of the geography of travel and exploration which deals with routes, the identification of places, the explanation of place-names and the evolution of the map, or in its absence, of the mental picture of the regions reported on. Historical events are also considered, for the geographer can no more afford to ignore history than the historian dare cast a blind eye upon geography.
- Full Text:
- Date Issued: 1958
- Authors: Forbes, Vernon S (Vernon Siegfried)
- Date: 1958
- Subjects: Travelers -- South Africa , South Africa -- Description and travel -- Early works to 1800
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4886 , http://hdl.handle.net/10962/d1014908
- Description: This study seeks to provide a geographical commentary upon documents relating to travel in the Cape during the second half of the eighteenth century. These documents include not only books of travel, but also travel journals, letters and maps both published and unpublished. They have been examined in the first place to ascertain what light they throw on the evolution of geographical ideas concerning the phenomena now capable of classification under the broad heading of physical geography. Secondly the have been viewed as part of the geography of travel and exploration which deals with routes, the identification of places, the explanation of place-names and the evolution of the map, or in its absence, of the mental picture of the regions reported on. Historical events are also considered, for the geographer can no more afford to ignore history than the historian dare cast a blind eye upon geography.
- Full Text:
- Date Issued: 1958
The problem of authority in revelation
- Authors: Bax, Douglas S
- Date: 1958
- Subjects: Revelation , Revelation -- Biblical teaching , Revelation -- History of doctrines
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1283 , http://hdl.handle.net/10962/d1013468
- Description: From Preface: The problem of authority in religion can be stated as follows: what is the finally authoritative source and judge of religious truth? This was the fundamental question which Jesus Himself raised when He came to the Jews. It was the fundamental problem of the Reformation. It is also the fundamental problem that confronts the Church in our time. But it has never ceased to be the perennial question underlying all religious and philosophical thought.
- Full Text:
- Date Issued: 1958
- Authors: Bax, Douglas S
- Date: 1958
- Subjects: Revelation , Revelation -- Biblical teaching , Revelation -- History of doctrines
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1283 , http://hdl.handle.net/10962/d1013468
- Description: From Preface: The problem of authority in religion can be stated as follows: what is the finally authoritative source and judge of religious truth? This was the fundamental question which Jesus Himself raised when He came to the Jews. It was the fundamental problem of the Reformation. It is also the fundamental problem that confronts the Church in our time. But it has never ceased to be the perennial question underlying all religious and philosophical thought.
- Full Text:
- Date Issued: 1958
The South African anaphora: the development of the anaphora of the South African Eucharistic rite
- Authors: Hinchliff, Peter Bingham
- Date: 1958
- Subjects: Church of the Province of South Africa. Book of common prayer -- History -- Sources Eucharistic prayers Eucharistic prayers -- Anglican Communion Anglican Communion -- Liturgy -- History -- Sources Anglican Communion -- South Africa -- Liturgy -- History -- Sources.
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1260 , http://hdl.handle.net/10962/d1012293
- Description: The Prayer Book of the Church of England reached South Africa as a part of the establishment of the British Administration at the Cape. In its new environment it obviously required some revision. The Book of 1662 reflected the political and social conditions of its time. lt was designed for a Church not immediately concerned with missionary work amongst heathen peoples but directly established under the Crown. The circumstances of a Church in the colonies, particularly when the colonies became self-governing, required some modernisation of language, some omission and adaptation of old prayers and some addition of new ones. Yet the Church appears to have been wary of attempting anything more than this, and it was especially reluctant to make any revision which might imply a doctrinal change. The consecration prayer in the liturgy -'our incomparable liturgy' - was particularly sacrosanct by virtue of long use and the accretion of sentimental associations. Revision of this part of the book would naturally be slow and hesitant and this is the revision with which we are concerned - the most interesting and important part of the history of the South African Prayer Book. Chapter 1, p. 6.
- Full Text:
- Date Issued: 1958
- Authors: Hinchliff, Peter Bingham
- Date: 1958
- Subjects: Church of the Province of South Africa. Book of common prayer -- History -- Sources Eucharistic prayers Eucharistic prayers -- Anglican Communion Anglican Communion -- Liturgy -- History -- Sources Anglican Communion -- South Africa -- Liturgy -- History -- Sources.
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1260 , http://hdl.handle.net/10962/d1012293
- Description: The Prayer Book of the Church of England reached South Africa as a part of the establishment of the British Administration at the Cape. In its new environment it obviously required some revision. The Book of 1662 reflected the political and social conditions of its time. lt was designed for a Church not immediately concerned with missionary work amongst heathen peoples but directly established under the Crown. The circumstances of a Church in the colonies, particularly when the colonies became self-governing, required some modernisation of language, some omission and adaptation of old prayers and some addition of new ones. Yet the Church appears to have been wary of attempting anything more than this, and it was especially reluctant to make any revision which might imply a doctrinal change. The consecration prayer in the liturgy -'our incomparable liturgy' - was particularly sacrosanct by virtue of long use and the accretion of sentimental associations. Revision of this part of the book would naturally be slow and hesitant and this is the revision with which we are concerned - the most interesting and important part of the history of the South African Prayer Book. Chapter 1, p. 6.
- Full Text:
- Date Issued: 1958
Wages and employment of European women in industry in Durban, 1955/56
- Authors: Mesham, Noreen Ina
- Date: 1958
- Subjects: Women -- Employment -- South Africa , Wages -- Women -- South Africa -- Durban , Women -- South Africa -- Durban -- Economic conditions , Women -- South Africa -- Durban -- Social conditions , Durban (South Africa) -- Economic conditions -- 20th century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:1112 , http://hdl.handle.net/10962/d1013509
- Full Text:
- Date Issued: 1958
- Authors: Mesham, Noreen Ina
- Date: 1958
- Subjects: Women -- Employment -- South Africa , Wages -- Women -- South Africa -- Durban , Women -- South Africa -- Durban -- Economic conditions , Women -- South Africa -- Durban -- Social conditions , Durban (South Africa) -- Economic conditions -- 20th century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:1112 , http://hdl.handle.net/10962/d1013509
- Full Text:
- Date Issued: 1958
A conductimetric investigation of phenomena in extremely dilute aqueous solutions
- Authors: Faure, Pierre Knobel
- Date: 1957
- Subjects: Adsorption , Solution (Chemistry)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4524 , http://hdl.handle.net/10962/d1014891
- Description: 1. The apparatus used in this investigation is fully described, and a new method is outlined for the calibration of bridge resistances "in situ". 2. A chart is given for the accurate correction of weights in air to weights in vacuum for a range of temperatures extending from 10° to 28°C, and for pressures from 690 to 730 mm. 3. An automatic recycling still has been designed for the continuous production of "ultra-pure" water. This still is capable of delivering daily, in routine operation, 16 l. of water of conductivity less than 100 nm/cm after aeration with "C0₂- and NH₃-free" air. 4. A very soluble layer appears to form on the surface of' glass when it is dried; this layer is readily removed on contact with water. 5. The removal of carbon dioxide and of ammonia from aqueous solution by aeration with an indifferent gas has been fully investigated, and it has been shown that these gases can be completely eliminated by such a process. Whereas the carbon dioxide is removed fairly rapidly, however, the ammonia, whether present alone or together with carbon dioxide, only goes out of solution rather slowly. 6. It has been shown that ammonia is adsorbed from aqueous solution on the glass walls of the cell. 7. There does not appear to be any ammonium bicarbonate in the residual impurity left in the "ultra-pure" water obtained from the still; the impurity can, in fact, be regarded as neutral salt with sufficient accuracy for most purposes. 8. The resistance change which accompanies any variation in the rate of bubbling of the stirring gas through the water has been investigated, but no solution has been found as to the cause of this change. 9. A comparison has been made of the efficiency of different gases for stirring purposes, and it seems that, for general work, nitrogen is by far the most suitable of the common gases. 10. The extrapolation to be used for converting resistances to their values at infinite frequency appears ...
- Full Text:
- Date Issued: 1957
- Authors: Faure, Pierre Knobel
- Date: 1957
- Subjects: Adsorption , Solution (Chemistry)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4524 , http://hdl.handle.net/10962/d1014891
- Description: 1. The apparatus used in this investigation is fully described, and a new method is outlined for the calibration of bridge resistances "in situ". 2. A chart is given for the accurate correction of weights in air to weights in vacuum for a range of temperatures extending from 10° to 28°C, and for pressures from 690 to 730 mm. 3. An automatic recycling still has been designed for the continuous production of "ultra-pure" water. This still is capable of delivering daily, in routine operation, 16 l. of water of conductivity less than 100 nm/cm after aeration with "C0₂- and NH₃-free" air. 4. A very soluble layer appears to form on the surface of' glass when it is dried; this layer is readily removed on contact with water. 5. The removal of carbon dioxide and of ammonia from aqueous solution by aeration with an indifferent gas has been fully investigated, and it has been shown that these gases can be completely eliminated by such a process. Whereas the carbon dioxide is removed fairly rapidly, however, the ammonia, whether present alone or together with carbon dioxide, only goes out of solution rather slowly. 6. It has been shown that ammonia is adsorbed from aqueous solution on the glass walls of the cell. 7. There does not appear to be any ammonium bicarbonate in the residual impurity left in the "ultra-pure" water obtained from the still; the impurity can, in fact, be regarded as neutral salt with sufficient accuracy for most purposes. 8. The resistance change which accompanies any variation in the rate of bubbling of the stirring gas through the water has been investigated, but no solution has been found as to the cause of this change. 9. A comparison has been made of the efficiency of different gases for stirring purposes, and it seems that, for general work, nitrogen is by far the most suitable of the common gases. 10. The extrapolation to be used for converting resistances to their values at infinite frequency appears ...
- Full Text:
- Date Issued: 1957
Liquid junction potentials at mixed electrolyte salt bridges
- Authors: Finkelstein, Noel Phillip
- Date: 1957
- Subjects: Hydrogen-ion concentration -- Measurement , Hydrogen-ion concentration , Electrochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4473 , http://hdl.handle.net/10962/d1011835 , Hydrogen-ion concentration -- Measurement , Hydrogen-ion concentration , Electrochemistry
- Description: The potentiometric method is one of the most exact techniques of electrochemistry. Its use is widespread in both routine measurements, such as pH determination, and in applications which demand the highest accuracy. Perhaps its severest limitation is the error due to liquid junction potentials. Although this has been the subject of much study, and although various means of combating it have been proposed, it has defied all attempts at a satisfactory solution. Indeed, so serious is the position that it has become the accepted practice in the more accurate fields to abandon altogether the use of potentiometric techniques in favour of others, usually less convenient and otherwise less accurate, when the presence of liquid junctions cannot be avoided. Intro. p. 1.
- Full Text:
- Date Issued: 1957
- Authors: Finkelstein, Noel Phillip
- Date: 1957
- Subjects: Hydrogen-ion concentration -- Measurement , Hydrogen-ion concentration , Electrochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4473 , http://hdl.handle.net/10962/d1011835 , Hydrogen-ion concentration -- Measurement , Hydrogen-ion concentration , Electrochemistry
- Description: The potentiometric method is one of the most exact techniques of electrochemistry. Its use is widespread in both routine measurements, such as pH determination, and in applications which demand the highest accuracy. Perhaps its severest limitation is the error due to liquid junction potentials. Although this has been the subject of much study, and although various means of combating it have been proposed, it has defied all attempts at a satisfactory solution. Indeed, so serious is the position that it has become the accepted practice in the more accurate fields to abandon altogether the use of potentiometric techniques in favour of others, usually less convenient and otherwise less accurate, when the presence of liquid junctions cannot be avoided. Intro. p. 1.
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- Date Issued: 1957