Product development as part of a positioning strategy for the hunting industry in the Eastern Cape
- Van Niekerk, Pieter du Preez
- Authors: Van Niekerk, Pieter du Preez
- Date: 2002
- Subjects: New products -- Marketing , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- Eastern Cape , Venison -- Marketing , Meat industry and trade -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10894 , http://hdl.handle.net/10948/111 , New products -- Marketing , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- Eastern Cape , Venison -- Marketing , Meat industry and trade -- South Africa -- Eastern Cape
- Description: In this study on product development and positioning in the hunting industry in the Eastern Cape, two conceptual frameworks were developed, based on a literature study. These positioning and product development concepts were tested against primary and secondary information gathered about the hunting industry. The game and hunting industries were in a strong growth phase at the time of this study. These industries are playing an increasingly important role in the economy of the Eastern Cape, and more and more agricultural land is utilised for game ranching. From the perspective of obtaining a competitive advantage in an increasingly competitive environment, it is therefore important for hunting providers to develop suitable products, and to position these products correctly. It is also important to investigate the characteristics of the game and hunting industries in the Eastern Cape and to get information about the characteristics of the market in which product development and positioning take place. Hunting is the most important form of game utilisation in the Eastern Cape, followed by cropping of game and live game sales. At the time of this study, the total value of the game utilised annually in the Eastern Cape was in excess of R168 million. Game utilisation seemed to be taking place on a sustainable basis, as the number of animals utilised annually was less than the annual production. Kudu and springbok provide the biggest total income, and, together with mountain reedbuck, are the most abundant species in the Eastern Cape. The main game-producing areas in the Eastern Cape coincide with the areas where extensive beef, sheep and goat farming are practised. The hunting products on offer from hunting providers, differ in certain ways. Aspects like price, type of hunting provided, game species available for hunting, terrain where hunting takes place, and various other aspects in connection with the hunt, differ from hunting provider to hunting provider. Characteristics of the hunting experience that hunters desire may be divided into core and variable elements. The core elements include: · the conditions pertaining to the hunt being spelt out clearly; · the maintenance of safety standards; · reasonable day fees; · the presence of game in sufficient numbers; and · other aspects generally desired by hunters. In the study it was found that the needs of hunters also differ regarding certain aspects of the hunting experience. These variable elements include price levels, type and availability of accommodation, and the role of the hunting provider. The core aspects that hunters desire are as a rule part of the product offering. From a product development perspective, the variable elements provide an opportunity to customise products to hunter needs. The inclusion or exclusion of variable elements from the product offering give rise to certain unique product features, and therefore provide the opportunity for product differentiation. After development, products are positioned firstly by selecting a market segment to focus on. Secondly, the needs of hunters in the target segment should be clearly identified, followed by the development of suitable products based on hunter needs, and taking into account the features of competitive offerings. Decisions should also be taken about the features to be included in the product offering to achieve product differentiation. After development of a suitable product, an image or brand should be chosen for the product, and this image should be effectively communicated to the market. A number of possible positioning options were identified for hunting providers. It was found that factors like the physical features of the ranch, available infrastructure, the market segment chosen, desires of the hunting providers, and the perception of the needs of hunters, eventually influence decisions about product development and positioning. The final decisions on positioning should take the core competencies of the hunting provider into account and should ensure that the hunting provider has the ability to fill the chosen position in the market.
- Full Text:
- Date Issued: 2002
- Authors: Van Niekerk, Pieter du Preez
- Date: 2002
- Subjects: New products -- Marketing , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- Eastern Cape , Venison -- Marketing , Meat industry and trade -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10894 , http://hdl.handle.net/10948/111 , New products -- Marketing , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- Eastern Cape , Venison -- Marketing , Meat industry and trade -- South Africa -- Eastern Cape
- Description: In this study on product development and positioning in the hunting industry in the Eastern Cape, two conceptual frameworks were developed, based on a literature study. These positioning and product development concepts were tested against primary and secondary information gathered about the hunting industry. The game and hunting industries were in a strong growth phase at the time of this study. These industries are playing an increasingly important role in the economy of the Eastern Cape, and more and more agricultural land is utilised for game ranching. From the perspective of obtaining a competitive advantage in an increasingly competitive environment, it is therefore important for hunting providers to develop suitable products, and to position these products correctly. It is also important to investigate the characteristics of the game and hunting industries in the Eastern Cape and to get information about the characteristics of the market in which product development and positioning take place. Hunting is the most important form of game utilisation in the Eastern Cape, followed by cropping of game and live game sales. At the time of this study, the total value of the game utilised annually in the Eastern Cape was in excess of R168 million. Game utilisation seemed to be taking place on a sustainable basis, as the number of animals utilised annually was less than the annual production. Kudu and springbok provide the biggest total income, and, together with mountain reedbuck, are the most abundant species in the Eastern Cape. The main game-producing areas in the Eastern Cape coincide with the areas where extensive beef, sheep and goat farming are practised. The hunting products on offer from hunting providers, differ in certain ways. Aspects like price, type of hunting provided, game species available for hunting, terrain where hunting takes place, and various other aspects in connection with the hunt, differ from hunting provider to hunting provider. Characteristics of the hunting experience that hunters desire may be divided into core and variable elements. The core elements include: · the conditions pertaining to the hunt being spelt out clearly; · the maintenance of safety standards; · reasonable day fees; · the presence of game in sufficient numbers; and · other aspects generally desired by hunters. In the study it was found that the needs of hunters also differ regarding certain aspects of the hunting experience. These variable elements include price levels, type and availability of accommodation, and the role of the hunting provider. The core aspects that hunters desire are as a rule part of the product offering. From a product development perspective, the variable elements provide an opportunity to customise products to hunter needs. The inclusion or exclusion of variable elements from the product offering give rise to certain unique product features, and therefore provide the opportunity for product differentiation. After development, products are positioned firstly by selecting a market segment to focus on. Secondly, the needs of hunters in the target segment should be clearly identified, followed by the development of suitable products based on hunter needs, and taking into account the features of competitive offerings. Decisions should also be taken about the features to be included in the product offering to achieve product differentiation. After development of a suitable product, an image or brand should be chosen for the product, and this image should be effectively communicated to the market. A number of possible positioning options were identified for hunting providers. It was found that factors like the physical features of the ranch, available infrastructure, the market segment chosen, desires of the hunting providers, and the perception of the needs of hunters, eventually influence decisions about product development and positioning. The final decisions on positioning should take the core competencies of the hunting provider into account and should ensure that the hunting provider has the ability to fill the chosen position in the market.
- Full Text:
- Date Issued: 2002
The development of a self-disintegrating core-body for use in an art bronze-casting foundry which employs the ceramic-shell investment technique
- Authors: Lomax, Lawrence Talbot
- Date: 2004
- Subjects: Sculpture -- Technique , Bronze founding , Precision casting , Shell molding (Founding)
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:8499 , http://hdl.handle.net/10948/219 , Sculpture -- Technique , Bronze founding , Precision casting , Shell molding (Founding)
- Description: The development of a disintegrating core-body for use in an art bronze foundry, which employs the ceramic shell investment process, begins with an investigation of four principal materials that will constitute the core formula. The specifications for the disintegration of the designed core-body formula fall within the parameters that are normally set and used in the ceramic shell art bronze casting process. The raison d’ être for the disintegrating formula is based on the premise that cement breaks down (spalling) after being subjected to heat above a certain temperature. It was shown that pure cement in the form of naked test bars 100 mm x 20 mm x 20 mm does indeed break down into separate pieces when fired to and above 9000C; where 9000C is the lowest recommended temperature required for sintering the ceramic shell investment mould. The addition of calcium carbonate to pure cement in the form of naked test bars, produced a more unified formula that did not break into separate pieces when fired to 9450C. However this combination of cement and calcium carbonate had a slow setting time of 12 hours and a shrinkage value of 2,3%, which were both above the parameters being sought for a quick-setting formula with a shrinkage value of below 1%. The combination of cement, plaster of paris and silica produced formulae that set within six hours and had shrinkage values of less than 1% but did not disintegrate within 72 hours. It was only after the addition of calcium carbonate to the these mixes that formulae resulted that set within six hours, had relatively low shrinkage values and showed signs of breaking up after 60 hours. It was further shown that by altering the ratios of cement, plaster of paris, calcium carbonate and silica, that the parameters for quick-setting formulae with shrinkage values of 1% and below, that also disintegrated within 55 hours, could be achieved. xvi It was also proved by subjecting these formulae to higher relative humidity conditions that the disintegrating times could be reduced and brought to below 48 hours. Selected formulae were then subjected to temperatures of between 9000C and 10000C. It was found that as the temperatures were increased so the disintegration times were reduced and were even further reduced under higher relative humidity conditions. It was found from the above experiments that the selected formula determined to be suitable in all respects as a disintegrating core-body was too difficult to remove from the hollow bronze cast when subjected to an actual bronze pour. Further experimentation using increased proportions of silica in the formula resulted in a final core-body that could be quickly and easily removed from its bronze cast as soon as the core-body had cooled to room temperature. The selected core-body formula (F21D) that was used in the final set of bronze casting procedures was found to function optimally when fired to a temperature of 9000C and could be quickly and easily removed from the bronze casts leaving a clean inner bronze surface, free from any remnants of the fired core. The document concludes by recording the delimitations and advantages of the final core-body formula F21D, as well as making recommendations based on these parameters for further study relating to disintegrating core-body formulations.
- Full Text:
- Date Issued: 2004
- Authors: Lomax, Lawrence Talbot
- Date: 2004
- Subjects: Sculpture -- Technique , Bronze founding , Precision casting , Shell molding (Founding)
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:8499 , http://hdl.handle.net/10948/219 , Sculpture -- Technique , Bronze founding , Precision casting , Shell molding (Founding)
- Description: The development of a disintegrating core-body for use in an art bronze foundry, which employs the ceramic shell investment process, begins with an investigation of four principal materials that will constitute the core formula. The specifications for the disintegration of the designed core-body formula fall within the parameters that are normally set and used in the ceramic shell art bronze casting process. The raison d’ être for the disintegrating formula is based on the premise that cement breaks down (spalling) after being subjected to heat above a certain temperature. It was shown that pure cement in the form of naked test bars 100 mm x 20 mm x 20 mm does indeed break down into separate pieces when fired to and above 9000C; where 9000C is the lowest recommended temperature required for sintering the ceramic shell investment mould. The addition of calcium carbonate to pure cement in the form of naked test bars, produced a more unified formula that did not break into separate pieces when fired to 9450C. However this combination of cement and calcium carbonate had a slow setting time of 12 hours and a shrinkage value of 2,3%, which were both above the parameters being sought for a quick-setting formula with a shrinkage value of below 1%. The combination of cement, plaster of paris and silica produced formulae that set within six hours and had shrinkage values of less than 1% but did not disintegrate within 72 hours. It was only after the addition of calcium carbonate to the these mixes that formulae resulted that set within six hours, had relatively low shrinkage values and showed signs of breaking up after 60 hours. It was further shown that by altering the ratios of cement, plaster of paris, calcium carbonate and silica, that the parameters for quick-setting formulae with shrinkage values of 1% and below, that also disintegrated within 55 hours, could be achieved. xvi It was also proved by subjecting these formulae to higher relative humidity conditions that the disintegrating times could be reduced and brought to below 48 hours. Selected formulae were then subjected to temperatures of between 9000C and 10000C. It was found that as the temperatures were increased so the disintegration times were reduced and were even further reduced under higher relative humidity conditions. It was found from the above experiments that the selected formula determined to be suitable in all respects as a disintegrating core-body was too difficult to remove from the hollow bronze cast when subjected to an actual bronze pour. Further experimentation using increased proportions of silica in the formula resulted in a final core-body that could be quickly and easily removed from its bronze cast as soon as the core-body had cooled to room temperature. The selected core-body formula (F21D) that was used in the final set of bronze casting procedures was found to function optimally when fired to a temperature of 9000C and could be quickly and easily removed from the bronze casts leaving a clean inner bronze surface, free from any remnants of the fired core. The document concludes by recording the delimitations and advantages of the final core-body formula F21D, as well as making recommendations based on these parameters for further study relating to disintegrating core-body formulations.
- Full Text:
- Date Issued: 2004
Material characterisation of laser formed dual phase steel components
- Authors: Els-Botes, Annelize
- Date: 2005
- Subjects: Steel -- Fatigue , Bending , Lasers , Sheet-steel -- Effect of lasers on
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9609 , http://hdl.handle.net/10948/176 , Steel -- Fatigue , Bending , Lasers , Sheet-steel -- Effect of lasers on
- Description: The nature and scope of this thesis can be divided into four categories: • FORMING PARAMETERS • Identification of various laser forming parameters in order to produce specimens of similar dimension (radius of curvature). • TEMPERATURE AND MICROSTRUCTURE • To study the effect of maximum temperature reached during the forming operation on the microstructure of the various specimens. • FATIGUE LIFE • Compare the fatigue life of the specimens produced by various laser parameters to that of the original material, and also the fatigue life of mechanical formed specimens. • RESIDUAL STRESS PROFILE Determine if the laser forming process induces detrimental residual stress magnitudes in the specimens. The main objective of this thesis was to gain an understanding of the way in which laser forming affects the fatigue performance and residual stress magnitude / distribution of dual phase steel. Although lasers have been used successfully in various manufacturing processes (welding, cutting, marking, etc.), little information is available on the influence of laser forming on many automotive alloys such as dual phase steel. The first part of the work involved a literature review of the process and factors affecting the laser forming process. It became clear from the literature overview that laser forming of sheet material thicker than 1mm is complex in nature. The variables that can influence the process are complicated and their interaction with each other is not easily controlled. The main parameters that were thus controlled in this study are as follows: • Laser power (P) • Laser head travel speed (v) • Laser beam size (mm) The chapters that follow the literature review, deals with the laser forming process of dual phase steel and the production of fatigue specimens using various laser parameters. It was found that the following laser parameters resulted in specimens with approximately the same radius of curvature: Laser power KW Beam diameter mm Interval spacing % Overlap Scanning velocity m/min Line Energy J/m 5 20 10 50 2,5 2000 3,1 14 10,5 25 2 1550 1,5 7,5 7,5 0 1,2 1250 From the results obtained from fatigue testing specimens produced with the above settings, it is clear that the laser forming process has the potential to be employed as a production stage in the manufacture of wheel centre discs while maintaining adequate fatigue strength. Large beam diameters which cause heat penetration through the thickness of the specimen and hence microstructure breakdown should be avoided, since it was shown that these specimens exhibited impaired mechanical properties than those produced with a smaller laser beam diameter. The microstructural changes observed during the forming process needs to be considered since the mechanical properties of the material changes with a change in microstructure. A dramatic change in microstructure was observed; therefore it is of crucial importance that microstructural evaluation plays an important part in deciding optimum laser parameters for the forming process of ferrous alloys. During residual stress analysis, trends were observed between measurements taken at the same location of the samples; regardless whether measurements were taken on the laser irradiated side or the reverse side of the specimen. The only difference was the magnitude of the relieved residual stress. In most cases the obtained relieved residual stress was much smaller in magnitude than that of the original plate (in the bulk of the material). The surface indicated a slight tensile residual stress for most samples evaluated. A good correlation in distribution profile was obtained between microhardness and relieved residual stress distribution at the ‘middle of sample’ location. This indicates that an increase in hardness indicates an increase in residual stress magnitude for the laser formed specimens. In conclusion, this research has proved that it is possible to deform metal plate of a 3,5mm thickness with a CO2 laser system. The research also established the effect of process parameters on the final product’s shape/bend angle and characterised the effect of the laser forming process on the material’s mechanical properties and structural integrity.
- Full Text:
- Date Issued: 2005
- Authors: Els-Botes, Annelize
- Date: 2005
- Subjects: Steel -- Fatigue , Bending , Lasers , Sheet-steel -- Effect of lasers on
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9609 , http://hdl.handle.net/10948/176 , Steel -- Fatigue , Bending , Lasers , Sheet-steel -- Effect of lasers on
- Description: The nature and scope of this thesis can be divided into four categories: • FORMING PARAMETERS • Identification of various laser forming parameters in order to produce specimens of similar dimension (radius of curvature). • TEMPERATURE AND MICROSTRUCTURE • To study the effect of maximum temperature reached during the forming operation on the microstructure of the various specimens. • FATIGUE LIFE • Compare the fatigue life of the specimens produced by various laser parameters to that of the original material, and also the fatigue life of mechanical formed specimens. • RESIDUAL STRESS PROFILE Determine if the laser forming process induces detrimental residual stress magnitudes in the specimens. The main objective of this thesis was to gain an understanding of the way in which laser forming affects the fatigue performance and residual stress magnitude / distribution of dual phase steel. Although lasers have been used successfully in various manufacturing processes (welding, cutting, marking, etc.), little information is available on the influence of laser forming on many automotive alloys such as dual phase steel. The first part of the work involved a literature review of the process and factors affecting the laser forming process. It became clear from the literature overview that laser forming of sheet material thicker than 1mm is complex in nature. The variables that can influence the process are complicated and their interaction with each other is not easily controlled. The main parameters that were thus controlled in this study are as follows: • Laser power (P) • Laser head travel speed (v) • Laser beam size (mm) The chapters that follow the literature review, deals with the laser forming process of dual phase steel and the production of fatigue specimens using various laser parameters. It was found that the following laser parameters resulted in specimens with approximately the same radius of curvature: Laser power KW Beam diameter mm Interval spacing % Overlap Scanning velocity m/min Line Energy J/m 5 20 10 50 2,5 2000 3,1 14 10,5 25 2 1550 1,5 7,5 7,5 0 1,2 1250 From the results obtained from fatigue testing specimens produced with the above settings, it is clear that the laser forming process has the potential to be employed as a production stage in the manufacture of wheel centre discs while maintaining adequate fatigue strength. Large beam diameters which cause heat penetration through the thickness of the specimen and hence microstructure breakdown should be avoided, since it was shown that these specimens exhibited impaired mechanical properties than those produced with a smaller laser beam diameter. The microstructural changes observed during the forming process needs to be considered since the mechanical properties of the material changes with a change in microstructure. A dramatic change in microstructure was observed; therefore it is of crucial importance that microstructural evaluation plays an important part in deciding optimum laser parameters for the forming process of ferrous alloys. During residual stress analysis, trends were observed between measurements taken at the same location of the samples; regardless whether measurements were taken on the laser irradiated side or the reverse side of the specimen. The only difference was the magnitude of the relieved residual stress. In most cases the obtained relieved residual stress was much smaller in magnitude than that of the original plate (in the bulk of the material). The surface indicated a slight tensile residual stress for most samples evaluated. A good correlation in distribution profile was obtained between microhardness and relieved residual stress distribution at the ‘middle of sample’ location. This indicates that an increase in hardness indicates an increase in residual stress magnitude for the laser formed specimens. In conclusion, this research has proved that it is possible to deform metal plate of a 3,5mm thickness with a CO2 laser system. The research also established the effect of process parameters on the final product’s shape/bend angle and characterised the effect of the laser forming process on the material’s mechanical properties and structural integrity.
- Full Text:
- Date Issued: 2005
The development of best practice guidelines for the contingency management of health-related absenteeism in the motor manufacturing industry
- Authors: Werner, Amanda
- Date: 2005
- Subjects: Sick leave , Absenteeism (Labor) , Contingency theory (Management) , Automobile industry and trade -- South Africa
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9379 , http://hdl.handle.net/10948/160 , Sick leave , Absenteeism (Labor) , Contingency theory (Management) , Automobile industry and trade -- South Africa
- Description: The research problem in this study was to identify best practices for the contingency management of health-related absenteeism. To achieve this goal, the following actions were taken: A literature study was conducted to identify the scope and impact of health-related absenteeism on organisations and the legal parameters within which health-related absenteeism should be managed. A literature study was also conducted to identify strategies to prevent and reduce health-related absenteeism and strategies to ensure the continuous provision of products and services in periods of high absenteeism. The theoretical study focused on the management of absenteeism, wellness, ill-health/mental problems and HIV/AIDS, as well as contingency strategies aimed at maintaining production and service provision. iii The findings from the literature study were integrated into a model of best practices for the contingency management of health-related absenteeism. This model was used as a basis for the development of a survey questionnaire to determine whether senior human resources practitioners, occupational health practitioners or line managers, who were responsible for the management of health-related absenteeism in organisations, agreed with the best practice guidelines developed in the study. The survey was conducted in the motor and motor component industry in the Nelson Mandela Metropolitan Municipality and Buffalo City Metropole. The empirical results from the study showed a strong concurrence with the best practices guidelines developed in the study, with the exception of the strategies aimed at maintaining undisrupted production and service provision during periods of high absenteeism. In particular, disagreement was shown with regard to alternative work arrangements such as flexible work-hours, a compressed workweek, telecommuting and job-sharing. Absenteeism, in general, is an issue that organisations are challenged with on a daily basis. The proliferation of various diseases, specifically HIV/AIDS, is contributing to this problem. An integrated and strategic approach is required to deal effectively and constructively with the immediate and expected future impact of health-related issues on absenteeism. Organisations could use the best practices guidelines, identified in this study, as a mechanism to benchmark how well they manage health-related absenteeism
- Full Text:
- Date Issued: 2005
- Authors: Werner, Amanda
- Date: 2005
- Subjects: Sick leave , Absenteeism (Labor) , Contingency theory (Management) , Automobile industry and trade -- South Africa
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9379 , http://hdl.handle.net/10948/160 , Sick leave , Absenteeism (Labor) , Contingency theory (Management) , Automobile industry and trade -- South Africa
- Description: The research problem in this study was to identify best practices for the contingency management of health-related absenteeism. To achieve this goal, the following actions were taken: A literature study was conducted to identify the scope and impact of health-related absenteeism on organisations and the legal parameters within which health-related absenteeism should be managed. A literature study was also conducted to identify strategies to prevent and reduce health-related absenteeism and strategies to ensure the continuous provision of products and services in periods of high absenteeism. The theoretical study focused on the management of absenteeism, wellness, ill-health/mental problems and HIV/AIDS, as well as contingency strategies aimed at maintaining production and service provision. iii The findings from the literature study were integrated into a model of best practices for the contingency management of health-related absenteeism. This model was used as a basis for the development of a survey questionnaire to determine whether senior human resources practitioners, occupational health practitioners or line managers, who were responsible for the management of health-related absenteeism in organisations, agreed with the best practice guidelines developed in the study. The survey was conducted in the motor and motor component industry in the Nelson Mandela Metropolitan Municipality and Buffalo City Metropole. The empirical results from the study showed a strong concurrence with the best practices guidelines developed in the study, with the exception of the strategies aimed at maintaining undisrupted production and service provision during periods of high absenteeism. In particular, disagreement was shown with regard to alternative work arrangements such as flexible work-hours, a compressed workweek, telecommuting and job-sharing. Absenteeism, in general, is an issue that organisations are challenged with on a daily basis. The proliferation of various diseases, specifically HIV/AIDS, is contributing to this problem. An integrated and strategic approach is required to deal effectively and constructively with the immediate and expected future impact of health-related issues on absenteeism. Organisations could use the best practices guidelines, identified in this study, as a mechanism to benchmark how well they manage health-related absenteeism
- Full Text:
- Date Issued: 2005
The development of motivational strategies for public sector workers in Kenya
- Authors: Chepkilot, Ronald Kiprop
- Date: 2005
- Subjects: Public administration -- Kenya , Employee motivation , Civil service -- Kenya -- Personnel management
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9380 , http://hdl.handle.net/10948/161 , Public administration -- Kenya , Employee motivation , Civil service -- Kenya -- Personnel management
- Description: The purpose of this study was to develop motivational strategies for motivating public sector workers in Kenya. To achieve this objective the following procedure was followed: • An examination of the public service was undertaken and the following factors were considered: The history of the public service; Past government reform programmes; The problem of corruption; Future government reform programmes; and The motivational climate in the service. iv • A literature survey was conducted on the approaches used by organisations in motivating employees. The findings were used to develop a motivational strategy model. On the basis of the strategies in the model, a questionnaire was developed for the empirical research study. • The empirical study was undertaken to examine the level of motivation in the public service and to identify the motivational strategies currently used in the public service in Kenya. The study also sought to determine the extent to which public sector managers agreed or disagreed that the motivational strategies developed by the study would be effective in motivating employees in their organisations. The results of the empirical study were incorporated into the integrated motivational strategy model presented in chapter six. The study established that the level of motivation among the public sector workers was extremely low. According to the research findings, 87 per cent of the respondents indicated that the level of motivation of employees in their organisation was low while 13 per cent indicated that it was high. It was also established that the climate in the public service was not conducive for motivating employees: the indicators were lack of job security; very low salaries; limited training and development opportunities; lack of career development programmes and lack of adequate working tools and equipment. It was further established that the government could no longer afford to make any substantial increases in salaries to the workers because the wage bill was extremely high at the level of 9.6 per cent of the GDP. It was observed that any further increases in salaries would v have a negative impact on the economy of the country. In view of the above, this study becomes extremely relevant as it suggests ways of enhancing the levels of motivation in the public service to improve service delivery in the public sector without allocation of vast financial resources. The study strongly recommends the application of the integrated motivational strategy model in its entirety; to enhance the level of employee’s motivation and work performance and achieve efficiency and effectiveness in service delivery. The study also recommends that further research be carried out to determine the effects of corruption on employee motivation and ways of eliminating the vice in the public service.
- Full Text:
- Date Issued: 2005
- Authors: Chepkilot, Ronald Kiprop
- Date: 2005
- Subjects: Public administration -- Kenya , Employee motivation , Civil service -- Kenya -- Personnel management
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9380 , http://hdl.handle.net/10948/161 , Public administration -- Kenya , Employee motivation , Civil service -- Kenya -- Personnel management
- Description: The purpose of this study was to develop motivational strategies for motivating public sector workers in Kenya. To achieve this objective the following procedure was followed: • An examination of the public service was undertaken and the following factors were considered: The history of the public service; Past government reform programmes; The problem of corruption; Future government reform programmes; and The motivational climate in the service. iv • A literature survey was conducted on the approaches used by organisations in motivating employees. The findings were used to develop a motivational strategy model. On the basis of the strategies in the model, a questionnaire was developed for the empirical research study. • The empirical study was undertaken to examine the level of motivation in the public service and to identify the motivational strategies currently used in the public service in Kenya. The study also sought to determine the extent to which public sector managers agreed or disagreed that the motivational strategies developed by the study would be effective in motivating employees in their organisations. The results of the empirical study were incorporated into the integrated motivational strategy model presented in chapter six. The study established that the level of motivation among the public sector workers was extremely low. According to the research findings, 87 per cent of the respondents indicated that the level of motivation of employees in their organisation was low while 13 per cent indicated that it was high. It was also established that the climate in the public service was not conducive for motivating employees: the indicators were lack of job security; very low salaries; limited training and development opportunities; lack of career development programmes and lack of adequate working tools and equipment. It was further established that the government could no longer afford to make any substantial increases in salaries to the workers because the wage bill was extremely high at the level of 9.6 per cent of the GDP. It was observed that any further increases in salaries would v have a negative impact on the economy of the country. In view of the above, this study becomes extremely relevant as it suggests ways of enhancing the levels of motivation in the public service to improve service delivery in the public sector without allocation of vast financial resources. The study strongly recommends the application of the integrated motivational strategy model in its entirety; to enhance the level of employee’s motivation and work performance and achieve efficiency and effectiveness in service delivery. The study also recommends that further research be carried out to determine the effects of corruption on employee motivation and ways of eliminating the vice in the public service.
- Full Text:
- Date Issued: 2005
The oxidative coupling of phenols using stoichiometric metal oxidants
- Authors: Hoffmann, Eric
- Date: 2005
- Subjects: Phenols , Oxidation , Stoichiometry
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10977 , http://hdl.handle.net/10948/180 , Phenols , Oxidation , Stoichiometry
- Description: The oxidative coupling of 2,6-di-t-butylphenol under mild reaction conditions is well documented and the subject of many patents. However, the coupling of other monoand di- substituted phenols is not as well documented and thus there is scope for further investigation for providing a convenient, environmentally friendly and economically viable method for the oxidative coupling of these phenols. In this study, the oxidative coupling of a variety of alkylated phenolic substrates, 2-tbutylphenol, 2,6-di-t-butylphenol, 2,4 -di-t-butylphenol and ,4-dimethylphenol, using a range of different oxidizing agents, were investigated by means of experimental and/or theoretical means. The dibutylated aromatics provided the highest selectivities to their respective coupled products, with results obtained with the dimethyl analogue being only satisfactory, and that for 2 -t-butylphenol being totally inefficient. PM3 Molecular orbital (MO) calculations were used to predict the possible modes of coupling for the substrates 2,6 -di-t-butylphenol and 2,4-di-t-butylphenol, and these results were then compared with those obtained experimentally in the laboratory. Preliminarily, the coupling of unsubstituted phenolics was also assessed by means of MO calculations. Much emphasis was placed on Ce(IV) as the oxidant, and the reaction conditions under which it was used and the results that were obtained have not been reported before and are therefore novel. The oxidation of 2,4-di-t-butylphenol using Ce(IV) in the presence of methanesulphonic acid was optimized to afford high yields and selectivities to the desired ortho C-ortho C coupled product under mild reaction conditions. Various reaction parameters were also investigated in this case, such as varying the MeSO3H concentration, the solvent, the reaction temperature, the reaction time, the substrate loading, the rate of oxidant addition and the substrate to oxidant ratio. Ce(IV) also gave a high selectivity to the para C-para C coupled product when IX using 2,6-di-t-butylphenol as the substrate. However, it was not as effective with 2,4- dimethylphenol, and even less so with 2-t-butylphenol. The oxidation reactions of 2-t-butylphenol and 2,4-dimethylphenol with various coupling agents were also investigated with the intention of obtaining high selectivities to the respective desired coupled products. In these studies, 2-t-butylphenol afforded a large number of products, irrespective of the oxidant used. The dimethyl analogue was more selective, but results were not optimal. It was clear that the number of substituents on the phenol ring, their nature and their position with regards to the hydroxyl moiety was of great importance and made a significant impact on the preferred coupling mode of the substrate. It was observed that steric effects also played a major role in the outcome of these reactions: 2,6-di-t-butylphenol never afforded any C-O coupled products whereas 2-t-butylphenol, 2,4-di-t-butylphenol and 2,4-dimethylphenol all appeared to undergo some C-O coupling. Finally, reaction mechanisms were provided for both the K3Fe(CN)6 and Ce(IV) work, these reacting in basic and acidic media, respectively. It was proposed that both of these mechanisms operate through the initial formation of the phenoxyl radical.
- Full Text:
- Date Issued: 2005
- Authors: Hoffmann, Eric
- Date: 2005
- Subjects: Phenols , Oxidation , Stoichiometry
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10977 , http://hdl.handle.net/10948/180 , Phenols , Oxidation , Stoichiometry
- Description: The oxidative coupling of 2,6-di-t-butylphenol under mild reaction conditions is well documented and the subject of many patents. However, the coupling of other monoand di- substituted phenols is not as well documented and thus there is scope for further investigation for providing a convenient, environmentally friendly and economically viable method for the oxidative coupling of these phenols. In this study, the oxidative coupling of a variety of alkylated phenolic substrates, 2-tbutylphenol, 2,6-di-t-butylphenol, 2,4 -di-t-butylphenol and ,4-dimethylphenol, using a range of different oxidizing agents, were investigated by means of experimental and/or theoretical means. The dibutylated aromatics provided the highest selectivities to their respective coupled products, with results obtained with the dimethyl analogue being only satisfactory, and that for 2 -t-butylphenol being totally inefficient. PM3 Molecular orbital (MO) calculations were used to predict the possible modes of coupling for the substrates 2,6 -di-t-butylphenol and 2,4-di-t-butylphenol, and these results were then compared with those obtained experimentally in the laboratory. Preliminarily, the coupling of unsubstituted phenolics was also assessed by means of MO calculations. Much emphasis was placed on Ce(IV) as the oxidant, and the reaction conditions under which it was used and the results that were obtained have not been reported before and are therefore novel. The oxidation of 2,4-di-t-butylphenol using Ce(IV) in the presence of methanesulphonic acid was optimized to afford high yields and selectivities to the desired ortho C-ortho C coupled product under mild reaction conditions. Various reaction parameters were also investigated in this case, such as varying the MeSO3H concentration, the solvent, the reaction temperature, the reaction time, the substrate loading, the rate of oxidant addition and the substrate to oxidant ratio. Ce(IV) also gave a high selectivity to the para C-para C coupled product when IX using 2,6-di-t-butylphenol as the substrate. However, it was not as effective with 2,4- dimethylphenol, and even less so with 2-t-butylphenol. The oxidation reactions of 2-t-butylphenol and 2,4-dimethylphenol with various coupling agents were also investigated with the intention of obtaining high selectivities to the respective desired coupled products. In these studies, 2-t-butylphenol afforded a large number of products, irrespective of the oxidant used. The dimethyl analogue was more selective, but results were not optimal. It was clear that the number of substituents on the phenol ring, their nature and their position with regards to the hydroxyl moiety was of great importance and made a significant impact on the preferred coupling mode of the substrate. It was observed that steric effects also played a major role in the outcome of these reactions: 2,6-di-t-butylphenol never afforded any C-O coupled products whereas 2-t-butylphenol, 2,4-di-t-butylphenol and 2,4-dimethylphenol all appeared to undergo some C-O coupling. Finally, reaction mechanisms were provided for both the K3Fe(CN)6 and Ce(IV) work, these reacting in basic and acidic media, respectively. It was proposed that both of these mechanisms operate through the initial formation of the phenoxyl radical.
- Full Text:
- Date Issued: 2005
A critical analysis of organisational strategies for employee engagement
- Authors: Poisat, Paul
- Date: 2006
- Subjects: Employees -- Attitudes , Employee motivation , Personnel management
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9378 , http://hdl.handle.net/10948/466 , Employees -- Attitudes , Employee motivation , Personnel management
- Description: Organisations are continuously searching for ways to increase their competitiveness as a means to survive in the global economy. More recently approaches have focused on the role that people perform in bringing about competitive advantage. Research indicates that engaged employees contribute vastly to the financial bottom-line of the organisation (see section 3.2.2). The research problem in this study was to identify strategies that organisations can use to engage their employees. To achieve this objective a theoretical employee engagement model was presented. The presentation of the theoretical model consisted of the following sub-processes: § Firstly, a literature survey was conducted to determine the underlying drivers/constructs of employee engagement. Abstract iii § The second comprised surveying the literature dealing specifically with approaches for measuring employee engagement. § Thirdly, the literature was surveyed to identify strategies and models used by organisations for engaging employees. The theoretical employee engagement model served as a basis for the compilation of the survey questionnaire that determined the extent to which human resource practitioners and line managers agree with the theoretical model developed in this study. The questionnaire was administered to a random sample of individuals employed in the automotive cluster in the Nelson Mandela Metropolitan Municipality and the Buffalo City Metropole. The empirical results obtained from the survey indicated that respondents strongly concurred with the theoretical employee engagement model presented in the study. These results were included in the theoretical model, which lead to the development of the integrated organisational employee engagement model. The model comprises of four interrelated categories that all contribute to enhancing employees’ engagement. These categories are organisational leadership, organisational culture, organisational strategies and the manager’s role. From the literature survey and the study it became clear that the role of the manager, had the most significant impact on employee engagement of all the categories. In addition, the integrated organisational employee engagement model can be used by organisations as an applied strategy for the measurement of employee engagement. The main findings from this research are that 60 per cent of organisations that participated in the empirical study had implemented strategies to engage their employees. However, the majority of organisations reporting not having an engagement strategy were among organisations that employed less than 700 employees (smaller organisations). The study also highlighted certain variables that required special attention, especially when implementing employee engagement within the South African context. South African companies as compared to their overseas counterparts, rated organisational engagement variables such as remuneration, benefits and gain sharing lower. A further variable that was identified by the study requiring special attention was, ‘senior management shows a sincere interest in employees’ well-being’. A final point emanating from the study is that the implementation of employee engagement, as a strategy to enhance organisational competitiveness, must be viewed as a continuous process. Organisations should prior, to the implementation of an employee engagement strategy, consider whether they are prepared to share engagement results, take corrective action commensurate with the results and deal with employee expectations that may be incurred. The strategies espoused by the integrated organisational employee engagement model developed in this study, can be used by organisations to increase organisational competitiveness by improving their employees’ level of engagement.
- Full Text:
- Date Issued: 2006
- Authors: Poisat, Paul
- Date: 2006
- Subjects: Employees -- Attitudes , Employee motivation , Personnel management
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9378 , http://hdl.handle.net/10948/466 , Employees -- Attitudes , Employee motivation , Personnel management
- Description: Organisations are continuously searching for ways to increase their competitiveness as a means to survive in the global economy. More recently approaches have focused on the role that people perform in bringing about competitive advantage. Research indicates that engaged employees contribute vastly to the financial bottom-line of the organisation (see section 3.2.2). The research problem in this study was to identify strategies that organisations can use to engage their employees. To achieve this objective a theoretical employee engagement model was presented. The presentation of the theoretical model consisted of the following sub-processes: § Firstly, a literature survey was conducted to determine the underlying drivers/constructs of employee engagement. Abstract iii § The second comprised surveying the literature dealing specifically with approaches for measuring employee engagement. § Thirdly, the literature was surveyed to identify strategies and models used by organisations for engaging employees. The theoretical employee engagement model served as a basis for the compilation of the survey questionnaire that determined the extent to which human resource practitioners and line managers agree with the theoretical model developed in this study. The questionnaire was administered to a random sample of individuals employed in the automotive cluster in the Nelson Mandela Metropolitan Municipality and the Buffalo City Metropole. The empirical results obtained from the survey indicated that respondents strongly concurred with the theoretical employee engagement model presented in the study. These results were included in the theoretical model, which lead to the development of the integrated organisational employee engagement model. The model comprises of four interrelated categories that all contribute to enhancing employees’ engagement. These categories are organisational leadership, organisational culture, organisational strategies and the manager’s role. From the literature survey and the study it became clear that the role of the manager, had the most significant impact on employee engagement of all the categories. In addition, the integrated organisational employee engagement model can be used by organisations as an applied strategy for the measurement of employee engagement. The main findings from this research are that 60 per cent of organisations that participated in the empirical study had implemented strategies to engage their employees. However, the majority of organisations reporting not having an engagement strategy were among organisations that employed less than 700 employees (smaller organisations). The study also highlighted certain variables that required special attention, especially when implementing employee engagement within the South African context. South African companies as compared to their overseas counterparts, rated organisational engagement variables such as remuneration, benefits and gain sharing lower. A further variable that was identified by the study requiring special attention was, ‘senior management shows a sincere interest in employees’ well-being’. A final point emanating from the study is that the implementation of employee engagement, as a strategy to enhance organisational competitiveness, must be viewed as a continuous process. Organisations should prior, to the implementation of an employee engagement strategy, consider whether they are prepared to share engagement results, take corrective action commensurate with the results and deal with employee expectations that may be incurred. The strategies espoused by the integrated organisational employee engagement model developed in this study, can be used by organisations to increase organisational competitiveness by improving their employees’ level of engagement.
- Full Text:
- Date Issued: 2006
A strategy for the development of team leaders in the East Cape motor industry cluster : a competency based approach
- Authors: Melamed, Graham Morrison
- Date: 2006
- Subjects: Leadership , Teams in the workplace , Automobile industry and trade -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:8568 , http://hdl.handle.net/10948/419 , Leadership , Teams in the workplace , Automobile industry and trade -- South Africa -- Eastern Cape
- Description: The research undertaken in this study was to identify the strategy needed to be adopted by the East Cape Motor Industry Cluster (ECMIC) in order to develop the competencies of its Team Leaders. v Hamel and Prahalad (1994: 28) are of the opinion that the focus of a company must move from current market share, to the share of tomorrow’s opportunities that the company can reasonably expect to gain. The company must therefore consider what it can achieve with its existing set of competencies, and what new competencies need to be acquired in order to prosper in the future. The development of competencies is thus deemed to be critical to the South African economy as the various local automotive manufacturers enter the export field. The ECMIC has traditionally been considered the heart of the automotive industry in South Africa with three of the major manufacturers located in the Nelson Mandela and Buffalo City Metropoles. In order to support these manufacturers, a vast number of component manufacturers and service providers have been established to support the automotive manufacturers both in the ECMIC and in other areas of the country. Since the establishment of a democratic South Africa and the removal of sanctions, the automotive industry has started to establish itself globally. This study will undertake a literature study of the application of competencies in the workplace, teams and team leaders and how competencies are applied in the ECMIC. The results of an empirical study into core competencies in the ECMIC will be used to elucidate a set of competencies which will be used to develop a strategy utilising the competency approach in team leaders in the ECMIC.
- Full Text:
- Date Issued: 2006
- Authors: Melamed, Graham Morrison
- Date: 2006
- Subjects: Leadership , Teams in the workplace , Automobile industry and trade -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:8568 , http://hdl.handle.net/10948/419 , Leadership , Teams in the workplace , Automobile industry and trade -- South Africa -- Eastern Cape
- Description: The research undertaken in this study was to identify the strategy needed to be adopted by the East Cape Motor Industry Cluster (ECMIC) in order to develop the competencies of its Team Leaders. v Hamel and Prahalad (1994: 28) are of the opinion that the focus of a company must move from current market share, to the share of tomorrow’s opportunities that the company can reasonably expect to gain. The company must therefore consider what it can achieve with its existing set of competencies, and what new competencies need to be acquired in order to prosper in the future. The development of competencies is thus deemed to be critical to the South African economy as the various local automotive manufacturers enter the export field. The ECMIC has traditionally been considered the heart of the automotive industry in South Africa with three of the major manufacturers located in the Nelson Mandela and Buffalo City Metropoles. In order to support these manufacturers, a vast number of component manufacturers and service providers have been established to support the automotive manufacturers both in the ECMIC and in other areas of the country. Since the establishment of a democratic South Africa and the removal of sanctions, the automotive industry has started to establish itself globally. This study will undertake a literature study of the application of competencies in the workplace, teams and team leaders and how competencies are applied in the ECMIC. The results of an empirical study into core competencies in the ECMIC will be used to elucidate a set of competencies which will be used to develop a strategy utilising the competency approach in team leaders in the ECMIC.
- Full Text:
- Date Issued: 2006
Monitoring and intelligent control for complex curvature friction stir welding
- Hua, Tao
- Authors: Hua, Tao
- Date: 2006
- Subjects: Friction welding , Fuzzy systems
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9612 , http://hdl.handle.net/10948/420 , Friction welding , Fuzzy systems
- Description: A multi-input multi-output system to implement on-line process monitoring and intelligent control of complex curvature friction stir welding was proposed. An extra rotation axis was added to the existing three translation axes to perform friction stir welding of complex curvature other than straight welding line. A clamping system was designed for locating and holding the workpieces to bear the large force involved in the process between the welding tool and workpieces. Process parameters (feed rate, spindle speed, tilt angle and plunge depth), and process conditions (parent material and curvature), were used as factors for the orthogonal array experiments to collect sensor data of force, torque and tool temperature using multiple sensors and telemetry system. Using statistic analysis of the experimental data, sensitive signal features were selected to train the feed-forward neural networks, which were used for mapping the relationships between process parameters, process conditions and sensor data. A fuzzy controller with initial input/output membership functions and fuzzy rules generated on-line from the trained neural network was applied to perceive process condition changes and make adjustment of process parameters to maintain tool/workpiece contact and energy input. Input/output scaling factors of the fuzzy controller were tuned on-line to improve output response to the amount and trend of control variable deviation from the reference value. Simulation results showed that the presented neuro-fuzzy control scheme has adaptability to process conditions such as parent material and curvature changes, and that the control variables were well regulated. The presented neuro-fuzzy control scheme can be also expected to be applied in other multi-input multi-output machining processes.
- Full Text:
- Date Issued: 2006
- Authors: Hua, Tao
- Date: 2006
- Subjects: Friction welding , Fuzzy systems
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9612 , http://hdl.handle.net/10948/420 , Friction welding , Fuzzy systems
- Description: A multi-input multi-output system to implement on-line process monitoring and intelligent control of complex curvature friction stir welding was proposed. An extra rotation axis was added to the existing three translation axes to perform friction stir welding of complex curvature other than straight welding line. A clamping system was designed for locating and holding the workpieces to bear the large force involved in the process between the welding tool and workpieces. Process parameters (feed rate, spindle speed, tilt angle and plunge depth), and process conditions (parent material and curvature), were used as factors for the orthogonal array experiments to collect sensor data of force, torque and tool temperature using multiple sensors and telemetry system. Using statistic analysis of the experimental data, sensitive signal features were selected to train the feed-forward neural networks, which were used for mapping the relationships between process parameters, process conditions and sensor data. A fuzzy controller with initial input/output membership functions and fuzzy rules generated on-line from the trained neural network was applied to perceive process condition changes and make adjustment of process parameters to maintain tool/workpiece contact and energy input. Input/output scaling factors of the fuzzy controller were tuned on-line to improve output response to the amount and trend of control variable deviation from the reference value. Simulation results showed that the presented neuro-fuzzy control scheme has adaptability to process conditions such as parent material and curvature changes, and that the control variables were well regulated. The presented neuro-fuzzy control scheme can be also expected to be applied in other multi-input multi-output machining processes.
- Full Text:
- Date Issued: 2006
Restoring trust by verifying information integrity through continuous auditing
- Authors: Flowerday, Stephen
- Date: 2006
- Subjects: Auditing, Internal , Corporate governance
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9796 , http://hdl.handle.net/10948/504 , http://hdl.handle.net/10948/d1011920 , Auditing, Internal , Corporate governance
- Description: Corporate scandals such as Enron, WorldCom and Parmalat, have focused recent governance efforts in the domain of financial reporting due to fraudulent and/or erroneous accounting practices. In addition, the ineffectiveness of the current system of controls has been highlighted, including that some directors have been weak and ineffective monitors of managers. This board of director ‘weakness’ has called for additional mechanisms for monitoring and controlling of management, focusing on financial reporting. This problem intensifies in that today companies function in real-time, and decisions are based on available realtime financial information. However, the assurances provided by traditional auditing take place months after the transactions have occurred and therefore, a trust problem arises because information is not verified in real-time. Consequently, the errors and fraud concealed within the financial information is not discovered until months later. To address this trust problem a conceptual causal model is proposed in this study based on the principles of systems theory. The emergent property of the causal model is increased trust and control. This study establishes that mutual assurances assist in building trust and that information security assists in safeguarding trust. Subsequently, in order to have a positive relationship between the company directors and various stakeholders, uncertainty needs to be contained, and the level of trust needs to surpass the perceived risks. The study concludes that assurances need to be provided in real-time to restore stakeholder confidence and trust in the domain of financial reporting. In order to provide assurances in real-time, continuous auditing is required to verify the integrity of financial information when it becomes available, and not months later. A continuous auditing process has its foundations grounded in information technology and attends to the challenges in real-time by addressing the standardisation of data to enable effective analysis, the validation of the accuracy of the data and the reliability of the system.
- Full Text:
- Date Issued: 2006
- Authors: Flowerday, Stephen
- Date: 2006
- Subjects: Auditing, Internal , Corporate governance
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9796 , http://hdl.handle.net/10948/504 , http://hdl.handle.net/10948/d1011920 , Auditing, Internal , Corporate governance
- Description: Corporate scandals such as Enron, WorldCom and Parmalat, have focused recent governance efforts in the domain of financial reporting due to fraudulent and/or erroneous accounting practices. In addition, the ineffectiveness of the current system of controls has been highlighted, including that some directors have been weak and ineffective monitors of managers. This board of director ‘weakness’ has called for additional mechanisms for monitoring and controlling of management, focusing on financial reporting. This problem intensifies in that today companies function in real-time, and decisions are based on available realtime financial information. However, the assurances provided by traditional auditing take place months after the transactions have occurred and therefore, a trust problem arises because information is not verified in real-time. Consequently, the errors and fraud concealed within the financial information is not discovered until months later. To address this trust problem a conceptual causal model is proposed in this study based on the principles of systems theory. The emergent property of the causal model is increased trust and control. This study establishes that mutual assurances assist in building trust and that information security assists in safeguarding trust. Subsequently, in order to have a positive relationship between the company directors and various stakeholders, uncertainty needs to be contained, and the level of trust needs to surpass the perceived risks. The study concludes that assurances need to be provided in real-time to restore stakeholder confidence and trust in the domain of financial reporting. In order to provide assurances in real-time, continuous auditing is required to verify the integrity of financial information when it becomes available, and not months later. A continuous auditing process has its foundations grounded in information technology and attends to the challenges in real-time by addressing the standardisation of data to enable effective analysis, the validation of the accuracy of the data and the reliability of the system.
- Full Text:
- Date Issued: 2006
MISSTEV : model for information security shared tacit espoused values
- Authors: Thomson, Kerry-Lynn
- Date: 2007
- Subjects: Computer security -- Management , Management information systems -- Security measures , Data protection
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9787 , http://hdl.handle.net/10948/717 , Computer security -- Management , Management information systems -- Security measures , Data protection
- Description: One of the most critical assets in most organisations is information. It is often described as the lifeblood of an organisation. For this reason, it is vital that this asset is protected through sound information security practices. However, the incorrect and indifferent behaviour of employees often leads to information assets becoming vulnerable. Incorrect employee behaviour could have an extremely negative impact on the protection of information. An information security solution should be a fundamental component in most organisations. It is, however, possible for an organisation to have the most comprehensive physical and technical information security controls in place, but the operational controls, and associated employee behaviour, have not received much consideration. Therefore, the issue of employee behaviour must be addressed in an organisation to assist in ensuring the protection of information assets. The corporate culture of an organisation is largely responsible for the actions and behaviour of employees. Therefore, to address operational information security controls, the corporate culture of an organisation should be considered. To ensure the integration of information security into the corporate culture of an organisation, the protection of information should become part of the way the employees conduct their everyday tasks – from senior management, right throughout the entire organisation. Therefore, information security should become an integral component of the corporate culture of the organisation. To address the integration of information security into the corporate culture of an organisation, a model was developed which depicted the learning stages and modes of knowledge creation necessary to transform the corporate culture into one that is information security aware.
- Full Text:
- Date Issued: 2007
- Authors: Thomson, Kerry-Lynn
- Date: 2007
- Subjects: Computer security -- Management , Management information systems -- Security measures , Data protection
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9787 , http://hdl.handle.net/10948/717 , Computer security -- Management , Management information systems -- Security measures , Data protection
- Description: One of the most critical assets in most organisations is information. It is often described as the lifeblood of an organisation. For this reason, it is vital that this asset is protected through sound information security practices. However, the incorrect and indifferent behaviour of employees often leads to information assets becoming vulnerable. Incorrect employee behaviour could have an extremely negative impact on the protection of information. An information security solution should be a fundamental component in most organisations. It is, however, possible for an organisation to have the most comprehensive physical and technical information security controls in place, but the operational controls, and associated employee behaviour, have not received much consideration. Therefore, the issue of employee behaviour must be addressed in an organisation to assist in ensuring the protection of information assets. The corporate culture of an organisation is largely responsible for the actions and behaviour of employees. Therefore, to address operational information security controls, the corporate culture of an organisation should be considered. To ensure the integration of information security into the corporate culture of an organisation, the protection of information should become part of the way the employees conduct their everyday tasks – from senior management, right throughout the entire organisation. Therefore, information security should become an integral component of the corporate culture of the organisation. To address the integration of information security into the corporate culture of an organisation, a model was developed which depicted the learning stages and modes of knowledge creation necessary to transform the corporate culture into one that is information security aware.
- Full Text:
- Date Issued: 2007
A model to improve the effectiveness of the Occupational Health and Safety Inspectorate function relative to South African construction
- Authors: Geminiani, Franco Luciano
- Date: 2008
- Subjects: Construction industry -- Safety measures
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9695 , http://hdl.handle.net/10948/719 , Construction industry -- Safety measures
- Description: Irrespective of all the efforts made by the Department of Labour (DoL) and other relevant stakeholders to improve the performance of Occupational Health and Safety (OH&S) in construction. In the Construction Industry, there is still a very high level of accidents and fatalities in South Africa. Injuries and accidents to workers do not help a community in any nation. The construction industry in South Africa is generally known to be one of the most hazardous and has one of the most dismal OH&S records among all industrial segments with an unacceptably high level of injuries and fatalities resulting in considerable human suffering. A doctoral study was recently conducted with the aim of investigating the effectiveness and performance of the DoL OH&S Inspectorate in South Africa. The empirical study was conducted among a range of stakeholders: civil engineering and building contractors; OH&S consultants; project managers; DoL inspectors; and designers by means of a questionnaire survey. The methodology adopted in this study included the exploratory and descriptive methods, which entails the technique of observation including the use of questionnaires and data analysis. The salient findings of the study are presented and elucidate that the DoL OH&S Inspectorate is not effective in terms of OH&S relative to the construction industry in South Africa. Conclusions and recommendations included expound that the DoL OH&S Inspectorate is not effectively conducting their duties reinforcing the need for a reviewed OH&S Inspectorate model framework. The proposed structured normative model consists of fundamental elements which would improve the effectiveness of the DoL OH&S Inspectorate. The findings of the study with recommendations are included.
- Full Text:
- Date Issued: 2008
- Authors: Geminiani, Franco Luciano
- Date: 2008
- Subjects: Construction industry -- Safety measures
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9695 , http://hdl.handle.net/10948/719 , Construction industry -- Safety measures
- Description: Irrespective of all the efforts made by the Department of Labour (DoL) and other relevant stakeholders to improve the performance of Occupational Health and Safety (OH&S) in construction. In the Construction Industry, there is still a very high level of accidents and fatalities in South Africa. Injuries and accidents to workers do not help a community in any nation. The construction industry in South Africa is generally known to be one of the most hazardous and has one of the most dismal OH&S records among all industrial segments with an unacceptably high level of injuries and fatalities resulting in considerable human suffering. A doctoral study was recently conducted with the aim of investigating the effectiveness and performance of the DoL OH&S Inspectorate in South Africa. The empirical study was conducted among a range of stakeholders: civil engineering and building contractors; OH&S consultants; project managers; DoL inspectors; and designers by means of a questionnaire survey. The methodology adopted in this study included the exploratory and descriptive methods, which entails the technique of observation including the use of questionnaires and data analysis. The salient findings of the study are presented and elucidate that the DoL OH&S Inspectorate is not effective in terms of OH&S relative to the construction industry in South Africa. Conclusions and recommendations included expound that the DoL OH&S Inspectorate is not effectively conducting their duties reinforcing the need for a reviewed OH&S Inspectorate model framework. The proposed structured normative model consists of fundamental elements which would improve the effectiveness of the DoL OH&S Inspectorate. The findings of the study with recommendations are included.
- Full Text:
- Date Issued: 2008
Development of a reciprocating aerofoil wind energy harvester
- Authors: Phillips, Russell Leslie
- Date: 2008
- Subjects: Windmills , Wind power , Wind turbines
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9622 , http://hdl.handle.net/10948/899 , Windmills , Wind power , Wind turbines
- Description: Cross flow wind turbines are not unique. The performance of Savonius and Darrieus turbines is well documented. Both share the advantage of being able to accept fluid flow from any direction. The Savonius is drag based and hence has poor power output while the Darrieus is lift based. Due to the fact that the Darrieus has fixed blades the fluid flow through the rotor does not result in optimal lift being generated at all points in the rotation circle. A drawback of the Darrieus system is that it has to operate at a high tip-to wind-speed ratio to obtain reasonable performance with the fixed blades. Deviation from a small optimal range of tip speed ratios results in poor performance. The Darrieus also has poor starting torque. The research conducted in this project focused on overcoming the shortcomings of other turbines and developing an effective cross flow turbine capable of good performance. A number of different concepts were experimented with, however all were based on a symmetrical aerofoil presented to the actual relative airflow at an angle that would produce the highest lift force at all times. The lift force was then utilized to generate movement and to do work on an electrical generator. All concepts contemplated were researched to ascertain their appropriateness for the intended application. During development of the final experimental platform and after lodging of a provisional patent (RSA 2007/00927) it was ascertained that the design shared some similarities with an American patent 5503525 dated 28/4/1994. This patent employed complex electronic sensing and control equipment for control of blade angle. This was thought to be overly complex and costly, particularly for small scale wind energy generation applications and a simpler mechanical solution was sought in the design of the final experimental platform used in this project. The design of the mechanical control system was refined in an attempt to make it simpler, more durable and employ the least number of moving parts. Literature studies and patent searches conducted, suggested that the mechanical control system as developed for the final experimental platform was unique. The enormous variation in the power available from the wind at the different wind speeds likely to be encountered by the device necessitated some means of control. In high wind conditions control of the amount of wind power into the device was deemed to be the preferable means of control. A number of different concepts to achieve this were devised and tested. The final concept employed limited the tail angle deflection and hence the lift produced by the aerofoils. This resulted in a seamless “throttle” control allowing the device to be used in any wind strength by adjusting the control to a position that resulted in the device receiving a suitable amount of power from the wind. The outcome of performance tests conducted indicated that the device has the potential to be developed into a viable wind turbine for both small and large scale applications. The ability to control the power input from the wind to the machine from zero to a maximum is considered to be one of the most beneficial outcomes of this project and together with the quiet operation and low speed, are considered the main advantages of the device over existing wind turbine designs. The possibilities of using the device to compress air for energy storage are exciting avenues that warrant further research.
- Full Text:
- Date Issued: 2008
- Authors: Phillips, Russell Leslie
- Date: 2008
- Subjects: Windmills , Wind power , Wind turbines
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9622 , http://hdl.handle.net/10948/899 , Windmills , Wind power , Wind turbines
- Description: Cross flow wind turbines are not unique. The performance of Savonius and Darrieus turbines is well documented. Both share the advantage of being able to accept fluid flow from any direction. The Savonius is drag based and hence has poor power output while the Darrieus is lift based. Due to the fact that the Darrieus has fixed blades the fluid flow through the rotor does not result in optimal lift being generated at all points in the rotation circle. A drawback of the Darrieus system is that it has to operate at a high tip-to wind-speed ratio to obtain reasonable performance with the fixed blades. Deviation from a small optimal range of tip speed ratios results in poor performance. The Darrieus also has poor starting torque. The research conducted in this project focused on overcoming the shortcomings of other turbines and developing an effective cross flow turbine capable of good performance. A number of different concepts were experimented with, however all were based on a symmetrical aerofoil presented to the actual relative airflow at an angle that would produce the highest lift force at all times. The lift force was then utilized to generate movement and to do work on an electrical generator. All concepts contemplated were researched to ascertain their appropriateness for the intended application. During development of the final experimental platform and after lodging of a provisional patent (RSA 2007/00927) it was ascertained that the design shared some similarities with an American patent 5503525 dated 28/4/1994. This patent employed complex electronic sensing and control equipment for control of blade angle. This was thought to be overly complex and costly, particularly for small scale wind energy generation applications and a simpler mechanical solution was sought in the design of the final experimental platform used in this project. The design of the mechanical control system was refined in an attempt to make it simpler, more durable and employ the least number of moving parts. Literature studies and patent searches conducted, suggested that the mechanical control system as developed for the final experimental platform was unique. The enormous variation in the power available from the wind at the different wind speeds likely to be encountered by the device necessitated some means of control. In high wind conditions control of the amount of wind power into the device was deemed to be the preferable means of control. A number of different concepts to achieve this were devised and tested. The final concept employed limited the tail angle deflection and hence the lift produced by the aerofoils. This resulted in a seamless “throttle” control allowing the device to be used in any wind strength by adjusting the control to a position that resulted in the device receiving a suitable amount of power from the wind. The outcome of performance tests conducted indicated that the device has the potential to be developed into a viable wind turbine for both small and large scale applications. The ability to control the power input from the wind to the machine from zero to a maximum is considered to be one of the most beneficial outcomes of this project and together with the quiet operation and low speed, are considered the main advantages of the device over existing wind turbine designs. The possibilities of using the device to compress air for energy storage are exciting avenues that warrant further research.
- Full Text:
- Date Issued: 2008
Practical and scalable synthesis of N-Alkyl-N,N'Diacylhydrazines
- Authors: Gouws, Melissa Claire
- Date: 2008
- Subjects: Chemistry, Organic , Acylation , Insecticides
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10406 , http://hdl.handle.net/10948/696 , Chemistry, Organic , Acylation , Insecticides
- Description: The work presented in this thesis is concerned with the evaluation of potential synthetic routes for the diacylhydrazine group of compounds, and particularly, unsymmetrical diacylhydrazines. Diacylhydrazines form the basis for a relatively new group of insecticides that have molt accelerating properties, and which are considered to offer substantial advantages over other insecticides used for the control of certain insects. The overall objective for this study is to evaluate different potential synthetic routes for a model diacylhydrazine with the view to define potentially scaleable routes. The compound selected for this study was the unsymmetrical diacylhydrazine, N-[N-(tertbutyl) phenylcarbonylamino](4-methylphenyl)-carboxamide since it offers the same range of challenges that would be expected for the synthesis of other similar unsymmetrical diacylhydrazines. Thus, the synthesis of unsymmetrical diacylhydrazines require two reaction steps: The first step is the synthesis of the intermediate mono-acylhydrazine, while the second step is the synthesis of the desired diacylhydrazine from the intermediate mono-acylhydrazine. The most important factor in the two-step reaction sequence is to obtain a high degree of selectivity for the desired mono-acylhydrazine isomer. Acylation of t-butylhydrazine using 4-methylbenzoyl chloride can produce the desired product N-[(tert-butyl)amino](4-methylphenyl)carboxamide in yields above 90 percent, but this reaction produces a variety of by-products, including the “wrong” isomer (N-amino-N- (tert-butyl)(4-methylphenyl)carboximide). Unexpected byproducts for this particular acylation reaction, not previously reported in the literature have also been identified during this investigation. This includes a de-butylated diacylhydrazine, (4-methylphenyl)- N-[(4-methylphenyl)carbonylamino] carboxamide. Although the reaction between tert-butylhydrazine and 4-methylbenzaldehyde is very selective giving near quantitative yields of the desired hydrazone, the subsequent conversion of the hydrazone into the desired mono-acylhydrazine is problematic. The most promising route appears via bromination to form the hydrazidic bromide, followed by hydrolysis of the hydrazidic bromide. Yields for the bromination reaction during this investigation were somewhat higher than that reported previously in literature. Hydrolysis of the hydrazidic bromide, apparently also results in the hydrolysis of the reaction product to give an ester of the free acid (when an ester solvent is used). The synthesis of N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide was only briefly considered to evaluate essentially two approaches, namely: · The conversion of the monoacylhydrazine, N-[(tert-butyl)amino](4- methylphenyl)carboxamide, by acylating with either benzoyl chloride or methylbenzoate (gave 86 percent N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide when benzoyl chloride was used as acylating agent); and · The one-pot conversion of the hydrazone, [(1E)-2-(4-methylphenyl)-1- azavinyl](tert-butyl)]amine, by bromination/hydrolysis and acylation. In this case, benzoyl chloride (2 percent N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide), benzoic acid (80.67 percent N-[N-(tertbutyl) phenylcarbonylamino](4-methylphenyl)carboxamide) were evaluated as potential acylating agents.
- Full Text:
- Date Issued: 2008
- Authors: Gouws, Melissa Claire
- Date: 2008
- Subjects: Chemistry, Organic , Acylation , Insecticides
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10406 , http://hdl.handle.net/10948/696 , Chemistry, Organic , Acylation , Insecticides
- Description: The work presented in this thesis is concerned with the evaluation of potential synthetic routes for the diacylhydrazine group of compounds, and particularly, unsymmetrical diacylhydrazines. Diacylhydrazines form the basis for a relatively new group of insecticides that have molt accelerating properties, and which are considered to offer substantial advantages over other insecticides used for the control of certain insects. The overall objective for this study is to evaluate different potential synthetic routes for a model diacylhydrazine with the view to define potentially scaleable routes. The compound selected for this study was the unsymmetrical diacylhydrazine, N-[N-(tertbutyl) phenylcarbonylamino](4-methylphenyl)-carboxamide since it offers the same range of challenges that would be expected for the synthesis of other similar unsymmetrical diacylhydrazines. Thus, the synthesis of unsymmetrical diacylhydrazines require two reaction steps: The first step is the synthesis of the intermediate mono-acylhydrazine, while the second step is the synthesis of the desired diacylhydrazine from the intermediate mono-acylhydrazine. The most important factor in the two-step reaction sequence is to obtain a high degree of selectivity for the desired mono-acylhydrazine isomer. Acylation of t-butylhydrazine using 4-methylbenzoyl chloride can produce the desired product N-[(tert-butyl)amino](4-methylphenyl)carboxamide in yields above 90 percent, but this reaction produces a variety of by-products, including the “wrong” isomer (N-amino-N- (tert-butyl)(4-methylphenyl)carboximide). Unexpected byproducts for this particular acylation reaction, not previously reported in the literature have also been identified during this investigation. This includes a de-butylated diacylhydrazine, (4-methylphenyl)- N-[(4-methylphenyl)carbonylamino] carboxamide. Although the reaction between tert-butylhydrazine and 4-methylbenzaldehyde is very selective giving near quantitative yields of the desired hydrazone, the subsequent conversion of the hydrazone into the desired mono-acylhydrazine is problematic. The most promising route appears via bromination to form the hydrazidic bromide, followed by hydrolysis of the hydrazidic bromide. Yields for the bromination reaction during this investigation were somewhat higher than that reported previously in literature. Hydrolysis of the hydrazidic bromide, apparently also results in the hydrolysis of the reaction product to give an ester of the free acid (when an ester solvent is used). The synthesis of N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide was only briefly considered to evaluate essentially two approaches, namely: · The conversion of the monoacylhydrazine, N-[(tert-butyl)amino](4- methylphenyl)carboxamide, by acylating with either benzoyl chloride or methylbenzoate (gave 86 percent N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide when benzoyl chloride was used as acylating agent); and · The one-pot conversion of the hydrazone, [(1E)-2-(4-methylphenyl)-1- azavinyl](tert-butyl)]amine, by bromination/hydrolysis and acylation. In this case, benzoyl chloride (2 percent N-[N-(tert-butyl)phenylcarbonylamino](4-methyl phenyl)carboxamide), benzoic acid (80.67 percent N-[N-(tertbutyl) phenylcarbonylamino](4-methylphenyl)carboxamide) were evaluated as potential acylating agents.
- Full Text:
- Date Issued: 2008
Selective para-funtionalization of phenol
- Authors: Indurkar, Jayant R
- Date: 2008
- Subjects: Phenol
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10402 , http://hdl.handle.net/10948/710 , Phenol
- Description: In previous work done in our laboratories, a method was discovered to produce phenolic mono-ethers from 4-hydroxyacetophenone and other 4-hydroxyketones by treating with ammonium peroxy-disulfate in an alcohol as a reaction solvent and in the presence of concentrated sulphuric acid or other strong protonic acids. Since this method of producing 4-alkoxyphenol ethers provides a very convenient way to modify hydroquinone and substituted hydroquinones to produce a variety of phenol mono-ethers, it was of interest to study the general scope of this reaction, including a more detailed investigation of the reaction mechanism. In previous studies, it was suggested that interaction between the aromatic pi-system of hydroquinone and the cyclohexa-2,5-diene structure of benzoquinone plays a significant role during the reaction. It was therefore of interest to investigate whether other compounds that are also capable of forming the cyclohexa-2,5-diene structure, will interact in a manner analogous to the hydroquinone/benzoquinone couple. Two specific compounds were selected for this purpose, namely 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one . The scope of etherification reactions of hydroquinone-benzoquinone or hydroquinone/benzoquinone like substrates such as 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one in the presence of acid catalyst and alcohols was investigated. These studies showed that hydroquinone, 4- nitrosophenol and 4-(diphenylmethylene)cyclohexa-2,5-dien-1-one successfully affords the phenolic ethers in good to excellent yield. For example, quantitative yield of 4-methoxyphenol could be obtained from a 1:1 mixture of hydroquinone and benzoquinone at the reflux temperature of methanol. In order to study the reaction mechanism, the cross-over reaction between tertbutylhydroquinone and benzoquinone (or hydroquinone and tertbutylbenzoquinone) was studied in detail. The results of these cross-over reactions were used to propose a mechanistic pathway that could explain the requirement for pi-interaction between the hydroquinone and benzoquinone molecules, the role of the acid catalyst, as well as the relative rates of hydroquinone and benzoquinone consumption during these reactions. The mechanism was also capable of explaining all the reaction products observed during these reactions. The work was then extended to reactions of 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one with methanol in the presence of either hydroquinone or benzoquinone. The results of these investigations strongly suggest the presence of similar interactions between these molecules that also influence the outcome of the reactions. The exploitation of pi-interactions between two molecules of these types investigated during this work opens an interesting field of chemistry. Clearly, the level of understanding developed during this work is only beginning to address this interesting field of chemistry and much work will need to be done to gain a fuller understanding of the chemistry involved as well as the potential synthetic value of these interactions.
- Full Text:
- Date Issued: 2008
- Authors: Indurkar, Jayant R
- Date: 2008
- Subjects: Phenol
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10402 , http://hdl.handle.net/10948/710 , Phenol
- Description: In previous work done in our laboratories, a method was discovered to produce phenolic mono-ethers from 4-hydroxyacetophenone and other 4-hydroxyketones by treating with ammonium peroxy-disulfate in an alcohol as a reaction solvent and in the presence of concentrated sulphuric acid or other strong protonic acids. Since this method of producing 4-alkoxyphenol ethers provides a very convenient way to modify hydroquinone and substituted hydroquinones to produce a variety of phenol mono-ethers, it was of interest to study the general scope of this reaction, including a more detailed investigation of the reaction mechanism. In previous studies, it was suggested that interaction between the aromatic pi-system of hydroquinone and the cyclohexa-2,5-diene structure of benzoquinone plays a significant role during the reaction. It was therefore of interest to investigate whether other compounds that are also capable of forming the cyclohexa-2,5-diene structure, will interact in a manner analogous to the hydroquinone/benzoquinone couple. Two specific compounds were selected for this purpose, namely 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one . The scope of etherification reactions of hydroquinone-benzoquinone or hydroquinone/benzoquinone like substrates such as 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one in the presence of acid catalyst and alcohols was investigated. These studies showed that hydroquinone, 4- nitrosophenol and 4-(diphenylmethylene)cyclohexa-2,5-dien-1-one successfully affords the phenolic ethers in good to excellent yield. For example, quantitative yield of 4-methoxyphenol could be obtained from a 1:1 mixture of hydroquinone and benzoquinone at the reflux temperature of methanol. In order to study the reaction mechanism, the cross-over reaction between tertbutylhydroquinone and benzoquinone (or hydroquinone and tertbutylbenzoquinone) was studied in detail. The results of these cross-over reactions were used to propose a mechanistic pathway that could explain the requirement for pi-interaction between the hydroquinone and benzoquinone molecules, the role of the acid catalyst, as well as the relative rates of hydroquinone and benzoquinone consumption during these reactions. The mechanism was also capable of explaining all the reaction products observed during these reactions. The work was then extended to reactions of 4-nitrosophenol and 4- (diphenylmethylene)cyclohexa-2,5-dien-1-one with methanol in the presence of either hydroquinone or benzoquinone. The results of these investigations strongly suggest the presence of similar interactions between these molecules that also influence the outcome of the reactions. The exploitation of pi-interactions between two molecules of these types investigated during this work opens an interesting field of chemistry. Clearly, the level of understanding developed during this work is only beginning to address this interesting field of chemistry and much work will need to be done to gain a fuller understanding of the chemistry involved as well as the potential synthetic value of these interactions.
- Full Text:
- Date Issued: 2008
A model for evaluating training and development initiatives in the Botswana public service
- Tshukudu, Theophilus Tebetso
- Authors: Tshukudu, Theophilus Tebetso
- Date: 2009
- Subjects: Civil service -- Personnel management -- Botswana , Civil service -- Labor productivity -- Botswana , Civil service -- Botswana -- Evaluation , Employees -- Training of , Public administration
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9384 , http://hdl.handle.net/10948/879 , Civil service -- Personnel management -- Botswana , Civil service -- Labor productivity -- Botswana , Civil service -- Botswana -- Evaluation , Employees -- Training of , Public administration
- Description: The purpose of this study was to develop an integrated model for evaluating training and development initiatives used by the Botswana public service. To achieve this goal, the following actions were taken: A literature study was conducted to identify the scope and impact of an effective training and development initiative and its evaluation; A literature study was conducted to identify strategies for evaluating training and development initiatives. The theoretical study focused on effective training and development strategies and their evaluation and critical organisational factors that contribute to successful training evaluation; The findings from the literature study were integrated into a model for evaluating training and development initiatives to be used by the Botswana public service; and This model was used as the basis for the development of a survey questionnaire to determine whether trainers, training managers and supervisors who were responsible for training and development in the public service agreed with the effective strategies for evaluating training and development developed in the study. The survey was conducted in ministries and departments in the south east district of Botswana, mainly in Gaborone, where ministries and government departments are located. The empirical results from the study showed that the majority of respondents’ training and development activities were not evaluated and that there is no link between training and development and performance management. In particular, disagreements were shown with regard to ten strategies and critical organisational factors. Evaluation of training and development in general, is an issue that organisations are challenged with on a daily basis. Lack of skills by trainers on how to evaluate training and development is one major contributing factor to this problem. An integrated and strategic approach towards the evaluation of training and development is required to effectively and constructively train and development employees according to strategic organisational goals, rather than according to individual trainee’s goals.
- Full Text:
- Date Issued: 2009
- Authors: Tshukudu, Theophilus Tebetso
- Date: 2009
- Subjects: Civil service -- Personnel management -- Botswana , Civil service -- Labor productivity -- Botswana , Civil service -- Botswana -- Evaluation , Employees -- Training of , Public administration
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9384 , http://hdl.handle.net/10948/879 , Civil service -- Personnel management -- Botswana , Civil service -- Labor productivity -- Botswana , Civil service -- Botswana -- Evaluation , Employees -- Training of , Public administration
- Description: The purpose of this study was to develop an integrated model for evaluating training and development initiatives used by the Botswana public service. To achieve this goal, the following actions were taken: A literature study was conducted to identify the scope and impact of an effective training and development initiative and its evaluation; A literature study was conducted to identify strategies for evaluating training and development initiatives. The theoretical study focused on effective training and development strategies and their evaluation and critical organisational factors that contribute to successful training evaluation; The findings from the literature study were integrated into a model for evaluating training and development initiatives to be used by the Botswana public service; and This model was used as the basis for the development of a survey questionnaire to determine whether trainers, training managers and supervisors who were responsible for training and development in the public service agreed with the effective strategies for evaluating training and development developed in the study. The survey was conducted in ministries and departments in the south east district of Botswana, mainly in Gaborone, where ministries and government departments are located. The empirical results from the study showed that the majority of respondents’ training and development activities were not evaluated and that there is no link between training and development and performance management. In particular, disagreements were shown with regard to ten strategies and critical organisational factors. Evaluation of training and development in general, is an issue that organisations are challenged with on a daily basis. Lack of skills by trainers on how to evaluate training and development is one major contributing factor to this problem. An integrated and strategic approach towards the evaluation of training and development is required to effectively and constructively train and development employees according to strategic organisational goals, rather than according to individual trainee’s goals.
- Full Text:
- Date Issued: 2009
Development of a process for the preparation of linalool from CIS-2-pinanol
- Authors: Buddoo, Subash Ramnarain
- Date: 2009
- Subjects: Odors , Perfumes -- History , Perfumes -- Formulae , Fermentation
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10425 , http://hdl.handle.net/10948/d1016219
- Description: Linalool is a key intermediate for the production of important fragrance chemicals such as geraniol, nerol, geranial, and neral. Linalool can be produced via a two-step process from α-pinene which is a major component of crude sulphated turpentine (CST) a foul-smelling, volatile waste product of the pulp and paper industry. The key step in this process is the pyrolysis step which involves the isomerisation of cis-2-pinanol to linalool and requires high temperatures (600-650°C) and is not very selective due to the decomposition of the product itself under these conditions. A client of the CSIR, Teubes Pty. Ltd., is a manufacturer of flavour and fragrance compounds for the local and international fragrance market and expressed an interest in producing linalool since the company would then gain access to other valuable fragrance chemicals via relatively simple processes. Earlier work conducted by AECI, R & D did not meet with much success since the selectivity to linalool was very poor and the process could hardly be deemed as scalable. The main objective of this project was therefore to develop a process for the selective isomerisation of cis-2-pinanol to linalool with minimum by-product formation and using process equipment that could be scaled to full-scale production. Since cis-2- pinanol could not be purchased in sufficient quantities for process development, a process had to be developed for the bench-scale preparation of kilogram quantities of cis-2-pinanol from α-pinene obtained from the client. Although this synthesis formed a minor part of this investigation, several process improvements and innovations were introduced to produce high quality cis-2-pinanol, in very good yields at kilogram scale. A major part of this investigation was the design and set up of a pyrolyis rig capable of operating at elevated temperatures (400 - 750°C) for the evaluation of various process parameters. Various vaporizer, reactor, and condensation systems were evaluated for their ability to cope with the demanding conditions on a consistent basis. The initial part of the investigation was a screening exercise to evaluate various process parameters as well as solvents, materials of construction, catalysts, etc. A comprehensive statistical design was also conducted to determine the critical process parameters and the model obtained was used to predict the optimum conditions required for the preparation of in-specification product on a consistent basis. These conditions were used in the preparation of a 1kg sample which was required by theclient for market evaluation purposes. The use of a novel microreactor system was also evaluated for the pinanol pyrolysis reaction. To our knowledge, this is the first time that a microreactor has been successfully used for this type of reaction in the Fragrance industry and a patent application is being filed by the CSIR. The kinetics of the reaction in both the tubular reactor system and the microreactor system was investigated. Computer modelling studies on both the systems were also conducted. The raw material cost to produce a kilogram of linalool is $1.40. There is a significant margin of 60.8 percent between the raw material cost of linalool and the current selling price ($3.57/kg). This clearly indicates that the project is potentially feasible from an economic point of view and we can now proceed with confidence to the next stage which is the engineering design, building and commissioning of the large scale pyrolysis rig. The rest of the process steps will be conducted on existing equipment currently present at the CSIR’s large scale facility (Imbiza in Isando, Gauteng).
- Full Text:
- Date Issued: 2009
- Authors: Buddoo, Subash Ramnarain
- Date: 2009
- Subjects: Odors , Perfumes -- History , Perfumes -- Formulae , Fermentation
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10425 , http://hdl.handle.net/10948/d1016219
- Description: Linalool is a key intermediate for the production of important fragrance chemicals such as geraniol, nerol, geranial, and neral. Linalool can be produced via a two-step process from α-pinene which is a major component of crude sulphated turpentine (CST) a foul-smelling, volatile waste product of the pulp and paper industry. The key step in this process is the pyrolysis step which involves the isomerisation of cis-2-pinanol to linalool and requires high temperatures (600-650°C) and is not very selective due to the decomposition of the product itself under these conditions. A client of the CSIR, Teubes Pty. Ltd., is a manufacturer of flavour and fragrance compounds for the local and international fragrance market and expressed an interest in producing linalool since the company would then gain access to other valuable fragrance chemicals via relatively simple processes. Earlier work conducted by AECI, R & D did not meet with much success since the selectivity to linalool was very poor and the process could hardly be deemed as scalable. The main objective of this project was therefore to develop a process for the selective isomerisation of cis-2-pinanol to linalool with minimum by-product formation and using process equipment that could be scaled to full-scale production. Since cis-2- pinanol could not be purchased in sufficient quantities for process development, a process had to be developed for the bench-scale preparation of kilogram quantities of cis-2-pinanol from α-pinene obtained from the client. Although this synthesis formed a minor part of this investigation, several process improvements and innovations were introduced to produce high quality cis-2-pinanol, in very good yields at kilogram scale. A major part of this investigation was the design and set up of a pyrolyis rig capable of operating at elevated temperatures (400 - 750°C) for the evaluation of various process parameters. Various vaporizer, reactor, and condensation systems were evaluated for their ability to cope with the demanding conditions on a consistent basis. The initial part of the investigation was a screening exercise to evaluate various process parameters as well as solvents, materials of construction, catalysts, etc. A comprehensive statistical design was also conducted to determine the critical process parameters and the model obtained was used to predict the optimum conditions required for the preparation of in-specification product on a consistent basis. These conditions were used in the preparation of a 1kg sample which was required by theclient for market evaluation purposes. The use of a novel microreactor system was also evaluated for the pinanol pyrolysis reaction. To our knowledge, this is the first time that a microreactor has been successfully used for this type of reaction in the Fragrance industry and a patent application is being filed by the CSIR. The kinetics of the reaction in both the tubular reactor system and the microreactor system was investigated. Computer modelling studies on both the systems were also conducted. The raw material cost to produce a kilogram of linalool is $1.40. There is a significant margin of 60.8 percent between the raw material cost of linalool and the current selling price ($3.57/kg). This clearly indicates that the project is potentially feasible from an economic point of view and we can now proceed with confidence to the next stage which is the engineering design, building and commissioning of the large scale pyrolysis rig. The rest of the process steps will be conducted on existing equipment currently present at the CSIR’s large scale facility (Imbiza in Isando, Gauteng).
- Full Text:
- Date Issued: 2009
Factors influencing survivor qualities after downsizing
- Authors: Chipunza, Crispen
- Date: 2009
- Subjects: Downsizing of organizations -- South Africa , Organizational change -- South Africa , Cost control , Unemployment -- Psychological aspects
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9381 , http://hdl.handle.net/10948/1219 , Downsizing of organizations -- South Africa , Organizational change -- South Africa , Cost control , Unemployment -- Psychological aspects
- Description: Today organisations all over the world have to cope with the ever-increasing rate of local and global change. Those in developing countries have to cope with the inefficiencies engendered by state-led economic, developmental and political strategies, such as new government regulations. These have had an impact on the management of human resources and are exemplified by an increasing adoption of strategies meant to reduce pressure on costs and margins. An increasing popular management response to these challenges has been to engage in some form of organisational restructuring such as downsizing. Often employees who remain (survivors) after downsizing are not given much attention, yet the achievement of new strategic goals depends on the survivors having positive attitudes, relentless commitment and high motivation. Research indicates that employees who are motivated and committed contribute vastly to the financial-bottom-line of the organisation. Therefore, downsizing organisations should continuously search for ways to increase such qualities among their survivors. The objective of this study was to identify the factors that influence the attitudes, commitment and motivation of survivors in a developing economy with a volatile environment. To achieve this objective, a theoretical survivor quality model was presented. In order to present the model, firstly, a literature survey on the importance of survivor quality in terms of attitudes, commitment, and motivation among survivors was conducted. Secondly, literature survey pertaining to the drivers of survivor quality was done, and thirdly, literature dealing with strategies to deal with survivor quality was surveyed. The theoretical survivor quality model was used to compile the research instrument that determined the attitudinal, commitment and motivational levels of survivors, how the three constructs are related after downsizing, as well as the factors influencing the observed levels. The questionnaire was randomly distributed among survivors in the selected manufacturing organisations in Zimbabwe. The empirical results obtained from the study showed that survivors in a developing economy with a volatile environment had moderate levels of attitudes, commitment ad motivation. Two categories of factors were identified as important in influencing these levels. They were downsizing strategy and demographic factors. The downsizing strategy factors were communication and victim support, while education, age, and number of years employed emerged as the demographic factors. The study further highlighted that older survivors with less education contributed more to the moderate levels of attitude, commitment and motivation observed. The study highlights that these variables must be taken into consideration when implementing downsizing in an economically volatile environment in order to manage survivor quality. A further point emanating from the study is that prior to downsizing, organisations should adopt effective communication strategies throughout the process. The key factors identified as influencing survivor quality in this study were integrated into the survivor quality model which can be used by other organisations in a similar context to manage survivor quality in order to increase their efficiency, effectiveness, iv and competitive advantage after downsizing.
- Full Text:
- Date Issued: 2009
- Authors: Chipunza, Crispen
- Date: 2009
- Subjects: Downsizing of organizations -- South Africa , Organizational change -- South Africa , Cost control , Unemployment -- Psychological aspects
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:9381 , http://hdl.handle.net/10948/1219 , Downsizing of organizations -- South Africa , Organizational change -- South Africa , Cost control , Unemployment -- Psychological aspects
- Description: Today organisations all over the world have to cope with the ever-increasing rate of local and global change. Those in developing countries have to cope with the inefficiencies engendered by state-led economic, developmental and political strategies, such as new government regulations. These have had an impact on the management of human resources and are exemplified by an increasing adoption of strategies meant to reduce pressure on costs and margins. An increasing popular management response to these challenges has been to engage in some form of organisational restructuring such as downsizing. Often employees who remain (survivors) after downsizing are not given much attention, yet the achievement of new strategic goals depends on the survivors having positive attitudes, relentless commitment and high motivation. Research indicates that employees who are motivated and committed contribute vastly to the financial-bottom-line of the organisation. Therefore, downsizing organisations should continuously search for ways to increase such qualities among their survivors. The objective of this study was to identify the factors that influence the attitudes, commitment and motivation of survivors in a developing economy with a volatile environment. To achieve this objective, a theoretical survivor quality model was presented. In order to present the model, firstly, a literature survey on the importance of survivor quality in terms of attitudes, commitment, and motivation among survivors was conducted. Secondly, literature survey pertaining to the drivers of survivor quality was done, and thirdly, literature dealing with strategies to deal with survivor quality was surveyed. The theoretical survivor quality model was used to compile the research instrument that determined the attitudinal, commitment and motivational levels of survivors, how the three constructs are related after downsizing, as well as the factors influencing the observed levels. The questionnaire was randomly distributed among survivors in the selected manufacturing organisations in Zimbabwe. The empirical results obtained from the study showed that survivors in a developing economy with a volatile environment had moderate levels of attitudes, commitment ad motivation. Two categories of factors were identified as important in influencing these levels. They were downsizing strategy and demographic factors. The downsizing strategy factors were communication and victim support, while education, age, and number of years employed emerged as the demographic factors. The study further highlighted that older survivors with less education contributed more to the moderate levels of attitude, commitment and motivation observed. The study highlights that these variables must be taken into consideration when implementing downsizing in an economically volatile environment in order to manage survivor quality. A further point emanating from the study is that prior to downsizing, organisations should adopt effective communication strategies throughout the process. The key factors identified as influencing survivor quality in this study were integrated into the survivor quality model which can be used by other organisations in a similar context to manage survivor quality in order to increase their efficiency, effectiveness, iv and competitive advantage after downsizing.
- Full Text:
- Date Issued: 2009
The development of a commercial production process for p-menthane-3,8-diol
- Authors: Rust, Nico
- Date: 2009
- Subjects: Insect pests -- Control , Repellents
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10427 , http://hdl.handle.net/10948/d1018273
- Description: The synthesis of p-menthane-3,8-diol via the acid-catalyzed cyclization of citronellal in a dilute aqueous sulphuric acid medium was investigated using conventional batch and continuous systems in order to develop a commercial production process for said p-menthane-3,8-diol (PMD). The batch studies conducted during the first part of this study showed that the formation of PMD from citronellal occurs via an intra-molecular Prins reaction that results in the formation of both the desired PMD product, as well as the partially hydrated isopulegol. It was shown that the formationof the by- product, PMD-acetal, results from the reaction between an intermediate, 5-methyl-2- isopropylcyclohexanol, and the citronellal starting material, and not from the reaction between PMD and citronellal as previously reported. Kinetic studies confirmed the existence of a complicated kinetic model. The formation of PMD from citronellal displayed typical pseudo first order kinetics up to conversions of 70 after which the kinetic model becomes complicated as the result of the establishment of quasi equilibrium reactions between PMD and isopulegol (dehydration of PMD and hydration of isopulegol) and between PMD the PMD-acetal, both systems being acid catalysed. The PMD-acetal formation reaction appears to be second order with respect to PMD. Scale-up studies of the batch process to 30L and 50L scales showed that it would be extremely difficult to limit the level of PMD-acetal formation below the desired level of 1 percent, even if citronellal conversions are restricted to about 50 percent. During studies conducted on a commercially availablemicro-structured organic synthesis plant (OSP) it was shown that it is possible to perform the PMD reaction as a continuous process. The results obtained showed that the use of a micro-mixer such as the caterpillar micro-mixer did not provide enough residence time in order for desirable conversions (- 40 percent) to be obtained. By combining themicro-mixer with delay-loops of different thicknesses and lengths, and using increasing reaction temperatures, it was shown that the conversion of citronellal could be improved to some extent, but compared poorly to the expected conversions for a well-stirred batch reactor. By packing selected delay loops with inert SiC particles, improved mass transfer was observed between the organic and aqueous phases as reflected in the increased conversion of citronellal. Using the observations that were made during the use of the OSP, a continuous-flow, tubular reactor system was designed and constructed. Advanced statistical techniques were used to investigate the effect of variables such as temperature, acid concentration, reactor length, flow rate and the organic to aqueous ratio on the rate and selectivity of the reaction. Mathematical models were derived for citronellal conversion, yield of PMD and yield of PMD- acetals, and used to predict the concentrations of citronellal, PMD and PMD-acetals at set experimental conditions. The results obtained showed that it was possible to obtain a product which approached desired specifications.Downstream processing of the PMD reaction mixture as it exits the reactor requires phase separation and neutralization of the acid catalyst solution, followed by further work-up to recover unreacted starting material and intermediates for recycle back to the synthesis reactor, followed by purification of crude PMD to the desired specification. The study showed that neutralization, prior or after phase separation, does not affect the selectivity of the PMD to such a great extent, but does influence the relative conversion due to extended contact of the catalyst with the organic phase after the reaction is terminated. Recovery of unreacted citronellal and isopulegol could be achieved by a simple vacuum evaporation step, which may either be carried out in a batch manner using traditional distillation equipment, or in a continuous process using wiped-film (short path) techniques. It was also shown that selective crystallization of PMD from the crude product mixture by addition of a solvent, such as heptanes or hexane proved to be the best way of achieving the desired product specification.
- Full Text:
- Date Issued: 2009
- Authors: Rust, Nico
- Date: 2009
- Subjects: Insect pests -- Control , Repellents
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10427 , http://hdl.handle.net/10948/d1018273
- Description: The synthesis of p-menthane-3,8-diol via the acid-catalyzed cyclization of citronellal in a dilute aqueous sulphuric acid medium was investigated using conventional batch and continuous systems in order to develop a commercial production process for said p-menthane-3,8-diol (PMD). The batch studies conducted during the first part of this study showed that the formation of PMD from citronellal occurs via an intra-molecular Prins reaction that results in the formation of both the desired PMD product, as well as the partially hydrated isopulegol. It was shown that the formationof the by- product, PMD-acetal, results from the reaction between an intermediate, 5-methyl-2- isopropylcyclohexanol, and the citronellal starting material, and not from the reaction between PMD and citronellal as previously reported. Kinetic studies confirmed the existence of a complicated kinetic model. The formation of PMD from citronellal displayed typical pseudo first order kinetics up to conversions of 70 after which the kinetic model becomes complicated as the result of the establishment of quasi equilibrium reactions between PMD and isopulegol (dehydration of PMD and hydration of isopulegol) and between PMD the PMD-acetal, both systems being acid catalysed. The PMD-acetal formation reaction appears to be second order with respect to PMD. Scale-up studies of the batch process to 30L and 50L scales showed that it would be extremely difficult to limit the level of PMD-acetal formation below the desired level of 1 percent, even if citronellal conversions are restricted to about 50 percent. During studies conducted on a commercially availablemicro-structured organic synthesis plant (OSP) it was shown that it is possible to perform the PMD reaction as a continuous process. The results obtained showed that the use of a micro-mixer such as the caterpillar micro-mixer did not provide enough residence time in order for desirable conversions (- 40 percent) to be obtained. By combining themicro-mixer with delay-loops of different thicknesses and lengths, and using increasing reaction temperatures, it was shown that the conversion of citronellal could be improved to some extent, but compared poorly to the expected conversions for a well-stirred batch reactor. By packing selected delay loops with inert SiC particles, improved mass transfer was observed between the organic and aqueous phases as reflected in the increased conversion of citronellal. Using the observations that were made during the use of the OSP, a continuous-flow, tubular reactor system was designed and constructed. Advanced statistical techniques were used to investigate the effect of variables such as temperature, acid concentration, reactor length, flow rate and the organic to aqueous ratio on the rate and selectivity of the reaction. Mathematical models were derived for citronellal conversion, yield of PMD and yield of PMD- acetals, and used to predict the concentrations of citronellal, PMD and PMD-acetals at set experimental conditions. The results obtained showed that it was possible to obtain a product which approached desired specifications.Downstream processing of the PMD reaction mixture as it exits the reactor requires phase separation and neutralization of the acid catalyst solution, followed by further work-up to recover unreacted starting material and intermediates for recycle back to the synthesis reactor, followed by purification of crude PMD to the desired specification. The study showed that neutralization, prior or after phase separation, does not affect the selectivity of the PMD to such a great extent, but does influence the relative conversion due to extended contact of the catalyst with the organic phase after the reaction is terminated. Recovery of unreacted citronellal and isopulegol could be achieved by a simple vacuum evaporation step, which may either be carried out in a batch manner using traditional distillation equipment, or in a continuous process using wiped-film (short path) techniques. It was also shown that selective crystallization of PMD from the crude product mixture by addition of a solvent, such as heptanes or hexane proved to be the best way of achieving the desired product specification.
- Full Text:
- Date Issued: 2009
The selective dechlorination of poly-chlorophenols
- Authors: Thomas, Maxwell Paul
- Date: 2009
- Subjects: Sewage -- Purification -- Chlorination , Pesticides -- Toxicology , Chlorine -- Toxicology
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10391 , http://hdl.handle.net/10948/1124 , Sewage -- Purification -- Chlorination , Pesticides -- Toxicology , Chlorine -- Toxicology
- Description: Liquid phase catalytic hydrodechlorinations can provide a convenient and environmentally friendly method for treating organic chlorinated compounds in waste streams generated during the manufacturing of agrochemicals. During such treatment hydrochloric acid is generated as a by-product, which can be easily neutralized employing a base to yield an inorganic salt. This work describes the results obtained during the liquid phase hydrodechlorination of 2,6-dichlorophenol (2,6-DCP) and 2,4,6-trichlorophenol (2,4,6-TCP). The hydrodechlorination of these chlorinated phenolic compounds in a mixture of methanol and water was investigated using supported and unsupported palladium catalysts to yield lower chlorinated phenols or phenol. Various parameters were investigated such as catalyst concentration, ammonium formate concentration, effect of base addition and effect of temperature. During this study two methods of hydrodechlorination were also investigated such as hydride-transfer hydrogenolysis, using ammonium formate, and hydrogenolysis, using dihydrogen. These methods offer a mild treatment in terms of the reaction temperature with temperatures used below 800C. A comparison of the palladium catalyst systems using these methods also showed that Pd/C produced the best results in terms of the hydrodechlorination rate and the selectivity towards phenol. When the ammonium formate method was used, complete hydrodechlorination of both substrates was achieved in 1h of reaction time at a selectivity of 100 percent towards phenol. A comparison of the method using dihydrogen and Pd/C showed that the reaction rate and the selectivity towards phenol during the hydrodechlorination of 2,6-DCP were 87.92 percent and 93.30 percent. Similarly, the reaction rate and selectivity during 2,4,6- TCP hydrodechlorination were 63.77 percent and 70.57 percent. These results were achieved in a reaction time of 3 hours. A high catalyst loading increases the reaction rate at the expense of selectivity, due to the formation of cyclohexanone, formed during further hydrogenation of phenol. The formation of cyclohexanone was limited at high temperatures (ca. 800C) with none detected during the hydrodechlorination of 2,6-DCP and 0.19 percent during the hydrodechlorination of 2,4,6-TCP. Evaluation of the hydrodechlorination parameters showed that the catalytic efficiency of the Pd/C catalysts was inhibited as the reaction proceeded due to the formation of HCl as by-product. A significant increase in the reaction rate was achieved when the reaction was performed in the presence of an inorganic base, which neutralized HCl.
- Full Text:
- Date Issued: 2009
- Authors: Thomas, Maxwell Paul
- Date: 2009
- Subjects: Sewage -- Purification -- Chlorination , Pesticides -- Toxicology , Chlorine -- Toxicology
- Language: English
- Type: Thesis , Doctoral , DTech
- Identifier: vital:10391 , http://hdl.handle.net/10948/1124 , Sewage -- Purification -- Chlorination , Pesticides -- Toxicology , Chlorine -- Toxicology
- Description: Liquid phase catalytic hydrodechlorinations can provide a convenient and environmentally friendly method for treating organic chlorinated compounds in waste streams generated during the manufacturing of agrochemicals. During such treatment hydrochloric acid is generated as a by-product, which can be easily neutralized employing a base to yield an inorganic salt. This work describes the results obtained during the liquid phase hydrodechlorination of 2,6-dichlorophenol (2,6-DCP) and 2,4,6-trichlorophenol (2,4,6-TCP). The hydrodechlorination of these chlorinated phenolic compounds in a mixture of methanol and water was investigated using supported and unsupported palladium catalysts to yield lower chlorinated phenols or phenol. Various parameters were investigated such as catalyst concentration, ammonium formate concentration, effect of base addition and effect of temperature. During this study two methods of hydrodechlorination were also investigated such as hydride-transfer hydrogenolysis, using ammonium formate, and hydrogenolysis, using dihydrogen. These methods offer a mild treatment in terms of the reaction temperature with temperatures used below 800C. A comparison of the palladium catalyst systems using these methods also showed that Pd/C produced the best results in terms of the hydrodechlorination rate and the selectivity towards phenol. When the ammonium formate method was used, complete hydrodechlorination of both substrates was achieved in 1h of reaction time at a selectivity of 100 percent towards phenol. A comparison of the method using dihydrogen and Pd/C showed that the reaction rate and the selectivity towards phenol during the hydrodechlorination of 2,6-DCP were 87.92 percent and 93.30 percent. Similarly, the reaction rate and selectivity during 2,4,6- TCP hydrodechlorination were 63.77 percent and 70.57 percent. These results were achieved in a reaction time of 3 hours. A high catalyst loading increases the reaction rate at the expense of selectivity, due to the formation of cyclohexanone, formed during further hydrogenation of phenol. The formation of cyclohexanone was limited at high temperatures (ca. 800C) with none detected during the hydrodechlorination of 2,6-DCP and 0.19 percent during the hydrodechlorination of 2,4,6-TCP. Evaluation of the hydrodechlorination parameters showed that the catalytic efficiency of the Pd/C catalysts was inhibited as the reaction proceeded due to the formation of HCl as by-product. A significant increase in the reaction rate was achieved when the reaction was performed in the presence of an inorganic base, which neutralized HCl.
- Full Text:
- Date Issued: 2009