Exploring the statistical equivalence of the English and Xhosa versions of the Woodcock-Munõz Language Survey
- Authors: Ntantiso, Mzamo
- Date: 2009
- Subjects: Equivalence (Linguistics) , Woodcock-Muñoz Language Survey
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9952 , http://hdl.handle.net/10948/d1018620
- Description: This study explored statistical equivalence of the adapted Xhosa and English version of the Woodcock-Muñoz Language Survey (WMLS) by investigating group differences on each subscale, in terms of mean scores, index reliability, and item characteristics for two language groups. A Convenience quota sampling technique was used to select 188 Xhosa (n = 188) and 198 English (n = 198) learners from Grades 6 and 7 living in rural and urban Eastern Cape. The WMLS Xhosa and English versions were administered to learners in their first languages. Significant mean group differences were found, but differences were not found on the reliability indices, or mean item characteristics. This pointed in the direction of statistical equivalence. However, scrutiny of the item characteristics of the individual items per subscale indicated possible problems at an item level that need to be investigated further with differential functioning analyses. Thus, stringent DIF analyses were suggested for future research on DIF items before the versions of the WMLS can be considered as equivalent.
- Full Text:
- Date Issued: 2009
- Authors: Ntantiso, Mzamo
- Date: 2009
- Subjects: Equivalence (Linguistics) , Woodcock-Muñoz Language Survey
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9952 , http://hdl.handle.net/10948/d1018620
- Description: This study explored statistical equivalence of the adapted Xhosa and English version of the Woodcock-Muñoz Language Survey (WMLS) by investigating group differences on each subscale, in terms of mean scores, index reliability, and item characteristics for two language groups. A Convenience quota sampling technique was used to select 188 Xhosa (n = 188) and 198 English (n = 198) learners from Grades 6 and 7 living in rural and urban Eastern Cape. The WMLS Xhosa and English versions were administered to learners in their first languages. Significant mean group differences were found, but differences were not found on the reliability indices, or mean item characteristics. This pointed in the direction of statistical equivalence. However, scrutiny of the item characteristics of the individual items per subscale indicated possible problems at an item level that need to be investigated further with differential functioning analyses. Thus, stringent DIF analyses were suggested for future research on DIF items before the versions of the WMLS can be considered as equivalent.
- Full Text:
- Date Issued: 2009
Economic evaluation of possible loss of Prosopis pods as a result of biological control in the Northern Cape Province, South Africa
- Authors: Nqobizitha, Dube
- Date: 2009
- Subjects: Trees -- South Africa , Mimosaceae , Forests and forestry -- South Africa , Forest conservation -- Economic aspects -- South Africa , Mimosaceae -- Biological control -- South Africa , Mesquite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11165 , http://hdl.handle.net/10353/394 , Trees -- South Africa , Mimosaceae , Forests and forestry -- South Africa , Forest conservation -- Economic aspects -- South Africa , Mimosaceae -- Biological control -- South Africa , Mesquite -- South Africa
- Description: Species of Prosopis (Mimosaceae), or mesquite, are native to the Americas and introduced in South Africa as agro forestry trees to provide wood, fodder and shade in the late 1800s. In the Northern Cape Province, these trees have been particularly used for their pods by local farmers and local industry. However due to Prosopis’ ability to spread rapidly there has been increasing pressure to step up control of the tree. Due to the costs associated with most control methods biological control has been singled out as the most viable control method worth pursuing. This thesis attempts to explain and shed light on the effects that increased biological control of Prosopis would have on the farming community and Prosopis based businesses in the area. Two hypothetical scenarios were used, the first being a possible 50% reduction in available pods and the other a possible 100% reduction. In an effort to explain these effects data was collected from a series of collection activities in the form of a pilot study and two unique questionnaire surveys. Twenty-seven farmers and one Prosopis based business were interviewed at random with the data analysed and documented. Results showed that the business community is the main user of pods incurring crippling losses in the event of a 50% or 100% decrease in available pods. Using control costs from working for water De Aar long term costs of the presence of Prosopis were estimated and compared to the estimated provincial cost of losing pods giving a cost comparison ratio of (α)270 million : Y(N(15.7million)). Only 48% of the respondents valued pods and 11% had traded in pods, the top concern resulting from the invasion was the loss of underground water. With a 50% decline in available pods, all respondents indicated unchanged effects. However empirical results showed that with a 100% decline in pods estimate losses of R 5 818 per farm are expected. The cost comparison ratio showing the losses farmers bore with Prosopis in the area and the losses they would suffer with a 100% decline in pods was R11 389 + (K): R5 818. In light of the empirical results, policy recommendations that support the introduction of more effective biological control agents have been made with areas for further research identified and discussed.
- Full Text:
- Date Issued: 2009
- Authors: Nqobizitha, Dube
- Date: 2009
- Subjects: Trees -- South Africa , Mimosaceae , Forests and forestry -- South Africa , Forest conservation -- Economic aspects -- South Africa , Mimosaceae -- Biological control -- South Africa , Mesquite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11165 , http://hdl.handle.net/10353/394 , Trees -- South Africa , Mimosaceae , Forests and forestry -- South Africa , Forest conservation -- Economic aspects -- South Africa , Mimosaceae -- Biological control -- South Africa , Mesquite -- South Africa
- Description: Species of Prosopis (Mimosaceae), or mesquite, are native to the Americas and introduced in South Africa as agro forestry trees to provide wood, fodder and shade in the late 1800s. In the Northern Cape Province, these trees have been particularly used for their pods by local farmers and local industry. However due to Prosopis’ ability to spread rapidly there has been increasing pressure to step up control of the tree. Due to the costs associated with most control methods biological control has been singled out as the most viable control method worth pursuing. This thesis attempts to explain and shed light on the effects that increased biological control of Prosopis would have on the farming community and Prosopis based businesses in the area. Two hypothetical scenarios were used, the first being a possible 50% reduction in available pods and the other a possible 100% reduction. In an effort to explain these effects data was collected from a series of collection activities in the form of a pilot study and two unique questionnaire surveys. Twenty-seven farmers and one Prosopis based business were interviewed at random with the data analysed and documented. Results showed that the business community is the main user of pods incurring crippling losses in the event of a 50% or 100% decrease in available pods. Using control costs from working for water De Aar long term costs of the presence of Prosopis were estimated and compared to the estimated provincial cost of losing pods giving a cost comparison ratio of (α)270 million : Y(N(15.7million)). Only 48% of the respondents valued pods and 11% had traded in pods, the top concern resulting from the invasion was the loss of underground water. With a 50% decline in available pods, all respondents indicated unchanged effects. However empirical results showed that with a 100% decline in pods estimate losses of R 5 818 per farm are expected. The cost comparison ratio showing the losses farmers bore with Prosopis in the area and the losses they would suffer with a 100% decline in pods was R11 389 + (K): R5 818. In light of the empirical results, policy recommendations that support the introduction of more effective biological control agents have been made with areas for further research identified and discussed.
- Full Text:
- Date Issued: 2009
Establishing explicit perspectives of personality for a sample of Xhosa-speaking South Africans
- Authors: Nopote, Nomvuyiseko Minty
- Date: 2009
- Subjects: Personality assessment -- South Africa Cross-cultural studies , Psychological tests -- South Africa -- Cross-cultural studies , Language and languages -- Ability testing -- South Africa , Xhosa language -- South Africa -- Comparison
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9892 , http://hdl.handle.net/10948/1145 , Personality assessment -- South Africa Cross-cultural studies , Psychological tests -- South Africa -- Cross-cultural studies , Language and languages -- Ability testing -- South Africa , Xhosa language -- South Africa -- Comparison
- Description: Cross-cultural assessment in South Africa has become more prominent since the first democratic elections held in April 1994, as stronger demands for the cultural appropriateness of psychological tests have been made. The use of psychometric testing, including personality assessment in the workplace, is now strictly controlled by legislation, among others the Constitution of the Republic of South Africa (Act 108 of 1996), the Labour Relations Act (66 of 1995), and the Employment Equity Act (55 of 1998), and the Health Professions Act (56 of 1974). The present study forms part of the development process of the South African Personality Inventory (SAPI), which seeks to explore the indigenous personality structure of all the 11 official language groups found in South Africa and to then develop a personality inventory based on this. The present study aimed to explore and describe the personality facets and clusters that were found among a sample of 95 Xhosa-speaking South Africans. An exploratory descriptive research method was used and participants were selected by means of non-probability purposive sampling. Data were gathered by administering a biographical questionnaire and a tape-recorded 10- item interview questionnaire. Content analysis was used to analyse and reduce the data obtained from interviews into personality descriptors. Of the 1872 personality-descriptive words obtained from the interview questions, 164 facets of different personality characteristics were finally configured as a consequence of a data-reduction process. These facets were further categorised into a total of 37 personality sub-clusters and nine personality clusters which were labelled as Extraversion, Soft-heartedness, Conscientiousness, Emotional Stability, Intellect, Openness, Integrity, Relationship Harmony and Facilitating. These clusters and their sub-clusters resonate well with significant aspects and values of the Xhosa culture (e.g., Ubuntu). There also seems to be a moderate correspondence between the clusters and sub-clusters identified in the Xhosa-speaking sample and factors of the Five-Factor Model, especially with respect to the six clusters of Extraversion, Soft-heartedness, Conscientiousness, Emotional Stability, Intellect, and Openness. Nonetheless, differences in the composition of the clusters/facets were found, some of which are due to the more unique facets and sub-facets of personality identified in the Xhosa-speaking sample. The limitations of the study are identified and suggestions are made for further research.
- Full Text:
- Date Issued: 2009
- Authors: Nopote, Nomvuyiseko Minty
- Date: 2009
- Subjects: Personality assessment -- South Africa Cross-cultural studies , Psychological tests -- South Africa -- Cross-cultural studies , Language and languages -- Ability testing -- South Africa , Xhosa language -- South Africa -- Comparison
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9892 , http://hdl.handle.net/10948/1145 , Personality assessment -- South Africa Cross-cultural studies , Psychological tests -- South Africa -- Cross-cultural studies , Language and languages -- Ability testing -- South Africa , Xhosa language -- South Africa -- Comparison
- Description: Cross-cultural assessment in South Africa has become more prominent since the first democratic elections held in April 1994, as stronger demands for the cultural appropriateness of psychological tests have been made. The use of psychometric testing, including personality assessment in the workplace, is now strictly controlled by legislation, among others the Constitution of the Republic of South Africa (Act 108 of 1996), the Labour Relations Act (66 of 1995), and the Employment Equity Act (55 of 1998), and the Health Professions Act (56 of 1974). The present study forms part of the development process of the South African Personality Inventory (SAPI), which seeks to explore the indigenous personality structure of all the 11 official language groups found in South Africa and to then develop a personality inventory based on this. The present study aimed to explore and describe the personality facets and clusters that were found among a sample of 95 Xhosa-speaking South Africans. An exploratory descriptive research method was used and participants were selected by means of non-probability purposive sampling. Data were gathered by administering a biographical questionnaire and a tape-recorded 10- item interview questionnaire. Content analysis was used to analyse and reduce the data obtained from interviews into personality descriptors. Of the 1872 personality-descriptive words obtained from the interview questions, 164 facets of different personality characteristics were finally configured as a consequence of a data-reduction process. These facets were further categorised into a total of 37 personality sub-clusters and nine personality clusters which were labelled as Extraversion, Soft-heartedness, Conscientiousness, Emotional Stability, Intellect, Openness, Integrity, Relationship Harmony and Facilitating. These clusters and their sub-clusters resonate well with significant aspects and values of the Xhosa culture (e.g., Ubuntu). There also seems to be a moderate correspondence between the clusters and sub-clusters identified in the Xhosa-speaking sample and factors of the Five-Factor Model, especially with respect to the six clusters of Extraversion, Soft-heartedness, Conscientiousness, Emotional Stability, Intellect, and Openness. Nonetheless, differences in the composition of the clusters/facets were found, some of which are due to the more unique facets and sub-facets of personality identified in the Xhosa-speaking sample. The limitations of the study are identified and suggestions are made for further research.
- Full Text:
- Date Issued: 2009
Dynamics of development intervention, the case of Peddie, Eastern Cape
- Authors: Nondumiso, Fukweni
- Date: 2009
- Subjects: Sustainable development -- South Africa -- Peddie District , Poverty -- South Africa -- Eastern Cape -- Peddie District , Natural resources -- South Africa -- Peddie District , Rural development projects -- South Africa -- Peddie District , Peddie (South Africa) -- Economic conditions , Peddie (Soutb Africa) -- Social conditions , Agriculture -- South Africa -- Eastern Cape -- Peddie District
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11936 , http://hdl.handle.net/10353/183 , Sustainable development -- South Africa -- Peddie District , Poverty -- South Africa -- Eastern Cape -- Peddie District , Natural resources -- South Africa -- Peddie District , Rural development projects -- South Africa -- Peddie District , Peddie (South Africa) -- Economic conditions , Peddie (Soutb Africa) -- Social conditions , Agriculture -- South Africa -- Eastern Cape -- Peddie District
- Description: A large number of development initiatives, aimed at improving the overall quality of life of communities, have had a limited success rate in addressing poverty levels. Poverty has increased drastically and more and more people are among the poorest of the poor in spite of all the development actions and programmes that are aimed at improving the quality of life (Chambers, 1997;1) The study explores the dynamics of commercialization of agriculture at Prudo and Benton villages in Peddie, Eastern Cape. These dynamics include labour issues, lack of people involvement in decision making processes and the sharing of benefits within the pineapple project at Benton. It also explores the challenges of cash cropping at Prudo. Additionally, the study looks at the challenges faced by the poor within small projects administered by the Department of Agriculture and the Department of Social Development. Finally, the study explores the role that natural resources play in livelihoods in Peddie. To achieve these objectives, a review of literature and empirical research presented in the form of case studies will be used. The central argument of this thesis is that development has failed the majority of the poor in Peddie. Despite that, rural people continue to survive. Development projects did not generally bring about any significant reduction in poverty; neither did they bring about any significant economic transformations.
- Full Text:
- Date Issued: 2009
- Authors: Nondumiso, Fukweni
- Date: 2009
- Subjects: Sustainable development -- South Africa -- Peddie District , Poverty -- South Africa -- Eastern Cape -- Peddie District , Natural resources -- South Africa -- Peddie District , Rural development projects -- South Africa -- Peddie District , Peddie (South Africa) -- Economic conditions , Peddie (Soutb Africa) -- Social conditions , Agriculture -- South Africa -- Eastern Cape -- Peddie District
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11936 , http://hdl.handle.net/10353/183 , Sustainable development -- South Africa -- Peddie District , Poverty -- South Africa -- Eastern Cape -- Peddie District , Natural resources -- South Africa -- Peddie District , Rural development projects -- South Africa -- Peddie District , Peddie (South Africa) -- Economic conditions , Peddie (Soutb Africa) -- Social conditions , Agriculture -- South Africa -- Eastern Cape -- Peddie District
- Description: A large number of development initiatives, aimed at improving the overall quality of life of communities, have had a limited success rate in addressing poverty levels. Poverty has increased drastically and more and more people are among the poorest of the poor in spite of all the development actions and programmes that are aimed at improving the quality of life (Chambers, 1997;1) The study explores the dynamics of commercialization of agriculture at Prudo and Benton villages in Peddie, Eastern Cape. These dynamics include labour issues, lack of people involvement in decision making processes and the sharing of benefits within the pineapple project at Benton. It also explores the challenges of cash cropping at Prudo. Additionally, the study looks at the challenges faced by the poor within small projects administered by the Department of Agriculture and the Department of Social Development. Finally, the study explores the role that natural resources play in livelihoods in Peddie. To achieve these objectives, a review of literature and empirical research presented in the form of case studies will be used. The central argument of this thesis is that development has failed the majority of the poor in Peddie. Despite that, rural people continue to survive. Development projects did not generally bring about any significant reduction in poverty; neither did they bring about any significant economic transformations.
- Full Text:
- Date Issued: 2009
The value of shared corporate services in improving patient care
- Authors: Nompozolo, Nikiwe Nomapelo
- Date: 2009
- Subjects: East London Hospital Complex Hospital care -- Quality control -- South Africa -- East London Case studies Customer services -- Quality control -- South Africa -- East London Case studies Customer services -- Rating of -- South Africa -- East London Hospital care -- Evaluation -- South Africa -- East London
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:724 , http://hdl.handle.net/10962/d1003844
- Description: This case study was undertaken from mid 2003 to December 2005. It investigates the influence of the Corporate Services Centre (CSC) on customer (patient) service quality in the East London Hospital Complex (ELHC). This approach was justified on the basis that even though most patients do not have enough knowledge of clinical practices in order to make an accurate assessment on their quality, the same patients would readily appreciate factors such as faster turnaround times, drug availability and cleanliness. The study focuses on both service providers and end users for a quality health service delivery by looking at the potential of the shared corporate services centre. This was done by identifying important areas for improvements, such as response times, waiting periods and other aspects of the various services. The ELHC was formed from the merger of Frere and Cecilia Makiwane Hospitals, with a distance of 26km between the two institutions. The complex itself was in its infancy stages, having had to go through a process of re-engineering, rationalisation and standardisation of the two hospitals. The study seeks to answer the following key question: What has been the contribution of the corporate service centres in relation to health care service quality? The study examines the impediments to the realization of full potential of the Corporate Services Centre (CSC) through expedited decision-making and improved turnaround times. The main functions of the CSC were Procurement and Asset Management; General Administration (including but not limited to Transport, Office equipment, Patient Administration, Office Support, and Professional Secretariat Support); Financial Management and Administration; and Human Resource Management and Human Resources Administration. The study recommends that the CSC, to justify its existence, needs to consult with the clinicians and the patients to better understand what their needs and aspirations are. The study also emphasizes that the CSC is there purely to remove the administrative load and ease the processes and the biggest mistake is to make it an authority over the hospital, instead of being a support. Finally, it was realized that a lot of structural changes, business processes and organisational cultural changes are essential if one wants to create an impact through shared corporate services.
- Full Text:
- Date Issued: 2009
- Authors: Nompozolo, Nikiwe Nomapelo
- Date: 2009
- Subjects: East London Hospital Complex Hospital care -- Quality control -- South Africa -- East London Case studies Customer services -- Quality control -- South Africa -- East London Case studies Customer services -- Rating of -- South Africa -- East London Hospital care -- Evaluation -- South Africa -- East London
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:724 , http://hdl.handle.net/10962/d1003844
- Description: This case study was undertaken from mid 2003 to December 2005. It investigates the influence of the Corporate Services Centre (CSC) on customer (patient) service quality in the East London Hospital Complex (ELHC). This approach was justified on the basis that even though most patients do not have enough knowledge of clinical practices in order to make an accurate assessment on their quality, the same patients would readily appreciate factors such as faster turnaround times, drug availability and cleanliness. The study focuses on both service providers and end users for a quality health service delivery by looking at the potential of the shared corporate services centre. This was done by identifying important areas for improvements, such as response times, waiting periods and other aspects of the various services. The ELHC was formed from the merger of Frere and Cecilia Makiwane Hospitals, with a distance of 26km between the two institutions. The complex itself was in its infancy stages, having had to go through a process of re-engineering, rationalisation and standardisation of the two hospitals. The study seeks to answer the following key question: What has been the contribution of the corporate service centres in relation to health care service quality? The study examines the impediments to the realization of full potential of the Corporate Services Centre (CSC) through expedited decision-making and improved turnaround times. The main functions of the CSC were Procurement and Asset Management; General Administration (including but not limited to Transport, Office equipment, Patient Administration, Office Support, and Professional Secretariat Support); Financial Management and Administration; and Human Resource Management and Human Resources Administration. The study recommends that the CSC, to justify its existence, needs to consult with the clinicians and the patients to better understand what their needs and aspirations are. The study also emphasizes that the CSC is there purely to remove the administrative load and ease the processes and the biggest mistake is to make it an authority over the hospital, instead of being a support. Finally, it was realized that a lot of structural changes, business processes and organisational cultural changes are essential if one wants to create an impact through shared corporate services.
- Full Text:
- Date Issued: 2009
Comparative electrocatalytic behavior of self-assembled monolayer of thiol derivatised Co (II) phthalocyanines on gold disk, ultramicro cylinder and fiber electrodes
- Nombona, Nolwazi, Geraldo, Daniela A, Hakuzimana, Jean, Schwarz, Anne, Westbroek, Philippe, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Geraldo, Daniela A , Hakuzimana, Jean , Schwarz, Anne , Westbroek, Philippe , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263488 , vital:53632 , xlink:href="https://doi.org/10.1007/s10800-008-9716-y"
- Description: This paper reports on the use of thiol derivatised cobalt phthalocyanines as self assembled monolayers (SAMs) on gold disk electrode, gold ultramicro-cylinder electrode (UMCE) and on gold coated fiber for the detection of L-cysteine. The complexes are peripherally and non-peripherally substituted with phenylthio substituents. The SAM modified electrodes showed enhancement of catalytic currents and overpotential reduction occurred on the gold modified electrodes with different geometries. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultramicro cylinder electrode were less stable towards the electrocatalytic oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential.
- Full Text:
- Date Issued: 2009
- Authors: Nombona, Nolwazi , Geraldo, Daniela A , Hakuzimana, Jean , Schwarz, Anne , Westbroek, Philippe , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263488 , vital:53632 , xlink:href="https://doi.org/10.1007/s10800-008-9716-y"
- Description: This paper reports on the use of thiol derivatised cobalt phthalocyanines as self assembled monolayers (SAMs) on gold disk electrode, gold ultramicro-cylinder electrode (UMCE) and on gold coated fiber for the detection of L-cysteine. The complexes are peripherally and non-peripherally substituted with phenylthio substituents. The SAM modified electrodes showed enhancement of catalytic currents and overpotential reduction occurred on the gold modified electrodes with different geometries. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultramicro cylinder electrode were less stable towards the electrocatalytic oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential.
- Full Text:
- Date Issued: 2009
Electrochemical studies of titanium, manganese and cobalt phthalocyanines
- Authors: Nombona, Nolwazi
- Date: 2009
- Subjects: Titanium , Manganese , Cobalt , Phthalocyanines , Electrochemistry , Electrodes , Self-assembly (Chemistry)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4312 , http://hdl.handle.net/10962/d1004970 , Titanium , Manganese , Cobalt , Phthalocyanines , Electrochemistry , Electrodes , Self-assembly (Chemistry)
- Description: Syntheses, spectral, electrochemical and spectroelectrochemical studies of phenylthio and amino derivatised metallophthalocyanines complexes are reported. The complexes are immobilized onto a gold macro disk, gold ultramicroelectrode and gold coated fiber electrodes via self assembly with phenylthio MPc derivatives or onto a glassy carbon electrode via electropolymerisation with amino MPc derivatives. For the first time MPc SAMs were formed on gold coated fiber. The electrocatalytic behavior of the modified electrodes was studied for the detection of nitrite and L-cysteine, all modified electrodes showed improved electrocatalytic oxidation compared to the unmodified electrode. The MPc complexes catalyzed nitrite oxidation via a two-electron mechanism producing nitrate. Cobalt tetraaminophthalocyanine showed the best catalytic activity for nitrite oxidation in terms of overpotential lowering compared to other complexes and thus was used for nitrite detection in a food sample, the nitrite concentration was determined to be 59.13 ppm, well within the limit for cured meat products. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultamicro cylinder electrode were less stable towards the electro-oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential. The phenylthio cobalt phthalocyanine derivative gave the best catalytic activity for L-cysteine oxidation in terms of overpotential lowering compared to other phenylthio derivatized MPc complexes. The amount of L-cysteine in human urine was 2.4 mM, well within the urinary L-cysteine excretion range for a healthy human being.
- Full Text:
- Date Issued: 2009
- Authors: Nombona, Nolwazi
- Date: 2009
- Subjects: Titanium , Manganese , Cobalt , Phthalocyanines , Electrochemistry , Electrodes , Self-assembly (Chemistry)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4312 , http://hdl.handle.net/10962/d1004970 , Titanium , Manganese , Cobalt , Phthalocyanines , Electrochemistry , Electrodes , Self-assembly (Chemistry)
- Description: Syntheses, spectral, electrochemical and spectroelectrochemical studies of phenylthio and amino derivatised metallophthalocyanines complexes are reported. The complexes are immobilized onto a gold macro disk, gold ultramicroelectrode and gold coated fiber electrodes via self assembly with phenylthio MPc derivatives or onto a glassy carbon electrode via electropolymerisation with amino MPc derivatives. For the first time MPc SAMs were formed on gold coated fiber. The electrocatalytic behavior of the modified electrodes was studied for the detection of nitrite and L-cysteine, all modified electrodes showed improved electrocatalytic oxidation compared to the unmodified electrode. The MPc complexes catalyzed nitrite oxidation via a two-electron mechanism producing nitrate. Cobalt tetraaminophthalocyanine showed the best catalytic activity for nitrite oxidation in terms of overpotential lowering compared to other complexes and thus was used for nitrite detection in a food sample, the nitrite concentration was determined to be 59.13 ppm, well within the limit for cured meat products. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultamicro cylinder electrode were less stable towards the electro-oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential. The phenylthio cobalt phthalocyanine derivative gave the best catalytic activity for L-cysteine oxidation in terms of overpotential lowering compared to other phenylthio derivatized MPc complexes. The amount of L-cysteine in human urine was 2.4 mM, well within the urinary L-cysteine excretion range for a healthy human being.
- Full Text:
- Date Issued: 2009
The synthesis, cyclic voltammetry and spectroelectrochemical studies of Co (II) phthalocyanines tetra-substituted at the α and β positions with phenylthio groups
- Nombona, Nolwazi, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264529 , vital:53742 , xlink:href="https://doi.org/10.1016/j.dyepig.2008.06.002"
- Description: Non-peripherally substituted cobalt 1,(4)-(tetraphenylthiophthalocyaninato) and peripherally substituted cobalt 2,(3)-(tetraphenylthiophthalocyaninato) complexes were synthesized. Redox processes were observed at E1/2 = −1.44 V (I), −0.39 V (II), +0.37 V (III), +0.78 V (IV) and 1.15 V (V) for the non-peripherally substituted and at E1/2 = −1.42 V (I), −0.57, −0.39 V (II), +0.27 V (III), +0.79 V (IV) and +1.10 V (V) for the peripherally substituted complexes, respectively. The couples were assigned to CoIPc−2/CoIPc−3 (I), CoIIPc−2/CoIPc−2 (II), CoIIIPc−2/CoIIPc−2 (III), and CoIIIPc−1/CoIIIPc−2 (IV) using spectroelectrochemistry. The last process (V) could not be ascertained by spectroelectrochemistry but is associated with ring oxidation. Upon reduction or oxidation, the Q band of the non-peripherally substituted complex became less red shifted compared to that of its peripherally substituted counterpart.
- Full Text:
- Date Issued: 2009
- Authors: Nombona, Nolwazi , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264529 , vital:53742 , xlink:href="https://doi.org/10.1016/j.dyepig.2008.06.002"
- Description: Non-peripherally substituted cobalt 1,(4)-(tetraphenylthiophthalocyaninato) and peripherally substituted cobalt 2,(3)-(tetraphenylthiophthalocyaninato) complexes were synthesized. Redox processes were observed at E1/2 = −1.44 V (I), −0.39 V (II), +0.37 V (III), +0.78 V (IV) and 1.15 V (V) for the non-peripherally substituted and at E1/2 = −1.42 V (I), −0.57, −0.39 V (II), +0.27 V (III), +0.79 V (IV) and +1.10 V (V) for the peripherally substituted complexes, respectively. The couples were assigned to CoIPc−2/CoIPc−3 (I), CoIIPc−2/CoIPc−2 (II), CoIIIPc−2/CoIIPc−2 (III), and CoIIIPc−1/CoIIIPc−2 (IV) using spectroelectrochemistry. The last process (V) could not be ascertained by spectroelectrochemistry but is associated with ring oxidation. Upon reduction or oxidation, the Q band of the non-peripherally substituted complex became less red shifted compared to that of its peripherally substituted counterpart.
- Full Text:
- Date Issued: 2009
The impact of shiftwork on productivity
- Authors: Njela, Clive Jonathan
- Date: 2009
- Subjects: Shift systems , Labor productivity , Shift systems -- Psychological aspects , Job satisfaction
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8661 , http://hdl.handle.net/10948/1299 , Shift systems , Labor productivity , Shift systems -- Psychological aspects , Job satisfaction
- Description: Shiftwork is common in the private sector but not exclusive from the public sector like nursing. In order to secure a continuous operation, and optimization of equipment, businesses introduced shiftwork. The author wanted to test certain hypotheses to better understand the impact of shiftwork. In this research the author first embarked on a theoretical study into shiftwork and its associated problems, which include the impact on productivity, the impact on the employer’s attitude towards the work, the impact on the family life, the impact on social life, the impact on physical health and the psychological effects. Thereafter, an empirical study was conducted to ascertain to what extend shiftwork affects productivity and the life of the employees. The data was then analysed to explain the impact of shiftwork and productivity. Lastly, recommendations were made based on the research.
- Full Text:
- Date Issued: 2009
- Authors: Njela, Clive Jonathan
- Date: 2009
- Subjects: Shift systems , Labor productivity , Shift systems -- Psychological aspects , Job satisfaction
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8661 , http://hdl.handle.net/10948/1299 , Shift systems , Labor productivity , Shift systems -- Psychological aspects , Job satisfaction
- Description: Shiftwork is common in the private sector but not exclusive from the public sector like nursing. In order to secure a continuous operation, and optimization of equipment, businesses introduced shiftwork. The author wanted to test certain hypotheses to better understand the impact of shiftwork. In this research the author first embarked on a theoretical study into shiftwork and its associated problems, which include the impact on productivity, the impact on the employer’s attitude towards the work, the impact on the family life, the impact on social life, the impact on physical health and the psychological effects. Thereafter, an empirical study was conducted to ascertain to what extend shiftwork affects productivity and the life of the employees. The data was then analysed to explain the impact of shiftwork and productivity. Lastly, recommendations were made based on the research.
- Full Text:
- Date Issued: 2009
Aspects of memory in the sculptural work of Jane Alexander 1982-2009
- Authors: Nicol, Tracy-Lee
- Date: 2009
- Subjects: Alexander, Jane, 1959- Collective memory -- South Africa Memory in art Women artists -- South Africa Art, African -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2417 , http://hdl.handle.net/10962/d1002213
- Description: Over three decades of research has shown that memories have significant effect on the behaviour, attitudes, beliefs, and identities of individuals and collectives, revealing also how experiences of trauma and acts of narrativisation have pertinence to the ways in which memories are stored and reconstructed. In this thesis a link is developed between memory, trauma, narrativisation processes and the interpretation of works by Jane Alexander, a contemporary artist whose work is informed by observations about South African life. Alexander’s sculptures are revealed to be not only important vessels of collective memories and experiences, but also evocations of individuals’ countermemories and traumas that remain unarticulated and invisible. Through an exploration of the workings of memory and its relation to her art, it is revealed how the past continues to exert its influence on many of South Africa’s present sociopolitical concerns and interpersonal dynamics. Indeed constantly changing memories have a significant effect on future generations’ perceptions of, and connectedness to, the past. While theories about memory have been deployed in Art History as well as the Humanities in general, Alexander’s work has not previously been considered in light of the influence of these ideas. This thesis thus contributes a new dimension to literature on the artist.
- Full Text:
- Date Issued: 2009
- Authors: Nicol, Tracy-Lee
- Date: 2009
- Subjects: Alexander, Jane, 1959- Collective memory -- South Africa Memory in art Women artists -- South Africa Art, African -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2417 , http://hdl.handle.net/10962/d1002213
- Description: Over three decades of research has shown that memories have significant effect on the behaviour, attitudes, beliefs, and identities of individuals and collectives, revealing also how experiences of trauma and acts of narrativisation have pertinence to the ways in which memories are stored and reconstructed. In this thesis a link is developed between memory, trauma, narrativisation processes and the interpretation of works by Jane Alexander, a contemporary artist whose work is informed by observations about South African life. Alexander’s sculptures are revealed to be not only important vessels of collective memories and experiences, but also evocations of individuals’ countermemories and traumas that remain unarticulated and invisible. Through an exploration of the workings of memory and its relation to her art, it is revealed how the past continues to exert its influence on many of South Africa’s present sociopolitical concerns and interpersonal dynamics. Indeed constantly changing memories have a significant effect on future generations’ perceptions of, and connectedness to, the past. While theories about memory have been deployed in Art History as well as the Humanities in general, Alexander’s work has not previously been considered in light of the influence of these ideas. This thesis thus contributes a new dimension to literature on the artist.
- Full Text:
- Date Issued: 2009
Geomagnetically induced current characteristics in southern Africa
- Authors: Ngwira, Chigomezyo Mudala
- Date: 2009
- Subjects: Magnetic Observatory (South African Council for Scientific and Industrial Research) Geomagnetism -- Africa,Southern Computer networks -- Africa, Southern Magnetospheric currents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5469 , http://hdl.handle.net/10962/d1005254
- Description: Geomagnetically induced currents (GICs), resulting from adverse space weather, have been demonstrated to cause damage to power transformers at mid-latitudes. There is growing concern over possible GIC effects in the Southern African network due to its long power lines. Previous efforts to model the electric field associated with GICs in the Southern Africa region used a uniform ground conductivity model. In an effort to improve the modelling of GICs, GIC data together with Hermanus Magnetic Observatory geomagnetic field data were used to obtain a multilayered ground conductivity model. This process requires a definition of the network coefficients, which are then used in subsequent calculations. This study shows that GIC computed with the new network coefficients and the multilayered ground conductivity model improves the accuracy of GIC modelling. Then GIC statistics are derived based on the recordings of the geomagnetic field at Hermanus, the new network coefficients and ground conductivity model. The geoelectric field is modelled using the plane wave method. The properties of the geomagnetic field, their time derivatives and local geomagnetic indices were investigated to determine their characteristics in relation to the GIC. The pattern of the time derivatives of the horizontal geomagnetic field closely follow the rate of change of the north-south geomagnetic component rather than the east-west component. The correlation between the GIC and the local geomagnetic field indices was also investigated. The results show that there is a higher correlation between the GIC and the east-west components of the geomagnetic local indices than between the GIC and the north-south components. This corresponds very well with the orientation of the power lines feeding the power transformers at the South African Grassridge electrical substation GIC site. Thus, the geoelectric field driving the GIC at Grassridge is north-south oriented. Further, it is shown that the geomagnetic observation sites have a strong directional preference with respect to the Grassridge GIC site.
- Full Text:
- Date Issued: 2009
- Authors: Ngwira, Chigomezyo Mudala
- Date: 2009
- Subjects: Magnetic Observatory (South African Council for Scientific and Industrial Research) Geomagnetism -- Africa,Southern Computer networks -- Africa, Southern Magnetospheric currents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5469 , http://hdl.handle.net/10962/d1005254
- Description: Geomagnetically induced currents (GICs), resulting from adverse space weather, have been demonstrated to cause damage to power transformers at mid-latitudes. There is growing concern over possible GIC effects in the Southern African network due to its long power lines. Previous efforts to model the electric field associated with GICs in the Southern Africa region used a uniform ground conductivity model. In an effort to improve the modelling of GICs, GIC data together with Hermanus Magnetic Observatory geomagnetic field data were used to obtain a multilayered ground conductivity model. This process requires a definition of the network coefficients, which are then used in subsequent calculations. This study shows that GIC computed with the new network coefficients and the multilayered ground conductivity model improves the accuracy of GIC modelling. Then GIC statistics are derived based on the recordings of the geomagnetic field at Hermanus, the new network coefficients and ground conductivity model. The geoelectric field is modelled using the plane wave method. The properties of the geomagnetic field, their time derivatives and local geomagnetic indices were investigated to determine their characteristics in relation to the GIC. The pattern of the time derivatives of the horizontal geomagnetic field closely follow the rate of change of the north-south geomagnetic component rather than the east-west component. The correlation between the GIC and the local geomagnetic field indices was also investigated. The results show that there is a higher correlation between the GIC and the east-west components of the geomagnetic local indices than between the GIC and the north-south components. This corresponds very well with the orientation of the power lines feeding the power transformers at the South African Grassridge electrical substation GIC site. Thus, the geoelectric field driving the GIC at Grassridge is north-south oriented. Further, it is shown that the geomagnetic observation sites have a strong directional preference with respect to the Grassridge GIC site.
- Full Text:
- Date Issued: 2009
The ISO/IEC 27002 and ISO/IEC 27799 information security management standards : a comparative analysis from a healthcare perspective
- Authors: Ngqondi, Tembisa Grace
- Date: 2009
- Subjects: Computer security , Computer networks -- Security measures -- Standards , Data protection -- Management -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9765 , http://hdl.handle.net/10948/1066 , Computer security , Computer networks -- Security measures -- Standards , Data protection -- Management -- Standards
- Description: Technological shift has become significant and an area of concern in the health sector with regard to securing health information assets. Health information systems hosting personal health information expose these information assets to ever-evolving threats. This information includes aspects of an extremely sensitive nature, for example, a particular patient may have a history of drug abuse, which would be reflected in the patient’s medical record. The private nature of patient information places a higher demand on the need to ensure privacy. Ensuring that the security and privacy of health information remain intact is therefore vital in the healthcare environment. In order to protect information appropriately and effectively, good information security management practices should be followed. To this end, the International Organization for Standardization (ISO) published a code of practice for information security management, namely the ISO 27002 (2005). This standard is widely used in industry but is a generic standard aimed at all industries. Therefore it does not consider the unique security needs of a particular environment. Because of the unique nature of personal health information and its security and privacy requirements, the need to introduce a healthcare sector-specific standard for information security management was identified. The ISO 27799 was therefore published as an industry-specific variant of the ISO 27002 which is geared towards addressing security requirements in health informatics. It serves as an implementation guide for the ISO 27002 when implemented in the health sector. The publication of the ISO 27799 is considered as a positive development in the quest to improve health information security. However, the question arises whether the ISO 27799 addresses the security needs of the healthcare domain sufficiently. The extensive use of the ISO 27002 implies that many proponents of this standard (in healthcare), now have to ensure that they meet the (assumed) increased requirements of the ISO 27799. The purpose of this research is therefore to conduct a comprehensive comparison of the ISO 27002 and ISO 27799 standards to determine whether the ISO 27799 serves the specific needs of the health sector from an information security management point of view.
- Full Text:
- Date Issued: 2009
- Authors: Ngqondi, Tembisa Grace
- Date: 2009
- Subjects: Computer security , Computer networks -- Security measures -- Standards , Data protection -- Management -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9765 , http://hdl.handle.net/10948/1066 , Computer security , Computer networks -- Security measures -- Standards , Data protection -- Management -- Standards
- Description: Technological shift has become significant and an area of concern in the health sector with regard to securing health information assets. Health information systems hosting personal health information expose these information assets to ever-evolving threats. This information includes aspects of an extremely sensitive nature, for example, a particular patient may have a history of drug abuse, which would be reflected in the patient’s medical record. The private nature of patient information places a higher demand on the need to ensure privacy. Ensuring that the security and privacy of health information remain intact is therefore vital in the healthcare environment. In order to protect information appropriately and effectively, good information security management practices should be followed. To this end, the International Organization for Standardization (ISO) published a code of practice for information security management, namely the ISO 27002 (2005). This standard is widely used in industry but is a generic standard aimed at all industries. Therefore it does not consider the unique security needs of a particular environment. Because of the unique nature of personal health information and its security and privacy requirements, the need to introduce a healthcare sector-specific standard for information security management was identified. The ISO 27799 was therefore published as an industry-specific variant of the ISO 27002 which is geared towards addressing security requirements in health informatics. It serves as an implementation guide for the ISO 27002 when implemented in the health sector. The publication of the ISO 27799 is considered as a positive development in the quest to improve health information security. However, the question arises whether the ISO 27799 addresses the security needs of the healthcare domain sufficiently. The extensive use of the ISO 27002 implies that many proponents of this standard (in healthcare), now have to ensure that they meet the (assumed) increased requirements of the ISO 27799. The purpose of this research is therefore to conduct a comprehensive comparison of the ISO 27002 and ISO 27799 standards to determine whether the ISO 27799 serves the specific needs of the health sector from an information security management point of view.
- Full Text:
- Date Issued: 2009
Continuous assessment in Oshikwanyama: a case study
- Nghiueuelekuah, Soini Tuhafeni
- Authors: Nghiueuelekuah, Soini Tuhafeni
- Date: 2009
- Subjects: Educational tests and measurements -- Namibia -- Case studies Kuanyama language -- Namibia -- Case studies Kuanyama language -- Study and teaching -- Namibia -- Case studies Language and education -- Namibia -- Case studies
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1465 , http://hdl.handle.net/10962/d1003346
- Description: This study is about Continuous Assessment (CA) in teaching and learning, a new concept and approach in independent Namibia. The country's education system was reformed shortly after independence in 1990 to fulfill the intention for Education for All. The Namibian education system then moved from a behaviorist to constructivist philosophy of education. The move made from one philosophy to another resulted in many changes in teaching and learning including changes in assessment in education. CA is born out of a constructivist philosophy. It is believed to facilitate learning with understanding. In this study I explored the understanding of Oshikwanyama teachers and their practice of CA in teaching and learning. Interviews, classroom observations and document analysis were used. The research focused on 10 participants in the Ohangwena and Oshana regions. The participants ranged from a Head of Department to members of the curriculum panel, subject advisors and Oshikwanyama subject facilitators as well as teachers at the classroom level. It was revealed that generally speaking, CA as a term is understood, but the practice is not well implemented. In the practice of CA, instead of learners being assessed for further learning, the emphasis is on scored marks without further assistance in learning. Further, the collection of marks during CA is often seen as largely for the purpose of contributing to the marks for summative final marks. Informal assessment which is part of CA was not given attention, which is a key factor preventing the effective use of CA in teaching and learning. Methods such as marking grids that are provided in the syllabus, as well as portfolios and learners' profiles, were not mentioned in the interviews nor observed as being in use. Participants in the study did acknowledge that they did not fully understand how best to implement CA. Overall, the evidence pointed to a conclusion that the identified shortcomings in the implementation of formative assessment is limiting the realization of the rich potential for CA as a day-to-day tool to facilitate learning for understanding in the observed classes.
- Full Text:
- Date Issued: 2009
- Authors: Nghiueuelekuah, Soini Tuhafeni
- Date: 2009
- Subjects: Educational tests and measurements -- Namibia -- Case studies Kuanyama language -- Namibia -- Case studies Kuanyama language -- Study and teaching -- Namibia -- Case studies Language and education -- Namibia -- Case studies
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1465 , http://hdl.handle.net/10962/d1003346
- Description: This study is about Continuous Assessment (CA) in teaching and learning, a new concept and approach in independent Namibia. The country's education system was reformed shortly after independence in 1990 to fulfill the intention for Education for All. The Namibian education system then moved from a behaviorist to constructivist philosophy of education. The move made from one philosophy to another resulted in many changes in teaching and learning including changes in assessment in education. CA is born out of a constructivist philosophy. It is believed to facilitate learning with understanding. In this study I explored the understanding of Oshikwanyama teachers and their practice of CA in teaching and learning. Interviews, classroom observations and document analysis were used. The research focused on 10 participants in the Ohangwena and Oshana regions. The participants ranged from a Head of Department to members of the curriculum panel, subject advisors and Oshikwanyama subject facilitators as well as teachers at the classroom level. It was revealed that generally speaking, CA as a term is understood, but the practice is not well implemented. In the practice of CA, instead of learners being assessed for further learning, the emphasis is on scored marks without further assistance in learning. Further, the collection of marks during CA is often seen as largely for the purpose of contributing to the marks for summative final marks. Informal assessment which is part of CA was not given attention, which is a key factor preventing the effective use of CA in teaching and learning. Methods such as marking grids that are provided in the syllabus, as well as portfolios and learners' profiles, were not mentioned in the interviews nor observed as being in use. Participants in the study did acknowledge that they did not fully understand how best to implement CA. Overall, the evidence pointed to a conclusion that the identified shortcomings in the implementation of formative assessment is limiting the realization of the rich potential for CA as a day-to-day tool to facilitate learning for understanding in the observed classes.
- Full Text:
- Date Issued: 2009
Assessment and monitoring of land degradation using remote sensing and geographic information systems (GIS): a case study of Qoqodala within the Wit-Kei catchment in the Eastern Cape, South Africa
- Ngcofe, Luncedo Dalithemba Sanelisiwe
- Authors: Ngcofe, Luncedo Dalithemba Sanelisiwe
- Date: 2009
- Subjects: Geographic information systems -- South Africa -- Eastern Cape , Remote sensing -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4818 , http://hdl.handle.net/10962/d1005492 , Geographic information systems -- South Africa -- Eastern Cape , Remote sensing -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape
- Description: Land degradation is a global problem affecting many countries including South Africa. This study was conducted in order to assess and monitor the nature and extent of land degradation within Qoqodala in the Eastern Cape Province, of South Africa. The study used GIS and Remote Sensing techniques together with household interviews in determining extent, spatial characteristics and nature of land degradation within the study area. Vegetation cover and bare-ground change were the land degradation indicators assessed and monitored by this study. Through RGB band combination, Tasselled Cap Analysis and Unsupervised ISODATA classification techniques, Landsat images over the past eighteen years (1984, 1993, 1996, 2000 and 2002) have been analysed. The results showed that there is vegetation cover and bare-ground increase in the study area. The vegetation increase has been seen as a sign of land degradation increase due to the encroachment of indigenous vegetation by Euryops species (also known as Lapesi by the local community). The bare-ground land degradation indicator has also increased. The analyses of slope showed the spatial characteristics of bare-ground occurring on moderate to flat slopes while vegetation cover occurs on steep to very steep slopes. Furthermore the photographs captured during field visits show rills and gullies or dongas occurring on bare-ground. The interviewed respondents indicated that decline in food production, increase in dongas and vast increase in Euryops and a decline in grassland are the indicators of degradation that are observed in the study area. The occurrence of erosion features (rills and dongas) on bare-ground and the increase of vegetation shown by GIS and Remote Sensing techniques showed a positive correlation with field and household survey towards establishing the nature of land degradation. In this study Landsat images together with interviews proved to be a very useful tool for land degradation research. However the suggestion of a higher spatial resolution satellite image on small catchment studies is recommended
- Full Text:
- Date Issued: 2009
- Authors: Ngcofe, Luncedo Dalithemba Sanelisiwe
- Date: 2009
- Subjects: Geographic information systems -- South Africa -- Eastern Cape , Remote sensing -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4818 , http://hdl.handle.net/10962/d1005492 , Geographic information systems -- South Africa -- Eastern Cape , Remote sensing -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape
- Description: Land degradation is a global problem affecting many countries including South Africa. This study was conducted in order to assess and monitor the nature and extent of land degradation within Qoqodala in the Eastern Cape Province, of South Africa. The study used GIS and Remote Sensing techniques together with household interviews in determining extent, spatial characteristics and nature of land degradation within the study area. Vegetation cover and bare-ground change were the land degradation indicators assessed and monitored by this study. Through RGB band combination, Tasselled Cap Analysis and Unsupervised ISODATA classification techniques, Landsat images over the past eighteen years (1984, 1993, 1996, 2000 and 2002) have been analysed. The results showed that there is vegetation cover and bare-ground increase in the study area. The vegetation increase has been seen as a sign of land degradation increase due to the encroachment of indigenous vegetation by Euryops species (also known as Lapesi by the local community). The bare-ground land degradation indicator has also increased. The analyses of slope showed the spatial characteristics of bare-ground occurring on moderate to flat slopes while vegetation cover occurs on steep to very steep slopes. Furthermore the photographs captured during field visits show rills and gullies or dongas occurring on bare-ground. The interviewed respondents indicated that decline in food production, increase in dongas and vast increase in Euryops and a decline in grassland are the indicators of degradation that are observed in the study area. The occurrence of erosion features (rills and dongas) on bare-ground and the increase of vegetation shown by GIS and Remote Sensing techniques showed a positive correlation with field and household survey towards establishing the nature of land degradation. In this study Landsat images together with interviews proved to be a very useful tool for land degradation research. However the suggestion of a higher spatial resolution satellite image on small catchment studies is recommended
- Full Text:
- Date Issued: 2009
A critical assessment of the implementation of performance management in the Nelson Mandela Bay Municipality
- Authors: Ngcelwane, Mnikeli Jackson
- Date: 2009
- Subjects: Nelson Mandela Metropolitan Municipality (Eastern Cape, South Africa) -- Administration Performance -- Management -- South Africa -- Eastern Cape Industrial Management Teams in the workplace -- Management Municipal government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:736 , http://hdl.handle.net/10962/d1003856
- Description: The transformation of all spheres of South African government to a more effective and efficient administration became a priority after the election of the country's first democratic government in April 1994. An important aspect of South Africa's democratisation was the promise by the new government to improve the lives of the people of this country, and provide a better life for all the citizens of South Africa. One of the most effective ways of achieving this goal is generally accepted to be the proper management and strengthening of the local government sphere. Local government is the sphere of government that is closest to the people, and generally the performance of National Government is assessed through the performance of municipalities. In strengthening local government, various pieces of legislation were developed since 1994 to ensure that the objectives of Section 152 of the Constitution are achieved. As a result of these imperatives, the Department of Provincial and Local Government introduced a White Paper on Local Government on 9 March 1998, with a vision of working towards a new developmental local government system. Various statutes emanated from this strategic framework, such as the Local Government: Municipal Structures Act No. 117 of 1998, the Local Government: Municipal Systems Act No. 32 of 2000 and the Local Government: Municipal Finance Management Act No. 56 of 2003. These legislative enactments endeavour to ensure that the local sphere of government is managed more strategically than previously, and is responsive to the needs of communities. Municipalities are expected to deliver efficient and affordable services to the local communities, and failure to do so could result in the recent spate of violent protest that has been recently experienced in various parts of the country. In order to measure the extent of service delivery to the communities, and to assess whether the objectives named in the municipality's Integrated Development Plan (IDP) document are being achieved, municipalities are compelled to implement performance management for all members of staff, political office bearers and service providers, in terms of the Municipal Systems Act No. 32 of 2000. This thesis therefore looks at challenges faced by the Senior Management (i.e. Section 57 employees, Directors and Assistant Directors) in the implementation of performance management within the Nelson Mandela Bay Municipality, during the first five years of their term in office (i.e. Senior Management appointed after 6 December 2000 local government elections), and recommending performance management steps as well as performance management model that can be used to cascade performance management amongst all levels of staff. This thesis begins by introducing the subject of performance management, briefly discussing the demarcation of the research, the research method utilised, the historical background of performance management, as well as the current status of performance management within the municipality. The introduction of the topic is followed by a theoretical overview of the subject of performance management. This is followed by the discussion of the research methodology followed when conducting this research study. The findings are discussed in detail after the research methodology, giving a synopsis of what the interviewees disclosed during the interview process. The last chapter provides a brief discussion of the findings, and discusses the recommended performance management steps and performance management model, that can be used by the municipality to cascade performance amongst all members of staff.
- Full Text:
- Date Issued: 2009
- Authors: Ngcelwane, Mnikeli Jackson
- Date: 2009
- Subjects: Nelson Mandela Metropolitan Municipality (Eastern Cape, South Africa) -- Administration Performance -- Management -- South Africa -- Eastern Cape Industrial Management Teams in the workplace -- Management Municipal government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:736 , http://hdl.handle.net/10962/d1003856
- Description: The transformation of all spheres of South African government to a more effective and efficient administration became a priority after the election of the country's first democratic government in April 1994. An important aspect of South Africa's democratisation was the promise by the new government to improve the lives of the people of this country, and provide a better life for all the citizens of South Africa. One of the most effective ways of achieving this goal is generally accepted to be the proper management and strengthening of the local government sphere. Local government is the sphere of government that is closest to the people, and generally the performance of National Government is assessed through the performance of municipalities. In strengthening local government, various pieces of legislation were developed since 1994 to ensure that the objectives of Section 152 of the Constitution are achieved. As a result of these imperatives, the Department of Provincial and Local Government introduced a White Paper on Local Government on 9 March 1998, with a vision of working towards a new developmental local government system. Various statutes emanated from this strategic framework, such as the Local Government: Municipal Structures Act No. 117 of 1998, the Local Government: Municipal Systems Act No. 32 of 2000 and the Local Government: Municipal Finance Management Act No. 56 of 2003. These legislative enactments endeavour to ensure that the local sphere of government is managed more strategically than previously, and is responsive to the needs of communities. Municipalities are expected to deliver efficient and affordable services to the local communities, and failure to do so could result in the recent spate of violent protest that has been recently experienced in various parts of the country. In order to measure the extent of service delivery to the communities, and to assess whether the objectives named in the municipality's Integrated Development Plan (IDP) document are being achieved, municipalities are compelled to implement performance management for all members of staff, political office bearers and service providers, in terms of the Municipal Systems Act No. 32 of 2000. This thesis therefore looks at challenges faced by the Senior Management (i.e. Section 57 employees, Directors and Assistant Directors) in the implementation of performance management within the Nelson Mandela Bay Municipality, during the first five years of their term in office (i.e. Senior Management appointed after 6 December 2000 local government elections), and recommending performance management steps as well as performance management model that can be used to cascade performance management amongst all levels of staff. This thesis begins by introducing the subject of performance management, briefly discussing the demarcation of the research, the research method utilised, the historical background of performance management, as well as the current status of performance management within the municipality. The introduction of the topic is followed by a theoretical overview of the subject of performance management. This is followed by the discussion of the research methodology followed when conducting this research study. The findings are discussed in detail after the research methodology, giving a synopsis of what the interviewees disclosed during the interview process. The last chapter provides a brief discussion of the findings, and discusses the recommended performance management steps and performance management model, that can be used by the municipality to cascade performance amongst all members of staff.
- Full Text:
- Date Issued: 2009
Awkward working postures and precision performance as an example of the relationship between ergonomics and production quality
- Ngcamu, Nokubonga Slindele (Sma)
- Authors: Ngcamu, Nokubonga Slindele (Sma)
- Date: 2009
- Subjects: Human engineering , Posture , Posture disorders , Musculoskeletal system -- Diseases , Work -- Physiological aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5105 , http://hdl.handle.net/10962/d1005183 , Human engineering , Posture , Posture disorders , Musculoskeletal system -- Diseases , Work -- Physiological aspects
- Description: Ergonomics aims to improve worker health and enhance productivity and quality. Knowledge and practical evidence of this relationship would be instrumental for optimising organisational performance particularly in industrially developing countries where the discipline is still in its developmental stages. Therefore this thesis set out to analyse the relationship between ergonomics deficiencies and performance. A survey was first conducted to establish the severity of quality problems in the South African manufacturing industry and to determine if these were related to Ergonomic deficiencies. The results indicated that quality problems continue to plague industry, a challenge associated with huge cost implications. Furthermore organisations were not cognisant of the fact that ergonomics deficiencies such as poor workstation design and awkward or constrained working postures are a major contributing factor to poor quality and performance decrements. This demonstrates that much is yet to be done in raising awareness about the benefits of ergonomics in South Africa and other industrially developing countries. However, for this to be effective, tangible evidence of these purported benefits is required. In lieu of this, a laboratory study was then conducted to establish the relationship between awkward working postures and the performance of precision tasks. Acknowledging that the task and the worker are interrelated elements, the impact of precision task demands on the postural strain experienced by the human was also investigated. A high and low precision task quantified positional precision while a force task (combination of pushing and pulling) was utilised to assess the ability to maintain a precise force over time. These three tasks were performed in eight different postures; namely seated, standing, stooping 300 and 600, working overhead, lying supine, and twisting to either side. A combination of the tasks and postures resulted in 24 experimental conditions that were tested on forty eight healthy male and female participants. The performance related dependent variables were movement time, deviation from the centre of the target, and the trend/slope followed by the force exerted. Muscle activity of eight arm, shoulder and back muscles, iii supplemented with heart rate and local ratings of perceived exertion, were utilised to quantify the impact of the tasks and the postures on the individual. The results revealed that awkward working postures do in fact influence performance outcomes. In this regard, awkward working postures (such as overhead work and lying supine and stooping) were evidenced to significantly affect movement time, deviations from the target and the ability to maintain a constant force over time. These variables have a direct relationship with organisational priorities such as productivity and quality. Furthermore, the results indicated that high precision demands augment postural strain elicited through high muscle activity responses and may have negative implications for the precipitation of musculoskeletal disorders. Essentially, the work done on this thesis reflected the complex nature of ergonomics by drawing on both macro and micro-ergonomics approaches. In so doing, challenges perceived to be relevant to industry as reported by organisations formed the foundation for further laboratory studies. Therefore, more collaborative research and knowledge transfer between industry and ergonomics researchers is a necessity particularly in industrially developing countries where ergonomics is still in its developmental stages.
- Full Text:
- Date Issued: 2009
- Authors: Ngcamu, Nokubonga Slindele (Sma)
- Date: 2009
- Subjects: Human engineering , Posture , Posture disorders , Musculoskeletal system -- Diseases , Work -- Physiological aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5105 , http://hdl.handle.net/10962/d1005183 , Human engineering , Posture , Posture disorders , Musculoskeletal system -- Diseases , Work -- Physiological aspects
- Description: Ergonomics aims to improve worker health and enhance productivity and quality. Knowledge and practical evidence of this relationship would be instrumental for optimising organisational performance particularly in industrially developing countries where the discipline is still in its developmental stages. Therefore this thesis set out to analyse the relationship between ergonomics deficiencies and performance. A survey was first conducted to establish the severity of quality problems in the South African manufacturing industry and to determine if these were related to Ergonomic deficiencies. The results indicated that quality problems continue to plague industry, a challenge associated with huge cost implications. Furthermore organisations were not cognisant of the fact that ergonomics deficiencies such as poor workstation design and awkward or constrained working postures are a major contributing factor to poor quality and performance decrements. This demonstrates that much is yet to be done in raising awareness about the benefits of ergonomics in South Africa and other industrially developing countries. However, for this to be effective, tangible evidence of these purported benefits is required. In lieu of this, a laboratory study was then conducted to establish the relationship between awkward working postures and the performance of precision tasks. Acknowledging that the task and the worker are interrelated elements, the impact of precision task demands on the postural strain experienced by the human was also investigated. A high and low precision task quantified positional precision while a force task (combination of pushing and pulling) was utilised to assess the ability to maintain a precise force over time. These three tasks were performed in eight different postures; namely seated, standing, stooping 300 and 600, working overhead, lying supine, and twisting to either side. A combination of the tasks and postures resulted in 24 experimental conditions that were tested on forty eight healthy male and female participants. The performance related dependent variables were movement time, deviation from the centre of the target, and the trend/slope followed by the force exerted. Muscle activity of eight arm, shoulder and back muscles, iii supplemented with heart rate and local ratings of perceived exertion, were utilised to quantify the impact of the tasks and the postures on the individual. The results revealed that awkward working postures do in fact influence performance outcomes. In this regard, awkward working postures (such as overhead work and lying supine and stooping) were evidenced to significantly affect movement time, deviations from the target and the ability to maintain a constant force over time. These variables have a direct relationship with organisational priorities such as productivity and quality. Furthermore, the results indicated that high precision demands augment postural strain elicited through high muscle activity responses and may have negative implications for the precipitation of musculoskeletal disorders. Essentially, the work done on this thesis reflected the complex nature of ergonomics by drawing on both macro and micro-ergonomics approaches. In so doing, challenges perceived to be relevant to industry as reported by organisations formed the foundation for further laboratory studies. Therefore, more collaborative research and knowledge transfer between industry and ergonomics researchers is a necessity particularly in industrially developing countries where ergonomics is still in its developmental stages.
- Full Text:
- Date Issued: 2009
Relative deprivation and relative gratification as predictors of intergroup discrimination: can prejudice be reduced by equality?
- Authors: Neuwenhuis, Bridgitte
- Date: 2009
- Subjects: Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11608 , http://hdl.handle.net/10353/147 , Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Description: It has long been identified that relative deprivation increases prejudice. Guimond and Dambrun (2002) demonstrated that relative gratification, as the opposite of relative deprivation, is also an important variable in predicting intergroup discrimination. Guimond and Dambrun (2002), further suggest that in order to prevent destructive conflicts between groups, such as intergroup discrimination, the goal of equality rather than economic improvements has to be kept in mind. The present paper will report three experiments which aimed to replicate Guimond and Dambrun’s (2002) findings on relative deprivation and relative gratification and which further aimed to test their proposal that equality would reduce prejudice. The results of the three experiments confirmed the predicted effects of relative deprivation and relative gratification on intergroup discrimination. However, the results did not confirm that equality reduces prejudice. Methodological and theoretical reasons for these results are provided and discussed in detail.
- Full Text:
- Date Issued: 2009
- Authors: Neuwenhuis, Bridgitte
- Date: 2009
- Subjects: Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Psych)
- Identifier: vital:11608 , http://hdl.handle.net/10353/147 , Collective behavior , Social perception , Intergroup relations , Deprivation (Psychology)
- Description: It has long been identified that relative deprivation increases prejudice. Guimond and Dambrun (2002) demonstrated that relative gratification, as the opposite of relative deprivation, is also an important variable in predicting intergroup discrimination. Guimond and Dambrun (2002), further suggest that in order to prevent destructive conflicts between groups, such as intergroup discrimination, the goal of equality rather than economic improvements has to be kept in mind. The present paper will report three experiments which aimed to replicate Guimond and Dambrun’s (2002) findings on relative deprivation and relative gratification and which further aimed to test their proposal that equality would reduce prejudice. The results of the three experiments confirmed the predicted effects of relative deprivation and relative gratification on intergroup discrimination. However, the results did not confirm that equality reduces prejudice. Methodological and theoretical reasons for these results are provided and discussed in detail.
- Full Text:
- Date Issued: 2009
An exploration of problems experienced in the interpretation of word problems by grade 12 learners
- Authors: Neshuku, Christian N
- Date: 2009
- Subjects: Education (Secondary) -- Namibia Word problems (Mathematics) Teachers -- Training of -- Namibia Curriculum planning -- Namibia Mathematics -- Study and teaching (Secondary)
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1951 , http://hdl.handle.net/10962/d1008206
- Description: This research sought to investigate the problems experienced in the interpretation of word problems by senior secondary school learners, in particular to see how the language used in the articulation of word problems affects the interpretation. The study was conducted in a school in the Oshikoto region of Namibia, a school located in a semi-rural area of Namibia, and selected owing to the accessibility of the required participants. The research was located within an interpretive paradigm focusing on a study sample of 40 learners from a specified class in the selected school. Data were collected through written tests and a semi-structured interview based on written tests, and a comprehensive descriptive analysis of test results was prepared. The findings of the study indicate that the language in which the word problem was articulated did not make a difference. The performance in both English and Oshindonga tests was almost the same. The findings also indicate that vocabulary, syntactic interpretation, semantic relationships, algebraic skills, and practical sense making in relation to real-life are all important for the successful interpretation and solving of word problems. In view of these findings, the study has provided valuable insights into aspects of the teacher education curriculum that need to be revisited in order to improve the training of teachers In teaching word problems.
- Full Text:
- Date Issued: 2009
- Authors: Neshuku, Christian N
- Date: 2009
- Subjects: Education (Secondary) -- Namibia Word problems (Mathematics) Teachers -- Training of -- Namibia Curriculum planning -- Namibia Mathematics -- Study and teaching (Secondary)
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1951 , http://hdl.handle.net/10962/d1008206
- Description: This research sought to investigate the problems experienced in the interpretation of word problems by senior secondary school learners, in particular to see how the language used in the articulation of word problems affects the interpretation. The study was conducted in a school in the Oshikoto region of Namibia, a school located in a semi-rural area of Namibia, and selected owing to the accessibility of the required participants. The research was located within an interpretive paradigm focusing on a study sample of 40 learners from a specified class in the selected school. Data were collected through written tests and a semi-structured interview based on written tests, and a comprehensive descriptive analysis of test results was prepared. The findings of the study indicate that the language in which the word problem was articulated did not make a difference. The performance in both English and Oshindonga tests was almost the same. The findings also indicate that vocabulary, syntactic interpretation, semantic relationships, algebraic skills, and practical sense making in relation to real-life are all important for the successful interpretation and solving of word problems. In view of these findings, the study has provided valuable insights into aspects of the teacher education curriculum that need to be revisited in order to improve the training of teachers In teaching word problems.
- Full Text:
- Date Issued: 2009
Purification and characterization of fructosyltransferase for the synthesis of short-chain fructo-oligosaccharides and investigation into thier anti-carcinogenic properties
- Authors: Nemukula, Aluwani
- Date: 2009
- Subjects: Oligosaccharides , Polygalacturonase , Aspergillus , Fructose , Inulin , Cancer -- Prevention , Cancer -- Research , Carcinogens , High performance liquid chromatography
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3927 , http://hdl.handle.net/10962/d1003986 , Oligosaccharides , Polygalacturonase , Aspergillus , Fructose , Inulin , Cancer -- Prevention , Cancer -- Research , Carcinogens , High performance liquid chromatography
- Description: There is a growing attention in the synthesis of fructo-oligosaccharides (FOS) due to their excellent bio-functional and health-promoting properties. The current production processes are limited to chemical hydrolysis reactions of plant extracts, which are often associated with several drawbacks. In this study, fructosyltransferase (FTase) and polygalacturonase (PGase) activities, present in a commercial enzyme preparation (Pectinex® Ultra SP-L) sourced from Aspergillus aculeatus, have been separated and fully purified by anion-exchange and sizeexclusion chromatography. The FTase possesses fructosyl transfer activity for FOS synthesis and the PGase has pectin hydrolytic activity. Fructosyltransferase is a single-band protein with a molecular weight of 85 kDa, whereas PGase is a distinct protein of 40 kDa. The temperature and pH optima of FTase were 60 ºC and 6.0, with a half-life of 8 h; while that for PGase were 40 ºC and 6.0, respectively. FTase was slightly inhibited in the presence of Ni²⁺, Mg²⁺ and urea; but PGase was more susceptible to divalent ions such as Ca²⁺, Mg²⁺ and Mn²⁺. The kinetic parameters (Km and Vmax) of FTase for the hydrolysis of β-(2→1) linkages from sucrose were 752.3 mM and 120.5 μmol.min⁻¹.mL⁻¹, respectively; whereas the same parameters for pectin hydrolysis by PGase were 13.0 mg.mL⁻¹ and 263 μmol.min-1.mL⁻¹, respectively. The purified FTase was able to transfer fructosyl residues from sucrose, synthesizing the corresponding chains of FOS. PGase was relatively stable at 40 ºC (t½ > 3 h), depolymerizing the pectin backbone while releasing the inulins from within the chicory roots. Analysis of various mixtures of FOS by mass spectrometry, HPLC and ¹H-NMR was undertaken. Results indicated that MS with electrospray ionization and ¹H-NMR are capable of providing relative quantitative data of the FOS present in the mixtures. The pharmaceutical effects of various sc-FOS (0.5%, v/v) and SCFA (0.3%, v/v) on certain bacterial enzymes (β-glucuronidase, urease and β-glucosidase) associated with the formation of carcinogens were also studied. These enzyme activities were not directly influenced by the sc-FOS, but were found to be remarkably decreased by SCFA, pointing toward the prebiotic effect of FOS in intestinal microflora modulation.
- Full Text:
- Date Issued: 2009
- Authors: Nemukula, Aluwani
- Date: 2009
- Subjects: Oligosaccharides , Polygalacturonase , Aspergillus , Fructose , Inulin , Cancer -- Prevention , Cancer -- Research , Carcinogens , High performance liquid chromatography
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3927 , http://hdl.handle.net/10962/d1003986 , Oligosaccharides , Polygalacturonase , Aspergillus , Fructose , Inulin , Cancer -- Prevention , Cancer -- Research , Carcinogens , High performance liquid chromatography
- Description: There is a growing attention in the synthesis of fructo-oligosaccharides (FOS) due to their excellent bio-functional and health-promoting properties. The current production processes are limited to chemical hydrolysis reactions of plant extracts, which are often associated with several drawbacks. In this study, fructosyltransferase (FTase) and polygalacturonase (PGase) activities, present in a commercial enzyme preparation (Pectinex® Ultra SP-L) sourced from Aspergillus aculeatus, have been separated and fully purified by anion-exchange and sizeexclusion chromatography. The FTase possesses fructosyl transfer activity for FOS synthesis and the PGase has pectin hydrolytic activity. Fructosyltransferase is a single-band protein with a molecular weight of 85 kDa, whereas PGase is a distinct protein of 40 kDa. The temperature and pH optima of FTase were 60 ºC and 6.0, with a half-life of 8 h; while that for PGase were 40 ºC and 6.0, respectively. FTase was slightly inhibited in the presence of Ni²⁺, Mg²⁺ and urea; but PGase was more susceptible to divalent ions such as Ca²⁺, Mg²⁺ and Mn²⁺. The kinetic parameters (Km and Vmax) of FTase for the hydrolysis of β-(2→1) linkages from sucrose were 752.3 mM and 120.5 μmol.min⁻¹.mL⁻¹, respectively; whereas the same parameters for pectin hydrolysis by PGase were 13.0 mg.mL⁻¹ and 263 μmol.min-1.mL⁻¹, respectively. The purified FTase was able to transfer fructosyl residues from sucrose, synthesizing the corresponding chains of FOS. PGase was relatively stable at 40 ºC (t½ > 3 h), depolymerizing the pectin backbone while releasing the inulins from within the chicory roots. Analysis of various mixtures of FOS by mass spectrometry, HPLC and ¹H-NMR was undertaken. Results indicated that MS with electrospray ionization and ¹H-NMR are capable of providing relative quantitative data of the FOS present in the mixtures. The pharmaceutical effects of various sc-FOS (0.5%, v/v) and SCFA (0.3%, v/v) on certain bacterial enzymes (β-glucuronidase, urease and β-glucosidase) associated with the formation of carcinogens were also studied. These enzyme activities were not directly influenced by the sc-FOS, but were found to be remarkably decreased by SCFA, pointing toward the prebiotic effect of FOS in intestinal microflora modulation.
- Full Text:
- Date Issued: 2009
The war againts organised crime: a critical assessment of South African asset forfeiture law and its impact on redress for victims of crime
- Ndzengu, Nkululeko Christopher
- Authors: Ndzengu, Nkululeko Christopher
- Date: 2009
- Subjects: Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10173 , http://hdl.handle.net/10948/905 , Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Description: This research will be undertaken in the field of both criminal and civil law with particular focus on international interventions in the fight against organized criminal activities, assets forfeitsure in South Africa in general and its treatment of victims of the underlying forfeitsure crimes ("the victims") in assert forfeitsure, more specifically.
- Full Text: false
- Date Issued: 2009
- Authors: Ndzengu, Nkululeko Christopher
- Date: 2009
- Subjects: Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10173 , http://hdl.handle.net/10948/905 , Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Description: This research will be undertaken in the field of both criminal and civil law with particular focus on international interventions in the fight against organized criminal activities, assets forfeitsure in South Africa in general and its treatment of victims of the underlying forfeitsure crimes ("the victims") in assert forfeitsure, more specifically.
- Full Text: false
- Date Issued: 2009