Transformative, transgressive social learning: Rethinking higher education pedagogy in times of systemic global dysfunction
- Lotz-Sisitka, Heila, Wals, Arjen E, Kronlid, David O, McGarry, Dylan K
- Authors: Lotz-Sisitka, Heila , Wals, Arjen E , Kronlid, David O , McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/392190 , vital:68729 , xlink:href="https://doi.org/10.1016/j.cosust.2015.07.018"
- Description: The nature of the sustainability challenges currently at hand is such that dominant pedagogies and forms of learning that characterize higher education need to be reconsidered to enable students and staff to deal with accelerating change, increasing complexity, contested knowledge claims and inevitable uncertainty. In this contribution we identified four streams of emerging transformative, transgressive learning research and praxis in the sustainability sciences that appear generative of a higher education pedagogy that appears more responsive to the key challenges of our time: (1) reflexive social learning and capabilities theory, (2) critical phenomenology, (3) socio-cultural and cultural historical activity theory, and (4) new social movement, postcolonial and decolonisation theory. The paper critiques the current tendency in sustainability science and learning to rely on resilience and adaptive capacity building and argues that in order to break with maladaptive resilience of unsustainable systems it is essential to strengthen transgressive learning and disruptive capacity-building.
- Full Text:
- Date Issued: 2015
- Authors: Lotz-Sisitka, Heila , Wals, Arjen E , Kronlid, David O , McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/392190 , vital:68729 , xlink:href="https://doi.org/10.1016/j.cosust.2015.07.018"
- Description: The nature of the sustainability challenges currently at hand is such that dominant pedagogies and forms of learning that characterize higher education need to be reconsidered to enable students and staff to deal with accelerating change, increasing complexity, contested knowledge claims and inevitable uncertainty. In this contribution we identified four streams of emerging transformative, transgressive learning research and praxis in the sustainability sciences that appear generative of a higher education pedagogy that appears more responsive to the key challenges of our time: (1) reflexive social learning and capabilities theory, (2) critical phenomenology, (3) socio-cultural and cultural historical activity theory, and (4) new social movement, postcolonial and decolonisation theory. The paper critiques the current tendency in sustainability science and learning to rely on resilience and adaptive capacity building and argues that in order to break with maladaptive resilience of unsustainable systems it is essential to strengthen transgressive learning and disruptive capacity-building.
- Full Text:
- Date Issued: 2015
Editorial. Perspectives on transformations in learning and education
- Authors: Lotz-Sisitka, Heila
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387277 , vital:68221 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137656"
- Description: Perspectives on transformations in learning and education
- Full Text:
- Date Issued: 2015
- Authors: Lotz-Sisitka, Heila
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387277 , vital:68221 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137656"
- Description: Perspectives on transformations in learning and education
- Full Text:
- Date Issued: 2015
Transformative, transgressive social learning: Rethinking higher education pedagogy in times of systemic global dysfunction
- Lotz-Sisitka, Heila, Wals, Arjen E J, Kronlid, David O, McGarry, Dylan K
- Authors: Lotz-Sisitka, Heila , Wals, Arjen E J , Kronlid, David O , McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/372794 , vital:66623 , xlink:href="https://doi.org/10.1016/j.cosust.2015.07.018"
- Description: The nature of the sustainability challenges currently at hand is such that dominant pedagogies and forms of learning that characterize higher education need to be reconsidered to enable students and staff to deal with accelerating change, increasing complexity, contested knowledge claims and inevitable uncertainty. In this contribution we identified four streams of emerging transformative, transgressive learning research and praxis in the sustainability sciences that appear generative of a higher education pedagogy that appears more responsive to the key challenges of our time: (1) reflexive social learning and capabilities theory, (2) critical phenomenology, (3) socio-cultural and cultural historical activity theory, and (4) new social movement, postcolonial and decolonisation theory. The paper critiques the current tendency in sustainability science and learning to rely on resilience and adaptive capacity building and argues that in order to break with maladaptive resilience of unsustainable systems it is essential to strengthen transgressive learning and disruptive capacity-building.
- Full Text:
- Date Issued: 2015
- Authors: Lotz-Sisitka, Heila , Wals, Arjen E J , Kronlid, David O , McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/372794 , vital:66623 , xlink:href="https://doi.org/10.1016/j.cosust.2015.07.018"
- Description: The nature of the sustainability challenges currently at hand is such that dominant pedagogies and forms of learning that characterize higher education need to be reconsidered to enable students and staff to deal with accelerating change, increasing complexity, contested knowledge claims and inevitable uncertainty. In this contribution we identified four streams of emerging transformative, transgressive learning research and praxis in the sustainability sciences that appear generative of a higher education pedagogy that appears more responsive to the key challenges of our time: (1) reflexive social learning and capabilities theory, (2) critical phenomenology, (3) socio-cultural and cultural historical activity theory, and (4) new social movement, postcolonial and decolonisation theory. The paper critiques the current tendency in sustainability science and learning to rely on resilience and adaptive capacity building and argues that in order to break with maladaptive resilience of unsustainable systems it is essential to strengthen transgressive learning and disruptive capacity-building.
- Full Text:
- Date Issued: 2015
Book Review: Global Governance and the New Wars
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298640 , vital:57723 , xlink:href="https://doi.org/10.1080/02589346.2015.1008676"
- Description: Mark Duffield's second edition of ‘Global Governance and the New Wars’ offers an important and biting critique of how different actors within the security and development discourse have adapted to the various transformations of war in the post-cold war era. In this picture drawn by Duffield, the power of states in the South continues to be eroded by an exclusionary market that is driven by the global political economy wherein state's development and security responsibilities are increasingly assumed by non-state actors (predominately constituted by Western aid agencies). Those who fall outside the bounds of the state, development and humanitarian aid agencies can be found operating in an expanding shadow economy that is also shaped by a global dynamics which make the conditions for ‘network war' possible. In this context, the lines between ‘war' and peace” are difficult to distinguish. Overall, the book paints a depressing picture on the lack of substantive changes in the livelihoods of the poor as attention has been directed to discussions about ‘new wars' or altered forms of violence that have characterized the post-cold war era. The book unforgivingly exposes the failures of the discursive changes post-cold war to reconceptualize development and security in terms that move beyond description and into substantive change especially regarding shifting the development discourse from its historic modernizing impulses.
- Full Text:
- Date Issued: 2015
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298640 , vital:57723 , xlink:href="https://doi.org/10.1080/02589346.2015.1008676"
- Description: Mark Duffield's second edition of ‘Global Governance and the New Wars’ offers an important and biting critique of how different actors within the security and development discourse have adapted to the various transformations of war in the post-cold war era. In this picture drawn by Duffield, the power of states in the South continues to be eroded by an exclusionary market that is driven by the global political economy wherein state's development and security responsibilities are increasingly assumed by non-state actors (predominately constituted by Western aid agencies). Those who fall outside the bounds of the state, development and humanitarian aid agencies can be found operating in an expanding shadow economy that is also shaped by a global dynamics which make the conditions for ‘network war' possible. In this context, the lines between ‘war' and peace” are difficult to distinguish. Overall, the book paints a depressing picture on the lack of substantive changes in the livelihoods of the poor as attention has been directed to discussions about ‘new wars' or altered forms of violence that have characterized the post-cold war era. The book unforgivingly exposes the failures of the discursive changes post-cold war to reconceptualize development and security in terms that move beyond description and into substantive change especially regarding shifting the development discourse from its historic modernizing impulses.
- Full Text:
- Date Issued: 2015
Women combatants and the liberation movements in South Africa
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298584 , vital:57718 , xlink:href="https://doi.org/10.1080/10246029.2015.1088645"
- Description: This article examines women's role as combatants in national liberation forces in South Africa. Three categories – guerrilla girls, combative mothers and the in-betweeners – are introduced to underscore the varied ways in which women have participated in combat within the national liberation movements. Factors such as age and one's ability to leave the country affected whether women could participate in combat as ‘guerrilla girls’ or if it limited them to fighting apartheid violence from home, or if there were women who can be defined as having fallen somewhere in between these categories. These categories are used to theorise women's combat roles in the anti-apartheid struggle, thus broadening and challenging the dominant notions of combat that often hide women's contributions in war. In this regard, different periods of struggle, physical location, as well as age, determined the methods of activism available to men and women.
- Full Text:
- Date Issued: 2015
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298584 , vital:57718 , xlink:href="https://doi.org/10.1080/10246029.2015.1088645"
- Description: This article examines women's role as combatants in national liberation forces in South Africa. Three categories – guerrilla girls, combative mothers and the in-betweeners – are introduced to underscore the varied ways in which women have participated in combat within the national liberation movements. Factors such as age and one's ability to leave the country affected whether women could participate in combat as ‘guerrilla girls’ or if it limited them to fighting apartheid violence from home, or if there were women who can be defined as having fallen somewhere in between these categories. These categories are used to theorise women's combat roles in the anti-apartheid struggle, thus broadening and challenging the dominant notions of combat that often hide women's contributions in war. In this regard, different periods of struggle, physical location, as well as age, determined the methods of activism available to men and women.
- Full Text:
- Date Issued: 2015
Book Review: A Renegade called Simphiwe
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298595 , vital:57719 , xlink:href="https://doi.org/10.1177/0021909614533638"
- Description: A Renegade called Simphiwe is a “creative-intellectual portrait” of the public (and private) life of the musician Simphiwe Dana (p. 150). Gqola defines the book as “one writer’s engagement with the Simphiwe Dana of the South African public imagination [who]… troubles many categories of belonging in the South African public imagination in remarkable ways” (pp. 17, 32). The book comes at a poignant time as South Africa reflects on the success and challenges of the first 20 years of democracy. Fittingly, Gqola positions Dana within a long tradition of griots in Africa whose art always spoke truth to power.
- Full Text:
- Date Issued: 2015
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298595 , vital:57719 , xlink:href="https://doi.org/10.1177/0021909614533638"
- Description: A Renegade called Simphiwe is a “creative-intellectual portrait” of the public (and private) life of the musician Simphiwe Dana (p. 150). Gqola defines the book as “one writer’s engagement with the Simphiwe Dana of the South African public imagination [who]… troubles many categories of belonging in the South African public imagination in remarkable ways” (pp. 17, 32). The book comes at a poignant time as South Africa reflects on the success and challenges of the first 20 years of democracy. Fittingly, Gqola positions Dana within a long tradition of griots in Africa whose art always spoke truth to power.
- Full Text:
- Date Issued: 2015
Synthesis, characterization and photophysical properties of an acenaphthalene fused-ring-expanded NIR absorbing aza-BODIPY dye
- Majumdar, Poulomi, Mack, John, Nyokong, Tebello
- Authors: Majumdar, Poulomi , Mack, John , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189763 , vital:44929 , xlink:href="https://doi.org/10.1039/C5RA14916A"
- Description: The synthesis and characterization of an NIR absorbing acenaphthalene fused-ring-expanded aza-BODIPY dye are reported. In contrast with its naphtho-fused analogue, a stable complex is obtained when the corresponding phthalonitrile is used as the precursor. A comparison is made with the photophysical properties of 3,5-diphenyl-aza-dibenzoBODIPY.
- Full Text:
- Date Issued: 2015
- Authors: Majumdar, Poulomi , Mack, John , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189763 , vital:44929 , xlink:href="https://doi.org/10.1039/C5RA14916A"
- Description: The synthesis and characterization of an NIR absorbing acenaphthalene fused-ring-expanded aza-BODIPY dye are reported. In contrast with its naphtho-fused analogue, a stable complex is obtained when the corresponding phthalonitrile is used as the precursor. A comparison is made with the photophysical properties of 3,5-diphenyl-aza-dibenzoBODIPY.
- Full Text:
- Date Issued: 2015
Photodynamic antimicrobial chemotherapy activity of (5, 10, 15, 20-tetrakis (4-(4-carboxyphenycarbonoimidoyl) phenyl) porphyrinato) chloro gallium (III)
- Managa, Muthumuni, Amuhaya, Edith K, Nyokong, Tebello
- Authors: Managa, Muthumuni , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189043 , vital:44811 , xlink:href="https://doi.org/10.1016/j.saa.2015.06.088"
- Description: (5,10,15,20-Tetrakis(4-(4-carboxyphenycarbonoimidoyl)phenyl)porphyrinato) chloro gallium(III) (complex 1) was conjugated to platinum nanoparticles (PtNPs) (represented as 1-PtNPs). The resulting conjugate showed 18 nm red shift in the Soret band when compared to 1 alone. Complex 1 and 1-PtNPs showed promising photodynamic antimicrobial chemotherapy (PACT) activity against Staphylococcus aureus, Escherichia coli and Candida albicans in solution where the log reductions obtained were 4.92, 3.76, and 3.95, respectively for 1-PtNPs. The singlet oxygen quantum yields obtained were higher at 0.56 for 1-PtNPs in DMF while that of 1 was 0.52 in the same solvent. This resulted in improved PACT activity for 1-PtNPs compared to 1 alone.
- Full Text:
- Date Issued: 2015
- Authors: Managa, Muthumuni , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189043 , vital:44811 , xlink:href="https://doi.org/10.1016/j.saa.2015.06.088"
- Description: (5,10,15,20-Tetrakis(4-(4-carboxyphenycarbonoimidoyl)phenyl)porphyrinato) chloro gallium(III) (complex 1) was conjugated to platinum nanoparticles (PtNPs) (represented as 1-PtNPs). The resulting conjugate showed 18 nm red shift in the Soret band when compared to 1 alone. Complex 1 and 1-PtNPs showed promising photodynamic antimicrobial chemotherapy (PACT) activity against Staphylococcus aureus, Escherichia coli and Candida albicans in solution where the log reductions obtained were 4.92, 3.76, and 3.95, respectively for 1-PtNPs. The singlet oxygen quantum yields obtained were higher at 0.56 for 1-PtNPs in DMF while that of 1 was 0.52 in the same solvent. This resulted in improved PACT activity for 1-PtNPs compared to 1 alone.
- Full Text:
- Date Issued: 2015
Photodynamic antimicrobial chemotherapy activity of gallium tetra-(4-carboxyphenyl) porphyrin when conjugated to differently shaped platinum nanoparticles
- Managa, Muthumuni, Nyokong, Tebello
- Authors: Managa, Muthumuni , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189088 , vital:44815 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.06.077"
- Description: This work reports on the conjugation of differently shaped Pt nanoparticles (PtNPs) with ClGa(III) 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin (ClGaTCPP). The resulting conjugates were used for photodynamic antimicrobial chemotherapy against Staphylococcus aureus. The degree of photoinactivation is dependent on concentration of the conjugates, light dose (fluence) and illumination time. The log reduction obtained for ClGaTCPP when conjugated to cubic PtNPs was 4.64 log (which indicate 99.99% of the bacteria have been killed), which is much higher than 3.94 log unit for ClGaTCPPHexagonal PtNPs and 3.31 log units for ClGaTCPP-Unshaped PtNPs. ClGaTCPP alone gave a log unit reduction of less than 3, showing the importance of conjugation to PtNPs.
- Full Text:
- Date Issued: 2015
- Authors: Managa, Muthumuni , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189088 , vital:44815 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.06.077"
- Description: This work reports on the conjugation of differently shaped Pt nanoparticles (PtNPs) with ClGa(III) 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin (ClGaTCPP). The resulting conjugates were used for photodynamic antimicrobial chemotherapy against Staphylococcus aureus. The degree of photoinactivation is dependent on concentration of the conjugates, light dose (fluence) and illumination time. The log reduction obtained for ClGaTCPP when conjugated to cubic PtNPs was 4.64 log (which indicate 99.99% of the bacteria have been killed), which is much higher than 3.94 log unit for ClGaTCPPHexagonal PtNPs and 3.31 log units for ClGaTCPP-Unshaped PtNPs. ClGaTCPP alone gave a log unit reduction of less than 3, showing the importance of conjugation to PtNPs.
- Full Text:
- Date Issued: 2015
Electrocatalytic activity of bimetallic Au–Pd nanoparticles in the presence of cobalt tetraaminophthalocyanine
- Maringa, Audacity, Mashazi, Philani N, Nyokong, Tebello
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189719 , vital:44925 , xlink:href="https://doi.org/10.1016/j.jcis.2014.10.056"
- Description: Au and Pd nanoparticles were individually or together electrodeposited on top of polymerized cobalt tetraaminophthalocyanine (poly-CoTAPc). When Pd and Au nanoparticles are co-deposited together, the electrode is denoted as Au–Pd (co-deposited)/poly-CoTAPc-GCE. X-ray photoelectron spectroscopy (XPS) was used to show the successful deposition of AuNPs, PdNPs and Au–Pd (co-deposited). The scanning electrochemical microscopy showed that Au–Pd (co-deposited)/poly-CoTAPc-GCE (with current range of 9.5–13.5 lA) was more conducting than Au–Pd (co-deposited)-GCE (with current range of 8–12 lA). Electrochemical impedance spectroscopy (EIS) showed that there was less resistance to charge transfer for Au–Pd (co-deposited)/poly-CoTAPc-GCE compared to the rest of the electrodes. Au–Pd (co-deposited)/poly-CoTAPc-GCE showed the best activity for the electrooxidation of hydrazine in terms of limit of detection (0.5 lM), hence shows promise as an electrocatalyst for electrooxidation of hydrazine.
- Full Text:
- Date Issued: 2015
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189719 , vital:44925 , xlink:href="https://doi.org/10.1016/j.jcis.2014.10.056"
- Description: Au and Pd nanoparticles were individually or together electrodeposited on top of polymerized cobalt tetraaminophthalocyanine (poly-CoTAPc). When Pd and Au nanoparticles are co-deposited together, the electrode is denoted as Au–Pd (co-deposited)/poly-CoTAPc-GCE. X-ray photoelectron spectroscopy (XPS) was used to show the successful deposition of AuNPs, PdNPs and Au–Pd (co-deposited). The scanning electrochemical microscopy showed that Au–Pd (co-deposited)/poly-CoTAPc-GCE (with current range of 9.5–13.5 lA) was more conducting than Au–Pd (co-deposited)-GCE (with current range of 8–12 lA). Electrochemical impedance spectroscopy (EIS) showed that there was less resistance to charge transfer for Au–Pd (co-deposited)/poly-CoTAPc-GCE compared to the rest of the electrodes. Au–Pd (co-deposited)/poly-CoTAPc-GCE showed the best activity for the electrooxidation of hydrazine in terms of limit of detection (0.5 lM), hence shows promise as an electrocatalyst for electrooxidation of hydrazine.
- Full Text:
- Date Issued: 2015
DNA-based identification of Lepidoptera associated with citrus in South Africa
- Marsberg, Tamryn, Hill, Martin P, Moore, Sean D, Timm, A E
- Authors: Marsberg, Tamryn , Hill, Martin P , Moore, Sean D , Timm, A E
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405782 , vital:70205 , xlink:href="https://hdl.handle.net/10520/EJC167513"
- Description: A number of insects, primarily Lepidoptera, cause damage to citrus in South Africa. A major limitation to the management and control of these pests is their correct identification. The aim of this study was to develop a database of gene sequences to aid in the identification of these Lepidoptera. Multiple specimens of 12 species were sequenced for the ~650 bp of the cytochrome oxidase I gene. These sequence data were supplemented and validated using sequences available in public databases. Results showed that each species could be unambiguously identified, and neighbour-joining analysis based on K2P distances formed highly supported, distinct clusters for each species, i.e. the maximum intraspecific genetic distance was less than that of the minimum interspecific genetic distances. Thus, this data set provides a molecular means to successfully identify the most important Lepidoptera associated with citrus in South Africa.
- Full Text:
- Date Issued: 2015
- Authors: Marsberg, Tamryn , Hill, Martin P , Moore, Sean D , Timm, A E
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405782 , vital:70205 , xlink:href="https://hdl.handle.net/10520/EJC167513"
- Description: A number of insects, primarily Lepidoptera, cause damage to citrus in South Africa. A major limitation to the management and control of these pests is their correct identification. The aim of this study was to develop a database of gene sequences to aid in the identification of these Lepidoptera. Multiple specimens of 12 species were sequenced for the ~650 bp of the cytochrome oxidase I gene. These sequence data were supplemented and validated using sequences available in public databases. Results showed that each species could be unambiguously identified, and neighbour-joining analysis based on K2P distances formed highly supported, distinct clusters for each species, i.e. the maximum intraspecific genetic distance was less than that of the minimum interspecific genetic distances. Thus, this data set provides a molecular means to successfully identify the most important Lepidoptera associated with citrus in South Africa.
- Full Text:
- Date Issued: 2015
Electrocatalytic studies of covalently immobilized metal tetra-amino phthalocyanines onto derivatized screen-printed gold electrodes
- Mashazi, Philani N, Nyokong, Tebello
- Authors: Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249059 , vital:51774 , xlink:href="https://doi.org/10.1007/s00604-010-0438-6"
- Description: Metal tetra-amino phthalocyanine complexes (MTAPc; where M is Co or Mn) were immobilized on screen-printed gold electrodes pre-modified with monolayers of benzylamino groups. The functionalized electrodes were then activated using benzene-1,4-dicarbaldehyde as a linker before MTAPc complexes were immobilized. The surface coverages for the modified electrodes confirmed the perpendicular orientation of the MTAPcs. The apparent electron transfer constant (kapp) for the electrodes is 2.2 × 10−5 cm.s−1 for both CoTAPc and MnTAPc modified electrodes as calculated with data from impedance measurements. The kapp values for the bare and benzylamino modified electrodes were found to be 1.2 × 10−4 cm.s−1 and 4.9 × 10−6 cm.s−1, respectively. The electrocatalysis of the modified electrodes towards detection of H2O2 gave significant peak current densities and electrocatalytic potentials at −0.28 V and −0.31 V for the MnTAPc and CoTAPc modified electrodes, respectively.
- Full Text:
- Date Issued: 2015
- Authors: Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249059 , vital:51774 , xlink:href="https://doi.org/10.1007/s00604-010-0438-6"
- Description: Metal tetra-amino phthalocyanine complexes (MTAPc; where M is Co or Mn) were immobilized on screen-printed gold electrodes pre-modified with monolayers of benzylamino groups. The functionalized electrodes were then activated using benzene-1,4-dicarbaldehyde as a linker before MTAPc complexes were immobilized. The surface coverages for the modified electrodes confirmed the perpendicular orientation of the MTAPcs. The apparent electron transfer constant (kapp) for the electrodes is 2.2 × 10−5 cm.s−1 for both CoTAPc and MnTAPc modified electrodes as calculated with data from impedance measurements. The kapp values for the bare and benzylamino modified electrodes were found to be 1.2 × 10−4 cm.s−1 and 4.9 × 10−6 cm.s−1, respectively. The electrocatalysis of the modified electrodes towards detection of H2O2 gave significant peak current densities and electrocatalytic potentials at −0.28 V and −0.31 V for the MnTAPc and CoTAPc modified electrodes, respectively.
- Full Text:
- Date Issued: 2015
The listening train: A collaborative, connective aesthetics approach to transgressive social learning
- Authors: McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/371023 , vital:66404 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137658"
- Description: This paper explores a personal iterative retrospective of a series of expansive social-learning processes that were collaboratively developed through practice-based enquiry across 17 South African towns/contexts. This reflexive narrative explores the development of a ‘Climate Train’, a mobile social-learning platform, that was conceived and created through a collaborative social movement of ‘cultural practitioners’ ranging from visual artists, poets, film-makers, theatre-makers, guerrilla-gardeners, musicians, facilitators, to educational researchers, among others, who created new ‘connective aesthetic’ social spaces for dialogue and exchange. Drawing from a variety of artistic genres, including but not limited to theatre and social sculpture (an expanded concept of public/participatory art), I reflect on the formative, foundational qualities of these approaches and share insights into social-learning praxis that emerged on the tracks. Of primary focus is the use of aesthetic praxis as a means that transforms how we engage with our inner capacities as well as how we develop our relational sensibilities. Key findings include the vital role of connective aesthetics in establishing imaginal thinking, moral intuition, empathy, participative parity, and emergence, and how these are important for transformation and establishing new capacities for ecological/global citizenship and collaborative intelligence.
- Full Text:
- Date Issued: 2015
- Authors: McGarry, Dylan K
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/371023 , vital:66404 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137658"
- Description: This paper explores a personal iterative retrospective of a series of expansive social-learning processes that were collaboratively developed through practice-based enquiry across 17 South African towns/contexts. This reflexive narrative explores the development of a ‘Climate Train’, a mobile social-learning platform, that was conceived and created through a collaborative social movement of ‘cultural practitioners’ ranging from visual artists, poets, film-makers, theatre-makers, guerrilla-gardeners, musicians, facilitators, to educational researchers, among others, who created new ‘connective aesthetic’ social spaces for dialogue and exchange. Drawing from a variety of artistic genres, including but not limited to theatre and social sculpture (an expanded concept of public/participatory art), I reflect on the formative, foundational qualities of these approaches and share insights into social-learning praxis that emerged on the tracks. Of primary focus is the use of aesthetic praxis as a means that transforms how we engage with our inner capacities as well as how we develop our relational sensibilities. Key findings include the vital role of connective aesthetics in establishing imaginal thinking, moral intuition, empathy, participative parity, and emergence, and how these are important for transformation and establishing new capacities for ecological/global citizenship and collaborative intelligence.
- Full Text:
- Date Issued: 2015
The women of Willowvale-crafting livelihoods from the wild date palm
- Mjoli, Nwabisa, Shackleton, Charlie M
- Authors: Mjoli, Nwabisa , Shackleton, Charlie M
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182322 , vital:43820 , xlink:href="https://hdl.handle.net/10520/EJC185235"
- Description: The Wild Coast of the Eastern Cape is renowned for its cultural landscapes, stunning scenery and remarkable biodiversity. It is also one of the least developed regions of South Africa, which underpins the small productive base and limited economic opportunities for the hundreds of rural communities scattered along the hilltops. It is not surprising therefore, that many inhabitants make extensive use of natural resources, such as firewood, reed mats, medicinal plants and wild vegetables, in their daily lives, as well as for sources of income when the opportunity arises.
- Full Text:
- Date Issued: 2015
- Authors: Mjoli, Nwabisa , Shackleton, Charlie M
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182322 , vital:43820 , xlink:href="https://hdl.handle.net/10520/EJC185235"
- Description: The Wild Coast of the Eastern Cape is renowned for its cultural landscapes, stunning scenery and remarkable biodiversity. It is also one of the least developed regions of South Africa, which underpins the small productive base and limited economic opportunities for the hundreds of rural communities scattered along the hilltops. It is not surprising therefore, that many inhabitants make extensive use of natural resources, such as firewood, reed mats, medicinal plants and wild vegetables, in their daily lives, as well as for sources of income when the opportunity arises.
- Full Text:
- Date Issued: 2015
The trade in and household use of Phoenix reclinata palm frond hand brushes on the Wild Coast, South Africa: Effects on soil nutrients
- Mjoli, Nwabisa, Shackleton, Charlie M
- Authors: Mjoli, Nwabisa , Shackleton, Charlie M
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180800 , vital:43647 , xlink:href="https://doi.org/10.1007/s12231-015-9316-9"
- Description: The Trade in and Household Use of Phoenix reclinata Palm Frond Hand Brushes on the Wild Coast, South Africa. This paper reports on an investigation of the harvesting, trade, and use of hand brushes made from fronds of the wild palm, Phoenix reclinata. We considered both the abundance of the resource as well as the demand. Within the harvesting areas, there were approximately 141 palm plants per hectare, of which almost two-thirds showed no signs of frond harvesting. During harvesting, most fronds (82%) were left on the plant, 16% were removed to make brushes, and 2% were cut and discarded. Although the number of harvesters had increased during the last decade, most felt that the number of palm plants had remained stable or even increased over the same period. There was strong consensus that cut fronds were replaced within two months, after which a particular stem could be harvested again. Harvesting and trade were practiced largely by middle-aged to elderly women, who had limited formal education, skills, and employment prospects. Most had entered the trade because of cash income poverty. The main markets for selling the palm brushes were in nearby urban areas. The income earned from the trade was modest, but still rated highly by the traders, for most of whom it was the second most-important source of cash income. For many users, the palm brushes was found to be the only type of brush suitable for cleaning mud and cow-dung flooring and, most importantly for many, their use forms part of a long household use history and culture.
- Full Text:
- Date Issued: 2015
- Authors: Mjoli, Nwabisa , Shackleton, Charlie M
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180800 , vital:43647 , xlink:href="https://doi.org/10.1007/s12231-015-9316-9"
- Description: The Trade in and Household Use of Phoenix reclinata Palm Frond Hand Brushes on the Wild Coast, South Africa. This paper reports on an investigation of the harvesting, trade, and use of hand brushes made from fronds of the wild palm, Phoenix reclinata. We considered both the abundance of the resource as well as the demand. Within the harvesting areas, there were approximately 141 palm plants per hectare, of which almost two-thirds showed no signs of frond harvesting. During harvesting, most fronds (82%) were left on the plant, 16% were removed to make brushes, and 2% were cut and discarded. Although the number of harvesters had increased during the last decade, most felt that the number of palm plants had remained stable or even increased over the same period. There was strong consensus that cut fronds were replaced within two months, after which a particular stem could be harvested again. Harvesting and trade were practiced largely by middle-aged to elderly women, who had limited formal education, skills, and employment prospects. Most had entered the trade because of cash income poverty. The main markets for selling the palm brushes were in nearby urban areas. The income earned from the trade was modest, but still rated highly by the traders, for most of whom it was the second most-important source of cash income. For many users, the palm brushes was found to be the only type of brush suitable for cleaning mud and cow-dung flooring and, most importantly for many, their use forms part of a long household use history and culture.
- Full Text:
- Date Issued: 2015
Synthesis, photophysical and photochemical properties of octa-substituted antimony phthalocyanines
- Modibane, Desmond Kwena, Nyokong, Tebello
- Authors: Modibane, Desmond Kwena , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264226 , vital:53711 , xlink:href="https://doi.org/10.1016/j.poly.2008.11.052"
- Description: This work reports on the synthesis and photophysicochemical parameters of unsubstituted [SbIIIPc]+I3- and octa-phenoxy ([SbIIIOPPc]+I3-) and -4-t-butylphenoxy ([SbIIIOTBPPc]+I3-) substituted antimony phthalocyanines. Photophysical and photochemical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide and toluene. The excitation spectra of oxidized antimony (Sb(V)Pc) derivates were similar to absorption spectra. Low fluorescence quantum yields, high triplet quantum yields and low triplet lifetimes were observed as the result of heavy atom (antimony ion).
- Full Text:
- Date Issued: 2009
- Authors: Modibane, Desmond Kwena , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264226 , vital:53711 , xlink:href="https://doi.org/10.1016/j.poly.2008.11.052"
- Description: This work reports on the synthesis and photophysicochemical parameters of unsubstituted [SbIIIPc]+I3- and octa-phenoxy ([SbIIIOPPc]+I3-) and -4-t-butylphenoxy ([SbIIIOTBPPc]+I3-) substituted antimony phthalocyanines. Photophysical and photochemical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide and toluene. The excitation spectra of oxidized antimony (Sb(V)Pc) derivates were similar to absorption spectra. Low fluorescence quantum yields, high triplet quantum yields and low triplet lifetimes were observed as the result of heavy atom (antimony ion).
- Full Text:
- Date Issued: 2009
Amoxicillin removal from aqueous media using multi-walled carbon nanotubes
- Mohammadi, Ali, Kazemipour, Maryam, Walker, Roderick B, Ansari, Mehdi
- Authors: Mohammadi, Ali , Kazemipour, Maryam , Walker, Roderick B , Ansari, Mehdi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183861 , vital:44076 , xlink:href="https://doi.org/10.1080/1536383X.2013.866944"
- Description: Multi-walled carbon nanotubes (MWCNT) were used to separate amoxicillin from aqueous media. The parameters affecting amoxicillin adsorption such as pH, temperature, time, interferences of similar molecules, and the amount of adsorbent used were studied. Amoxicillin adsorption using MWCNT was compared to that using Fullerene C60 and activated carbon (AC). The adsorption efficiency of 0.1 and 0.2 g of MWCNT using in a continuous mode were 86.5% and 87.9%, respectively. Evaluation of the adsorbent capacity showed that each gram of MWCNT can absorb 22.9 mg amoxicillin. The effect of pH was studied over the range 2–8 and revealed that adsorption of the amoxicillin at the initial pH of 4.6 was more effective than any other pH. The adsorption of amoxicillin on MWCNT was much greater than Fullerene C60 and AC. Adsorption data showed that they were best fitted to the Langmuir isotherm.
- Full Text:
- Date Issued: 2015
- Authors: Mohammadi, Ali , Kazemipour, Maryam , Walker, Roderick B , Ansari, Mehdi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183861 , vital:44076 , xlink:href="https://doi.org/10.1080/1536383X.2013.866944"
- Description: Multi-walled carbon nanotubes (MWCNT) were used to separate amoxicillin from aqueous media. The parameters affecting amoxicillin adsorption such as pH, temperature, time, interferences of similar molecules, and the amount of adsorbent used were studied. Amoxicillin adsorption using MWCNT was compared to that using Fullerene C60 and activated carbon (AC). The adsorption efficiency of 0.1 and 0.2 g of MWCNT using in a continuous mode were 86.5% and 87.9%, respectively. Evaluation of the adsorbent capacity showed that each gram of MWCNT can absorb 22.9 mg amoxicillin. The effect of pH was studied over the range 2–8 and revealed that adsorption of the amoxicillin at the initial pH of 4.6 was more effective than any other pH. The adsorption of amoxicillin on MWCNT was much greater than Fullerene C60 and AC. Adsorption data showed that they were best fitted to the Langmuir isotherm.
- Full Text:
- Date Issued: 2015
Book Review Growing the next generation of researchers: A handbook for emerging researchers and their mentors, Holness, L
- Motshoane, Puleng, Muthama, Evelyn, McKenna, Sioux
- Authors: Motshoane, Puleng , Muthama, Evelyn , McKenna, Sioux
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187205 , vital:44579 , xlink:href="https://doi.org/10.14426/cristal.v3i2.56"
- Description: South Africa urgently needs more researchers (NRF, 2008; NDP, 2011). We also need a transformation in the demographics of our researchers. One indicator of this is that currently only 14% of university professors are black African, and only 2% are black African females (DHET, 2012). The Staffing South Africa's Universities Framework includes a number of initiatives to drive the process of growing the next generation of academics. For example, the nGAP project has inserted 125 new posts into the higher education system in 2015, with more to follow. This project allows for new academics to undertake postgraduate study and develop as teachers and researchers through mentorship, a reduced teaching load and so on.
- Full Text:
- Date Issued: 2015
- Authors: Motshoane, Puleng , Muthama, Evelyn , McKenna, Sioux
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187205 , vital:44579 , xlink:href="https://doi.org/10.14426/cristal.v3i2.56"
- Description: South Africa urgently needs more researchers (NRF, 2008; NDP, 2011). We also need a transformation in the demographics of our researchers. One indicator of this is that currently only 14% of university professors are black African, and only 2% are black African females (DHET, 2012). The Staffing South Africa's Universities Framework includes a number of initiatives to drive the process of growing the next generation of academics. For example, the nGAP project has inserted 125 new posts into the higher education system in 2015, with more to follow. This project allows for new academics to undertake postgraduate study and develop as teachers and researchers through mentorship, a reduced teaching load and so on.
- Full Text:
- Date Issued: 2015
Photoinactivation of Candida albicans and Escherichia coli using aluminium phthalocyanine on gold nanoparticles
- Mthethwa, Thandekile, Nyokong, Tebello
- Authors: Mthethwa, Thandekile , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189854 , vital:44940 , xlink:href="https://doi.org/10.1039/C4PP00315B"
- Description: The conjugates of aluminium phthalocyanine (complex 1) with gold nanorods (complex 1–AuNRs) and bipyramids (complex 1–AuBPs) showed improved singlet oxygen quantum yields of 0.23 and 0.24, respectively, compared to that of complex 1 alone at 0.12. Complex 1 and its conjugates were used for the photoinactivation of fungi (C. albicans) and bacteria cells (E. coli). The Q band absorbances were the same for the Pc alone and when conjugated to AuNPs. The efficiency of these conjugates was evaluated by measuring the log reduction of the microorganisms (C. albicans and E. coli) after irradiation with visible light in the presence of photosensitizers. Aluminium phthalocyanine alone showed log 1.78 and log 2.51 reductions for C. albicans and E. coli respectively. However, the conjugates showed higher photosensitization with log 2.08 and log 3.34 for C. albicans and E. coli, respectively using 1–AuBPs. For complex 1–AuNRs log 2.53 and log 3.71 were achieved for C. albicans and E. coli respectively. The statistical analysis of the results showed that the enhanced photoinactivation observed in both microorganisms was irrespective of the shape of the nanoparticles conjugated. Photoinactivation of C. albicans was less than that of E. coli even though a higher concentration of complex 1 or its conjugates was used in C. albicans.
- Full Text:
- Date Issued: 2015
- Authors: Mthethwa, Thandekile , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189854 , vital:44940 , xlink:href="https://doi.org/10.1039/C4PP00315B"
- Description: The conjugates of aluminium phthalocyanine (complex 1) with gold nanorods (complex 1–AuNRs) and bipyramids (complex 1–AuBPs) showed improved singlet oxygen quantum yields of 0.23 and 0.24, respectively, compared to that of complex 1 alone at 0.12. Complex 1 and its conjugates were used for the photoinactivation of fungi (C. albicans) and bacteria cells (E. coli). The Q band absorbances were the same for the Pc alone and when conjugated to AuNPs. The efficiency of these conjugates was evaluated by measuring the log reduction of the microorganisms (C. albicans and E. coli) after irradiation with visible light in the presence of photosensitizers. Aluminium phthalocyanine alone showed log 1.78 and log 2.51 reductions for C. albicans and E. coli respectively. However, the conjugates showed higher photosensitization with log 2.08 and log 3.34 for C. albicans and E. coli, respectively using 1–AuBPs. For complex 1–AuNRs log 2.53 and log 3.71 were achieved for C. albicans and E. coli respectively. The statistical analysis of the results showed that the enhanced photoinactivation observed in both microorganisms was irrespective of the shape of the nanoparticles conjugated. Photoinactivation of C. albicans was less than that of E. coli even though a higher concentration of complex 1 or its conjugates was used in C. albicans.
- Full Text:
- Date Issued: 2015
Fluorescence behavior and singlet oxygen generating abilities of aluminum phthalocyanine in the presence of anisotropic gold nanoparticles
- Mthethwa, Thandekile, Nyokong, Tebello
- Authors: Mthethwa, Thandekile , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193598 , vital:45351 , xlink:href="https://doi.org/10.1016/j.jlumin.2014.09.005"
- Description: Gold nanoparticles (spheres, rods and bipyramids) were synthesized. The nanocrystals were characterized by UV–visible spectrometry, transmission electron microscopy (TEM) and X-ray diffractometry (XRD). The as prepared gold nanoparticles were then conjugated to a quaternized 2,(3)-tetra [2-(dimethylamino) ethanethio] substituted Al(OH) phthalocyanine (complex 1). The conjugation of phthalocyanines with gold nanoparticles resulted in a decrease in the fluorescence quantum yields and lifetimes. Conversely, an increase in the singlet oxygen quantum yields was observed for the conjugated complex 1 in the presence of AuNPs.
- Full Text:
- Date Issued: 2015
- Authors: Mthethwa, Thandekile , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193598 , vital:45351 , xlink:href="https://doi.org/10.1016/j.jlumin.2014.09.005"
- Description: Gold nanoparticles (spheres, rods and bipyramids) were synthesized. The nanocrystals were characterized by UV–visible spectrometry, transmission electron microscopy (TEM) and X-ray diffractometry (XRD). The as prepared gold nanoparticles were then conjugated to a quaternized 2,(3)-tetra [2-(dimethylamino) ethanethio] substituted Al(OH) phthalocyanine (complex 1). The conjugation of phthalocyanines with gold nanoparticles resulted in a decrease in the fluorescence quantum yields and lifetimes. Conversely, an increase in the singlet oxygen quantum yields was observed for the conjugated complex 1 in the presence of AuNPs.
- Full Text:
- Date Issued: 2015