Ligand substitution effects in uranyl ο-hydroxyarylcarbonyl complexes
- Authors: Haigh, John M
- Date: 1974
- Language: English
- Type: text , Article
- Identifier: vital:6372 , http://hdl.handle.net/10962/d1006075
- Description: Twenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituents. Values of v(U=O) correlate well with these values. Evidence is cited suggesting almost complete non-aromaticity of the chelate ring, and the transmission of the electronic effects of the chelate ring substituent through the uranium atom in the pyridine and pyridine N-oxide base adducts.
- Full Text:
- Date Issued: 1974
- Authors: Haigh, John M
- Date: 1974
- Language: English
- Type: text , Article
- Identifier: vital:6372 , http://hdl.handle.net/10962/d1006075
- Description: Twenty-two base adducts of uranyl o-hydroxyarylcarbonyl complexes [UO2L2B] (L = o-hydroxyarylcarbonyl compound, B = H2O, pyridine, pyridine N-oxide) have been prepared. Pure field substituent parameters are used to derive a quantitative order of the electronic effects of the chelate ring substituents. Values of v(U=O) correlate well with these values. Evidence is cited suggesting almost complete non-aromaticity of the chelate ring, and the transmission of the electronic effects of the chelate ring substituent through the uranium atom in the pyridine and pyridine N-oxide base adducts.
- Full Text:
- Date Issued: 1974
The Educational Journal
- Date: 1974-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35177 , vital:33643 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-02
- Date: 1974-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35177 , vital:33643 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-02
The Educational Journal
- Date: 1974-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35449 , vital:33723 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-03
- Date: 1974-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35449 , vital:33723 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-03
The Educational Journal
- Date: 1974-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34905 , vital:33522 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-05
- Date: 1974-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34905 , vital:33522 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-05
The Educational Journal
- Date: 1974-08
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35299 , vital:33700 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-08
- Date: 1974-08
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35299 , vital:33700 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-08
The Educational Journal
- Date: 1974-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35906 , vital:33860 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-09
- Date: 1974-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35906 , vital:33860 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-09
The Educational Journal
- Date: 1974-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35616 , vital:33763 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-11
- Date: 1974-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35616 , vital:33763 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-11
The Educational Journal
- Date: 1974-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34977 , vital:33593 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-12
- Date: 1974-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34977 , vital:33593 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1974-12
The Educational Journal
- Date: 1975-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35187 , vital:33645 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-02
- Date: 1975-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35187 , vital:33645 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-02
The Educational Journal
- Date: 1975-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35501 , vital:33745 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-03
- Date: 1975-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35501 , vital:33745 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-03
The Educational Journal
- Date: 1975-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35379 , vital:33715 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-06
- Date: 1975-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35379 , vital:33715 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-06
The Educational Journal
- Date: 1975-08
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/38199 , vital:34416 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-08
- Date: 1975-08
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/38199 , vital:34416 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-08
The Educational Journal
- Date: 1975-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35916 , vital:33861 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-09
- Date: 1975-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35916 , vital:33861 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-09
The Educational Journal
- Date: 1975-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35651 , vital:33772 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-11
- Date: 1975-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35651 , vital:33772 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-11
The Educational Journal
- Date: 1975-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34987 , vital:33594 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-12
- Date: 1975-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34987 , vital:33594 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1975-12
The crystal and molecular structure of the bis(4-N, N1-dimethylaminopyridine) solvate of disalicylicacidatobis(nitrotodioxouranium)(VI)
- Nassimbeni, L R, Rodgers, Allen L, Haigh, John M
- Authors: Nassimbeni, L R , Rodgers, Allen L , Haigh, John M
- Date: 1976
- Language: English
- Type: text , Article
- Identifier: vital:6415 , http://hdl.handle.net/10962/d1006526
- Description: The structure of the title compound [(C7H4NO8U)(C7H11N2)]2 has been determined by Patterson and Fourier methods from single crystal X-ray diffraction data collected on a four-circle diffractometer. Full-matrix least-squares refinement yielded a final conventional R of 0.041 for 2189 reflections. The complex crystallizes in the space group P with a = 11.004(5), b = 9.981(5), c = 9.928(5) Å, α = 119.6(3), β = 107.7(3), γ = 81.9(3)°, Dm = 2.17, Dc = 2.173g cm−3. The structure is dimeric. The uranium atoms are eight-coordinate and are bridged via centrosymmetrically related carboxylic oxygen atoms. The nitrate group is bidentate and the average U---O (ligand) distance is 2.463 Å. Hydrogen bonding of the type N---HO links two dimethyl-aminopyridine molecules to the dimer.
- Full Text:
- Date Issued: 1976
- Authors: Nassimbeni, L R , Rodgers, Allen L , Haigh, John M
- Date: 1976
- Language: English
- Type: text , Article
- Identifier: vital:6415 , http://hdl.handle.net/10962/d1006526
- Description: The structure of the title compound [(C7H4NO8U)(C7H11N2)]2 has been determined by Patterson and Fourier methods from single crystal X-ray diffraction data collected on a four-circle diffractometer. Full-matrix least-squares refinement yielded a final conventional R of 0.041 for 2189 reflections. The complex crystallizes in the space group P with a = 11.004(5), b = 9.981(5), c = 9.928(5) Å, α = 119.6(3), β = 107.7(3), γ = 81.9(3)°, Dm = 2.17, Dc = 2.173g cm−3. The structure is dimeric. The uranium atoms are eight-coordinate and are bridged via centrosymmetrically related carboxylic oxygen atoms. The nitrate group is bidentate and the average U---O (ligand) distance is 2.463 Å. Hydrogen bonding of the type N---HO links two dimethyl-aminopyridine molecules to the dimer.
- Full Text:
- Date Issued: 1976
The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI)
- Haigh, John M, Nassimbeni, Luigi R, Pauptit, Richard A, Rodgers, Allen L, Sheldrick, George M
- Authors: Haigh, John M , Nassimbeni, Luigi R , Pauptit, Richard A , Rodgers, Allen L , Sheldrick, George M
- Date: 1976
- Subjects: Aliphatic amine adducts , Uranyl acetylacetonate
- Language: English
- Type: Article , text
- Identifier: vital:6373 , http://hdl.handle.net/10962/d1006077
- Description: Crystals of the title compound are monoclinic with a= 8.314 (5), b= 22.723 (9), c= 12.589 (6) A, /3= 123.0 (2t, Z=4, space group P2dc. The structure was determined by Patterson and Fourier methods and refined by full-matrix least squares to a final R of 0.030 for 2043 independent reflexions. The U atom has pentagonal bipyramidal coordination and the N-methylacetylacetoneamine is bonded to U via O. There are two intramolecular N-H. . .0 hydrogen bonds which govern the geometry of the adduct molecule.
- Full Text:
- Date Issued: 1976
- Authors: Haigh, John M , Nassimbeni, Luigi R , Pauptit, Richard A , Rodgers, Allen L , Sheldrick, George M
- Date: 1976
- Subjects: Aliphatic amine adducts , Uranyl acetylacetonate
- Language: English
- Type: Article , text
- Identifier: vital:6373 , http://hdl.handle.net/10962/d1006077
- Description: Crystals of the title compound are monoclinic with a= 8.314 (5), b= 22.723 (9), c= 12.589 (6) A, /3= 123.0 (2t, Z=4, space group P2dc. The structure was determined by Patterson and Fourier methods and refined by full-matrix least squares to a final R of 0.030 for 2043 independent reflexions. The U atom has pentagonal bipyramidal coordination and the N-methylacetylacetoneamine is bonded to U via O. There are two intramolecular N-H. . .0 hydrogen bonds which govern the geometry of the adduct molecule.
- Full Text:
- Date Issued: 1976
The Educational Journal
- Date: 1976-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35200 , vital:33646 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-02
- Date: 1976-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35200 , vital:33646 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-02
The Educational Journal
- Date: 1976-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35512 , vital:33746 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-03
- Date: 1976-03
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35512 , vital:33746 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-03
The Educational Journal
- Date: 1976-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34885 , vital:33520 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-05
- Date: 1976-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34885 , vital:33520 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1976-05