A statistical evaluation and analysis of mosquito repellent combination
- Authors: Asquith, Ilse Bernadette
- Date: 2004
- Subjects: Mosquitoes -- Control , Insect baits and repellents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10422 , http://hdl.handle.net/10948/d1015732
- Description: The present product development project was aimed at studying the synergism and/or antagonism amongst various known insect repellent actives with the view to formulating a multi-active repellent product with improved properties when compared to current single-active commercial products. Advanced statistical methods were used to identify synergism between individual active substances and to define a formulation as close as possible to the “ideal” formulation. Several mosquito repellent samples were prepared and sent to the South African Bureau of Standards (SABS) in Pretoria to test for their efficiency in repelling mosquitoes. From the results of the repellency tests of the various active combinations, three actives were identified that showed promising signs of synergism. These actives were then studied in further detail to determine their optimum combination. In addition, it was shown that when using a natural flavourant as promoter and incorporating a slow-release agent into formulations for aerosols and lotions, a product is obtained that gives comparable levels of efficiency to current commercial products, but at much reduced levels of active loading. Accelerated stability tests performed on the final combination of the three actives used in the final formulation showed no adverse reactions over a three-week study. These tests shall be repeated once the final application form (lotion, aerosol, etc) and product packing have been decided.
- Full Text:
- Date Issued: 2004
- Authors: Asquith, Ilse Bernadette
- Date: 2004
- Subjects: Mosquitoes -- Control , Insect baits and repellents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10422 , http://hdl.handle.net/10948/d1015732
- Description: The present product development project was aimed at studying the synergism and/or antagonism amongst various known insect repellent actives with the view to formulating a multi-active repellent product with improved properties when compared to current single-active commercial products. Advanced statistical methods were used to identify synergism between individual active substances and to define a formulation as close as possible to the “ideal” formulation. Several mosquito repellent samples were prepared and sent to the South African Bureau of Standards (SABS) in Pretoria to test for their efficiency in repelling mosquitoes. From the results of the repellency tests of the various active combinations, three actives were identified that showed promising signs of synergism. These actives were then studied in further detail to determine their optimum combination. In addition, it was shown that when using a natural flavourant as promoter and incorporating a slow-release agent into formulations for aerosols and lotions, a product is obtained that gives comparable levels of efficiency to current commercial products, but at much reduced levels of active loading. Accelerated stability tests performed on the final combination of the three actives used in the final formulation showed no adverse reactions over a three-week study. These tests shall be repeated once the final application form (lotion, aerosol, etc) and product packing have been decided.
- Full Text:
- Date Issued: 2004
Distribution of heavy minerals sand in Namalope deposit, Moma district, Mozambique
- Authors: Assane, Ali Ossufo
- Date: 2014
- Subjects: Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5056 , http://hdl.handle.net/10962/d1012169 , Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Description: The spatial distribution of heavy minerals along the mine paths 2014 and 2015 at the wet concentrate plant B shows an increase of heavy minerals sand concentration northwards and slime contents southwards, and it is commonly associated with depth and grain sorting; the increase of heavy minerals concentration with depth is considered to be from the surface formed by Unit 6 to the bottom of Unit 7. The Unit 82 is characterized by low heavy minerals concentrations and high slime contents declining northwards. The mineral proportion estimation suggests that ilmenite is the most abundant heavy mineral in the entire area followed by zircon, rutile and mozanite, and some accessory minerals such as chromite, kyanite, staurolite, tourmaline, epidote, spinel and quartz. The ilmenite occurrence is divided into ilmenite low (< 53% TiO₂) and high (> 53% TiO₂); the ilmenite high with zircon and rutile shows tendency to increase northwards while ilmenite low increase southwards. Zircon, monazite, rutile, chromite, kyanite and staurolite show low variability, which is probably associated with high resistance of minerals for abrasion during transportation and diagenesis. The depositional model of the Namalope deposit, in the flat area and wet concentrate plant B in particular, suggests deposition in a shallow marine environment associated with regression for deposition of Unit 6, 7 and 9 and transgression during deposition of Unit 82. The spatial distribution of heavy minerals in the Namalope deposit and its environment of deposition are the key points for discovery of new deposits around the Namalope with the same characteristic of mineral assemblage and they are used for mine strategic plans such as update block model and mine design.
- Full Text:
- Date Issued: 2014
- Authors: Assane, Ali Ossufo
- Date: 2014
- Subjects: Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5056 , http://hdl.handle.net/10962/d1012169 , Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Description: The spatial distribution of heavy minerals along the mine paths 2014 and 2015 at the wet concentrate plant B shows an increase of heavy minerals sand concentration northwards and slime contents southwards, and it is commonly associated with depth and grain sorting; the increase of heavy minerals concentration with depth is considered to be from the surface formed by Unit 6 to the bottom of Unit 7. The Unit 82 is characterized by low heavy minerals concentrations and high slime contents declining northwards. The mineral proportion estimation suggests that ilmenite is the most abundant heavy mineral in the entire area followed by zircon, rutile and mozanite, and some accessory minerals such as chromite, kyanite, staurolite, tourmaline, epidote, spinel and quartz. The ilmenite occurrence is divided into ilmenite low (< 53% TiO₂) and high (> 53% TiO₂); the ilmenite high with zircon and rutile shows tendency to increase northwards while ilmenite low increase southwards. Zircon, monazite, rutile, chromite, kyanite and staurolite show low variability, which is probably associated with high resistance of minerals for abrasion during transportation and diagenesis. The depositional model of the Namalope deposit, in the flat area and wet concentrate plant B in particular, suggests deposition in a shallow marine environment associated with regression for deposition of Unit 6, 7 and 9 and transgression during deposition of Unit 82. The spatial distribution of heavy minerals in the Namalope deposit and its environment of deposition are the key points for discovery of new deposits around the Namalope with the same characteristic of mineral assemblage and they are used for mine strategic plans such as update block model and mine design.
- Full Text:
- Date Issued: 2014
Thermoluminescence of annealed synthetic quartz
- Atang, Elizabeth Fende Midiki
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
Using co-located radars and instruments to analyse ionespheric events over South Africa
- Authors: Athieno, Racheal
- Date: 2012
- Subjects: Ionosphere -- Research -- South Africa , Space environment -- Research -- South Africa , Meteorology -- Research -- South Africa , Ionosondes -- Research -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5493 , http://hdl.handle.net/10962/d1005279 , Ionosphere -- Research -- South Africa , Space environment -- Research -- South Africa , Meteorology -- Research -- South Africa , Ionosondes -- Research -- South Africa
- Description: Space weather and its effect on technological systems are important for scientific research. Developing an understanding of the behaviour, sources and effects of ionospheric events form a basis for improving space weather prediction. This thesis attempts to use co-located radars and instruments for the analysis of ionospheric events over South Africa. The HF Doppler radar, ionosonde, Global Positioning System (GPS) and GPS ionospheric scintillation monitor (GISTM) receivers are co-located in Hermanus (34.4°S, 19.2°E), one of the observatories for the space science directorate of the South African National Space Agency (SANSA). Data was obtained from these radars and instruments and analysed for ionospheric events. Only the Hermanus station was selected for this analysis, because it is currently the only South African station that hosts all the mentioned radars and instruments. Ionospheric events identified include wave-like structures, Doppler spread, sudden frequency deviations and ionospheric oscillations associated with geomagnetic pulsations. For the purpose of this work, ionospheric events are defined as any unusual structures observed on the received signal and inferred from observations made by the HF Doppler radar. They were identified by visual inspection of the Doppler shift spectrograms. The magnitude and nature of the events vary, depending on their source and were observed by all, some or one instrument. This study suggests that the inclusion of a wider data coverage and more stations in South Africa merit consideration, especially since plans are underway to host a co-located radar network similar to that in Hermanus at at least three additional observatory sites in South Africa. This study lays a foundation for multi-station co-located radar and instrument observation and analysis of ionospheric events which should enhance the accuracy of space weather and HF communication prediction.
- Full Text:
- Date Issued: 2012
- Authors: Athieno, Racheal
- Date: 2012
- Subjects: Ionosphere -- Research -- South Africa , Space environment -- Research -- South Africa , Meteorology -- Research -- South Africa , Ionosondes -- Research -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5493 , http://hdl.handle.net/10962/d1005279 , Ionosphere -- Research -- South Africa , Space environment -- Research -- South Africa , Meteorology -- Research -- South Africa , Ionosondes -- Research -- South Africa
- Description: Space weather and its effect on technological systems are important for scientific research. Developing an understanding of the behaviour, sources and effects of ionospheric events form a basis for improving space weather prediction. This thesis attempts to use co-located radars and instruments for the analysis of ionospheric events over South Africa. The HF Doppler radar, ionosonde, Global Positioning System (GPS) and GPS ionospheric scintillation monitor (GISTM) receivers are co-located in Hermanus (34.4°S, 19.2°E), one of the observatories for the space science directorate of the South African National Space Agency (SANSA). Data was obtained from these radars and instruments and analysed for ionospheric events. Only the Hermanus station was selected for this analysis, because it is currently the only South African station that hosts all the mentioned radars and instruments. Ionospheric events identified include wave-like structures, Doppler spread, sudden frequency deviations and ionospheric oscillations associated with geomagnetic pulsations. For the purpose of this work, ionospheric events are defined as any unusual structures observed on the received signal and inferred from observations made by the HF Doppler radar. They were identified by visual inspection of the Doppler shift spectrograms. The magnitude and nature of the events vary, depending on their source and were observed by all, some or one instrument. This study suggests that the inclusion of a wider data coverage and more stations in South Africa merit consideration, especially since plans are underway to host a co-located radar network similar to that in Hermanus at at least three additional observatory sites in South Africa. This study lays a foundation for multi-station co-located radar and instrument observation and analysis of ionospheric events which should enhance the accuracy of space weather and HF communication prediction.
- Full Text:
- Date Issued: 2012
Multi-temporal assessment of spatial changes in vegetation distribution in the Swartkops estuary, Port Elizabeth, Eastern Cape, South Africa
- Authors: Atyosi, Yonwaba
- Date: 2017
- Subjects: Climatic changes -- South Africa -- Eastern Cape Environmental impact analysis Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13762 , vital:39710
- Description: Over the last decade, image classification has been widely used as a change detection method and provides detailed information for detecting and monitoring changes in land use and land cover (LULC). The main objective of this study was to reconstruct long-term changes in the spatial distribution of different vegetation types in the Swartkops Estuary from 1983 to 2013. The Swartkops Estuary is ecologically important for its wide range of vegetation types that are habitat to estuarine and riverine organisms. Four Landsat images for the years 1984 (Thematic Mapper), 1993 (Thematic Mapper), 2003(Enhanced Thematic Mapper +) and 2013 (Operational Land Imager) were used with the aid of aerial photographs that were used as an ancillary data source. The research methodology comprised of supervised classification, classification accuracy assessment and image differencing. Supervised classification was performed and results of the image classification process for the four time periods were compared to derive information on changes that occurred over the 29-year study period. Images were classified into the following classes: Estuarine water, Salt works, Zostera capensis, Spartina maritima, Terrestrial vegetation, Salt marsh, Swartkops thicket, Built-up areas, Bare areas, and Beach sand, using the Maximum likelihood classifier on Erdas IMAGINE 2014 Software. The significance of the image classification was tested using linear trend regression analysis. Image differencing was performed using 1984 and 2013 Landsat images to reconstruct overall changes in vegetation distribution of the Swartkops Estuary. Results of this investigation revealed significant changes in all land cover types, 24 ha increase from 1984 to 2013 in Zostera capensis as well as Spartina maritima, salt marshes increased by 14 ha between 1984 and 2013, terrestrial vegetation declined by 18 ha between 1984 and 2013. There was a stable increase in estuarine water from 1984 to 2013 by a total area of 29 ha. Water increased by 14 ha between 1984 and 1993, 11 ha increase between 1993 and 2003. However, there was a decline in estuarine water in the period between 2003 and 2013.This decline is associated with the increase in submerged macrophytes like Zostera capensis which utilise open water habitat. The dominant salt marsh species Limonium peregrinum, Sarcoconia pillansii and Spartina maritima occurred in the intertidal, supratidal and floodplain areas where the water table was the shallowest, with the soil moisture being the highest. These results indicate that Remote Sensing and GIS can be effectively used to detect and monitor changes in estuarine biodiversity and habitat in South Africa.
- Full Text:
- Date Issued: 2017
- Authors: Atyosi, Yonwaba
- Date: 2017
- Subjects: Climatic changes -- South Africa -- Eastern Cape Environmental impact analysis Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13762 , vital:39710
- Description: Over the last decade, image classification has been widely used as a change detection method and provides detailed information for detecting and monitoring changes in land use and land cover (LULC). The main objective of this study was to reconstruct long-term changes in the spatial distribution of different vegetation types in the Swartkops Estuary from 1983 to 2013. The Swartkops Estuary is ecologically important for its wide range of vegetation types that are habitat to estuarine and riverine organisms. Four Landsat images for the years 1984 (Thematic Mapper), 1993 (Thematic Mapper), 2003(Enhanced Thematic Mapper +) and 2013 (Operational Land Imager) were used with the aid of aerial photographs that were used as an ancillary data source. The research methodology comprised of supervised classification, classification accuracy assessment and image differencing. Supervised classification was performed and results of the image classification process for the four time periods were compared to derive information on changes that occurred over the 29-year study period. Images were classified into the following classes: Estuarine water, Salt works, Zostera capensis, Spartina maritima, Terrestrial vegetation, Salt marsh, Swartkops thicket, Built-up areas, Bare areas, and Beach sand, using the Maximum likelihood classifier on Erdas IMAGINE 2014 Software. The significance of the image classification was tested using linear trend regression analysis. Image differencing was performed using 1984 and 2013 Landsat images to reconstruct overall changes in vegetation distribution of the Swartkops Estuary. Results of this investigation revealed significant changes in all land cover types, 24 ha increase from 1984 to 2013 in Zostera capensis as well as Spartina maritima, salt marshes increased by 14 ha between 1984 and 2013, terrestrial vegetation declined by 18 ha between 1984 and 2013. There was a stable increase in estuarine water from 1984 to 2013 by a total area of 29 ha. Water increased by 14 ha between 1984 and 1993, 11 ha increase between 1993 and 2003. However, there was a decline in estuarine water in the period between 2003 and 2013.This decline is associated with the increase in submerged macrophytes like Zostera capensis which utilise open water habitat. The dominant salt marsh species Limonium peregrinum, Sarcoconia pillansii and Spartina maritima occurred in the intertidal, supratidal and floodplain areas where the water table was the shallowest, with the soil moisture being the highest. These results indicate that Remote Sensing and GIS can be effectively used to detect and monitor changes in estuarine biodiversity and habitat in South Africa.
- Full Text:
- Date Issued: 2017
The value of remnant habitat patches for conserving butterflies (Lepidoptera) in King Sabata Dalindyebo (KSD) Local Municipality, Eastern Cape, South Africa
- Authors: Avuletey, Richard
- Date: 2011
- Subjects: Butterflies -- Research Butterflies -- Behaviour South Africa -- Transkei
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:18490 , http://hdl.handle.net/11260/d1011285
- Description: Butterflies (Lepidoptera) have attracted more attention as indicators of terrestrial ecosystems than other invertebrates. This taxon is widely used as tools or subjects for biodiversity conservation planning in the Northern and Southern Hemispheres. The study determined butterfly species turnover at a-priori selected habitat patches in a protected area (Nduli Nature Reserve) and non-formally protected areas (outside Nduli Nature Reserve) of the KSD Local Municipality and their response to measured environmental variables. Using transect survey methods, 516 butterfly individuals belonging to 22 species were caught from 16 sampling units. Species dominance curves showed more butterfly species evenness outside reserve sites than inside. Hierarchical clustering using Bray-Curtis similarity matrices and Correspondence analysis (CA) grouped sampling units according to butterfly species sampled. Site habitat patches outside the reserve were richer in butterfly and overall abundance than inside the reserve. The Canonical Correspondence analysis (CCA) results revealed that certain site variables such as percentage herb cover, area of patch size, average grass height, grazing intensity, distance to the city centre and average flower density accounted for species distribution patterns at various sampling units. The conservation implications of the study suggest that patch level management of micro-habitats with sufficient flowering herbs, structural vegetation, and patch size with minimal disturbance within and outside reserve areas can encourage rare and common butterfly species richness and diversity.
- Full Text:
- Date Issued: 2011
- Authors: Avuletey, Richard
- Date: 2011
- Subjects: Butterflies -- Research Butterflies -- Behaviour South Africa -- Transkei
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:18490 , http://hdl.handle.net/11260/d1011285
- Description: Butterflies (Lepidoptera) have attracted more attention as indicators of terrestrial ecosystems than other invertebrates. This taxon is widely used as tools or subjects for biodiversity conservation planning in the Northern and Southern Hemispheres. The study determined butterfly species turnover at a-priori selected habitat patches in a protected area (Nduli Nature Reserve) and non-formally protected areas (outside Nduli Nature Reserve) of the KSD Local Municipality and their response to measured environmental variables. Using transect survey methods, 516 butterfly individuals belonging to 22 species were caught from 16 sampling units. Species dominance curves showed more butterfly species evenness outside reserve sites than inside. Hierarchical clustering using Bray-Curtis similarity matrices and Correspondence analysis (CA) grouped sampling units according to butterfly species sampled. Site habitat patches outside the reserve were richer in butterfly and overall abundance than inside the reserve. The Canonical Correspondence analysis (CCA) results revealed that certain site variables such as percentage herb cover, area of patch size, average grass height, grazing intensity, distance to the city centre and average flower density accounted for species distribution patterns at various sampling units. The conservation implications of the study suggest that patch level management of micro-habitats with sufficient flowering herbs, structural vegetation, and patch size with minimal disturbance within and outside reserve areas can encourage rare and common butterfly species richness and diversity.
- Full Text:
- Date Issued: 2011
Regulation of the indoleamines by sex steroids
- Authors: Awah, Edmund Kpabi
- Date: 1992
- Subjects: Steroids -- Research , Steroid drugs -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4053 , http://hdl.handle.net/10962/d1004114 , Steroids -- Research , Steroid drugs -- Research
- Description: Alteration of serum tryptophan leads to parallel alterations in brain tryptophan levels. Such changes in brain tryptophan levels has been shown to lead to mood disturbances. The primary enzyme responsible for altering serum tryptophan levels is the liver cytosolic enzyme, tryptophan pyrrolase. Activation of this enzyme is responsible for the enhanced catabolism of circulating tryptophan. The purpose of the present study was firstly to establish whether there is a link between sex steroids and tryptophan pyrrolase activity especially since sex steroids are also known to cause mood disturbances and secondly to determine the effects of sex steroids on brain indolamine metabolism. The results show that all three sex steroids induce the activity of tryptophan pyrrolase implying that they decrease serum tryptophan levels by the activation of tryptophan pyrrolase, thus making less tryptophan available for uptake by the brain. It was also shown that the sex steroids enhance the uptake of ¹⁴C-tryptophan by brain synatopsomes. In addition, the sex steroids influenced the pattern of metabolism of serotonin by organ cultures of rat pineal glands. It is possible that the sex steroids regulate the availability and uptake of indoleamines in the brain.
- Full Text:
- Date Issued: 1992
- Authors: Awah, Edmund Kpabi
- Date: 1992
- Subjects: Steroids -- Research , Steroid drugs -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4053 , http://hdl.handle.net/10962/d1004114 , Steroids -- Research , Steroid drugs -- Research
- Description: Alteration of serum tryptophan leads to parallel alterations in brain tryptophan levels. Such changes in brain tryptophan levels has been shown to lead to mood disturbances. The primary enzyme responsible for altering serum tryptophan levels is the liver cytosolic enzyme, tryptophan pyrrolase. Activation of this enzyme is responsible for the enhanced catabolism of circulating tryptophan. The purpose of the present study was firstly to establish whether there is a link between sex steroids and tryptophan pyrrolase activity especially since sex steroids are also known to cause mood disturbances and secondly to determine the effects of sex steroids on brain indolamine metabolism. The results show that all three sex steroids induce the activity of tryptophan pyrrolase implying that they decrease serum tryptophan levels by the activation of tryptophan pyrrolase, thus making less tryptophan available for uptake by the brain. It was also shown that the sex steroids enhance the uptake of ¹⁴C-tryptophan by brain synatopsomes. In addition, the sex steroids influenced the pattern of metabolism of serotonin by organ cultures of rat pineal glands. It is possible that the sex steroids regulate the availability and uptake of indoleamines in the brain.
- Full Text:
- Date Issued: 1992
A contribution to a generic revision of Simochromis and Tropheus (Pisces : Cichlidae) - from Lake Tanganyika, with special reference to the Pharyngeal Apophysis and its taxonomic importance
- Authors: Axelrod, Glen S
- Date: 1978
- Subjects: Cichlids -- Tanganyika, Lake
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5349 , http://hdl.handle.net/10962/d1007510 , Cichlids -- Tanganyika, Lake
- Description: The purpose of this thesis is to investigate the taxonomic status of Simochromis and Tropheue. Material for the study wae collected during three visits to Lake Tanganyika in 1976-1977. Tropheus polli G. S . Axelrod 1977, was found and described, and a new species of Simochromis was found and will be described in a forthcoming paper. Nine colour varieties of Tropheus maorii and three colour varieties of Tropheus duboisi were found and described. A diagnosis and description, with colour photographs, is given using morphometries and meristics of the five species of Simochromis and four species of Tropheus. A dissection and cleaning technique tor the pharyngeal apophysis and lower pharyngeal bone is explained, together with a method for the interpretation of relative bone composition of the pharyngeal apophysis. Photographs are included. The dentition is examined, evaluated and figured. Doubt has been cast upon the taxonomic validity of the composition of the pharyngeal apophysis as an indicator of affinity at the sub familial level. This is shown by its seeming lack of functional relationship, apparent arbitrary variation, interspecific variability in Simochromis and Tropheus, and intraspecific variability in S. diagramma and T. duboisi. Thus, the apophysis cannot be considered a reliable cichlid taxonomic characteristic at any level of classification, unless its validity is Substantiated in each instance. Furthermore, it is considered very probable that the Tropheus-Simochromis species complex is a monophyletic assemblage at the genus level, on the basis of similar dentition and mouth form, which is unique in Lake Tanganyika. It is proposed on phyletic grounds that Simochromis and Tropheus be united into the one genus Tropheus, and that Tropheus be divided into the subgenera , Tropheus (Tropheus) and Tropheus (Simochromis), along the lines of its previous division in two separate genera. Characteristics supporting this division include differences in the anal and dorsal fin meristic counts noted in the original descriptions of the genera. In addition, two modifications of the dentition were found during the course of this study which are not mentioned in any previous literature. It is considered probable, that Tropheus (Tropheus) and Tropheus (Simochromis) are monophyletic sister groups within the Tropheus complex. Pseudosimochromis Nelissen 1977 is not considered to be a taxonomically valid genus on either phyletic or gradistic grounds, and is included within Tropheus (Simochromis). The lower pharyngeal bone of T . (S.) diagramma is considered to be plesiomorphic in tooth arrangement, size and shape. A preliminary worKing hypothesis is established on the basis of the conjectures made and other available information which supports the phyletic relationship suggested by Fryer and lIes (1972). An illustration is given.
- Full Text:
- Date Issued: 1978
- Authors: Axelrod, Glen S
- Date: 1978
- Subjects: Cichlids -- Tanganyika, Lake
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5349 , http://hdl.handle.net/10962/d1007510 , Cichlids -- Tanganyika, Lake
- Description: The purpose of this thesis is to investigate the taxonomic status of Simochromis and Tropheue. Material for the study wae collected during three visits to Lake Tanganyika in 1976-1977. Tropheus polli G. S . Axelrod 1977, was found and described, and a new species of Simochromis was found and will be described in a forthcoming paper. Nine colour varieties of Tropheus maorii and three colour varieties of Tropheus duboisi were found and described. A diagnosis and description, with colour photographs, is given using morphometries and meristics of the five species of Simochromis and four species of Tropheus. A dissection and cleaning technique tor the pharyngeal apophysis and lower pharyngeal bone is explained, together with a method for the interpretation of relative bone composition of the pharyngeal apophysis. Photographs are included. The dentition is examined, evaluated and figured. Doubt has been cast upon the taxonomic validity of the composition of the pharyngeal apophysis as an indicator of affinity at the sub familial level. This is shown by its seeming lack of functional relationship, apparent arbitrary variation, interspecific variability in Simochromis and Tropheus, and intraspecific variability in S. diagramma and T. duboisi. Thus, the apophysis cannot be considered a reliable cichlid taxonomic characteristic at any level of classification, unless its validity is Substantiated in each instance. Furthermore, it is considered very probable that the Tropheus-Simochromis species complex is a monophyletic assemblage at the genus level, on the basis of similar dentition and mouth form, which is unique in Lake Tanganyika. It is proposed on phyletic grounds that Simochromis and Tropheus be united into the one genus Tropheus, and that Tropheus be divided into the subgenera , Tropheus (Tropheus) and Tropheus (Simochromis), along the lines of its previous division in two separate genera. Characteristics supporting this division include differences in the anal and dorsal fin meristic counts noted in the original descriptions of the genera. In addition, two modifications of the dentition were found during the course of this study which are not mentioned in any previous literature. It is considered probable, that Tropheus (Tropheus) and Tropheus (Simochromis) are monophyletic sister groups within the Tropheus complex. Pseudosimochromis Nelissen 1977 is not considered to be a taxonomically valid genus on either phyletic or gradistic grounds, and is included within Tropheus (Simochromis). The lower pharyngeal bone of T . (S.) diagramma is considered to be plesiomorphic in tooth arrangement, size and shape. A preliminary worKing hypothesis is established on the basis of the conjectures made and other available information which supports the phyletic relationship suggested by Fryer and lIes (1972). An illustration is given.
- Full Text:
- Date Issued: 1978
Construction project manager health and safety interventions towards improving workers' performance
- Authors: Ayessaki, Winn-Yam Houdou
- Date: 2016
- Subjects: Construction industry -- Management -- Health aspects Construction workers -- Health aspects -- South Africa Construction workers -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12275 , vital:27050
- Description: Optimum construction worker (CW) performance is required to achieve project delivery within project parameters. It is not always the case as CWs are regularly exposed to hazards, involved in accidents, their productivity is poor, they suffer from ill health, suffer from work-related musculoskeletal disorders (WMSDs) and contractors lack resources to allocate towards H&S. However, the lack or the absence of health and safety (H&S) measures, which the aforementioned depend on, has a negative impact on workers’ performance. Two descriptive surveys were conducted among professional construction project managers (CPMs) registered with the South African Council for Project and Construction Management Professions (SACPCMP) and general contractors (GCs) registered with the East Cape Master Builders Association (ECMBA). Interviews were also conducted with CPMs registered with the SACPCMP residing in the Nelson Mandela Bay metropolitan area. The salient findings include: • Accidents, which occur on construction sites, impact workers’ performance; • Inadequate H&S implementation affects both CW skills and motivation, which in turn affects their performance; • Poor constructability is relevant to H&S and CWs’ skills; • Provision and maintenance of welfare facilities are commonly inadequate and affect workers’ performance, and • Projects do not benefit from the adequate financial provision for H&S. It was concluded that exposure to hazards, poor site conditions, inadequate provision of welfare facilities, WMSDs, and insufficient financial provision for H&S affect workers’ performance by either incapacitating or demotivating them. Recommendations include : CPMs should make better use of their influence on clients; they should improve communication channels between project stakeholders; legislators need to raise awareness regarding H&S and worker welfare, and training and education institutions need to empower workers and professionals with H&S knowledge.
- Full Text:
- Date Issued: 2016
- Authors: Ayessaki, Winn-Yam Houdou
- Date: 2016
- Subjects: Construction industry -- Management -- Health aspects Construction workers -- Health aspects -- South Africa Construction workers -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12275 , vital:27050
- Description: Optimum construction worker (CW) performance is required to achieve project delivery within project parameters. It is not always the case as CWs are regularly exposed to hazards, involved in accidents, their productivity is poor, they suffer from ill health, suffer from work-related musculoskeletal disorders (WMSDs) and contractors lack resources to allocate towards H&S. However, the lack or the absence of health and safety (H&S) measures, which the aforementioned depend on, has a negative impact on workers’ performance. Two descriptive surveys were conducted among professional construction project managers (CPMs) registered with the South African Council for Project and Construction Management Professions (SACPCMP) and general contractors (GCs) registered with the East Cape Master Builders Association (ECMBA). Interviews were also conducted with CPMs registered with the SACPCMP residing in the Nelson Mandela Bay metropolitan area. The salient findings include: • Accidents, which occur on construction sites, impact workers’ performance; • Inadequate H&S implementation affects both CW skills and motivation, which in turn affects their performance; • Poor constructability is relevant to H&S and CWs’ skills; • Provision and maintenance of welfare facilities are commonly inadequate and affect workers’ performance, and • Projects do not benefit from the adequate financial provision for H&S. It was concluded that exposure to hazards, poor site conditions, inadequate provision of welfare facilities, WMSDs, and insufficient financial provision for H&S affect workers’ performance by either incapacitating or demotivating them. Recommendations include : CPMs should make better use of their influence on clients; they should improve communication channels between project stakeholders; legislators need to raise awareness regarding H&S and worker welfare, and training and education institutions need to empower workers and professionals with H&S knowledge.
- Full Text:
- Date Issued: 2016
The effectiveness of health and safety service providers' relative to construction
- Authors: Ayesu-Koranteng, Emma
- Date: 2017
- Subjects: Construction industry -- Health aspects -- South Africa Industrial safety -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15149 , vital:28151
- Description: The construction industry (CI) is well known to be one of the most dangerous industries in South Africa (SA) due to the complex nature of construction activities, advancement in technologies and an aging workforce, emphasising the need for training. Over the past two decades, the industry has come under the spotlight regarding Health and Safety (H&S). The Occupational Health and Safety (OH&S) Act 85 of 1993 and Construction Regulations (CR) 2014 as amended are the statutes that govern the H&S in the construction workplace. These statutes aim to provide minimum guidelines by which all operating in the industry should abide by in order to ensure the safety of all persons at work. A fundamental aspect of the OH&S Act and CR is for construction employers to assess occupational hazards and conduct risk assessments with remedies to mitigate or prevent such risks. Furthermore, employers are compelled by law to ensure that employees are made aware of the risks at the induction stage, in addition to preventative measures associated with their work activities. Therefore, training forms the structure by which H&S in the workplace can be improved. Training in itself is not enough if it is not based on the employees’ needs as assessed. Training needs to be relevant and effective if it is to have a significant effect in the prevention and possible reduction in the number of occupational injuries and fatalities in the CI. A question that led to the basis of this research was why there were such poor H&S practices in the CI when the statutes clearly require the importance of training. This research is aimed at establishing the effectiveness of service providers relative to construction. Service providers offer services such as training, auditing, SHEQ management, and other H&S related matters. Of fundamental importance is that training has a direct or indirect influence on the health and safety (H&S) of employees in the workplace. Thus, this research aims to determine the effectiveness of training offered by these service providers relative to construction. The researcher utilised the quantitative data collection method to collect primary data from a sample surveyed through a questionnaire, whilst collecting secondary data from books, the Internet, professional journals, and articles. The sampled population consisted of service providers, health and safety practitioners, construction managers, supervisors, and workers, all from the Nelson Mandela Bay Municipal Area. The data was analysed quantitatively using the Statistical Package for Social Sciences (SPSS), ANOVA and the one-sample t-test. The literature reviewed and findings of this quantitative research amongst construction personal such as top, senior, middle management (TSMM), and general workers and labourers (GWL) in the Nelson Mandela Bay Municipal area formed the basis of this study. The study reveals that training offered by service providers was indirectly unrelated to construction. Furthermore, the study also showed that management concurred that there was a strong belief that language did not influence their ability to understand the contents of the training, which is mainly provided in English. The group believed that training from service providers were at the correct level. Alternatively, GWL were of the belief that language influenced their ability to understand the training received. The study also indicated that procurement of these service providers were not based on their skills, knowledge and background in construction. This may be attributed to the fact that management are more advanced in terms of education than GWL. Lastly, the study revealed that a significant number of Safety, Health and Environment (SHE) officers are in the process of registering with the South African Council for the Project and Construction Management Professions (SACPCMP), the professional body responsible for the registration of Construction Health and Safety (CH&S) professions. This study will conclude with findings, conclusions, and recommendations that will be valuable to construction companies relative to the services of service providers.
- Full Text:
- Date Issued: 2017
- Authors: Ayesu-Koranteng, Emma
- Date: 2017
- Subjects: Construction industry -- Health aspects -- South Africa Industrial safety -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15149 , vital:28151
- Description: The construction industry (CI) is well known to be one of the most dangerous industries in South Africa (SA) due to the complex nature of construction activities, advancement in technologies and an aging workforce, emphasising the need for training. Over the past two decades, the industry has come under the spotlight regarding Health and Safety (H&S). The Occupational Health and Safety (OH&S) Act 85 of 1993 and Construction Regulations (CR) 2014 as amended are the statutes that govern the H&S in the construction workplace. These statutes aim to provide minimum guidelines by which all operating in the industry should abide by in order to ensure the safety of all persons at work. A fundamental aspect of the OH&S Act and CR is for construction employers to assess occupational hazards and conduct risk assessments with remedies to mitigate or prevent such risks. Furthermore, employers are compelled by law to ensure that employees are made aware of the risks at the induction stage, in addition to preventative measures associated with their work activities. Therefore, training forms the structure by which H&S in the workplace can be improved. Training in itself is not enough if it is not based on the employees’ needs as assessed. Training needs to be relevant and effective if it is to have a significant effect in the prevention and possible reduction in the number of occupational injuries and fatalities in the CI. A question that led to the basis of this research was why there were such poor H&S practices in the CI when the statutes clearly require the importance of training. This research is aimed at establishing the effectiveness of service providers relative to construction. Service providers offer services such as training, auditing, SHEQ management, and other H&S related matters. Of fundamental importance is that training has a direct or indirect influence on the health and safety (H&S) of employees in the workplace. Thus, this research aims to determine the effectiveness of training offered by these service providers relative to construction. The researcher utilised the quantitative data collection method to collect primary data from a sample surveyed through a questionnaire, whilst collecting secondary data from books, the Internet, professional journals, and articles. The sampled population consisted of service providers, health and safety practitioners, construction managers, supervisors, and workers, all from the Nelson Mandela Bay Municipal Area. The data was analysed quantitatively using the Statistical Package for Social Sciences (SPSS), ANOVA and the one-sample t-test. The literature reviewed and findings of this quantitative research amongst construction personal such as top, senior, middle management (TSMM), and general workers and labourers (GWL) in the Nelson Mandela Bay Municipal area formed the basis of this study. The study reveals that training offered by service providers was indirectly unrelated to construction. Furthermore, the study also showed that management concurred that there was a strong belief that language did not influence their ability to understand the contents of the training, which is mainly provided in English. The group believed that training from service providers were at the correct level. Alternatively, GWL were of the belief that language influenced their ability to understand the training received. The study also indicated that procurement of these service providers were not based on their skills, knowledge and background in construction. This may be attributed to the fact that management are more advanced in terms of education than GWL. Lastly, the study revealed that a significant number of Safety, Health and Environment (SHE) officers are in the process of registering with the South African Council for the Project and Construction Management Professions (SACPCMP), the professional body responsible for the registration of Construction Health and Safety (CH&S) professions. This study will conclude with findings, conclusions, and recommendations that will be valuable to construction companies relative to the services of service providers.
- Full Text:
- Date Issued: 2017
Effect of diet and sex-sorting on growth and gonad development in farmed South African abalone, Haliotis midae
- Authors: Ayres, Devin William Philip
- Date: 2014
- Subjects: Haliotis midae -- South Africa , Haliotis midae fisheries -- South Africa , Abalone culture -- South Africa , Abalones -- Physiology -- South Africa , Abalones -- South Africa -- Growth , Abalones -- Feeding and feeds -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5357 , http://hdl.handle.net/10962/d1010856 , Haliotis midae -- South Africa , Haliotis midae fisheries -- South Africa , Abalone culture -- South Africa , Abalones -- Physiology -- South Africa , Abalones -- South Africa -- Growth , Abalones -- Feeding and feeds -- South Africa
- Description: Abalone, Haliotis midae, farmers in South Africa that feed formulated diets reported a periodic drop in abalone growth during periods of increased gonad development. A large drop in abalone biomass was noticed after presumed spawning events. This study was aimed to determine the effect of diet and sex-sorting on gonad development in abalone. Experiments were conducted on a commercial abalone farm from July 2012 to the end of June 2013. Isonitrogenous and isoenergetic diets were formulated with two protein sources. A fishmeal and soybean meal (S-diet) diet and a fishmeal only (F-diet) diet were fed to abalone (50 - 70 g abalone⁻¹) over 12 months. Weight and length gain, gonad bulk index (GBI), visceral index (%) and meat mass index (%) were determined monthly and seasonally. A histological study on the female gonads was conducted. This study also included an experiment to test the effect of sex-sorting (70 - 80 g abalone⁻¹) on growth and body composition with treatments including males (M), females (F) and equal numbers of males and females (MF). Weight gain and length gain were faster in S-diet-fed abalone (RM-ANOVA, F ₍₁, ₁₆₎ = 7.77, p = 0.01; F ₍₁, ₆₉₎ = 49.9, p < 0.001, respectively). Gonad development was significantly affected by the inclusion of soybean meal with S-diet-fed abalone showing higher GBI-values than F-diet-fed abalone (RM-ANOVA, F ₍₁, ₃₃)= 16.22, p = 0.0003). Male abalone had higher GBI-values than females (RM-ANOVA, F ₍₁, ₃₃₎ = 39.87, p < 0.0001). There was no significant difference in average feed conversion ratio (FCR) between diets over time (RM-ANOVA, F ₍₁, ₂₁₎ = 0.008, p = 0.97). However, average FCR-values were significantly highest between November 2012 and March 2013, the presumed spawning season. The visceral mass (gut and gonad) as a proportion of whole mass (visceral index, %) was significantly higher in abalone fed the S-diet (RM-ANOVA; F ₍₁, ₆₉₎ = 68.06, p < 0.0001). There was no difference in meat mass index (%) between diets for both male and female abalone (RM-ANOVA; F ₍₇, ₂₄₈₎ = 0.80, p = 0.60; F ₍₇, ₂₄₁₎ = 1.7, p = 0.11,respectively). Meat mass index significantly decreased from September 2012 to February 2013 coinciding with the period of high GBI-values. The distribution of oocyte maturity stages differed between diets. The majority of oocytes within S-diet-fed abalone were fully mature stage 8 oocytes compared to a majority of stage 7 oocytes in F-diet-fed abalone. Histology corroborated peaks in GBI-values for abalone fed both diets. There was no significant difference in growth, GBI, visceral index (%) and meat mass index (%) between abalone sorted into monosex and mixed-sex populations. Thus, the presence of the opposite sex did not have an effect on growth and gonad mass in H. midae. The phytoestrogens daidzin, glycitin, genistin, daidzein, glycitein and genistein were present in soybean meal and only traceable amounts were found in the F-diet. This study provided evidence that soybean meal present in formulated feed affected growth and gonad development in H.midae. The difference in the distribution of the maturity stages of oocytes was affected by diet. Sex-sorting abalone into monosex and mixed-sex populations had no influence on weight and length gain and gonad development.
- Full Text:
- Date Issued: 2014
- Authors: Ayres, Devin William Philip
- Date: 2014
- Subjects: Haliotis midae -- South Africa , Haliotis midae fisheries -- South Africa , Abalone culture -- South Africa , Abalones -- Physiology -- South Africa , Abalones -- South Africa -- Growth , Abalones -- Feeding and feeds -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5357 , http://hdl.handle.net/10962/d1010856 , Haliotis midae -- South Africa , Haliotis midae fisheries -- South Africa , Abalone culture -- South Africa , Abalones -- Physiology -- South Africa , Abalones -- South Africa -- Growth , Abalones -- Feeding and feeds -- South Africa
- Description: Abalone, Haliotis midae, farmers in South Africa that feed formulated diets reported a periodic drop in abalone growth during periods of increased gonad development. A large drop in abalone biomass was noticed after presumed spawning events. This study was aimed to determine the effect of diet and sex-sorting on gonad development in abalone. Experiments were conducted on a commercial abalone farm from July 2012 to the end of June 2013. Isonitrogenous and isoenergetic diets were formulated with two protein sources. A fishmeal and soybean meal (S-diet) diet and a fishmeal only (F-diet) diet were fed to abalone (50 - 70 g abalone⁻¹) over 12 months. Weight and length gain, gonad bulk index (GBI), visceral index (%) and meat mass index (%) were determined monthly and seasonally. A histological study on the female gonads was conducted. This study also included an experiment to test the effect of sex-sorting (70 - 80 g abalone⁻¹) on growth and body composition with treatments including males (M), females (F) and equal numbers of males and females (MF). Weight gain and length gain were faster in S-diet-fed abalone (RM-ANOVA, F ₍₁, ₁₆₎ = 7.77, p = 0.01; F ₍₁, ₆₉₎ = 49.9, p < 0.001, respectively). Gonad development was significantly affected by the inclusion of soybean meal with S-diet-fed abalone showing higher GBI-values than F-diet-fed abalone (RM-ANOVA, F ₍₁, ₃₃)= 16.22, p = 0.0003). Male abalone had higher GBI-values than females (RM-ANOVA, F ₍₁, ₃₃₎ = 39.87, p < 0.0001). There was no significant difference in average feed conversion ratio (FCR) between diets over time (RM-ANOVA, F ₍₁, ₂₁₎ = 0.008, p = 0.97). However, average FCR-values were significantly highest between November 2012 and March 2013, the presumed spawning season. The visceral mass (gut and gonad) as a proportion of whole mass (visceral index, %) was significantly higher in abalone fed the S-diet (RM-ANOVA; F ₍₁, ₆₉₎ = 68.06, p < 0.0001). There was no difference in meat mass index (%) between diets for both male and female abalone (RM-ANOVA; F ₍₇, ₂₄₈₎ = 0.80, p = 0.60; F ₍₇, ₂₄₁₎ = 1.7, p = 0.11,respectively). Meat mass index significantly decreased from September 2012 to February 2013 coinciding with the period of high GBI-values. The distribution of oocyte maturity stages differed between diets. The majority of oocytes within S-diet-fed abalone were fully mature stage 8 oocytes compared to a majority of stage 7 oocytes in F-diet-fed abalone. Histology corroborated peaks in GBI-values for abalone fed both diets. There was no significant difference in growth, GBI, visceral index (%) and meat mass index (%) between abalone sorted into monosex and mixed-sex populations. Thus, the presence of the opposite sex did not have an effect on growth and gonad mass in H. midae. The phytoestrogens daidzin, glycitin, genistin, daidzein, glycitein and genistein were present in soybean meal and only traceable amounts were found in the F-diet. This study provided evidence that soybean meal present in formulated feed affected growth and gonad development in H.midae. The difference in the distribution of the maturity stages of oocytes was affected by diet. Sex-sorting abalone into monosex and mixed-sex populations had no influence on weight and length gain and gonad development.
- Full Text:
- Date Issued: 2014
Biogeomorphic aspects of lichen colonisation in part of western Dronning Maud Land, Antarctica
- Authors: Ayres, Gabrielle Alexzena
- Date: 2017
- Subjects: Lichen communities -- Queen Maud Land , Lichens -- Ecology -- Queen Maud Land , Polar regions , Ecology -- Polar regions , Antarctica , Ecology -- Antarctica
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/19713 , vital:22477
- Description: Ice-free regions in Antarctica provide natural laboratories for investigating and modelling change in landscapes and ecosystems. The terrestrial ecosystems in western Dronning Maud Land are potentially critical to improve current understanding of polar ecosystems, however, they remain poorly represented and under-protected. Lichen habitats were used to elucidate geomorphic-biological feedbacks that shape the landscape’s topography and biodiversity, which in turn promote environmental heterogeneity. Environmental parameters acting on two landforms were measured to determine the colonisation and growth of lichens in niche habitats. The habitats were identified and characterised, and topographic heterogeneity was found to control lichen colonisation. Micro-topographical niches provide the most stable environments for colonisation, and are preferred habitats. Lichen-habitat interactions were species specific, and closely related to insolation and moisture availability. The bidirectional relationships between rock weathering and lichen colonisation was ascertained. Results showed that lichens are good indicators of landform heterogeneity, but also promote landform heterogeneity. Given the habitat preferences of specific lichen species, they provide proxy to evaluating environmental responses, especially environmental change. The findings of this research are to be used as baseline data for future studies exploring ecosystem development in emerging landforms.
- Full Text:
- Date Issued: 2017
- Authors: Ayres, Gabrielle Alexzena
- Date: 2017
- Subjects: Lichen communities -- Queen Maud Land , Lichens -- Ecology -- Queen Maud Land , Polar regions , Ecology -- Polar regions , Antarctica , Ecology -- Antarctica
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/19713 , vital:22477
- Description: Ice-free regions in Antarctica provide natural laboratories for investigating and modelling change in landscapes and ecosystems. The terrestrial ecosystems in western Dronning Maud Land are potentially critical to improve current understanding of polar ecosystems, however, they remain poorly represented and under-protected. Lichen habitats were used to elucidate geomorphic-biological feedbacks that shape the landscape’s topography and biodiversity, which in turn promote environmental heterogeneity. Environmental parameters acting on two landforms were measured to determine the colonisation and growth of lichens in niche habitats. The habitats were identified and characterised, and topographic heterogeneity was found to control lichen colonisation. Micro-topographical niches provide the most stable environments for colonisation, and are preferred habitats. Lichen-habitat interactions were species specific, and closely related to insolation and moisture availability. The bidirectional relationships between rock weathering and lichen colonisation was ascertained. Results showed that lichens are good indicators of landform heterogeneity, but also promote landform heterogeneity. Given the habitat preferences of specific lichen species, they provide proxy to evaluating environmental responses, especially environmental change. The findings of this research are to be used as baseline data for future studies exploring ecosystem development in emerging landforms.
- Full Text:
- Date Issued: 2017
In vitro cytotoxic effects of selected Nigerian medicinal plant extracts on cancer cell lines
- Authors: Baatjies, Lucinda
- Date: 2012
- Subjects: Cancer -- Treatment , Cancer cells , Medicinal plants , Plant extracts , Traditional medicine , Public health
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10316 , http://hdl.handle.net/10948/d1008191 , Cancer -- Treatment , Cancer cells , Medicinal plants , Plant extracts , Traditional medicine , Public health
- Description: Cancer is a disease that imposes a heavy burden on public health and poses a challenge to science. The World Health Organization estimates that 80 percent of people in developing countries of the world rely on traditional medicine for their primary health needs, and about 85 percent of traditional medicine involves the use of plant extracts. This is particularly true in Africa where a large percentage of the population depends upon medicinal plants for health care. Therefore, detailed screening and evaluation of bioactive substances for chemotherapeutic purposes of African plants are urgently warranted. Furthermore, this will serve to validate the efficacy and safety of African traditional medicine. The current study investigated the in vitro cytotoxic effects of 17 ethanolic extracts of the following 16 plants used in traditional anticancer medicine in Nigeria: Sapium ellipticum leaves, Sapium ellipticum stembark, Combretum paniculatum, Celosia trigyna, Pupalia lappacea, Justica extensa, Hedranthera barteri leaves, Alternanthera sessilis, Ethulia conyzoides leaves, Lannea nigritana stembark, Combretum zenkeri root, Combretum molle leaves, Adenanthera parvoniana, Lannea acida, Cyathula achyranthoides, Drymaria cordata, Cyathula prostrata, against HeLa cancer cells. Five of the most promising extracts (Sapium ellipticum leaves, Combretum paniculatum, Celosia trigyna, Drymaria cordata, Cyathula prostrata) were selected for further screening against HT29 and MCF-7 cancer cells. Of the five, the first two were investigated further based on their activities in the screening phase. The S. ellipticum leaf extract yielded IC50 values of 88.60 ± 0.03 and 93.03 ± 0.03 μg/ml against HeLa and MCF-7, respectively. The toxicity was also evaluated on normal cells and an IC50 of 77.66 μg/ml was obtained for peripheral blood mononuclear cells (PBMCs). The IC50 values for proliferating and confluent Chang liver cells were both >125 μg/ml. These results suggest that the extract may be selective for specific cell types. Bio-assay guided fractionation of the S. ellipticum ethanolic extract yielded two active fractions; chloroform and ethyl acetate. Two compounds isolated from the chloroform extract were screened against the three cancer cell lines and found to be inactive. Three compounds were isolated from the ethyl acetate fraction and revealed IC50 values < 62.5 and < 31 μg/ml against MCF-7. Unfortunately these two compounds soon lost activity before any further work could be done on them and work was continued with the crude extract.
- Full Text:
- Date Issued: 2012
- Authors: Baatjies, Lucinda
- Date: 2012
- Subjects: Cancer -- Treatment , Cancer cells , Medicinal plants , Plant extracts , Traditional medicine , Public health
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10316 , http://hdl.handle.net/10948/d1008191 , Cancer -- Treatment , Cancer cells , Medicinal plants , Plant extracts , Traditional medicine , Public health
- Description: Cancer is a disease that imposes a heavy burden on public health and poses a challenge to science. The World Health Organization estimates that 80 percent of people in developing countries of the world rely on traditional medicine for their primary health needs, and about 85 percent of traditional medicine involves the use of plant extracts. This is particularly true in Africa where a large percentage of the population depends upon medicinal plants for health care. Therefore, detailed screening and evaluation of bioactive substances for chemotherapeutic purposes of African plants are urgently warranted. Furthermore, this will serve to validate the efficacy and safety of African traditional medicine. The current study investigated the in vitro cytotoxic effects of 17 ethanolic extracts of the following 16 plants used in traditional anticancer medicine in Nigeria: Sapium ellipticum leaves, Sapium ellipticum stembark, Combretum paniculatum, Celosia trigyna, Pupalia lappacea, Justica extensa, Hedranthera barteri leaves, Alternanthera sessilis, Ethulia conyzoides leaves, Lannea nigritana stembark, Combretum zenkeri root, Combretum molle leaves, Adenanthera parvoniana, Lannea acida, Cyathula achyranthoides, Drymaria cordata, Cyathula prostrata, against HeLa cancer cells. Five of the most promising extracts (Sapium ellipticum leaves, Combretum paniculatum, Celosia trigyna, Drymaria cordata, Cyathula prostrata) were selected for further screening against HT29 and MCF-7 cancer cells. Of the five, the first two were investigated further based on their activities in the screening phase. The S. ellipticum leaf extract yielded IC50 values of 88.60 ± 0.03 and 93.03 ± 0.03 μg/ml against HeLa and MCF-7, respectively. The toxicity was also evaluated on normal cells and an IC50 of 77.66 μg/ml was obtained for peripheral blood mononuclear cells (PBMCs). The IC50 values for proliferating and confluent Chang liver cells were both >125 μg/ml. These results suggest that the extract may be selective for specific cell types. Bio-assay guided fractionation of the S. ellipticum ethanolic extract yielded two active fractions; chloroform and ethyl acetate. Two compounds isolated from the chloroform extract were screened against the three cancer cell lines and found to be inactive. Three compounds were isolated from the ethyl acetate fraction and revealed IC50 values < 62.5 and < 31 μg/ml against MCF-7. Unfortunately these two compounds soon lost activity before any further work could be done on them and work was continued with the crude extract.
- Full Text:
- Date Issued: 2012
Towards understanding the effect of size variation on the aggressive and feeding behaviours of juvenile dusky kob Argyrosomus japonicus (Pisces: Sciaenidae)
- Authors: Babane, Siviwe Elvis
- Date: 2018
- Subjects: Argyrosomus -- Feeding and feeds , Aquaculture , Fishes -- Cannibalism , Fishes -- Feeding and feeds
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/59592 , vital:27629
- Description: Many studies have been conducted on the effect of size-grading in other fish species. However, there is a paucity of scientific information on the effects of size variation on cannibalism of juvenile dusky kob. Thus, a study focusing on the effect of size variation on juvenile dusky kob aggressive and feeding (browsing) behaviours was conducted. Three separate groups of hatchery-reared juvenile dusky kob of were obtained from Oceanwise (Pty) Ltd for use in a series of three experimental trials. In all trials, juvenile fish of the same age were size-graded and the COV-value was used to determine the size variation. The focal fish (largest fish) was exposed to groups of fish with different size variation for 30-min. behavioural observations before and after feeding in randomised trials. The first experimental trial (Chapter 2) quantified the effect of increasing size variation and observation time on the aggressive and browsing behaviours of juvenile dusky kob. On average, juvenile dusky kob weighed 3.60 ± 0.68 g fish-1 and measured 5.8 ± 0.41 mm. Each focal fish was observed (a) before feeding in the morning, (b) 2 h after feeding, (c) 6 h after feeding and (d) 12 h after feeding. Fish increased browsing behaviours (averaging 6.60 ± 0.56) and decreased intimidating aggressive behaviours (18.60 ± 1.39) 12 h after feeding. Other aggressive behaviours occurred but did not differ between observation times. Aggressive and browsing behaviours positively correlated with size variation variables, predominantly, 12 h after feeding. An average frequency of 19 chases were observed positively correlated with size variation, followed by average frequencies of 17 body bites and browses, and 11 tail bites per 30 min. Some behaviours including average frequencies of 0.2 chases, 4 tail bites, 2.4 intimidating and 0.3 browsing behaviours negatively correlated with the size variation, generally closer to the last meal. These preliminary observations thus showed that fish have become hungry approximately 6-12 h after feeding and substituted certain behaviours for others as time after feeding passed and as size variation increased. The second experimental trial (Chapter 3) consisted of the observations further testing the relationship between aggressive behaviours and size variation of juveniles of dusky kob averaging 0.43 ± 0.27 g fish-1. The focal fish was exposed to groups of fish of four size variation (COV) treatments for observations before and 12 h after feeding. Aggressive behaviours positively correlated with size variation both before and 12 h after feeding. An average frequency of 437 body bites positively correlated more often with COV, followed by average frequencies of 365 intimidating behaviours and 199 tail bites per 30 min., respectively, before and 12 h after feeding. The least often exhibited aggressive behaviours averaged 26 chases while positively correlating with size variation on the times specified. An average frequency of 311 intimidating behaviours before and after feeding including average of 28 tail bites after feeding negatively correlated with size variation. This may relate to shift of behaviours depending on the needs and capacity of the fish. Apparently, aggressive fish can change its behaviour as a function of COV-values rather than the mean size of the other fish. The third trial (Chapter 4) investigated the effect of the aggressor’s (focal fish) size in relation its aggressive and browsing behaviours to other fish (non-focal fish). Juvenile fish used for this trial, on average, weighed 30 ± 7.63 g fish-1. Aggressive and browsing behaviours were observed in four treatments of a) high COV and mean weight below, b) low COV and mean weight less, c) high COV and mean weight equivalent to and d) low COV and mean weight higher than that of the focal fish. Increased frequencies of aggressive and browsing behaviours per 30 min. occurred in treatment A, sharing similar frequencies in treatment C, compared to the other treatments (B and D) which shared certain frequencies. The intimidating behaviours predominated, followed by browsing, body bites, chases and tail bites, respectively. The results of the overall study suggest that the time passed after feeding and increasing size variation and differences facilitated aggressive and browsing behaviours in juvenile dusky kob. Dusky kob showed increasing aggressive behaviours as early as in the first two weeks after hatching, averaging 0.43 ± 0.27 g fish-1 with the frequency correlating with size differences. Consistent size-grading technique in the same-age fish should be used to manage size variation associated with aggressive behaviours. The period of about 4-6 h after feeding may explain the noticeable increased aggressive and browsing behaviours. Thus, fish should be fed immediately before or after evacuation of their guts to maintain less-aggressive behaviours of juvenile dusky kob. Fish generally increased aggressive and browsing acts before and long time after feeding than closer to after feeding. The study has provided the fundamental scientific groundwork for fish farmers and future researchers can further explore size variation, time after feeding and gut evacuation rate as critical components of aggressive behaviours. The scientific knowledge of aggressive and cannibalistic behaviours has essential application in farming management to achieve improved survival and growth rates in juvenile fish.
- Full Text:
- Date Issued: 2018
- Authors: Babane, Siviwe Elvis
- Date: 2018
- Subjects: Argyrosomus -- Feeding and feeds , Aquaculture , Fishes -- Cannibalism , Fishes -- Feeding and feeds
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/59592 , vital:27629
- Description: Many studies have been conducted on the effect of size-grading in other fish species. However, there is a paucity of scientific information on the effects of size variation on cannibalism of juvenile dusky kob. Thus, a study focusing on the effect of size variation on juvenile dusky kob aggressive and feeding (browsing) behaviours was conducted. Three separate groups of hatchery-reared juvenile dusky kob of were obtained from Oceanwise (Pty) Ltd for use in a series of three experimental trials. In all trials, juvenile fish of the same age were size-graded and the COV-value was used to determine the size variation. The focal fish (largest fish) was exposed to groups of fish with different size variation for 30-min. behavioural observations before and after feeding in randomised trials. The first experimental trial (Chapter 2) quantified the effect of increasing size variation and observation time on the aggressive and browsing behaviours of juvenile dusky kob. On average, juvenile dusky kob weighed 3.60 ± 0.68 g fish-1 and measured 5.8 ± 0.41 mm. Each focal fish was observed (a) before feeding in the morning, (b) 2 h after feeding, (c) 6 h after feeding and (d) 12 h after feeding. Fish increased browsing behaviours (averaging 6.60 ± 0.56) and decreased intimidating aggressive behaviours (18.60 ± 1.39) 12 h after feeding. Other aggressive behaviours occurred but did not differ between observation times. Aggressive and browsing behaviours positively correlated with size variation variables, predominantly, 12 h after feeding. An average frequency of 19 chases were observed positively correlated with size variation, followed by average frequencies of 17 body bites and browses, and 11 tail bites per 30 min. Some behaviours including average frequencies of 0.2 chases, 4 tail bites, 2.4 intimidating and 0.3 browsing behaviours negatively correlated with the size variation, generally closer to the last meal. These preliminary observations thus showed that fish have become hungry approximately 6-12 h after feeding and substituted certain behaviours for others as time after feeding passed and as size variation increased. The second experimental trial (Chapter 3) consisted of the observations further testing the relationship between aggressive behaviours and size variation of juveniles of dusky kob averaging 0.43 ± 0.27 g fish-1. The focal fish was exposed to groups of fish of four size variation (COV) treatments for observations before and 12 h after feeding. Aggressive behaviours positively correlated with size variation both before and 12 h after feeding. An average frequency of 437 body bites positively correlated more often with COV, followed by average frequencies of 365 intimidating behaviours and 199 tail bites per 30 min., respectively, before and 12 h after feeding. The least often exhibited aggressive behaviours averaged 26 chases while positively correlating with size variation on the times specified. An average frequency of 311 intimidating behaviours before and after feeding including average of 28 tail bites after feeding negatively correlated with size variation. This may relate to shift of behaviours depending on the needs and capacity of the fish. Apparently, aggressive fish can change its behaviour as a function of COV-values rather than the mean size of the other fish. The third trial (Chapter 4) investigated the effect of the aggressor’s (focal fish) size in relation its aggressive and browsing behaviours to other fish (non-focal fish). Juvenile fish used for this trial, on average, weighed 30 ± 7.63 g fish-1. Aggressive and browsing behaviours were observed in four treatments of a) high COV and mean weight below, b) low COV and mean weight less, c) high COV and mean weight equivalent to and d) low COV and mean weight higher than that of the focal fish. Increased frequencies of aggressive and browsing behaviours per 30 min. occurred in treatment A, sharing similar frequencies in treatment C, compared to the other treatments (B and D) which shared certain frequencies. The intimidating behaviours predominated, followed by browsing, body bites, chases and tail bites, respectively. The results of the overall study suggest that the time passed after feeding and increasing size variation and differences facilitated aggressive and browsing behaviours in juvenile dusky kob. Dusky kob showed increasing aggressive behaviours as early as in the first two weeks after hatching, averaging 0.43 ± 0.27 g fish-1 with the frequency correlating with size differences. Consistent size-grading technique in the same-age fish should be used to manage size variation associated with aggressive behaviours. The period of about 4-6 h after feeding may explain the noticeable increased aggressive and browsing behaviours. Thus, fish should be fed immediately before or after evacuation of their guts to maintain less-aggressive behaviours of juvenile dusky kob. Fish generally increased aggressive and browsing acts before and long time after feeding than closer to after feeding. The study has provided the fundamental scientific groundwork for fish farmers and future researchers can further explore size variation, time after feeding and gut evacuation rate as critical components of aggressive behaviours. The scientific knowledge of aggressive and cannibalistic behaviours has essential application in farming management to achieve improved survival and growth rates in juvenile fish.
- Full Text:
- Date Issued: 2018
Studies on captive rearing of spotted grunter, pommadasys commersonnii (Pisces : Haemulidae) under ambient conditions
- Authors: Bacela, Ntobeko
- Date: 1999
- Subjects: Grunts (Fishes)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5322 , http://hdl.handle.net/10962/d1005167 , Grunts (Fishes)
- Description: The effects of stocking density, size grading, feeding frequency and ambient temperature on the growth performance and size variation of spotted grunter, Pomadasys commersonnii were investigated. The time that would be required to rear the species to market size was modelled. An area where maximum growth rate could be achieved under ambient temperature conditions, and therefore the location of a commercial farm within the distribution range of spotted grunter along the coast of South Africa, was predicted. The growth performance of spotted grunter was not significantly affected by stocking density. Growth performance seemed to improve with increasing stocking density. Competitive behaviour was absent among fish in the various stocking densities. Growth in terms of fork length and body weight was not significantly different between stocking densities. The highest specific growth rate, best food consumption, food conversion ratio and protein efficiency ratio of the fish were recorded at a density of 6.4 kg/m³, whereas the best condition factor was recorded at a density of 3.8 kg/m³. The lack of significant difference in many of the growth parameters between the various stocking densities suggest that juvenile spotted grunter could be reared at densities higher than 6.4 kg/m³. Further investigations are needed to determine the optimal initial stocking density of juvenile spotted grunter under ambient temperature and photoperiod conditions. Replacing the largest fish with average sized fish did not have a significant effect on the specific growth rate and competitive behaviour based on the relationship between the coefficient of variation and average size. Feeding frequency had a sIgnificant effect on food consumption, food conversion and protein efficiency ratio, and not on size increase, specific growth rate and condition factor. Its effect on competitive behaviour could not be conclusively explained. The best food conversion ratio recorded when feeding once a day showed that although the fish consumed a limited amount of food, they utilised the food that was fed most effectively. It is suggested that the fish be fed three times a day. The survival of juvenile spotted grunter was 95.6 % when feeding three times a day compared to 90 and 90.2 % when feeding once and five times a day, respectively. Fluctuating ambient temperature had a dramatic effect on specific growth rate and food consumption of spotted grunter. Growth modelling showed that the fish could be reared to a market size of 550 g (270 mm FL) in 19 months under ambient temperature conditions (23.2°C) at Richard's Bay. The optimal predicted rearing period of 19 months is approximately seven months less than that calculated for fish in the wild, and can possibly, be reduced further by feeding a balanced diet. The overall food consumption (on a dry weight basis) in the three size classes ranged from 0.15 ± 0.16 to 0.38 ± 0.35 % body weight per day. Food conversion ratio improved with increasing fish size. This relationship was attributed to diet quality and more specifically, the protein : energy ratio. As a result, fish in the large size class had the best overall protein efficiency ratio. Maximum specific growth rates of1.5, 0.84 and 0.74 % body weight per day were recorded from the small, medium and large size classes in the peak of summer with average daily temperature ranging from 21 to 22°C. Positive slopes in the coefficient of variation against fish size in the large size class indicated the presence of competitive behaviour which was attributed to the onset of adolescence. The information from this study can be used for pilot production of spotted grunter. Further research should be undertaken to investigate captive reproduction of the species.
- Full Text:
- Date Issued: 1999
- Authors: Bacela, Ntobeko
- Date: 1999
- Subjects: Grunts (Fishes)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5322 , http://hdl.handle.net/10962/d1005167 , Grunts (Fishes)
- Description: The effects of stocking density, size grading, feeding frequency and ambient temperature on the growth performance and size variation of spotted grunter, Pomadasys commersonnii were investigated. The time that would be required to rear the species to market size was modelled. An area where maximum growth rate could be achieved under ambient temperature conditions, and therefore the location of a commercial farm within the distribution range of spotted grunter along the coast of South Africa, was predicted. The growth performance of spotted grunter was not significantly affected by stocking density. Growth performance seemed to improve with increasing stocking density. Competitive behaviour was absent among fish in the various stocking densities. Growth in terms of fork length and body weight was not significantly different between stocking densities. The highest specific growth rate, best food consumption, food conversion ratio and protein efficiency ratio of the fish were recorded at a density of 6.4 kg/m³, whereas the best condition factor was recorded at a density of 3.8 kg/m³. The lack of significant difference in many of the growth parameters between the various stocking densities suggest that juvenile spotted grunter could be reared at densities higher than 6.4 kg/m³. Further investigations are needed to determine the optimal initial stocking density of juvenile spotted grunter under ambient temperature and photoperiod conditions. Replacing the largest fish with average sized fish did not have a significant effect on the specific growth rate and competitive behaviour based on the relationship between the coefficient of variation and average size. Feeding frequency had a sIgnificant effect on food consumption, food conversion and protein efficiency ratio, and not on size increase, specific growth rate and condition factor. Its effect on competitive behaviour could not be conclusively explained. The best food conversion ratio recorded when feeding once a day showed that although the fish consumed a limited amount of food, they utilised the food that was fed most effectively. It is suggested that the fish be fed three times a day. The survival of juvenile spotted grunter was 95.6 % when feeding three times a day compared to 90 and 90.2 % when feeding once and five times a day, respectively. Fluctuating ambient temperature had a dramatic effect on specific growth rate and food consumption of spotted grunter. Growth modelling showed that the fish could be reared to a market size of 550 g (270 mm FL) in 19 months under ambient temperature conditions (23.2°C) at Richard's Bay. The optimal predicted rearing period of 19 months is approximately seven months less than that calculated for fish in the wild, and can possibly, be reduced further by feeding a balanced diet. The overall food consumption (on a dry weight basis) in the three size classes ranged from 0.15 ± 0.16 to 0.38 ± 0.35 % body weight per day. Food conversion ratio improved with increasing fish size. This relationship was attributed to diet quality and more specifically, the protein : energy ratio. As a result, fish in the large size class had the best overall protein efficiency ratio. Maximum specific growth rates of1.5, 0.84 and 0.74 % body weight per day were recorded from the small, medium and large size classes in the peak of summer with average daily temperature ranging from 21 to 22°C. Positive slopes in the coefficient of variation against fish size in the large size class indicated the presence of competitive behaviour which was attributed to the onset of adolescence. The information from this study can be used for pilot production of spotted grunter. Further research should be undertaken to investigate captive reproduction of the species.
- Full Text:
- Date Issued: 1999
Structures and thermal behaviour of some monooxalato and dioxalato metal complexes
- Authors: Bacsa, John
- Date: 1996
- Subjects: Oxalates -- Research , Crystallography -- Research , Chemistry, Inorganic -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4351 , http://hdl.handle.net/10962/d1005016 , Oxalates -- Research , Crystallography -- Research , Chemistry, Inorganic -- Research
- Description: The crystal structure of Ba [Cu(C₂0₄)₂(H₂O)].5H₂O has been determined using single crystal X-ray diffractometry. It crystallises in the triclinic system, space group Pī , with a = 6.539(2) Å, b = 9.211(3) Å, c = 10.928(3) Å, a = 85.42(3)°, β = 79.22(3)° , γ = 80.30(3)°, V = 636.08(8)ų and Z = 2. The structure consists of [Cu(C₂0₄)₂(H₂O)]²⁻ ions weakly bridged by barium ions and water molecules. The copper(II) ions are in a tetragonally elongated square-pyramidal environment with some trigonal distortion. The two oxalate groups occupy the equatorial positions and a water molecule occupies the axial position. The barium ion is surrounded by nine oxygens: five oxygens from water molecules and four oxygens from oxalate groups. The thermal behaviour of Ba [Cu(C₂0₄)₂(H₂O)].5H₂0 in N₂ has been examined using thermogravimetry (TG) and differential scanning calorimetry (DSC). The dehydration starts at relatively low temperatures (~80°C), but continues until the onset of the decomposition (~280°C). The decomposition takes place in two major stages. The mass of the intermediate after the first stage corresponded to the formation of barium oxalate and copper metal and, after the second stage, to the formation of barium carbonate and copper metal. The enthalpy for the dehydration was found to be 311 ±30 kJ mol⁻¹. The overall enthalpy change for the decomposition of Ba[Cu(C₂0₄)₂]in N₂ was estimated from the combined area of the peaks of the DSC curve as -347 kJ mol⁻¹. The kinetics of the thermal dehydration and decomposition were studied using isothermal TG. The dehydration was strongly deceleratory and the α-time curves could be described by the three-dimensional diffusion (D3) model. The values of the activation energy and the pre-exponential factor for the dehydration were 125 ±4 kJ mol⁻¹ and (1.38 ±0.08)x10¹⁵ min⁻¹, respectively. The decomposition was complex, consisting of at least two concurrent processes. The decomposition was analysed in terms of two overlapping deceleratory processes. One process was fast and could be described by the contracting-geometry model with n = 5. The other process was slow and could also be described by the contracting-geometry model , but with n = 2. The values of Eₐ and A were 206 ±23 kJ mol⁻¹ and (2.2 ±O.5)xl0¹⁹min⁻¹, respectively, for the fast process, and 259 ±37 kJ mol⁻¹ and (6.3 ±1.8)x10²³min⁻¹, respectively, for the slow process.The crystal structure of zinc oxalate dihydrate ([Zn(C₂0₄)(H₂O)₂]n) has also been determined by X-ray diffraction methods. It crystallises in the monoclinic system, space group C2/c with a = 11.786(2) Å, b = 5.397(1)Å, c = 9.712(1) Å, B = 126.19(5)°, V = 498.58(8)ų, Z = 4 and R = 0.037 for 435 absorption-corrected independent reflections and 50 parameters. The asymmetric unit consists of half the monomeric unit [Zn(C₂0₄)(H₂O)₂). The structure consists of infinite, linear chains of zinc ions bridged by oxalate groups. The geometry of the coordination polyhedron surrounding the zinc ion is octahedral, with the oxalate oxygens occupying the equatorial positions and water molecules occupying the axial positions.
- Full Text:
- Date Issued: 1996
- Authors: Bacsa, John
- Date: 1996
- Subjects: Oxalates -- Research , Crystallography -- Research , Chemistry, Inorganic -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4351 , http://hdl.handle.net/10962/d1005016 , Oxalates -- Research , Crystallography -- Research , Chemistry, Inorganic -- Research
- Description: The crystal structure of Ba [Cu(C₂0₄)₂(H₂O)].5H₂O has been determined using single crystal X-ray diffractometry. It crystallises in the triclinic system, space group Pī , with a = 6.539(2) Å, b = 9.211(3) Å, c = 10.928(3) Å, a = 85.42(3)°, β = 79.22(3)° , γ = 80.30(3)°, V = 636.08(8)ų and Z = 2. The structure consists of [Cu(C₂0₄)₂(H₂O)]²⁻ ions weakly bridged by barium ions and water molecules. The copper(II) ions are in a tetragonally elongated square-pyramidal environment with some trigonal distortion. The two oxalate groups occupy the equatorial positions and a water molecule occupies the axial position. The barium ion is surrounded by nine oxygens: five oxygens from water molecules and four oxygens from oxalate groups. The thermal behaviour of Ba [Cu(C₂0₄)₂(H₂O)].5H₂0 in N₂ has been examined using thermogravimetry (TG) and differential scanning calorimetry (DSC). The dehydration starts at relatively low temperatures (~80°C), but continues until the onset of the decomposition (~280°C). The decomposition takes place in two major stages. The mass of the intermediate after the first stage corresponded to the formation of barium oxalate and copper metal and, after the second stage, to the formation of barium carbonate and copper metal. The enthalpy for the dehydration was found to be 311 ±30 kJ mol⁻¹. The overall enthalpy change for the decomposition of Ba[Cu(C₂0₄)₂]in N₂ was estimated from the combined area of the peaks of the DSC curve as -347 kJ mol⁻¹. The kinetics of the thermal dehydration and decomposition were studied using isothermal TG. The dehydration was strongly deceleratory and the α-time curves could be described by the three-dimensional diffusion (D3) model. The values of the activation energy and the pre-exponential factor for the dehydration were 125 ±4 kJ mol⁻¹ and (1.38 ±0.08)x10¹⁵ min⁻¹, respectively. The decomposition was complex, consisting of at least two concurrent processes. The decomposition was analysed in terms of two overlapping deceleratory processes. One process was fast and could be described by the contracting-geometry model with n = 5. The other process was slow and could also be described by the contracting-geometry model , but with n = 2. The values of Eₐ and A were 206 ±23 kJ mol⁻¹ and (2.2 ±O.5)xl0¹⁹min⁻¹, respectively, for the fast process, and 259 ±37 kJ mol⁻¹ and (6.3 ±1.8)x10²³min⁻¹, respectively, for the slow process.The crystal structure of zinc oxalate dihydrate ([Zn(C₂0₄)(H₂O)₂]n) has also been determined by X-ray diffraction methods. It crystallises in the monoclinic system, space group C2/c with a = 11.786(2) Å, b = 5.397(1)Å, c = 9.712(1) Å, B = 126.19(5)°, V = 498.58(8)ų, Z = 4 and R = 0.037 for 435 absorption-corrected independent reflections and 50 parameters. The asymmetric unit consists of half the monomeric unit [Zn(C₂0₄)(H₂O)₂). The structure consists of infinite, linear chains of zinc ions bridged by oxalate groups. The geometry of the coordination polyhedron surrounding the zinc ion is octahedral, with the oxalate oxygens occupying the equatorial positions and water molecules occupying the axial positions.
- Full Text:
- Date Issued: 1996
The precambrian iron-formations in the Limpopo belt as represented by the magnetite quartzite deposits at Moonlight, Koedoesrand area, Northern Transvaal
- Authors: Badenhorst, Jaco Cornelis
- Date: 1991 , 2013-02-20
- Subjects: Iron ores -- Geology -- South Africa , Quartzite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5064 , http://hdl.handle.net/10962/d1013309
- Description: This dissertation is based largely on data that was accumulated during the execution of an exploration program by Iscor Ltd in the Northern Transvaal. The program included geological mapping, geophysical surveys and drilling, on Precambrian iron-formations in the Central Zone of the Limpopo Belt. The structure, stratigraphy, metamorphism, and economic importance of the magnetite quartzites and associated lithologies of the Moonlight prospect are discussed. The lithologies underlying the Moonlight prospect area consist of various pink- and grey-banded gneisses and pink granulite, together with a variety of metasedimentary supracrustal rock-types and concordant serpentinite bodies. The gneissic rock-types consist of chlorite-quartz-feldspar gneiss, chlorite-quartz-feldspar augen gneiss, hornblende-quartz-feldspar gneiss, biotite-quartz-feldspar gneiss, felsic and mafic granulite, and foliated amphibolite. The metasedimentary lithologies are represented by calc-silicates and marble, white quartz-feldspar granulite, magnetite quartzite, metaquartzite and garnet-bearing granulite and gneiss (metapelites). The concordant ultramafic bodies consist of serpentinite with lesser amphibolite, dunite, and chromitite. Intrusive pegmatites and diabase dykes are also present in the prospect area. Metamorphism reached granulite-facies, and more than one retrqgrade metamorphic event is recognized . Amphibolite-facies assemblages are present, but it is uncertain whether they represent another retrograde event . Polyphase deformation has produced intense and complex folding , resulting in irregular magnetite quartzite orebodies. The high metamorphic grades have resulted in medium- grained recrystallization of the magnetite-quartzites with a loss of prominent banding often associated with these rock-types . The magnetite quartzite occurs as three seperate but related ore zones, consisting of one or more ore-bands seperated by other lithologies. All three zones form poor outcrops and suboutcrops in a generally flat lying and sand covered area. · Although representing a low-grade iron ore (32% total Fe), the magnetite quartzite deposits at Moonlight are regarded as potentially viable due to the large opencast tonnages available at low stripping ratios, and the relatively cheap and easy beneficiation process needed to produce a magnetite concentrate with 69-70% total Fe.
- Full Text:
- Date Issued: 1991
- Authors: Badenhorst, Jaco Cornelis
- Date: 1991 , 2013-02-20
- Subjects: Iron ores -- Geology -- South Africa , Quartzite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5064 , http://hdl.handle.net/10962/d1013309
- Description: This dissertation is based largely on data that was accumulated during the execution of an exploration program by Iscor Ltd in the Northern Transvaal. The program included geological mapping, geophysical surveys and drilling, on Precambrian iron-formations in the Central Zone of the Limpopo Belt. The structure, stratigraphy, metamorphism, and economic importance of the magnetite quartzites and associated lithologies of the Moonlight prospect are discussed. The lithologies underlying the Moonlight prospect area consist of various pink- and grey-banded gneisses and pink granulite, together with a variety of metasedimentary supracrustal rock-types and concordant serpentinite bodies. The gneissic rock-types consist of chlorite-quartz-feldspar gneiss, chlorite-quartz-feldspar augen gneiss, hornblende-quartz-feldspar gneiss, biotite-quartz-feldspar gneiss, felsic and mafic granulite, and foliated amphibolite. The metasedimentary lithologies are represented by calc-silicates and marble, white quartz-feldspar granulite, magnetite quartzite, metaquartzite and garnet-bearing granulite and gneiss (metapelites). The concordant ultramafic bodies consist of serpentinite with lesser amphibolite, dunite, and chromitite. Intrusive pegmatites and diabase dykes are also present in the prospect area. Metamorphism reached granulite-facies, and more than one retrqgrade metamorphic event is recognized . Amphibolite-facies assemblages are present, but it is uncertain whether they represent another retrograde event . Polyphase deformation has produced intense and complex folding , resulting in irregular magnetite quartzite orebodies. The high metamorphic grades have resulted in medium- grained recrystallization of the magnetite-quartzites with a loss of prominent banding often associated with these rock-types . The magnetite quartzite occurs as three seperate but related ore zones, consisting of one or more ore-bands seperated by other lithologies. All three zones form poor outcrops and suboutcrops in a generally flat lying and sand covered area. · Although representing a low-grade iron ore (32% total Fe), the magnetite quartzite deposits at Moonlight are regarded as potentially viable due to the large opencast tonnages available at low stripping ratios, and the relatively cheap and easy beneficiation process needed to produce a magnetite concentrate with 69-70% total Fe.
- Full Text:
- Date Issued: 1991
Regolith mapping and gold geochemical anomalies in the Siguiri Gold Mine of AngloGold Ashanti, Guinea, West Africa
- Authors: Bah, Boubacar
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
- Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
- Full Text:
- Date Issued: 2015
- Authors: Bah, Boubacar
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
- Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
- Full Text:
- Date Issued: 2015
The use of thermal modelling in improving rural subsistence aquaculture
- Authors: Bailey, Dylan Francis
- Date: 2007
- Subjects: Sustainable aquaculture -- South Africa , Aquaculture industry -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10715 , http://hdl.handle.net/10948/473 , Sustainable aquaculture -- South Africa , Aquaculture industry -- South Africa
- Description: There has been a long history of attempts to promote subsistence rural aquaculture within South Africa. Many of these attempts have failed due to inadequate support from government and support agencies. There has been a recent revived interest in promoting rural aquaculture development. Presented in this project are six scenarios demonstrating the potential application of thermal modelling techniques to improving subsistence rural aquaculture. These scenarios were based on a model validated against a real life system, and run with environmental data for the year 2005. Bovine manure, grass thatch, cereal straw and Typha spp. water reeds were tested for thermal performance. These results were then applied to the scenarios. The open and kraal enclosed pond scenarios yielded the widest deviation in temperatures throughout the year, with an average temperature of 3.8oC and 6.0oC above ambient and a temperature range of 10.6oC and 12.4oC for the year respectively. Eliminating solar radiation and reducing wind speed resulted in an average difference of 1.5oC below ambient and a temperature range of 7.5oC for the year. When completely enclosed in a well-sealed traditional Xhosa style hut, the pond had an average difference of 5.6oC below outside ambient temperature, with a range of 7.8oC for the year. A passive solar heating scenario added to the sealed hut scenario, which when run continuously maintained an average difference of 34.7oC above outside ambient temperatures, with a range of 56oC for the year. When a hypothetical 25oC temperature control was included in the model, the system maintained an average of 7.1oC above ambient outside temperatures, with a temperature range of 0.8oC throughout the year. The wider range of temperatures made available through the use of thermal modelling approaches provides a more diverse range of species available for subsistence rural aquaculture at any site, significantly improving its potential.
- Full Text:
- Date Issued: 2007
- Authors: Bailey, Dylan Francis
- Date: 2007
- Subjects: Sustainable aquaculture -- South Africa , Aquaculture industry -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10715 , http://hdl.handle.net/10948/473 , Sustainable aquaculture -- South Africa , Aquaculture industry -- South Africa
- Description: There has been a long history of attempts to promote subsistence rural aquaculture within South Africa. Many of these attempts have failed due to inadequate support from government and support agencies. There has been a recent revived interest in promoting rural aquaculture development. Presented in this project are six scenarios demonstrating the potential application of thermal modelling techniques to improving subsistence rural aquaculture. These scenarios were based on a model validated against a real life system, and run with environmental data for the year 2005. Bovine manure, grass thatch, cereal straw and Typha spp. water reeds were tested for thermal performance. These results were then applied to the scenarios. The open and kraal enclosed pond scenarios yielded the widest deviation in temperatures throughout the year, with an average temperature of 3.8oC and 6.0oC above ambient and a temperature range of 10.6oC and 12.4oC for the year respectively. Eliminating solar radiation and reducing wind speed resulted in an average difference of 1.5oC below ambient and a temperature range of 7.5oC for the year. When completely enclosed in a well-sealed traditional Xhosa style hut, the pond had an average difference of 5.6oC below outside ambient temperature, with a range of 7.8oC for the year. A passive solar heating scenario added to the sealed hut scenario, which when run continuously maintained an average difference of 34.7oC above outside ambient temperatures, with a range of 56oC for the year. When a hypothetical 25oC temperature control was included in the model, the system maintained an average of 7.1oC above ambient outside temperatures, with a temperature range of 0.8oC throughout the year. The wider range of temperatures made available through the use of thermal modelling approaches provides a more diverse range of species available for subsistence rural aquaculture at any site, significantly improving its potential.
- Full Text:
- Date Issued: 2007
The influence of artificial light on the foraging efficiency and diet of insect eating bats
- Authors: Bailey, Lauren
- Date: 2019
- Subjects: Predation (Biology) , Bats -- Effect of light on , Bats -- Nutrition , Moths
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76376 , vital:30555
- Description: Artificial light may be altering the interactions between bats and moth prey. Unable to make use of bat evasion strategies around artificial light, eared moths are susceptible to exploitation by syntonic bats (using echolocation frequencies between 20-50 kHz within the hearing range of eared moths). Using a handheld plasma metabolite analyzer, I evaluated the foraging success of syntonic bats and rarer allotonic bats (using echolocation frequencies outside the hearing range of eared moths), in areas with artificial light and in areas of natural darkness. I used microscope diet analysis to determine whether bats were consuming more or fewer moths in areas with artificial light and in areas of natural darkness. Syntonic bats were more selective for moth prey under lit conditions, likely owing to a reduction in the ability of tympanate moths to evade bats. Moths increased in the diets of generalist syntonic bats (Pipistrellus hesperidus) foraging around artificial light sources. Some P. hesperidus individuals showed high β-hydroxybutyrate levels around lights, but there was no difference in β-hydroxybutyrate levels between lit and unlit conditions. There is insufficient evidence to reject the null hypothesis that the foraging success of syntonic bats is equivalent in lit vs unlit conditions. The foraging success and diets of allotonic bats, Rhinolophus capensis, appear to be negligibly impacted by artificial light on a small scale. My study emphasizes the need for a mechanistic understanding of the influence of artificial light on the foraging success of bat species. Bat-moth interactions may be influenced by other factors apart from the common assumption that increased refuelling rates will occur in syntonic species foraging on moths around artificial light.
- Full Text:
- Date Issued: 2019
- Authors: Bailey, Lauren
- Date: 2019
- Subjects: Predation (Biology) , Bats -- Effect of light on , Bats -- Nutrition , Moths
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76376 , vital:30555
- Description: Artificial light may be altering the interactions between bats and moth prey. Unable to make use of bat evasion strategies around artificial light, eared moths are susceptible to exploitation by syntonic bats (using echolocation frequencies between 20-50 kHz within the hearing range of eared moths). Using a handheld plasma metabolite analyzer, I evaluated the foraging success of syntonic bats and rarer allotonic bats (using echolocation frequencies outside the hearing range of eared moths), in areas with artificial light and in areas of natural darkness. I used microscope diet analysis to determine whether bats were consuming more or fewer moths in areas with artificial light and in areas of natural darkness. Syntonic bats were more selective for moth prey under lit conditions, likely owing to a reduction in the ability of tympanate moths to evade bats. Moths increased in the diets of generalist syntonic bats (Pipistrellus hesperidus) foraging around artificial light sources. Some P. hesperidus individuals showed high β-hydroxybutyrate levels around lights, but there was no difference in β-hydroxybutyrate levels between lit and unlit conditions. There is insufficient evidence to reject the null hypothesis that the foraging success of syntonic bats is equivalent in lit vs unlit conditions. The foraging success and diets of allotonic bats, Rhinolophus capensis, appear to be negligibly impacted by artificial light on a small scale. My study emphasizes the need for a mechanistic understanding of the influence of artificial light on the foraging success of bat species. Bat-moth interactions may be influenced by other factors apart from the common assumption that increased refuelling rates will occur in syntonic species foraging on moths around artificial light.
- Full Text:
- Date Issued: 2019