Presidential Address
- Date: 1996-01
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32365 , vital:32027 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 1996-01
- Date: 1996-01
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32365 , vital:32027 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 1996-01
Alkaline rocks in the Kuboos-Bremen Igneous Province, southern Namibia: the Grootpenseiland and Marinkas Kwela Complexes
- Smithies, Robert H, Marsh, Julian S
- Authors: Smithies, Robert H , Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145838 , vital:38471
- Description: The early Cambrian Kuboos-Bremen Igneous Province of northwestern South Africa and southern Namibia comprises a series of intrusive bodies that collectively encompass virtually the entire range of alkaline rock types. Two of these bodies, the Grootpenseiland and Marinkas Kwela Complexes lie immediately north of the Orange River and are amongst the few that show this wide lithological range on a local scale.
- Full Text:
- Date Issued: 1996
- Authors: Smithies, Robert H , Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145838 , vital:38471
- Description: The early Cambrian Kuboos-Bremen Igneous Province of northwestern South Africa and southern Namibia comprises a series of intrusive bodies that collectively encompass virtually the entire range of alkaline rock types. Two of these bodies, the Grootpenseiland and Marinkas Kwela Complexes lie immediately north of the Orange River and are amongst the few that show this wide lithological range on a local scale.
- Full Text:
- Date Issued: 1996
Cyclic voltammetry and spectroelectrochemistry of osmium phthalocyanines in aqueous and non-aqueous solvents
- Sekota, Mantoa, Nyokong, Tebello
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293358 , vital:57078 , xlink:href="https://doi.org/10.1016/0277-5387(95)00581-1"
- Description: Cyclic voltammetry of osmium phthalocyanine complexes, [(CN)2OsIIPc]2− and (py)2OSIIPc (PC = phthalocyanine dianion), show two oxidation couples and two reduction couples in acetonitrile and dimethy1formamide. Oxidation and reduction in these complexes occur at the ring to form cation and anion radical species, respectively. The [(CN)2OsIIPC]2− complexes show a remarkable ease of ring oxidation with oxidation potentials that are much lower than is typical for metallophthalocyanines. Half-wave potentials of 0.25 and 0.67 V (versus saturated calomel electrode, SCE) were obtained for the first and second ring oxidations, respectively. The [(CN)2OSIIPc]2− complex is soluble in water at pHs greater than 4. This complex shows one oxidation couple in pH 9 buffer at −0.11 V versus SCE.
- Full Text:
- Date Issued: 1996
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293358 , vital:57078 , xlink:href="https://doi.org/10.1016/0277-5387(95)00581-1"
- Description: Cyclic voltammetry of osmium phthalocyanine complexes, [(CN)2OsIIPc]2− and (py)2OSIIPc (PC = phthalocyanine dianion), show two oxidation couples and two reduction couples in acetonitrile and dimethy1formamide. Oxidation and reduction in these complexes occur at the ring to form cation and anion radical species, respectively. The [(CN)2OsIIPC]2− complexes show a remarkable ease of ring oxidation with oxidation potentials that are much lower than is typical for metallophthalocyanines. Half-wave potentials of 0.25 and 0.67 V (versus saturated calomel electrode, SCE) were obtained for the first and second ring oxidations, respectively. The [(CN)2OSIIPc]2− complex is soluble in water at pHs greater than 4. This complex shows one oxidation couple in pH 9 buffer at −0.11 V versus SCE.
- Full Text:
- Date Issued: 1996
Electrocatalytic oxidation of cysteine by molybdenum (V) phthalocyanine complexes
- Mafatle, Tsukutlane J, Nyokong, Tebello
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293369 , vital:57079 , xlink:href="https://doi.org/10.1016/0022-0728(95)04519-8"
- Description: Chemically modified electrodes, constructed by incorporating oxomolybdenum(V) phthalocyanine (OMo(V)(OH)Pc, Pc = phthalocyanine dianion) into graphite powder were used to catalyse the oxidation of cysteine. Solution catalysis of cysteine by oxomolybdenum(V) tetrasulfophthalocyanine, [OMo(V)(OH)TSPc]4−, was also investigated. A considerable reduction in overpotential for cysteine oxidation was observed. Cysteine oxidation occurred at 0.26 and 0.28 V vs. Ag/vbAgCl for catalysis by Omo(V)(OH)Pc and [OMo(V)(OH)TSPc]4− respectively as opposed to 0.77 V vs. Ag/vbAgCl observed on CoPc chemically modified electrodes. The anodic peak currents vary linearly with cysteine concentration in the range 0.02 to 0.08 mol dm−3 and 0.008 to 0.02 mol dm−3 for [OMo(V)(OH)TSPc]4− and OMo(V)Pc respectively.
- Full Text:
- Date Issued: 1996
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293369 , vital:57079 , xlink:href="https://doi.org/10.1016/0022-0728(95)04519-8"
- Description: Chemically modified electrodes, constructed by incorporating oxomolybdenum(V) phthalocyanine (OMo(V)(OH)Pc, Pc = phthalocyanine dianion) into graphite powder were used to catalyse the oxidation of cysteine. Solution catalysis of cysteine by oxomolybdenum(V) tetrasulfophthalocyanine, [OMo(V)(OH)TSPc]4−, was also investigated. A considerable reduction in overpotential for cysteine oxidation was observed. Cysteine oxidation occurred at 0.26 and 0.28 V vs. Ag/vbAgCl for catalysis by Omo(V)(OH)Pc and [OMo(V)(OH)TSPc]4− respectively as opposed to 0.77 V vs. Ag/vbAgCl observed on CoPc chemically modified electrodes. The anodic peak currents vary linearly with cysteine concentration in the range 0.02 to 0.08 mol dm−3 and 0.008 to 0.02 mol dm−3 for [OMo(V)(OH)TSPc]4− and OMo(V)Pc respectively.
- Full Text:
- Date Issued: 1996
Geochemical stratigraphy of the Mohale Dame-Katse Dam areas, Lesotho. Report on contract LHDA, Mohale Tunnel: Sampling and Testing of Cores. Lesotho Highlands Tunnel Partnership (Mohale)
- Authors: Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144857 , vital:38385
- Description: In monotonous basalt sequences, such as the Karoo basalt sequence in Lesotho, geochemistry can be a useful adjunct to stratigraphic studies. The acceptance of geochemical criteria in defining stratigraphic units arises from work in the Columbia River Group in NW SA (Swanson et al., 1979) and is now widely employed. It has recently been successfully applied in the Karoo basalts (Marsh et al., in press). In the current investigation a stratigraphic framework for construction work related to the Katse-Mohale tunnel has been developed using the compositions of basalt samples collected from a number of borehole cores in relation to the geochemical stratigraphy of Marshet al. (in press).
- Full Text:
- Date Issued: 1996
- Authors: Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144857 , vital:38385
- Description: In monotonous basalt sequences, such as the Karoo basalt sequence in Lesotho, geochemistry can be a useful adjunct to stratigraphic studies. The acceptance of geochemical criteria in defining stratigraphic units arises from work in the Columbia River Group in NW SA (Swanson et al., 1979) and is now widely employed. It has recently been successfully applied in the Karoo basalts (Marsh et al., in press). In the current investigation a stratigraphic framework for construction work related to the Katse-Mohale tunnel has been developed using the compositions of basalt samples collected from a number of borehole cores in relation to the geochemical stratigraphy of Marshet al. (in press).
- Full Text:
- Date Issued: 1996
Geology Field Trip Guide: Natural Sciences and Geography Educators visit
- Authors: Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144878 , vital:38387
- Description: This is a brief guide to some of the interesting geological features in the immediate vicinity of Grahamstown. It summarises the geological history of the area, emphasizes that small-scale geological features are frequently part of much larger features, demonstrates how careful observation of rocks can lead to solving geological problems and reconstruction of ancient environments in which rocks formed, the importance to society, and how rocks in the Grahamstown area have contributed to a global scale understanding of the dynamic nature of planet Earth.
- Full Text:
- Date Issued: 1996
- Authors: Marsh, Julian S
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144878 , vital:38387
- Description: This is a brief guide to some of the interesting geological features in the immediate vicinity of Grahamstown. It summarises the geological history of the area, emphasizes that small-scale geological features are frequently part of much larger features, demonstrates how careful observation of rocks can lead to solving geological problems and reconstruction of ancient environments in which rocks formed, the importance to society, and how rocks in the Grahamstown area have contributed to a global scale understanding of the dynamic nature of planet Earth.
- Full Text:
- Date Issued: 1996
George Webb Hardy's the Black Peril and the social meaning of ‘Black Peril’ in early twentieth-century South Africa
- Authors: Cornwell, Gareth D N
- Date: 1996
- Language: English
- Type: text , article
- Identifier: vital:6116 , http://hdl.handle.net/10962/d1004240 , https://doi.org/10.1080/03057079608708504
- Description: preprint , The 'Black Peril' — the threatened rape of white women by black men — was an important factor in the moral economy underpinning colonial debate about the 'Native Question' in early twentieth-century South Africa. This essay gives sympathetic consideration to studies which have attempted to link the recurrence of Black Peril panics with specific disturbances in the economy or body politic, before offering symptomatic readings of two pieces of writing by George Webb Hardy, the article 'The Black Peril' (1904) and the novel The Black Peril (1912). These readings suggest that the rape threat was essentially a rationalization of white men's fear of sexual competition from black men. The imagery of purity and contagion, in terms of which the 'endogamous imperative' is typically represented in such texts, suggests that the idea of caste may usefully be invoked in attempts to explain the seemingly irrational public hysteria surrounding the Black Peril phenomenon.
- Full Text:
- Date Issued: 1996
- Authors: Cornwell, Gareth D N
- Date: 1996
- Language: English
- Type: text , article
- Identifier: vital:6116 , http://hdl.handle.net/10962/d1004240 , https://doi.org/10.1080/03057079608708504
- Description: preprint , The 'Black Peril' — the threatened rape of white women by black men — was an important factor in the moral economy underpinning colonial debate about the 'Native Question' in early twentieth-century South Africa. This essay gives sympathetic consideration to studies which have attempted to link the recurrence of Black Peril panics with specific disturbances in the economy or body politic, before offering symptomatic readings of two pieces of writing by George Webb Hardy, the article 'The Black Peril' (1904) and the novel The Black Peril (1912). These readings suggest that the rape threat was essentially a rationalization of white men's fear of sexual competition from black men. The imagery of purity and contagion, in terms of which the 'endogamous imperative' is typically represented in such texts, suggests that the idea of caste may usefully be invoked in attempts to explain the seemingly irrational public hysteria surrounding the Black Peril phenomenon.
- Full Text:
- Date Issued: 1996
Karoo and Etendeks flood basalt provinces, southern Africa and the tectonic development of their adjacent margins:
- Marsh, Julian S, Watkeys, M K
- Authors: Marsh, Julian S , Watkeys, M K
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144868 , vital:38386
- Description: Southern Africa hosts remnants of two continental flood basalt provinces emplaced in association with fragmentation of Gondwana. The earliest is the 183 Ma Karoo Province whose relationship to continental breakup and sea floor spreading is complex. Geochemical stratigraphy, Ar-Ar Dating and palaeomagnetism indicate that Karoo mafic igneous rocks throughout Southern Africa were emplaced over a very short interval at 183 Ma.
- Full Text:
- Date Issued: 1996
- Authors: Marsh, Julian S , Watkeys, M K
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144868 , vital:38386
- Description: Southern Africa hosts remnants of two continental flood basalt provinces emplaced in association with fragmentation of Gondwana. The earliest is the 183 Ma Karoo Province whose relationship to continental breakup and sea floor spreading is complex. Geochemical stratigraphy, Ar-Ar Dating and palaeomagnetism indicate that Karoo mafic igneous rocks throughout Southern Africa were emplaced over a very short interval at 183 Ma.
- Full Text:
- Date Issued: 1996
Marine algal remains from the Upper Devonian of South Africa
- Hiller, Norton, Gess, Robert W
- Authors: Hiller, Norton , Gess, Robert W
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/72753 , vital:30107 , https://doi.org/10.1016/0034-6667(95)00062-3
- Description: The remains of what are interpreted to be marine brown algae are described from Late Devonian clastic rocks in South Africa. Dichotomously-branched specimens with rounded terminations are placed in the new species Hungerfordia fionae and the closely related H. dichotoma Fry and Banks is placed in synonymy with Buthotrephis trichotoma Douglas and Jell. A large strap-like form is described as a new species, Yeaia africana.
- Full Text: false
- Date Issued: 1996
- Authors: Hiller, Norton , Gess, Robert W
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/72753 , vital:30107 , https://doi.org/10.1016/0034-6667(95)00062-3
- Description: The remains of what are interpreted to be marine brown algae are described from Late Devonian clastic rocks in South Africa. Dichotomously-branched specimens with rounded terminations are placed in the new species Hungerfordia fionae and the closely related H. dichotoma Fry and Banks is placed in synonymy with Buthotrephis trichotoma Douglas and Jell. A large strap-like form is described as a new species, Yeaia africana.
- Full Text: false
- Date Issued: 1996
Perceptions of affirmative action
- Scott, Judith, Amos, Trevor L, Richard Scott, W
- Authors: Scott, Judith , Amos, Trevor L , Richard Scott, W
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270914 , vital:54491 , xlink:href="https://hdl.handle.net/10520/EJC-67e7bffd2"
- Description: Private and public South African employers have instituted affirmative action policies meant to provide employment opportunities to Black South Africans. A body of literature suggests that because of affirmative action policies Black hopes have been raised while Whites view such policies as having a negative impact on their opportunities. However, no extant literature details an empirical investigation of these suggestions. Therefore, this study focusses on the affirmative action perceptions held by 350 South African university commerce students.
- Full Text:
- Date Issued: 1996
- Authors: Scott, Judith , Amos, Trevor L , Richard Scott, W
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270914 , vital:54491 , xlink:href="https://hdl.handle.net/10520/EJC-67e7bffd2"
- Description: Private and public South African employers have instituted affirmative action policies meant to provide employment opportunities to Black South Africans. A body of literature suggests that because of affirmative action policies Black hopes have been raised while Whites view such policies as having a negative impact on their opportunities. However, no extant literature details an empirical investigation of these suggestions. Therefore, this study focusses on the affirmative action perceptions held by 350 South African university commerce students.
- Full Text:
- Date Issued: 1996
Pharmacokinetics of cyclizine following intravenous administration to human volunteers
- Kanfer, Isadore, Walker, Roderick B
- Authors: Kanfer, Isadore , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184389 , vital:44214 , xlink:href="https://doi.org/10.1016/0928-0987(96)00177-7"
- Description: The pharmacokinetics of cyclizine, a piperazine derivative useful in the prevention and treatment of nausea and vomiting, was investigated in six healthy male volunteers following an intravenous bolus dose. The drug is extensively distributed with a mean volume of distribution of 16.50 ± 3.33 l/kg and a mean total clearance of 0.870 ± 0.105 l/h per kg. Urinary excretion data showed that less than one percent of the dose was excreted up to 36 h as unchanged drug in the urine. The extremely low mean renal clearance (0.005 ± 0.002 l/h per kg) for the parent drug comprised only a small proportion of total clearance indicating that urinary excretion of parent drug is not a major route of elimination for cyclizine. The drug appears to exhibit biexponential pharmacokinetics and has a terminal elimination half-life of approximately 13 h.
- Full Text:
- Date Issued: 1996
- Authors: Kanfer, Isadore , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184389 , vital:44214 , xlink:href="https://doi.org/10.1016/0928-0987(96)00177-7"
- Description: The pharmacokinetics of cyclizine, a piperazine derivative useful in the prevention and treatment of nausea and vomiting, was investigated in six healthy male volunteers following an intravenous bolus dose. The drug is extensively distributed with a mean volume of distribution of 16.50 ± 3.33 l/kg and a mean total clearance of 0.870 ± 0.105 l/h per kg. Urinary excretion data showed that less than one percent of the dose was excreted up to 36 h as unchanged drug in the urine. The extremely low mean renal clearance (0.005 ± 0.002 l/h per kg) for the parent drug comprised only a small proportion of total clearance indicating that urinary excretion of parent drug is not a major route of elimination for cyclizine. The drug appears to exhibit biexponential pharmacokinetics and has a terminal elimination half-life of approximately 13 h.
- Full Text:
- Date Issued: 1996
Photochemically induced electron transfer between sulfur dioxide and tin (IV) mono-and di-phthalocyanines
- Nensala, Ngudiankama, Nzimande, Ayanda, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
- Full Text:
- Date Issued: 1996
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
- Full Text:
- Date Issued: 1996
Spectroelectrochemical studies of tin (IV) diphthalocyanine
- Nensala, Ngudiankama, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Full Text:
- Date Issued: 1996
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Full Text:
- Date Issued: 1996
Suppositories: An underutilized dosage form
- Webster, Jessica A, Dowse, Roslind, Walker, Roderick B
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
- Full Text:
- Date Issued: 1996
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
- Full Text:
- Date Issued: 1996
New Unity Movement Presidential Address
- Date: 1996-12
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32427 , vital:32103 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 1996-12
- Date: 1996-12
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32427 , vital:32103 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 1996-12
Catalytic behavior of osmium (II), rhodium (III) and ruthenium (II) Phthalocyanines towards the electrooxidation of cysteine on glassy carbon electrodes
- Sekota, Mantoa, Nyokong, Tebello
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293290 , vital:57072 , xlink:href=" https://doi.org/10.1002/elan.1140091608"
- Description: Glassy carbon electrodes (GCE's) modified with phthalocyanine complexes of Rh, Ru and Os are employed for the catalytic oxidation of cysteine. When cyanide and dimethylsulfoxide (DMSO) are used as axial ligands giving (DMSO)(Cl)RhIIIPc, [(CN)2RhIIIPc]−, (DMSO)2OsPcII, and [(DMSO)2Ru(II)Pc]·2DMSO complexes, the peak currents for the oxidation of cysteine increase after each scan, indicating an increase in the catalytic activity of the electrode with repetitive scanning. This improvement in the catalytic activity of the GCE after the first scan is attributed to the formation of dimeric π cation radical species at the electrode surface.
- Full Text:
- Date Issued: 1997
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293290 , vital:57072 , xlink:href=" https://doi.org/10.1002/elan.1140091608"
- Description: Glassy carbon electrodes (GCE's) modified with phthalocyanine complexes of Rh, Ru and Os are employed for the catalytic oxidation of cysteine. When cyanide and dimethylsulfoxide (DMSO) are used as axial ligands giving (DMSO)(Cl)RhIIIPc, [(CN)2RhIIIPc]−, (DMSO)2OsPcII, and [(DMSO)2Ru(II)Pc]·2DMSO complexes, the peak currents for the oxidation of cysteine increase after each scan, indicating an increase in the catalytic activity of the electrode with repetitive scanning. This improvement in the catalytic activity of the GCE after the first scan is attributed to the formation of dimeric π cation radical species at the electrode surface.
- Full Text:
- Date Issued: 1997
First-row transition metal phthalocyanines as catalysts for water electrolysis
- Chebotareva, Natalia, Nyokong, Tebello
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293391 , vital:57081 , xlink:href="https://doi.org/10.1016/S0013-4686(97)00033-9"
- Description: Modification of carbon electrodes with first row transition metal phthalocyanines results in the lowering of the potentials needed for water electrolysis in basic media, by 600 to 700 mV when compared to unmodified carbon electrodes. Nickel(II), cobalt(II) and iron(II) phthalocyanines show higher catalytic activity than zinc(II), manganese(II), copper(II) and metal free phthalocyanines.
- Full Text:
- Date Issued: 1997
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293391 , vital:57081 , xlink:href="https://doi.org/10.1016/S0013-4686(97)00033-9"
- Description: Modification of carbon electrodes with first row transition metal phthalocyanines results in the lowering of the potentials needed for water electrolysis in basic media, by 600 to 700 mV when compared to unmodified carbon electrodes. Nickel(II), cobalt(II) and iron(II) phthalocyanines show higher catalytic activity than zinc(II), manganese(II), copper(II) and metal free phthalocyanines.
- Full Text:
- Date Issued: 1997
Management education and training
- Authors: Amos, Trevor L , Quinn, Lynn
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270902 , vital:54490 , xlink:href="https://hdl.handle.net/10520/AJA10113487_559"
- Description: The paper outlines the role of language in leaming and cognitive development and argues that management education and training needs to be integrated with language development to enable students to cope with the demands made of them at university as well as with those of careers in the business world. An integrated language developmEint project developed by the Depanment of Management and academic language practitioners at Rhodes Uhlvetsity is descriptionbed and suggestions are outlined as to how university Management departments can integrate language development in their mainstream teaching.
- Full Text:
- Date Issued: 1997
- Authors: Amos, Trevor L , Quinn, Lynn
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270902 , vital:54490 , xlink:href="https://hdl.handle.net/10520/AJA10113487_559"
- Description: The paper outlines the role of language in leaming and cognitive development and argues that management education and training needs to be integrated with language development to enable students to cope with the demands made of them at university as well as with those of careers in the business world. An integrated language developmEint project developed by the Depanment of Management and academic language practitioners at Rhodes Uhlvetsity is descriptionbed and suggestions are outlined as to how university Management departments can integrate language development in their mainstream teaching.
- Full Text:
- Date Issued: 1997
Metallophthalocyanine catalysed electroreduction of nitrate and nitrite ions in alkaline media
- Chebotareva, Natalia, Nyokong, Tebello
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293301 , vital:57073 , xlink:href="https://doi.org/10.1023/A:1018466021838"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text: false
- Date Issued: 1997
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293301 , vital:57073 , xlink:href="https://doi.org/10.1023/A:1018466021838"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text: false
- Date Issued: 1997
New placoderm fishes from the Late Devonian of South Africa
- Long, John A, Anderson, M Eric, Gess, Robert W, Hiller, Norton
- Authors: Long, John A , Anderson, M Eric , Gess, Robert W , Hiller, Norton
- Date: 1997
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/72763 , vital:30108 , https://doi.org/10.1080/02724634.1997.10010973
- Description: New placoderm fishes are described from a black shale lens in the Famennian Witpoort Formation, near Grahamstown, South Africa. Arthrodires include a new species of Groenlandaspis, G. riniensis sp. nov., a new genus of groenlandaspidid, Africanaspis doryssa gen. et sp. nov., and a new species of the antiarch Bothriolepis, B. africana sp. nov. This is the first record of the ubiquitous genera Bothriolepis and Groenlandaspis from the African continent. The South African placoderm fauna has demonstrable links with the eastern Gondwana faunas in the close affinity of the Bothriolepis africana with B. barred of Antarctica, and the high diversity of groenlandaspid species, especially the presence of a very high crested form having affinities to Tiaraspis.
- Full Text: false
- Date Issued: 1997
- Authors: Long, John A , Anderson, M Eric , Gess, Robert W , Hiller, Norton
- Date: 1997
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/72763 , vital:30108 , https://doi.org/10.1080/02724634.1997.10010973
- Description: New placoderm fishes are described from a black shale lens in the Famennian Witpoort Formation, near Grahamstown, South Africa. Arthrodires include a new species of Groenlandaspis, G. riniensis sp. nov., a new genus of groenlandaspidid, Africanaspis doryssa gen. et sp. nov., and a new species of the antiarch Bothriolepis, B. africana sp. nov. This is the first record of the ubiquitous genera Bothriolepis and Groenlandaspis from the African continent. The South African placoderm fauna has demonstrable links with the eastern Gondwana faunas in the close affinity of the Bothriolepis africana with B. barred of Antarctica, and the high diversity of groenlandaspid species, especially the presence of a very high crested form having affinities to Tiaraspis.
- Full Text: false
- Date Issued: 1997