A comparative photophysicochemical study of mono substituted phthalocyanines grafted onto silica nanoparticles
- Authors: Fashina, Adebayo , Antunes, Edith M , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193844 , vital:45399 , xlink:href="https://doi.org/10.1142/S1088424614500138"
- Description: In this study, we report on the covalent linking of carboxylic acid functionalized silica nanoparticles with zinc phthalocyanine mono-substituted non-peripherally and peripherally with either a 4-amino phenoxy (1, peripheral and 2, non-peripheral) or an amino group (3 peripheral). The grafting is achieved via the formation of an amide bond between the carboxylic acid of the silica nanoparticles and the amino group of the phthalocyanine complexes. The hybrid nanoparticles retained the amorphous nature of silica nanoparticles after conjugation. A slight decrease in fluorescence and a general improvement in triplet quantum yields compared to free Pcs were observed. Triplet lifetimes for 2-SiNPs and 3-SiNPs also improved when compared to the free phthalocyanine. The changes in singlet oxygen quantum yields upon conjugation were minimal.
- Full Text:
- Date Issued: 2014
A comparative photophysicochemical study of phthalocyanines encapsulated in core–shell silica nanoparticles
- Authors: Fashina, Adedayo , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189708 , vital:44924 , xlink:href="https://doi.org/10.1016/j.saa.2014.08.062"
- Description: This work presents the synthesis and characterization of a new zinc phthalocyanine complex tetrasubstituted with 3-carboxyphenoxy in the peripheral position. The photophysical properties of the new complex are compared with those of phthalocyanines tetra substituted with 3-carboxyphenoxy or 4- carboxyphenoxy at non-peripheral positions. Three phthalocyanine complexes were encapsulated within silica matrix to form a core shell and the hybrid nanoparticles particles obtained were spherical and mono dispersed. When encapsulated within the silica shell nanoparticles, phthalocyanines showed improved triplet quantum yields and singlet oxygen quantum yields than surface grafted derivatives. The improvements observed could be attributed to the protection provided for the phthalocyanine complexes by the silica matrix.
- Full Text:
- Date Issued: 2015
A comparative physicochemical study of unsymmetrical indium phthalocyanines in the presence of magnetic nanoparticles or quantum dots
- Authors: Osifeko, Olawale L , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188743 , vital:44781 , xlink:href="https://doi.org/10.1080/00958972.2016.1152628"
- Description: Asymmetric indium phthalocyanine (3, containing an NH2 group) was conjugated (via an amide bond) to magnetic nanoparticle (MNP) functionalized with carboxylic acid or glutathione-capped CdTe/ZnSe/ZnO quantum dots to form 3-MNPs or 3-QDs. Techniques such as time-resolved fluorescence measurements, transmission electron microscopy, XPS, elemental analysis, FTIR, NMR (1H, 13C, and cozy), electronic spectroscopy, as well as mass spectroscopy were employed to characterize 3 and its nanoconjugates. The phthalocyanine conjugated to quantum dot (3-QDs) possesses the lowest Фpd higher Ф∆ and ФT as well as longer triplet lifetimes compares to 3-MNPs and free phthalocyanine.
- Full Text:
- Date Issued: 2016
A Comparative Study of mLAN and CobraNet Technologies and their use in the Sound Installation Industry
- Authors: Klinkradt, Bradley , Foss, Richard
- Date: 2003
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427331 , vital:72431 , https://www.aes.org/e-lib/browse.cfm?elib=12593
- Description: This paper highlights the two interconnection technologies of CobraNet and mLAN, and provides a comparative study of these technologies and their applicability to the sound installation industry, through a discussion of constraints inherent within such an installation. Issues such as the adherence to standards, costs, latency, speed, connection management, and the control and monitoring of devices are explored.
- Full Text:
- Date Issued: 2003
A comparative study of the dosimetric features of α-Al2O3: C, Mg and α-Al2O3: C
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/113058 , vital:33694 , https://doi.org/10.1093/rpd/ncx039
- Description: A comparative study of the dosimetric features of α-Al2O3:C,Mg and α-Al2O3:C relevant to thermoluminescence dosimetry is reported. A glow curve of α-Al2O3:C,Mg measured at 1°C/s after beta irradiation to 1 Gy shows two subsidiary peaks at 42°C (labelled as I) and 72°C (II) and the main peak at 161°C (III) whereas a glow curve of α-Al2O3:C measured under the same conditions shows the main peak at 178°C (II′) and a lower intensity peak at 48°C (I′). Apart from these ones, there are several other peaks at temperatures beyond that of the main peak in both α-Al2O3:C,Mg and α-Al2O3:C. However, the latter are not included in this study. We report a comparative quantitative analysis of dose response and fading of peaks I, II and III of α-Al2O3:C,Mg and peaks I′ and II′ of α-Al2O3:C. Analysis shows that the dose response of peaks I and III is sublinear within 1–10 Gy whereas that of peak II is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy. In comparison, the dose response of peak I′ is superlinear within 1–4 Gy followed by a sublinear region within 4–10 Gy whereas that of peak II′ is sublinear within 1–4 Gy followed by a superlinear region within 4–10 Gy. As regards to fading corresponding to 1 Gy, peak I is very unstable and fades within 300 s, peak II is more stable and takes up to 43200 s to fade. In comparison, peak III fades down to 30% of its initial intensity within 2400 s. Interestingly, between 2400 and 800 s, the intensity fades by 17% only. Regarding fading in α-Al2O3:C, peak I′ fades within 600 s whereas peak II′ shows an inverse fading behaviour up to 64800 s. The rate of fading for peaks I, II and III in α-Al2O3:C,Mg was found to decrease with increase in dose. However, no such behaviour was observed in α-Al2O3:C. The fading in both samples is discussed on the basis of a charge hopping mechanism.
- Full Text:
- Date Issued: 2017
A comparative study of the effect of different stabilizers on the critical quality attributes of self-assembling nano co-crystals
- Authors: Witika, Bwalya A , Smith, Vincent J , Walker, Roderick B
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183224 , vital:43931 , xlink:href=" https://doi.org/10.3390/pharmaceutics12020182"
- Description: Lamivudine (3TC) and zidovudine (AZT) are antiviral agents used orally to manage HIV/AIDS infection. A pseudo one-solvent bottom-up approach was used to develop and produce nano co-crystals of 3TC and AZT. Equimolar amounts of 3TC dissolved in de-ionized water and AZT in methanol were rapidly injected into a pre-cooled vessel and sonicated at 4 °C. The resultant suspensions were characterized using a Zetasizer. The particle size, polydispersity index and Zeta potential were elucidated. Further characterization was undertaken using powder X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry, and energy dispersive X-ray spectroscopy scanning electron microscopy. Different surfactants were assessed for their ability to stabilize the nano co-crystals and for their ability to produce nano co-crystals with specific and desirable critical quality attributes (CQA) including particle size (PS) less than 1000 nm, polydispersity index (PDI) less than 0.500 and Zeta potential (ZP) less than −30 mV. All surfactants produced co-crystals in the nanometer range. The PDI and PS are concentration-dependent for all nano co-crystals manufactured while only ZP was within specification when sodium dodecyl sulfate was used in the process.
- Full Text:
- Date Issued: 2020
A comparative study of the photophysicochemical and photodynamic activity properties of meso-4-methylthiophenyl functionalized Sn (IV) tetraarylporphyrins and triarylcorroles
- Authors: Dingiswayo, Somila , Babu, Balaji , Prinsloo, Earl , Mack, John , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186157 , vital:44469 , xlink:href="https://doi.org/10.1142/S1088424620500273"
- Description: Tin(IV) complexes of a 4-methylthiophenyl functionalized porphyrin (1-Sn) and its corrole analogue (2-Sn) were synthesized so that their photophysicochemical properties and photodynamic activities against MCF-7 breast cancer cells could be compared. Singlet oxygen luminescence studies revealed that 1-Sn and 2-Sn have comparable ΦΔΦΔ values in DMF of 0.59 and 0.60, respectively, while the IC5050 values after irradiation of MCF-7 cells for 30 min with a Thorlabs 625 nm LED (432 J · cm−2)−2) were determined to be 12.4 and 8.9 μμM. The results demonstrate that the cellular uptake of 2-Sn and its molar absorptivity at the irradiation wavelength play a crucial role during in vitro cytotoxicity studies.
- Full Text:
- Date Issued: 2020
A comparative study of the singlet oxygen generation capability of a zinc phthalocyanine linked to graphene quantum dots through π-π stacking and covalent conjugation when embedded in asymmetric polymer membranes
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187461 , vital:44655 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.11.096"
- Description: Following the establishment of graphene quantum dots as potential phthalocyanine supports in photoactive membrane preparation for phthalocyanines lacking linkage functional groups, the practical efficiency of p-p stacking versus covalent linkage was investigated. Synthesized materials were characterized using FT-IR, Raman, powder X-ray diffraction, and UVeVis spectroscopies and also by transmission electron and scanning electron microscopies. Phthalocyanine loadings onto graphene quantum dots of 0.40 mg/mg and 0.14 mg/mg (Pc mass/conjugate mass) for the p-p stacked and covalent linked conjugates respectively were observed. Covalent linkage to graphene quantum dots proved to be functionally superior to p-p linkage, where singlet oxygen quantum yield value of the phthalocyanine in the membrane for the covalent linked conjugate was approximately twice that of the p-p stacked membrane.
- Full Text:
- Date Issued: 2019
A comparative study on the sensitive detection of hydroxyl radical using thiol-capped CdTe and CdTe/ZnS quantum dots
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242778 , vital:51077 , xlink:href="https://doi.org/10.1007/s10895-012-1089-2"
- Description: Four types of water-soluble luminescent quantum dots (QDs) whose surface was functionlaized with thioglycolic acid (TGA), 3-mercaptopropionic acid (MPA), or glutathione (GSH), were investigated for the sensitive and selective detection of hydroxyl radical (●OH) in aqueous media. It was found that the type of capping agent and QD influenced the sensitivity of the probe. The order of sensitivity of the probe was: GSH-CdTe@ZnS > MPA-CdTe@ZnS > TGA-CdTe > MPA-CdTe QDs. Under the optimum conditions, a limit of detection as low as 8.5 × 10-8 M was obtained using GSH-CdTe@ZnS. The effects of foreign reactive oxygen species and the Fenton reactants and products as possible interferences on the proposed probe were negligible for CdTe@ZnS QDs. Besides, experimental results indicated that CdTe@ZnS QDs were more attractive for the selective recognition of ●OH than CdTe QDs. The mechanistic reaction pathway between the QDs and ●OH is proposed.
- Full Text:
- Date Issued: 2012
A comparison of anthropogenic and elephant disturbance on Acacia xanthophloea (fever tree) populations in the Lowveld, South Africa
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181629 , vital:43753 , xlink:href="https://doi.org/10.4102/koedoe.v45i1.10"
- Description: Acacia xanthophloea (the ‘fever tree’) is a popular medicinal species that is traded widely in South Africa. Although it occurs throughout southern Africa, there is increasing pressure on its riverine and marshy habitats. This study compares the impact of harvesting on an A. xanthophloea population located on private land near Komatipoort, Mpumalanga, with two protected populations situated within the Kruger National Park. The densities of the harvested and protected populations were similar (84±8 trees/ha and 85±20 trees/ha, respectively). There were fluctuations in the quotients between frequencies of trees in successive diameter classes, which is common in savanna where high levels of fire, mega-herbivore and anthropogenic disturbance are experienced. The extent of stem damage (stripping of bark and breakage) by elephants in the protected area was significantly higher than the extent of harvesting on private land, although the degree of damage was relatively low, with only 7 % of the populations having been damaged at rates >26 %. The degree of harvesting on private land was relatively low, with the majority of trees having been harvested at rates of less than 10 % of the stem below 2 m. Despite this, ringbarking had occurred (4 %). The basal diameters and heights were significantly lower in the protected population than in the harvested one, suggesting that over time elephant impact was the more severe disturbance. Acacia xanthophloea exhibited high resilience to disturbance, with all the elephant damaged trees and harvested individuals surviving. However, the mean bark thickness measured in local markets (6.3±1.4 mm) was significantly lower than that measured in either the harvested (12.4±1.0 mm) or the KNP (10.3±0.8 mm) populations. As harvesters tend to select the largest individuals in a population to maximise their financial returns, this could mean that smaller individuals are being harvested, and/or bark is not being given sufficient time to grow back after harvesting. Acacia xanthophloea outside protected areas thus need to be monitored and the management improved, preferably in conjunction with the resource users. In addition, traditional healers, those selling medicinal plants and other members of the community need to continue to be encouraged to cultivate this fast growing species.
- Full Text:
- Date Issued: 2002
A Comparison of Four End-User Devices as Thin Clients for Public Access to the Internet in Poor Communities
- Authors: Duff, Kevin , Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430892 , vital:72725 , https://doi.org/10.1007/978-3-319-16886-9_24
- Description: In poor areas, where ICT infrastructure is being deployed with devel-opmental aims, there is a need to provide appropriate, sustainable technologies that meet the needs of the local community. Current trends for ICT interventions favour the use of mobile user equipment, such as tablets and cellphones, but we think that they are inappropriate to allow production as opposed to mainly consumption of digital con-tent, at least for the foreseeable future. Thus our objective is to reduce the cost of deployment of traditional communal Internet Access Points using PCs. In this paper we compare four candidate computers to be used as thin clients in such settings, according to seven different cate-gories. Our study identifies the strengths, weaknesses and problems of each device, and concludes with recommendations for anybody wish-ing to deploy such devices as Linux Terminal Server Project (LTSP) thin clients in a public Internet Access Point.
- Full Text:
- Date Issued: 2015
A comparison of four microcomputer operating systems
- Authors: Wells, George C
- Date: 1993
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430422 , vital:72690 , https://doi.org/10.1007/BF01088835
- Description: This article describes a comparative study of four operating systems for IBM-PC compatible microcomputers. The assessment concentrated on the suitability of the operating systems for use in real-time applications, and on their use as development environments for real-time systems. The study evaluated the predictability and the performance of the operating systems in several areas critical in real-time systems by using comparative benchmarks. In addition, a small-scale simulation of a process control system was developed for each of the systems. The operating systems that were studied were UNIX, OS/2, QNX and FlexOS. These operating systems represent a broad spectrum of systems from general purpose operating systems to small, specialized real-time operating systems. The details of the evaluation process are given and a summary of the results is presented.
- Full Text:
- Date Issued: 1993
A comparison of genetic structure in two low-dispersal crabs from the Wild Coast, South Africa
- Authors: Qhaji, Y , Jansen van Vuuren, Bettine , Papadopoulos, Isabelle , McQuaid, Christopher D , Teske, Peter R
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444770 , vital:74297 , https://doi.org/10.2989/1814232X.2015.1077474
- Description: The Wild Coast in south-eastern South Africa is strongly influenced by the warm, southward-flowing Agulhas Current. This current has a significant impact on dispersal in the coastal biota of the region, and facilitates high levels of connectivity among populations. However, it is not known how the region's high-velocity hydrology affects genetic population structure in endemic estuarine species, populations of which are frequently isolated from the sea. Here, we compared genetic structure in two estuarine crabs of the family Hymenosomatidae. Both are presumed to have low dispersal potential, but they differ in terms of their life histories. Hymenosoma longicrure has abbreviated larval development and can complete its entire life cycle within estuaries, whereas Neorhynchoplax bovis is a direct developer that lacks planktonic larvae.
- Full Text:
- Date Issued: 2015
A comparison of the ichthyofaunas in two permanently open eastern Cape estuaries
- Authors: Whitfield, Alan K , Paterson, Angus W , Bok, Anton H , Kok, H M
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447364 , vital:74618 , https://www.ajol.info/index.php/az/article/view/154297
- Description: The Kowie and Great Fish estuaries are situated less than 30 km apart, yet they differ considerably in terms of riverine inflow, turbidity, food resources and habitat availability. The ichthyofauna of the two estuaries were sampled using plankton, seine and gill nets. A greater ichthyofaunal richness (R) was recorded in the Kowie estuary and this is attributed to the wider range of habitats and greater degree of marine influence in this system. In contrast, all three sampling gears revealed an approximate 3:1 ratio between fish abundance in the Great Fish and Kowie estuaries.
- Full Text:
- Date Issued: 1994
A comparison of the Linux and Windows device driver architectures
- Authors: Tsegaye, Melekam , Foss, Richard
- Date: 2004
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427198 , vital:72421 , https://dl.acm.org/doi/pdf/10.1145/991130.991132
- Description: In this paper the device driver architectures currently used by two of the most popular operating systems, Linux and Microsoft's Windows, are examined. Driver components required when implementing device drivers for each operating system are presented and compared. The process of implementing a driver, for each operating system, that performs I/O to a kernel buffer is also presented. The paper concludes by examining the device driver development environments and facilities provided to developers by each operating system.
- Full Text:
- Date Issued: 2004
A Comparison Of The Resource Requirements Of Snort And Bro In Production Networks
- Authors: Barnett, Richard J , Irwin, Barry V W
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430040 , vital:72661 , https://www.iadisportal.org/applied-computing-2009-proceedings
- Description: Intrusion Detection is essential in modern networking. However, with the increas-ing load on modern networks, the resource requirements of NIDS are significant. This paper explores and compares the requirements of Snort and Bro, and finds that Snort is more efficient at processing network traffic than Bro. It also finds that both systems are capable of analysing current network loads on commodity hardware, but may be unable to do so for higher bandwidth networks. This is ben-eficial in a South African context due to the increasing international bandwidth that will come online with the launch of the SEACOM Cable, and local projects such as SANREN.
- Full Text:
- Date Issued: 2009
A comparison of three models used to determine water fluxes over the Albany Thicket, Eastern Cape, South Africa:
- Authors: Palmer, Anthony R , Ezenne, G I , Choruma, D J , Gwate, O , Mantel, Sukhmani K , Tanner, Jane L
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150047 , vital:38934 , https://doi.org/10.1016/j.agrformet.2020.107984
- Description: The Albany Thicket (AT) biome contains outstanding global biodiversity as well as the potential to achieve carbon credits associated with water-efficient Crasslucean acid metabolism (CAM). Understanding the water fluxes in the AT is crucial to determining carbon (C) sequestration rates and water-use efficiency. Despite large variation in water fluxes across the AT, only a few studies have been conducted in this region with their results validated against short periods of observed data. This study aims to evaluate three models of water fluxes over AT against data from an eddy covariance (EC) system active from October 2015 to May 2018. ET was modelled using the BioGeoChemistry Management (BGC-MAN) model, a biophysical model (Penman-Monteith-Leuning (PML)) and a remotely-sensed product (MOD16), and their results compared with that from the EC system.
- Full Text:
- Date Issued: 2020
A comparison of three techniques for fluorochrome marking of juvenile Clarias gariepinus otoliths
- Authors: Wartenberg, Reece , Booth, Anthony J , Weyl, Olaf L F
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123520 , vital:35450 , https://doi.10.3377/004.046.0119
- Description: African sharptooth catfish, Clarias gariepinus (Burchell 1822), is widely distributed with a natural range that extends from southern Turkey to the Orange River, South Africa (Skelton 2001). In addition to translocations within its southerly range (Cambray 2003), Cambray (2005) noted that as a result of poor aquaculture practices and introductions from a number of unknown sources, C. gariepinus has now invaded South America, Europe, Asia, and Australia. Its life history characteristics include a fast growth rate to a maximum length of 1300mmtotal length (TL) (Bruton 1976), a high fecundity, an omnivorous diet and the ability to breathe air (de Moor & Bruton 1988; Cambray 2003). Understanding the biology and population dynamics of this invader would assist in its management and possibly eradication.
- Full Text:
- Date Issued: 2011
A computer network attack taxonomy and ontology
- Authors: Van Heerden, Renier P , Irwin, Barry V W , Burke, Ivan D , Leenen, Louise
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430064 , vital:72663 , DOI: 10.4018/ijcwt.2012070102
- Description: Computer network attacks differ in the motivation of the entity behind the attack, the execution and the end result. The diversity of attacks has the consequence that no standard classification ex-ists. The benefit of automated classification of attacks, means that an attack could be mitigated accordingly. The authors extend a previous, initial taxonomy of computer network attacks which forms the basis of a proposed network attack ontology in this pa-per. The objective of this ontology is to automate the classifica-tion of a network attack during its early stages. Most published taxonomies present an attack from either the attacker's or defend-er's point of view. The authors' taxonomy presents both these points of view. The framework for an ontology was developed using a core class, the "Attack Scenario", which can be used to characterize and classify computer network attacks.
- Full Text:
- Date Issued: 2012
A conceptually relevant and practically sophisticated journalism syllabus for Africa
- Authors: Banda, Fackson
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454547 , vital:75354 , https://hdl.handle.net/10520/EJC139370
- Description: Over 35 African journalism educators gathered in Grahamstown, South Africa in September last year, at the invitation of the SAB Ltd-Unesco Chair of Media and Democracy, to present and discuss initial research papers aimed at defining a common vision of journalism education on the African continent. The meeting was held against the backdrop of the bid by Rhodes University, under the auspices of the School of Journalism and Media Studies, to host the 2nd World Journalism Education Congress (WJEC).
- Full Text:
- Date Issued: 2010