- Title
- Cu (III) triarylcorroles with asymmetric push–pull meso-substitutions
- Creator
- Liang, Xu, Niu, Yingjie, Zhang, Ojanchong, Mack, John, Yi, Xiaoyi, Hlatshwayo, Zweli, Li, Minzhi, Zhu, Weihua, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2017
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/232947
- Identifier
- vital:50040
- Identifier
- xlink:href="https://doi.org/10.1039/C7DT00716G"
- Description
- The synthesis of four low symmetry A2B type Cu (III)triarylcorroles with meso-aryl substituents that provide electron donating (push) and withdrawing (pull) properties is reported, along with their structural characterization by NMR spectroscopy and X-ray crystallography. An analysis of the structure–property relationships in the optical and redox properties has been carried out by comparing their optical spectroscopy, electrochemistry, and spectroelectrochemistry to trends predicted in DFT and TD-DFT calculations. The results demonstrate that A2B type Cu(III)triarylcorroles are highly efficient catalysts for electrocatalyzed hydrogen evolution reactions (HERs) and that their reactivity can be modulated by changing the nature of the B-position meso-substituent.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- Royal Society of Chemistry
- Language
- English
- Relation
- Dalton Transactions, Liang, X., Niu, Y., Zhang, Q., Mack, J., Yi, X., Hlatshwayo, Z., Nyokong, T., Li, M. and Zhu, W., 2017. Cu (III) triarylcorroles with asymmetric push–pull meso-substitutions: tunable molecular electrochemically catalyzed hydrogen evolution. Dalton Transactions, 46(21), pp.6912-6920, Dalton Transactions volume 46 number 21 p. 6912 2017 1477-9234
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Royal Society of Chemistry Terms and Conditions Statement (https://0-www.rsc.org.wam.seals.ac.za/help-legal/)
- Rights
- Open Access
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Collections
Mack, John (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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|---|---|---|---|---|---|---|---|
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