- Title
- Effect of nature of nanoparticles on the photophysicochemical properties of asymmetrically substituted Zn phthalocyanines
- Creator
- Magadla, Aviwe, Oluwole, David O, Britton, Jonathan, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2018
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/234539
- Identifier
- vital:50206
- Identifier
- xlink:href="https://doi.org/10.1016/j.ica.2018.06.043"
- Description
- In this work, low symmetry Zn mono caffeic acid tri-tert butyl (1) and Zn monocarboxyphenoxy tri-(tert-butylphenoxyl) (2) phthalocyanines (Pcs) were covalently linked to amino (using glutathione, GSH, or 3-aminopropyl)triethoxysilane, APTES) functionalised nanoparticles. The nanoparticles are represented as: AgNPs-GSH, SiNPs-APTES, Fe3O4-Ag-SiNPs-APTES and Fe3O4-AgNPs-GSH). The photophysical and photochemical behaviour of the complexes 1 and 2 and their conjugates with nanoparticles were investigated in dimethyl sulfoxide. The conjugates of the Pc complexes with the NPs afforded increase in triplet quantum yields with corresponding decrease in fluorescence quantum yield compared to the Pc complexes alone. The conjugates of 1-AgNPs-GSH, 2-SiNPs-APTES and 2-Fe3O4-Ag-SiNPs-APTES showed higher singlet oxygen quantum yield values as compared to the Pc complexes alone.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganica Chimica Acta, Magadla, A., Oluwole, D.O., Britton, J. and Nyokong, T., 2018. Effect of nature of nanoparticles on the photophysicochemical properties of asymmetrically substituted Zn phthalocyanines. Inorganica Chimica Acta, 482, pp.438-446, Inorganica Chimica Acta volume 482 p. 438 2018 1873-3255
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Britton, Jonathan (Dr)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Effect of nature of nanoparticles on the photophysicochemical properties.pdf | 695 KB | Adobe Acrobat PDF | View Details Download |