The ichthyofauna and piscivorous avifauna in a small temporarily open/closed Eastern Cape estuary, South Africa
- Authors: Blake, Justin David
- Date: 2010
- Subjects: Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5709 , http://hdl.handle.net/10962/d1005395 , Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Description: The spatial and temporal patterns in selected components of the ichthyofauna and piscivorous avifauna in the small temporarily open/closed Riet River Estuary located on the eastern seaboard of southern Africa was investigated monthly over the period August 2005 to July 2006. The ichthyofauna within the littoral zone of the estuary was sampled using a 5 m seine net (8 stations) while a 30 m seine net (4 stations) was employed to sample the fish in the channel. Bird counts were made along repeat transects along the length of the estuary. Total ichthyofaunal abundances and biomass ranged between 1.60 and 8.67 individuals m⁻² and 0.45 to 21.76 g wwt m⁻² within the littoral zone, and between 0.08 and 0.44 individuals m⁻² and 0.58 and 36.52 g wwt m⁻² in the channel of the estuary. The highest values were generally recorded during the summer months. Results of the numerical analysis indicated that the breaching events recorded over the study period did not lead to a common trend in the ichthyofaunal community. In the absence of a link to the marine environment, the ichthyofaunal community in the littoral zone was numerically dominated by the estuarine resident species, Gilchristella aestuaria and to a lesser extent by Glossogobius callidus, which collectively accounted for ca. 54% of the total ichthyofauna sampled. The establishment of a link to the marine environment coincided with increased numbers of marine breeding species including Atherina breviceps and Rhabdosargus holubi to total fish counts within the estuary. Hierarchical cluster analysis did not identify any spatial patterns in the community structure of the ichthyofauna in the littoral zone or channel zone of the estuary, which could likely be linked to the absence of any distinct horizontal patterns in salinity and temperature within the system. A total of thirteen piscivorous bird species was recorded over the study period. Of the recorded species, six species were wading piscivores, four species were aerial divers and the remaining three species were pursuit swimmers. There were no significant correlations between the estimates of the ichthyofaunal abundance and biomass and bird numbers evident during the study (P> 0.05 in both cases). The Reed Cormorant (Phalacrocorax africanus) was the dominant species throughout the study, with a mean of 8.25 (SD ± 7.90) individuals per count. Mean values of the Pied Kingfisher (Ceryle rudis) and Giant Kingfisher (Megaceryle maximus) were 3.42 (SD ± 1.20) and 1.17 (SD ± 0.60) individuals per count, respectively. The remaining species revealed mean values < 0.5 individuals per count. The highest bird numbers were recorded in winter reflecting the migration of large numbers of the Reed Cormorant into the system. Breaching events were associated with a decrease in total bird numbers, which was most likely due to loss of potential foraging habitat (littoral zone) for waders resulting from reduced water levels. Monthly food consumption by all piscivorous birds revealed large temporal variability, ranging from 26.35 to 140.58 kg per month. The observed variability could be linked to mouth phase and bird numbers.
- Full Text:
- Date Issued: 2010
- Authors: Blake, Justin David
- Date: 2010
- Subjects: Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5709 , http://hdl.handle.net/10962/d1005395 , Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Description: The spatial and temporal patterns in selected components of the ichthyofauna and piscivorous avifauna in the small temporarily open/closed Riet River Estuary located on the eastern seaboard of southern Africa was investigated monthly over the period August 2005 to July 2006. The ichthyofauna within the littoral zone of the estuary was sampled using a 5 m seine net (8 stations) while a 30 m seine net (4 stations) was employed to sample the fish in the channel. Bird counts were made along repeat transects along the length of the estuary. Total ichthyofaunal abundances and biomass ranged between 1.60 and 8.67 individuals m⁻² and 0.45 to 21.76 g wwt m⁻² within the littoral zone, and between 0.08 and 0.44 individuals m⁻² and 0.58 and 36.52 g wwt m⁻² in the channel of the estuary. The highest values were generally recorded during the summer months. Results of the numerical analysis indicated that the breaching events recorded over the study period did not lead to a common trend in the ichthyofaunal community. In the absence of a link to the marine environment, the ichthyofaunal community in the littoral zone was numerically dominated by the estuarine resident species, Gilchristella aestuaria and to a lesser extent by Glossogobius callidus, which collectively accounted for ca. 54% of the total ichthyofauna sampled. The establishment of a link to the marine environment coincided with increased numbers of marine breeding species including Atherina breviceps and Rhabdosargus holubi to total fish counts within the estuary. Hierarchical cluster analysis did not identify any spatial patterns in the community structure of the ichthyofauna in the littoral zone or channel zone of the estuary, which could likely be linked to the absence of any distinct horizontal patterns in salinity and temperature within the system. A total of thirteen piscivorous bird species was recorded over the study period. Of the recorded species, six species were wading piscivores, four species were aerial divers and the remaining three species were pursuit swimmers. There were no significant correlations between the estimates of the ichthyofaunal abundance and biomass and bird numbers evident during the study (P> 0.05 in both cases). The Reed Cormorant (Phalacrocorax africanus) was the dominant species throughout the study, with a mean of 8.25 (SD ± 7.90) individuals per count. Mean values of the Pied Kingfisher (Ceryle rudis) and Giant Kingfisher (Megaceryle maximus) were 3.42 (SD ± 1.20) and 1.17 (SD ± 0.60) individuals per count, respectively. The remaining species revealed mean values < 0.5 individuals per count. The highest bird numbers were recorded in winter reflecting the migration of large numbers of the Reed Cormorant into the system. Breaching events were associated with a decrease in total bird numbers, which was most likely due to loss of potential foraging habitat (littoral zone) for waders resulting from reduced water levels. Monthly food consumption by all piscivorous birds revealed large temporal variability, ranging from 26.35 to 140.58 kg per month. The observed variability could be linked to mouth phase and bird numbers.
- Full Text:
- Date Issued: 2010
Deploying DNSSEC in islands of security
- Authors: Murisa, Wesley Vengayi
- Date: 2013 , 2013-03-31
- Subjects: Internet domain names , Computer security , Computer network protocols , Computer security -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4577 , http://hdl.handle.net/10962/d1003053 , Internet domain names , Computer security , Computer network protocols , Computer security -- Africa
- Description: The Domain Name System (DNS), a name resolution protocol is one of the vulnerable network protocols that has been subjected to many security attacks such as cache poisoning, denial of service and the 'Kaminsky' spoofing attack. When DNS was designed, security was not incorporated into its design. The DNS Security Extensions (DNSSEC) provides security to the name resolution process by using public key cryptosystems. Although DNSSEC has backward compatibility with unsecured zones, it only offers security to clients when communicating with security aware zones. Widespread deployment of DNSSEC is therefore necessary to secure the name resolution process and provide security to the Internet. Only a few Top Level Domains (TLD's) have deployed DNSSEC, this inherently makes it difficult for their sub-domains to implement the security extensions to the DNS. This study analyses mechanisms that can be used by domains in islands of security to deploy DNSSEC so that the name resolution process can be secured in two specific cases where either the TLD is not signed or the domain registrar is not able to support signed domains. The DNS client side mechanisms evaluated in this study include web browser plug-ins, local validating resolvers and domain look-aside validation. The results of the study show that web browser plug-ins cannot work on their own without local validating resolvers. The web browser validators, however, proved to be useful in indicating to the user whether a domain has been validated or not. Local resolvers present a more secure option for Internet users who cannot trust the communication channel between their stub resolvers and remote name servers. However, they do not provide a way of showing the user whether a domain name has been correctly validated or not. Based on the results of the tests conducted, it is recommended that local validators be used with browser validators for visibility and improved security. On the DNS server side, Domain Look-aside Validation (DLV) presents a viable alternative for organizations in islands of security like most countries in Africa where only two country code Top Level Domains (ccTLD) have deployed DNSSEC. This research recommends use of DLV by corporates to provide DNS security to both internal and external users accessing their web based services. , LaTeX with hyperref package , pdfTeX-1.40.10
- Full Text:
- Date Issued: 2013
- Authors: Murisa, Wesley Vengayi
- Date: 2013 , 2013-03-31
- Subjects: Internet domain names , Computer security , Computer network protocols , Computer security -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4577 , http://hdl.handle.net/10962/d1003053 , Internet domain names , Computer security , Computer network protocols , Computer security -- Africa
- Description: The Domain Name System (DNS), a name resolution protocol is one of the vulnerable network protocols that has been subjected to many security attacks such as cache poisoning, denial of service and the 'Kaminsky' spoofing attack. When DNS was designed, security was not incorporated into its design. The DNS Security Extensions (DNSSEC) provides security to the name resolution process by using public key cryptosystems. Although DNSSEC has backward compatibility with unsecured zones, it only offers security to clients when communicating with security aware zones. Widespread deployment of DNSSEC is therefore necessary to secure the name resolution process and provide security to the Internet. Only a few Top Level Domains (TLD's) have deployed DNSSEC, this inherently makes it difficult for their sub-domains to implement the security extensions to the DNS. This study analyses mechanisms that can be used by domains in islands of security to deploy DNSSEC so that the name resolution process can be secured in two specific cases where either the TLD is not signed or the domain registrar is not able to support signed domains. The DNS client side mechanisms evaluated in this study include web browser plug-ins, local validating resolvers and domain look-aside validation. The results of the study show that web browser plug-ins cannot work on their own without local validating resolvers. The web browser validators, however, proved to be useful in indicating to the user whether a domain has been validated or not. Local resolvers present a more secure option for Internet users who cannot trust the communication channel between their stub resolvers and remote name servers. However, they do not provide a way of showing the user whether a domain name has been correctly validated or not. Based on the results of the tests conducted, it is recommended that local validators be used with browser validators for visibility and improved security. On the DNS server side, Domain Look-aside Validation (DLV) presents a viable alternative for organizations in islands of security like most countries in Africa where only two country code Top Level Domains (ccTLD) have deployed DNSSEC. This research recommends use of DLV by corporates to provide DNS security to both internal and external users accessing their web based services. , LaTeX with hyperref package , pdfTeX-1.40.10
- Full Text:
- Date Issued: 2013
Occupational health and safety and industrial relations in the South African construction industry : case studies of selected construction firms in Grahamstown
- Nene, Sinenhlanhla Sindisiwe
- Authors: Nene, Sinenhlanhla Sindisiwe
- Date: 2015
- Subjects: Industrial safety -- South Africa , Industrial relations -- South Africa , Construction industry -- South Africa -- Grahamstown , Management -- Employee participation
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3401 , http://hdl.handle.net/10962/d1018663
- Description: The construction industry is one of the most dangerous industries in the world, with many workplace fatalities every day. The existence of legislation that governs Occupational Health and Safety (OHS) is an intervention to ensure that all governments, employers and employees play their part in establishing and implementing policies that will help secure healthy and safe working environments. The study is qualitative and with the help of an interview guide, semistructured interviews were used to collect the data. The respondents were selected using purposive and snowball sampling methods. Ten managers from ten (five small, five large) construction firms, two employees from each firm, and the OHS inspector from the Department of Labour in Grahamstown were interviewed. Having explored management’s practices, communication methods, training and distribution of information, employee representation and participation, and industrial relations, several conclusions were reached. During the study it was found that there are a number of obstacles that are hampering effective OHS in the construction industry. Some of these include; management’s lack of commitment to a participatory approach in OHS decision-making, limited resources to invest adequately in OHS, and the lack of sufficient trade union involvement. In addition, we know very little about OHS in the construction industry, and the mere existence of OHS legislation does not help reduce the risks associated with construction work, especially when there is a shortage of skilled personnel to enforce the legislation and regulations.
- Full Text:
- Date Issued: 2015
- Authors: Nene, Sinenhlanhla Sindisiwe
- Date: 2015
- Subjects: Industrial safety -- South Africa , Industrial relations -- South Africa , Construction industry -- South Africa -- Grahamstown , Management -- Employee participation
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3401 , http://hdl.handle.net/10962/d1018663
- Description: The construction industry is one of the most dangerous industries in the world, with many workplace fatalities every day. The existence of legislation that governs Occupational Health and Safety (OHS) is an intervention to ensure that all governments, employers and employees play their part in establishing and implementing policies that will help secure healthy and safe working environments. The study is qualitative and with the help of an interview guide, semistructured interviews were used to collect the data. The respondents were selected using purposive and snowball sampling methods. Ten managers from ten (five small, five large) construction firms, two employees from each firm, and the OHS inspector from the Department of Labour in Grahamstown were interviewed. Having explored management’s practices, communication methods, training and distribution of information, employee representation and participation, and industrial relations, several conclusions were reached. During the study it was found that there are a number of obstacles that are hampering effective OHS in the construction industry. Some of these include; management’s lack of commitment to a participatory approach in OHS decision-making, limited resources to invest adequately in OHS, and the lack of sufficient trade union involvement. In addition, we know very little about OHS in the construction industry, and the mere existence of OHS legislation does not help reduce the risks associated with construction work, especially when there is a shortage of skilled personnel to enforce the legislation and regulations.
- Full Text:
- Date Issued: 2015
Vulnerability, irreplaceability and reserve selection for the elephant-impacted flora of the Addo National Elephant Park, Eastern Cape, South Africa
- Authors: Johnson, Catherine Fiona
- Date: 1998
- Subjects: Addo Elephant National Park (South Africa) , Veld plants -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4202 , http://hdl.handle.net/10962/d1003771 , Addo Elephant National Park (South Africa) , Veld plants -- South Africa -- Eastern Cape
- Description: The Addo Elephant National Park (AENP) is the only existing national park situated in succulent thicket. This unique veld type is endemic to the Eastern Cape, and forms an important centre of endemism for small succulents and geophytes which comprise the subdominant component of the vegetation. It is regarded as the most threatened vegetation type in the Eastern Cape, as much of it has been severely degraded by farming activities and its rate of regeneration is very low. Thus the AENP represents an important sanctuary for certain species. However, large herbivores, particularly elephants, pose a further threat to the vegetation, and areas from which elephants have been excluded in the park (botanical reserves) have been shown to be more speciesrich than the surrounding vegetation. Most elephant-impact studies have focussed on the large shrub component of the vegetation, and only preliminary studies have been done in AENP to date. As the elephant population continues to grow, there is pressure to utilise the botanical reserves to increase the amount of available grazing. It is thus important that the botanical reserve system be highly effective and efficient in terms of area. Existing botanical reserves were established ad hoc and are therefore not necessarily optimal in this regard. An iterative reserve-selection algorithm was used to maximise plant species conservation in the most efficient area.
- Full Text:
- Date Issued: 1998
- Authors: Johnson, Catherine Fiona
- Date: 1998
- Subjects: Addo Elephant National Park (South Africa) , Veld plants -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4202 , http://hdl.handle.net/10962/d1003771 , Addo Elephant National Park (South Africa) , Veld plants -- South Africa -- Eastern Cape
- Description: The Addo Elephant National Park (AENP) is the only existing national park situated in succulent thicket. This unique veld type is endemic to the Eastern Cape, and forms an important centre of endemism for small succulents and geophytes which comprise the subdominant component of the vegetation. It is regarded as the most threatened vegetation type in the Eastern Cape, as much of it has been severely degraded by farming activities and its rate of regeneration is very low. Thus the AENP represents an important sanctuary for certain species. However, large herbivores, particularly elephants, pose a further threat to the vegetation, and areas from which elephants have been excluded in the park (botanical reserves) have been shown to be more speciesrich than the surrounding vegetation. Most elephant-impact studies have focussed on the large shrub component of the vegetation, and only preliminary studies have been done in AENP to date. As the elephant population continues to grow, there is pressure to utilise the botanical reserves to increase the amount of available grazing. It is thus important that the botanical reserve system be highly effective and efficient in terms of area. Existing botanical reserves were established ad hoc and are therefore not necessarily optimal in this regard. An iterative reserve-selection algorithm was used to maximise plant species conservation in the most efficient area.
- Full Text:
- Date Issued: 1998
The development and distribution of heavy mineral concentrations in alluvial systems
- Authors: Lynn, Michael David
- Date: 1992
- Subjects: Heavy minerals -- Research , Alluvial plains -- Research , Geomorphology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4937 , http://hdl.handle.net/10962/d1005549 , Heavy minerals -- Research , Alluvial plains -- Research , Geomorphology -- South Africa
- Description: The objective of this review is to summarise the characteristics, significance and evolution of heavy minerals and their accumulations, and to identify the key controls on the development and distribution of heavy mineral concentrations in alluvial systems. These controls can be broadly classified as tectonic setting, geomorphic setting and grain-scale concentrating processes, each of which is discussed. Based on this review, exploration models are developed which are designed to indicate favourable localities for the accumulation of heavy minerals, and trends likely to be exhibited within these accumulations. The models are structured from the broadest scale of target selection, down to the local scale of sample site selection. The major conclusion of this work is that an understanding of process geomorphology is required to develop genetic models of placer development, including a detailed evaluation of climatic fluctuations throughout the Caenozoic. Palaeoplacers such as the Witwatersrand goldfield, are inferred to have formed under similar circumstances of tectonic setting as genetically comparable Caenozoic placers such as those of Otago, New Zealand. The means of preservation of such major basins is however poorly understood.
- Full Text:
- Date Issued: 1992
- Authors: Lynn, Michael David
- Date: 1992
- Subjects: Heavy minerals -- Research , Alluvial plains -- Research , Geomorphology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4937 , http://hdl.handle.net/10962/d1005549 , Heavy minerals -- Research , Alluvial plains -- Research , Geomorphology -- South Africa
- Description: The objective of this review is to summarise the characteristics, significance and evolution of heavy minerals and their accumulations, and to identify the key controls on the development and distribution of heavy mineral concentrations in alluvial systems. These controls can be broadly classified as tectonic setting, geomorphic setting and grain-scale concentrating processes, each of which is discussed. Based on this review, exploration models are developed which are designed to indicate favourable localities for the accumulation of heavy minerals, and trends likely to be exhibited within these accumulations. The models are structured from the broadest scale of target selection, down to the local scale of sample site selection. The major conclusion of this work is that an understanding of process geomorphology is required to develop genetic models of placer development, including a detailed evaluation of climatic fluctuations throughout the Caenozoic. Palaeoplacers such as the Witwatersrand goldfield, are inferred to have formed under similar circumstances of tectonic setting as genetically comparable Caenozoic placers such as those of Otago, New Zealand. The means of preservation of such major basins is however poorly understood.
- Full Text:
- Date Issued: 1992
The precambrian iron-formations in the Limpopo belt as represented by the magnetite quartzite deposits at Moonlight, Koedoesrand area, Northern Transvaal
- Authors: Badenhorst, Jaco Cornelis
- Date: 1991 , 2013-02-20
- Subjects: Iron ores -- Geology -- South Africa , Quartzite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5064 , http://hdl.handle.net/10962/d1013309
- Description: This dissertation is based largely on data that was accumulated during the execution of an exploration program by Iscor Ltd in the Northern Transvaal. The program included geological mapping, geophysical surveys and drilling, on Precambrian iron-formations in the Central Zone of the Limpopo Belt. The structure, stratigraphy, metamorphism, and economic importance of the magnetite quartzites and associated lithologies of the Moonlight prospect are discussed. The lithologies underlying the Moonlight prospect area consist of various pink- and grey-banded gneisses and pink granulite, together with a variety of metasedimentary supracrustal rock-types and concordant serpentinite bodies. The gneissic rock-types consist of chlorite-quartz-feldspar gneiss, chlorite-quartz-feldspar augen gneiss, hornblende-quartz-feldspar gneiss, biotite-quartz-feldspar gneiss, felsic and mafic granulite, and foliated amphibolite. The metasedimentary lithologies are represented by calc-silicates and marble, white quartz-feldspar granulite, magnetite quartzite, metaquartzite and garnet-bearing granulite and gneiss (metapelites). The concordant ultramafic bodies consist of serpentinite with lesser amphibolite, dunite, and chromitite. Intrusive pegmatites and diabase dykes are also present in the prospect area. Metamorphism reached granulite-facies, and more than one retrqgrade metamorphic event is recognized . Amphibolite-facies assemblages are present, but it is uncertain whether they represent another retrograde event . Polyphase deformation has produced intense and complex folding , resulting in irregular magnetite quartzite orebodies. The high metamorphic grades have resulted in medium- grained recrystallization of the magnetite-quartzites with a loss of prominent banding often associated with these rock-types . The magnetite quartzite occurs as three seperate but related ore zones, consisting of one or more ore-bands seperated by other lithologies. All three zones form poor outcrops and suboutcrops in a generally flat lying and sand covered area. · Although representing a low-grade iron ore (32% total Fe), the magnetite quartzite deposits at Moonlight are regarded as potentially viable due to the large opencast tonnages available at low stripping ratios, and the relatively cheap and easy beneficiation process needed to produce a magnetite concentrate with 69-70% total Fe.
- Full Text:
- Date Issued: 1991
- Authors: Badenhorst, Jaco Cornelis
- Date: 1991 , 2013-02-20
- Subjects: Iron ores -- Geology -- South Africa , Quartzite -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5064 , http://hdl.handle.net/10962/d1013309
- Description: This dissertation is based largely on data that was accumulated during the execution of an exploration program by Iscor Ltd in the Northern Transvaal. The program included geological mapping, geophysical surveys and drilling, on Precambrian iron-formations in the Central Zone of the Limpopo Belt. The structure, stratigraphy, metamorphism, and economic importance of the magnetite quartzites and associated lithologies of the Moonlight prospect are discussed. The lithologies underlying the Moonlight prospect area consist of various pink- and grey-banded gneisses and pink granulite, together with a variety of metasedimentary supracrustal rock-types and concordant serpentinite bodies. The gneissic rock-types consist of chlorite-quartz-feldspar gneiss, chlorite-quartz-feldspar augen gneiss, hornblende-quartz-feldspar gneiss, biotite-quartz-feldspar gneiss, felsic and mafic granulite, and foliated amphibolite. The metasedimentary lithologies are represented by calc-silicates and marble, white quartz-feldspar granulite, magnetite quartzite, metaquartzite and garnet-bearing granulite and gneiss (metapelites). The concordant ultramafic bodies consist of serpentinite with lesser amphibolite, dunite, and chromitite. Intrusive pegmatites and diabase dykes are also present in the prospect area. Metamorphism reached granulite-facies, and more than one retrqgrade metamorphic event is recognized . Amphibolite-facies assemblages are present, but it is uncertain whether they represent another retrograde event . Polyphase deformation has produced intense and complex folding , resulting in irregular magnetite quartzite orebodies. The high metamorphic grades have resulted in medium- grained recrystallization of the magnetite-quartzites with a loss of prominent banding often associated with these rock-types . The magnetite quartzite occurs as three seperate but related ore zones, consisting of one or more ore-bands seperated by other lithologies. All three zones form poor outcrops and suboutcrops in a generally flat lying and sand covered area. · Although representing a low-grade iron ore (32% total Fe), the magnetite quartzite deposits at Moonlight are regarded as potentially viable due to the large opencast tonnages available at low stripping ratios, and the relatively cheap and easy beneficiation process needed to produce a magnetite concentrate with 69-70% total Fe.
- Full Text:
- Date Issued: 1991
Removal of copper and nickel from solution by the non-viable biomass of the water fern Azolla filiculoides in an upscaled fixed-bed column system
- Authors: Thompson, Denis Alan
- Date: 2001
- Subjects: Copper , Nickel , Azolla , Heavy metals -- Absorption and adsorption
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3914 , http://hdl.handle.net/10962/d1003973 , Copper , Nickel , Azolla , Heavy metals -- Absorption and adsorption
- Description: The potential of non-viable Azalia filiculaides for the removal of Cu and Ni from aqueous solutions and the possibility of scaling up existing lab scale Azalia column systems was investigated. The effects of factors such as metal starting concentration, pH and two metals in solution on the removal of Ni and Cu from aqueous solution by dried and crushed Azalia biomass were studied in batch systems. Aqueous solutions of Ni with starting concentrations between 1000 and 2000J.lmolll gave the most efficient Ni removal by Azalla biomass. For Cu the optimum starting concentration for adsorption was 50J.lmol/l. The adsorption capacity of both eu and Ni increased as the starting pH of the sorption media increased. The optimum pH for Ni adsorption was found at pH 7 and for Cu, at pH 5. - Awlla biomass had a higher. maximum binding capacity (qrnax) for Cu than for Ni at pH 5. The removal of both Cu allct Ni showed little or no variation with the presence another metal in solution. Kinetic studies show that both Cu and Ni adsorbed rapidly onto the Azalia biomass. The removal of Cu and Ni from aqueous solutions using non-viable Azalia biomass was investigated in a lab scale fixed-bed column and an upscaled 4L column system. The nonviable Azalla filiculaides biomass when dried and used in a column for adsorption of Cu and Ni showed good physical stability under many different conditions. Preparation of the biomass before it could be used in the columns was very simple and did not involve any significant pretreatment steps. Prolonged exposure to UV light decreases Azalia biomass capacity for Ni and Cu adsorption. Column adsorption of Cu and Ni from aqueous solutions was successfully upscaled approximately 100 times. Relative to the lab scale column, the 4L column performed better for the uptake of Cu and Ni per gram of biomass. The larger column was also able to operate at relatively higher flow rates. The biomass showed good reusability with little change in the amount of Ni adsorbed in 10 consecutive cycles. Electron micrographs showecf little or no change in the physical structure and integrity of the Azolla biomass after exposure to mineral acids, Ni solution and high flow rates over 10 consecutive adsorption and desorption cycles. As much as 80% Ni and 70 % Cu was recovered when desorption profiles were generated using O.lMHCI as a desorption agent. The 4L column system was also tested using a highly concen~rat:~ Ni plating bath solution.(Nicrolyte 1). Only 18 % of the Ni could be removed from the expended Nicrolyte 1 pla~Jng solution after treating only 25L, indicating that Azolla biomass is more suited for removal of metals from more dilute industrial effluents.
- Full Text:
- Date Issued: 2001
- Authors: Thompson, Denis Alan
- Date: 2001
- Subjects: Copper , Nickel , Azolla , Heavy metals -- Absorption and adsorption
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3914 , http://hdl.handle.net/10962/d1003973 , Copper , Nickel , Azolla , Heavy metals -- Absorption and adsorption
- Description: The potential of non-viable Azalia filiculaides for the removal of Cu and Ni from aqueous solutions and the possibility of scaling up existing lab scale Azalia column systems was investigated. The effects of factors such as metal starting concentration, pH and two metals in solution on the removal of Ni and Cu from aqueous solution by dried and crushed Azalia biomass were studied in batch systems. Aqueous solutions of Ni with starting concentrations between 1000 and 2000J.lmolll gave the most efficient Ni removal by Azalla biomass. For Cu the optimum starting concentration for adsorption was 50J.lmol/l. The adsorption capacity of both eu and Ni increased as the starting pH of the sorption media increased. The optimum pH for Ni adsorption was found at pH 7 and for Cu, at pH 5. - Awlla biomass had a higher. maximum binding capacity (qrnax) for Cu than for Ni at pH 5. The removal of both Cu allct Ni showed little or no variation with the presence another metal in solution. Kinetic studies show that both Cu and Ni adsorbed rapidly onto the Azalia biomass. The removal of Cu and Ni from aqueous solutions using non-viable Azalia biomass was investigated in a lab scale fixed-bed column and an upscaled 4L column system. The nonviable Azalla filiculaides biomass when dried and used in a column for adsorption of Cu and Ni showed good physical stability under many different conditions. Preparation of the biomass before it could be used in the columns was very simple and did not involve any significant pretreatment steps. Prolonged exposure to UV light decreases Azalia biomass capacity for Ni and Cu adsorption. Column adsorption of Cu and Ni from aqueous solutions was successfully upscaled approximately 100 times. Relative to the lab scale column, the 4L column performed better for the uptake of Cu and Ni per gram of biomass. The larger column was also able to operate at relatively higher flow rates. The biomass showed good reusability with little change in the amount of Ni adsorbed in 10 consecutive cycles. Electron micrographs showecf little or no change in the physical structure and integrity of the Azolla biomass after exposure to mineral acids, Ni solution and high flow rates over 10 consecutive adsorption and desorption cycles. As much as 80% Ni and 70 % Cu was recovered when desorption profiles were generated using O.lMHCI as a desorption agent. The 4L column system was also tested using a highly concen~rat:~ Ni plating bath solution.(Nicrolyte 1). Only 18 % of the Ni could be removed from the expended Nicrolyte 1 pla~Jng solution after treating only 25L, indicating that Azolla biomass is more suited for removal of metals from more dilute industrial effluents.
- Full Text:
- Date Issued: 2001
The development of an in vitro system for the production of drug metabolites using microsomal enzymes from bovine liver
- Authors: Morrison, Roxanne
- Date: 2011
- Subjects: Drugs -- Metabolism , Xenobiotics -- Metabolism , Metabolites , Drugs -- Testing , Toxicity testing -- In vitro , Doping in horse racing -- Control -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4087 , http://hdl.handle.net/10962/d1007698 , Drugs -- Metabolism , Xenobiotics -- Metabolism , Metabolites , Drugs -- Testing , Toxicity testing -- In vitro , Doping in horse racing -- Control -- Research
- Description: Drug metabolism is a specialised subset of xenobiotic metabolism, pertaining to the breakdown and elimination of pharmaceutical drugs. The enzymes involved in these pathways are the cytochrome P450 family of isozymes. Metabolism is an important factor in determining the pharmacological effects of drugs. The main aim of this study was to develop a system whereby the major metabolites of drugs can be produced in vitro. An in vitro system was developed and optimised using commercially prepared microsomes from rat liver and coumarin (by monitoring its conversion to 7-hydroxycoumarin) as a model. The optimum running conditions for the incubations were 50 μM coumarin, 50 μg protein/ml microsomes, 1 mM NADP⁺, 5 mM G6P and 1U/ml G6PDH incubated for 30 minutes at 38℃. The HPLC method for the detection of coumarin and 7-hydroxycoumarin was also validated with respect to linearity, reproducibility, precision, accuracy and lower limits of detection and quantification. The system developed was then tested using microsomes prepared from fresh bovine liver on these ten drugs of interest in doping control in horse racing: diazepam, nordiazepam, oxazepam, promazine, acepromazine, chlorpromazine, morphine, codeine, etoricoxib and lumiracoxib. The bovine liver microsomes were prepared using differential centrifugation and had activity on a par with the commercial preparations. This in vitro system metabolised the drugs and produced both phase I and II metabolites, similar to those observed in humans and horses in vivo. For example, the major metabolites of the benzodiazepine drug, diazepam, nordiazepam, temazepam and oxazepam as well as the glucuronidated phase II products were all found after incubations with the bovine liver microsomes. The metabolism of the drugs was also investigated in silico using the computational procedure, MetaSite. MetaSite was able to successfully predict known metabolites for most of the drugs studied. Differences were observed from the in vitro incubations and this is most likely due to MetaSite using only human cytochrome P450s for analysis.
- Full Text:
- Date Issued: 2011
- Authors: Morrison, Roxanne
- Date: 2011
- Subjects: Drugs -- Metabolism , Xenobiotics -- Metabolism , Metabolites , Drugs -- Testing , Toxicity testing -- In vitro , Doping in horse racing -- Control -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4087 , http://hdl.handle.net/10962/d1007698 , Drugs -- Metabolism , Xenobiotics -- Metabolism , Metabolites , Drugs -- Testing , Toxicity testing -- In vitro , Doping in horse racing -- Control -- Research
- Description: Drug metabolism is a specialised subset of xenobiotic metabolism, pertaining to the breakdown and elimination of pharmaceutical drugs. The enzymes involved in these pathways are the cytochrome P450 family of isozymes. Metabolism is an important factor in determining the pharmacological effects of drugs. The main aim of this study was to develop a system whereby the major metabolites of drugs can be produced in vitro. An in vitro system was developed and optimised using commercially prepared microsomes from rat liver and coumarin (by monitoring its conversion to 7-hydroxycoumarin) as a model. The optimum running conditions for the incubations were 50 μM coumarin, 50 μg protein/ml microsomes, 1 mM NADP⁺, 5 mM G6P and 1U/ml G6PDH incubated for 30 minutes at 38℃. The HPLC method for the detection of coumarin and 7-hydroxycoumarin was also validated with respect to linearity, reproducibility, precision, accuracy and lower limits of detection and quantification. The system developed was then tested using microsomes prepared from fresh bovine liver on these ten drugs of interest in doping control in horse racing: diazepam, nordiazepam, oxazepam, promazine, acepromazine, chlorpromazine, morphine, codeine, etoricoxib and lumiracoxib. The bovine liver microsomes were prepared using differential centrifugation and had activity on a par with the commercial preparations. This in vitro system metabolised the drugs and produced both phase I and II metabolites, similar to those observed in humans and horses in vivo. For example, the major metabolites of the benzodiazepine drug, diazepam, nordiazepam, temazepam and oxazepam as well as the glucuronidated phase II products were all found after incubations with the bovine liver microsomes. The metabolism of the drugs was also investigated in silico using the computational procedure, MetaSite. MetaSite was able to successfully predict known metabolites for most of the drugs studied. Differences were observed from the in vitro incubations and this is most likely due to MetaSite using only human cytochrome P450s for analysis.
- Full Text:
- Date Issued: 2011
Assessment of organochlorine pesticide residues in fish samples from the Okavango Delta, Botswana
- Authors: Mpofu, Christopher
- Date: 2011 , 2011-02-28
- Subjects: Pesticides , Organochlorine compounds , Freshwater fishes -- Effect of pesticides on -- Botswana -- Okavango River Delta , Water -- Pesticide content -- Botswana -- Okavango River Delta , Catfishes -- Botswana -- Okavango River Delta , Tigerfish -- Botswana -- Okavango River Delta , Redbreast tilapia -- Botswana -- Okavango River Delta
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4404 , http://hdl.handle.net/10962/d1006707 , Pesticides , Organochlorine compounds , Freshwater fishes -- Effect of pesticides on -- Botswana -- Okavango River Delta , Water -- Pesticide content -- Botswana -- Okavango River Delta , Catfishes -- Botswana -- Okavango River Delta , Tigerfish -- Botswana -- Okavango River Delta , Redbreast tilapia -- Botswana -- Okavango River Delta
- Description: This thesis presents an evaluation of the dispersive solid-phase extraction (d-SPE) method referred to as the quick, easy, cheap, effective, rugged and safe (QuEChERS) method for the determination of four organochlorine pesticide residues in fish samples. The pesticides investigated in this study were o, p′-DDT, p, p′-DDE, aldrin and dieldrin. The combined use of Gas Chromatography with an Electron Capture Detector (GC-ECD) and sensitive Time of Flight (TOF) mass detector facilitated the identification of the target analytes. In the absence of certified reference material, the overall analytical procedure was validated by systematic recovery experiments on spiked samples at three levels of 2, 5 and 10 ng/g. The targeted compounds were successfully extracted and their recovery ranged from 76 to 96% with relative standard deviations of less than 13%. The optimum QuEChERS conditions were 2g of fish powder, 10 ml acetonitrile and 1 min shaking time. The optimal conditions were applied to assess the levels of chlorinated pesticides in blunt-tooth catfish (Clarias ngamensis), tigerfish (Hydrocynus vittatus), Oreochromis andersonii and red-breasted tilapia (Tilapia rendalli) from the Okavango Delta, Botswana. Dieldrin, p, p′-DDE and aldrin were detected in all the analysed samples with a concentration range of 0.04 – 0.29, 0.07 – 0.33, 0.04 – 0.28 and 0.03 – 0.24 ng/g per dry weight in O. andersonii, C. ngamensis, T. rendalli and H. vittatus respectively. These concentrations were below the US-EPA 0.1 μg/g allowable limit in edible fish and the Australian Maximum Residue Limit (MRL) of 50 - 1000 ng/g in fresh fish. DDT was not detected in all the fish species investigated. The mean lipid content recorded in the fish samples were 1.24, 2.16, 2.18 and 4.21% for H. vittatus, T. rendalli, O. andersonni and C. ngamensis respectively. No systematic trend was observed between fish age and pesticide levels in fish. Acetylcholinesterase (AChE) activity assays were performed to assess the effects of organochlorine pesticides in Clarias ngamensis. The enzyme activity recorded in Clarias ngamensis from the Okavango Delta and the reference site was 12.31 μmol of acetylcholine iodide hydrolysed/min/g brain tissue. The enzyme activity remained the same indicating no enzyme inhibition. The conclusions drawn from this study are that the QuEChERS method is applicable for the determination of organochlorine pesticide residues in fish matrices. The fish from the Okavango Delta are safe for human consumption.
- Full Text:
- Date Issued: 2011
- Authors: Mpofu, Christopher
- Date: 2011 , 2011-02-28
- Subjects: Pesticides , Organochlorine compounds , Freshwater fishes -- Effect of pesticides on -- Botswana -- Okavango River Delta , Water -- Pesticide content -- Botswana -- Okavango River Delta , Catfishes -- Botswana -- Okavango River Delta , Tigerfish -- Botswana -- Okavango River Delta , Redbreast tilapia -- Botswana -- Okavango River Delta
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4404 , http://hdl.handle.net/10962/d1006707 , Pesticides , Organochlorine compounds , Freshwater fishes -- Effect of pesticides on -- Botswana -- Okavango River Delta , Water -- Pesticide content -- Botswana -- Okavango River Delta , Catfishes -- Botswana -- Okavango River Delta , Tigerfish -- Botswana -- Okavango River Delta , Redbreast tilapia -- Botswana -- Okavango River Delta
- Description: This thesis presents an evaluation of the dispersive solid-phase extraction (d-SPE) method referred to as the quick, easy, cheap, effective, rugged and safe (QuEChERS) method for the determination of four organochlorine pesticide residues in fish samples. The pesticides investigated in this study were o, p′-DDT, p, p′-DDE, aldrin and dieldrin. The combined use of Gas Chromatography with an Electron Capture Detector (GC-ECD) and sensitive Time of Flight (TOF) mass detector facilitated the identification of the target analytes. In the absence of certified reference material, the overall analytical procedure was validated by systematic recovery experiments on spiked samples at three levels of 2, 5 and 10 ng/g. The targeted compounds were successfully extracted and their recovery ranged from 76 to 96% with relative standard deviations of less than 13%. The optimum QuEChERS conditions were 2g of fish powder, 10 ml acetonitrile and 1 min shaking time. The optimal conditions were applied to assess the levels of chlorinated pesticides in blunt-tooth catfish (Clarias ngamensis), tigerfish (Hydrocynus vittatus), Oreochromis andersonii and red-breasted tilapia (Tilapia rendalli) from the Okavango Delta, Botswana. Dieldrin, p, p′-DDE and aldrin were detected in all the analysed samples with a concentration range of 0.04 – 0.29, 0.07 – 0.33, 0.04 – 0.28 and 0.03 – 0.24 ng/g per dry weight in O. andersonii, C. ngamensis, T. rendalli and H. vittatus respectively. These concentrations were below the US-EPA 0.1 μg/g allowable limit in edible fish and the Australian Maximum Residue Limit (MRL) of 50 - 1000 ng/g in fresh fish. DDT was not detected in all the fish species investigated. The mean lipid content recorded in the fish samples were 1.24, 2.16, 2.18 and 4.21% for H. vittatus, T. rendalli, O. andersonni and C. ngamensis respectively. No systematic trend was observed between fish age and pesticide levels in fish. Acetylcholinesterase (AChE) activity assays were performed to assess the effects of organochlorine pesticides in Clarias ngamensis. The enzyme activity recorded in Clarias ngamensis from the Okavango Delta and the reference site was 12.31 μmol of acetylcholine iodide hydrolysed/min/g brain tissue. The enzyme activity remained the same indicating no enzyme inhibition. The conclusions drawn from this study are that the QuEChERS method is applicable for the determination of organochlorine pesticide residues in fish matrices. The fish from the Okavango Delta are safe for human consumption.
- Full Text:
- Date Issued: 2011
Remora : implementing adaptive parallelism on a heterogeneous cluster of networked workstations
- Authors: Rehmet, Geoffrey Michael
- Date: 1995
- Subjects: LINDA (Computer system) , Local area networks (Computer networks) , Computer networks , Remora (Computer system)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4673 , http://hdl.handle.net/10962/d1006696 , LINDA (Computer system) , Local area networks (Computer networks) , Computer networks , Remora (Computer system)
- Description: Computers connected to a local area network are often only fully utilized for short periods of time. In fact, most workstations are not used at all for a significant portion of the day. The combined "idle time" of the workstations on a network constitutes a significant computing resource, which is generally wasted. If harnessed properly, such a resource could constitute a cheap alternative to expensive high-performance computers. Adaptive parallelism refers to the parallel execution of a computation on a dynamically changing set of processors. This thesis investigates the viability of this approach as a vehicle to harness the "idle cycles" available on a heterogeneous cluster of networked computers. A system, called Remora, which implements adaptive parallelism via the Linda programming paradigm, is presented. Experiments, performed using Remora, show that adaptive parallelism provides an efficient vehicle for using idle processor cycles, without having an adverse effect on the tasks which constitute the normal workload of the computers being used.
- Full Text:
- Date Issued: 1995
- Authors: Rehmet, Geoffrey Michael
- Date: 1995
- Subjects: LINDA (Computer system) , Local area networks (Computer networks) , Computer networks , Remora (Computer system)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4673 , http://hdl.handle.net/10962/d1006696 , LINDA (Computer system) , Local area networks (Computer networks) , Computer networks , Remora (Computer system)
- Description: Computers connected to a local area network are often only fully utilized for short periods of time. In fact, most workstations are not used at all for a significant portion of the day. The combined "idle time" of the workstations on a network constitutes a significant computing resource, which is generally wasted. If harnessed properly, such a resource could constitute a cheap alternative to expensive high-performance computers. Adaptive parallelism refers to the parallel execution of a computation on a dynamically changing set of processors. This thesis investigates the viability of this approach as a vehicle to harness the "idle cycles" available on a heterogeneous cluster of networked computers. A system, called Remora, which implements adaptive parallelism via the Linda programming paradigm, is presented. Experiments, performed using Remora, show that adaptive parallelism provides an efficient vehicle for using idle processor cycles, without having an adverse effect on the tasks which constitute the normal workload of the computers being used.
- Full Text:
- Date Issued: 1995
The effects of melatonin on the testis, epididymis and sperm physiology of the Wistar rat
- Authors: Gwayi, Noluzuko
- Date: 2001
- Subjects: Rats as laboratory animals , Rats -- physiology , Spermatozoa , Melatonin , Testis , Epididymis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5681 , http://hdl.handle.net/10962/d1005366 , Rats as laboratory animals , Rats -- physiology , Spermatozoa , Melatonin , Testis , Epididymis
- Description: Melatonin is a product of the pineal gland and is postulated to play an antigonadotropic role in the reproductive system of mammals. The reproductive system of non-seasonally breeding mammals is believed to be not as responsive to melatonin treatment as that of seasonally breeding mammals. Recently, there has been increasing support from in vivo and in vitro studies, for the hypothesis that melatonin has negative effects on sperm physiology, especially on sperm motility. High and/or low seminal concentrations of melatonin have been associated with abnormalities in human sperm motility and concentration. In this study, I examined the effects of melatonin on the testis, epididymis and sperm physiology, using in vivo and in vitro experiments, in a non-seasonally breeding mammal. Treatment, in vivo, with exogenous melatonin for six weeks did not inhibit testosterone production or spermatogenesis, nor did it affect the mass of the testes and epididymides at dissection, the concentration the morphology of speimatozoa. However, melatonin in vivo had a small, but significant negative effect on sperm motility and sperm motility index. In vitro incubation of spermatozoa Fith melatonin reduced the percentage (%) of forward progressive movement (fpm), increased the % reduction in fpm, reduced the vigor or quality of sperm motility, reduced the sperm motility index, and delayed and/or prolonged the transition of one pattern of sperm motility to the subsequent patterns. Melatonin increased the pH of the culture medium, and the increased pH, and the ethanol utilized as a solvent for melatonin, both negatively affected all the sperm motility parameters that were assessed in my study. The effects of ethanol increased with time, and the effects of pH increased with both time and increasing pH. Melatonin in vitro did not inhibit capacitation and the acrosome reaction, but it delayed the onset and the progression of capacitation and the acrosome reaction. These results suggest that while melatonin did not inhibit spermatogenesis in the Wistar rat, it may influence sperm motility. Therefore, the presence of high concentrations of melatonin in the reproductive fluids may inhibit sperm motility. With further detailed research, melatonin may have a potential use as a contraceptive drug.
- Full Text:
- Date Issued: 2001
- Authors: Gwayi, Noluzuko
- Date: 2001
- Subjects: Rats as laboratory animals , Rats -- physiology , Spermatozoa , Melatonin , Testis , Epididymis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5681 , http://hdl.handle.net/10962/d1005366 , Rats as laboratory animals , Rats -- physiology , Spermatozoa , Melatonin , Testis , Epididymis
- Description: Melatonin is a product of the pineal gland and is postulated to play an antigonadotropic role in the reproductive system of mammals. The reproductive system of non-seasonally breeding mammals is believed to be not as responsive to melatonin treatment as that of seasonally breeding mammals. Recently, there has been increasing support from in vivo and in vitro studies, for the hypothesis that melatonin has negative effects on sperm physiology, especially on sperm motility. High and/or low seminal concentrations of melatonin have been associated with abnormalities in human sperm motility and concentration. In this study, I examined the effects of melatonin on the testis, epididymis and sperm physiology, using in vivo and in vitro experiments, in a non-seasonally breeding mammal. Treatment, in vivo, with exogenous melatonin for six weeks did not inhibit testosterone production or spermatogenesis, nor did it affect the mass of the testes and epididymides at dissection, the concentration the morphology of speimatozoa. However, melatonin in vivo had a small, but significant negative effect on sperm motility and sperm motility index. In vitro incubation of spermatozoa Fith melatonin reduced the percentage (%) of forward progressive movement (fpm), increased the % reduction in fpm, reduced the vigor or quality of sperm motility, reduced the sperm motility index, and delayed and/or prolonged the transition of one pattern of sperm motility to the subsequent patterns. Melatonin increased the pH of the culture medium, and the increased pH, and the ethanol utilized as a solvent for melatonin, both negatively affected all the sperm motility parameters that were assessed in my study. The effects of ethanol increased with time, and the effects of pH increased with both time and increasing pH. Melatonin in vitro did not inhibit capacitation and the acrosome reaction, but it delayed the onset and the progression of capacitation and the acrosome reaction. These results suggest that while melatonin did not inhibit spermatogenesis in the Wistar rat, it may influence sperm motility. Therefore, the presence of high concentrations of melatonin in the reproductive fluids may inhibit sperm motility. With further detailed research, melatonin may have a potential use as a contraceptive drug.
- Full Text:
- Date Issued: 2001
Synthesis and electrochemistry of octapentylthio phthalocyanine complexes of manganese, titanium and vanadium
- Authors: Mbambisa, Gcineka
- Date: 2009
- Subjects: Electrochemistry , Phthalocyanines -- Synthesis , Manganese , Titanium , Vanadium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4368 , http://hdl.handle.net/10962/d1005033 , Electrochemistry , Phthalocyanines -- Synthesis , Manganese , Titanium , Vanadium
- Description: Synthesis of new thio derivatised Pcs with manganese, titanium and vanadium as a central metal is reported. The complexes synthesised were characterised using spectroscopic and electrochemical means. The complexes displayed interesting spectroscopic properties with absorption of the Q band being observed in the near infrared region. These complexes have unusual colours for MPc complexes, with purple or red colour being observed in solution. Interesting electrochemical properties were observed, with rare observation of the MnIV/MnIII redox couple. There was observation of oxidation peaks for the pentylthio derivatised Pc with titanium as the central metal; this is unusual since for reported thio derivatives based on TiPc, no oxidation was observed. The vanadium based Pc showed an interesting spectrum for the first ring based reduction. The absorption spectrum obtained for the 1st reduction of the vanadium complex using spectroelectrochemistry would normally indicate a metal based process but comparing with literature it was concluded that it is a ring based reduction process. Generally all the MPc complexes formed a well ordered stable monolayer on the gold electrode. Electrocatalytic studies using L-cysteine revealed that the SAM based on manganese (III) octapentylthio phthalocyanine (AcOMnOPTPc) was the most effective since it catalyses L-cysteine at much lower oxidation potentials and it is also much more stable.
- Full Text:
- Date Issued: 2009
- Authors: Mbambisa, Gcineka
- Date: 2009
- Subjects: Electrochemistry , Phthalocyanines -- Synthesis , Manganese , Titanium , Vanadium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4368 , http://hdl.handle.net/10962/d1005033 , Electrochemistry , Phthalocyanines -- Synthesis , Manganese , Titanium , Vanadium
- Description: Synthesis of new thio derivatised Pcs with manganese, titanium and vanadium as a central metal is reported. The complexes synthesised were characterised using spectroscopic and electrochemical means. The complexes displayed interesting spectroscopic properties with absorption of the Q band being observed in the near infrared region. These complexes have unusual colours for MPc complexes, with purple or red colour being observed in solution. Interesting electrochemical properties were observed, with rare observation of the MnIV/MnIII redox couple. There was observation of oxidation peaks for the pentylthio derivatised Pc with titanium as the central metal; this is unusual since for reported thio derivatives based on TiPc, no oxidation was observed. The vanadium based Pc showed an interesting spectrum for the first ring based reduction. The absorption spectrum obtained for the 1st reduction of the vanadium complex using spectroelectrochemistry would normally indicate a metal based process but comparing with literature it was concluded that it is a ring based reduction process. Generally all the MPc complexes formed a well ordered stable monolayer on the gold electrode. Electrocatalytic studies using L-cysteine revealed that the SAM based on manganese (III) octapentylthio phthalocyanine (AcOMnOPTPc) was the most effective since it catalyses L-cysteine at much lower oxidation potentials and it is also much more stable.
- Full Text:
- Date Issued: 2009
A comparative study of the performance of English and Xhosa speaking children on the Wechsler Intelligence Scale for Children-Revised (WISC-R)
- Authors: Runciman, Carey Lynn
- Date: 1996 , 2013-10-03
- Subjects: Wechsler Intelligence Scale for Children -- Cross-cultural studies , Children -- Intelligence testing , Psychological tests -- Cross-cultural studies , Educational tests and measurements -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3150 , http://hdl.handle.net/10962/d1007467 , Wechsler Intelligence Scale for Children -- Cross-cultural studies , Children -- Intelligence testing , Psychological tests -- Cross-cultural studies , Educational tests and measurements -- South Africa
- Description: The purpose of this study was to compare the WISC-R subtest score scatter patterns and obtain preliminary normative data on the WISC-R Adjunctive tests (Digit Span Forward; Digit Span Backward; Digit Supraspan; Coding Immediate Recall and Coding Delayed Recall) on a non-clinical population of South African English (n= 15) and Xhosa (n= 12) speaking, standard six children, studying in English medium schools. Tests were administered to 27 subjects, both male (n=19) and female (n=8), with a mean age of 14.1 years (range = 13.3-15.3). The results show that White English speaking children outperform Black Xhosa speaking children on Verbal, Performance and Full Scale IQs and all subtests, but that these differences tended to disappear when Full Scale IQ and school grade average were controlled for. No subtest score scatter was present for either group although more specific test items appeared to be more difficult for Xhosa speaking subjects and may have contributed to generally lowered scores. Results suggest that caution must be employed in assigning Xhosa speaking South African children to absolute IQ categories. However, the WISC-R has validity for diagnostic use on both White English speaking and Black Xhosa speaking South African children as there was no evidence of a significant Verbal IQ/Performance IQ discrepancy, or significant low subtest scatter for either group. Normative tables are presented for the use of WISC-R Adjunctive tests. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1996
- Authors: Runciman, Carey Lynn
- Date: 1996 , 2013-10-03
- Subjects: Wechsler Intelligence Scale for Children -- Cross-cultural studies , Children -- Intelligence testing , Psychological tests -- Cross-cultural studies , Educational tests and measurements -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3150 , http://hdl.handle.net/10962/d1007467 , Wechsler Intelligence Scale for Children -- Cross-cultural studies , Children -- Intelligence testing , Psychological tests -- Cross-cultural studies , Educational tests and measurements -- South Africa
- Description: The purpose of this study was to compare the WISC-R subtest score scatter patterns and obtain preliminary normative data on the WISC-R Adjunctive tests (Digit Span Forward; Digit Span Backward; Digit Supraspan; Coding Immediate Recall and Coding Delayed Recall) on a non-clinical population of South African English (n= 15) and Xhosa (n= 12) speaking, standard six children, studying in English medium schools. Tests were administered to 27 subjects, both male (n=19) and female (n=8), with a mean age of 14.1 years (range = 13.3-15.3). The results show that White English speaking children outperform Black Xhosa speaking children on Verbal, Performance and Full Scale IQs and all subtests, but that these differences tended to disappear when Full Scale IQ and school grade average were controlled for. No subtest score scatter was present for either group although more specific test items appeared to be more difficult for Xhosa speaking subjects and may have contributed to generally lowered scores. Results suggest that caution must be employed in assigning Xhosa speaking South African children to absolute IQ categories. However, the WISC-R has validity for diagnostic use on both White English speaking and Black Xhosa speaking South African children as there was no evidence of a significant Verbal IQ/Performance IQ discrepancy, or significant low subtest scatter for either group. Normative tables are presented for the use of WISC-R Adjunctive tests. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 1996
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