Metallogenetic evolution of the Canadian Cordilleran Orogen
- Authors: Mathe, H L M
- Date: 1983
- Subjects: Orogeny -- Canadian Cordillera , Plate tectonics -- Canadian Cordillera , Metallogeny -- Canadian Cordillera , Geology, Structural -- Canadian Cordillera
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5025 , http://hdl.handle.net/10962/d1006890
- Description: From Introduction: The Canadian Cordilleran Orogenic Belt forms part of the circum-Pacific orogenic zone. It underlies an area of about 1,54 million sq. kilometres, is over 2400 kilometres long and 800 kilometres wide. The region is characteristically mountainous, much of it glaciated and alpine, containing plateaux, trenches, valleys, and fjords. The mountains, in general, rise to elevations between 2100 m and 3600 m above sea level, although Mount Logan in the St. Elias Mountains attains an altitude of 6000 m. The Canadian Cordillera is divided into two dominant orogenic belts: the eastern Columbian Orogenic Belt comprising defonned miogeosynclinal rocks and the western Pacific Orogenic Belt comprising allochthonous eugeosynclinal rocks. The Cordillera is further subdivided into five longitudinal tectonic belts within which rocks are broadly similar in type, age, and history. These belts are, from east to west: the Rocky Mountain Belt, the Omineca Crystalline Belt, the Intermontane Belt, the Coast Plutonic Complex, and the Insular Belt (Wheeler et al., 1972a). The Canadian Cordillera is important in that it contains: one of the world's largest lead-zinc-silver mine, Sullivan; the second-largest molybdenum mine, Endako; one of the most important concentrations of porphyry copper deposits, Highland Valley; Canada's largest tungsten mines, Cantung and Mactung; and Canada's second-largest silver district, Keno Hill (Sutherland Brown et a1., 1971). In addition, it contains several large massive sulphide and lead-zinc deposits.
- Full Text:
- Date Issued: 1983
- Authors: Mathe, H L M
- Date: 1983
- Subjects: Orogeny -- Canadian Cordillera , Plate tectonics -- Canadian Cordillera , Metallogeny -- Canadian Cordillera , Geology, Structural -- Canadian Cordillera
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5025 , http://hdl.handle.net/10962/d1006890
- Description: From Introduction: The Canadian Cordilleran Orogenic Belt forms part of the circum-Pacific orogenic zone. It underlies an area of about 1,54 million sq. kilometres, is over 2400 kilometres long and 800 kilometres wide. The region is characteristically mountainous, much of it glaciated and alpine, containing plateaux, trenches, valleys, and fjords. The mountains, in general, rise to elevations between 2100 m and 3600 m above sea level, although Mount Logan in the St. Elias Mountains attains an altitude of 6000 m. The Canadian Cordillera is divided into two dominant orogenic belts: the eastern Columbian Orogenic Belt comprising defonned miogeosynclinal rocks and the western Pacific Orogenic Belt comprising allochthonous eugeosynclinal rocks. The Cordillera is further subdivided into five longitudinal tectonic belts within which rocks are broadly similar in type, age, and history. These belts are, from east to west: the Rocky Mountain Belt, the Omineca Crystalline Belt, the Intermontane Belt, the Coast Plutonic Complex, and the Insular Belt (Wheeler et al., 1972a). The Canadian Cordillera is important in that it contains: one of the world's largest lead-zinc-silver mine, Sullivan; the second-largest molybdenum mine, Endako; one of the most important concentrations of porphyry copper deposits, Highland Valley; Canada's largest tungsten mines, Cantung and Mactung; and Canada's second-largest silver district, Keno Hill (Sutherland Brown et a1., 1971). In addition, it contains several large massive sulphide and lead-zinc deposits.
- Full Text:
- Date Issued: 1983
Cognitive behavioural treatment of chronic fatigue syndrome: an in-depth case study
- Authors: Rusch, Mary L
- Date: 2001
- Subjects: Chronic fatigue syndrome , Chronic fatigue syndrome -- Psychological aspects , Chronic fatigue syndrome -- Exercise therapy , Chronic fatigue syndrome -- Treatment
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3046 , http://hdl.handle.net/10962/d1002555
- Description: Chronic Fatigue Syndrome (CFS) is a chronic disabling condition characterised by persistent physical and mental fatigue, and a variety of somatic, psychological and neurological symptoms. The aetiology of CFS is unknown and the cause of the illness remains controversial. Cognitive-behavioural therapy (CBT) is a non-pharmacological treatment approach that has been shown to be effective in treating patients with CFS. It is based on a model that hypothesises that certain maladaptive thoughts and dysfunctional beliefs may contribute to self-defeating behaviour that perpetuates symptoms and disability, and thereby impedes recovery. The main aim of this study was to critically examine the cognitive-behavioural approach of CFS outlined by Sharpe, Chalder, Palmer & Wessely (1997) by conducting three in-depth case studies. An additional aim was to present a full cognitive developmental case conceptualisation of CFS based on the theories of Leahy (1996) and Young (1994). This case study evaluated the effectiveness of a CBT treatment programme in a 48-year-old Caucasian woman diagnosed with CFS for three years. The treatment consisted of sixteen sessions of CBT and was evaluated both quantitatively and qualitatively. On the basis of this study, a set of core maladaptive schema in the area of disconnection and rejection was identified. In addition, it was found that specific compensatory schemas had developed to offset the core maladaptive schemas and that this compensatory strategy played an important role in maintaining the condition. The results also showed a significant decline in fatigue coupled with a moderate decline in functional disability and depression. A one-month follow-up interview revealed evidence of a substantial consolidation of therapeutic gains in that the improvements observed at the end of the treatment were sustained. Finally, the feasibility of incorporating a cognitive-developmental and/or schema-focused model into the standard CBT treatment model is discussed and the case study method as a research toll is evaluated in light of the findings.
- Full Text:
- Date Issued: 2001
- Authors: Rusch, Mary L
- Date: 2001
- Subjects: Chronic fatigue syndrome , Chronic fatigue syndrome -- Psychological aspects , Chronic fatigue syndrome -- Exercise therapy , Chronic fatigue syndrome -- Treatment
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3046 , http://hdl.handle.net/10962/d1002555
- Description: Chronic Fatigue Syndrome (CFS) is a chronic disabling condition characterised by persistent physical and mental fatigue, and a variety of somatic, psychological and neurological symptoms. The aetiology of CFS is unknown and the cause of the illness remains controversial. Cognitive-behavioural therapy (CBT) is a non-pharmacological treatment approach that has been shown to be effective in treating patients with CFS. It is based on a model that hypothesises that certain maladaptive thoughts and dysfunctional beliefs may contribute to self-defeating behaviour that perpetuates symptoms and disability, and thereby impedes recovery. The main aim of this study was to critically examine the cognitive-behavioural approach of CFS outlined by Sharpe, Chalder, Palmer & Wessely (1997) by conducting three in-depth case studies. An additional aim was to present a full cognitive developmental case conceptualisation of CFS based on the theories of Leahy (1996) and Young (1994). This case study evaluated the effectiveness of a CBT treatment programme in a 48-year-old Caucasian woman diagnosed with CFS for three years. The treatment consisted of sixteen sessions of CBT and was evaluated both quantitatively and qualitatively. On the basis of this study, a set of core maladaptive schema in the area of disconnection and rejection was identified. In addition, it was found that specific compensatory schemas had developed to offset the core maladaptive schemas and that this compensatory strategy played an important role in maintaining the condition. The results also showed a significant decline in fatigue coupled with a moderate decline in functional disability and depression. A one-month follow-up interview revealed evidence of a substantial consolidation of therapeutic gains in that the improvements observed at the end of the treatment were sustained. Finally, the feasibility of incorporating a cognitive-developmental and/or schema-focused model into the standard CBT treatment model is discussed and the case study method as a research toll is evaluated in light of the findings.
- Full Text:
- Date Issued: 2001
The antecedents of customer satisfaction in a financial institution : a qualitative study
- Authors: Bleske, Adrian
- Date: 2008
- Subjects: Standard Bank Properties , Banks and banking -- South Africa , Banks and banking -- Customer services -- South Africa , Financial services industry -- South Africa , Bank management -- South Africa , Banks and banking -- Customer services -- Effect of marketing on
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:840 , http://hdl.handle.net/10962/d1015482
- Description: The following is a case study report on the Cape Town business unit of Standard Bank Properties. The research project falls within the ambit of services marketing which introduces several unique management challenges for service businesses that sell services as a core offering. The principal aim of the case study is to gain an understanding of why customers bank at the business unit and to discover what aspects are critical to customer satisfaction. A further goal of the research is to examine how the business unit could improve customer satisfaction and to highlight any impediments to further improving customer satisfaction at the business unit. It is generally regarded that quality customer service is essential to building customer relationships and hence the research project emphasis on services marketing and customer satisfaction within a financial services context. The paper commences with an overview of the South African Banking Sector and its unique challenges such as the Financial Service Charter and newly introduced legislation such as Financial Intelligence Centre Act. The case study will specifically investigate the property finance industry and a detailed analysis of the business unit's operations and process flow will also be undertaken. The reason for this background information is to assist the reader to understand how the business unit operates. The research project will investigate four unique differences between goods marketing and services marketing whereafter three theoretical propositions are introduced, namely the dyadic interaction and service encounter, the Service Profit Chain and finally Relationship Marketing. Evidence in the form of a narrative will be led from insights obtained from interviews conducted with customers and staff at the business unit against these propositions with support (or otherwise) from independent surveys and documents from the business unit. The result of this analysis is the identification of several areas of concern specifically: New employees and the service encounter, Problems with FICA, Lack of a customer complaint handling system, Empowerment issues, Turnaround times, Reliance on key staff These insights together with the evidence from the literature review will be analysed and several recommendations made to improve customer service and ultimately customer satisfaction at the business unit. Several recommendations for further research are offered as well as the identification of limitations including but not limited to the specificity of the case study report.
- Full Text:
- Date Issued: 2008
- Authors: Bleske, Adrian
- Date: 2008
- Subjects: Standard Bank Properties , Banks and banking -- South Africa , Banks and banking -- Customer services -- South Africa , Financial services industry -- South Africa , Bank management -- South Africa , Banks and banking -- Customer services -- Effect of marketing on
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:840 , http://hdl.handle.net/10962/d1015482
- Description: The following is a case study report on the Cape Town business unit of Standard Bank Properties. The research project falls within the ambit of services marketing which introduces several unique management challenges for service businesses that sell services as a core offering. The principal aim of the case study is to gain an understanding of why customers bank at the business unit and to discover what aspects are critical to customer satisfaction. A further goal of the research is to examine how the business unit could improve customer satisfaction and to highlight any impediments to further improving customer satisfaction at the business unit. It is generally regarded that quality customer service is essential to building customer relationships and hence the research project emphasis on services marketing and customer satisfaction within a financial services context. The paper commences with an overview of the South African Banking Sector and its unique challenges such as the Financial Service Charter and newly introduced legislation such as Financial Intelligence Centre Act. The case study will specifically investigate the property finance industry and a detailed analysis of the business unit's operations and process flow will also be undertaken. The reason for this background information is to assist the reader to understand how the business unit operates. The research project will investigate four unique differences between goods marketing and services marketing whereafter three theoretical propositions are introduced, namely the dyadic interaction and service encounter, the Service Profit Chain and finally Relationship Marketing. Evidence in the form of a narrative will be led from insights obtained from interviews conducted with customers and staff at the business unit against these propositions with support (or otherwise) from independent surveys and documents from the business unit. The result of this analysis is the identification of several areas of concern specifically: New employees and the service encounter, Problems with FICA, Lack of a customer complaint handling system, Empowerment issues, Turnaround times, Reliance on key staff These insights together with the evidence from the literature review will be analysed and several recommendations made to improve customer service and ultimately customer satisfaction at the business unit. Several recommendations for further research are offered as well as the identification of limitations including but not limited to the specificity of the case study report.
- Full Text:
- Date Issued: 2008
Towards a corpus of Indian South African English (ISAE) : an investigation of lexical and syntactic features in a spoken corpus of contemporary ISAE
- Authors: Pienaar, Cheryl Leelavathie
- Date: 2008
- Subjects: English language -- South Africa Computational linguistics -- Methodology Discourse analysis -- Data processing English language -- Syntax -- South Africa English language -- Usage -- South Africa East Indians -- South Africa -- Language Lexicology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2357 , http://hdl.handle.net/10962/d1002640
- Description: There is consensus among scholars that there is not just one English language but a family of “World Englishes”. The umbrella-term “World Englishes” provides a conceptual framework to accommodate the different varieties of English that have evolved as a result of the linguistic cross-fertilization attendant upon colonization, migration, trade and transplantation of the original “strain” or variety. Various theoretical models have emerged in an attempt to understand and classify the extant and emerging varieties of this global language. The hierarchically based model of English, which classifies world English as “First Language”, “Second Language” and “Foreign Language”, has been challenged by more equitably-conceived models which refer to the emerging varieties as New Englishes. The situation in a country such as multi-lingual South Africa is a complex one: there are 11 official languages, one of which is English. However the English used in South Africa (or “South African English”), is not a homogeneous variety, since its speakers include those for whom it is a first language, those for whom it is an additional language and those for whom it is a replacement language. The Indian population in South Africa are amongst the latter group, as theirs is a case where English has ousted the traditional Indian languages and become a de facto first language, which has retained strong community resonances. This study was undertaken using the methodology of corpus linguistics to initiate the creation of a repository of linguistic evidence (or corpus), of Indian South African English, a sub-variety of South African English (Mesthrie 1992b, 1996, 2002). Although small (approximately 60 000 words), and representing a narrow age band of young adults, the resulting corpus of spoken data confirmed the existence of robust features identified in prior research into the sub-variety. These features include the use of ‘y’all’ as a second person plural pronoun, the use of but in a sentence-final position, and ‘lakker’ /'lVk@/ as a pronunciation variant of ‘lekker’ (meaning ‘good’, ‘nice’ or great’). An examination of lexical frequency lists revealed examples of general South African English such as the colloquially pervasive ‘ja’, ‘bladdy’ (for bloody) and jol(ling) (for partying or enjoying oneself) together with neologisms such as ‘eish’, the latter previously associated with speakers of Black South African English. The frequency lists facilitated cross-corpora comparisons with data from the British National Corpus and the Corpus of London Teenage Language and similarities and differences were noted and discussed. The study also used discourse analysis frameworks to investigate the role of high frequency lexical items such as ‘like’ in the data. In recent times ‘like’ has emerged globally as a lexicalized discourse marker, and its appearance in the corpus of Indian South African English confirms this trend. The corpus built as part of this study is intended as the first building block towards a full corpus of Indian South African English which could serve as a standard for referencing research into the sub-variety. Ultimately, it is argued that the establishment of similar corpora of other known sub-varieties of South African English could contribute towards the creation of a truly representative large corpus of South African English and a more nuanced understanding and definition of this important variety of World English.
- Full Text:
- Date Issued: 2008
- Authors: Pienaar, Cheryl Leelavathie
- Date: 2008
- Subjects: English language -- South Africa Computational linguistics -- Methodology Discourse analysis -- Data processing English language -- Syntax -- South Africa English language -- Usage -- South Africa East Indians -- South Africa -- Language Lexicology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2357 , http://hdl.handle.net/10962/d1002640
- Description: There is consensus among scholars that there is not just one English language but a family of “World Englishes”. The umbrella-term “World Englishes” provides a conceptual framework to accommodate the different varieties of English that have evolved as a result of the linguistic cross-fertilization attendant upon colonization, migration, trade and transplantation of the original “strain” or variety. Various theoretical models have emerged in an attempt to understand and classify the extant and emerging varieties of this global language. The hierarchically based model of English, which classifies world English as “First Language”, “Second Language” and “Foreign Language”, has been challenged by more equitably-conceived models which refer to the emerging varieties as New Englishes. The situation in a country such as multi-lingual South Africa is a complex one: there are 11 official languages, one of which is English. However the English used in South Africa (or “South African English”), is not a homogeneous variety, since its speakers include those for whom it is a first language, those for whom it is an additional language and those for whom it is a replacement language. The Indian population in South Africa are amongst the latter group, as theirs is a case where English has ousted the traditional Indian languages and become a de facto first language, which has retained strong community resonances. This study was undertaken using the methodology of corpus linguistics to initiate the creation of a repository of linguistic evidence (or corpus), of Indian South African English, a sub-variety of South African English (Mesthrie 1992b, 1996, 2002). Although small (approximately 60 000 words), and representing a narrow age band of young adults, the resulting corpus of spoken data confirmed the existence of robust features identified in prior research into the sub-variety. These features include the use of ‘y’all’ as a second person plural pronoun, the use of but in a sentence-final position, and ‘lakker’ /'lVk@/ as a pronunciation variant of ‘lekker’ (meaning ‘good’, ‘nice’ or great’). An examination of lexical frequency lists revealed examples of general South African English such as the colloquially pervasive ‘ja’, ‘bladdy’ (for bloody) and jol(ling) (for partying or enjoying oneself) together with neologisms such as ‘eish’, the latter previously associated with speakers of Black South African English. The frequency lists facilitated cross-corpora comparisons with data from the British National Corpus and the Corpus of London Teenage Language and similarities and differences were noted and discussed. The study also used discourse analysis frameworks to investigate the role of high frequency lexical items such as ‘like’ in the data. In recent times ‘like’ has emerged globally as a lexicalized discourse marker, and its appearance in the corpus of Indian South African English confirms this trend. The corpus built as part of this study is intended as the first building block towards a full corpus of Indian South African English which could serve as a standard for referencing research into the sub-variety. Ultimately, it is argued that the establishment of similar corpora of other known sub-varieties of South African English could contribute towards the creation of a truly representative large corpus of South African English and a more nuanced understanding and definition of this important variety of World English.
- Full Text:
- Date Issued: 2008
Synthesis, photochemical and photophysical properties of gallium and indium phthalocyanine derivatives
- Authors: Chauke, Vongani Portia
- Date: 2008
- Subjects: Phthalocyanines , Photochemotherapy , Electrochemistry , Gallium , Indium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4375 , http://hdl.handle.net/10962/d1005040 , Phthalocyanines , Photochemotherapy , Electrochemistry , Gallium , Indium
- Description: The syntheses of octasubstituted and unsusbstitituted Gallium(III) chloride and indium(III) chloride phthalocyanines (GaPc and InPc), their photophysical, photochemical and nonlinear optical parameters are hereby presented. The photocatalytic oxidation of 1-hexene using the synthesized GaPc and InPc complexes as well as electrochemical characterization is also presented in this thesis. Fluorescence quantum yields do not vary much among the four Ga complexes, except for complex 21c; therefore it was concluded that the effect of substituents is not significant among them. Solvents however, had an effect on the results. Lower Φ[subscript F] values were obtained in low viscosity solvents like toluene, relative to highly viscous solvents, such as DMSO. The triplet quantum yields were found to be lower in DMSO than in DMF and toluene. The rate constants for fluorescence, intersystem crossing and internal conversion as well as fluorescence and triplet lifetimes are reported. Photodegradation and singlet oxygen quantum yields have also been reported. There was no clear correlation between the latter parameters. It was however established that the four gallium MPcs were stable, within the allowed stability range for phthalocyanines. High quantum yields of triplet state (Φ[subscript T] ranging from 0.70 to 0.91 in dimethysulfoxide, DMSO) and singlet oxygen generation (Φ[subscript greek capital letter delta], ranging from 0.61 to 0.79 in DMSO) were obtained. Short triplet lifetimes 50 to 60 μs were obtained in DMSO). Calculated non-linear parameters of these complexes are compared with those of the corresponding GaPc derivatives and tetrasubstituted GaPc and InPc complexes. The optical limiting threshold intensity (I[subscript lim]) values for the InPc and GaPc derivatives were calculated and compared with those of corresponding tetrasubstituted InPc and GaPc complexes. The octasubstituted were found to be better optical limiters. Photocatalytic oxidation of 1-hexene by GaPc (21a-c) and InPc (22a-c) derivatives is also presented. The photocatalytic oxidation products for 1-hexene were 1,2- epoxyhexane and 1-hexen-3-ol. The % conversion values of 1-hexene and % selectivity of 1,2-epoxyhexane were generally higher for InPc derivatives. Even though InPc derivatives showed better photocatalytic results than GaPc derivatives, the former were less stable relative to the latter. Both type I and type II mechanism were implicated in the photocatalysis mechanism.
- Full Text:
- Date Issued: 2008
- Authors: Chauke, Vongani Portia
- Date: 2008
- Subjects: Phthalocyanines , Photochemotherapy , Electrochemistry , Gallium , Indium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4375 , http://hdl.handle.net/10962/d1005040 , Phthalocyanines , Photochemotherapy , Electrochemistry , Gallium , Indium
- Description: The syntheses of octasubstituted and unsusbstitituted Gallium(III) chloride and indium(III) chloride phthalocyanines (GaPc and InPc), their photophysical, photochemical and nonlinear optical parameters are hereby presented. The photocatalytic oxidation of 1-hexene using the synthesized GaPc and InPc complexes as well as electrochemical characterization is also presented in this thesis. Fluorescence quantum yields do not vary much among the four Ga complexes, except for complex 21c; therefore it was concluded that the effect of substituents is not significant among them. Solvents however, had an effect on the results. Lower Φ[subscript F] values were obtained in low viscosity solvents like toluene, relative to highly viscous solvents, such as DMSO. The triplet quantum yields were found to be lower in DMSO than in DMF and toluene. The rate constants for fluorescence, intersystem crossing and internal conversion as well as fluorescence and triplet lifetimes are reported. Photodegradation and singlet oxygen quantum yields have also been reported. There was no clear correlation between the latter parameters. It was however established that the four gallium MPcs were stable, within the allowed stability range for phthalocyanines. High quantum yields of triplet state (Φ[subscript T] ranging from 0.70 to 0.91 in dimethysulfoxide, DMSO) and singlet oxygen generation (Φ[subscript greek capital letter delta], ranging from 0.61 to 0.79 in DMSO) were obtained. Short triplet lifetimes 50 to 60 μs were obtained in DMSO). Calculated non-linear parameters of these complexes are compared with those of the corresponding GaPc derivatives and tetrasubstituted GaPc and InPc complexes. The optical limiting threshold intensity (I[subscript lim]) values for the InPc and GaPc derivatives were calculated and compared with those of corresponding tetrasubstituted InPc and GaPc complexes. The octasubstituted were found to be better optical limiters. Photocatalytic oxidation of 1-hexene by GaPc (21a-c) and InPc (22a-c) derivatives is also presented. The photocatalytic oxidation products for 1-hexene were 1,2- epoxyhexane and 1-hexen-3-ol. The % conversion values of 1-hexene and % selectivity of 1,2-epoxyhexane were generally higher for InPc derivatives. Even though InPc derivatives showed better photocatalytic results than GaPc derivatives, the former were less stable relative to the latter. Both type I and type II mechanism were implicated in the photocatalysis mechanism.
- Full Text:
- Date Issued: 2008
The visual communication of environmental awareness issues in Jeff Orlowski's,Chasing Ice (2012) and Yann Arthurs -Bertrand's home (2009)
- Authors: Van der Walt, Nadia Elize
- Date: 2018
- Subjects: Visual communication , Environmentalism in motion pictures Documentary films -- History and critism
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/45547 , vital:38665
- Description: This study presents an investigation into the visual communication complexities within the genre of documentary film, specifically aimed at the development of a set of criteria of cinematic techniques for the visual communication of environmental awareness issues. This process utilises a theoretical approach to understanding the development and communicative possibilities of documentary film, as well as an analytical interpretation structured on semiotic film theory. The theoretical investigation reveals Bill Nichols’ (2010) documentary modes as an established analytical model. This study engages with four of Nichols’ six modes – namely, the poetic, the expository, the observational and the participatory modes, as the criteria for the extraction of scenes and/or images from Chasing Ice (2012) by Jeff Orlowski and Home (2009) by Yann Arthurs-Bertrand. Once Nichols’ modes have been identified, a semiotic reading is conducted. Gillian Rose’s (2016) visual analysis framework underpinned by Pieter J. Fourie’s (1988) sociological approach to film analysis, is utilised to read the selected film texts. A comparative analysis of Chasing Ice (2012) and Home (2009) reveals that the inclusion of different and multiple modes constructs the visualisation of environmental awareness issues in the documentary film genre. The cinematic techniques specific to the documentary modes represented in Chasing Ice (2012) and Home (2009) are appropriated in the construction of three film shorts within the researcher’s documentary film study, Karoo (2017). This combination of theory and practice yields the researcher a considered and informed approach to constructing documentary imagery aimed at visualising the current environment of the Karoo Basin prior to the possibility of shale gas exploration and/or exploitation.
- Full Text:
- Date Issued: 2018
- Authors: Van der Walt, Nadia Elize
- Date: 2018
- Subjects: Visual communication , Environmentalism in motion pictures Documentary films -- History and critism
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/45547 , vital:38665
- Description: This study presents an investigation into the visual communication complexities within the genre of documentary film, specifically aimed at the development of a set of criteria of cinematic techniques for the visual communication of environmental awareness issues. This process utilises a theoretical approach to understanding the development and communicative possibilities of documentary film, as well as an analytical interpretation structured on semiotic film theory. The theoretical investigation reveals Bill Nichols’ (2010) documentary modes as an established analytical model. This study engages with four of Nichols’ six modes – namely, the poetic, the expository, the observational and the participatory modes, as the criteria for the extraction of scenes and/or images from Chasing Ice (2012) by Jeff Orlowski and Home (2009) by Yann Arthurs-Bertrand. Once Nichols’ modes have been identified, a semiotic reading is conducted. Gillian Rose’s (2016) visual analysis framework underpinned by Pieter J. Fourie’s (1988) sociological approach to film analysis, is utilised to read the selected film texts. A comparative analysis of Chasing Ice (2012) and Home (2009) reveals that the inclusion of different and multiple modes constructs the visualisation of environmental awareness issues in the documentary film genre. The cinematic techniques specific to the documentary modes represented in Chasing Ice (2012) and Home (2009) are appropriated in the construction of three film shorts within the researcher’s documentary film study, Karoo (2017). This combination of theory and practice yields the researcher a considered and informed approach to constructing documentary imagery aimed at visualising the current environment of the Karoo Basin prior to the possibility of shale gas exploration and/or exploitation.
- Full Text:
- Date Issued: 2018
Electrospun fiber based colorimetric probes for aspartate aminotransferase and I7ß-estradiol
- Authors: Pule, Bellah Oreeditse
- Date: 2014
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/54869 , vital:26623
- Description: Fabrication, characterization and application of electrospun polymer composite based colorimetric probes are presented in this thesis. The first part of the thesis involved the development of a protocol for in situ reduction of gold trication (Au³+) into metallic gold atoms with sodium borohydride. The prepared PS-Au NPs showed an SPR band at 542 nm. Furthermore the absorbance of the colloidal Au NPs in polystyrene exhibited a good linear correlation (r2 = 0.9934) to E2 concentration in the range 5 to 50 ppb. The lowest naked eye detection limit was found to be 0.5 ppb and could further be easily monitored by UV-vis spectrophotometer. Upon interaction with E2 Au NPs aggregated to give nanoparticle clusters, confirmed through TEM analysis. Different concentrations of Au NPs were found to have a significant effect on the conductivity of the PS-Au NPs solution. At low concentrations of Au NPs (0.002, 0.015 and 0.025% w/v) PS-Au NPs solution could be electrospun without clogging. The FE-SEM images showed a non-beaded morphology of PS-Au NPs composite fibers. Upon interaction of the colorimetric probe strips with various E2 concentrations it was observed that with increasing E2 concentrations (50 ng/ml to 1000 µg/ml) the colour of the probe changed gradually from white to shades of pink and eventually to shades of blue at higher E2 concentrations. The visible cut-off concentration was 100 ng/ml. The second component of the thesis focussed on the development of diazonium dye-nylon 6 colorimetric probe for aspartate aminotransferase. At optimal pH 7.4 the enzyme was stable, highly active and catalyzed a reaction that was susceptible to detailed kinetic analysis by continuous optical methods. The KM values for L-aspartate, a- ketoglutarate and oxaloacetate were 2.60, 0.59 and 0.066 mM, respectively. On the basis of these KM values the solid-state colorimetric probe was developed. A colour change occurred when an electrospun dye-N 6 probes were exposed to visibly detectable concentrations of oxaloacetate, an AST-catalyzed reaction product. While monitoring AST activity at 530 run, a linear relation was obtained between oxaloacetate concentrations ranging from 0.4 - 7.4 µg/ml. Naked eye detection limit of 2.4 µg/ml oxalaoacetate equivalence of 10 times the normal AST activity was attained. The colorimetric probe was in addition, tested against co-substrates aspartate, ketoglutarate and a variety of other compounds such as alanine, pryruvate, as well as glutamic, malaic and succinic acids known to interfere with AST activity. Each compound elicited a distinct and unambiguous colour change upon interaction with the colorimetric probe. Further X-ray powder diffraction (XRD), duNouy ring tensiometer, Brunauer- Emmett- Teller (BET) and energy dispersive X-ray spectroscopy (EDS/EDX) characterization confirmed composition and stability of the colorimetric probes. Colorimetric probes developed in this thesis are relatively cost effective, simple and "rugged" for measurement of analytes with visual detection without sample pretreatment in matrices, such as plasma and dairy effluents. The probes warrant further investigation as they have shown potential and offer a promising solid-state platform for both clinical diagnostics and environmental monitoring.
- Full Text:
- Date Issued: 2014
- Authors: Pule, Bellah Oreeditse
- Date: 2014
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/54869 , vital:26623
- Description: Fabrication, characterization and application of electrospun polymer composite based colorimetric probes are presented in this thesis. The first part of the thesis involved the development of a protocol for in situ reduction of gold trication (Au³+) into metallic gold atoms with sodium borohydride. The prepared PS-Au NPs showed an SPR band at 542 nm. Furthermore the absorbance of the colloidal Au NPs in polystyrene exhibited a good linear correlation (r2 = 0.9934) to E2 concentration in the range 5 to 50 ppb. The lowest naked eye detection limit was found to be 0.5 ppb and could further be easily monitored by UV-vis spectrophotometer. Upon interaction with E2 Au NPs aggregated to give nanoparticle clusters, confirmed through TEM analysis. Different concentrations of Au NPs were found to have a significant effect on the conductivity of the PS-Au NPs solution. At low concentrations of Au NPs (0.002, 0.015 and 0.025% w/v) PS-Au NPs solution could be electrospun without clogging. The FE-SEM images showed a non-beaded morphology of PS-Au NPs composite fibers. Upon interaction of the colorimetric probe strips with various E2 concentrations it was observed that with increasing E2 concentrations (50 ng/ml to 1000 µg/ml) the colour of the probe changed gradually from white to shades of pink and eventually to shades of blue at higher E2 concentrations. The visible cut-off concentration was 100 ng/ml. The second component of the thesis focussed on the development of diazonium dye-nylon 6 colorimetric probe for aspartate aminotransferase. At optimal pH 7.4 the enzyme was stable, highly active and catalyzed a reaction that was susceptible to detailed kinetic analysis by continuous optical methods. The KM values for L-aspartate, a- ketoglutarate and oxaloacetate were 2.60, 0.59 and 0.066 mM, respectively. On the basis of these KM values the solid-state colorimetric probe was developed. A colour change occurred when an electrospun dye-N 6 probes were exposed to visibly detectable concentrations of oxaloacetate, an AST-catalyzed reaction product. While monitoring AST activity at 530 run, a linear relation was obtained between oxaloacetate concentrations ranging from 0.4 - 7.4 µg/ml. Naked eye detection limit of 2.4 µg/ml oxalaoacetate equivalence of 10 times the normal AST activity was attained. The colorimetric probe was in addition, tested against co-substrates aspartate, ketoglutarate and a variety of other compounds such as alanine, pryruvate, as well as glutamic, malaic and succinic acids known to interfere with AST activity. Each compound elicited a distinct and unambiguous colour change upon interaction with the colorimetric probe. Further X-ray powder diffraction (XRD), duNouy ring tensiometer, Brunauer- Emmett- Teller (BET) and energy dispersive X-ray spectroscopy (EDS/EDX) characterization confirmed composition and stability of the colorimetric probes. Colorimetric probes developed in this thesis are relatively cost effective, simple and "rugged" for measurement of analytes with visual detection without sample pretreatment in matrices, such as plasma and dairy effluents. The probes warrant further investigation as they have shown potential and offer a promising solid-state platform for both clinical diagnostics and environmental monitoring.
- Full Text:
- Date Issued: 2014
From labour reserve to investment opportunity: economic development planning in the Mbashe Local Municipal area in the Eastern Cape
- Authors: Reynolds, John Hunter
- Date: 2003
- Subjects: Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , South Africa -- Economic policy , Planning -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3353 , http://hdl.handle.net/10962/d1007490 , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , South Africa -- Economic policy , Planning -- South Africa -- Eastern Cape
- Description: Planning for economic development at the local level has become increasingly important in many countries of the world. South Africa is no exception and has had the local focus entrenched through constitutional provisions for developmental local government. This developmental approach has been intimately linked to, and influenced by, the broader legislative, policy and planning context within which the development challenges of post-Apartheid South Africa have been addressed. It has also been implemented in a context of far-reaching transformation of public institutions aimed, in the final analysis, at the effective functioning of three spheres of government. In this thesis, the Mbashe Local Municipal area is used as a case study for an examination of the linkages between economic development planning at the local, provincial and national levels. It is not a case study in the sense that an in-depth analysis of practice is undertaken; it is used rather as a lens through which the economic development planning activities of the three spheres of government are viewed. Its value as a lens lies in its location in the former Transkei, which is characterised by high levels of unemployment and poverty and low levels of service infrastructure, and in its status as one of the newly demarcated local municipalities in South Africa. Mbashe is a pilot site of the Promotion of Rural Livelihoods Programme, which has been linked to the Eastern Cape Province's Integrated Sustainable Rural Development Programme. It also includes one of the nodes of the Wild Coast Spatial Development Initiative, which has, since 1998, been promoted as a vehicle for economic development in the former Transkei. Research comprised extensive documentary research, individual interviews with key role players in the Mbashe Local Municipality, the Promotion of Rural Livelihoods Programme and the Wild Coast Spatial Development Initiative, and a group interview with members of the Local Economic Development Sub-Committee of the Mbashe Local Municipal Council. An attempt was made to understand the complex layers of policy and planning frameworks that guide planning at the national and provincial levels and within which local level economic development is situated, and to explore the responses that have been forged by agents within the Mbashe area. Key in this endeavour has been the initiatives developed under the guidance of the Mbashe Local Economic Development Sub-Committee. It is argued that the severe resource constraints faced within Mbashe, combined with limited knowledge of and participation in larger planning and resource mobilisation frameworks, lock Local Economic Development within the top-down and investmentled approaches, rather than the more integrated approach that is promoted in terms of legislation and that is required if poverty is to be addressed successfully. The limitations on state fiscal expenditure and the market-led approach to service provision and economic development, implemented in terms of South Africa's macroeconomic framework, combined with limited synchronisation of planning cycles in which integrated development planning at the local level is privileged, leave little scope for endogenous economic development at local level. There is scope for creative engagement with the interlocking local, provincial, national and continental economies by actively shifting resources in support of integrated, endogenous approaches. Such approaches could serve as counter-narratives to the dominance of neoliberalism and allow for the establishment of local economic development practice that addresses the needs of the poor and that builds integrated local economies under the control of democratic institutions. It is only with such a shifting of approach that economic development within Mbashe will shift the structural conditions that lock it into economic dependence and poverty.
- Full Text:
- Date Issued: 2003
- Authors: Reynolds, John Hunter
- Date: 2003
- Subjects: Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , South Africa -- Economic policy , Planning -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3353 , http://hdl.handle.net/10962/d1007490 , Economic development -- South Africa -- Eastern Cape , Community development -- South Africa -- Eastern Cape , South Africa -- Economic policy , Planning -- South Africa -- Eastern Cape
- Description: Planning for economic development at the local level has become increasingly important in many countries of the world. South Africa is no exception and has had the local focus entrenched through constitutional provisions for developmental local government. This developmental approach has been intimately linked to, and influenced by, the broader legislative, policy and planning context within which the development challenges of post-Apartheid South Africa have been addressed. It has also been implemented in a context of far-reaching transformation of public institutions aimed, in the final analysis, at the effective functioning of three spheres of government. In this thesis, the Mbashe Local Municipal area is used as a case study for an examination of the linkages between economic development planning at the local, provincial and national levels. It is not a case study in the sense that an in-depth analysis of practice is undertaken; it is used rather as a lens through which the economic development planning activities of the three spheres of government are viewed. Its value as a lens lies in its location in the former Transkei, which is characterised by high levels of unemployment and poverty and low levels of service infrastructure, and in its status as one of the newly demarcated local municipalities in South Africa. Mbashe is a pilot site of the Promotion of Rural Livelihoods Programme, which has been linked to the Eastern Cape Province's Integrated Sustainable Rural Development Programme. It also includes one of the nodes of the Wild Coast Spatial Development Initiative, which has, since 1998, been promoted as a vehicle for economic development in the former Transkei. Research comprised extensive documentary research, individual interviews with key role players in the Mbashe Local Municipality, the Promotion of Rural Livelihoods Programme and the Wild Coast Spatial Development Initiative, and a group interview with members of the Local Economic Development Sub-Committee of the Mbashe Local Municipal Council. An attempt was made to understand the complex layers of policy and planning frameworks that guide planning at the national and provincial levels and within which local level economic development is situated, and to explore the responses that have been forged by agents within the Mbashe area. Key in this endeavour has been the initiatives developed under the guidance of the Mbashe Local Economic Development Sub-Committee. It is argued that the severe resource constraints faced within Mbashe, combined with limited knowledge of and participation in larger planning and resource mobilisation frameworks, lock Local Economic Development within the top-down and investmentled approaches, rather than the more integrated approach that is promoted in terms of legislation and that is required if poverty is to be addressed successfully. The limitations on state fiscal expenditure and the market-led approach to service provision and economic development, implemented in terms of South Africa's macroeconomic framework, combined with limited synchronisation of planning cycles in which integrated development planning at the local level is privileged, leave little scope for endogenous economic development at local level. There is scope for creative engagement with the interlocking local, provincial, national and continental economies by actively shifting resources in support of integrated, endogenous approaches. Such approaches could serve as counter-narratives to the dominance of neoliberalism and allow for the establishment of local economic development practice that addresses the needs of the poor and that builds integrated local economies under the control of democratic institutions. It is only with such a shifting of approach that economic development within Mbashe will shift the structural conditions that lock it into economic dependence and poverty.
- Full Text:
- Date Issued: 2003
Determination of the optimum environmental requirements of juvenile marine fish : the development of a protocol
- Authors: Deacon, Neil
- Date: 1997
- Subjects: Mariculture Fishes -- Ecology Grunts (Fishes) -- Ecology Pomadasys -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5254 , http://hdl.handle.net/10962/d1005097
- Description: The spotted grunter, Pomodasys commersonnii, has been identified as a candidate species for mariculture in South Africa due to its high market demand and apparent biological suitability for culture. In common with most other potential mariculture species the spotted grunter has an estuarine juvenile phase. In this respect, the difficulties encountered in determining the optimum environmental requirements of spotted grunter are applicable to the majority of other potential mariculture species. Due the variability of estuarine habitats determination of the optimum environmental requirements of estuarine species under laboratory conditions are a prerequisite to subsequent evaluation of aquaculture potential. Therefore, using the spotted grunter as a representative of a typical potent ial mariculture species, the aim of this study was to contribute to the protocol for evaluating the environmental requirements of potential aquaculture species. The growth of fish is dependent on the relationship between food intake, metabolism and environmental factors. In this relationship, environmental factors do not act on growth per se, but rather act through metabolism on growth. Consequently, the environmental factors affecting the growth of a fish species can be classified into functional categories according to their respective influence on metabolic processes. Five functional categories are recognised, namely: controlling, limiting, masking, directive and lethal factors. In this study, the functional categories were sequenced to develop a theoretical protocol for determining the optimum environmental requirements of potential mariculture species under artificial conditions. It was hypothesised that the correct sequence for experimentally determining the optimum environmental requirements of a species should correspond to theoretical protocol. The hypothesis was tested from the experimental investigation into the individual effects of temperature, salinity, light intensity, photoperiod and food intake on growth performance of juvenile spotted grunter. The investigations quantified the relative effects of controlling, masking, directive and limiting factors on growth performance. The results of the studies were statistically compared to obtain a ranking of the effects of the environmental factors (e.g. temperature, salinity, etc.) on growth performance of juvenile spotted grunter. The statistical ranking facilitated the formulation of a second protocol for sequentially determining the optimum environmental requirements of a species. The second protocol was derived purely from the experimental data. Based on the corroboration between the theoretical protocol and that formulated from the experimental investigations, the hypothesis was accepted. Confirmation of the protocol for examining the effects of controlling, limiting, masking and directive factors provided a basis for the development of a preliminary experimental sequence for determining the optimum environmental requirements of juvenile marine fish. In the development of the experimental sequence, the protocol was interpreted in conjunction with the experimental methods used to determine the effects of environmental factors on the growth of juvenile spotted grunter. The experimental sequence provides a logical frame work within which the optimum environmental requirements of other marine fish species can be determined. In addition, evaluation of growth performance by this method provides a basis for comparison of the mariculture potential between species.
- Full Text:
- Date Issued: 1997
- Authors: Deacon, Neil
- Date: 1997
- Subjects: Mariculture Fishes -- Ecology Grunts (Fishes) -- Ecology Pomadasys -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5254 , http://hdl.handle.net/10962/d1005097
- Description: The spotted grunter, Pomodasys commersonnii, has been identified as a candidate species for mariculture in South Africa due to its high market demand and apparent biological suitability for culture. In common with most other potential mariculture species the spotted grunter has an estuarine juvenile phase. In this respect, the difficulties encountered in determining the optimum environmental requirements of spotted grunter are applicable to the majority of other potential mariculture species. Due the variability of estuarine habitats determination of the optimum environmental requirements of estuarine species under laboratory conditions are a prerequisite to subsequent evaluation of aquaculture potential. Therefore, using the spotted grunter as a representative of a typical potent ial mariculture species, the aim of this study was to contribute to the protocol for evaluating the environmental requirements of potential aquaculture species. The growth of fish is dependent on the relationship between food intake, metabolism and environmental factors. In this relationship, environmental factors do not act on growth per se, but rather act through metabolism on growth. Consequently, the environmental factors affecting the growth of a fish species can be classified into functional categories according to their respective influence on metabolic processes. Five functional categories are recognised, namely: controlling, limiting, masking, directive and lethal factors. In this study, the functional categories were sequenced to develop a theoretical protocol for determining the optimum environmental requirements of potential mariculture species under artificial conditions. It was hypothesised that the correct sequence for experimentally determining the optimum environmental requirements of a species should correspond to theoretical protocol. The hypothesis was tested from the experimental investigation into the individual effects of temperature, salinity, light intensity, photoperiod and food intake on growth performance of juvenile spotted grunter. The investigations quantified the relative effects of controlling, masking, directive and limiting factors on growth performance. The results of the studies were statistically compared to obtain a ranking of the effects of the environmental factors (e.g. temperature, salinity, etc.) on growth performance of juvenile spotted grunter. The statistical ranking facilitated the formulation of a second protocol for sequentially determining the optimum environmental requirements of a species. The second protocol was derived purely from the experimental data. Based on the corroboration between the theoretical protocol and that formulated from the experimental investigations, the hypothesis was accepted. Confirmation of the protocol for examining the effects of controlling, limiting, masking and directive factors provided a basis for the development of a preliminary experimental sequence for determining the optimum environmental requirements of juvenile marine fish. In the development of the experimental sequence, the protocol was interpreted in conjunction with the experimental methods used to determine the effects of environmental factors on the growth of juvenile spotted grunter. The experimental sequence provides a logical frame work within which the optimum environmental requirements of other marine fish species can be determined. In addition, evaluation of growth performance by this method provides a basis for comparison of the mariculture potential between species.
- Full Text:
- Date Issued: 1997
Homogenous and heterogenous catalytic activity of metallophthalocyanines towards electrochemical detection of organic compounds
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
A study of bantu retail traders in certain areas of the Eastern Cape
- Authors: Savage, R B
- Date: 1967
- Subjects: Retail trade -- Bantu-speaking peoples -- South Africa -- Eastern Cape , Black people -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1069 , http://hdl.handle.net/10962/d1007703 , Retail trade -- Bantu-speaking peoples -- South Africa -- Eastern Cape , Black people -- South Africa -- Eastern Cape
- Description: The beginning of the eighteenth century marks the start of economic relations between the colonists of the Cape and the Bantu. As early as 1702 a quarrel about the bartering of cattle had broken out between parties of Whites and Bantu, each of which had made their way, from opposite directions, into the area between the Gamtoos and the Kei Rivers. The Bantu, who were encountered in the Eastern Cape, belonged to the Xhosa-speaking tribes. They were cattle farmers who also practised some agriculture, but this was considered a subsidiary activity which was left to the women. Their economy was a self-sufficient subsistence one with each family an almost entirely self-supporting unit. Each relied on its own cattle and crops and built its own dwellings. To serve its own requirements, each family made domestic utensils out of wood, grass and clay. Iron implements were, however, made by special smiths.
- Full Text:
- Date Issued: 1967
- Authors: Savage, R B
- Date: 1967
- Subjects: Retail trade -- Bantu-speaking peoples -- South Africa -- Eastern Cape , Black people -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1069 , http://hdl.handle.net/10962/d1007703 , Retail trade -- Bantu-speaking peoples -- South Africa -- Eastern Cape , Black people -- South Africa -- Eastern Cape
- Description: The beginning of the eighteenth century marks the start of economic relations between the colonists of the Cape and the Bantu. As early as 1702 a quarrel about the bartering of cattle had broken out between parties of Whites and Bantu, each of which had made their way, from opposite directions, into the area between the Gamtoos and the Kei Rivers. The Bantu, who were encountered in the Eastern Cape, belonged to the Xhosa-speaking tribes. They were cattle farmers who also practised some agriculture, but this was considered a subsidiary activity which was left to the women. Their economy was a self-sufficient subsistence one with each family an almost entirely self-supporting unit. Each relied on its own cattle and crops and built its own dwellings. To serve its own requirements, each family made domestic utensils out of wood, grass and clay. Iron implements were, however, made by special smiths.
- Full Text:
- Date Issued: 1967
Abraham as a covenant mediator
- Authors: Mitchell, Gordon Barry
- Date: 1978
- Subjects: Abraham (Biblical patriarch) , Covenant theology -- Biblical teaching
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1238 , http://hdl.handle.net/10962/d1007657 , Abraham (Biblical patriarch) , Covenant theology -- Biblical teaching
- Description: Conclusion: The [Abrahamic] stories reveal a man caught up in the struggle of faith. But the God who took the initiative in establishing the Covenant shows that in spite of first appearances, He is faithful. The stories present various pictures of Abraham as a Covenant Mediator. Because he is in a sense Israel in microcosm it is not strange that he is described in the terms of Israel's most important institutions: prophet, priest, and king. Nevertheless the most significant Sitz im Leben is the family. While he is usually meant to be understood as an individual representing his immediate family, his descendants, and even all nations, at times, because he is the founding ancestor of Israel and therefore Israel in microcosm, he is best understood as a "Corporate Person". He and Israel are to be a source of blessing to the nations.
- Full Text:
- Date Issued: 1978
- Authors: Mitchell, Gordon Barry
- Date: 1978
- Subjects: Abraham (Biblical patriarch) , Covenant theology -- Biblical teaching
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1238 , http://hdl.handle.net/10962/d1007657 , Abraham (Biblical patriarch) , Covenant theology -- Biblical teaching
- Description: Conclusion: The [Abrahamic] stories reveal a man caught up in the struggle of faith. But the God who took the initiative in establishing the Covenant shows that in spite of first appearances, He is faithful. The stories present various pictures of Abraham as a Covenant Mediator. Because he is in a sense Israel in microcosm it is not strange that he is described in the terms of Israel's most important institutions: prophet, priest, and king. Nevertheless the most significant Sitz im Leben is the family. While he is usually meant to be understood as an individual representing his immediate family, his descendants, and even all nations, at times, because he is the founding ancestor of Israel and therefore Israel in microcosm, he is best understood as a "Corporate Person". He and Israel are to be a source of blessing to the nations.
- Full Text:
- Date Issued: 1978
An investigation into perceptions of learner participation in the governance of secondary schools
- Authors: Nongubo, Mphuthumi J
- Date: 2005
- Subjects: Education and state -- South Africa , School management and organization -- South Africa , Education, Secondary -- South Africa , Student government -- South Africa , Student participation in administration -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2007 , http://hdl.handle.net/10962/d1015747
- Description: The question of learner participation or involvement in school governance has been a thorny issue in South Africa for decades. This study investigated secondary learners’ participation in the governance of their schools through representation by the Representative Council of Learners (RCLs), formerly known as school representative councils (SRCs). The study attempted to find out how learners participation is perceived by both the RCLs and the School Management Teams (SMTs). The study was conducted in five secondary schools in the Eastern Cape townships of Grahamstown. The research participants were members of School Management Teams and Representative Councils of Learners from these schools. The study was oriented in an interpretive paradigm following a qualitative approach. Questionnaires and in-depth semi-structured interviews were used to explore the perceptions of the two groups involved. The Department of Education documents that sanction RCL participation were referred to throughout and especially when analysing the respondents’ views. The main finding of the study is that learner involvement in school governance is still problematic, though it is presently provided for by policies that govern schools, including the South African Schools Act and the Guides for Representative Councils of Learners of 1999, in which their roles are outlined. The findings of the study reveal an indecisive and autocratic mindset among educators regarding the issue of learner involvement in governance and management. Furthermore, the Department of Education documents in place betray a narrow conception of RCL participation in school governance and still display an element of mistrust towards the learners concerning their roles in governance. As a result of these forces, the democratic potential of learner participation is undermined, and RCLs compromised as legitimate stakeholders.
- Full Text:
- Date Issued: 2005
- Authors: Nongubo, Mphuthumi J
- Date: 2005
- Subjects: Education and state -- South Africa , School management and organization -- South Africa , Education, Secondary -- South Africa , Student government -- South Africa , Student participation in administration -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2007 , http://hdl.handle.net/10962/d1015747
- Description: The question of learner participation or involvement in school governance has been a thorny issue in South Africa for decades. This study investigated secondary learners’ participation in the governance of their schools through representation by the Representative Council of Learners (RCLs), formerly known as school representative councils (SRCs). The study attempted to find out how learners participation is perceived by both the RCLs and the School Management Teams (SMTs). The study was conducted in five secondary schools in the Eastern Cape townships of Grahamstown. The research participants were members of School Management Teams and Representative Councils of Learners from these schools. The study was oriented in an interpretive paradigm following a qualitative approach. Questionnaires and in-depth semi-structured interviews were used to explore the perceptions of the two groups involved. The Department of Education documents that sanction RCL participation were referred to throughout and especially when analysing the respondents’ views. The main finding of the study is that learner involvement in school governance is still problematic, though it is presently provided for by policies that govern schools, including the South African Schools Act and the Guides for Representative Councils of Learners of 1999, in which their roles are outlined. The findings of the study reveal an indecisive and autocratic mindset among educators regarding the issue of learner involvement in governance and management. Furthermore, the Department of Education documents in place betray a narrow conception of RCL participation in school governance and still display an element of mistrust towards the learners concerning their roles in governance. As a result of these forces, the democratic potential of learner participation is undermined, and RCLs compromised as legitimate stakeholders.
- Full Text:
- Date Issued: 2005
Fuzzy uniform spaces
- Authors: Burton, Michael Howard
- Date: 1992
- Subjects: Fuzzy sets -- Research Uniform spaces -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5408 , http://hdl.handle.net/10962/d1005222
- Description: For a fuzzy uniform space, the notion of a Cauchy prefilter, a precompact fuzzy set, a complete fuzzy set and a bounded fuzzy set are defined in such a way that these notions are good extensions of the corresponding notions for a uniform space. A theory of fuzzy uniform spaces is developed which generalises the theory of uniform spaces.
- Full Text:
- Date Issued: 1992
- Authors: Burton, Michael Howard
- Date: 1992
- Subjects: Fuzzy sets -- Research Uniform spaces -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5408 , http://hdl.handle.net/10962/d1005222
- Description: For a fuzzy uniform space, the notion of a Cauchy prefilter, a precompact fuzzy set, a complete fuzzy set and a bounded fuzzy set are defined in such a way that these notions are good extensions of the corresponding notions for a uniform space. A theory of fuzzy uniform spaces is developed which generalises the theory of uniform spaces.
- Full Text:
- Date Issued: 1992
The design of a tannery near Bulawayo, Republic of Zimbabwe
- Authors: Sibanda, Sinqumo
- Date: 2016
- Subjects: Factories -- Zimbabwe -- Designs and plans Architecture, Industrial -- Zimbabwe -- Designs and plans , Tanneries -- Zimbabwe -- Designs and plans Architecture, Modern -- 21st century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/18707 , vital:28709
- Description: The purpose of this research is to develop a design for a tannery using alternative tanning methods where natural chemicals would be used in the place of metal based acid. There are unprecedented levels of contamination in the natural water systems due to partially processed chemicals coming out of industries with tanneries producing a significant amount of untreated effluent. The aim of the research is to investigate the process of reclamation, rehabilitation and reuse of the animal hides as well as the reproduction of the inherent context, where a mutually beneficial interaction between the program and the context will be realized. This will involve a process of reclamation of the existing waste land, the remodeling of the existing dilapidated sewerage treatment infrastructure such that the existing structures and the waste treatment processes are adapted for the benefaction of the tannery. The design will explore the symbiotic nature and the contrasts that are inherent in factories as a type, with high volumes of waste and the envisaged mitigation mechanism this facility will have to the natural environment. Spatial concepts dealing with these programmatic contrasts, that is, containment and openness, heavy and light, interiority and exteriority, threshold and termination will be interrogated.
- Full Text:
- Date Issued: 2016
- Authors: Sibanda, Sinqumo
- Date: 2016
- Subjects: Factories -- Zimbabwe -- Designs and plans Architecture, Industrial -- Zimbabwe -- Designs and plans , Tanneries -- Zimbabwe -- Designs and plans Architecture, Modern -- 21st century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/18707 , vital:28709
- Description: The purpose of this research is to develop a design for a tannery using alternative tanning methods where natural chemicals would be used in the place of metal based acid. There are unprecedented levels of contamination in the natural water systems due to partially processed chemicals coming out of industries with tanneries producing a significant amount of untreated effluent. The aim of the research is to investigate the process of reclamation, rehabilitation and reuse of the animal hides as well as the reproduction of the inherent context, where a mutually beneficial interaction between the program and the context will be realized. This will involve a process of reclamation of the existing waste land, the remodeling of the existing dilapidated sewerage treatment infrastructure such that the existing structures and the waste treatment processes are adapted for the benefaction of the tannery. The design will explore the symbiotic nature and the contrasts that are inherent in factories as a type, with high volumes of waste and the envisaged mitigation mechanism this facility will have to the natural environment. Spatial concepts dealing with these programmatic contrasts, that is, containment and openness, heavy and light, interiority and exteriority, threshold and termination will be interrogated.
- Full Text:
- Date Issued: 2016
The war againts organised crime: a critical assessment of South African asset forfeiture law and its impact on redress for victims of crime
- Ndzengu, Nkululeko Christopher
- Authors: Ndzengu, Nkululeko Christopher
- Date: 2009
- Subjects: Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10173 , http://hdl.handle.net/10948/905 , Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Description: This research will be undertaken in the field of both criminal and civil law with particular focus on international interventions in the fight against organized criminal activities, assets forfeitsure in South Africa in general and its treatment of victims of the underlying forfeitsure crimes ("the victims") in assert forfeitsure, more specifically.
- Full Text: false
- Date Issued: 2009
- Authors: Ndzengu, Nkululeko Christopher
- Date: 2009
- Subjects: Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10173 , http://hdl.handle.net/10948/905 , Forfeiture -- South Africa , Organized crime , Victims of crimes -- Legal status, laws, etc. -- South Africa , Reparation (Criminal justice) -- South Africa
- Description: This research will be undertaken in the field of both criminal and civil law with particular focus on international interventions in the fight against organized criminal activities, assets forfeitsure in South Africa in general and its treatment of victims of the underlying forfeitsure crimes ("the victims") in assert forfeitsure, more specifically.
- Full Text: false
- Date Issued: 2009
The impact of road construction on the livelihoods of rural communities : a case of Nyandeni Municipality in Eastern Cape, South Africa
- Authors: Ndesi, Zabambo Nale
- Date: 2017
- Subjects: Roads -- Economic aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/8769 , vital:33542
- Description: All over the world many rural households are engaged in different economic activities to sustain their livelihoods. To a large extent, a household’s ability to do this depends on access to basic assets such as infrastructure, social, human, finance or physical. Access to these assets can be affected by large projects such as road construction which can either enhance or hinder access to key assets. The main objective of the study is to investigate the impact of the construction of the N2 Wild Coast Highway in the Eastern Cape Province on the livelihoods of rural households in the Nyandeni local municipality. The study also seeks to investigate the dominant household economic activities within the municipality, factors affecting the choice of these activities and the probable impact of the construction of the N2 highway on these economic activities and livelihood strategies. The road construction is translated as a ‘shock’ in the livelihood context, hence the study further seeks to document how households respond to road construction ‘shock’ to their livelihoods, based on the findings of the study. The study applied a mixed methods approach, applying both qualitative and quantitative data. Two sources of data are used; a survey of 40 households in the Nyandeni local municipality which provided the qualitative data and survey data from the PSPPD-II quantitative data from project conducted by the Economics department at the University of Fort Hare, which provided the quantitative data. The multinomial logistic regression was used to determine the livelihood strategies used as well as the related determinants. The results showed that financial, social and physical capitals are key assets that support livelihoods in Nyandeni municipality, which were highly determined by the deprivation score, social grants and community networks. To get a clearer understanding of the underlying effects of the road construction, focus prompts interviews were also conducted. These were analysed using thematic analysis. The results showed that the road construction had both the negative and positive effects. The positive effects included better links to social facilities such as hospitals and schools as well as neighbouring municipalities. The construction also created employment for construction workers. In addition, the construction company helped households whose houses were destroyed near the road to build better houses. Although the households complained of danger from high speed vehicles because of better roads, they also indicated that the speed bumps in some areas led to an improvement in well-being especially for school children. The negative effects included destruction of burial grounds as well as the weakening of housing structures due to blasting. Further, some vegetation which was used by households as a source of livelihood was destroyed during road construction. In some cases, social capital assets were also disturbed as a result of the displacement that occurred in the process. Responses by households have been mixed, with some households taking advantage of increased access to markets as well as finances to find alternative sources of livelihoods. Households that responded negatively constantly seek out reimbursement from the government and construction company without much success.
- Full Text:
- Date Issued: 2017
- Authors: Ndesi, Zabambo Nale
- Date: 2017
- Subjects: Roads -- Economic aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/8769 , vital:33542
- Description: All over the world many rural households are engaged in different economic activities to sustain their livelihoods. To a large extent, a household’s ability to do this depends on access to basic assets such as infrastructure, social, human, finance or physical. Access to these assets can be affected by large projects such as road construction which can either enhance or hinder access to key assets. The main objective of the study is to investigate the impact of the construction of the N2 Wild Coast Highway in the Eastern Cape Province on the livelihoods of rural households in the Nyandeni local municipality. The study also seeks to investigate the dominant household economic activities within the municipality, factors affecting the choice of these activities and the probable impact of the construction of the N2 highway on these economic activities and livelihood strategies. The road construction is translated as a ‘shock’ in the livelihood context, hence the study further seeks to document how households respond to road construction ‘shock’ to their livelihoods, based on the findings of the study. The study applied a mixed methods approach, applying both qualitative and quantitative data. Two sources of data are used; a survey of 40 households in the Nyandeni local municipality which provided the qualitative data and survey data from the PSPPD-II quantitative data from project conducted by the Economics department at the University of Fort Hare, which provided the quantitative data. The multinomial logistic regression was used to determine the livelihood strategies used as well as the related determinants. The results showed that financial, social and physical capitals are key assets that support livelihoods in Nyandeni municipality, which were highly determined by the deprivation score, social grants and community networks. To get a clearer understanding of the underlying effects of the road construction, focus prompts interviews were also conducted. These were analysed using thematic analysis. The results showed that the road construction had both the negative and positive effects. The positive effects included better links to social facilities such as hospitals and schools as well as neighbouring municipalities. The construction also created employment for construction workers. In addition, the construction company helped households whose houses were destroyed near the road to build better houses. Although the households complained of danger from high speed vehicles because of better roads, they also indicated that the speed bumps in some areas led to an improvement in well-being especially for school children. The negative effects included destruction of burial grounds as well as the weakening of housing structures due to blasting. Further, some vegetation which was used by households as a source of livelihood was destroyed during road construction. In some cases, social capital assets were also disturbed as a result of the displacement that occurred in the process. Responses by households have been mixed, with some households taking advantage of increased access to markets as well as finances to find alternative sources of livelihoods. Households that responded negatively constantly seek out reimbursement from the government and construction company without much success.
- Full Text:
- Date Issued: 2017
Individualism, collectivism and gender as correlates of the work ethic among the employees in a government department in the Eastern Cape
- Authors: Gwelo, Blessing
- Date: 2016
- Subjects: Individualism Collectivism Work ethic
- Language: English
- Type: Thesis , Masters , Industrial Psychology
- Identifier: http://hdl.handle.net/10353/11608 , vital:39089
- Description: This study investigated the relationship between individualism, collectivism and gender among the employees at the Department of Justice and Constitutional Development situated in East London, South Africa. Individualism, collectivism and gender were used as independent variables in the study while the work ethic was used as the dependent variable. Data was gathered from a random sample of 260 employees in the Department. A questionnaire consisting of three parts was used for data collection. To gather biographical and occupational data, a self-designed 5-item questionnaire was used. The 65 item Multidimensional Work Ethic Profile (MWEP) scale Miller et al. (2002) was used to measure the work ethic. A 16-item individualism/collectivism scale (also known as the Culture Orientation Scale) formulated by Triandis & Gelfand (1998) was used in the research to measure individualism/collectivism. Data analysis was done by means of various statistical techniques, including the Pearson Product Moment Correlation Technique and Multiple Regression Analysis. The results indicated that there is a significant positive correlation between individualism and the work ethic, noting that a positive correlation for individualism implies a negative correlation for collectivism. The results of this study also found males showing to have higher work ethic than females. The results indicated that individualism/collectivism and gender together do not account for a higher proportion of variance in work ethic than any of the two separately. The study, therefore, recommends that managers must do all in their power to promote the growth and development of work ethic in their organisations through encouraging individualism, and through striving to increase the work ethic in females.
- Full Text:
- Date Issued: 2016
- Authors: Gwelo, Blessing
- Date: 2016
- Subjects: Individualism Collectivism Work ethic
- Language: English
- Type: Thesis , Masters , Industrial Psychology
- Identifier: http://hdl.handle.net/10353/11608 , vital:39089
- Description: This study investigated the relationship between individualism, collectivism and gender among the employees at the Department of Justice and Constitutional Development situated in East London, South Africa. Individualism, collectivism and gender were used as independent variables in the study while the work ethic was used as the dependent variable. Data was gathered from a random sample of 260 employees in the Department. A questionnaire consisting of three parts was used for data collection. To gather biographical and occupational data, a self-designed 5-item questionnaire was used. The 65 item Multidimensional Work Ethic Profile (MWEP) scale Miller et al. (2002) was used to measure the work ethic. A 16-item individualism/collectivism scale (also known as the Culture Orientation Scale) formulated by Triandis & Gelfand (1998) was used in the research to measure individualism/collectivism. Data analysis was done by means of various statistical techniques, including the Pearson Product Moment Correlation Technique and Multiple Regression Analysis. The results indicated that there is a significant positive correlation between individualism and the work ethic, noting that a positive correlation for individualism implies a negative correlation for collectivism. The results of this study also found males showing to have higher work ethic than females. The results indicated that individualism/collectivism and gender together do not account for a higher proportion of variance in work ethic than any of the two separately. The study, therefore, recommends that managers must do all in their power to promote the growth and development of work ethic in their organisations through encouraging individualism, and through striving to increase the work ethic in females.
- Full Text:
- Date Issued: 2016
Exploring mythical creatures and their influence on mental health amongst black South Africans residing in rural areas of the Eastern Cape Province, South Africa
- Authors: Sibam, Zimkhitha
- Date: 2019
- Subjects: Supernatural beliefs
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/44717 , vital:38150
- Description: In various cultures, supernatural beliefs abound and influence individuals through mythical ideas and figures. In South Africa and other parts of the world, mythical creatures are held accountable for terrorising individuals and instilling fear or, held accountable for a host of psychosocial experiences. For example, the tokoloshe is a mythical creature whose very name raises fear and suspicion amongst many Black South Africans. Using community narratives, this study explored the potential influence of the belief in mythical creatures, specifically the tokoloshe on mental health and well - being in rural communities in South Africa (SA). This understanding is considered important given the existing gap in the literature focussing on supernatural beliefs and their influence on mental health which resonates with a current movement in SA focusing on the transformation of psychology considering the need to transform and contextualise the relevance of psychology to population groups in SA, understanding supernatural cultural beliefs becomes important. This study employed a qualitative design and the participants were purposively sampled from rural communities in the Eastern Cape (EC) Province. Four focus group discussions consisting of five to six participants in each were conducted, with the central aim of exploring the potential mental health implications of the belief in mythical creatures. The following ethical considerations were adhered to whilst conducting the study; informed consent, voluntary participation, anonymity ad confidentiality and doing no harm to participants. In this study thematic content analysis was used following Braun and Clarkes (2013) analytical steps. Participants suggested that a strong cultural belief in the existence and reality of the tokoloshe exists and described the tokoloshe as a short and hairy male who sexually assaults women mostly in their sleep and causes people to disappear, only to be found dead. Amongst other things, the tokoloshe is believed to be responsible for psychological, social and physical experiences like, misfortune, possession, numbness and fatigue. The tokoloshe is suggested by the participants as causing Running Head: EXPLORATION OF MYTHICAL CREATURES AND MENTAL HEALTH 9 fear influencing an individual’s psychosocial and emotional well - being. Traditional healers and prophets were further suggested as the most likely to be consulted if the above symptoms were experienced, rather than a psychologist. The findings of the study suggests that supernatural beliefs currently influence the understanding and treatment of a variety of experiences and that unless psychological science begins to incorporate such beliefs into its therapeutic modalities, as a discipline it may not adequately provide services to a diverse population group. Future research should consider exploring role of mythical creatures specifically the tokoloshe on mental illness, with the aim of identifying ways of incorporating such beliefs into psychological interventions. Future studies could consider exploring community narratives of mythical creatures, specifically the tokoloshe on different cultures within South Africa, to compare the differences and similarities. The study also identified several interesting themes, including the potential violence against women, from the tokoloshe. While these narratives were a reflection of personal experience and belief, the implication this poses to the psychology of gender and violence must be explored further.
- Full Text:
- Date Issued: 2019
- Authors: Sibam, Zimkhitha
- Date: 2019
- Subjects: Supernatural beliefs
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/44717 , vital:38150
- Description: In various cultures, supernatural beliefs abound and influence individuals through mythical ideas and figures. In South Africa and other parts of the world, mythical creatures are held accountable for terrorising individuals and instilling fear or, held accountable for a host of psychosocial experiences. For example, the tokoloshe is a mythical creature whose very name raises fear and suspicion amongst many Black South Africans. Using community narratives, this study explored the potential influence of the belief in mythical creatures, specifically the tokoloshe on mental health and well - being in rural communities in South Africa (SA). This understanding is considered important given the existing gap in the literature focussing on supernatural beliefs and their influence on mental health which resonates with a current movement in SA focusing on the transformation of psychology considering the need to transform and contextualise the relevance of psychology to population groups in SA, understanding supernatural cultural beliefs becomes important. This study employed a qualitative design and the participants were purposively sampled from rural communities in the Eastern Cape (EC) Province. Four focus group discussions consisting of five to six participants in each were conducted, with the central aim of exploring the potential mental health implications of the belief in mythical creatures. The following ethical considerations were adhered to whilst conducting the study; informed consent, voluntary participation, anonymity ad confidentiality and doing no harm to participants. In this study thematic content analysis was used following Braun and Clarkes (2013) analytical steps. Participants suggested that a strong cultural belief in the existence and reality of the tokoloshe exists and described the tokoloshe as a short and hairy male who sexually assaults women mostly in their sleep and causes people to disappear, only to be found dead. Amongst other things, the tokoloshe is believed to be responsible for psychological, social and physical experiences like, misfortune, possession, numbness and fatigue. The tokoloshe is suggested by the participants as causing Running Head: EXPLORATION OF MYTHICAL CREATURES AND MENTAL HEALTH 9 fear influencing an individual’s psychosocial and emotional well - being. Traditional healers and prophets were further suggested as the most likely to be consulted if the above symptoms were experienced, rather than a psychologist. The findings of the study suggests that supernatural beliefs currently influence the understanding and treatment of a variety of experiences and that unless psychological science begins to incorporate such beliefs into its therapeutic modalities, as a discipline it may not adequately provide services to a diverse population group. Future research should consider exploring role of mythical creatures specifically the tokoloshe on mental illness, with the aim of identifying ways of incorporating such beliefs into psychological interventions. Future studies could consider exploring community narratives of mythical creatures, specifically the tokoloshe on different cultures within South Africa, to compare the differences and similarities. The study also identified several interesting themes, including the potential violence against women, from the tokoloshe. While these narratives were a reflection of personal experience and belief, the implication this poses to the psychology of gender and violence must be explored further.
- Full Text:
- Date Issued: 2019
The development and implementation of a mental toughness training programme for cricketers
- Authors: McInerney, Michael
- Date: 2014
- Subjects: Sports -- Psychological aspects , Athletes -- Conduct of life , Mental discipline , Achievement motivation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3234 , http://hdl.handle.net/10962/d1013155
- Description: The professional turn in sports has prompted the search for explanations beyond the physical when discussing quality of performance. Mental Toughness has been recognised as one of the most important psychological attributes in achieving performance excellence across multiple sport settings. Yet, despite this, little research has been conducted into mental toughness development. This research seeks to answer the question: What insights can the development and implementation of a mental toughness programme for a semi-professional South African cricket team provide regarding Mental Toughness development? Based on a theoretical framework of mental toughness in cricket, a programme was developed in collaboration with the Border Cricket Team and Coaches. Incorporating elements that focussed on education, environment, awareness and mental skills, the programme was implemented in both individual and group settings during the off- and pre-seasons. An analysis of the participants’ experiences identified the need for a theoretical understanding of mental toughness within teams, facilitating the design of interventions that integrate the team and the individual. Future programmes should include measures of mastery, and individually customised approaches to mental toughness enhancement that acknowledge the potential contextual and individual variation in mental toughness.
- Full Text:
- Date Issued: 2014
- Authors: McInerney, Michael
- Date: 2014
- Subjects: Sports -- Psychological aspects , Athletes -- Conduct of life , Mental discipline , Achievement motivation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3234 , http://hdl.handle.net/10962/d1013155
- Description: The professional turn in sports has prompted the search for explanations beyond the physical when discussing quality of performance. Mental Toughness has been recognised as one of the most important psychological attributes in achieving performance excellence across multiple sport settings. Yet, despite this, little research has been conducted into mental toughness development. This research seeks to answer the question: What insights can the development and implementation of a mental toughness programme for a semi-professional South African cricket team provide regarding Mental Toughness development? Based on a theoretical framework of mental toughness in cricket, a programme was developed in collaboration with the Border Cricket Team and Coaches. Incorporating elements that focussed on education, environment, awareness and mental skills, the programme was implemented in both individual and group settings during the off- and pre-seasons. An analysis of the participants’ experiences identified the need for a theoretical understanding of mental toughness within teams, facilitating the design of interventions that integrate the team and the individual. Future programmes should include measures of mastery, and individually customised approaches to mental toughness enhancement that acknowledge the potential contextual and individual variation in mental toughness.
- Full Text:
- Date Issued: 2014