William Blake’s animal symbols: tensions and intersections between science and allegory In Eighteenth-Century attitudes towards animals
- Authors: Singh, Jyoti
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4590 , vital:20696
- Description: This thesis explores the tensions and intersections between science, allegory, and related eighteenth-century attitudes towards animals in William Blake’s poetry through detailed analysis of individual animal symbols and tropes. It will focus specifically on the period between 1794 and 1820, to coincide with the dates of Blake’s major works. Chapter One outlines Blake’s key philosophies, concentrating on his particular approach to symbolism. By rejecting certain Enlightenment ideals and beliefs surrounding allegory, Blake created his own form of the literary tradition, and the subjects and symbols of his poetry clearly demonstrate shifting allegorical frames. The chapter also explains why he argued for the recognition, and even valorisation, of the imaginative faculty, or “Poetic Genius”, in an era which accepted reason and rational thinking as one of the main means of apprehending the world. Chapter Two considers the significance of Blake’s use of predatory animals in the SONGS Of INNOCENCE and Of EXPERIENCE. In focussing on symbolic animals, the chapter assesses whether the ‘real’ animals (with all their scientific associations) are alluded to, and the extent to which they influence their symbolic counterparts. In choosing these symbols to represent key themes throughout his oeuvre, Blake drew on some familiar associations and contemporary attitudes towards animals, but offered no critique of society’s attitudes to animals. Chapter Three identifies and analyses the “fragments of Eternity” represented in the contraries of “Good” and “Evil”, and “Energy” and “Reason” embodied by the animals in THE MARRIAGE of HEAVEN and HELL. The symbols’ division between “Reason” and “Energy” develops an understanding of the complex attitudes towards animals, both in Blake’s mind, and in that of the eighteenth-century British public. Chapter Four is concerned with Blake’s depictions of the Worm and Serpent in his poetry, and how his conception of “Beulah” provides more insight into these symbols and their functions. It also grapples with Rod Preece’s argument that the poet recognised the sanctity and divinity in all forms of life, and sought to endorse these beliefs through his animal symbols. As the thesis illustrates, though, Blake is not arguing for the sanctity of all life to be upheld, nor does he see any divinity in the beings and objects found in nature. Sanctity and divinity are constructs of the imagination, and it is through exercising the imaginative faculty - the “Poetic Genius’’ - along with our senses and instincts, that we are able to make sense of the world. The study thus concludes by considering the extent to which ‘real’ animals intrude upon Blake’s oeuvre, and attempts to determine the value of reading the symbols through an “animal studies” paradigm. It also argues that ‘real’ animals are inseparable from their cultural and symbolic representations, because these are the only means of interpretation we have.
- Full Text:
- Date Issued: 2017
- Authors: Singh, Jyoti
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4590 , vital:20696
- Description: This thesis explores the tensions and intersections between science, allegory, and related eighteenth-century attitudes towards animals in William Blake’s poetry through detailed analysis of individual animal symbols and tropes. It will focus specifically on the period between 1794 and 1820, to coincide with the dates of Blake’s major works. Chapter One outlines Blake’s key philosophies, concentrating on his particular approach to symbolism. By rejecting certain Enlightenment ideals and beliefs surrounding allegory, Blake created his own form of the literary tradition, and the subjects and symbols of his poetry clearly demonstrate shifting allegorical frames. The chapter also explains why he argued for the recognition, and even valorisation, of the imaginative faculty, or “Poetic Genius”, in an era which accepted reason and rational thinking as one of the main means of apprehending the world. Chapter Two considers the significance of Blake’s use of predatory animals in the SONGS Of INNOCENCE and Of EXPERIENCE. In focussing on symbolic animals, the chapter assesses whether the ‘real’ animals (with all their scientific associations) are alluded to, and the extent to which they influence their symbolic counterparts. In choosing these symbols to represent key themes throughout his oeuvre, Blake drew on some familiar associations and contemporary attitudes towards animals, but offered no critique of society’s attitudes to animals. Chapter Three identifies and analyses the “fragments of Eternity” represented in the contraries of “Good” and “Evil”, and “Energy” and “Reason” embodied by the animals in THE MARRIAGE of HEAVEN and HELL. The symbols’ division between “Reason” and “Energy” develops an understanding of the complex attitudes towards animals, both in Blake’s mind, and in that of the eighteenth-century British public. Chapter Four is concerned with Blake’s depictions of the Worm and Serpent in his poetry, and how his conception of “Beulah” provides more insight into these symbols and their functions. It also grapples with Rod Preece’s argument that the poet recognised the sanctity and divinity in all forms of life, and sought to endorse these beliefs through his animal symbols. As the thesis illustrates, though, Blake is not arguing for the sanctity of all life to be upheld, nor does he see any divinity in the beings and objects found in nature. Sanctity and divinity are constructs of the imagination, and it is through exercising the imaginative faculty - the “Poetic Genius’’ - along with our senses and instincts, that we are able to make sense of the world. The study thus concludes by considering the extent to which ‘real’ animals intrude upon Blake’s oeuvre, and attempts to determine the value of reading the symbols through an “animal studies” paradigm. It also argues that ‘real’ animals are inseparable from their cultural and symbolic representations, because these are the only means of interpretation we have.
- Full Text:
- Date Issued: 2017
The valuation of amounts for the purpose of inclusion in gross income
- Authors: Spearman, Tarryn Leigh
- Date: 2012
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:887 , http://hdl.handle.net/10962/d1001641
- Description: The present research investigates the valuation of amounts for the purpose of inclusion in gross income. Because the gross income definition in section 1 of the Income Tax Act includes "amounts in cash or otherwise", valuations are often required in order to establish a value in money terms for amounts received or accrued in a form otherwise than in cash. The basis on which these valuations are made can vary and the courts have frequently been called upon to decide on the correct method of valuation. There has been an ongoing debate in the courts as to whether a strict objective approach or a more flexible subjective approach should be adopted when valuing an amount in a form other than cash, which was finally settled in the decision by the Supreme Court of Appeal in CIR v Brummeria Renaissance (Pty) Ltd, which held that an objective approach must be followed. The present research will demonstrate how the strict rule of interpretation tends to result in purely objective valuations as it requires that the ordinary grammatical meaning of words be applied and does not allow the court to consider the purpose of the legislation or introduce any subjectivity based on the circumstances of each individual taxpayer and the facts of each particular case, which a purposive interpretation approach does. The purposive approach to interpretation is therefore more closely aligned with the subjective approach to valuation. Both the objective and subjective approaches to valuation have advantages and disadvantages, which are addressed in the research. The need for certainty in taxation was articulated as early as 1776 by Adam Smith in his Wealth of Nations. The objective approach appears to create a level of consistency as all income received by a taxpayer is effectively taxed as if received by a third party in an arm’s length transaction. The approach has led to unfair decisions at odds with economic reality and generally accepted accounting principles, which could be challenged on the basis of a lack of equity and fairness as required by the Constitution of the Republic of South Africa. The research demonstrates that an objective method of valuation is neither fully objective nor appropriate in certain circumstances, while a subjective approach may be more appropriate as it ensures that each taxpayer’s individual rights are protected. Although the subjective approach successfully addresses the issue of fairness, it threatens to introduce an unacceptable level of inconsistency and is, in reality, not always administratively feasible. The present research concludes that a trade-off between fairness and consistency is often necessary.
- Full Text:
- Date Issued: 2012
- Authors: Spearman, Tarryn Leigh
- Date: 2012
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:887 , http://hdl.handle.net/10962/d1001641
- Description: The present research investigates the valuation of amounts for the purpose of inclusion in gross income. Because the gross income definition in section 1 of the Income Tax Act includes "amounts in cash or otherwise", valuations are often required in order to establish a value in money terms for amounts received or accrued in a form otherwise than in cash. The basis on which these valuations are made can vary and the courts have frequently been called upon to decide on the correct method of valuation. There has been an ongoing debate in the courts as to whether a strict objective approach or a more flexible subjective approach should be adopted when valuing an amount in a form other than cash, which was finally settled in the decision by the Supreme Court of Appeal in CIR v Brummeria Renaissance (Pty) Ltd, which held that an objective approach must be followed. The present research will demonstrate how the strict rule of interpretation tends to result in purely objective valuations as it requires that the ordinary grammatical meaning of words be applied and does not allow the court to consider the purpose of the legislation or introduce any subjectivity based on the circumstances of each individual taxpayer and the facts of each particular case, which a purposive interpretation approach does. The purposive approach to interpretation is therefore more closely aligned with the subjective approach to valuation. Both the objective and subjective approaches to valuation have advantages and disadvantages, which are addressed in the research. The need for certainty in taxation was articulated as early as 1776 by Adam Smith in his Wealth of Nations. The objective approach appears to create a level of consistency as all income received by a taxpayer is effectively taxed as if received by a third party in an arm’s length transaction. The approach has led to unfair decisions at odds with economic reality and generally accepted accounting principles, which could be challenged on the basis of a lack of equity and fairness as required by the Constitution of the Republic of South Africa. The research demonstrates that an objective method of valuation is neither fully objective nor appropriate in certain circumstances, while a subjective approach may be more appropriate as it ensures that each taxpayer’s individual rights are protected. Although the subjective approach successfully addresses the issue of fairness, it threatens to introduce an unacceptable level of inconsistency and is, in reality, not always administratively feasible. The present research concludes that a trade-off between fairness and consistency is often necessary.
- Full Text:
- Date Issued: 2012
The teaching of the Acts of the Apostles concerning the Holy Spirit
- Authors: Woods, B J
- Date: 1955
- Subjects: Bible. Acts , Holy Spirit
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1281 , http://hdl.handle.net/10962/d1013453
- Description: There must be certain reasons why one embarks on a study of the Holy Spirit. The first is perhaps because there is a need today for a Biblical doctrine of the Spirit. The second follows from the first, for there is a need for a deeper knowledge of the Spirit and His work. He is the life-giving Spirit, and we need today to be spiritually alive. The third reason for a study of this kind is that we need a deeper understanding of the power of the Spirit in the affairs of men in the world. We have got away from the idea that God works amongst us through His Spirit, and we tend to think more and more of the achievements of man, and the power of the machine to do as we wish. We need to return to the power of the Spirit, and to be instruments of God's wishes. Finally, our Christianity today, in this country, appears to be so lifeless, so stuck in the groove of routine - the interminable bazaars, money raising efforts, and social half-hours - that we have lost the enthusiasm of first century Christianity, the driving force of the Spirit spurring us on to bring the Gospel of Life to the hungry world. We need in our modern experience and our modern condition, to find the powerful enthusiasm, as a result of the Spirit' s working in us, that the early Christians found when they were filled with Him and worked under His guidance. So we undertake the study of the Spirit among the early Church, in the hope that we too may desire to be filled as the Apostles were filled.
- Full Text:
- Date Issued: 1955
- Authors: Woods, B J
- Date: 1955
- Subjects: Bible. Acts , Holy Spirit
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1281 , http://hdl.handle.net/10962/d1013453
- Description: There must be certain reasons why one embarks on a study of the Holy Spirit. The first is perhaps because there is a need today for a Biblical doctrine of the Spirit. The second follows from the first, for there is a need for a deeper knowledge of the Spirit and His work. He is the life-giving Spirit, and we need today to be spiritually alive. The third reason for a study of this kind is that we need a deeper understanding of the power of the Spirit in the affairs of men in the world. We have got away from the idea that God works amongst us through His Spirit, and we tend to think more and more of the achievements of man, and the power of the machine to do as we wish. We need to return to the power of the Spirit, and to be instruments of God's wishes. Finally, our Christianity today, in this country, appears to be so lifeless, so stuck in the groove of routine - the interminable bazaars, money raising efforts, and social half-hours - that we have lost the enthusiasm of first century Christianity, the driving force of the Spirit spurring us on to bring the Gospel of Life to the hungry world. We need in our modern experience and our modern condition, to find the powerful enthusiasm, as a result of the Spirit' s working in us, that the early Christians found when they were filled with Him and worked under His guidance. So we undertake the study of the Spirit among the early Church, in the hope that we too may desire to be filled as the Apostles were filled.
- Full Text:
- Date Issued: 1955
The spectrochemical determination of certain minor trace elements in plant material
- Authors: Eve, Desmond John
- Date: 1961
- Subjects: Trace elements Spectrum analysis Plants -- Analysis Plants -- Effect of trace elements on Trace elements in agriculture
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4469 , http://hdl.handle.net/10962/d1011773
- Description: A study has been made of three organic complexing reagents , namely dithizone, oxine and cupferron with a view to developing suitable methods for the separation and concentration of Zn, Co, Ni, Pb, Cu, Mn, Ti , V and Mo prior to the spectrometric determination of their concentrations. In particular the influence of pH on the chloroform extraction of ditihizonates, oxinates and cupferrates from aqueous tartrate and citrate solutions and the separation of iron by oxine extraction has been investigated. The development of a method for the chemical concentration and spectrcgraphic determination of Zn, Co, Ni, Pb, Ti, V and Mo is described and the possibility of determining Nn and Cu flame photometrically as part of the analysis scheme is demonstrated. A specially designed slide rule for the calculation of spectrographic results is described. A direct reading spectrometric method for the determination of Zn, Pb and Cu in plant material is presented. The analysis of plant ash for zinc using the 2138 . 6A spectrum line has been studied and a simple, rapid analysis method is described.
- Full Text:
- Date Issued: 1961
- Authors: Eve, Desmond John
- Date: 1961
- Subjects: Trace elements Spectrum analysis Plants -- Analysis Plants -- Effect of trace elements on Trace elements in agriculture
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4469 , http://hdl.handle.net/10962/d1011773
- Description: A study has been made of three organic complexing reagents , namely dithizone, oxine and cupferron with a view to developing suitable methods for the separation and concentration of Zn, Co, Ni, Pb, Cu, Mn, Ti , V and Mo prior to the spectrometric determination of their concentrations. In particular the influence of pH on the chloroform extraction of ditihizonates, oxinates and cupferrates from aqueous tartrate and citrate solutions and the separation of iron by oxine extraction has been investigated. The development of a method for the chemical concentration and spectrcgraphic determination of Zn, Co, Ni, Pb, Ti, V and Mo is described and the possibility of determining Nn and Cu flame photometrically as part of the analysis scheme is demonstrated. A specially designed slide rule for the calculation of spectrographic results is described. A direct reading spectrometric method for the determination of Zn, Pb and Cu in plant material is presented. The analysis of plant ash for zinc using the 2138 . 6A spectrum line has been studied and a simple, rapid analysis method is described.
- Full Text:
- Date Issued: 1961
The role of agricultural co-operatives in food security in the Eastern Cape, Province of South Africa: the case of the Nkonkobe Local Municipality
- Authors: Dyalvane, Ncumisa
- Date: 2015
- Subjects: Agriculture, Cooperative -- South Africa -- Eastern Cape , Food security -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/2867 , vital:28110
- Description: This study highlights the contribution of agricultural co-operatives in promoting food security in the Nkonkobe Local Municipality in the Eastern Cape Province of South Africa.Although the dawn of democracy saw the government making efforts to address food insecurity and provide solutions to the challenges related to it a lot remains to be done. As a result, food insecurity remains a fundamental concern in South Africa in particular among villagers in the Nkonkobe Local Municipality. Consequently, the study focuses on the state of Agricultural Co-operatives in the Nkonkobe Municipality and their role in food security. Therefore, this dissertation therefore discusses problems plaguing Agricultural Co-operatives in Nkonkobe. This study highlights the contribution of agricultural co-operatives in promoting food security in the Nkonkobe Local Municipality in the Eastern Cape Province of South Africa.Although the dawn of democracy saw the government making efforts to address food insecurity and provide solutions to the challenges related to it a lot remains to be done. As a result, food insecurity remains a fundamental concern in South Africa in particular among villagers in the Nkonkobe Local Municipality. Consequently, the study focuses on the state of Agricultural Co-operatives in the Nkonkobe Municipality and their role in food security. Therefore, this dissertation therefore discusses problems plaguing Agricultural Co-operatives in Nkonkobe. The qualitative methodology was used because it seeks to dig out in-depth information so as to understand the causes of food insecurity despite agricultural co-operatives and government assistance being in place. The food security situation was analysed using the sustainable livelihoods and basic needs approaches. The findings of the study reveal that agricultural co-operatives face a number of challenges. These include inadequate funds, poor market places, transport problems, shortage of farming equipment and insufficient water supply. In addition, the ability of agricultural co-operatives to make a worthy contribution to food security is being adversely hindered by poor implementation capacity and financial management. This in turn makes them unable to strengthen and expand their business operations. The study suggests that the government or the municipality should build sustainable water sources like dams as well as provide taps in the community to boost productivity all year round in the agricultural cooperatives hence guaranteeing food security in Nkonkobe Local Municipality,the Eastern Cape and South Africa at large.
- Full Text:
- Date Issued: 2015
- Authors: Dyalvane, Ncumisa
- Date: 2015
- Subjects: Agriculture, Cooperative -- South Africa -- Eastern Cape , Food security -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/2867 , vital:28110
- Description: This study highlights the contribution of agricultural co-operatives in promoting food security in the Nkonkobe Local Municipality in the Eastern Cape Province of South Africa.Although the dawn of democracy saw the government making efforts to address food insecurity and provide solutions to the challenges related to it a lot remains to be done. As a result, food insecurity remains a fundamental concern in South Africa in particular among villagers in the Nkonkobe Local Municipality. Consequently, the study focuses on the state of Agricultural Co-operatives in the Nkonkobe Municipality and their role in food security. Therefore, this dissertation therefore discusses problems plaguing Agricultural Co-operatives in Nkonkobe. This study highlights the contribution of agricultural co-operatives in promoting food security in the Nkonkobe Local Municipality in the Eastern Cape Province of South Africa.Although the dawn of democracy saw the government making efforts to address food insecurity and provide solutions to the challenges related to it a lot remains to be done. As a result, food insecurity remains a fundamental concern in South Africa in particular among villagers in the Nkonkobe Local Municipality. Consequently, the study focuses on the state of Agricultural Co-operatives in the Nkonkobe Municipality and their role in food security. Therefore, this dissertation therefore discusses problems plaguing Agricultural Co-operatives in Nkonkobe. The qualitative methodology was used because it seeks to dig out in-depth information so as to understand the causes of food insecurity despite agricultural co-operatives and government assistance being in place. The food security situation was analysed using the sustainable livelihoods and basic needs approaches. The findings of the study reveal that agricultural co-operatives face a number of challenges. These include inadequate funds, poor market places, transport problems, shortage of farming equipment and insufficient water supply. In addition, the ability of agricultural co-operatives to make a worthy contribution to food security is being adversely hindered by poor implementation capacity and financial management. This in turn makes them unable to strengthen and expand their business operations. The study suggests that the government or the municipality should build sustainable water sources like dams as well as provide taps in the community to boost productivity all year round in the agricultural cooperatives hence guaranteeing food security in Nkonkobe Local Municipality,the Eastern Cape and South Africa at large.
- Full Text:
- Date Issued: 2015
The reliability of firearm identification in South Africa : a comparative perspective
- Authors: Mutsavi, Tanyarara
- Date: 2018
- Subjects: Forensic sciences Firearms -- Identification
- Language: English
- Type: Thesis , Masters , Law
- Identifier: http://hdl.handle.net/10353/10850 , vital:35860
- Description: Crime has become a well-known and worrying fact of life in South Africa. It constrains the ability of citizens to participate actively and meaningfully in all spheres of social and economic life. In many cases where a crime is committed, a firearm is involved. In order to fight gun crime there is a need for the perpetrators to be prosecuted. For prosecution to take place, there must be evidence to link the suspects to the committed crime. This is when firearm identification as a form of expert scientific evidence comes into play. This type of evidence links the bullets and cartridges recovered from the crime scene to the suspect.s firearms through the process of matching which is done by using a comparison microscope. Expert scientific evidence like firearm identification evidence, needs to be scientifically reliable because unreliable evidence may lead to the conviction of the innocent and exoneration of the guilty. Case law, authoritative reports and other literature have shown that firearm identification is not scientific and therefore it is not reliable. This is a disturbing position, considering the fact that this type of evidence is still being used in courts and no alternative has been found thus far to replace it. This study therefore proposes some reforms and recommendations which have been registered in authoritative reports which assist South Africa in dealing with firearm identification evidence. To achieve reliability, some writers have suggested that South Africa should adopt the US approach with regard to admissibility where judges play a .gate keeping. role by making sure that expert evidence is reliable before it enters the court. However, this study argues that scientific reliability, in South Africa, should not be a criterion for admissibility, but should rather be a central factor in deciding what weight should be attached to the expert evidence given in a particular case. The reason for this is that, in South Africa, the jury system is not used and therefore the judge does not have to exercise a .gate keeping. role, as he or she will be the final arbiter as to whether the evidence is reliable. In this context, reliability is considered during cross-examination. Cross-examination by the defence is crucial and this study proposes some possible cross-examination questions that can be helpful in testing the reliability of firearm identification evidence.
- Full Text:
- Date Issued: 2018
- Authors: Mutsavi, Tanyarara
- Date: 2018
- Subjects: Forensic sciences Firearms -- Identification
- Language: English
- Type: Thesis , Masters , Law
- Identifier: http://hdl.handle.net/10353/10850 , vital:35860
- Description: Crime has become a well-known and worrying fact of life in South Africa. It constrains the ability of citizens to participate actively and meaningfully in all spheres of social and economic life. In many cases where a crime is committed, a firearm is involved. In order to fight gun crime there is a need for the perpetrators to be prosecuted. For prosecution to take place, there must be evidence to link the suspects to the committed crime. This is when firearm identification as a form of expert scientific evidence comes into play. This type of evidence links the bullets and cartridges recovered from the crime scene to the suspect.s firearms through the process of matching which is done by using a comparison microscope. Expert scientific evidence like firearm identification evidence, needs to be scientifically reliable because unreliable evidence may lead to the conviction of the innocent and exoneration of the guilty. Case law, authoritative reports and other literature have shown that firearm identification is not scientific and therefore it is not reliable. This is a disturbing position, considering the fact that this type of evidence is still being used in courts and no alternative has been found thus far to replace it. This study therefore proposes some reforms and recommendations which have been registered in authoritative reports which assist South Africa in dealing with firearm identification evidence. To achieve reliability, some writers have suggested that South Africa should adopt the US approach with regard to admissibility where judges play a .gate keeping. role by making sure that expert evidence is reliable before it enters the court. However, this study argues that scientific reliability, in South Africa, should not be a criterion for admissibility, but should rather be a central factor in deciding what weight should be attached to the expert evidence given in a particular case. The reason for this is that, in South Africa, the jury system is not used and therefore the judge does not have to exercise a .gate keeping. role, as he or she will be the final arbiter as to whether the evidence is reliable. In this context, reliability is considered during cross-examination. Cross-examination by the defence is crucial and this study proposes some possible cross-examination questions that can be helpful in testing the reliability of firearm identification evidence.
- Full Text:
- Date Issued: 2018
The impact of government support on growth, survival and performance of cooperatives in selected areas of Eastern Cape province; South Africa
- Authors: Mqaba, Mzuyanda Victor
- Date: 2015
- Subjects: Cooperative societies -- South Africa -- Eastern Cape Producer cooperatives -- South Africa -- Eastern Cape Agriculture, Cooperative -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Com (Business Management)
- Identifier: http://hdl.handle.net/10353/1612 , vital:27488
- Description: This study investigated the impact of government support on growth, survival and performance of agricultural cooperatives in selected areas of Eastern Cape Province of South Africa. The objectives of this empirical study were to examine (1) the impact of government support on growth of cooperatives, (2) assess the impact of government support on the performance of cooperatives, (3) reviewing the impact of government support on survival of cooperatives. A total sample of 157 agricultural cooperatives which consisted of poultry, maize, goat, nursery, sheep and vegetable coops was used. Stratified random sampling technique was used and a self-administered questionnaire used to gather primary data. The primary data of the study was gathered from the cooperatives managers only as they were the targeted respondents. Gathered data went through factor analysis, anova test and correlation analysis for the statistical analysis purposefully to arrive in study findings and conclusion. The findings of the study drawn from the 66% response rate concluded that government support has a statistical significant impact on growth of cooperatives. The study also indicated that government support has a significant impact on the survival of cooperatives. It is also reported that the performance of cooperatives is significantly impacted positively by government support. The findings of the study also indicated that agricultural cooperatives are not satisfied with the present government support.
- Full Text:
- Date Issued: 2015
- Authors: Mqaba, Mzuyanda Victor
- Date: 2015
- Subjects: Cooperative societies -- South Africa -- Eastern Cape Producer cooperatives -- South Africa -- Eastern Cape Agriculture, Cooperative -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Com (Business Management)
- Identifier: http://hdl.handle.net/10353/1612 , vital:27488
- Description: This study investigated the impact of government support on growth, survival and performance of agricultural cooperatives in selected areas of Eastern Cape Province of South Africa. The objectives of this empirical study were to examine (1) the impact of government support on growth of cooperatives, (2) assess the impact of government support on the performance of cooperatives, (3) reviewing the impact of government support on survival of cooperatives. A total sample of 157 agricultural cooperatives which consisted of poultry, maize, goat, nursery, sheep and vegetable coops was used. Stratified random sampling technique was used and a self-administered questionnaire used to gather primary data. The primary data of the study was gathered from the cooperatives managers only as they were the targeted respondents. Gathered data went through factor analysis, anova test and correlation analysis for the statistical analysis purposefully to arrive in study findings and conclusion. The findings of the study drawn from the 66% response rate concluded that government support has a statistical significant impact on growth of cooperatives. The study also indicated that government support has a significant impact on the survival of cooperatives. It is also reported that the performance of cooperatives is significantly impacted positively by government support. The findings of the study also indicated that agricultural cooperatives are not satisfied with the present government support.
- Full Text:
- Date Issued: 2015
The geology and metallogeny of the Otavi mountain land, Damara orogen, SWA/Namibia, with particular reference to the Berg Aukas Zn-Pb-V deposit a model of ore genesis
- Authors: Misiewicz, Julian Edward
- Date: 1988
- Subjects: Geology -- Namibia -- Damaraland , Ore deposits -- Namibia , Orogeny , Metallogeny , Geodynamics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4959 , http://hdl.handle.net/10962/d1005571 , Geology -- Namibia -- Damaraland , Ore deposits -- Namibia , Orogeny , Metallogeny , Geodynamics
- Description: The Olavi Mountain Land is a 10 000 km2 mineral province located at the eastern extremity of the exposed Northern Platform of the Damara Pan African orogenic belt. The Olavi Mountain Land is tbe most important mineral province on the Northern Platform. Exploitation of tbe Cu-Pb-Zn-V province has been on-going since the possession of the territory by the German colonial authority in 1890. Production has been mostly from four mines which in order of importance are Tsumeb, Kombat, Berg Aukas and Abeoab. A second mineral province on the Northern Platform located in the west is centred on Sesfontein where as yet only insignificant mineralization has been noted. Besides these localities, the Northern Platform is conspicuously devoid of notable mineralization. The aim of this thesis has been to document tbe Berg Aukas deposit, an important end-member type of mineralization in the Otavi Mountain Land. The basic premise bas been to show tbat the derivation and localization of the mineralization is a consequence of two broad controls which can be simply summarised as features of the basement and of the carbonate sequences. The geodynamic evolution of the Damara Belt commenced with intra-continental rifting approximately 900 Ma ago. Rift grabens trending north-east were filled by the Nosib Group which comprises mostly clastic lithologies but also some volcanics. The earliest and largest rift is referred to as the Northern Rift. Separation of the Congo, Kalahari, and proto-South American cratons resulted in rifting and rapid downwarping so that an encroaching sea and an Olavi Group carbonate shelf developed along the northern margin of the Northern Rift. Significantly, the carbonates only covered the Northern Rift in the area of the Otavi Mountain Land where a basinal dome, referred to as the Grootfontein Basement High, marked the basin edge. In the west, the carbonates covered the less important Sesfonfein Rift, and it is only in these two areas where Nosib sequences underlie the carbonate platform. Carbonate sedimentation was interrupted by a major period of crustal readjustment and the deposition of an extensive mixtite throughout the geosynclinal Swakop Trough and Northern Platform. This is referred to as the Chuos Formation and subdivides the Olavi Group into a lower Abenab and an upper Tsumeb Subgroup. Reversal of spreading led to plate collision and subduction of tbe Kalahari craton beneath the Congo craton. It was accompanied by orogenesis which resulted in F1 folding of the Northern Platform into a series of north-easterly trending intermontane basins into which a molasse sequence known as the Mulden Group was unconformably deposited. Following this major north-south deformation mild east-west compression initiated F2 folding and the formation of doubly plunging synclines. The Berg Aukas Syncline represents a primary depositional basin which was subsequently folded. The original basin was formed by late Nosib rifting wben spreading caused the Swakop geosynclinal Trough to form. Carbonates of the basal Berg Aukas Formation were deposited in a lagoonal setting typified by reef and fore-reef facies witb peri-platform conditions. Rapid subsidence caused these sediments to be overlain by deep water carbonates of the Gauss Formation. Two styles of mineralization known as the Tsumeb-type and Berg Aukas-type are stratigraphically, isotopically, and mineralogically distinct. The Tsumeb-type is a cupriferous variety of discordant bodies confined to the upper sequences beneath the Mulden unconformity. The Berg Aukas-type is a Zn-Pb variety confined to tbe basal unconformity. The Berg Aukas deposit comprises three ore bodies known as the Northern Ore Horizon, the Central Ore Body, and the Hanging Wall Ore Body. Sphalerite and galena constitute the bypogene ore. Willemite, smithsonite, cerussite, and descloizite are important supergene ores. A review of genetic models concludes that a magmatic origin initially proposed for tbe Tsumeb deposit is entirely rejected and a basin dewatering model in line with Mississippi Valley-type deposits is proposed. The syntectonic nature of mineralization at Berg Aukas and elsewhere in the Otavi Mountain Land indicates that orogenesis encouraged dewatering and leaching of metals from a broad mineralizing front along the margin of the Swakop Trough. These were transported by acidic saline brines which migrated along the clastic aquifers and structural conduits provided by the Northern Rift. Fluid inclusion studies indicate that the hydrothermal fluids at Berg Aukas were very saline (23% TDS) and were transported at temperatures ranging between 92° to 210°C. Hydrothermal fluids which mineralized Berg AukaS-type deposits migrated along the basal unconformity towards the basement high and were responsible for hydrothermally altering the basement granites and gabbros and the Nosib clastic rocks. Tsumeb-type deposits resulted by migration of fluids through the carbonate pile and along north-easterly trending basement geofractures. As a consequence of variation in transport, the Berg Aukas-type and Tsumeb-type fluids leached different sources and therefore derived mineralogically and isotopically seperable characteristics. The localization of the Berg Aukas ores was controlled by the carbonate stratigraphy and structure. Hydrothermal karsting and ore deposition took place on the contact between Massive Grey and Light Grey Dolostones which represents a permeability contrast. The movement of the hydrothermal fluids was controlled by north-south trending vertical fractures caused by F2 folding which resulted in a peric1inal structure. Hydrothermal karsting was accompanied by ca1citic, dolomitic and silicic alteration. The heated acidic fluids initiated solution collapse and a variety of breccia types. Supergene processes resulted in oxidation and upgrading of the ore. Vanadium derived indirectly from gabbros in the basement complex were transported as calcium metavanadate complexes and deposited on contact with the oxidizing base metal sulphides.
- Full Text:
- Date Issued: 1988
- Authors: Misiewicz, Julian Edward
- Date: 1988
- Subjects: Geology -- Namibia -- Damaraland , Ore deposits -- Namibia , Orogeny , Metallogeny , Geodynamics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4959 , http://hdl.handle.net/10962/d1005571 , Geology -- Namibia -- Damaraland , Ore deposits -- Namibia , Orogeny , Metallogeny , Geodynamics
- Description: The Olavi Mountain Land is a 10 000 km2 mineral province located at the eastern extremity of the exposed Northern Platform of the Damara Pan African orogenic belt. The Olavi Mountain Land is tbe most important mineral province on the Northern Platform. Exploitation of tbe Cu-Pb-Zn-V province has been on-going since the possession of the territory by the German colonial authority in 1890. Production has been mostly from four mines which in order of importance are Tsumeb, Kombat, Berg Aukas and Abeoab. A second mineral province on the Northern Platform located in the west is centred on Sesfontein where as yet only insignificant mineralization has been noted. Besides these localities, the Northern Platform is conspicuously devoid of notable mineralization. The aim of this thesis has been to document tbe Berg Aukas deposit, an important end-member type of mineralization in the Otavi Mountain Land. The basic premise bas been to show tbat the derivation and localization of the mineralization is a consequence of two broad controls which can be simply summarised as features of the basement and of the carbonate sequences. The geodynamic evolution of the Damara Belt commenced with intra-continental rifting approximately 900 Ma ago. Rift grabens trending north-east were filled by the Nosib Group which comprises mostly clastic lithologies but also some volcanics. The earliest and largest rift is referred to as the Northern Rift. Separation of the Congo, Kalahari, and proto-South American cratons resulted in rifting and rapid downwarping so that an encroaching sea and an Olavi Group carbonate shelf developed along the northern margin of the Northern Rift. Significantly, the carbonates only covered the Northern Rift in the area of the Otavi Mountain Land where a basinal dome, referred to as the Grootfontein Basement High, marked the basin edge. In the west, the carbonates covered the less important Sesfonfein Rift, and it is only in these two areas where Nosib sequences underlie the carbonate platform. Carbonate sedimentation was interrupted by a major period of crustal readjustment and the deposition of an extensive mixtite throughout the geosynclinal Swakop Trough and Northern Platform. This is referred to as the Chuos Formation and subdivides the Olavi Group into a lower Abenab and an upper Tsumeb Subgroup. Reversal of spreading led to plate collision and subduction of tbe Kalahari craton beneath the Congo craton. It was accompanied by orogenesis which resulted in F1 folding of the Northern Platform into a series of north-easterly trending intermontane basins into which a molasse sequence known as the Mulden Group was unconformably deposited. Following this major north-south deformation mild east-west compression initiated F2 folding and the formation of doubly plunging synclines. The Berg Aukas Syncline represents a primary depositional basin which was subsequently folded. The original basin was formed by late Nosib rifting wben spreading caused the Swakop geosynclinal Trough to form. Carbonates of the basal Berg Aukas Formation were deposited in a lagoonal setting typified by reef and fore-reef facies witb peri-platform conditions. Rapid subsidence caused these sediments to be overlain by deep water carbonates of the Gauss Formation. Two styles of mineralization known as the Tsumeb-type and Berg Aukas-type are stratigraphically, isotopically, and mineralogically distinct. The Tsumeb-type is a cupriferous variety of discordant bodies confined to the upper sequences beneath the Mulden unconformity. The Berg Aukas-type is a Zn-Pb variety confined to tbe basal unconformity. The Berg Aukas deposit comprises three ore bodies known as the Northern Ore Horizon, the Central Ore Body, and the Hanging Wall Ore Body. Sphalerite and galena constitute the bypogene ore. Willemite, smithsonite, cerussite, and descloizite are important supergene ores. A review of genetic models concludes that a magmatic origin initially proposed for tbe Tsumeb deposit is entirely rejected and a basin dewatering model in line with Mississippi Valley-type deposits is proposed. The syntectonic nature of mineralization at Berg Aukas and elsewhere in the Otavi Mountain Land indicates that orogenesis encouraged dewatering and leaching of metals from a broad mineralizing front along the margin of the Swakop Trough. These were transported by acidic saline brines which migrated along the clastic aquifers and structural conduits provided by the Northern Rift. Fluid inclusion studies indicate that the hydrothermal fluids at Berg Aukas were very saline (23% TDS) and were transported at temperatures ranging between 92° to 210°C. Hydrothermal fluids which mineralized Berg AukaS-type deposits migrated along the basal unconformity towards the basement high and were responsible for hydrothermally altering the basement granites and gabbros and the Nosib clastic rocks. Tsumeb-type deposits resulted by migration of fluids through the carbonate pile and along north-easterly trending basement geofractures. As a consequence of variation in transport, the Berg Aukas-type and Tsumeb-type fluids leached different sources and therefore derived mineralogically and isotopically seperable characteristics. The localization of the Berg Aukas ores was controlled by the carbonate stratigraphy and structure. Hydrothermal karsting and ore deposition took place on the contact between Massive Grey and Light Grey Dolostones which represents a permeability contrast. The movement of the hydrothermal fluids was controlled by north-south trending vertical fractures caused by F2 folding which resulted in a peric1inal structure. Hydrothermal karsting was accompanied by ca1citic, dolomitic and silicic alteration. The heated acidic fluids initiated solution collapse and a variety of breccia types. Supergene processes resulted in oxidation and upgrading of the ore. Vanadium derived indirectly from gabbros in the basement complex were transported as calcium metavanadate complexes and deposited on contact with the oxidizing base metal sulphides.
- Full Text:
- Date Issued: 1988
The experiences of couples in relationships characterized by alcohol dependency
- Authors: Mgilane, Nomgcobo Eunice
- Date: 2001
- Subjects: Alcoholism -- South Africa Alcoholics -- Family relationships Alcoholics' spouses -- South Africa Alcoholics -- South Africa -- Conduct of life
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:702 , http://hdl.handle.net/10962/d1006461
- Description: The study focused on the expenences of Xhosa-speaking couples in relationships characterized by alcohol dependency. The goal was to generate greater understanding of the descriptions of relationship issues faced by alcohol dependent respondents and their partners. Specifically, the study focused on exploring how the alcohol dependent respondents relate to their partners, their behaviour at home when drinking prior to their admission for rehabilitation, the experiences of their partners in living with alcohol dependent partners and how they coped with the situation. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the alcohol dependent individual's behaviour, his emotions, relapse, the family's coping strategies, alcohol and marital problems and the role of the social worker as part of the rehabilitation team. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Fifteen alcohol dependent clients who were admitted for treatment and rehabilitation at Thembelitsha Rehabilitation Centre (TRC) were selected. These clients were admitted to TRC during the period starting from January 1997 to June 1999 and were discharged to their homes during the research study. To collect data, interviews were conducted separately to a total of thirty respondents. Two interview schedules were used, one for the alcohol dependent respondents (Appendix A) and the other for their partners (Appendix B). This study revealed a remarkable consistency in the descriptions of relationship issues faced by alcohol dependent respondents and their partners. These are abusive behaviours by alcohol dependent respondents. The partners were reluctant and feared challenging the behaviour. The way in which partners responded to drinking and the reactions of alcohol dependent respondents are indicative of the difficult issues faced by the couples. The study also revealed that couples experience communication, financial and sexual relationship problems. The study concludes with recommendations based on the research findings
- Full Text:
- Date Issued: 2001
- Authors: Mgilane, Nomgcobo Eunice
- Date: 2001
- Subjects: Alcoholism -- South Africa Alcoholics -- Family relationships Alcoholics' spouses -- South Africa Alcoholics -- South Africa -- Conduct of life
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:702 , http://hdl.handle.net/10962/d1006461
- Description: The study focused on the expenences of Xhosa-speaking couples in relationships characterized by alcohol dependency. The goal was to generate greater understanding of the descriptions of relationship issues faced by alcohol dependent respondents and their partners. Specifically, the study focused on exploring how the alcohol dependent respondents relate to their partners, their behaviour at home when drinking prior to their admission for rehabilitation, the experiences of their partners in living with alcohol dependent partners and how they coped with the situation. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the alcohol dependent individual's behaviour, his emotions, relapse, the family's coping strategies, alcohol and marital problems and the role of the social worker as part of the rehabilitation team. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Fifteen alcohol dependent clients who were admitted for treatment and rehabilitation at Thembelitsha Rehabilitation Centre (TRC) were selected. These clients were admitted to TRC during the period starting from January 1997 to June 1999 and were discharged to their homes during the research study. To collect data, interviews were conducted separately to a total of thirty respondents. Two interview schedules were used, one for the alcohol dependent respondents (Appendix A) and the other for their partners (Appendix B). This study revealed a remarkable consistency in the descriptions of relationship issues faced by alcohol dependent respondents and their partners. These are abusive behaviours by alcohol dependent respondents. The partners were reluctant and feared challenging the behaviour. The way in which partners responded to drinking and the reactions of alcohol dependent respondents are indicative of the difficult issues faced by the couples. The study also revealed that couples experience communication, financial and sexual relationship problems. The study concludes with recommendations based on the research findings
- Full Text:
- Date Issued: 2001
The effectiveness of public participation in the environmental politics of hydraulic fracturing : the case of the Great Karoo
- Kalipa-Mini, Nomampondomise Cynthia
- Authors: Kalipa-Mini, Nomampondomise Cynthia
- Date: 2018
- Subjects: Hydraulic fracturing Hydraulic fracturing -- Environmental aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Environmental Studies
- Identifier: http://hdl.handle.net/10353/10779 , vital:35760
- Description: Shale gas has become a part of the world’s energy mix. South Africa (SA) is facing huge energy problems and job creation challenges whilst the Karoo region has large amounts of shale gas reserves. It is against this background that the South African government is considering fracking, showing interest by lifting fracking ban and repeatedly calling it a game changer. This generated debates among environmentalists, farmer groups, capitalists, politicians, researchers and community groups, as they voiced their views regarding fracking. The debates influenced the study to focus on public participation regarding the Karoo fracking initiative, with particular emphasis on the marginalised persons. The aim was to examine the effectiveness of public participation in the environmental politics of fracking in the Great Karoo region in Eastern Cape Province. The study adopted a qualitative case study approach through document analysis, questionnaires given to the interested and affected parties, relevant government department, local municipality and non-governmental organisations as well as focus group discussions with 35 participants from marginalised groupings. It was grounded on the Integrated Environmental Management (IEM) paradigm using the outcomes-based framework in the thematic analysis of the collected data. The results showed little evidence of social learning among the marginalised persons when the collected data was benchmarked against the chosen pillars of the IEM paradigm within the outcomes-based approach. These results convey that effective and developmental public participation should be empowering, informing and educating rather than merely serving documentary purposes.
- Full Text:
- Date Issued: 2018
- Authors: Kalipa-Mini, Nomampondomise Cynthia
- Date: 2018
- Subjects: Hydraulic fracturing Hydraulic fracturing -- Environmental aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Environmental Studies
- Identifier: http://hdl.handle.net/10353/10779 , vital:35760
- Description: Shale gas has become a part of the world’s energy mix. South Africa (SA) is facing huge energy problems and job creation challenges whilst the Karoo region has large amounts of shale gas reserves. It is against this background that the South African government is considering fracking, showing interest by lifting fracking ban and repeatedly calling it a game changer. This generated debates among environmentalists, farmer groups, capitalists, politicians, researchers and community groups, as they voiced their views regarding fracking. The debates influenced the study to focus on public participation regarding the Karoo fracking initiative, with particular emphasis on the marginalised persons. The aim was to examine the effectiveness of public participation in the environmental politics of fracking in the Great Karoo region in Eastern Cape Province. The study adopted a qualitative case study approach through document analysis, questionnaires given to the interested and affected parties, relevant government department, local municipality and non-governmental organisations as well as focus group discussions with 35 participants from marginalised groupings. It was grounded on the Integrated Environmental Management (IEM) paradigm using the outcomes-based framework in the thematic analysis of the collected data. The results showed little evidence of social learning among the marginalised persons when the collected data was benchmarked against the chosen pillars of the IEM paradigm within the outcomes-based approach. These results convey that effective and developmental public participation should be empowering, informing and educating rather than merely serving documentary purposes.
- Full Text:
- Date Issued: 2018
The design and synthesis of novel HIV-1 protease inhibitors
- Authors: Tukulula, Matshawandile
- Date: 2009
- Subjects: Protease Inhibitors HIV infections -- Treatment AIDS (Disease) -- Treatment HIV (Viruses) Indolizine -- Derivatives Heterocyclic compounds -- Derivatives Nuclear magnetic resonance Quinoline
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4305 , http://hdl.handle.net/10962/d1004963
- Description: This study has focused on the synthesis of truncated analogues of the hydroxyethylene dipeptide isosteres, such as Ritonavir®, currently in clinical use as HIV-1 protease inhibitors. The reactions of pyridine-2- and quinoline-2-carbaldehydes with methyl acrylate, in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) or 3- hydroxyquinuclidine (3-HQ) as nucleophilic catalysts, have afforded a series of Baylis- Hillman adducts, acetylation and cyclisation of which have provided access to a series of indolizine-2-carboxylate esters. The carboxylic acids, obtained by base-catalyzed hydrolysis of these esters, have been coupled with various protected (and unprotected) amino compounds using the peptide coupling agent, 1,1’-carbonyldiimidazole (CDI), to afford a series of indolizine-2-carboxamides as indolizine-based truncated Ritonavir® analogues in quantitative yield. Aza-Michael reactions of pyridine-3-carbaldehydederived Baylis-Hillman adducts with various amino compounds have provided access to a range of pyridine-based products as mixtures of diastereomeric aza-Michael products. The assignment of the relative stereochemistry of the aza-Michael products has been established using 1-D and 2-NOESY experiments and computer modelling techniques. Computer modelling studies have also been conducted on selected aza-Michael products using ACCELRYS Cerius2 software, followed by interactive docking into the HIV-1 protease receptor site, using AUTODOCK 4.0. The docking studies have revealed hydrogen-bonding interactions between the enzyme and the synthetic ligands. Saturation Transfer Difference (STD) NMR experiments have also indicated binding of some of the aza-Michael products to the HIV-1 protease subtype C enzyme, thus indicating their binding and possible inhibitory potential.
- Full Text:
- Date Issued: 2009
- Authors: Tukulula, Matshawandile
- Date: 2009
- Subjects: Protease Inhibitors HIV infections -- Treatment AIDS (Disease) -- Treatment HIV (Viruses) Indolizine -- Derivatives Heterocyclic compounds -- Derivatives Nuclear magnetic resonance Quinoline
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4305 , http://hdl.handle.net/10962/d1004963
- Description: This study has focused on the synthesis of truncated analogues of the hydroxyethylene dipeptide isosteres, such as Ritonavir®, currently in clinical use as HIV-1 protease inhibitors. The reactions of pyridine-2- and quinoline-2-carbaldehydes with methyl acrylate, in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) or 3- hydroxyquinuclidine (3-HQ) as nucleophilic catalysts, have afforded a series of Baylis- Hillman adducts, acetylation and cyclisation of which have provided access to a series of indolizine-2-carboxylate esters. The carboxylic acids, obtained by base-catalyzed hydrolysis of these esters, have been coupled with various protected (and unprotected) amino compounds using the peptide coupling agent, 1,1’-carbonyldiimidazole (CDI), to afford a series of indolizine-2-carboxamides as indolizine-based truncated Ritonavir® analogues in quantitative yield. Aza-Michael reactions of pyridine-3-carbaldehydederived Baylis-Hillman adducts with various amino compounds have provided access to a range of pyridine-based products as mixtures of diastereomeric aza-Michael products. The assignment of the relative stereochemistry of the aza-Michael products has been established using 1-D and 2-NOESY experiments and computer modelling techniques. Computer modelling studies have also been conducted on selected aza-Michael products using ACCELRYS Cerius2 software, followed by interactive docking into the HIV-1 protease receptor site, using AUTODOCK 4.0. The docking studies have revealed hydrogen-bonding interactions between the enzyme and the synthetic ligands. Saturation Transfer Difference (STD) NMR experiments have also indicated binding of some of the aza-Michael products to the HIV-1 protease subtype C enzyme, thus indicating their binding and possible inhibitory potential.
- Full Text:
- Date Issued: 2009
Students’ perceptions of their employability as revealed by their understandings of the South African Labour Market
- Authors: Gabobegwe, Maoshadi Keletso
- Date: 2019
- Language: English
- Type: text , Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/71482 , vital:29857
- Description: The state of the South African labour market is characterized −among other things− by inequalities and the chronic issue of unemployment, with a rate that has come up to 27.7% in the third quarter of 2017. Considering this, unemployment in South Africa is explained by numerous authors as a structural issue. In a sense that unemployed people do not have the skills required by the labour market. But, since education attainment improves an individuals’ employment prospects and outcome. It would be expected that people with higher education would have high prospects of getting employment. Yet, people with higher education qualifications also face challenges of obtaining employment. Even though research finds that graduate unemployment is not as bad when compared to general and overall unemployment of the country. It still remains that skills shortages and/or mismatch are deemed to be the main contributor of the South African graduate unemployment. Existing research finds that just as the labour market is characterized with differences on the grounds of gender and race. This also reflects on how graduates enter the labour market. With the white race having more employment outcomes than blacks and males than females. It is against this background that this dissertation set out to explore what Rhodes University final-year students’ −who are nearing the transition from varsity to the labour market− perceive to be their employment prospects and outcomes. Taking into consideration the issue of unemployment and inequalities in the labour market. In essence, one of the key issues that the dissertation focuses on, is what students think of their employability based on their understanding of the labour market. More than that, the dissertation investigates how aspects such as the student’s field of study, race and gender factor into how students understand the labour market and ultimately how they perceive their employment prospects and outcomes. As a consequence, evidence suggests that students’ perceptions of the labour market influences how they perceive their employability. Over and above, the research finds that the students field of study especially, features significantly in how students perceive the labour market and their employability. While race and gender also factored in students’ responses, it was not as significant as compared to their field of study respectively. The general finding is that students are well aware of the issues of the labour market and are concerned about the implications of these issues on their employability. This awareness and concern varied based on students’ field of study, race and gender.
- Full Text:
- Date Issued: 2019
- Authors: Gabobegwe, Maoshadi Keletso
- Date: 2019
- Language: English
- Type: text , Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/71482 , vital:29857
- Description: The state of the South African labour market is characterized −among other things− by inequalities and the chronic issue of unemployment, with a rate that has come up to 27.7% in the third quarter of 2017. Considering this, unemployment in South Africa is explained by numerous authors as a structural issue. In a sense that unemployed people do not have the skills required by the labour market. But, since education attainment improves an individuals’ employment prospects and outcome. It would be expected that people with higher education would have high prospects of getting employment. Yet, people with higher education qualifications also face challenges of obtaining employment. Even though research finds that graduate unemployment is not as bad when compared to general and overall unemployment of the country. It still remains that skills shortages and/or mismatch are deemed to be the main contributor of the South African graduate unemployment. Existing research finds that just as the labour market is characterized with differences on the grounds of gender and race. This also reflects on how graduates enter the labour market. With the white race having more employment outcomes than blacks and males than females. It is against this background that this dissertation set out to explore what Rhodes University final-year students’ −who are nearing the transition from varsity to the labour market− perceive to be their employment prospects and outcomes. Taking into consideration the issue of unemployment and inequalities in the labour market. In essence, one of the key issues that the dissertation focuses on, is what students think of their employability based on their understanding of the labour market. More than that, the dissertation investigates how aspects such as the student’s field of study, race and gender factor into how students understand the labour market and ultimately how they perceive their employment prospects and outcomes. As a consequence, evidence suggests that students’ perceptions of the labour market influences how they perceive their employability. Over and above, the research finds that the students field of study especially, features significantly in how students perceive the labour market and their employability. While race and gender also factored in students’ responses, it was not as significant as compared to their field of study respectively. The general finding is that students are well aware of the issues of the labour market and are concerned about the implications of these issues on their employability. This awareness and concern varied based on students’ field of study, race and gender.
- Full Text:
- Date Issued: 2019
Some measurements of the conductivities of dilute potassium chloride solutions
- Authors: Faure, Abraham
- Date: 1954
- Subjects: Potassium chloride
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4471 , http://hdl.handle.net/10962/d1011787
- Description: A constant temperature room has been constructed in which the thermoregulator is controlled by a temperature-sensitive resistance. A thermostat has been constructed in which the 0 temperature is controlled to within 0.001°C. A precision conductance bridge has been built in a very convenient form. Improvements include the replacement of the telephone as null detector by a cathode ray oscilloscope, and the use of a resistance-capacity phase-shift oscillator, which gives a good wave-form. An automatic recycling conductance water still has been built which regularly gives water with a conductivity less than 0.09 micromhos per cm. The conductivities of dilute KCl solutions have been measured, taking special care to prevent errors due to the adsorption of KCl on the surface of glass. Two cells were used for these measurements : a modified Jones cell, and a special conductimetric titration cell. The modified Jones cell has given results in good agreement with the generally-accepted values. The results of the conductimetric titration cell do not agree well with the generally-accepted values; the greatest difference (for the most dilute solution) is 0.4%. The reason for this is not known.
- Full Text:
- Date Issued: 1954
- Authors: Faure, Abraham
- Date: 1954
- Subjects: Potassium chloride
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4471 , http://hdl.handle.net/10962/d1011787
- Description: A constant temperature room has been constructed in which the thermoregulator is controlled by a temperature-sensitive resistance. A thermostat has been constructed in which the 0 temperature is controlled to within 0.001°C. A precision conductance bridge has been built in a very convenient form. Improvements include the replacement of the telephone as null detector by a cathode ray oscilloscope, and the use of a resistance-capacity phase-shift oscillator, which gives a good wave-form. An automatic recycling conductance water still has been built which regularly gives water with a conductivity less than 0.09 micromhos per cm. The conductivities of dilute KCl solutions have been measured, taking special care to prevent errors due to the adsorption of KCl on the surface of glass. Two cells were used for these measurements : a modified Jones cell, and a special conductimetric titration cell. The modified Jones cell has given results in good agreement with the generally-accepted values. The results of the conductimetric titration cell do not agree well with the generally-accepted values; the greatest difference (for the most dilute solution) is 0.4%. The reason for this is not known.
- Full Text:
- Date Issued: 1954
Research into entrepreneurship and small business in South Africa: current status and future challenges
- Authors: Tai-Hing, Paul
- Date: 2012
- Subjects: Entrepreneurship -- South Africa , Small business -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8794 , http://hdl.handle.net/10948/d1015981
- Description: This research seeks to advance knowledge of the current state of entrepreneurship and small businesses in South Africa, and reports on a review of 32 articles and 244 research abstracts in the field. The studies as a whole indicate that entrepreneurs in South Africa require more knowledge in the fields of: Networking in business, Internationalisation of business, Entrepreneurship training. Since the 1990s, research in entrepreneurship has grown in terms of the number of articles published and conference papers presented. In many countries entrepreneurship has also become part of the political agenda as it is perceived as a possible solution to high unemployment rates. In addition, interest in entrepreneurship has heightened during the 2000s, especially in business schools. Much of this interest is driven by student demand for courses in entrepreneurship, either because of genuine interest in the subject, or because students see entrepreneurship education as a useful hedge given uncertain corporate careers. Most of the entrepreneurship research abstracts reviewed for this study focused on race, gender and ethical issues in South Africa. These three research topics focused on: Attitudes and experiences of black women: differ from other racial groups in business with the results indicating that black women were competent and highly-motivated, but lacked communication skills and Western business orientation. Many black women also desired equality although their male counterparts opposed this. Black women also lacked role models and career guidance. Different population groups participate in the economy: reflect regional, income, expenditure, skill, occupational and labour differences, including labour supply and demand. Ethics concerns: include whether it should be taught in the human resources management curricula taught in universities. From the findings it appeared that entrepreneurship research in South Africa is fairly similar to international research contexts. As entrepreneurship and small businesses are diverse and multi-disciplinary, the studies reviewed indicated a wide range of different models, theories, frameworks, and combinations of these. However, the theoretical richness of the studies reviewed was, in many cases, relatively low, and only a few of the studies could be regarded as highly-theoretical. In addition, the presentation of the various theories and models applied was very often inadequately reported. It is also important to note that altogether between 7 and 11 percent of the studies were without any well-argued theoretical framework. Thus, researchers in the field should discuss the theoretical frameworks applied in their empirical analyses, to ensure this will improve the theoretical understanding of the phenomenon. Although this study made use of the mixed-method approach to conduct the research, it is also important to note that, in 12 percent of cases, methodological issues were poorly described. Most of the studies often did not describe the data collection response rate provide sample demographic and firm size details as well as identify the target industry. These details were often missing or loosely defined. The reasons for the selection of a certain research approach were also poorly explained, making many of the research studies deficient or limited methodologically. These omissions present a challenge, not only to authors in the field, but also to reviewers and editors in academic journals, as this impacts on the scientific rigor of published papers. On the basis of published papers reviewed, it seems that, personally-administered data collection works best in South Africa. From the research studies undertaken in South Africa, it is evident that much has been researched in the areas of gender (specifically the role of women in business), entrepreneurship training and ethics in business. It is evident that during the 1980s, no research was conducted in South Africa in the areas of family businesses and entrepreneurship training, while international research focuses on these topics. During the 1990s, no research focused on networking in small businesses, and. during the 2000s, there was a lack of research on internationalisation of businesses as only six articles were published from 2000 until 2011 on these topics. This highlights a need for internationalisation research especially as it is well-documented that the South African economy cannot survive if it does not take cognisance of its international competitors. On the basis of the articles and abstracts reviewed, the current state of knowledge concerning entrepreneurship and small businesses in South Africa was assessed, especially the need for the internationalisation of South African small businesses. Moreover, research studies could also focus on the obstacles encountered in the internationalisation process of South African small businesses.
- Full Text:
- Date Issued: 2012
- Authors: Tai-Hing, Paul
- Date: 2012
- Subjects: Entrepreneurship -- South Africa , Small business -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8794 , http://hdl.handle.net/10948/d1015981
- Description: This research seeks to advance knowledge of the current state of entrepreneurship and small businesses in South Africa, and reports on a review of 32 articles and 244 research abstracts in the field. The studies as a whole indicate that entrepreneurs in South Africa require more knowledge in the fields of: Networking in business, Internationalisation of business, Entrepreneurship training. Since the 1990s, research in entrepreneurship has grown in terms of the number of articles published and conference papers presented. In many countries entrepreneurship has also become part of the political agenda as it is perceived as a possible solution to high unemployment rates. In addition, interest in entrepreneurship has heightened during the 2000s, especially in business schools. Much of this interest is driven by student demand for courses in entrepreneurship, either because of genuine interest in the subject, or because students see entrepreneurship education as a useful hedge given uncertain corporate careers. Most of the entrepreneurship research abstracts reviewed for this study focused on race, gender and ethical issues in South Africa. These three research topics focused on: Attitudes and experiences of black women: differ from other racial groups in business with the results indicating that black women were competent and highly-motivated, but lacked communication skills and Western business orientation. Many black women also desired equality although their male counterparts opposed this. Black women also lacked role models and career guidance. Different population groups participate in the economy: reflect regional, income, expenditure, skill, occupational and labour differences, including labour supply and demand. Ethics concerns: include whether it should be taught in the human resources management curricula taught in universities. From the findings it appeared that entrepreneurship research in South Africa is fairly similar to international research contexts. As entrepreneurship and small businesses are diverse and multi-disciplinary, the studies reviewed indicated a wide range of different models, theories, frameworks, and combinations of these. However, the theoretical richness of the studies reviewed was, in many cases, relatively low, and only a few of the studies could be regarded as highly-theoretical. In addition, the presentation of the various theories and models applied was very often inadequately reported. It is also important to note that altogether between 7 and 11 percent of the studies were without any well-argued theoretical framework. Thus, researchers in the field should discuss the theoretical frameworks applied in their empirical analyses, to ensure this will improve the theoretical understanding of the phenomenon. Although this study made use of the mixed-method approach to conduct the research, it is also important to note that, in 12 percent of cases, methodological issues were poorly described. Most of the studies often did not describe the data collection response rate provide sample demographic and firm size details as well as identify the target industry. These details were often missing or loosely defined. The reasons for the selection of a certain research approach were also poorly explained, making many of the research studies deficient or limited methodologically. These omissions present a challenge, not only to authors in the field, but also to reviewers and editors in academic journals, as this impacts on the scientific rigor of published papers. On the basis of published papers reviewed, it seems that, personally-administered data collection works best in South Africa. From the research studies undertaken in South Africa, it is evident that much has been researched in the areas of gender (specifically the role of women in business), entrepreneurship training and ethics in business. It is evident that during the 1980s, no research was conducted in South Africa in the areas of family businesses and entrepreneurship training, while international research focuses on these topics. During the 1990s, no research focused on networking in small businesses, and. during the 2000s, there was a lack of research on internationalisation of businesses as only six articles were published from 2000 until 2011 on these topics. This highlights a need for internationalisation research especially as it is well-documented that the South African economy cannot survive if it does not take cognisance of its international competitors. On the basis of the articles and abstracts reviewed, the current state of knowledge concerning entrepreneurship and small businesses in South Africa was assessed, especially the need for the internationalisation of South African small businesses. Moreover, research studies could also focus on the obstacles encountered in the internationalisation process of South African small businesses.
- Full Text:
- Date Issued: 2012
Morphometrics and reproduction of Terebrasabella heterouncinata (Polychaeta:Sabellidae), infesting abalone (Haliotis midae) from different culture environments
- Authors: Gray, Michael
- Date: 2003
- Subjects: Polychaeta , Sabellidae , Abalones -- Physiology , Abalones -- Nutrition , Abalone culture
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5384 , http://hdl.handle.net/10962/d1018231
- Description: In the late 1980's abalone culturalists noticed reduced growth rate and shell deformities in some abalone stocks. These problems were the result of infestations by a shell boring polychaete, Terebrasabella heterouncinata. Under intensive abalone culture conditions the level of infestation can reach epidemic proportions and there are often severe consequences for the host abalone. Heavy sabellid infestation levels have placed the economic viability of several South African farms under threat. This study formed part of an ongoing project that is aimed at investigating the basic biology of Terebrasabella heterouncinata. The majority of abalone farmers in South Africa feed their abalone either naturally occurring kelp (Ecklonia maxima) or the formulated abalone feed, Abfeed. Farmers have suggested that the use of Abfeed is associated with higher sabellid infestation levels and changing the abalone diet from Abfeed to kelp helps reduce sabellid infestation. Speculation has arisen indicating that older, slower growing abalone are more susceptible to sabellid infestation. The effect of host abalone diet history and their growth on sabellid settlement success, morphometries and reproduction was quantified. To better understand the plasticity of the expression of life history traits the variability of morphometric and reproductive characteristics was compared between different farm environments. And more...
- Full Text:
- Date Issued: 2003
- Authors: Gray, Michael
- Date: 2003
- Subjects: Polychaeta , Sabellidae , Abalones -- Physiology , Abalones -- Nutrition , Abalone culture
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5384 , http://hdl.handle.net/10962/d1018231
- Description: In the late 1980's abalone culturalists noticed reduced growth rate and shell deformities in some abalone stocks. These problems were the result of infestations by a shell boring polychaete, Terebrasabella heterouncinata. Under intensive abalone culture conditions the level of infestation can reach epidemic proportions and there are often severe consequences for the host abalone. Heavy sabellid infestation levels have placed the economic viability of several South African farms under threat. This study formed part of an ongoing project that is aimed at investigating the basic biology of Terebrasabella heterouncinata. The majority of abalone farmers in South Africa feed their abalone either naturally occurring kelp (Ecklonia maxima) or the formulated abalone feed, Abfeed. Farmers have suggested that the use of Abfeed is associated with higher sabellid infestation levels and changing the abalone diet from Abfeed to kelp helps reduce sabellid infestation. Speculation has arisen indicating that older, slower growing abalone are more susceptible to sabellid infestation. The effect of host abalone diet history and their growth on sabellid settlement success, morphometries and reproduction was quantified. To better understand the plasticity of the expression of life history traits the variability of morphometric and reproductive characteristics was compared between different farm environments. And more...
- Full Text:
- Date Issued: 2003
Invasion of Lantana into India: analyzing introduction, spread, human adaptations and management
- Hari Krishnan, Ramesh Kannan
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
Heterotrophic carbon dioxide fixation by Euglena
- Authors: Peak, Jennifer Grace
- Date: 1978
- Subjects: Euglena
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5824 , http://hdl.handle.net/10962/d1007650
- Description: Heterotrophic (dark, non-photosynthetic) carbon dioxide fixation was measured in the phytoflagellate Euglena gracilis. Variation in heterotrophic carbon dioxide fixation depends on the phase of batch growth and the mode of nutrition. A sharp increase in heterotrophic carbon dioxide fixation occurs during the mid- to late-logarithmic growth periods in Euglena growing photoautotrophically (with carbon dioxide as carbon source, light as energy source) and heterotrophically (in the dark with glucose as sole carbon and energy source). Cells growing heterotrophically with acetate or ethanol as sole carbon source do not increase their heterotrophic carbon dioxide fixation during the growth cycle. Addition of acetate to cultures of Euglena causes a reduction in dark carbon dioxide fixation. The results are consistent with the hypothesis that heterotrophic carbon dioxide fixation in Euglena functions in anaplerotic replenishment of the tricarboxylic acid cycle. The regulation of these changes in heterotrophic carbon dioxide fixation was shown to be controlled by exogenous ammonium in a complex fashion. Ammonium stimulates heterotrophic carbon dioxide fixation after a period of ammonium deprivation. The kinetics of the regulatory effects of the ammonium ion on dark carbon dioxide fixation are presented. A survey into the activities of carboxylating enzymes from both autotrophically and heterotrophically grown Euglena was conducted. The heterotrophic cultures were supplied with either glucose or acetate as substrate. PEP carboxykinase (E.C.4.1.1.38) and (E.C.4.1.1.49) could not be detected in any of the cultures tested. A trace amount of PEP carboxykinase (E.C.4.1.1.32) is present in the acetate grown cells only and a trace amount of pyruvate carboxylase (E.C.6.4.1.1.) is present in the glucose grown cells only. Malate enzyme (E.C.1.1.1.40), PEP carboxylase (E.C.4.1.1.31) and acetylcoenzyme A carboxylase (E.C.6.4.1.2) are present in all cells tested. Ammonium stimulation causes a small increase in specific activity of all the enzymes except acetyl-CoA carboxylase. The largest increase occurs in PEP carboxylase, but the increase is not sufficient to account for observed increases in whole cell dark carbon dioxide fixation after ammonium stimulation. Two isoenzymes of PEP carboxylase were purified from each other from both ammonium stimulated and non-stimulated cells. There are no significant differences between elution profiles of isoenzymes from ammonium stimulated and control cells. There are no significant differences between elution profiles of isoenzymes from autotrophic and heterotrophic cells. The kinetics of the regulation of the two isoenzymes by malate, citrate, succinate and 3-phosphoglycerate are presented. The products of heterotrophic carbon dioxide fixation by ammonium stimulated and control cells were identified and measured by chromatography. Ammonium stimulates the biosynthesis of glutamine, glycine, serine and alanine.
- Full Text:
- Date Issued: 1978
- Authors: Peak, Jennifer Grace
- Date: 1978
- Subjects: Euglena
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5824 , http://hdl.handle.net/10962/d1007650
- Description: Heterotrophic (dark, non-photosynthetic) carbon dioxide fixation was measured in the phytoflagellate Euglena gracilis. Variation in heterotrophic carbon dioxide fixation depends on the phase of batch growth and the mode of nutrition. A sharp increase in heterotrophic carbon dioxide fixation occurs during the mid- to late-logarithmic growth periods in Euglena growing photoautotrophically (with carbon dioxide as carbon source, light as energy source) and heterotrophically (in the dark with glucose as sole carbon and energy source). Cells growing heterotrophically with acetate or ethanol as sole carbon source do not increase their heterotrophic carbon dioxide fixation during the growth cycle. Addition of acetate to cultures of Euglena causes a reduction in dark carbon dioxide fixation. The results are consistent with the hypothesis that heterotrophic carbon dioxide fixation in Euglena functions in anaplerotic replenishment of the tricarboxylic acid cycle. The regulation of these changes in heterotrophic carbon dioxide fixation was shown to be controlled by exogenous ammonium in a complex fashion. Ammonium stimulates heterotrophic carbon dioxide fixation after a period of ammonium deprivation. The kinetics of the regulatory effects of the ammonium ion on dark carbon dioxide fixation are presented. A survey into the activities of carboxylating enzymes from both autotrophically and heterotrophically grown Euglena was conducted. The heterotrophic cultures were supplied with either glucose or acetate as substrate. PEP carboxykinase (E.C.4.1.1.38) and (E.C.4.1.1.49) could not be detected in any of the cultures tested. A trace amount of PEP carboxykinase (E.C.4.1.1.32) is present in the acetate grown cells only and a trace amount of pyruvate carboxylase (E.C.6.4.1.1.) is present in the glucose grown cells only. Malate enzyme (E.C.1.1.1.40), PEP carboxylase (E.C.4.1.1.31) and acetylcoenzyme A carboxylase (E.C.6.4.1.2) are present in all cells tested. Ammonium stimulation causes a small increase in specific activity of all the enzymes except acetyl-CoA carboxylase. The largest increase occurs in PEP carboxylase, but the increase is not sufficient to account for observed increases in whole cell dark carbon dioxide fixation after ammonium stimulation. Two isoenzymes of PEP carboxylase were purified from each other from both ammonium stimulated and non-stimulated cells. There are no significant differences between elution profiles of isoenzymes from ammonium stimulated and control cells. There are no significant differences between elution profiles of isoenzymes from autotrophic and heterotrophic cells. The kinetics of the regulation of the two isoenzymes by malate, citrate, succinate and 3-phosphoglycerate are presented. The products of heterotrophic carbon dioxide fixation by ammonium stimulated and control cells were identified and measured by chromatography. Ammonium stimulates the biosynthesis of glutamine, glycine, serine and alanine.
- Full Text:
- Date Issued: 1978
Grade 5 teachers' understanding and development of concepts in social studies in selected schools in Namibia
- Authors: Sichombe, Beatrice Sinyama
- Date: 2007
- Subjects: Social sciences -- Study and teaching (Elementary) -- Namibia Social science teachers -- Namibia Educational change -- Namibia Education -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1877 , http://hdl.handle.net/10962/d1005856
- Description: After the introduction of Learner Centred Education in Namibia, a number of studies were conducted on how teachers either perceived learner centred education or implemented it. However, very few studies investigated the teachers' understanding of both subject matter knowledge and pedagogical content knowledge; primarily, how they understand and develop key concepts. The purpose of this study was to investigate how Grade 5 teachers' understand and develop key concepts in Social Studies in selected schools in Namibia. The study focused on three teachers in three primary schools in the Caprivi educational region of Namibia. These teachers were purposefully selected as graduates of the teacher education programme instituted at the time of the Namibian education reform process. As a teacher educator, my main motive of conducting this study was to gain a better understanding of some of the issues that have been raised about these graduates' lack of content knowledge. The study adopts a qualitative approach and seeks to investigate (a) how the three teachers in this study understand key concepts and (b) the strategies they use to develop such concepts. Three data collection instruments were employed: interviews, document analysis and class observations. The findings indicate that despite the training that all three teachers in this study received, their understanding of the concepts they taught is problematic. Furthermore, some of the strategies that the teachers used did not bring about learning with understanding. The results of the study revealed how these teachers' problems with concepts and the development of conceptual understanding are related to specific issues and can be attributed to a number of factors. Because of this, the study has provided valuable insights into aspects of teacher education that need to be addressed both in terms of in-service and pre-service programmes to support teachers in teaching for understanding, a key idea underpinning the reform process.
- Full Text:
- Date Issued: 2007
- Authors: Sichombe, Beatrice Sinyama
- Date: 2007
- Subjects: Social sciences -- Study and teaching (Elementary) -- Namibia Social science teachers -- Namibia Educational change -- Namibia Education -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1877 , http://hdl.handle.net/10962/d1005856
- Description: After the introduction of Learner Centred Education in Namibia, a number of studies were conducted on how teachers either perceived learner centred education or implemented it. However, very few studies investigated the teachers' understanding of both subject matter knowledge and pedagogical content knowledge; primarily, how they understand and develop key concepts. The purpose of this study was to investigate how Grade 5 teachers' understand and develop key concepts in Social Studies in selected schools in Namibia. The study focused on three teachers in three primary schools in the Caprivi educational region of Namibia. These teachers were purposefully selected as graduates of the teacher education programme instituted at the time of the Namibian education reform process. As a teacher educator, my main motive of conducting this study was to gain a better understanding of some of the issues that have been raised about these graduates' lack of content knowledge. The study adopts a qualitative approach and seeks to investigate (a) how the three teachers in this study understand key concepts and (b) the strategies they use to develop such concepts. Three data collection instruments were employed: interviews, document analysis and class observations. The findings indicate that despite the training that all three teachers in this study received, their understanding of the concepts they taught is problematic. Furthermore, some of the strategies that the teachers used did not bring about learning with understanding. The results of the study revealed how these teachers' problems with concepts and the development of conceptual understanding are related to specific issues and can be attributed to a number of factors. Because of this, the study has provided valuable insights into aspects of teacher education that need to be addressed both in terms of in-service and pre-service programmes to support teachers in teaching for understanding, a key idea underpinning the reform process.
- Full Text:
- Date Issued: 2007
Gold nanoparticle–based colorimetric probes for dopamine detection
- Authors: Ngomane, Nokuthula
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4565 , http://hdl.handle.net/10962/d1021261
- Description: Colorimetric probes have become important tools in analysis and biomedical technology. This thesis reports on the development of such probes for the detection of dopamine (DA). Liquid and different solid state probes were developed utilizing un–functionalized gold nanoparticles (UF–AuNPs). The liquid state probe is based on the growth and aggregation of the UF–AuNPs in the presence of DA. Upon addition of the UF–AuNPs to various concentrations of DA, the shape, size and colour change results in spectral shifts from lower to higher wavelengths. The analyte can be easily monitored by the naked eye from 5.0 nM DA with a calculated limit of detection of 2.5 nM (3σ) under optimal pH. Ascorbic acid (AA) has a potential to interfere with DA detection in solution since it is often present in biological fluids, but in this case the interference was limited to solutions where its concentration was beyond 200 times greater than that of DA. Since most of the previously reported colorimetric probes, especially those for DA are solution based, the main focus of the thesis was in the development of a solid state based colorimetric probe in the form of nanofibre mats. To overcome the interference challenges experienced in the solution studies (the interference by high concentrations of AA), the suitability of molecularly imprinted polymers (MIPs) for the selective detection of DA was investigated. The results showed that the MIPs produced did not play a significant role in enhancing the selectivity towards DA. A probe composed of just the UF–AuNPs and Nylon–6 (UF–AuNPs + N6) was also developed. The UF–AuNPs were synthesized following an in situ reduction method. The probe was only selective to DA and insensitive to other catecholamines at physiological pH. Thus, the probe did not require any addition functionalities to achieve selectivity and sensitive to DA. The liquid state probe and the composite UF–AuNPs + N6 nanofibre probe were successfully applied to a whole blood sample and showed good selectivity towards DA. The simple, sensitive and selective probe could be an excellent alternative for on–site and immediate detection of DA without the use of instrumentation. For quantification of DA using the solid state probe, open–source software imageJ was used to assist in the analysis of the nanofibre colours. It was observed that the intensity of the colour increased with the increase in concentration of DA in a linear fashion. The use of imageJ can also be a great alternative where the colour changes are not so clear or for visually impaired people. The solid state probe developed can detect DA qualitatively and quantitatively. The work also forms a good foundation for development of such probes for other analyte.
- Full Text:
- Date Issued: 2016
- Authors: Ngomane, Nokuthula
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4565 , http://hdl.handle.net/10962/d1021261
- Description: Colorimetric probes have become important tools in analysis and biomedical technology. This thesis reports on the development of such probes for the detection of dopamine (DA). Liquid and different solid state probes were developed utilizing un–functionalized gold nanoparticles (UF–AuNPs). The liquid state probe is based on the growth and aggregation of the UF–AuNPs in the presence of DA. Upon addition of the UF–AuNPs to various concentrations of DA, the shape, size and colour change results in spectral shifts from lower to higher wavelengths. The analyte can be easily monitored by the naked eye from 5.0 nM DA with a calculated limit of detection of 2.5 nM (3σ) under optimal pH. Ascorbic acid (AA) has a potential to interfere with DA detection in solution since it is often present in biological fluids, but in this case the interference was limited to solutions where its concentration was beyond 200 times greater than that of DA. Since most of the previously reported colorimetric probes, especially those for DA are solution based, the main focus of the thesis was in the development of a solid state based colorimetric probe in the form of nanofibre mats. To overcome the interference challenges experienced in the solution studies (the interference by high concentrations of AA), the suitability of molecularly imprinted polymers (MIPs) for the selective detection of DA was investigated. The results showed that the MIPs produced did not play a significant role in enhancing the selectivity towards DA. A probe composed of just the UF–AuNPs and Nylon–6 (UF–AuNPs + N6) was also developed. The UF–AuNPs were synthesized following an in situ reduction method. The probe was only selective to DA and insensitive to other catecholamines at physiological pH. Thus, the probe did not require any addition functionalities to achieve selectivity and sensitive to DA. The liquid state probe and the composite UF–AuNPs + N6 nanofibre probe were successfully applied to a whole blood sample and showed good selectivity towards DA. The simple, sensitive and selective probe could be an excellent alternative for on–site and immediate detection of DA without the use of instrumentation. For quantification of DA using the solid state probe, open–source software imageJ was used to assist in the analysis of the nanofibre colours. It was observed that the intensity of the colour increased with the increase in concentration of DA in a linear fashion. The use of imageJ can also be a great alternative where the colour changes are not so clear or for visually impaired people. The solid state probe developed can detect DA qualitatively and quantitatively. The work also forms a good foundation for development of such probes for other analyte.
- Full Text:
- Date Issued: 2016
Gender differences and online shopping decisions of consumers in South Africa
- Authors: Mqulo, Thandokazi
- Date: 2019
- Subjects: Electronic commerce Consumer behavior
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/16952 , vital:40788
- Description: Online shopping has emerged as one of the most convenient ways of shopping in both emerging and advanced economies. In South Africa, it has received much attention due to its unique way of satisfying both the rural and urban populations. Online shopping is growing and carries great potential of contributing to a country and/or local areas’ economy and development. The primary aim of the study was to analyse the differences of online shopping between males and females in South Africa. The main objective of this study is to determine if there are significant differences between male and female online shoppers in South Africa. The study is motivated by the literature gap that exists on the online shopping discourse, in that there are few published studies on the online shopping differences between males and females in South Africa. Therefore, there is a lack of information on the importance of online shopping activities on promoting convenience for shoppers in these busy times that people live in. A quantitative approach was used to analyse the data that were collected using a questionnaire. Data was collected from a sample of 377 people who are online shoppers in the Eastern Cape, South Africa. Simple random sampling was utilised for this study. The results showed that there is a significant difference between males and females online shopping patterns as determined by specific variables mentioned in this study. Their study had findings on research hypothesis of attitude towards online shopping, the difference in the usefulness of media on online websites, perceived ease of use of online websites, intrinsic enjoyment, perceived risk and trust towards online shopping. The implications of this study unpack and provides discussion on empirical evidence drawn from the study’s statistical results. The implications are presented in a way which explains how the results of this study affect theoretical dimensions of the studied phenomenon, online shoppers and the retail industry. There is a need for more research in this environment and this research study will stimulate further studies in the online shopping environment. Future research may focus on the development of a customer satisfaction scale that uses service quality items in the retail industry, to gather data about what satisfies customers in the retail context.
- Full Text:
- Date Issued: 2019
- Authors: Mqulo, Thandokazi
- Date: 2019
- Subjects: Electronic commerce Consumer behavior
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/16952 , vital:40788
- Description: Online shopping has emerged as one of the most convenient ways of shopping in both emerging and advanced economies. In South Africa, it has received much attention due to its unique way of satisfying both the rural and urban populations. Online shopping is growing and carries great potential of contributing to a country and/or local areas’ economy and development. The primary aim of the study was to analyse the differences of online shopping between males and females in South Africa. The main objective of this study is to determine if there are significant differences between male and female online shoppers in South Africa. The study is motivated by the literature gap that exists on the online shopping discourse, in that there are few published studies on the online shopping differences between males and females in South Africa. Therefore, there is a lack of information on the importance of online shopping activities on promoting convenience for shoppers in these busy times that people live in. A quantitative approach was used to analyse the data that were collected using a questionnaire. Data was collected from a sample of 377 people who are online shoppers in the Eastern Cape, South Africa. Simple random sampling was utilised for this study. The results showed that there is a significant difference between males and females online shopping patterns as determined by specific variables mentioned in this study. Their study had findings on research hypothesis of attitude towards online shopping, the difference in the usefulness of media on online websites, perceived ease of use of online websites, intrinsic enjoyment, perceived risk and trust towards online shopping. The implications of this study unpack and provides discussion on empirical evidence drawn from the study’s statistical results. The implications are presented in a way which explains how the results of this study affect theoretical dimensions of the studied phenomenon, online shoppers and the retail industry. There is a need for more research in this environment and this research study will stimulate further studies in the online shopping environment. Future research may focus on the development of a customer satisfaction scale that uses service quality items in the retail industry, to gather data about what satisfies customers in the retail context.
- Full Text:
- Date Issued: 2019