Creating the Ideal Push-Pull System for Electrocatalysis A Comparative Study on Symmetrical and Asymmetrical Cardanol-based Cobalt Phthalocyanines
- Nkhahle, Reitumetse, Nyokong, Tebello
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44452 , xlink:href="https://doi.org/10.1002/elan.202060019"
- Description: A symmetrical cardanol-based cobalt phthalocyanine (Pc) along with its asymmetrical acid-based derivatives were synthesized and applied in the electrocatalysis of hydrazine. Despite the inhibition of electron movement by the bulky cardanol-based substituent throughout the series of molecules, an ideal combination of substituents was established in GCE-3 (2,9,16-tris(3- pentadecylphenoxy)-23-mono propionic acid phthalocyanato cobalt (II)) where a limit of detection (LoD) value of 5.10 μM (signal to noise ratio=5) was recorded for the detection of hydrazine. The results obtained serve as an illustration that the combination of electron-donating and electron-withdrawing substituents has a significant influence on the complete functioning of the phthalocyanine molecule(s) being investigated.
- Full Text:
- Date Issued: 2021
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44452 , xlink:href="https://doi.org/10.1002/elan.202060019"
- Description: A symmetrical cardanol-based cobalt phthalocyanine (Pc) along with its asymmetrical acid-based derivatives were synthesized and applied in the electrocatalysis of hydrazine. Despite the inhibition of electron movement by the bulky cardanol-based substituent throughout the series of molecules, an ideal combination of substituents was established in GCE-3 (2,9,16-tris(3- pentadecylphenoxy)-23-mono propionic acid phthalocyanato cobalt (II)) where a limit of detection (LoD) value of 5.10 μM (signal to noise ratio=5) was recorded for the detection of hydrazine. The results obtained serve as an illustration that the combination of electron-donating and electron-withdrawing substituents has a significant influence on the complete functioning of the phthalocyanine molecule(s) being investigated.
- Full Text:
- Date Issued: 2021
Drifting towards death: a South African patient safety incident through an HFE Systems lens
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
Malnutrition in children under the age of 5 years in a primary health care setting
- Kaswa, Ramprakash, Govender, Indiran, Rangiah, Selvandran, Nzaumvila, Doudou
- Authors: Kaswa, Ramprakash , Govender, Indiran , Rangiah, Selvandran , Nzaumvila, Doudou
- Date: 2021
- Subjects: Obesity Malnutrition Dietary supplements Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7260 , vital:53106 , xlink:href="https://doi.org/10.4102/safp.v63i1.5337"
- Description: In this study, we outlined the types of malnutrition amongst children, the causes of malnutrition intervention at the primary health care level and some recommendations to alleviate childhood malnutrition in South Africa. Keywords: obesity; severe acute malnutrition; individual factors; community level factors; dietary intervention.
- Full Text:
- Date Issued: 2021
- Authors: Kaswa, Ramprakash , Govender, Indiran , Rangiah, Selvandran , Nzaumvila, Doudou
- Date: 2021
- Subjects: Obesity Malnutrition Dietary supplements Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7260 , vital:53106 , xlink:href="https://doi.org/10.4102/safp.v63i1.5337"
- Description: In this study, we outlined the types of malnutrition amongst children, the causes of malnutrition intervention at the primary health care level and some recommendations to alleviate childhood malnutrition in South Africa. Keywords: obesity; severe acute malnutrition; individual factors; community level factors; dietary intervention.
- Full Text:
- Date Issued: 2021
The Primacy of Effective Human Capital Management to the Growth of Entrepreneurship Ventures. A Study of Cases from the Fast Food Restaurant Sector in Cape Town
- Asoba, Samson Nambei, Patricia, Nteboheng Mefi
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Entrepreneurship Human capital Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8135 , vital:61400 , xlink:href="https://www.abacademies.org/articles/the-primacy-of-effective-human-capital-management-to-the-growth-of-entrepreneurship-ventures-a-study-of-cases-from-the-fast-food-r-10259.html"
- Description: This paper draws on two fields, human resources management and entrepreneurship to examine the observed problem of stalled established business ownership even despite favourable Total Early Stage entrepreneurship (TEA) among many nations. The aim of the study was to established the perceptions of entrepreneurs on the influence of human capital on the growth and sustainability of entrepreneurial ventures from the restaurant sector in Cape Town. The study adopted a qualitative research design which was based on interviews to infer the entrepreneurs’ perceptions on the role of effective human capital management to growth of entrepreneurial ventures. Fifteen interviews were conducted and analysed following a thematic analyse procedure. Various themes and sub themes which pointed to the critically of effective human capital management were established. It was found the people possess certain social, philosophical, psychological and ideological attributes that cannot be found from other resources. At the end of the analysis, it was established that human resources are central to the growth of entrepreneurial ventures as they possess certain exploitable entrepreneurial talents, are capable of unlocking the value of other resources and also they are the drivers of growth. Following these findings, it was recommended that entrepreneurs should centralise effective human capital management for growth. Keywords: Entrepreneurship, Human Capital, Small Businesses, Business Growth, Competitive Advantage
- Full Text:
- Date Issued: 2021
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Entrepreneurship Human capital Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8135 , vital:61400 , xlink:href="https://www.abacademies.org/articles/the-primacy-of-effective-human-capital-management-to-the-growth-of-entrepreneurship-ventures-a-study-of-cases-from-the-fast-food-r-10259.html"
- Description: This paper draws on two fields, human resources management and entrepreneurship to examine the observed problem of stalled established business ownership even despite favourable Total Early Stage entrepreneurship (TEA) among many nations. The aim of the study was to established the perceptions of entrepreneurs on the influence of human capital on the growth and sustainability of entrepreneurial ventures from the restaurant sector in Cape Town. The study adopted a qualitative research design which was based on interviews to infer the entrepreneurs’ perceptions on the role of effective human capital management to growth of entrepreneurial ventures. Fifteen interviews were conducted and analysed following a thematic analyse procedure. Various themes and sub themes which pointed to the critically of effective human capital management were established. It was found the people possess certain social, philosophical, psychological and ideological attributes that cannot be found from other resources. At the end of the analysis, it was established that human resources are central to the growth of entrepreneurial ventures as they possess certain exploitable entrepreneurial talents, are capable of unlocking the value of other resources and also they are the drivers of growth. Following these findings, it was recommended that entrepreneurs should centralise effective human capital management for growth. Keywords: Entrepreneurship, Human Capital, Small Businesses, Business Growth, Competitive Advantage
- Full Text:
- Date Issued: 2021
Leadership Styles and Employee Job Satisfaction: A Case of Head of Departments in Walter Sisulu UniversityMonitoring and Management Mechanisms on Stress in HEI in Eastern Cape Province in South Africa: Critical Review
- Asoba, Samson Nambei, Patricia, Nteboheng Mefi
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Educational Leadership Education (Higher) College department heads Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8082 , vital:61392 , xlink:href="https://www.abacademies.org/articles/leadership-styles-and-employee-job-satisfaction-a-case-of-head-of-departments-in-walter-sisulu-university-10942.html"
- Description: This study was based on the relationship between the leadership styles of Academic head of Department and employee job satisfaction at the Higher Education Institution (HEI). In so doing, the study was based on the following questions: What is the relationship between leadership styles of HODs and employee job satisfaction in a Higher Education institution in the Eastern Cape Province of South Africa. A purposive sampling technique was utilised to select the participants, which comprised 80 academic staff members to which the researcher hand-delivered 80 questionnaires. The study employed a quantitative method to collect and analyse data. The study found that Perceptions on the leadership styles of academic HODs at the HEI are varied. No clear pattern emerged on what leadership styles are prevalent. The relationship between leadership styles and employee job satisfaction appears to be nonlinear. Job satisfaction is a phenomenon that is determined by many factors, not simply leadership styles.
- Full Text:
- Date Issued: 2021
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Educational Leadership Education (Higher) College department heads Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8082 , vital:61392 , xlink:href="https://www.abacademies.org/articles/leadership-styles-and-employee-job-satisfaction-a-case-of-head-of-departments-in-walter-sisulu-university-10942.html"
- Description: This study was based on the relationship between the leadership styles of Academic head of Department and employee job satisfaction at the Higher Education Institution (HEI). In so doing, the study was based on the following questions: What is the relationship between leadership styles of HODs and employee job satisfaction in a Higher Education institution in the Eastern Cape Province of South Africa. A purposive sampling technique was utilised to select the participants, which comprised 80 academic staff members to which the researcher hand-delivered 80 questionnaires. The study employed a quantitative method to collect and analyse data. The study found that Perceptions on the leadership styles of academic HODs at the HEI are varied. No clear pattern emerged on what leadership styles are prevalent. The relationship between leadership styles and employee job satisfaction appears to be nonlinear. Job satisfaction is a phenomenon that is determined by many factors, not simply leadership styles.
- Full Text:
- Date Issued: 2021
Electrocatalytic activity of Schiff base containing copper phthalocyanines towards the detection of catechol
- Ndebele, Nobuhle, Sen, Pinar, Nyokong, Tebello
- Authors: Ndebele, Nobuhle , Sen, Pinar , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231410 , vital:49885 , xlink:href="https://doi.org/10.1016/j.poly.2021.115518"
- Description: In this study, four new copper phthalocyanine complexes were synthesised and studied as electrocatalysts for the detection of catechol. Two of these complexes were derived from a symmetrical benzaldehyde phthalocyanine complex via the condensation of the benzaldehyde substituents with amine reagents. The electrocatalysts proved to be highly stable towards the detection of catechol. The oxidation peaks obtained using cyclic voltammetry range from 0.20 to 0.38 V. Detection limits were obtained via chronoamperometry and are as low as 0.16 µM with fairly high sensitives being obtained. Overall all four copper complexes exhibited excellent electrocatalytic activity towards the electrooxidation of catechol.
- Full Text:
- Date Issued: 2021
- Authors: Ndebele, Nobuhle , Sen, Pinar , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231410 , vital:49885 , xlink:href="https://doi.org/10.1016/j.poly.2021.115518"
- Description: In this study, four new copper phthalocyanine complexes were synthesised and studied as electrocatalysts for the detection of catechol. Two of these complexes were derived from a symmetrical benzaldehyde phthalocyanine complex via the condensation of the benzaldehyde substituents with amine reagents. The electrocatalysts proved to be highly stable towards the detection of catechol. The oxidation peaks obtained using cyclic voltammetry range from 0.20 to 0.38 V. Detection limits were obtained via chronoamperometry and are as low as 0.16 µM with fairly high sensitives being obtained. Overall all four copper complexes exhibited excellent electrocatalytic activity towards the electrooxidation of catechol.
- Full Text:
- Date Issued: 2021
Rural Tourism and Inclusive Development in Port St. Johns - South Africa
- Acha-Anyi, Paul Nkemngu, Ndolose, Ludwe, Solomon, Khunou Pula
- Authors: Acha-Anyi, Paul Nkemngu , Ndolose, Ludwe , Solomon, Khunou Pula
- Date: 2021
- Subjects: Rural tourism Community Inclusive development; Sustainable development Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7023 , vital:52758 , xlink:href=":https://doi.org/10.46222/ajhtl.19770720.197"
- Description: The purpose of this study was to explore ways of achieving an inclusive approach to tourism development in rural communities. Although tourism has generally been recommended as a means of orchestrating development in rural communities, achieving this laudable goal has often been illusive due to the fragmented approach adopted by tourism stakeholders. An exploratory quantitative research approach was adopted by using a structured survey instrument to generate 307 valid responses from community members in Port St. John in the Eastern Cape Province (ECP) of South Africa. Results obtained reveal similarities and some differences based on demographic characteristics with regards to the benefits of rural tourism to the community. Importantly, the study illuminates the fragmented way in which residents perceive tourism benefits, both from a gender perspective and personal benefit versus community dichotomy. The paper discusses policy as well as practical local economic development implications. Keywords: Rural tourism; community; Port St. Johns; inclusive development; sustainable development
- Full Text:
- Date Issued: 2021
- Authors: Acha-Anyi, Paul Nkemngu , Ndolose, Ludwe , Solomon, Khunou Pula
- Date: 2021
- Subjects: Rural tourism Community Inclusive development; Sustainable development Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7023 , vital:52758 , xlink:href=":https://doi.org/10.46222/ajhtl.19770720.197"
- Description: The purpose of this study was to explore ways of achieving an inclusive approach to tourism development in rural communities. Although tourism has generally been recommended as a means of orchestrating development in rural communities, achieving this laudable goal has often been illusive due to the fragmented approach adopted by tourism stakeholders. An exploratory quantitative research approach was adopted by using a structured survey instrument to generate 307 valid responses from community members in Port St. John in the Eastern Cape Province (ECP) of South Africa. Results obtained reveal similarities and some differences based on demographic characteristics with regards to the benefits of rural tourism to the community. Importantly, the study illuminates the fragmented way in which residents perceive tourism benefits, both from a gender perspective and personal benefit versus community dichotomy. The paper discusses policy as well as practical local economic development implications. Keywords: Rural tourism; community; Port St. Johns; inclusive development; sustainable development
- Full Text:
- Date Issued: 2021
Sustainable Human Resource Practices for Organizational Competitiveness Post the Covid-19 Pandemic
- Asoba, Samson Nambei, Patricia, Nteboheng Mefi
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Personel Management Covid-19 (Disease) Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8118 , vital:61396 , xlink:href="https://www.abacademies.org/articles/Sustainable-human-resource-practices-for-organizational-competitiveness-post-the-covid-19-1528-2686-27-2-480.pdf"
- Description: The study was formulated to tap into the future of HRM given the disruptions arising from the Covid-119 pandemic as well as the progression of the global technological environment to the fourth industrial revolution. The aim of the study was to: the Covid-19 induced HRM practices underpinning future organizational competitiveness. A literature review strategy was adopted to achieve the study objective. The study established seven emerging themes to inform HRM practices for the competitiveness of organizations in future following the Covid-19 disturbances. These themes are: primacy of HRM, increased cyber influences, digitalization, remote HRM, human-machine interface skills, human-organisation strategic links as well as human-technology interface competencies. Based on the study findings, the study recommended HRM departments to move to HR 4.0 through the adoption of industry 4.0 technologies, increased automation, and digitalization as well as strengthen virtualization systems.
- Full Text:
- Date Issued: 2021
- Authors: Asoba, Samson Nambei , Patricia, Nteboheng Mefi
- Date: 2021
- Subjects: Personel Management Covid-19 (Disease) Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/8118 , vital:61396 , xlink:href="https://www.abacademies.org/articles/Sustainable-human-resource-practices-for-organizational-competitiveness-post-the-covid-19-1528-2686-27-2-480.pdf"
- Description: The study was formulated to tap into the future of HRM given the disruptions arising from the Covid-119 pandemic as well as the progression of the global technological environment to the fourth industrial revolution. The aim of the study was to: the Covid-19 induced HRM practices underpinning future organizational competitiveness. A literature review strategy was adopted to achieve the study objective. The study established seven emerging themes to inform HRM practices for the competitiveness of organizations in future following the Covid-19 disturbances. These themes are: primacy of HRM, increased cyber influences, digitalization, remote HRM, human-machine interface skills, human-organisation strategic links as well as human-technology interface competencies. Based on the study findings, the study recommended HRM departments to move to HR 4.0 through the adoption of industry 4.0 technologies, increased automation, and digitalization as well as strengthen virtualization systems.
- Full Text:
- Date Issued: 2021
The nature of violence in South African universities African universities: The politics of process
- Mutongoza, Bonginkosi Hardy https://orcid.org/0000-0002-2939-1274
- Authors: Mutongoza, Bonginkosi Hardy https://orcid.org/0000-0002-2939-1274
- Date: 2021
- Subjects: Education, Higher -- Political aspects , Universities and colleges -- South Africa , Campus violence
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/27909 , vital:70816
- Description: The high levels of violence that plague South Africa’s universities are symptomatic of an education system that is under attack, with institutions of higher learning not reflecting the peacefulness and safety which are oftentimes associated with the pursuit of learning. While violence in societies and educational institutions globally continues to intensify in viciousness and frequency, this is especially worrisome for South Africa, a country regarded as one of the most violent in the world. South African education institutions are admittedly extremely violent, yet there are relatively few mechanisms to enable the verification of trends in violence, or to cross-reference and compare incidents, thus making the reduction of violence problematic. The contention is that the general outlook of violence at educational institutions appears to echo the relentless violence which haunts South African communities in general. Against this background, the current study sought to explore the nature of violence in South African universities. To achieve this, the study was guided by an exploration of student and staff experiences of violence in universities, the causes of violence in such sites, and the recording thereof. Underpinned by a pragmatist paradigm, this study utilised a mixed-methods approach to ‘get under the skin’ of the problem of violence in universities. Within the mixed-methods approach, the study employed a single-phase convergent design, which enabled the researcher to reach comprehensive conclusions on violence in universities, by merging and comparing qualitative and quantitative datasets. In the quantitative phase of the study, a simple random sampling technique was used to select a total of 1 776 students and 250 staff, while 32 students and four staff were conveniently sampled during the qualitative phase. The data for this study were collected using an online survey in the quantitative phase, and semi-structured interviews and document reviews in the qualitative phase. The findings of this investigation revealed that violence happened in six main configurations, namely student-on-student violence, staff-on-student violence, staff-on-staff violence, student-on-staff violence, self-directed violence, and protest-related violence. In addition, the findings revealed diverse causes of violence in universities, chief of which were alcohol and drug abuse, poor security, the abuse of power or authority, impunity, and psychosocial factors, among others. Factors that impeded the recording of violence in universities included the normalisation of violence, a lack of consequences for the perpetrators, a lack of procedural awareness, cronyism and brotherhoods, and a lack of protection from reprisal for reporting perpetrators. The production of violence in South African universities was also found to be significantly shaped by wider structures that included sexuality, gender, age, socioeconomic status, and race and ethnicity. These structures were found to be prominent in increasing the likelihood of violence being perpetrated. Based on the reported findings, the study moved to recommend that, in order to reduce experiences of violence in South African universities, institutions adopt multidimensional approaches to combatting this scourge. The fact that violence was noted to occur in multiple configurations, means multiple viewpoints are required to reduce and ultimately combat it. This calls for a multi-stakeholder approach that transcends a reliance on the traditional university policymakers, and a concerted consultative process to formulate and renew policies that can help to address university violence. The study further recommended that reporting structures be decentralised at universities, in a bid to improve the smoothness of related processes. In this respect, it will be essential for universities to consider setting up anonymous reporting platforms online, to move with the times and ensure more urgent responses, as opposed to a continued reliance on present systems that are replete with red tape. Additionally, universities may consider outsourcing divisions that deal with violence reporting, to minimise conflicts of interest when dealing with such cases. The researcher concluded that violence in universities threatens the very purpose of tertiary education – members of the university community must be able to freely pursue their aspirations in peaceful environments. As such, for as long as campuses experience violence in any of its varied forms, a proverbial dark cloud will forever frustrate the quest for quality and transformative education that has the potential to reverse-engineer inequality, poverty, and underdevelopment in South Africa, as contemplated in various development plans. , Thesis (PhD) -- Faculty of Education, 2021
- Full Text:
- Date Issued: 2021
- Authors: Mutongoza, Bonginkosi Hardy https://orcid.org/0000-0002-2939-1274
- Date: 2021
- Subjects: Education, Higher -- Political aspects , Universities and colleges -- South Africa , Campus violence
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/27909 , vital:70816
- Description: The high levels of violence that plague South Africa’s universities are symptomatic of an education system that is under attack, with institutions of higher learning not reflecting the peacefulness and safety which are oftentimes associated with the pursuit of learning. While violence in societies and educational institutions globally continues to intensify in viciousness and frequency, this is especially worrisome for South Africa, a country regarded as one of the most violent in the world. South African education institutions are admittedly extremely violent, yet there are relatively few mechanisms to enable the verification of trends in violence, or to cross-reference and compare incidents, thus making the reduction of violence problematic. The contention is that the general outlook of violence at educational institutions appears to echo the relentless violence which haunts South African communities in general. Against this background, the current study sought to explore the nature of violence in South African universities. To achieve this, the study was guided by an exploration of student and staff experiences of violence in universities, the causes of violence in such sites, and the recording thereof. Underpinned by a pragmatist paradigm, this study utilised a mixed-methods approach to ‘get under the skin’ of the problem of violence in universities. Within the mixed-methods approach, the study employed a single-phase convergent design, which enabled the researcher to reach comprehensive conclusions on violence in universities, by merging and comparing qualitative and quantitative datasets. In the quantitative phase of the study, a simple random sampling technique was used to select a total of 1 776 students and 250 staff, while 32 students and four staff were conveniently sampled during the qualitative phase. The data for this study were collected using an online survey in the quantitative phase, and semi-structured interviews and document reviews in the qualitative phase. The findings of this investigation revealed that violence happened in six main configurations, namely student-on-student violence, staff-on-student violence, staff-on-staff violence, student-on-staff violence, self-directed violence, and protest-related violence. In addition, the findings revealed diverse causes of violence in universities, chief of which were alcohol and drug abuse, poor security, the abuse of power or authority, impunity, and psychosocial factors, among others. Factors that impeded the recording of violence in universities included the normalisation of violence, a lack of consequences for the perpetrators, a lack of procedural awareness, cronyism and brotherhoods, and a lack of protection from reprisal for reporting perpetrators. The production of violence in South African universities was also found to be significantly shaped by wider structures that included sexuality, gender, age, socioeconomic status, and race and ethnicity. These structures were found to be prominent in increasing the likelihood of violence being perpetrated. Based on the reported findings, the study moved to recommend that, in order to reduce experiences of violence in South African universities, institutions adopt multidimensional approaches to combatting this scourge. The fact that violence was noted to occur in multiple configurations, means multiple viewpoints are required to reduce and ultimately combat it. This calls for a multi-stakeholder approach that transcends a reliance on the traditional university policymakers, and a concerted consultative process to formulate and renew policies that can help to address university violence. The study further recommended that reporting structures be decentralised at universities, in a bid to improve the smoothness of related processes. In this respect, it will be essential for universities to consider setting up anonymous reporting platforms online, to move with the times and ensure more urgent responses, as opposed to a continued reliance on present systems that are replete with red tape. Additionally, universities may consider outsourcing divisions that deal with violence reporting, to minimise conflicts of interest when dealing with such cases. The researcher concluded that violence in universities threatens the very purpose of tertiary education – members of the university community must be able to freely pursue their aspirations in peaceful environments. As such, for as long as campuses experience violence in any of its varied forms, a proverbial dark cloud will forever frustrate the quest for quality and transformative education that has the potential to reverse-engineer inequality, poverty, and underdevelopment in South Africa, as contemplated in various development plans. , Thesis (PhD) -- Faculty of Education, 2021
- Full Text:
- Date Issued: 2021
The stories African lawyers could tell when analysing legal issues: Lessons for social sciences teachers
- Authors: Zongwe, Dunia P
- Date: 2021
- Subjects: Decolonization Storytelling Law--Study and teaching Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/6989 , vital:52634 , xlink:href="https://doi.org/10.4102/hts.v77i2.6828"
- Description: Activists and academics have clamoured for the decolonisation of knowledge, including law. But, unfortunately hardly anyone has put forth strategies for how faculties should decolonise the law. A number of jurists have underscored the necessity to draw on customary laws and traditional values. Still, the #RhodesMustFall movement has, for the most part, been loud on the outcomes, but quiet on the methodologies. Joining the conversation on the decolonisation of epistemologies, this article contributes to the ongoing efforts to sanitise the law by proposing to revive African oral storytelling cultures as a way to analyse the questions of law facing society. To live up to this task, this article adopts decolonial theory and, through stylised examples, illustrates how lawyers and social scientists in Africa can utilise storytelling to contextualise, (de)construct, and comprehend those questions. This article assumes that lawyers can use African storytelling alongside the prevailing doctrinal method. That method, relaying the coloniality of law and captured by the acronym IRAC (issue(s), rules, application, and conclusion), trains students to approach conflict in society through a highly abstract and decontextualised problem-solving model. Lately, some (Western) social scientists have (re)discovered the practicality of storytelling in presenting analysis and research. However, in African oral traditions, stories worked differently from the manner in which those scientists employ them. African storytelling played a leading role, not only in conveying collective wisdom and social memory from one generation to the next, but also as a medium through which communities transmit the values that hold them together. Contribution: This article adds to the scholarship on storytelling and narratology by showing how educators can utilise stories to analyse legal questions. That rich scholarship in the humanities and the social sciences has so far not taken seriously the possibility of using stories to analyse research problems. Instead, scholars focus on storytelling mainly as a way of presenting science, not as an analytical tool. This article bridges that gap and demonstrates the analytical value of storytelling. Keywords: decolonisation of knowledge; decolonial theory; storytelling; Africa; analysis; epistemology; legal education; oral tradition.
- Full Text:
- Date Issued: 2021
- Authors: Zongwe, Dunia P
- Date: 2021
- Subjects: Decolonization Storytelling Law--Study and teaching Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/6989 , vital:52634 , xlink:href="https://doi.org/10.4102/hts.v77i2.6828"
- Description: Activists and academics have clamoured for the decolonisation of knowledge, including law. But, unfortunately hardly anyone has put forth strategies for how faculties should decolonise the law. A number of jurists have underscored the necessity to draw on customary laws and traditional values. Still, the #RhodesMustFall movement has, for the most part, been loud on the outcomes, but quiet on the methodologies. Joining the conversation on the decolonisation of epistemologies, this article contributes to the ongoing efforts to sanitise the law by proposing to revive African oral storytelling cultures as a way to analyse the questions of law facing society. To live up to this task, this article adopts decolonial theory and, through stylised examples, illustrates how lawyers and social scientists in Africa can utilise storytelling to contextualise, (de)construct, and comprehend those questions. This article assumes that lawyers can use African storytelling alongside the prevailing doctrinal method. That method, relaying the coloniality of law and captured by the acronym IRAC (issue(s), rules, application, and conclusion), trains students to approach conflict in society through a highly abstract and decontextualised problem-solving model. Lately, some (Western) social scientists have (re)discovered the practicality of storytelling in presenting analysis and research. However, in African oral traditions, stories worked differently from the manner in which those scientists employ them. African storytelling played a leading role, not only in conveying collective wisdom and social memory from one generation to the next, but also as a medium through which communities transmit the values that hold them together. Contribution: This article adds to the scholarship on storytelling and narratology by showing how educators can utilise stories to analyse legal questions. That rich scholarship in the humanities and the social sciences has so far not taken seriously the possibility of using stories to analyse research problems. Instead, scholars focus on storytelling mainly as a way of presenting science, not as an analytical tool. This article bridges that gap and demonstrates the analytical value of storytelling. Keywords: decolonisation of knowledge; decolonial theory; storytelling; Africa; analysis; epistemology; legal education; oral tradition.
- Full Text:
- Date Issued: 2021
The electrochemical detection of prostate specific antigen on glassy carbon electrode modified with combinations of graphene quantum dots, cobalt phthalocyanine and an aptamer
- Nxele, Siphesihle R, Nyokong, Tebello
- Authors: Nxele, Siphesihle R , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185013 , vital:44316 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2021.111462"
- Description: Herein, a novel aptasensor is developed for the electrochemical detection of prostate specific antigen (PSA) on electrode surfaces modified using various combinations of a Cobalt phthalocyanine (CoPc), an aptamer and graphene quantum dots (GQDs). Electrochemical impedance spectroscopy (EIS) as well as differential pulse voltammetry (DPV) are employed for the detection of PSA. In both analytical techniques, linear calibration curves were observed at a concentration range of 1.2–2.0 pM. The glassy carbon electrode where CoPc and GQDs are placed on the electrode when non-covalently linked followed by addition of the aptamer (GQDs-CoPc(ππ)-aptamer (sequential)) showed the best performance with a limit of detection (LoD) as low as 0.66 pM when using DPV. The detection limits were much lower than the dangerous levels reported for PSA in males tested for prostate cancer. This electrode showed selectivity for PSA in the presence of bovine serum albumin, glucose and L-cysteine. The aptasensor showed good stability, reproducibility and repeatability, deeming it a promising early detection device for prostate cancer.
- Full Text:
- Date Issued: 2021
- Authors: Nxele, Siphesihle R , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185013 , vital:44316 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2021.111462"
- Description: Herein, a novel aptasensor is developed for the electrochemical detection of prostate specific antigen (PSA) on electrode surfaces modified using various combinations of a Cobalt phthalocyanine (CoPc), an aptamer and graphene quantum dots (GQDs). Electrochemical impedance spectroscopy (EIS) as well as differential pulse voltammetry (DPV) are employed for the detection of PSA. In both analytical techniques, linear calibration curves were observed at a concentration range of 1.2–2.0 pM. The glassy carbon electrode where CoPc and GQDs are placed on the electrode when non-covalently linked followed by addition of the aptamer (GQDs-CoPc(ππ)-aptamer (sequential)) showed the best performance with a limit of detection (LoD) as low as 0.66 pM when using DPV. The detection limits were much lower than the dangerous levels reported for PSA in males tested for prostate cancer. This electrode showed selectivity for PSA in the presence of bovine serum albumin, glucose and L-cysteine. The aptasensor showed good stability, reproducibility and repeatability, deeming it a promising early detection device for prostate cancer.
- Full Text:
- Date Issued: 2021
Asymmetrical zinc (II) phthalocyanines cobalt tungstate nanomaterial conjugates for photodegradation of methylene blue
- Mgidlana, Sithi, Nyokong, Tebello
- Authors: Mgidlana, Sithi , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184991 , vital:44314 , xlink:href="https://doi.org/10.1016/j.jphotochem.2021.113421"
- Description: Herein, we present syntheses of three asymmetrical zinc(II) phthalocyanine (ZnPc) complexes and hydrothermal synthesis of cobalt tungstate nanoparticles. The ZnPc derivatives were covalently linked to cobalt tungstate nanoparticles. Photophysical and photochemical behaviour of Pcs and nanoconjugates were investigated. The nanoconjugates generated higher triplet quantum yield and singlet oxygen quantum yield than the ZnPcs alone. Furthermore, in this paper photocatalytic efficiencies of ZnPc complexes and nanoconjugates were investigated for the degradation of methylene blue and higher photocatalytic behaviour was observed for the conjugates. The kinetic model was used to study photocatalytic behaviour of all the prepared photocatalysts.
- Full Text:
- Date Issued: 2021
- Authors: Mgidlana, Sithi , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184991 , vital:44314 , xlink:href="https://doi.org/10.1016/j.jphotochem.2021.113421"
- Description: Herein, we present syntheses of three asymmetrical zinc(II) phthalocyanine (ZnPc) complexes and hydrothermal synthesis of cobalt tungstate nanoparticles. The ZnPc derivatives were covalently linked to cobalt tungstate nanoparticles. Photophysical and photochemical behaviour of Pcs and nanoconjugates were investigated. The nanoconjugates generated higher triplet quantum yield and singlet oxygen quantum yield than the ZnPcs alone. Furthermore, in this paper photocatalytic efficiencies of ZnPc complexes and nanoconjugates were investigated for the degradation of methylene blue and higher photocatalytic behaviour was observed for the conjugates. The kinetic model was used to study photocatalytic behaviour of all the prepared photocatalysts.
- Full Text:
- Date Issued: 2021
An investigation into stakeholder inclusivity and the board’s ability to create competitive advantage at South Africa’s “big five” retail banks
- Authors: Wolhuter, Darren Wilfred
- Date: 2022-04-06
- Subjects: Stakeholder management South Africa , Strategic planning South Africa , Banks and banking South Africa , Corporate governance South Africa , Competition , Resource-based theory
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/284548 , vital:56073
- Description: Stakeholder theory has long put forth the concept that managerial attention must be given to all stakeholders towards the realisation of value creation opportunities. Through the process of stakeholder engagement, and through the adoption of stakeholder inclusivity principles, an organisation can position itself to reap the benefits of understanding the legitimate needs and interests of all its stakeholders by seeking to satisfy all its stakeholders in turn. This study analysed the integrated reports of five retail banks, whose main base of operations were in South Africa, to assess the board’s ability to create value for its stakeholders through adopting a stakeholder inclusive approach to corporate governance as advocated for by the King Code on Corporate Governance in South Africa – King IV™. This assessment was done through an examination of a selection of outcomes relevant to the banking industry and related to each of the six capitals that form part of the value creation process as indicated for in the Integrated Reporting Framework (IIRC, 2013): 1) Financial Capital, 2) Manufactured Capital; 3) Intellectual Capital; 4) Human Capital; 5) Social and Relationship Capital, and; 6) Natural Capital. The results obtained, over a three-year period – 2018 to 2020, revealed that while the directors had a firm understanding of who their material stakeholders were, they struggled to create value that catered to all their stakeholders collectively. In addition, the directors were also unable to create sustainable value over the assessment period. As a result of this, most banks, with the exception of one, were unable to realise the value creation opportunities that could have led to a potential source of competitive advantage. The study concludes that while no observable sustainable competitive advantage was evident over the period of assessment, the concept of stakeholder inclusivity is an important corporate governance principle that drives value creation and, as such, warrants more attention from the director’s point of view. This research is intended to contribute to the growing knowledge on the importance of stakeholder inclusivity in corporate governance execution. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2022
- Full Text:
- Date Issued: 2022-04-06
- Authors: Wolhuter, Darren Wilfred
- Date: 2022-04-06
- Subjects: Stakeholder management South Africa , Strategic planning South Africa , Banks and banking South Africa , Corporate governance South Africa , Competition , Resource-based theory
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/284548 , vital:56073
- Description: Stakeholder theory has long put forth the concept that managerial attention must be given to all stakeholders towards the realisation of value creation opportunities. Through the process of stakeholder engagement, and through the adoption of stakeholder inclusivity principles, an organisation can position itself to reap the benefits of understanding the legitimate needs and interests of all its stakeholders by seeking to satisfy all its stakeholders in turn. This study analysed the integrated reports of five retail banks, whose main base of operations were in South Africa, to assess the board’s ability to create value for its stakeholders through adopting a stakeholder inclusive approach to corporate governance as advocated for by the King Code on Corporate Governance in South Africa – King IV™. This assessment was done through an examination of a selection of outcomes relevant to the banking industry and related to each of the six capitals that form part of the value creation process as indicated for in the Integrated Reporting Framework (IIRC, 2013): 1) Financial Capital, 2) Manufactured Capital; 3) Intellectual Capital; 4) Human Capital; 5) Social and Relationship Capital, and; 6) Natural Capital. The results obtained, over a three-year period – 2018 to 2020, revealed that while the directors had a firm understanding of who their material stakeholders were, they struggled to create value that catered to all their stakeholders collectively. In addition, the directors were also unable to create sustainable value over the assessment period. As a result of this, most banks, with the exception of one, were unable to realise the value creation opportunities that could have led to a potential source of competitive advantage. The study concludes that while no observable sustainable competitive advantage was evident over the period of assessment, the concept of stakeholder inclusivity is an important corporate governance principle that drives value creation and, as such, warrants more attention from the director’s point of view. This research is intended to contribute to the growing knowledge on the importance of stakeholder inclusivity in corporate governance execution. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2022
- Full Text:
- Date Issued: 2022-04-06
Effect of ultrasonic frequency and power on the sonodynamic therapy activity of cationic Zn (II) phthalocyanines
- Nene, Lindokuhle C, Sindelo, Azole, Britton, Jonathan, Nyokong, Tebello
- Authors: Nene, Lindokuhle C , Sindelo, Azole , Britton, Jonathan , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185737 , vital:44419 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2021.111397"
- Description: We report on the sonodynamic activity of cationic phthalocyanines (Pcs) and the effect of the variation of two parameters: ultrasound frequency and power (Par I (1 MHz, 1 W cm−2), Par II (1 MHz, 2 W cm−2), Par III (3 MHz, 1 W cm−2) and Par IV (3 MHz, 2 W cm−2)) on the efficiency of their reactive oxygen species generation and cancer eradication in vitro thereof. Where Par stands for the various combinations of these parameters. Four Pcs were investigated with substituents bearing diethylamine, ortho- and para-pyridine and morpholine groups. Overall, the para-pyridine and morpholine Pcs showed substantial sono-activity in the various ultrasound parameters with Par I and IV generally showing better singlet oxygen and hydroxyl radicals generation confirmed by electron paramagnetic resonance spectroscopy. In some cases, very high hydroxyl radicals' generation was observed at Par II. Furthermore, the fragmentation of the Pcs after Par II treatments was confirmed using UV–vis and magnetic circular dichroism spectroscopy. The reactive species generation efficacy decreased at Par III for all samples. Ultrasound assisted cytotoxicity of the Pcs was confirmed in vitro using the human (Michigan Cancer Foundation-7) breast cancer cell line.
- Full Text:
- Date Issued: 2021
- Authors: Nene, Lindokuhle C , Sindelo, Azole , Britton, Jonathan , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185737 , vital:44419 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2021.111397"
- Description: We report on the sonodynamic activity of cationic phthalocyanines (Pcs) and the effect of the variation of two parameters: ultrasound frequency and power (Par I (1 MHz, 1 W cm−2), Par II (1 MHz, 2 W cm−2), Par III (3 MHz, 1 W cm−2) and Par IV (3 MHz, 2 W cm−2)) on the efficiency of their reactive oxygen species generation and cancer eradication in vitro thereof. Where Par stands for the various combinations of these parameters. Four Pcs were investigated with substituents bearing diethylamine, ortho- and para-pyridine and morpholine groups. Overall, the para-pyridine and morpholine Pcs showed substantial sono-activity in the various ultrasound parameters with Par I and IV generally showing better singlet oxygen and hydroxyl radicals generation confirmed by electron paramagnetic resonance spectroscopy. In some cases, very high hydroxyl radicals' generation was observed at Par II. Furthermore, the fragmentation of the Pcs after Par II treatments was confirmed using UV–vis and magnetic circular dichroism spectroscopy. The reactive species generation efficacy decreased at Par III for all samples. Ultrasound assisted cytotoxicity of the Pcs was confirmed in vitro using the human (Michigan Cancer Foundation-7) breast cancer cell line.
- Full Text:
- Date Issued: 2021
Women’s experiences on the use of Implanon as a contraceptive method in a selected primary healthcare facility in KwaZulu-Natal
- Mgobhozi, Lucky N., Mbeje, Pretty N., Mchunu, Gugu G.
- Authors: Mgobhozi, Lucky N. , Mbeje, Pretty N. , Mchunu, Gugu G.
- Date: 2021
- Subjects: Contraception Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7159 , vital:53073 , xlink:href=" https://doi.org/10.4102/curationis.v44i1.2187"
- Description: Background: The South African department of health recently introduced subdermal Implanon contraceptive implant with the aim to reduce teenage pregnancy and maternal mortality. First used in all public healthcare facilities across the country since early 2014, this method of contraception has been described as highly effective. However, some women have reported unbearable side effects, forcing them to remove the contraceptive implant early before its expiry date. Negligible emphasis has been placed on staff training and development to equip the nurses with new protocol and policies on Implanon. Objectives: The objective of this study was to explore experiences of women using Implanon as method of contraception at a selected primary healthcare facility in KwaZulu-Natal province of South Africa. Methods: A qualitative, descriptive and exploratory study design was used. A purposive sampling technique was used and a sample of seven women aged between 15 and 50 years was selected for this study. Semi-structured interviews were used in the data collection process. The Tesch’s method for data coding and data analysis was utilised. Necessary ethical measures were taken to ensure that the study is trustworthy. The study was conducted at Community Health Centre, KwaZulu-Natal between June 2017 and December 2018. Results: The findings showed that some participants were still willing to continue using this method of contraception regardless of the unwanted side effects. Major side effects reported were heavy menstrual bleeding, pain and discomfort, weight loss, insomnia and decreased sexual interest, which resulted in most participants stopping the use of Implanon. Conclusion: Most of the participants’ experience unwanted side effects because of poor screening, counselling and support. There is a clear demand to develop a screening tool and facilitate training of healthcare workers when initiating the use of Implanon. Keywords: Implanon; Implanon users; experiences; perceptions; primary healthcare
- Full Text:
- Date Issued: 2021
- Authors: Mgobhozi, Lucky N. , Mbeje, Pretty N. , Mchunu, Gugu G.
- Date: 2021
- Subjects: Contraception Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7159 , vital:53073 , xlink:href=" https://doi.org/10.4102/curationis.v44i1.2187"
- Description: Background: The South African department of health recently introduced subdermal Implanon contraceptive implant with the aim to reduce teenage pregnancy and maternal mortality. First used in all public healthcare facilities across the country since early 2014, this method of contraception has been described as highly effective. However, some women have reported unbearable side effects, forcing them to remove the contraceptive implant early before its expiry date. Negligible emphasis has been placed on staff training and development to equip the nurses with new protocol and policies on Implanon. Objectives: The objective of this study was to explore experiences of women using Implanon as method of contraception at a selected primary healthcare facility in KwaZulu-Natal province of South Africa. Methods: A qualitative, descriptive and exploratory study design was used. A purposive sampling technique was used and a sample of seven women aged between 15 and 50 years was selected for this study. Semi-structured interviews were used in the data collection process. The Tesch’s method for data coding and data analysis was utilised. Necessary ethical measures were taken to ensure that the study is trustworthy. The study was conducted at Community Health Centre, KwaZulu-Natal between June 2017 and December 2018. Results: The findings showed that some participants were still willing to continue using this method of contraception regardless of the unwanted side effects. Major side effects reported were heavy menstrual bleeding, pain and discomfort, weight loss, insomnia and decreased sexual interest, which resulted in most participants stopping the use of Implanon. Conclusion: Most of the participants’ experience unwanted side effects because of poor screening, counselling and support. There is a clear demand to develop a screening tool and facilitate training of healthcare workers when initiating the use of Implanon. Keywords: Implanon; Implanon users; experiences; perceptions; primary healthcare
- Full Text:
- Date Issued: 2021
A Critical Review of Environmental Governance, Land Restitution, and Tourism in Protected Areas
- Authors: Ramukumba, Takalani
- Date: 2021
- Subjects: Tourism Land use Environmental protection Wildlife conservation Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7029 , vital:52756 , xlink:href=":https://doi.org/10.46222/ajhtl.19770720.200"
- Description: Natural areas, when protected, conserve the natural environment and function as social spaces in which tourism brings increased income, employment, and financial support for conservation. The inclusion of local community members in the planning and management of protected areas has been on the rise since the early 1900s. Tourism has been advocated as a strategy that can help in achieving economic development, especially in rural areas. However, governance issues and potential negative impacts of tourism development have been under inspection. Conservation efforts in Southern Africa especially in the late 1800s and early 1900s had negative impacts on the local communities since this led to many communities being displaced or having limited access to these protected areas. This has seen the need for ways and efforts to get local community members' despondency and attitudes towards protected areas change such that in the 20th century, there were efforts to use conservation models that included community members in the decision-making and benefit-sharing process to garner their support for protected areas. This paper reviews literature on environmental governance, land restitution in protected areas, tourism in protected areas, co-management, and the importance of community participation. These concepts are reviewed using Manyeleti Game Reserve as a case study. Keywords: Tourism, land restitution, environmental governance, wildlife resources, and stakeholder participation
- Full Text:
- Date Issued: 2021
- Authors: Ramukumba, Takalani
- Date: 2021
- Subjects: Tourism Land use Environmental protection Wildlife conservation Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7029 , vital:52756 , xlink:href=":https://doi.org/10.46222/ajhtl.19770720.200"
- Description: Natural areas, when protected, conserve the natural environment and function as social spaces in which tourism brings increased income, employment, and financial support for conservation. The inclusion of local community members in the planning and management of protected areas has been on the rise since the early 1900s. Tourism has been advocated as a strategy that can help in achieving economic development, especially in rural areas. However, governance issues and potential negative impacts of tourism development have been under inspection. Conservation efforts in Southern Africa especially in the late 1800s and early 1900s had negative impacts on the local communities since this led to many communities being displaced or having limited access to these protected areas. This has seen the need for ways and efforts to get local community members' despondency and attitudes towards protected areas change such that in the 20th century, there were efforts to use conservation models that included community members in the decision-making and benefit-sharing process to garner their support for protected areas. This paper reviews literature on environmental governance, land restitution in protected areas, tourism in protected areas, co-management, and the importance of community participation. These concepts are reviewed using Manyeleti Game Reserve as a case study. Keywords: Tourism, land restitution, environmental governance, wildlife resources, and stakeholder participation
- Full Text:
- Date Issued: 2021
Effect of Helicosporidium sp. (Chlorophyta; Trebouxiophyceae) infection on Cyrtobagous salviniae Calder and Sands (Coleoptera: Curculionidae), a biological control agent for the invasive Salvinia molesta D.S. Mitchell (Salviniaceae) in South
- Authors: Mphephu, Tshililo Emmanuel
- Date: 2022-10-14
- Subjects: Salvinia molesta South Africa , Weeds Biological control , Cyrtobagous salviniae , Ketoconazole
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365815 , vital:65792 , DOI https://doi.org/10.21504/10962/365815
- Description: The effectiveness of established biological control agents depends on biotic and abiotic interactions in the introduced range. The weevil, Cyrtobagous salviniae Calder and Sands (Coleoptera: Curculionidae), was released as a biological control against Salvinia molesta D.S. Mitchell (Salviniaceae) in South Africa in 1985. This agent has been highly successful against S. molesta and has significantly reduced the weed’s populations around the country. However, in 2007, the parasitic alga, Helicosporidium sp. (an undescribed species), was detected in field-collected C. salviniae adults in South Africa. The distribution and impacts of this disease on the weevil and its efficacy as a control agent were not known. In this thesis, the prevalence, infection load, and impact of Helicosporidium sp. on C. salviniae was determined. In 2019, adult weevils were collected from 10 sites across the Eastern Cape, KwaZulu-Natal, Limpopo, and Western Cape provinces and screened to determine the occurrence, infection load, and geographic distribution of Helicosporidium sp. Transmission mechanisms of this disease in C. salviniae were then evaluated. The possible impact of Helicosporidium sp. was assessed by comparing the feeding rates and the reproductive output of the diseased and healthy adults of C. salviniae. An attempt was then made to eliminate the disease in C. salviniae through the application of the antibiotic, ketoconazole. Further, the role of temperature on infection load in C. salviniae was also assessed. Finally, recommendations for the long-term biological control programme against S. molesta in South Africa were made. The disease covers the entire distribution range of C. salviniae in South Africa, with the disease occurrence rate ranging from 92.15% to 100% insects infected per site. Helicosporidium sp. was found to transmit vertically within the populations of C. salviniae. Infection by the Helicosporidium sp. disease reduced the reproductive output of C. salviniae as well its impact on biomass reduction of S. molesta when a diseased culture was compared to a healthy culture from the USA. 98.44 to 98.55% of Helicosporidium sp. loads were reduced through multiple applications of ketoconazole concentrations under in vitro trials. In vivo treatments resulted in 70% control of Helicosporidium sp. in the adults of C. salviniae that were fed ketoconazole three times over a 21 day period. Adult C. salviniae feeding and survival performances were similar when fed fronds of S. molesta inoculated with ketoconazole and water. The lowest and highest disease loads of Helicosporidium sp. were recorded when the weevils were reared at 30°C and 14°C, respectively. As expected, the highest impact and reproductive output of C. salviniae were at 30°C. The evaluations discussed in this thesis highlight the role of diseases in biological control agents, and gaps in both the pre-release and post-release monitoring that should integrate screening of diseases in these studies. Although the combined application of the antibiotic and temperature will reduce Helicosporidium sp. loads and impact, this technology is most likely only applicable where the weevils are reared in small numbers in a rearing facility and not really applicable to the field situation. It is important to release healthy agents that will cause efficient control of the target weed plant species, therefore, when introducing new biological control agents, the health status of such agents needs to be understood. Therefore, long-term field monitoring and assessment of the impact of C. salviniae on S. molesta should be conducted to track all the changes that may result due to the presence of Helicosporidium sp. This long-term monitoring and assessment will give a more informative role of Helicosporidium sp. in field populations of C. salviniae. , Thesis (PhD) -- Faculty of Science, Zoology and Entomology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Mphephu, Tshililo Emmanuel
- Date: 2022-10-14
- Subjects: Salvinia molesta South Africa , Weeds Biological control , Cyrtobagous salviniae , Ketoconazole
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365815 , vital:65792 , DOI https://doi.org/10.21504/10962/365815
- Description: The effectiveness of established biological control agents depends on biotic and abiotic interactions in the introduced range. The weevil, Cyrtobagous salviniae Calder and Sands (Coleoptera: Curculionidae), was released as a biological control against Salvinia molesta D.S. Mitchell (Salviniaceae) in South Africa in 1985. This agent has been highly successful against S. molesta and has significantly reduced the weed’s populations around the country. However, in 2007, the parasitic alga, Helicosporidium sp. (an undescribed species), was detected in field-collected C. salviniae adults in South Africa. The distribution and impacts of this disease on the weevil and its efficacy as a control agent were not known. In this thesis, the prevalence, infection load, and impact of Helicosporidium sp. on C. salviniae was determined. In 2019, adult weevils were collected from 10 sites across the Eastern Cape, KwaZulu-Natal, Limpopo, and Western Cape provinces and screened to determine the occurrence, infection load, and geographic distribution of Helicosporidium sp. Transmission mechanisms of this disease in C. salviniae were then evaluated. The possible impact of Helicosporidium sp. was assessed by comparing the feeding rates and the reproductive output of the diseased and healthy adults of C. salviniae. An attempt was then made to eliminate the disease in C. salviniae through the application of the antibiotic, ketoconazole. Further, the role of temperature on infection load in C. salviniae was also assessed. Finally, recommendations for the long-term biological control programme against S. molesta in South Africa were made. The disease covers the entire distribution range of C. salviniae in South Africa, with the disease occurrence rate ranging from 92.15% to 100% insects infected per site. Helicosporidium sp. was found to transmit vertically within the populations of C. salviniae. Infection by the Helicosporidium sp. disease reduced the reproductive output of C. salviniae as well its impact on biomass reduction of S. molesta when a diseased culture was compared to a healthy culture from the USA. 98.44 to 98.55% of Helicosporidium sp. loads were reduced through multiple applications of ketoconazole concentrations under in vitro trials. In vivo treatments resulted in 70% control of Helicosporidium sp. in the adults of C. salviniae that were fed ketoconazole three times over a 21 day period. Adult C. salviniae feeding and survival performances were similar when fed fronds of S. molesta inoculated with ketoconazole and water. The lowest and highest disease loads of Helicosporidium sp. were recorded when the weevils were reared at 30°C and 14°C, respectively. As expected, the highest impact and reproductive output of C. salviniae were at 30°C. The evaluations discussed in this thesis highlight the role of diseases in biological control agents, and gaps in both the pre-release and post-release monitoring that should integrate screening of diseases in these studies. Although the combined application of the antibiotic and temperature will reduce Helicosporidium sp. loads and impact, this technology is most likely only applicable where the weevils are reared in small numbers in a rearing facility and not really applicable to the field situation. It is important to release healthy agents that will cause efficient control of the target weed plant species, therefore, when introducing new biological control agents, the health status of such agents needs to be understood. Therefore, long-term field monitoring and assessment of the impact of C. salviniae on S. molesta should be conducted to track all the changes that may result due to the presence of Helicosporidium sp. This long-term monitoring and assessment will give a more informative role of Helicosporidium sp. in field populations of C. salviniae. , Thesis (PhD) -- Faculty of Science, Zoology and Entomology, 2022
- Full Text:
- Date Issued: 2022-10-14
Rapid Synthesis of Thiol-Co-Capped-CdTe/CdSe/ZnSe Core Shell-Shell Nanoparticles
- Daramola, Olamide, Siwe-Noundou, Xavier, Tseki, Potlaki, Krause, Rui W M
- Authors: Daramola, Olamide , Siwe-Noundou, Xavier , Tseki, Potlaki , Krause, Rui W M
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191758 , vital:45161 , xlink:href="https://doi.org/10.3390/nano11051193"
- Description: CdTe QDs has been demonstrated in many studies to possess good outstanding optical and photo-physical properties. However, it has been established from literature that the toxic Cd2+ that tends to leak out into nearby solutions can be protected by less toxic ZnS or ZnSe shells leading to the synthesis of core-shells and multi-core-shells. Hence, this has allowed the synthesis of CdTe multi-core-shells to have gained much interest. The preparation of most CdTe multi-core-shells reported from various studies usually has a longer reaction time (6–24 h) in reaching their highest emission maxima. The synthesis of CdTe multi-core-shells in this study only took 35 min to obtain a highest emission maximum compared to what has been reported from the literature. CdTe multi-core-shells were synthesized by injecting 7, 14, and 21 mL each of Zn complex solution and Se ions into the reacting mixture containing CdTe core-shells (3 h) at 5 min intervals over a 35 min reaction time. The emission maxima of the MPA-TGA-CdTe multi-core-shells at 21 mL injection was recorded around 625 nm. Therefore, we are reporting the rapid synthesis of five different thiol co-capped CdTe/CdSe/ZnSe multi-core-shell QDs with the highest emission maxima obtained at 35 min reaction time.
- Full Text:
- Date Issued: 2021
- Authors: Daramola, Olamide , Siwe-Noundou, Xavier , Tseki, Potlaki , Krause, Rui W M
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191758 , vital:45161 , xlink:href="https://doi.org/10.3390/nano11051193"
- Description: CdTe QDs has been demonstrated in many studies to possess good outstanding optical and photo-physical properties. However, it has been established from literature that the toxic Cd2+ that tends to leak out into nearby solutions can be protected by less toxic ZnS or ZnSe shells leading to the synthesis of core-shells and multi-core-shells. Hence, this has allowed the synthesis of CdTe multi-core-shells to have gained much interest. The preparation of most CdTe multi-core-shells reported from various studies usually has a longer reaction time (6–24 h) in reaching their highest emission maxima. The synthesis of CdTe multi-core-shells in this study only took 35 min to obtain a highest emission maximum compared to what has been reported from the literature. CdTe multi-core-shells were synthesized by injecting 7, 14, and 21 mL each of Zn complex solution and Se ions into the reacting mixture containing CdTe core-shells (3 h) at 5 min intervals over a 35 min reaction time. The emission maxima of the MPA-TGA-CdTe multi-core-shells at 21 mL injection was recorded around 625 nm. Therefore, we are reporting the rapid synthesis of five different thiol co-capped CdTe/CdSe/ZnSe multi-core-shell QDs with the highest emission maxima obtained at 35 min reaction time.
- Full Text:
- Date Issued: 2021
‘Don't educate them out of educating themselves’
- Krueger, Anton, Wunder, Albert
- Authors: Krueger, Anton , Wunder, Albert
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225481 , vital:49226 , xlink:href="https://doi.org/10.5920/pam.1005"
- Description: Al Wunder's biography, in his own words: I had four lucky breaks that precipitated my becoming a teacher of improvised movement theatre. Between the ages of eight and fourteen I broke my right leg four different times. In 1962, I began modern dance classes with Alwin Nikolais as a physical therapy. His choreography and improvisation sections of class inspired me to teach and perform professionally. I spent eight years studying, teaching, choreographing, and performing with Nikolais. 1970 saw me move to the San Francisco Bay area where I opened a dance studio teaching Nikolais dance technique and improvisation. In 1971, I joined forces with Terry Sendgraff and Ruth Zaporah creating The Berkeley Dance Theater and Gymnasium. My focus was to create a way to teach dance technique through improvisation. I met my Australian wife, Lynden Nicholls, in 1981 when she came to study Motivity at Terry’s studio in Berkeley. In 1982, I moved to Melbourne, Australia where Lynden and I set up a dance studio. My focus changed from teaching dance technique improvisationally to teaching improvised movement theatre performance
- Full Text:
- Date Issued: 2021
- Authors: Krueger, Anton , Wunder, Albert
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225481 , vital:49226 , xlink:href="https://doi.org/10.5920/pam.1005"
- Description: Al Wunder's biography, in his own words: I had four lucky breaks that precipitated my becoming a teacher of improvised movement theatre. Between the ages of eight and fourteen I broke my right leg four different times. In 1962, I began modern dance classes with Alwin Nikolais as a physical therapy. His choreography and improvisation sections of class inspired me to teach and perform professionally. I spent eight years studying, teaching, choreographing, and performing with Nikolais. 1970 saw me move to the San Francisco Bay area where I opened a dance studio teaching Nikolais dance technique and improvisation. In 1971, I joined forces with Terry Sendgraff and Ruth Zaporah creating The Berkeley Dance Theater and Gymnasium. My focus was to create a way to teach dance technique through improvisation. I met my Australian wife, Lynden Nicholls, in 1981 when she came to study Motivity at Terry’s studio in Berkeley. In 1982, I moved to Melbourne, Australia where Lynden and I set up a dance studio. My focus changed from teaching dance technique improvisationally to teaching improvised movement theatre performance
- Full Text:
- Date Issued: 2021
Nothing forever
- Authors: Krueger, Anton
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225533 , vital:49233 , xlink:href="https://doi.org/10.5920/pam.1013"
- Description: Thank you to everybody who made contributions to this bumper 2021 Special Issue on Improvisation. Many thanks to our peer reviewers and especially to co-editors Deborah and Daniel for their help with the selection and editing process which has now culminated in a baker’s dozen texts. With contributions from Australia, South Africa, and New Zealand, as well as from France, the USA and the UK, the issue includes five interviews, four articles, two book reviews, a reflection and a score.
- Full Text:
- Date Issued: 2021
- Authors: Krueger, Anton
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225533 , vital:49233 , xlink:href="https://doi.org/10.5920/pam.1013"
- Description: Thank you to everybody who made contributions to this bumper 2021 Special Issue on Improvisation. Many thanks to our peer reviewers and especially to co-editors Deborah and Daniel for their help with the selection and editing process which has now culminated in a baker’s dozen texts. With contributions from Australia, South Africa, and New Zealand, as well as from France, the USA and the UK, the issue includes five interviews, four articles, two book reviews, a reflection and a score.
- Full Text:
- Date Issued: 2021