Social upgrading or dependency?: Investigating the implications of the inclusion of commercial wine farms within South African Fairtrade certification
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
Land expropriation without compensation: a study of constructions of the Parliamentary process in selected mainstream and “ground-up” media from 27 February – 12 August 2018
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10
Demarcation of municipalities and service delivery capacity: a case of selected eastern cape municipalities
- Authors: Sokopo, Johannes
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/54574 , vital:46715
- Description: The study examines the relationship between demarcation of municipal boundaries and the capacity of a municipality to deliver services. The case of the amalgamation of Baviaans, Camdeboo, and Ikwezi local municipalities which has led to the establishment of the Dr Beyers Naudè Municipality in the Sara Baartman District Municipality in the Eastern Cape has been used to determine this relationship in this study. The amalgamation of these municipalities has led to the redetermination and dismantling of their boundaries and the establishment of the boundaries of the newly created and larger Dr Beyers Naudè Local Municipality. The study investigated whether the demarcation of municipal boundaries has, in this instance, enhanced the capacity of the municipality to deliver basic services. Organisational Theory was used to interpret the amalgamation of municipalities. This theory was used for the theoretical basis of organisational structure and highlighting the need for the alignment of organizational structure with the municipalities’ mandate, of effective and efficient service delivery. The study adopted a qualitative research method and employed a non-probability purposive sampling technique to select participants. Interviews were used for data collection. 38 participants were interviewed, namely 7 councillors, 5 municipal officials, 5 members of the ratepayers’ association and 21 members of the community. Mixed views were expressed by participants regarding the enhancement of the state on basic service delivery after the merger of the three local municipalities. Furthermore, the study did not find evidence of a feasibility study prior to the implementation of the amalgamation process. Subsequently, the study could not find conclusive evidence relating to the enhancement of the capacity of the municipality to deliver services after the redetermination of municipal boundaries. The study recommends, among others, that the demarcation of municipal boundaries should be preceded by an appropriate feasibility study and be done such that there is compliance with the relevant legislation, and it must also have an effective public participation. The study also recommends that the newly established Dr Beyers Naudè Local Municipality should focus on maintaining the service delivery infrastructure it has inherited from the merger of its three predecessor municipalities, enhance public participation in its programmes, and priorities community beneficiation as a critical aspect of its service delivery mandate. , Thesis (PhD) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Sokopo, Johannes
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/54574 , vital:46715
- Description: The study examines the relationship between demarcation of municipal boundaries and the capacity of a municipality to deliver services. The case of the amalgamation of Baviaans, Camdeboo, and Ikwezi local municipalities which has led to the establishment of the Dr Beyers Naudè Municipality in the Sara Baartman District Municipality in the Eastern Cape has been used to determine this relationship in this study. The amalgamation of these municipalities has led to the redetermination and dismantling of their boundaries and the establishment of the boundaries of the newly created and larger Dr Beyers Naudè Local Municipality. The study investigated whether the demarcation of municipal boundaries has, in this instance, enhanced the capacity of the municipality to deliver basic services. Organisational Theory was used to interpret the amalgamation of municipalities. This theory was used for the theoretical basis of organisational structure and highlighting the need for the alignment of organizational structure with the municipalities’ mandate, of effective and efficient service delivery. The study adopted a qualitative research method and employed a non-probability purposive sampling technique to select participants. Interviews were used for data collection. 38 participants were interviewed, namely 7 councillors, 5 municipal officials, 5 members of the ratepayers’ association and 21 members of the community. Mixed views were expressed by participants regarding the enhancement of the state on basic service delivery after the merger of the three local municipalities. Furthermore, the study did not find evidence of a feasibility study prior to the implementation of the amalgamation process. Subsequently, the study could not find conclusive evidence relating to the enhancement of the capacity of the municipality to deliver services after the redetermination of municipal boundaries. The study recommends, among others, that the demarcation of municipal boundaries should be preceded by an appropriate feasibility study and be done such that there is compliance with the relevant legislation, and it must also have an effective public participation. The study also recommends that the newly established Dr Beyers Naudè Local Municipality should focus on maintaining the service delivery infrastructure it has inherited from the merger of its three predecessor municipalities, enhance public participation in its programmes, and priorities community beneficiation as a critical aspect of its service delivery mandate. , Thesis (PhD) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
ZIMBABWE’S LIBERATION STRUGGLE: A CRITICAL DECADE OF THE ZIMBABWE AFRICAN NATIONAL UNION (ZANU)’S GUERRILLA WAR, 1970-1980
- Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
Cape Vultures (Gyps coprotheres) and the threat of wind farms: a race to extinction?
- Authors: Brooke, Francis Rae
- Date: 2022-04
- Subjects: Wind Turbines --Blades --Materials , Gyps --South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/55910 , vital:54399
- Description: The development of wind energy is increasing globally and is often considered more environmentally friendly when compared to fossil fuel technologies. However, one of the ecological drawbacks of wind energy are the collisions of wildlife with turbine blades. In addition, the resulting anthropogenic landscape transformation can negatively impact populations. The Cape Vulture (Gyps coprotheres), a large endangered southern African endemic species, thus may be at risk from turbine development. The species has decreased dramatically in the past 50 years and understanding how additional mortalities from wind turbine impacts affect the population is needed to ensure effective conservation efforts. This study aimed to determine the population response to this emerging threat. This study first reviewed the species-, site- and wind farm- specific traits that make Gyps species vulnerable to collision with wind energy infrastructure. It examined the monitoring practices employed during the pre- and post-construction phase and mitigation measures in South Africa and compared it with international standards. Furthermore, wind energy development may disrupt landscape connectivity and understanding which, and how habitat patches are used is needed. Using network theory combined with telemetry data from tagged individuals across three age classes, habitat patch use was identified. Further, environmental variables associated with identified habitat patches were identified. Additionally, considering the wind energy industry is expanding in South Africa, exploring how the Cape Vulture population will respond to this novel and emerging threat may aid future conservation management plans. Therefore, using a population viability analysis approach, the study explored how present and future wind turbine mortality scenarios impact the Cape Vulture population and how the population will respond to increased wind turbine development. , Thesis (PhD) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Brooke, Francis Rae
- Date: 2022-04
- Subjects: Wind Turbines --Blades --Materials , Gyps --South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/55910 , vital:54399
- Description: The development of wind energy is increasing globally and is often considered more environmentally friendly when compared to fossil fuel technologies. However, one of the ecological drawbacks of wind energy are the collisions of wildlife with turbine blades. In addition, the resulting anthropogenic landscape transformation can negatively impact populations. The Cape Vulture (Gyps coprotheres), a large endangered southern African endemic species, thus may be at risk from turbine development. The species has decreased dramatically in the past 50 years and understanding how additional mortalities from wind turbine impacts affect the population is needed to ensure effective conservation efforts. This study aimed to determine the population response to this emerging threat. This study first reviewed the species-, site- and wind farm- specific traits that make Gyps species vulnerable to collision with wind energy infrastructure. It examined the monitoring practices employed during the pre- and post-construction phase and mitigation measures in South Africa and compared it with international standards. Furthermore, wind energy development may disrupt landscape connectivity and understanding which, and how habitat patches are used is needed. Using network theory combined with telemetry data from tagged individuals across three age classes, habitat patch use was identified. Further, environmental variables associated with identified habitat patches were identified. Additionally, considering the wind energy industry is expanding in South Africa, exploring how the Cape Vulture population will respond to this novel and emerging threat may aid future conservation management plans. Therefore, using a population viability analysis approach, the study explored how present and future wind turbine mortality scenarios impact the Cape Vulture population and how the population will respond to increased wind turbine development. , Thesis (PhD) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-04
Délices et négation: une approche de l’écriture féminine à travers quelques romans Africains Francophones
- Authors: Anjugu, Taimako Ajigo
- Date: 2023-03-30
- Subjects: African fiction (French) History and criticism , Literature Women authors , Women authors, African , Reader-response criticism , Womanism in literature
- Language: French
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/409779 , vital:70629 , DOI 10.21504/10962/409779
- Description: From the onset, it is worthy to note that, nowadays, just as after the independence of most African countries, several writers from the African continent have been preoccupied with the fate of women. This is because, the African continent was since ancient times characterized by certain traditions and cultures which mainly have contributed to the plight of the women. This goes to emphasise that women in most cases are the victims of misdeeds such as early marriage, forced marriage, prejudices, violence, marginalisation, exploitation, discrimination; in short, vices that lead to devalorisation of African women in Africa. Over time, some contemporary French-speaking African writers have responded to the devaluation and valuation of women in their novels using 21st century objective view. With regard to the theme that we decided to address in this research, it is worth knowing that the preponderant task is based on the socio-critical theory, postulated by Claude Duchet. Meanwhile, recourse is also made to the comparative method by Rens, Bod et al. However, since the author’s message could be understood by the reader through the use of some expressions or terms that speak directly to the themes of the research, and that a reader’s role in reading experience cannot be overemphasised, we have been able to also lean on the Reader-response theory of Louise Michelle Rosenblatt. The three methods were used concurrently especially that the analysis of each text is based on how characters are being depicted leading us to realizing that our findings on how the African woman is devalued in the first part of the research, while in the second part of the thesis, our findings demonstrate that a lot of tributes are showered on the African woman due to her numerous outstanding qualities. In effect, our findings also reinforce a significant shift in the narrative that concerns the contemporary view on womanhood. Hence, moving from a dogmatic overconcentration on her lot to the new era woman whose lot is now redefined via the new wave feminist perspective on the negation of the African woman. This could be said to be in line with Amadiume Ifi’s contributions and pioneering work in feminist discourse towards new ways of thinking about sex and gender, the question of power, and women’s place in history and culture. , Pour commencer, il est nécessaire de se souvenir qu’à l’époque actuelle, comme juste après les indépendances de la plupart des pays africains, bon nombre des écrivains venant du continent africain décident de se préoccuper des méfaits sociaux tels que le mariage précoce et/ou forcé, les préjugés, la violence, la marginalisation, l’exploitation, la discrimination, entre autres. Tous ces vices sont issus de la négation de la femme africaine. Ceci se justifie par le fait que le continent africain était depuis l’antiquité caractérisé par certaines traditions et cultures qui ont contribué principalement aux dégâts ci-dessus soulignés subis par les femmes. En effet, nous estimons que beaucoup de femmes sont victimes de ces méfaits qui sont encore pratiqués dans certaines parties de l’Afrique. Avec le temps, certains écrivains africains francophones contemporains représentent la dévalorisation et la valorisation de la femme dans leurs romans en se servant d’une vision contemporaine, celle du XXIe siècle. En ce qui concerne le thème que nous avons décidé d'aborder dans cette recherche, il faut savoir que la tâche prépondérante repose sur la théorie sociocritique, postulée par Claude Duchet. Parallèlement, on a également recours à la méthode comparative de Bod Rens Et ses coauteurs. Cependant, puisque le message de l’auteur pourrait être compris aussi par le lecteur à travers l’usage de certaines expressions ou termes qui sont directement liés aux thèmes de la recherche, le rôle du lecteur dans l’expérience de lecture ne peut pas être surestimé, nous avons également pu nous appuyer sur la théorie de la réponse du lecteur de Louise Michelle Rosenblatt. Les trois méthodes ont été utilisées simultanément d'autant plus que l'analyse de chaque texte est basée sur la façon dont les personnages sont représentés ; ceci nous a amené à tirer nos conclusions sur la façon dont la femme africaine est dévalorisée dans la première partie de la recherche, tandis que dans la deuxième partie de la thèse, nos résultats démontrent que de nombreux hommages sont rendus à la femme africaine grâce à ses nombreuses qualités exceptionnelles. En effet, nos résultats renforcent également un changement important dans le récit qui concerne la vision contemporaine de la féminité. Par conséquent, passer d’une surconcentration dogmatique sur son sort à la femme de la nouvelle ère dont le sort est maintenant redéfini via la perspective féministe par rapport à la négation de la femme africaine telle a été la démarche. On pourrait dire que cela est au diapason avec les contributions d’Amadiume Ifi et avec son travail dans le discours féministe vers de nouvelles façons de penser le sexe et le genre, la question du pouvoir et la place de la femme dans l’histoire et la culture. , Thesis (PhD) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-03-30
- Authors: Anjugu, Taimako Ajigo
- Date: 2023-03-30
- Subjects: African fiction (French) History and criticism , Literature Women authors , Women authors, African , Reader-response criticism , Womanism in literature
- Language: French
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/409779 , vital:70629 , DOI 10.21504/10962/409779
- Description: From the onset, it is worthy to note that, nowadays, just as after the independence of most African countries, several writers from the African continent have been preoccupied with the fate of women. This is because, the African continent was since ancient times characterized by certain traditions and cultures which mainly have contributed to the plight of the women. This goes to emphasise that women in most cases are the victims of misdeeds such as early marriage, forced marriage, prejudices, violence, marginalisation, exploitation, discrimination; in short, vices that lead to devalorisation of African women in Africa. Over time, some contemporary French-speaking African writers have responded to the devaluation and valuation of women in their novels using 21st century objective view. With regard to the theme that we decided to address in this research, it is worth knowing that the preponderant task is based on the socio-critical theory, postulated by Claude Duchet. Meanwhile, recourse is also made to the comparative method by Rens, Bod et al. However, since the author’s message could be understood by the reader through the use of some expressions or terms that speak directly to the themes of the research, and that a reader’s role in reading experience cannot be overemphasised, we have been able to also lean on the Reader-response theory of Louise Michelle Rosenblatt. The three methods were used concurrently especially that the analysis of each text is based on how characters are being depicted leading us to realizing that our findings on how the African woman is devalued in the first part of the research, while in the second part of the thesis, our findings demonstrate that a lot of tributes are showered on the African woman due to her numerous outstanding qualities. In effect, our findings also reinforce a significant shift in the narrative that concerns the contemporary view on womanhood. Hence, moving from a dogmatic overconcentration on her lot to the new era woman whose lot is now redefined via the new wave feminist perspective on the negation of the African woman. This could be said to be in line with Amadiume Ifi’s contributions and pioneering work in feminist discourse towards new ways of thinking about sex and gender, the question of power, and women’s place in history and culture. , Pour commencer, il est nécessaire de se souvenir qu’à l’époque actuelle, comme juste après les indépendances de la plupart des pays africains, bon nombre des écrivains venant du continent africain décident de se préoccuper des méfaits sociaux tels que le mariage précoce et/ou forcé, les préjugés, la violence, la marginalisation, l’exploitation, la discrimination, entre autres. Tous ces vices sont issus de la négation de la femme africaine. Ceci se justifie par le fait que le continent africain était depuis l’antiquité caractérisé par certaines traditions et cultures qui ont contribué principalement aux dégâts ci-dessus soulignés subis par les femmes. En effet, nous estimons que beaucoup de femmes sont victimes de ces méfaits qui sont encore pratiqués dans certaines parties de l’Afrique. Avec le temps, certains écrivains africains francophones contemporains représentent la dévalorisation et la valorisation de la femme dans leurs romans en se servant d’une vision contemporaine, celle du XXIe siècle. En ce qui concerne le thème que nous avons décidé d'aborder dans cette recherche, il faut savoir que la tâche prépondérante repose sur la théorie sociocritique, postulée par Claude Duchet. Parallèlement, on a également recours à la méthode comparative de Bod Rens Et ses coauteurs. Cependant, puisque le message de l’auteur pourrait être compris aussi par le lecteur à travers l’usage de certaines expressions ou termes qui sont directement liés aux thèmes de la recherche, le rôle du lecteur dans l’expérience de lecture ne peut pas être surestimé, nous avons également pu nous appuyer sur la théorie de la réponse du lecteur de Louise Michelle Rosenblatt. Les trois méthodes ont été utilisées simultanément d'autant plus que l'analyse de chaque texte est basée sur la façon dont les personnages sont représentés ; ceci nous a amené à tirer nos conclusions sur la façon dont la femme africaine est dévalorisée dans la première partie de la recherche, tandis que dans la deuxième partie de la thèse, nos résultats démontrent que de nombreux hommages sont rendus à la femme africaine grâce à ses nombreuses qualités exceptionnelles. En effet, nos résultats renforcent également un changement important dans le récit qui concerne la vision contemporaine de la féminité. Par conséquent, passer d’une surconcentration dogmatique sur son sort à la femme de la nouvelle ère dont le sort est maintenant redéfini via la perspective féministe par rapport à la négation de la femme africaine telle a été la démarche. On pourrait dire que cela est au diapason avec les contributions d’Amadiume Ifi et avec son travail dans le discours féministe vers de nouvelles façons de penser le sexe et le genre, la question du pouvoir et la place de la femme dans l’histoire et la culture. , Thesis (PhD) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-03-30
A compliance framework for IT governance adoption and use by state-owned entities in South Africa
- Authors: Nxozi, Monelo
- Date: 2023-03-31
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/419244 , vital:71628
- Description: Embargoed. Possible release date in early 2025. , Thesis (PhD) -- Faculty of Commerce, Information Systems, 2023
- Full Text:
- Date Issued: 2023-03-31
- Authors: Nxozi, Monelo
- Date: 2023-03-31
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/419244 , vital:71628
- Description: Embargoed. Possible release date in early 2025. , Thesis (PhD) -- Faculty of Commerce, Information Systems, 2023
- Full Text:
- Date Issued: 2023-03-31
Spatial and temporal analysis of the critical zone in the Western rift valley corridor: towards earth stewardship science in East Africa
- Authors: Miller, Warren David
- Date: 2022-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/59771 , vital:62423
- Description: Over the coming decades, Africa is expected to experience disturbing effects due to climate change and increased land cover change due to human influences presenting a significant concern for the future well-being of human and biological systems, the latter being the foundation of ecosystem services supplied to humanity. Therefore, unprecedented transdisciplinary cooperation, coordination, and integration amongst researchers, government, and civil society are necessary to increase the resiliency of these systems. This study aims to provide an outline of the Africa Alive Corridors (AAC) as an essential model for the encouragement of sustainable development through Earth Stewardship science. These aims are accompanied by the quantification and forward modelling for land cover change of the Critical Zone over 10 Great Lake Basins across one of the AAC, the Western Rift Valley Corridor (WRVC), in East Africa between the years 2018 and 2060. This approach provides the foundation for implementing improved regional governance, better encouragement of sustainable development beyond the 2030 United Nations Sustainable Development Goals, and education programs, such as the AAC, that promote socio-ecological resilience through Earth Stewardship Science. The AAC archives a portion of East Africa as the WRVC, a corridor along the western branch of the East African Rift System that highlights twenty heritage nodes, primarily great lakes, mountain ranges, national parks, and biological hotspots. These heritage entities are associated with ca. 12-million-years of evolution and transformation of the East African topography and related African Great Lake (AGL) systems. The thesis defines the study area by delineating AGL basins intersected by the WRVC. Across these basins, land cover change analysis provides a platform for an integrated assessment of the projected health of the corridor region. Existing land cover datasets provide the initial conditions of the study area for 2008 and 2013. Land cover between 2008 and 2013 is cross-tabulated using the Land Cover Module in the Terrset software, followed by the iii delineation of sub-models and driver variable identification. The Multi-Layer Perceptron algorithm provides the transition potentials between tree cover, urban area, cropland, wetland, and open area classes. Change quantification and prediction using Markov Chain analysis are then established for 2018, 2030, and 2060. The model successfully simulated future land cover change and concluded that: (1) proximity to existing human activity, proximity to existing tree cover, and population are the primary drivers of change; (2) the dominant land cover of the ten lake basins for 2018 was cropland at ca. 48%, followed by tree cover at ca. 33%; (3) total anthropogenic change over the coming four decades equates to over ca. 52 000 km2 (5 200 000 ha), and particularly (4) an urban area is expected to increase by >130%. This assessment ultimately provides a platform for regional governance development at the basin scale and Earth Stewardship science in East Africa. These changes require transdisciplinary action from researchers to civil society. The AAC provides the foundation for understanding the dynamics of the systems that support life across broader spatial and temporal resolutions in Africa, highlighting the need for future generations to build socio-ecological resilience to anticipate challenges such as biodiversity loss posed by climate change and excessive land cover change. , Thesis (DSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-12
- Authors: Miller, Warren David
- Date: 2022-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/59771 , vital:62423
- Description: Over the coming decades, Africa is expected to experience disturbing effects due to climate change and increased land cover change due to human influences presenting a significant concern for the future well-being of human and biological systems, the latter being the foundation of ecosystem services supplied to humanity. Therefore, unprecedented transdisciplinary cooperation, coordination, and integration amongst researchers, government, and civil society are necessary to increase the resiliency of these systems. This study aims to provide an outline of the Africa Alive Corridors (AAC) as an essential model for the encouragement of sustainable development through Earth Stewardship science. These aims are accompanied by the quantification and forward modelling for land cover change of the Critical Zone over 10 Great Lake Basins across one of the AAC, the Western Rift Valley Corridor (WRVC), in East Africa between the years 2018 and 2060. This approach provides the foundation for implementing improved regional governance, better encouragement of sustainable development beyond the 2030 United Nations Sustainable Development Goals, and education programs, such as the AAC, that promote socio-ecological resilience through Earth Stewardship Science. The AAC archives a portion of East Africa as the WRVC, a corridor along the western branch of the East African Rift System that highlights twenty heritage nodes, primarily great lakes, mountain ranges, national parks, and biological hotspots. These heritage entities are associated with ca. 12-million-years of evolution and transformation of the East African topography and related African Great Lake (AGL) systems. The thesis defines the study area by delineating AGL basins intersected by the WRVC. Across these basins, land cover change analysis provides a platform for an integrated assessment of the projected health of the corridor region. Existing land cover datasets provide the initial conditions of the study area for 2008 and 2013. Land cover between 2008 and 2013 is cross-tabulated using the Land Cover Module in the Terrset software, followed by the iii delineation of sub-models and driver variable identification. The Multi-Layer Perceptron algorithm provides the transition potentials between tree cover, urban area, cropland, wetland, and open area classes. Change quantification and prediction using Markov Chain analysis are then established for 2018, 2030, and 2060. The model successfully simulated future land cover change and concluded that: (1) proximity to existing human activity, proximity to existing tree cover, and population are the primary drivers of change; (2) the dominant land cover of the ten lake basins for 2018 was cropland at ca. 48%, followed by tree cover at ca. 33%; (3) total anthropogenic change over the coming four decades equates to over ca. 52 000 km2 (5 200 000 ha), and particularly (4) an urban area is expected to increase by >130%. This assessment ultimately provides a platform for regional governance development at the basin scale and Earth Stewardship science in East Africa. These changes require transdisciplinary action from researchers to civil society. The AAC provides the foundation for understanding the dynamics of the systems that support life across broader spatial and temporal resolutions in Africa, highlighting the need for future generations to build socio-ecological resilience to anticipate challenges such as biodiversity loss posed by climate change and excessive land cover change. , Thesis (DSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-12
The incorporation of GeoGebra as a visualisation tool to teach calculus in teacher education institutions: the Zambian case
- Authors: Kangwa, Lemmy
- Date: 2022-10-14
- Subjects: GeoGebra , Calculus Study and teaching (Secondary) Zambia , Visual learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405470 , vital:70174 , DOI
- Description: This qualitative case study investigated teacher educators’ (lecturers) use of the dynamic mathematics software, GeoGebra, to teach calculus in three teacher education institutions (TEIs) in Zambia. Visualisation, a key characteristic of GeoGebra, is increasingly gaining recognition of playing a critical role in mathematics teaching and learning, especially in problem solving tasks. It is considered a powerful didactical tool for students to construct mental and physical representations that can enhance conceptual understanding of mathematics. GeoGebra is a visualisation tool that can be used for problem-oriented teaching and foster mathematical experiments and discoveries. GeoGebra’s inherent visualisation characteristics align well with the teaching of calculus, the mathematical domain of this study. The study (whose research methodology was underpinned by the interpretive paradigm) was undertaken with a broader goal of designing and implementing GeoGebra applets and instructional materials on various calculus topics. The study is located within the “Teaching and Learning Mathematics with GeoGebra (TLMG) project” – a project that involves mathematics teachers and lecturers in Zambia. The case in this study is the six mathematics lecturers who co-designed and used GeoGebra applets to teach derivatives and integrals to pre-service mathematics teachers in TEIs. The unit of analysis therefore is the six lecturers’ use of GeoGebra as a visualisation tool to teach calculus to enhance conceptual understanding, their perceptions and experiences of using GeoGebra and the enabling and constraining factors of using GeoGebra to teach and learn mathematics. The data for the study were video recordings of observations and interviews of lecturers. The data was analysed thematically and was guided and informed by an analytical framework adopted from the theory of constructivism – the umbrella theoretical framework of this study – and the models of Technological Pedagogical Content Knowledge (TPACK), and the Technology Acceptance Model (TAM). A detailed analysis of the lecturers’ interactions with the applets enabled me to gain insights into the participants’ experiences and perceptions of GeoGebra applets in the teaching and learning process. The findings of the study revealed that the visualisation characteristics of GeoGebra generally enhanced the conceptual understanding of calculus. It also revealed that adequate training, coupled with sufficient knowledge of the subject matter in calculus, were necessary for lecturers to use GeoGebra effectively, and that the lack of resources and expertise were major hindrances in the use of GeoGebra to teach mathematics in TEIs. It also revealed that there is a need to equip GeoGebra with other features that would make it more versatile, and suggested a teaching approach that would complement the use of conventional methods and GeoGebra to provide a link between abstract and concrete concepts of calculus. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Kangwa, Lemmy
- Date: 2022-10-14
- Subjects: GeoGebra , Calculus Study and teaching (Secondary) Zambia , Visual learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405470 , vital:70174 , DOI
- Description: This qualitative case study investigated teacher educators’ (lecturers) use of the dynamic mathematics software, GeoGebra, to teach calculus in three teacher education institutions (TEIs) in Zambia. Visualisation, a key characteristic of GeoGebra, is increasingly gaining recognition of playing a critical role in mathematics teaching and learning, especially in problem solving tasks. It is considered a powerful didactical tool for students to construct mental and physical representations that can enhance conceptual understanding of mathematics. GeoGebra is a visualisation tool that can be used for problem-oriented teaching and foster mathematical experiments and discoveries. GeoGebra’s inherent visualisation characteristics align well with the teaching of calculus, the mathematical domain of this study. The study (whose research methodology was underpinned by the interpretive paradigm) was undertaken with a broader goal of designing and implementing GeoGebra applets and instructional materials on various calculus topics. The study is located within the “Teaching and Learning Mathematics with GeoGebra (TLMG) project” – a project that involves mathematics teachers and lecturers in Zambia. The case in this study is the six mathematics lecturers who co-designed and used GeoGebra applets to teach derivatives and integrals to pre-service mathematics teachers in TEIs. The unit of analysis therefore is the six lecturers’ use of GeoGebra as a visualisation tool to teach calculus to enhance conceptual understanding, their perceptions and experiences of using GeoGebra and the enabling and constraining factors of using GeoGebra to teach and learn mathematics. The data for the study were video recordings of observations and interviews of lecturers. The data was analysed thematically and was guided and informed by an analytical framework adopted from the theory of constructivism – the umbrella theoretical framework of this study – and the models of Technological Pedagogical Content Knowledge (TPACK), and the Technology Acceptance Model (TAM). A detailed analysis of the lecturers’ interactions with the applets enabled me to gain insights into the participants’ experiences and perceptions of GeoGebra applets in the teaching and learning process. The findings of the study revealed that the visualisation characteristics of GeoGebra generally enhanced the conceptual understanding of calculus. It also revealed that adequate training, coupled with sufficient knowledge of the subject matter in calculus, were necessary for lecturers to use GeoGebra effectively, and that the lack of resources and expertise were major hindrances in the use of GeoGebra to teach mathematics in TEIs. It also revealed that there is a need to equip GeoGebra with other features that would make it more versatile, and suggested a teaching approach that would complement the use of conventional methods and GeoGebra to provide a link between abstract and concrete concepts of calculus. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
Integration of nanostructured metal sulfides into titanium (iv) oxide for high performance dye sensitized solar cell
- Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Authors: Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Date: 2020-01
- Subjects: Nanostructured materials , Sulfur compounds
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21523 , vital:48857
- Description: The work in this thesis describes synthesis, characterization and integration of nanostructured metal sulfides into titanium (IV) oxide for high performance dye sensitized solar cell. The synthesised single source precursors were evaluated using TGA, FTIR, , UV-Vis, PL,1H and 13CNMR, SEM, EDS, HRTEM, XRD, AFM, Raman, I-V, CV, Bode plot and EIS. TGA revealed the thermal degradation and quantified the mass percentage of metal sulphides as 33percent, 45percent and 27percent for CuS, PbS and SnS nanoparticles, respectively. FTIR analysis showed bands at 1580-1450 cm-1, and 1060-940 cm-1 tentatively assigned to C-N and C-S stretching frequencies correspondingly. The (M-S) stretching was observed at 577-406 cm-1 for the complexes using bis(N-di-isopropyl-N-octyldithiocarbamato) as primary ligands. IR spectra of bis(N-1,4-phenyl-N-(4-morpholinedithiocarbamato) as secondary ligands suggested the presence of (C-N) vibrations at 1508-1513 cm-1 for the complexes and 1507-1584 cm-1 for the ligands. The bands in the region of 973-1030 cm-1 were assigned to the complexes and 974- 983 cm-1 were attributed to the ligands, whereas vibration frequencies at 416-625 cm-1 were Nelson's Choice were included in these preliminary variety trials (PVTs) as checks. Twenty-five hybrids expressing high values for the Smith – Hazel selection index were identified across sites over years. Among those hybrids were two checks, namely Q16 (PAN5Q649R) and Q33 (Phb31MO7BR). The top five high – yielding hybrids selected based on the selection index were considered to be the most productive, stable and adaptable based on the GGE biplot and AMMI stability values. None of these single cross hybrids over yielded the best hybrid check (Q16) in the current study. A high potential environment, Centane, was the ideal environments for evaluating genotypes in the present study. The studies showed inbred lines L22, L23, L26, L28, L25, L29 and L31 to be low N stress tolerant at 0 kg N ha-1 based on the low N stress tolerance indices under glasshouse and the field conditions; they were also among the top ten grain-yielders under field conditions at 0 kg N ha-1. Also, in the NUE study, they were found to be among the top ten most N-efficient inbred lines under low N soils, under 30 kg N ha-1, and were among the top twenty-four inbred lines with high NUE values across the N levels in the study. Inbred lines L29 and L22 also produced testcross hybrids that were among the top twenty based on GY under 0 kg N ha-1. The testcross hybrids produced from these inbred lines were also among the top twenty-five with outstanding SCA effects for GY. These inbred lines were also parental lines of some of the top twenty- five best hybrids selected based on the Smith – Hazel selection index in the PVT study. Inbred lines L22, L23, L26, L28, L25, L29 and L31 can therefore further be evaluated and used as sources of N-tolerance genes in QPM breeding programs. tentatively assigned to M-S bond in the complexes. UV-Vis spectroscopy analysis for the complexes and from primary and secondary ligands are between within the range of 338 – 340 nm. PL studies of the primary ligands with metal complexes indicated emissions at 464 nm, 462 nm, 462 nm for Pb(II) and Sn(II), and Cu(II). The presence of secondary ligands was revealed by the absorption peaks at 455, 456 and 457 nm, exhibiting both the signals and chemical constituents of the respective ligands and their corresponding complexes. The electrochemistry in chapters 3 and 4 reveals that phase angle in the Bode plots changes with frequencies for Sn(II) complexes at 58, 57 and 8 respectively. Bode plots showed remarkable electronics of Cu(II) and Pb(II) complex interfaces. The CV curves exhibit two kinds of redox peaks indicating reduction at the negative potentials and oxidation at the positive potentials. The EIS, electrodes produced Rct for Pb(II), Cu(II) and Sn(II) electrodes in chapter 3. Moreover The EIS revealed that Sn(II) sensitizer displaced a stronger chemical capacitance and improved efficiency which could lead to better electron lifetime yield. The obtained CV exhibited anodic and cathodic peaks for Pb(II), connoting a reduction in Pb2+ and oxidation in Pb2-. Bode plot phase angle displayed Sn(II) and Pb(II) with maxima phase, indicating the presence of time constants of the electrode processes in Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes. From the results in chapter 4, the XRD patterns exhibited good crystalline nature of CuS as a result of sharp and strong diffraction peaks obtained. There are eight peaks of 2θ angle between 26° and 79° relating to orthorhombic structure of SnS. While PbS has a cubic structure with polycrystalline nature, PbS/HDA and PbS both correspond to their crystalline planes of (200), (111), (220), (311), (222), (400), (331), (420) and (422) affirming to PbS QDs structure. SnS/HDA and SnS photosensitizers displayed eleven peaks between the values of 27.02° to 66.05° for SnS/HDA and 26.03° to 66.04° for SnS, in confirming the orthorhombic structure. SEM analysis revealed hexagonal structure for CuS, while PbS and SnS exhibited mesoporous nanostructures with spherical nanoparticles. HRTEM images indicated spherical nano-particles with particle sizes in the range of 3.14 - 44.39 nm. The outcome of HRTEM analysis revealed crystallite sizes varying as 10.90 – 11.57 nm, 3.14 – 5.95 nm and 14.96 – 44.39 nm for the CuS, PbS and SnS, originated from the primary ligands. HRTEM images originating from the Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes indicated spherical nano-particles with particle sizes of 3.14 - 44.39 nm. Raman images in chapter 5 revealed the presence of Raman active modes of E2g 66 cm-1 and 304, cm-1 and E1g 627 cm-1 and 706 cm-1 for CuS, the active modes of TO 65 cm-1 and 2LO 626 cm-1 for PbS, active modes of B1g 69 cm-1 for SnS and 266 cm-1 for Ag. From the AFM results in chapter 5, CuS photosensitizer displayed a smooth surface and particle estimated to be 0.50 μm and height profile of 12percent. The PbS photosensitizer exhibited particle size of 1.82 μm and 0.654 μm for PbS/HDA, depicting a regular crystal growth rate. The size distribution of SnS nanoparticle at 357 nm connotes smooth surface and good compactness on the substrate. However, SnS/HDA at 122 nm displayed shape and size of non-symmetrical particles. AFM analysis in chapter 8 revealed good size roughness for CuS film. PbS exhibited particle size of 365 nm and size height of 18percent as the smoothest film, while PbS/HDA revealed 1.22 um size with 9percent size height. The evaluated particle sizes varied as 0.11- 1.18 um for SnS/HDA and 0.054 – 0.54 um for SnS films grown at 360 ℃ with size height of 16.8 and 8.4percent. The I-V efficiency obtained indicated that the CuS exhibited a much better efficiency in the QDSCs with higher Voc and the highest η being 2.85percent compared to CuS/HDA and Cu(II). High JSC of 11 mA/cm has been observed in the PbS/HDA QDSSCs, compared to the PbS and Pb(II) cells. The SnS/HDA exhibited a better performance compared to SnS and Sn(II) sensitizers due to the presence of HDA capping agent. , Thesis (MSc -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-01
- Authors: Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Date: 2020-01
- Subjects: Nanostructured materials , Sulfur compounds
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21523 , vital:48857
- Description: The work in this thesis describes synthesis, characterization and integration of nanostructured metal sulfides into titanium (IV) oxide for high performance dye sensitized solar cell. The synthesised single source precursors were evaluated using TGA, FTIR, , UV-Vis, PL,1H and 13CNMR, SEM, EDS, HRTEM, XRD, AFM, Raman, I-V, CV, Bode plot and EIS. TGA revealed the thermal degradation and quantified the mass percentage of metal sulphides as 33percent, 45percent and 27percent for CuS, PbS and SnS nanoparticles, respectively. FTIR analysis showed bands at 1580-1450 cm-1, and 1060-940 cm-1 tentatively assigned to C-N and C-S stretching frequencies correspondingly. The (M-S) stretching was observed at 577-406 cm-1 for the complexes using bis(N-di-isopropyl-N-octyldithiocarbamato) as primary ligands. IR spectra of bis(N-1,4-phenyl-N-(4-morpholinedithiocarbamato) as secondary ligands suggested the presence of (C-N) vibrations at 1508-1513 cm-1 for the complexes and 1507-1584 cm-1 for the ligands. The bands in the region of 973-1030 cm-1 were assigned to the complexes and 974- 983 cm-1 were attributed to the ligands, whereas vibration frequencies at 416-625 cm-1 were Nelson's Choice were included in these preliminary variety trials (PVTs) as checks. Twenty-five hybrids expressing high values for the Smith – Hazel selection index were identified across sites over years. Among those hybrids were two checks, namely Q16 (PAN5Q649R) and Q33 (Phb31MO7BR). The top five high – yielding hybrids selected based on the selection index were considered to be the most productive, stable and adaptable based on the GGE biplot and AMMI stability values. None of these single cross hybrids over yielded the best hybrid check (Q16) in the current study. A high potential environment, Centane, was the ideal environments for evaluating genotypes in the present study. The studies showed inbred lines L22, L23, L26, L28, L25, L29 and L31 to be low N stress tolerant at 0 kg N ha-1 based on the low N stress tolerance indices under glasshouse and the field conditions; they were also among the top ten grain-yielders under field conditions at 0 kg N ha-1. Also, in the NUE study, they were found to be among the top ten most N-efficient inbred lines under low N soils, under 30 kg N ha-1, and were among the top twenty-four inbred lines with high NUE values across the N levels in the study. Inbred lines L29 and L22 also produced testcross hybrids that were among the top twenty based on GY under 0 kg N ha-1. The testcross hybrids produced from these inbred lines were also among the top twenty-five with outstanding SCA effects for GY. These inbred lines were also parental lines of some of the top twenty- five best hybrids selected based on the Smith – Hazel selection index in the PVT study. Inbred lines L22, L23, L26, L28, L25, L29 and L31 can therefore further be evaluated and used as sources of N-tolerance genes in QPM breeding programs. tentatively assigned to M-S bond in the complexes. UV-Vis spectroscopy analysis for the complexes and from primary and secondary ligands are between within the range of 338 – 340 nm. PL studies of the primary ligands with metal complexes indicated emissions at 464 nm, 462 nm, 462 nm for Pb(II) and Sn(II), and Cu(II). The presence of secondary ligands was revealed by the absorption peaks at 455, 456 and 457 nm, exhibiting both the signals and chemical constituents of the respective ligands and their corresponding complexes. The electrochemistry in chapters 3 and 4 reveals that phase angle in the Bode plots changes with frequencies for Sn(II) complexes at 58, 57 and 8 respectively. Bode plots showed remarkable electronics of Cu(II) and Pb(II) complex interfaces. The CV curves exhibit two kinds of redox peaks indicating reduction at the negative potentials and oxidation at the positive potentials. The EIS, electrodes produced Rct for Pb(II), Cu(II) and Sn(II) electrodes in chapter 3. Moreover The EIS revealed that Sn(II) sensitizer displaced a stronger chemical capacitance and improved efficiency which could lead to better electron lifetime yield. The obtained CV exhibited anodic and cathodic peaks for Pb(II), connoting a reduction in Pb2+ and oxidation in Pb2-. Bode plot phase angle displayed Sn(II) and Pb(II) with maxima phase, indicating the presence of time constants of the electrode processes in Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes. From the results in chapter 4, the XRD patterns exhibited good crystalline nature of CuS as a result of sharp and strong diffraction peaks obtained. There are eight peaks of 2θ angle between 26° and 79° relating to orthorhombic structure of SnS. While PbS has a cubic structure with polycrystalline nature, PbS/HDA and PbS both correspond to their crystalline planes of (200), (111), (220), (311), (222), (400), (331), (420) and (422) affirming to PbS QDs structure. SnS/HDA and SnS photosensitizers displayed eleven peaks between the values of 27.02° to 66.05° for SnS/HDA and 26.03° to 66.04° for SnS, in confirming the orthorhombic structure. SEM analysis revealed hexagonal structure for CuS, while PbS and SnS exhibited mesoporous nanostructures with spherical nanoparticles. HRTEM images indicated spherical nano-particles with particle sizes in the range of 3.14 - 44.39 nm. The outcome of HRTEM analysis revealed crystallite sizes varying as 10.90 – 11.57 nm, 3.14 – 5.95 nm and 14.96 – 44.39 nm for the CuS, PbS and SnS, originated from the primary ligands. HRTEM images originating from the Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes indicated spherical nano-particles with particle sizes of 3.14 - 44.39 nm. Raman images in chapter 5 revealed the presence of Raman active modes of E2g 66 cm-1 and 304, cm-1 and E1g 627 cm-1 and 706 cm-1 for CuS, the active modes of TO 65 cm-1 and 2LO 626 cm-1 for PbS, active modes of B1g 69 cm-1 for SnS and 266 cm-1 for Ag. From the AFM results in chapter 5, CuS photosensitizer displayed a smooth surface and particle estimated to be 0.50 μm and height profile of 12percent. The PbS photosensitizer exhibited particle size of 1.82 μm and 0.654 μm for PbS/HDA, depicting a regular crystal growth rate. The size distribution of SnS nanoparticle at 357 nm connotes smooth surface and good compactness on the substrate. However, SnS/HDA at 122 nm displayed shape and size of non-symmetrical particles. AFM analysis in chapter 8 revealed good size roughness for CuS film. PbS exhibited particle size of 365 nm and size height of 18percent as the smoothest film, while PbS/HDA revealed 1.22 um size with 9percent size height. The evaluated particle sizes varied as 0.11- 1.18 um for SnS/HDA and 0.054 – 0.54 um for SnS films grown at 360 ℃ with size height of 16.8 and 8.4percent. The I-V efficiency obtained indicated that the CuS exhibited a much better efficiency in the QDSCs with higher Voc and the highest η being 2.85percent compared to CuS/HDA and Cu(II). High JSC of 11 mA/cm has been observed in the PbS/HDA QDSSCs, compared to the PbS and Pb(II) cells. The SnS/HDA exhibited a better performance compared to SnS and Sn(II) sensitizers due to the presence of HDA capping agent. , Thesis (MSc -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-01
Microalgal-bacterial flocs and extracellular polymeric substances for optimum function of integrated algal pond systems
- Authors: Jimoh, Taobat Adekilekun
- Date: 2021-10-29
- Subjects: Flocculation , Extracellular polymeric substances , Water Purification , Sewage Purification Anaerobic treatment , Integrated algae pond systems (IAPS) , Microalgal-bacterial flocs
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191214 , vital:45071 , 10.21504/10962/191214
- Description: Despite the dire state of sanitation infrastructures, water scarcity, and the dwindling reserve of natural resources due to ever-increasing population growth, implementation of a suitable technology that can provide a solution to all these issues continues to be ignored. The integrated algal pond system (IAPS) is a wastewater treatment technology that combines the processes of anaerobic digestion and photosynthetic oxygenation to achieve wastewater treatment and facilitate the recovery of treated water and resources in the form of biogas and microalgal-bacterial biomass. The natural process of bioflocculation through microalgal-bacterial mutualism and production of extracellular polymeric substances (EPS) in high rate algal oxidation ponds (HRAOPs) of an IAPS increases efficiency of wastewater treatment and potentially enhances harvestability and biomass recovery, which could contribute significantly to the successful establishment of a biorefinery. Using a 500 PE pilot-scale IAPS supplied domestic sewage coupled with laboratory experiments, this study investigated the importance and function of in situ EPS production and MaB-floc formation in HRAOP. A metagenomic study revealed the biological components of the biomass or mixed liquor suspended solids (MLSS) produced in HRAOP and showed that the suspended biomass is composed largely of eukaryotes that were dominated by the colonial microalgae Pseudopediastrum sp. and Desmodesmus sp., and a diverse range of prokaryotes including bacteria and cyanobacteria. Dominance, within the bacterial population, by a sulphur-oxidizing bacterium, Thiothrix which comprised up to 80% of the prokaryotes, coincided with a period of poor flocculation and was therefore rationalized to have contributed to bulking and poor biomass settleability. Otherwise, good flocs were formed in the MLSS with settleability up to 95% and, within 1 h. The formation of MaB-flocs appeared to be dependent on EPS concentration of the mixed liquor due to the observed positive correlation between soluble EPS (S-EPS), biomass concentration, and settleability. The contribution and role of MLSS components towards the formation and sustenance of MaB-flocs were further demonstrated in laboratory experiments using pure strains of microalgae, cyanobacteria, and bacteria. Results showed that pure cultures of dominant microalgae in MLSS, Pseudopediastrum sp. and Desmodesmus sp. achieved a rapid 92 and 75% settleability within 3 h. A self-flocculating filamentous cyanobacterium, Leptolyngbya strain ECCN 20BG was isolated, characterized, and shown to achieve 99% settleability within 5 min by forming large tightly aggregated flocs. In further experiments, this strain was found to improve the settleability of MLSS by an average of 20%. Bacterial strains identified as Bacillus strain ECCN 40b, Bacillus strain ECCN 41b, Planococcus strain ECCN 45b, and Exiguobacterium strain ECCN 46b were also observed to produce sticky EPS-like materials in pure cultures that could also contribute to the aggregation of cells in a mixed environment. Given these results, various factors and/or mechanisms that might enhance microbial aggregation and biomass recovery from HRAOP MLSS were identified in this study and include; (1) dominance by larger colonial microalgae prevents disintegration of MaB-flocs and enhances recovery of biomass from MLSS by gravity sedimentation, (2) presence of filamentous cyanobacteria species that can self-flocculate to form an interwoven network of filaments may play an important role in the structural stability and settleability of MaB-flocs in MLSS, and (3) production of EPS to form the matrix or scaffold whereon all microbial components aggregate to develop a microenvironment. Indeed, all forms of EPS, except for that produced by Bacillus strain ECCN 41b, showed bioflocculating property and were able to serve as flocculants for the recovery of Chlorella, an alga known for its poor settleability. A combination of biochemical analyses and FTIR spectroscopy revealed the importance of carbohydrate enrichment of these biopolymers. Carbohydrate concentration in all forms of EPS was between 12 and 41% suggesting that production of these compounds by microbes within the MLSS contributed to MaB-floc formation. EPS extracted from bulk MLSS and EPS produced by Bacillus strains possessed some surface-active properties that were comparable to Triton X-100, indicating potential application in bioremediation and recovery of oil from contaminated soil and water. In particular, EPS generated from Bacillus strain ECCN 41b displayed relatively distinct properties including the quantity produced (> 500 mg/L), increased viscosity, inability to flocculate microalgal cells, a rhamnolipid content of 32%, and a higher surface-activity. Based on these results, Bacillus strain ECCN 41b was rationalized to produce anionic EPS with potential application in metal or oil recovery. In addition to EPS production, the bacteria Planococcus strain ECCN 45b and Exiguobacterium strain ECCN 46b appeared pigmented. Based on partial characterization using UV/Vis spectrophotometry, thin-layer chromatography, FTIR, and NMR, the pigments produced by these two strains appeared to be identical and were tentatively identified as ketocarotenoids. This study successfully demonstrated the importance of EPS production and formation of MaB-flocs in the MLSS from HRAOP of an IAPS treating domestic sewage. It is evident that increased settleability of the biomass does contribute to the reported efficiency of wastewater treatment by IAPS and would reduce both total suspended solids (TSS) and chemical oxygen demand (COD). In addition, demonstration that this biomass contains products of value such as carotenoids and EPS with potential for commercial use strengthens the idea of using IAPS as a platform technology for innovation of the wastewater treatment process to a biorefinery. , Thesis (PhD) -- Faculty of Science, Institute for Environmental Biotechnology, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Jimoh, Taobat Adekilekun
- Date: 2021-10-29
- Subjects: Flocculation , Extracellular polymeric substances , Water Purification , Sewage Purification Anaerobic treatment , Integrated algae pond systems (IAPS) , Microalgal-bacterial flocs
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191214 , vital:45071 , 10.21504/10962/191214
- Description: Despite the dire state of sanitation infrastructures, water scarcity, and the dwindling reserve of natural resources due to ever-increasing population growth, implementation of a suitable technology that can provide a solution to all these issues continues to be ignored. The integrated algal pond system (IAPS) is a wastewater treatment technology that combines the processes of anaerobic digestion and photosynthetic oxygenation to achieve wastewater treatment and facilitate the recovery of treated water and resources in the form of biogas and microalgal-bacterial biomass. The natural process of bioflocculation through microalgal-bacterial mutualism and production of extracellular polymeric substances (EPS) in high rate algal oxidation ponds (HRAOPs) of an IAPS increases efficiency of wastewater treatment and potentially enhances harvestability and biomass recovery, which could contribute significantly to the successful establishment of a biorefinery. Using a 500 PE pilot-scale IAPS supplied domestic sewage coupled with laboratory experiments, this study investigated the importance and function of in situ EPS production and MaB-floc formation in HRAOP. A metagenomic study revealed the biological components of the biomass or mixed liquor suspended solids (MLSS) produced in HRAOP and showed that the suspended biomass is composed largely of eukaryotes that were dominated by the colonial microalgae Pseudopediastrum sp. and Desmodesmus sp., and a diverse range of prokaryotes including bacteria and cyanobacteria. Dominance, within the bacterial population, by a sulphur-oxidizing bacterium, Thiothrix which comprised up to 80% of the prokaryotes, coincided with a period of poor flocculation and was therefore rationalized to have contributed to bulking and poor biomass settleability. Otherwise, good flocs were formed in the MLSS with settleability up to 95% and, within 1 h. The formation of MaB-flocs appeared to be dependent on EPS concentration of the mixed liquor due to the observed positive correlation between soluble EPS (S-EPS), biomass concentration, and settleability. The contribution and role of MLSS components towards the formation and sustenance of MaB-flocs were further demonstrated in laboratory experiments using pure strains of microalgae, cyanobacteria, and bacteria. Results showed that pure cultures of dominant microalgae in MLSS, Pseudopediastrum sp. and Desmodesmus sp. achieved a rapid 92 and 75% settleability within 3 h. A self-flocculating filamentous cyanobacterium, Leptolyngbya strain ECCN 20BG was isolated, characterized, and shown to achieve 99% settleability within 5 min by forming large tightly aggregated flocs. In further experiments, this strain was found to improve the settleability of MLSS by an average of 20%. Bacterial strains identified as Bacillus strain ECCN 40b, Bacillus strain ECCN 41b, Planococcus strain ECCN 45b, and Exiguobacterium strain ECCN 46b were also observed to produce sticky EPS-like materials in pure cultures that could also contribute to the aggregation of cells in a mixed environment. Given these results, various factors and/or mechanisms that might enhance microbial aggregation and biomass recovery from HRAOP MLSS were identified in this study and include; (1) dominance by larger colonial microalgae prevents disintegration of MaB-flocs and enhances recovery of biomass from MLSS by gravity sedimentation, (2) presence of filamentous cyanobacteria species that can self-flocculate to form an interwoven network of filaments may play an important role in the structural stability and settleability of MaB-flocs in MLSS, and (3) production of EPS to form the matrix or scaffold whereon all microbial components aggregate to develop a microenvironment. Indeed, all forms of EPS, except for that produced by Bacillus strain ECCN 41b, showed bioflocculating property and were able to serve as flocculants for the recovery of Chlorella, an alga known for its poor settleability. A combination of biochemical analyses and FTIR spectroscopy revealed the importance of carbohydrate enrichment of these biopolymers. Carbohydrate concentration in all forms of EPS was between 12 and 41% suggesting that production of these compounds by microbes within the MLSS contributed to MaB-floc formation. EPS extracted from bulk MLSS and EPS produced by Bacillus strains possessed some surface-active properties that were comparable to Triton X-100, indicating potential application in bioremediation and recovery of oil from contaminated soil and water. In particular, EPS generated from Bacillus strain ECCN 41b displayed relatively distinct properties including the quantity produced (> 500 mg/L), increased viscosity, inability to flocculate microalgal cells, a rhamnolipid content of 32%, and a higher surface-activity. Based on these results, Bacillus strain ECCN 41b was rationalized to produce anionic EPS with potential application in metal or oil recovery. In addition to EPS production, the bacteria Planococcus strain ECCN 45b and Exiguobacterium strain ECCN 46b appeared pigmented. Based on partial characterization using UV/Vis spectrophotometry, thin-layer chromatography, FTIR, and NMR, the pigments produced by these two strains appeared to be identical and were tentatively identified as ketocarotenoids. This study successfully demonstrated the importance of EPS production and formation of MaB-flocs in the MLSS from HRAOP of an IAPS treating domestic sewage. It is evident that increased settleability of the biomass does contribute to the reported efficiency of wastewater treatment by IAPS and would reduce both total suspended solids (TSS) and chemical oxygen demand (COD). In addition, demonstration that this biomass contains products of value such as carotenoids and EPS with potential for commercial use strengthens the idea of using IAPS as a platform technology for innovation of the wastewater treatment process to a biorefinery. , Thesis (PhD) -- Faculty of Science, Institute for Environmental Biotechnology, 2021
- Full Text:
- Date Issued: 2021-10-29
Main thesis title
- Authors: Tsamago, Hodi, Elias
- Date: 2022-12
- Subjects: Technology integration , SOLEs pedagogy , Metacognitive
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/60549 , vital:65833
- Description: The study was carried out to investigate the effect of the use of technology in self-organised learning environments (SOLEs) (in Physical Sciences classrooms) on learners’ metacognitive skills. The study contributes by identifying a technology-enhanced pedagogy that can effectively equip learners with metacognitive skills, which many studies have reported as having an effect on Physical Sciences learners’ conceptual understanding. The study followed an experimental (control group quasi-experimental) methods design, in which both qualitative and quantitative data were collected and analysed. A multistep stratified sampling method (which caters for both quantitative and qualitative facets) was employed to choose four schools (two rural and two urban) to participate in the study. These schools were randomly chosen from the population of all schools offering Physical Sciences in Grade 11 in the Capricorn District of Limpopo Province, South Africa were assigned to urban experimental group and rural experimental group (UEG and REG) and urban control group and rural control group (UCG and RCG) using geographical demographics. The participants were selected using both simple random sampling (for quantitative methods) and purposive sampling (for qualitative methods). The experimental groups were taught by the researcher using self-organised learning environments (SOLEs) pedagogy, while control groups were taught (also by the researcher of the study) using a traditional chalk-and-talk approach. A Physical Sciences concepts pre-/post-test and the Metacognitive Self-Assessment Scale (MSAS) questionnaire were used to glean the quantitative data, while focus group interviews (FGIs) were used to obtain the qualitative data. The analysis of the quantitative data employed both descriptive (mean, standard deviation and graphs) and inferential (both parametric t-test and non-parametric Kruskal-Wallis and Wilcoxon signed-rank tests) statistics computed using the SPSS package version 22, while qualitative data were analysed thematically using coding techniques (applied on a sentence-by-sentence basis) after the transcription of the recorded FGIs. The study found that SOLEs pedagogy improves learners’ metacognitive skills, leading to better Physical Sciences conceptual understanding. In addition, the results indicate that all v aspects of metacognitive skills improved in experimental groups; however, certain aspects exhibited outstanding improvement such as “Respect shown to myself”; “Respect shown to others”; “Respect shown for empathy towards others” and “Respect shown towards problem solving”. Furthermore, the results of the FGIs revealed that a plausible explanation for the ability of SOLEs pedagogy to enhance metacognitive skills lies in its effortlessness to enable learners to link their classroom experiences to real-life experiences; simulate practical work; adapt to collaborative learning; use multiple channels for receiving information; and reducing learners’ reliance on the teacher. Hence, this study recommends the implementation of SOLEs pedagogy in the Physical Sciences classroom to improve learners’ metacognitive skills and conceptual understanding. However, the study had limitations, some of which included the sample size (which has an effect on the degree of generalisability of the research findings) and the period during which SOLEs pedagogy was implemented which might not have been long enough to exhaust its effect on metacognitive skills. Accordingly, further studies employing a longitudinal study design with a sample size bigger than 350 participants would be useful in understanding the effects of SOLEs pedagogy on metacognitive skills and improving the generalisability of research findings , Thesis (PhD) -- Faculty of education, 2022
- Full Text:
- Date Issued: 2022-12
- Authors: Tsamago, Hodi, Elias
- Date: 2022-12
- Subjects: Technology integration , SOLEs pedagogy , Metacognitive
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/60549 , vital:65833
- Description: The study was carried out to investigate the effect of the use of technology in self-organised learning environments (SOLEs) (in Physical Sciences classrooms) on learners’ metacognitive skills. The study contributes by identifying a technology-enhanced pedagogy that can effectively equip learners with metacognitive skills, which many studies have reported as having an effect on Physical Sciences learners’ conceptual understanding. The study followed an experimental (control group quasi-experimental) methods design, in which both qualitative and quantitative data were collected and analysed. A multistep stratified sampling method (which caters for both quantitative and qualitative facets) was employed to choose four schools (two rural and two urban) to participate in the study. These schools were randomly chosen from the population of all schools offering Physical Sciences in Grade 11 in the Capricorn District of Limpopo Province, South Africa were assigned to urban experimental group and rural experimental group (UEG and REG) and urban control group and rural control group (UCG and RCG) using geographical demographics. The participants were selected using both simple random sampling (for quantitative methods) and purposive sampling (for qualitative methods). The experimental groups were taught by the researcher using self-organised learning environments (SOLEs) pedagogy, while control groups were taught (also by the researcher of the study) using a traditional chalk-and-talk approach. A Physical Sciences concepts pre-/post-test and the Metacognitive Self-Assessment Scale (MSAS) questionnaire were used to glean the quantitative data, while focus group interviews (FGIs) were used to obtain the qualitative data. The analysis of the quantitative data employed both descriptive (mean, standard deviation and graphs) and inferential (both parametric t-test and non-parametric Kruskal-Wallis and Wilcoxon signed-rank tests) statistics computed using the SPSS package version 22, while qualitative data were analysed thematically using coding techniques (applied on a sentence-by-sentence basis) after the transcription of the recorded FGIs. The study found that SOLEs pedagogy improves learners’ metacognitive skills, leading to better Physical Sciences conceptual understanding. In addition, the results indicate that all v aspects of metacognitive skills improved in experimental groups; however, certain aspects exhibited outstanding improvement such as “Respect shown to myself”; “Respect shown to others”; “Respect shown for empathy towards others” and “Respect shown towards problem solving”. Furthermore, the results of the FGIs revealed that a plausible explanation for the ability of SOLEs pedagogy to enhance metacognitive skills lies in its effortlessness to enable learners to link their classroom experiences to real-life experiences; simulate practical work; adapt to collaborative learning; use multiple channels for receiving information; and reducing learners’ reliance on the teacher. Hence, this study recommends the implementation of SOLEs pedagogy in the Physical Sciences classroom to improve learners’ metacognitive skills and conceptual understanding. However, the study had limitations, some of which included the sample size (which has an effect on the degree of generalisability of the research findings) and the period during which SOLEs pedagogy was implemented which might not have been long enough to exhaust its effect on metacognitive skills. Accordingly, further studies employing a longitudinal study design with a sample size bigger than 350 participants would be useful in understanding the effects of SOLEs pedagogy on metacognitive skills and improving the generalisability of research findings , Thesis (PhD) -- Faculty of education, 2022
- Full Text:
- Date Issued: 2022-12
Indigenous knowledge systems and gender relations interface and its implications for food security: the case of Khambashe rural households in the Amathole District, South Africa
- Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Authors: Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Date: 2015-01
- Subjects: Food security -- South Africa -- Eastern Cape , Indigenous peoples -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26581 , vital:65660
- Description: The aim of this study was to find out about how the intersection of indigenous knowledge systems and gender relations affects food security in the rural households of the Khambashe village in the Eastern Cape. The focus is on food security-related indigenous knowledge utilized by women rather than the general indigenous knowledge of the people in the Eastern Cape. Ample literature exists on food security and gender, food security and indigenous knowledge systems and the role of gender dynamics in the application of indigenous knowledge systems. However, there is dearth of literature on studies on the role of the indigenous knowledge systems-gender relations interface in food security. Hence this study was directed at investigating the indigenous knowledge systems-gender dynamics interplay and its implications for food security and sustainable development with specific reference to the rural households of Khambashe village of the Eastern Cape Province. Furthermore, the study seeks to determine factors accounting for the attrition of women’s indigenous knowledge in food production systems of the Khambashe rural households. The main position advanced in this thesis is that domination coupled with marginalisation of women and indigenous knowledge systems by hegemonic Western power/knowledge and traditional African practices account for challenges faced by rural households with regard to food security and sustainable livelihoods. Put differently, the core argument of this study is that the intersection between gender and indigenous knowledge systems has two opposing possibilities for food security. On the one hand, through the various roles of women in the application of indigenous knowledge systems in rural areas, the indigenous knowledge and gender relations interplay can operate to enhance the likelihood of achieving sustainable rural livelihoods and hence food security. On the other hand, gender oppression, subjugation, exclusion and marginalization through various practices such as the utilization of discriminatory patriarchal cultural values and norms can inhibit the application of the rich folk knowledge reservoir of ideas held by women in food production processes. Key illustrative examples of the constraints imposed by cultural traditions that pose problems for the realization of sustainable rural livelihoods are cultural practices which prohibit women to inter alia own and inherit land. These cultural practices also deprive women the liberty to make their own decisions without the consultation of men despite being sole providers of their own households. In other words, lack of access to assets and other resources owing to the marginalization of local knowledge by the dominant Western-based scientific knowledge systems and culturally-derived gender discriminatory practices make the role of women in the process of utilizing indigenous knowledge systems for the purposes of food security difficult. The theoretical framework of this study is drawn from the post-development discourse derived from Foucault’s archaeology of power and knowledge, ecofeminism and African feminism. Such a framework has a utility to reinvigorate marginalised indigenous knowledge and thereby help women reclaim their leadership in processes of ensuring food security. In a situation where indigenous knowledge systems have been excluded and subjugated by the dominant Western knowledge systems, an extended post-development discourse of this nature is transformative. While Foucault’s theory will provide key insights around power/knowledge dynamics and issues, ecofeminism and African feminism will extend these insights in the exploration of the patterns of power in both the knowledge and gender relations domains. In fact interactions in food production processes are embedded in systematized knowledge and traditional gender relations. Hence, in order to ensure a deep-going analysis of these phenomena, Foucault’s framework on power/knowledge is augmented by the ideas of ecofeminism and African feminism owing to the fact that systems of domination whether in the knowledge arena or gender relations domain are responsible for the challenges relating to food secure households and sustainable rural livelihoods. The rationale for this approach is that subjugation and marginalization of indigenous knowledge systems by Western hegemonic power/knowledge coupled with exclusionary and discriminatory practices of patriarchal cultural values is seen as inhibiting the proper application of indigenous knowledge in food production processes. The extended post-development discourse adopted for this study takes into consideration the fact that oppression and discrimination the world over has taken the Foucauldian power/knowledge dimension in the sense that women in rural African settings are not only prevented by Western science from the application of indigenous knowledge for the development of sustainable livelihoods but that their own cultural traditions are also a hindrance towards them owning land and property, making their own decisions without recourse to men and exercising their own authority. A mixed method approach combining qualitative and quantitative research design was utilized in order to gain a full grasp of nuances of the interface between indigenous knowledge and gender dynamics in food production processes in Khambashe. This methodological triangulation was used for purposes of enhancing the capturing of comprehensive data and a holistic understanding of food security issues in the area. Further, owing to the fact that survey questionnaires as research instruments would have not given a voice to women as key research participants and that the deployment of in-depth interviews alone as research tools would have compromised the generalizability of the findings of the study, each of the two research methods were to confirm, clarify, complement, enhance and elaborate the research results of the other. In other words, in order to counterbalance the limitation of questionnaires with regard to artificiality and not affording a voice to research participants in-depth interviews were conducted. The lack of generalizability of the latter was compensated by the high degree of representativity afforded by the use of the former (that is, questionnaires). As already indicated above, the study setting for the empirical data was the Khambashe village in the Eastern Cape. Information gathered included the more positive effects of the IK-gender relations interplay on food security covered in Chapter 7. This chapter described and analysed the various roles women play inter alia animal husbandry, crop production, creation and utilization of indigenous technology in food production processes and in post-harvesting practices. In contrast, chapter 8 investigated and discusses the various constrains which account for the hindrance in the operationalization of IK in food production processes by women. Chief among the identified constrains in Khambashe are the marginalization of local knowledge by hegemonic Western science and the discriminatory traditional practices. The research results of this study show that despite the key role of women in the application of local knowledge, practices and technologies in food production processes, the penetration, colonization and domination of the African socio-economic and cultural sphere by the West has resulted in the deterioration in the use of indigenous knowledge. Imperialistic Western knowledge masquerading as modern science and technology manifested in inter alia chemical fertilizers and modified food is a constraint to the utility of women’s indigenous knowledge and practices that ensures both food security and sustainable development. In view of the fact that failure to utilize readily available indigenous knowledge, practices and technologies owing to the marginalisation of local epistemes by Western science and the discriminatory African traditional practices and gender relations has led to further impoverishment of rural communities, there is a need to both empower women and to revitalize their indigenous knowledge for purposes of food security and sustainable development in rural areas such as Khambashe. , Thesis (PhD) -- Faculty of Social Sciences & Humanities, 2015
- Full Text:
- Date Issued: 2015-01
- Authors: Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Date: 2015-01
- Subjects: Food security -- South Africa -- Eastern Cape , Indigenous peoples -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26581 , vital:65660
- Description: The aim of this study was to find out about how the intersection of indigenous knowledge systems and gender relations affects food security in the rural households of the Khambashe village in the Eastern Cape. The focus is on food security-related indigenous knowledge utilized by women rather than the general indigenous knowledge of the people in the Eastern Cape. Ample literature exists on food security and gender, food security and indigenous knowledge systems and the role of gender dynamics in the application of indigenous knowledge systems. However, there is dearth of literature on studies on the role of the indigenous knowledge systems-gender relations interface in food security. Hence this study was directed at investigating the indigenous knowledge systems-gender dynamics interplay and its implications for food security and sustainable development with specific reference to the rural households of Khambashe village of the Eastern Cape Province. Furthermore, the study seeks to determine factors accounting for the attrition of women’s indigenous knowledge in food production systems of the Khambashe rural households. The main position advanced in this thesis is that domination coupled with marginalisation of women and indigenous knowledge systems by hegemonic Western power/knowledge and traditional African practices account for challenges faced by rural households with regard to food security and sustainable livelihoods. Put differently, the core argument of this study is that the intersection between gender and indigenous knowledge systems has two opposing possibilities for food security. On the one hand, through the various roles of women in the application of indigenous knowledge systems in rural areas, the indigenous knowledge and gender relations interplay can operate to enhance the likelihood of achieving sustainable rural livelihoods and hence food security. On the other hand, gender oppression, subjugation, exclusion and marginalization through various practices such as the utilization of discriminatory patriarchal cultural values and norms can inhibit the application of the rich folk knowledge reservoir of ideas held by women in food production processes. Key illustrative examples of the constraints imposed by cultural traditions that pose problems for the realization of sustainable rural livelihoods are cultural practices which prohibit women to inter alia own and inherit land. These cultural practices also deprive women the liberty to make their own decisions without the consultation of men despite being sole providers of their own households. In other words, lack of access to assets and other resources owing to the marginalization of local knowledge by the dominant Western-based scientific knowledge systems and culturally-derived gender discriminatory practices make the role of women in the process of utilizing indigenous knowledge systems for the purposes of food security difficult. The theoretical framework of this study is drawn from the post-development discourse derived from Foucault’s archaeology of power and knowledge, ecofeminism and African feminism. Such a framework has a utility to reinvigorate marginalised indigenous knowledge and thereby help women reclaim their leadership in processes of ensuring food security. In a situation where indigenous knowledge systems have been excluded and subjugated by the dominant Western knowledge systems, an extended post-development discourse of this nature is transformative. While Foucault’s theory will provide key insights around power/knowledge dynamics and issues, ecofeminism and African feminism will extend these insights in the exploration of the patterns of power in both the knowledge and gender relations domains. In fact interactions in food production processes are embedded in systematized knowledge and traditional gender relations. Hence, in order to ensure a deep-going analysis of these phenomena, Foucault’s framework on power/knowledge is augmented by the ideas of ecofeminism and African feminism owing to the fact that systems of domination whether in the knowledge arena or gender relations domain are responsible for the challenges relating to food secure households and sustainable rural livelihoods. The rationale for this approach is that subjugation and marginalization of indigenous knowledge systems by Western hegemonic power/knowledge coupled with exclusionary and discriminatory practices of patriarchal cultural values is seen as inhibiting the proper application of indigenous knowledge in food production processes. The extended post-development discourse adopted for this study takes into consideration the fact that oppression and discrimination the world over has taken the Foucauldian power/knowledge dimension in the sense that women in rural African settings are not only prevented by Western science from the application of indigenous knowledge for the development of sustainable livelihoods but that their own cultural traditions are also a hindrance towards them owning land and property, making their own decisions without recourse to men and exercising their own authority. A mixed method approach combining qualitative and quantitative research design was utilized in order to gain a full grasp of nuances of the interface between indigenous knowledge and gender dynamics in food production processes in Khambashe. This methodological triangulation was used for purposes of enhancing the capturing of comprehensive data and a holistic understanding of food security issues in the area. Further, owing to the fact that survey questionnaires as research instruments would have not given a voice to women as key research participants and that the deployment of in-depth interviews alone as research tools would have compromised the generalizability of the findings of the study, each of the two research methods were to confirm, clarify, complement, enhance and elaborate the research results of the other. In other words, in order to counterbalance the limitation of questionnaires with regard to artificiality and not affording a voice to research participants in-depth interviews were conducted. The lack of generalizability of the latter was compensated by the high degree of representativity afforded by the use of the former (that is, questionnaires). As already indicated above, the study setting for the empirical data was the Khambashe village in the Eastern Cape. Information gathered included the more positive effects of the IK-gender relations interplay on food security covered in Chapter 7. This chapter described and analysed the various roles women play inter alia animal husbandry, crop production, creation and utilization of indigenous technology in food production processes and in post-harvesting practices. In contrast, chapter 8 investigated and discusses the various constrains which account for the hindrance in the operationalization of IK in food production processes by women. Chief among the identified constrains in Khambashe are the marginalization of local knowledge by hegemonic Western science and the discriminatory traditional practices. The research results of this study show that despite the key role of women in the application of local knowledge, practices and technologies in food production processes, the penetration, colonization and domination of the African socio-economic and cultural sphere by the West has resulted in the deterioration in the use of indigenous knowledge. Imperialistic Western knowledge masquerading as modern science and technology manifested in inter alia chemical fertilizers and modified food is a constraint to the utility of women’s indigenous knowledge and practices that ensures both food security and sustainable development. In view of the fact that failure to utilize readily available indigenous knowledge, practices and technologies owing to the marginalisation of local epistemes by Western science and the discriminatory African traditional practices and gender relations has led to further impoverishment of rural communities, there is a need to both empower women and to revitalize their indigenous knowledge for purposes of food security and sustainable development in rural areas such as Khambashe. , Thesis (PhD) -- Faculty of Social Sciences & Humanities, 2015
- Full Text:
- Date Issued: 2015-01
Characterization of bioflocculants produced by consortia of three marine bacteria belonging to the genera bacillus and cobetia previously isolated from the bottom sediment of Algoa Bay in the Eastern Cape Province of South Africa
- Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Authors: Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Date: 2013
- Subjects: Water -- Purification -- Flocculation , Water quality management , Flocculation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24454 , vital:62804
- Description: The bioflocculant-producing potentials of three marine bacteria isolated from the sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed. Analysis of the partial nucleotide sequence of the 16S rDNA of the bacteria revealed 99 percent, 99 percent, and 98 percent similarity to Cobetia sp. L222, Bacillus sp. A-5A, and Bacillus sp. HXG-C1 respectively and the sequence was deposited in GenBank as Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert (accession number JF799092, JF799093, and HQ537128 respectively). Cultivation condition studies for Cobetia sp. OAUIFE revealed that bioflocculant production was optimal with an inoculum size of 2 percent (v/v), initial pH of 6.0, Mn2+ as the metal ion, and glucose as the carbon source. Metal ions, including Na+, K+, Li+, Ca2+and Mg2+ stimulated bioflocculant production resulting in flocculating activity of above 90 percent. This crude bioflocculant is thermally stable, with about 78 percent of its flocculating activity remaining after heating at 100 oC for 25 min. Analysis of the purified bioflocculant revealed it to be an acidic extracellular polysaccharide. FTIR analysis revealed the presence of methoxyl, hydroxyl, and carboxyl - groups in the compound bioflocculant and SEM micrograph of the bioflocculant revealed a crystal-linear structure. On the other hand, bioflocculant production by Bacillus sp. MAYA was optimal when glucose (95.6 percent flocculating activity) and ammonium nitrate (83.3 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 2 percent (v/v); initial pH 6; and Ca2+ as coagulant aid. Chemical analysis of the purified bioflocculant shows that it is composed of uronic acid, neutral sugar and protein. FTIR analysis also revealed the presence of methoxyl, hydroxyl, carboxyl and amino- groups in this bioflocculant. The bioflocculant is thermostable with about 65.6 percent residual flocculating activity retained after heating the bioflocculant at 100 oC for 25 min. However bioflocculant production by Bacillus sp. Gilbert was optimal when sodium carbonate (95.2 percent flocculating activity) and potassium nitrate (76.6 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 3 percent (v/v); initial pH 9; and Al3+ as cation. The crude bioflocculant retained 44.2 percent residual flocculating activity after heating at 100 oC for 15 min. FTIR analysis reveals the presence of hydroxyl, carboxyl and methylene - groups in the compound bioflocculant. SEM micrograph of the bioflocculant revealed an amorphous compound. The consortia of these bacteria strains also produced bioflocculants with high flocculating activities which were highly efficient in removing turbidity and chemical oxygen demand (COD) from brewery wastewater, diary wastewater and river water. The bioflocculants from the consortia seemed better than traditional flocculants such as alum . The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE and Bacillus sp. MAYA showed that this extracellular bioflocculant, composed of 66percent uronic acid and 31percent protein and an optimum flocculation (90 percent) of kaolin suspension, when the dosage concentration was 0.8 mg/ml, under weak alkaline pH of 8, and Ca2+ as a coagulant aid. The bioflocculant is thermally stable, with a high residual flocculating activity of 86.7 percent, 89.3 percent and 87.0 percent after heating at 50 oC, 80 oC and 100 oC for 25 min respectively. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl functional groups. Scanning electron microscopy (SEM) image revealed a crystal-linear spongy-like bioflocculant structure and EDX analysis of the purified bioflocculant showed that the elemental composition in mass proportion of C,N,O,S and P was 6.67:6.23:37.55:0.38:4.42 (percent w/w). However, the characteristics of the bioflocculant produced by the consortium of Cobetia sp OAUIFE and Bacillus sp. Gilbert showed an optimum flocculation (90 percent) of kaolin suspension when the dosage concentration was 0.2 mg/ml, under neutral pH of 7, and Ca2+ as a coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl and carbonyl functional groups. Scanning electron microscopy (SEM) image revealed an amorphous morphology. On the other hand the bioflocculant produced by the consortium of Bacillus sp. MAYA and Bacillus sp. Gilbert showed similar characteristic with the bioflocculant from the consortium of Cobetia sp. OAUIFE and Bacillus sp. Gilbert except for Al3+ being the preferred coagulant aid. The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert showed an optimum flocculation (87 percent) of kaolin suspension when the dosage concentration was 1.0 mg/ml. Under strong alkaline pH of 12, flocculating activity reached (95 percent) when Al3+ was the coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl and phosphoryl functional groups. Scanning electron microscopy (SEM) image revealed a flaky amorphous morphological structure. Due to the excellent COD and turbidity removal efficiencies of the bioflocculants produced by the consortia, these make those attractive candidates for use in water and wastewater treatment. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013
- Authors: Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Date: 2013
- Subjects: Water -- Purification -- Flocculation , Water quality management , Flocculation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24454 , vital:62804
- Description: The bioflocculant-producing potentials of three marine bacteria isolated from the sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed. Analysis of the partial nucleotide sequence of the 16S rDNA of the bacteria revealed 99 percent, 99 percent, and 98 percent similarity to Cobetia sp. L222, Bacillus sp. A-5A, and Bacillus sp. HXG-C1 respectively and the sequence was deposited in GenBank as Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert (accession number JF799092, JF799093, and HQ537128 respectively). Cultivation condition studies for Cobetia sp. OAUIFE revealed that bioflocculant production was optimal with an inoculum size of 2 percent (v/v), initial pH of 6.0, Mn2+ as the metal ion, and glucose as the carbon source. Metal ions, including Na+, K+, Li+, Ca2+and Mg2+ stimulated bioflocculant production resulting in flocculating activity of above 90 percent. This crude bioflocculant is thermally stable, with about 78 percent of its flocculating activity remaining after heating at 100 oC for 25 min. Analysis of the purified bioflocculant revealed it to be an acidic extracellular polysaccharide. FTIR analysis revealed the presence of methoxyl, hydroxyl, and carboxyl - groups in the compound bioflocculant and SEM micrograph of the bioflocculant revealed a crystal-linear structure. On the other hand, bioflocculant production by Bacillus sp. MAYA was optimal when glucose (95.6 percent flocculating activity) and ammonium nitrate (83.3 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 2 percent (v/v); initial pH 6; and Ca2+ as coagulant aid. Chemical analysis of the purified bioflocculant shows that it is composed of uronic acid, neutral sugar and protein. FTIR analysis also revealed the presence of methoxyl, hydroxyl, carboxyl and amino- groups in this bioflocculant. The bioflocculant is thermostable with about 65.6 percent residual flocculating activity retained after heating the bioflocculant at 100 oC for 25 min. However bioflocculant production by Bacillus sp. Gilbert was optimal when sodium carbonate (95.2 percent flocculating activity) and potassium nitrate (76.6 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 3 percent (v/v); initial pH 9; and Al3+ as cation. The crude bioflocculant retained 44.2 percent residual flocculating activity after heating at 100 oC for 15 min. FTIR analysis reveals the presence of hydroxyl, carboxyl and methylene - groups in the compound bioflocculant. SEM micrograph of the bioflocculant revealed an amorphous compound. The consortia of these bacteria strains also produced bioflocculants with high flocculating activities which were highly efficient in removing turbidity and chemical oxygen demand (COD) from brewery wastewater, diary wastewater and river water. The bioflocculants from the consortia seemed better than traditional flocculants such as alum . The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE and Bacillus sp. MAYA showed that this extracellular bioflocculant, composed of 66percent uronic acid and 31percent protein and an optimum flocculation (90 percent) of kaolin suspension, when the dosage concentration was 0.8 mg/ml, under weak alkaline pH of 8, and Ca2+ as a coagulant aid. The bioflocculant is thermally stable, with a high residual flocculating activity of 86.7 percent, 89.3 percent and 87.0 percent after heating at 50 oC, 80 oC and 100 oC for 25 min respectively. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl functional groups. Scanning electron microscopy (SEM) image revealed a crystal-linear spongy-like bioflocculant structure and EDX analysis of the purified bioflocculant showed that the elemental composition in mass proportion of C,N,O,S and P was 6.67:6.23:37.55:0.38:4.42 (percent w/w). However, the characteristics of the bioflocculant produced by the consortium of Cobetia sp OAUIFE and Bacillus sp. Gilbert showed an optimum flocculation (90 percent) of kaolin suspension when the dosage concentration was 0.2 mg/ml, under neutral pH of 7, and Ca2+ as a coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl and carbonyl functional groups. Scanning electron microscopy (SEM) image revealed an amorphous morphology. On the other hand the bioflocculant produced by the consortium of Bacillus sp. MAYA and Bacillus sp. Gilbert showed similar characteristic with the bioflocculant from the consortium of Cobetia sp. OAUIFE and Bacillus sp. Gilbert except for Al3+ being the preferred coagulant aid. The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert showed an optimum flocculation (87 percent) of kaolin suspension when the dosage concentration was 1.0 mg/ml. Under strong alkaline pH of 12, flocculating activity reached (95 percent) when Al3+ was the coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl and phosphoryl functional groups. Scanning electron microscopy (SEM) image revealed a flaky amorphous morphological structure. Due to the excellent COD and turbidity removal efficiencies of the bioflocculants produced by the consortia, these make those attractive candidates for use in water and wastewater treatment. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013
Perceived success of skills-development readiness within 4IR in RSA
- Authors: Hunt, Norman William
- Date: 2021-04
- Subjects: Technological innovations -- Economic aspects , Labor demand -- Research -- South Africa , Labor supply -- Research -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/51567 , vital:43310
- Description: The purpose of this study was to develop four scenarios for South Africa over the next forty years. The Positive Seed scenario portrays a positive image of hope and determination, with positive institutional innovations, as well as positive innovative learning methodologies. While the Shankar scenario also portrays positive institutional innovations, it is lacking in terms of innovation learning methodologies. The Negative Seed is lacking in both innovation learning methodologies, as well as institutional innovations. Finally, the fourth scenario, that of the ‘What If’ scenario, portrays a scenario whether good innovative learning methodologies exist, or not, but lacks institutional innovativeness. The goal of this thesis was not only to affirm the known and knowable about the skills-development environment, but it is also aimed at exploring its future within the 4IR towards 2060. This was achieved by scenario planning and the Causal Layered Analyses (CLA) methodology, which is designed to help navigate through this creative process. This thesis starts off by identifying the forces of change, which it then combines in various ways to create the set of scenarios about how the future of the skills-development sector could evolve towards 2060. This thesis provides useful insight into drivers for change for the South African skills-development sector and how to anticipate skills-readiness in South Africa within the 4IR towards 2060 in accordance with the CLA and scenario planning methods. This thesis looks at the future of skills-development in South Africa over the next forty years from a decision makers point of view. , Thesis (DBA) -- Faculty of Business and Economic Sciences, Business Administration, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Hunt, Norman William
- Date: 2021-04
- Subjects: Technological innovations -- Economic aspects , Labor demand -- Research -- South Africa , Labor supply -- Research -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/51567 , vital:43310
- Description: The purpose of this study was to develop four scenarios for South Africa over the next forty years. The Positive Seed scenario portrays a positive image of hope and determination, with positive institutional innovations, as well as positive innovative learning methodologies. While the Shankar scenario also portrays positive institutional innovations, it is lacking in terms of innovation learning methodologies. The Negative Seed is lacking in both innovation learning methodologies, as well as institutional innovations. Finally, the fourth scenario, that of the ‘What If’ scenario, portrays a scenario whether good innovative learning methodologies exist, or not, but lacks institutional innovativeness. The goal of this thesis was not only to affirm the known and knowable about the skills-development environment, but it is also aimed at exploring its future within the 4IR towards 2060. This was achieved by scenario planning and the Causal Layered Analyses (CLA) methodology, which is designed to help navigate through this creative process. This thesis starts off by identifying the forces of change, which it then combines in various ways to create the set of scenarios about how the future of the skills-development sector could evolve towards 2060. This thesis provides useful insight into drivers for change for the South African skills-development sector and how to anticipate skills-readiness in South Africa within the 4IR towards 2060 in accordance with the CLA and scenario planning methods. This thesis looks at the future of skills-development in South Africa over the next forty years from a decision makers point of view. , Thesis (DBA) -- Faculty of Business and Economic Sciences, Business Administration, 2021
- Full Text:
- Date Issued: 2021-04
Modifcations to gravitational waves due to matter shells
- Authors: Naidoo, Monogaran
- Date: 2021-10-29
- Subjects: Gravitational waves , General relativity (Physics) , Einstein field equations , Cosmology , Matter shells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191118 , vital:45062 , 10.21504/10962/191119
- Description: As detections of gravitational waves (GWs) mount, the need to investigate various effects on the propagation of these waves from the time of emission until detection also grows. We investigate how a thin low density dust shell surrounding a gravitational wave source affects the propagation of GWs. The Bondi-Sachs (BS) formalism for the Einstein equations is used for the problem of a gravitational wave (GW) source surrounded by a spherical dust shell. Using linearised perturbation theory, we and the geometry of the regions exterior to, interior to and within the shell. We and that the dust shell causes the gravitational wave to be modified both in magnitude and phase, but without any energy being transferred to or from the dust. This finding is novel. In the context of cosmology, apart from the gravitational redshift, the effects are too small to be measurable; but the effect would be measurable if a GW event were to occur with a source surrounded by a massive shell and with the radius of the shell and the wavelength of the GWs of the same order. We extended our investigation to astrophysical scenarios such as binary black hole (BBH) mergers, binary neutron star (BNS) mergers, and core collapse supernovae (CCSNe). In these scenarios, instead of a monochromatic GW source, as we used in our initial investigation, we consider burst-like GW sources. The thin density shell approach is modified to include thick shells by considering concentric thin shells and integrating. Solutions are then found for these burst-like GW sources using Fourier transforms. We show that GW echoes that are claimed to be present in the Laser Interferometer Gravitational-Wave Observatory (LIGO) data of certain events, could not have been caused by a matter shell. We do and, however, that matter shells surrounding BBH mergers, BNS mergers, and CCSNe could make modifications of order a few percent to a GW signal. These modifications are expected to be measurable in GW data with current detectors if the event is close enough and at a detectable frequency; or in future detectors with increased frequency range and amplitude sensitivity. Substantial use is made of computer algebra in these investigations. In setting the scene for our investigations, we trace the evolution of general relativity (GR) from Einstein's postulation in 1915 to vindication of his theory with the confirmation of the existence of GWs a century later. We discuss the implications of our results to current and future considerations. Calculations of GWs, both analytical and numerical, have normally assumed their propagation from source to a detector on Earth in a vacuum spacetime, and so discounted the effect of intervening matter. As we enter an era of precision GW measurements, it becomes important to quantify any effects due to propagation of GWs through a non-vacuum spacetime Observational confirmation of the modification effect that we and in astrophysical scenarios involving black holes (BHs), neutron stars (NSs) and CCSNe, would also enhance our understanding of the details of the physics of these bodies. , Thesis (PhD) -- Faculty of Science, Mathematics (Pure and Applied), 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Naidoo, Monogaran
- Date: 2021-10-29
- Subjects: Gravitational waves , General relativity (Physics) , Einstein field equations , Cosmology , Matter shells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191118 , vital:45062 , 10.21504/10962/191119
- Description: As detections of gravitational waves (GWs) mount, the need to investigate various effects on the propagation of these waves from the time of emission until detection also grows. We investigate how a thin low density dust shell surrounding a gravitational wave source affects the propagation of GWs. The Bondi-Sachs (BS) formalism for the Einstein equations is used for the problem of a gravitational wave (GW) source surrounded by a spherical dust shell. Using linearised perturbation theory, we and the geometry of the regions exterior to, interior to and within the shell. We and that the dust shell causes the gravitational wave to be modified both in magnitude and phase, but without any energy being transferred to or from the dust. This finding is novel. In the context of cosmology, apart from the gravitational redshift, the effects are too small to be measurable; but the effect would be measurable if a GW event were to occur with a source surrounded by a massive shell and with the radius of the shell and the wavelength of the GWs of the same order. We extended our investigation to astrophysical scenarios such as binary black hole (BBH) mergers, binary neutron star (BNS) mergers, and core collapse supernovae (CCSNe). In these scenarios, instead of a monochromatic GW source, as we used in our initial investigation, we consider burst-like GW sources. The thin density shell approach is modified to include thick shells by considering concentric thin shells and integrating. Solutions are then found for these burst-like GW sources using Fourier transforms. We show that GW echoes that are claimed to be present in the Laser Interferometer Gravitational-Wave Observatory (LIGO) data of certain events, could not have been caused by a matter shell. We do and, however, that matter shells surrounding BBH mergers, BNS mergers, and CCSNe could make modifications of order a few percent to a GW signal. These modifications are expected to be measurable in GW data with current detectors if the event is close enough and at a detectable frequency; or in future detectors with increased frequency range and amplitude sensitivity. Substantial use is made of computer algebra in these investigations. In setting the scene for our investigations, we trace the evolution of general relativity (GR) from Einstein's postulation in 1915 to vindication of his theory with the confirmation of the existence of GWs a century later. We discuss the implications of our results to current and future considerations. Calculations of GWs, both analytical and numerical, have normally assumed their propagation from source to a detector on Earth in a vacuum spacetime, and so discounted the effect of intervening matter. As we enter an era of precision GW measurements, it becomes important to quantify any effects due to propagation of GWs through a non-vacuum spacetime Observational confirmation of the modification effect that we and in astrophysical scenarios involving black holes (BHs), neutron stars (NSs) and CCSNe, would also enhance our understanding of the details of the physics of these bodies. , Thesis (PhD) -- Faculty of Science, Mathematics (Pure and Applied), 2021
- Full Text:
- Date Issued: 2021-10-29
Computational analysis of known drug resistant mutants of Plasmodium falciparum Dihydrofolate Reductase (PfDHFR) and screening for novel antifolates against the enzyme
- Authors: Tata, Rolland Bantar
- Date: 2022-04-08
- Subjects: Uncatalogued
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/234184 , vital:50170
- Description: Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-04-08
- Authors: Tata, Rolland Bantar
- Date: 2022-04-08
- Subjects: Uncatalogued
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/234184 , vital:50170
- Description: Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-04-08
Identification of novel compounds against Plasmodium falciparum Cytochrome bc1 Complex inhibiting the trans-membrane electron transfer pathway: an In Silico study
- Authors: Chebon, Lorna Jemosop
- Date: 2022-10-14
- Subjects: Malaria , Plasmodium falciparum , Molecular dynamics , Antimalarials , Molecules Models , Docking , Cytochromes , Drug resistance , Computer simulation , Drugs Computer-aided design , System analysis
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365666 , vital:65774 , DOI https://doi.org/10.21504/10962/365666
- Description: Malaria continues to be a burden globally with a myriad of challenges deterring eradication efforts. With most antimalarials facing drug resistance, such as atovaquone (ATQ), alternative compounds that can withstand resistance are warranted. The Plasmodium falciparum cytochrome b (PfCytb), a subunit of P. falciparum cytochrome bc1 complex, is a validated drug target. Structurally, cytochrome b, cytochrome c1, and iron sulphur protein (ISP) subunits form the catalytic domain of the protein complex having heme bL, heme bH and iron-sulphur [2FE-2S] cluster cofactors. These cofactos have redox centres to aid in the electron transfer (ET) process. These subunits promote ET mainly through the enzyme’s ubiquinol oxidation (Qo) and ubiquinone reduction (Qi) processes in the catalytic domain. ATQ drug has been used in the prevention and treatment of uncomplicated malaria by targeting PfCytb protein. Once the mitochondrial transmembrane ET pathway is inhibited, it causes a collapse in its membrane potential. Previously reported ATQ drug resistance has been associated with the point mutations Y268C, Y268N and Y268S. Thus, in finding alternatives to the ATQ drug, this research aimed to: i) employ in silico approaches incorporating protein into phospholipid bilayer for the first time to understand the parasites’ resistance mechanism; ii) determine any sequence and structural differences that could be explored in drug design studies; and iii) screen for PfCytb-iron sulphur protein (Cytb-ISP) hit compounds from South African natural compound database (SANCDB) and Medicines for Malaria Venture (MMV) that can withstand the identified mutations. Using computational tools, comparative sequence and structural analyses were performed on the cytochrome b protein, where the ultimate focus was on P. falciparum cytochrome b and its human homolog. Through multiple sequence alignment, motif discovery and phylogeny, differences between P. falciparum and H. sapiens cytochrome b were identified. Protein modelling of both P. falciparum and H. sapiens cytochrome b - iron sulphur protein (PfCytb-ISP and HsCytb-ISP) was performed. Results showed that at the sequence level, there were few amino acid residue differences because the protein is highly conserved. Important to note is the four-residue deletion in Plasmodium spp. absent in the human homolog. Motif analysis discovered five unique motifs in P. falciparum cytochrome b protein which were mapped onto the predicted protein model. These motifs were not in regions of functional importance; hence their function is still unknown. At a structural level, the four-residue deletion was observed to alter the Qo substrate binding pocket as reported in previous studies and confirmed in this study. This deletion resulted in a 0.83 Å structural displacement. Also, there are currently no in silico studies that have performed experiments with P. falciparum cytochrome b protein incorporated into a phospholipid bilayer. Using 350 ns molecular dynamics (MD) simulations of the holo and ATQ-bound systems, the study highlighted the resistance mechanism of the parasite protein where the loss of active site residue-residue interactions was identified, all linked to the three mutations. The identified compromised interactions are likely to destabilise the protein’s function, specifically in the Qo substrate binding site. This showed the possible effect of mutations on ATQ drug activity, where all three mutations were reported to share a similar resistance mechanism. Thereafter, this research work utilised in silico approaches where both Qo active site and interface pocket were targeted by screening the South African natural compounds database (SANCDB) and Medicines for Malaria Venture (MMV) compounds to identify novel selective hits. SANCDB compounds are known for their structural complexity that preserves the potency of the drug molecule. Both SANCDB and MMV compounds have not been explored as inhibitors against the PfCytb drug target. Molecular docking, molecular dynamics (MD) simulations, principal component, and dynamic residue network (DRN; global and local) analyses were utilised to identify and confirm the potential selective inhibitors. Docking results identified compounds that bound selectively onto PfCytb-ISP with a binding energy ≤ -8.7 kcal/mol-1. Further, this work validated a total of eight potential selective compounds to inhibit PfCytb-ISP protein (Qo active site) not only in the wild-type but also in the presence of the point mutations Y268C, Y268N and Y268S. The selective binding of these hit compounds could be linked to the differences reported at sequence/residue level in chapter 3. DRN and residue contact map analyses of the eight compounds in holo and ligand-bound systems revealed reduced residue interactions and decreased protein communication. This suggests that the eight compounds show the possibility of inhibiting the parasite and disrupting important residue-residue interactions. Additionally, 13 selective compounds were identified to bind at the protein’s heterodimer interface, where global and local analysis confirmed their effect on active site residues (distal location) as well as on the communication network. Based on the sequence differences between PfCytb and the human homolog, these findings suggest these selective compounds as potential allosteric modulators of the parasite enzyme, which may serve as possible replacements of the already resistant ATQ drug. Therefore, these findings pave the way for further in vitro studies to establish their anti-plasmodial inhibition levels. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Chebon, Lorna Jemosop
- Date: 2022-10-14
- Subjects: Malaria , Plasmodium falciparum , Molecular dynamics , Antimalarials , Molecules Models , Docking , Cytochromes , Drug resistance , Computer simulation , Drugs Computer-aided design , System analysis
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365666 , vital:65774 , DOI https://doi.org/10.21504/10962/365666
- Description: Malaria continues to be a burden globally with a myriad of challenges deterring eradication efforts. With most antimalarials facing drug resistance, such as atovaquone (ATQ), alternative compounds that can withstand resistance are warranted. The Plasmodium falciparum cytochrome b (PfCytb), a subunit of P. falciparum cytochrome bc1 complex, is a validated drug target. Structurally, cytochrome b, cytochrome c1, and iron sulphur protein (ISP) subunits form the catalytic domain of the protein complex having heme bL, heme bH and iron-sulphur [2FE-2S] cluster cofactors. These cofactos have redox centres to aid in the electron transfer (ET) process. These subunits promote ET mainly through the enzyme’s ubiquinol oxidation (Qo) and ubiquinone reduction (Qi) processes in the catalytic domain. ATQ drug has been used in the prevention and treatment of uncomplicated malaria by targeting PfCytb protein. Once the mitochondrial transmembrane ET pathway is inhibited, it causes a collapse in its membrane potential. Previously reported ATQ drug resistance has been associated with the point mutations Y268C, Y268N and Y268S. Thus, in finding alternatives to the ATQ drug, this research aimed to: i) employ in silico approaches incorporating protein into phospholipid bilayer for the first time to understand the parasites’ resistance mechanism; ii) determine any sequence and structural differences that could be explored in drug design studies; and iii) screen for PfCytb-iron sulphur protein (Cytb-ISP) hit compounds from South African natural compound database (SANCDB) and Medicines for Malaria Venture (MMV) that can withstand the identified mutations. Using computational tools, comparative sequence and structural analyses were performed on the cytochrome b protein, where the ultimate focus was on P. falciparum cytochrome b and its human homolog. Through multiple sequence alignment, motif discovery and phylogeny, differences between P. falciparum and H. sapiens cytochrome b were identified. Protein modelling of both P. falciparum and H. sapiens cytochrome b - iron sulphur protein (PfCytb-ISP and HsCytb-ISP) was performed. Results showed that at the sequence level, there were few amino acid residue differences because the protein is highly conserved. Important to note is the four-residue deletion in Plasmodium spp. absent in the human homolog. Motif analysis discovered five unique motifs in P. falciparum cytochrome b protein which were mapped onto the predicted protein model. These motifs were not in regions of functional importance; hence their function is still unknown. At a structural level, the four-residue deletion was observed to alter the Qo substrate binding pocket as reported in previous studies and confirmed in this study. This deletion resulted in a 0.83 Å structural displacement. Also, there are currently no in silico studies that have performed experiments with P. falciparum cytochrome b protein incorporated into a phospholipid bilayer. Using 350 ns molecular dynamics (MD) simulations of the holo and ATQ-bound systems, the study highlighted the resistance mechanism of the parasite protein where the loss of active site residue-residue interactions was identified, all linked to the three mutations. The identified compromised interactions are likely to destabilise the protein’s function, specifically in the Qo substrate binding site. This showed the possible effect of mutations on ATQ drug activity, where all three mutations were reported to share a similar resistance mechanism. Thereafter, this research work utilised in silico approaches where both Qo active site and interface pocket were targeted by screening the South African natural compounds database (SANCDB) and Medicines for Malaria Venture (MMV) compounds to identify novel selective hits. SANCDB compounds are known for their structural complexity that preserves the potency of the drug molecule. Both SANCDB and MMV compounds have not been explored as inhibitors against the PfCytb drug target. Molecular docking, molecular dynamics (MD) simulations, principal component, and dynamic residue network (DRN; global and local) analyses were utilised to identify and confirm the potential selective inhibitors. Docking results identified compounds that bound selectively onto PfCytb-ISP with a binding energy ≤ -8.7 kcal/mol-1. Further, this work validated a total of eight potential selective compounds to inhibit PfCytb-ISP protein (Qo active site) not only in the wild-type but also in the presence of the point mutations Y268C, Y268N and Y268S. The selective binding of these hit compounds could be linked to the differences reported at sequence/residue level in chapter 3. DRN and residue contact map analyses of the eight compounds in holo and ligand-bound systems revealed reduced residue interactions and decreased protein communication. This suggests that the eight compounds show the possibility of inhibiting the parasite and disrupting important residue-residue interactions. Additionally, 13 selective compounds were identified to bind at the protein’s heterodimer interface, where global and local analysis confirmed their effect on active site residues (distal location) as well as on the communication network. Based on the sequence differences between PfCytb and the human homolog, these findings suggest these selective compounds as potential allosteric modulators of the parasite enzyme, which may serve as possible replacements of the already resistant ATQ drug. Therefore, these findings pave the way for further in vitro studies to establish their anti-plasmodial inhibition levels. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
Cultural and social factors affecting crop production at Gqumahashe and Melani, Alice District
- Komanisi, Mzwandile Paul 0000-0003-0866-666X
- Authors: Komanisi, Mzwandile Paul 0000-0003-0866-666X
- Date: 2016-06
- Subjects: Sharecropping , Food crops
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23023 , vital:55001
- Description: Over the years, sharecropping and work-parties have been seen as variables that maintain social cohesion among people and maximize agricultural production. This study seeks to validate the authenticity of this assertion in the context of two neighbouring villages. Although there are other variables that affect crop production in the study areas, Lower Gqumahashe and Melani, in the light of time constraints and the insignificant impact of these variables, the study focused only on sharecropping and work-parties. The study adopted empirical research design. The researcher realised that empirical research design would offer him an opportunity for intense or prolonged contact with informants in order to have a holistic picture of their behaviour. The researcher did not choose theoretical research design because it would not allow him to have an extensive interaction with informants since it relies on secondary data. The findings of the study suggest that sharecropping and work parties are the main variables that hinder the rate of crop production in the study areas. However, there are other secondary variables hindering crop production but they have insignificant impact. These are clan and kinship relations, political structure, religion and social identity. This study concludes that although local informants were in favour of sharecropping and work-parties in the past, they have discontinued them due to exploitation and hoodwinking. , Thesis (PhD) -- Faculty of Social Science and Humanities, 2016
- Full Text:
- Date Issued: 2016-06
- Authors: Komanisi, Mzwandile Paul 0000-0003-0866-666X
- Date: 2016-06
- Subjects: Sharecropping , Food crops
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23023 , vital:55001
- Description: Over the years, sharecropping and work-parties have been seen as variables that maintain social cohesion among people and maximize agricultural production. This study seeks to validate the authenticity of this assertion in the context of two neighbouring villages. Although there are other variables that affect crop production in the study areas, Lower Gqumahashe and Melani, in the light of time constraints and the insignificant impact of these variables, the study focused only on sharecropping and work-parties. The study adopted empirical research design. The researcher realised that empirical research design would offer him an opportunity for intense or prolonged contact with informants in order to have a holistic picture of their behaviour. The researcher did not choose theoretical research design because it would not allow him to have an extensive interaction with informants since it relies on secondary data. The findings of the study suggest that sharecropping and work parties are the main variables that hinder the rate of crop production in the study areas. However, there are other secondary variables hindering crop production but they have insignificant impact. These are clan and kinship relations, political structure, religion and social identity. This study concludes that although local informants were in favour of sharecropping and work-parties in the past, they have discontinued them due to exploitation and hoodwinking. , Thesis (PhD) -- Faculty of Social Science and Humanities, 2016
- Full Text:
- Date Issued: 2016-06
Parents and personnel’s partnership in early childhood education provisioning in the East London Education District
- Mudziwapasi, Lilymore https://orcid.org/0000-0002-7978-8499
- Authors: Mudziwapasi, Lilymore https://orcid.org/0000-0002-7978-8499
- Date: 2022-02
- Subjects: Education, Preschool -- Parent participation , Education, Preschool
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21700 , vital:51743
- Description: Early childhood development is fundamental to human development and success in later life. Several stakeholders influence that development. Developmental policies are advocating for formal education provision at that early childhood age. Therefore, relationships and interactions of these stakeholders are of paramount importance in ensuring effective early childhood education provisioning – especially between parents and practitioners. Yet it has been reported that sharing of information concerning children’s educational development is not happening between parents and ECD practitioners. ECD centres are said to face many problems such as poor teaching and learning which may result in weak childhood educational development. Some of these challenges can be addressed through enhancing the partnership between parents and the ECD practitioners. The purpose of this study was therefore to explore the parents and practitioners’ partnership in early childhood education provisioning in ECD centres in the East London district. This study used the mixed method approach in the sampling, data collection and data analysis processes. The study focused on the partnership between parents and ECD practitioners, on how they work together, their views, how they communicate, on decision making and the strategies to enhance the partnership of parents and practitioners. Research questions in this study required both qualitative and quantitative data and analysis techniques. Quantitative data was collected from the ECD practitioners and principals by using questionnaires and qualitative data was collected through interviews with the parents. Quantitative data was analysed using SPSS and qualitative data was analysed using the thematic approach. The findings indicated that both parents and practitioners are working together in supporting learning and development. Parents are said to provide resources for use at the centre. Parents and practitioners are using different modes of communication for the learning and development of the children, including technology-based WhatsApp and emails. Practitioners are said to include parents in some decision making. The results indicated that even though some parents are working together with practitioners, while other parents are still showing ignorance and lack of knowledge on how they can partner for the educational development of the children. , Thesis (PhD) -- Faculty of Education, 2022
- Full Text:
- Date Issued: 2022-02
- Authors: Mudziwapasi, Lilymore https://orcid.org/0000-0002-7978-8499
- Date: 2022-02
- Subjects: Education, Preschool -- Parent participation , Education, Preschool
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21700 , vital:51743
- Description: Early childhood development is fundamental to human development and success in later life. Several stakeholders influence that development. Developmental policies are advocating for formal education provision at that early childhood age. Therefore, relationships and interactions of these stakeholders are of paramount importance in ensuring effective early childhood education provisioning – especially between parents and practitioners. Yet it has been reported that sharing of information concerning children’s educational development is not happening between parents and ECD practitioners. ECD centres are said to face many problems such as poor teaching and learning which may result in weak childhood educational development. Some of these challenges can be addressed through enhancing the partnership between parents and the ECD practitioners. The purpose of this study was therefore to explore the parents and practitioners’ partnership in early childhood education provisioning in ECD centres in the East London district. This study used the mixed method approach in the sampling, data collection and data analysis processes. The study focused on the partnership between parents and ECD practitioners, on how they work together, their views, how they communicate, on decision making and the strategies to enhance the partnership of parents and practitioners. Research questions in this study required both qualitative and quantitative data and analysis techniques. Quantitative data was collected from the ECD practitioners and principals by using questionnaires and qualitative data was collected through interviews with the parents. Quantitative data was analysed using SPSS and qualitative data was analysed using the thematic approach. The findings indicated that both parents and practitioners are working together in supporting learning and development. Parents are said to provide resources for use at the centre. Parents and practitioners are using different modes of communication for the learning and development of the children, including technology-based WhatsApp and emails. Practitioners are said to include parents in some decision making. The results indicated that even though some parents are working together with practitioners, while other parents are still showing ignorance and lack of knowledge on how they can partner for the educational development of the children. , Thesis (PhD) -- Faculty of Education, 2022
- Full Text:
- Date Issued: 2022-02