The evaluation of environmental reporting by publicly listed South African banks
- Authors: Oduro-Kwateng, George
- Date: 2010
- Subjects: Environmental reporting -- South Africa Banks and banking -- South Africa Social responsibility in banking -- South Africa Social responsibility of business -- South Africa Environmental protection -- South Africa Environmental economics -- South Africa Economic development -- South Africa -- Environmental aspects Environmental management -- South Africa Climatic changes -- South Africa Coalition for Environmentally Responsible Economies Global Reporting Initiative Standard Bank Limited Nedbank ABSA Bank
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:740 , http://hdl.handle.net/10962/d1003860
- Description: Recently, bankers have come to realise that banking operations, especially corporate lending, affect and are affected by the natural environment and that consequently, the banks might have an important role to play in helping to raise environmental standards. Although the environment presents significant risks to banks, in particular environmental credit risk, it also perhaps presents profitable opportunities. Stricter environmental regulations have forced companies to invest in environmentally friendly technologies and pollution control measures and in tum generated lending opportunities for bankers. This research examines the corporate practices of three of the four dominant banks in South Africa with respect to the environment, focusing on issues of climate change and environmental risk management by way of reporting and disclosure to all stakeholders. The emphasis on environmental reporting by South African banks has been reinforced by the latest release of the King III Report on Corporate Governance in South Africa. Global governance requires that the triple-bottom line should be applied in all corporate undertakings due to globalisation and trade liberalisation; however, the banking sector has responded poorly to the clarion call. The false view that the banks have no significant relationship with environmental degradation is being disproved. Environmental management is a huge and massive reconstruction of what has gone wrong with nature by human influence. The South African banks have had to face with the challenging tasks of reporting on the direct and mostly the indirect impacts of their environmental activities. Based on the three sampled banks which incidentally had greater percentages of the market capitalizations, the banks have fairly performed in environmental reporting. For example, Standard Bank (SA) Ltd has just signed the Equator Principles in 2007 implying corporate lending was done in 2007 without any respect to environmental impact assessments by corporate borrowers. Consequently, environmental reporting was not done to facilitate informed decision-making by stakeholders mostly shareholders and the communities where borrowers tun businesses. The objective of this research study is to investigate the extent and quantity of/voluntary environmental disclosures in the annual and sustainability reports of the banks listed on Johannesburg Stock Exchange. The periods examined were those subsequent to the release of the Exposure Draft Coalition for Environmentally Responsible Economies (CERES) Global Reporting Initiatives (GRI) issued in 1999. Using content analysis to focus on the environmental aspects, the research study compared three annual reports and three sustainability reports of 2007 year for the three sampled banks in order to evaluate reporting practices in the period surrounding this intervention. The results suggest a trend to triple bottom-line reporting and the extent and quantity of environmental information, albeit in specific categories.
- Full Text:
- Date Issued: 2010
- Authors: Oduro-Kwateng, George
- Date: 2010
- Subjects: Environmental reporting -- South Africa Banks and banking -- South Africa Social responsibility in banking -- South Africa Social responsibility of business -- South Africa Environmental protection -- South Africa Environmental economics -- South Africa Economic development -- South Africa -- Environmental aspects Environmental management -- South Africa Climatic changes -- South Africa Coalition for Environmentally Responsible Economies Global Reporting Initiative Standard Bank Limited Nedbank ABSA Bank
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:740 , http://hdl.handle.net/10962/d1003860
- Description: Recently, bankers have come to realise that banking operations, especially corporate lending, affect and are affected by the natural environment and that consequently, the banks might have an important role to play in helping to raise environmental standards. Although the environment presents significant risks to banks, in particular environmental credit risk, it also perhaps presents profitable opportunities. Stricter environmental regulations have forced companies to invest in environmentally friendly technologies and pollution control measures and in tum generated lending opportunities for bankers. This research examines the corporate practices of three of the four dominant banks in South Africa with respect to the environment, focusing on issues of climate change and environmental risk management by way of reporting and disclosure to all stakeholders. The emphasis on environmental reporting by South African banks has been reinforced by the latest release of the King III Report on Corporate Governance in South Africa. Global governance requires that the triple-bottom line should be applied in all corporate undertakings due to globalisation and trade liberalisation; however, the banking sector has responded poorly to the clarion call. The false view that the banks have no significant relationship with environmental degradation is being disproved. Environmental management is a huge and massive reconstruction of what has gone wrong with nature by human influence. The South African banks have had to face with the challenging tasks of reporting on the direct and mostly the indirect impacts of their environmental activities. Based on the three sampled banks which incidentally had greater percentages of the market capitalizations, the banks have fairly performed in environmental reporting. For example, Standard Bank (SA) Ltd has just signed the Equator Principles in 2007 implying corporate lending was done in 2007 without any respect to environmental impact assessments by corporate borrowers. Consequently, environmental reporting was not done to facilitate informed decision-making by stakeholders mostly shareholders and the communities where borrowers tun businesses. The objective of this research study is to investigate the extent and quantity of/voluntary environmental disclosures in the annual and sustainability reports of the banks listed on Johannesburg Stock Exchange. The periods examined were those subsequent to the release of the Exposure Draft Coalition for Environmentally Responsible Economies (CERES) Global Reporting Initiatives (GRI) issued in 1999. Using content analysis to focus on the environmental aspects, the research study compared three annual reports and three sustainability reports of 2007 year for the three sampled banks in order to evaluate reporting practices in the period surrounding this intervention. The results suggest a trend to triple bottom-line reporting and the extent and quantity of environmental information, albeit in specific categories.
- Full Text:
- Date Issued: 2010
The impact of HAART on sexuality and medicine taking behaviours among people living with HIV/AIDS in Grahamstown
- Authors: Chizanga, Tongai Aldridge
- Date: 2010
- Subjects: AIDS (Disease) -- Treatment -- South Africa -- Grahamstown HIV infections -- Treatment -- South Africa -- Grahamstown Antiretroviral agents -- South Africa -- Grahamstown Patient compliance -- South Africa -- Grahamstown AIDS (Disease) -- Social aspects -- South Africa -- Grahamstown HIV infections -- Social aspects -- South Africa -- Grahamstown AIDS (Disease) -- Patients -- South Africa -- Grahamstown -- Sexual behavior HIV-positive persons -- South Africa -- Grahamstown -- Sexual behavior Patient education -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: vital:3750 , http://hdl.handle.net/10962/d1003228
- Description: Introduction: Adherence to Highly Active Antiretroviral Therapy (HAART) is critical for optimal therapeutic outcomes. A possible factor in adherence is the impact of HAART on sexual functioning. Methods: A mixed methods approach was used. A cohort of 14 people living with HIV/AIDS (PLWHA) in Grahamstown was identified. Two semi-structured interviews and two structured questionnaires were administered. In-depth interviews were conducted with two HIV counsellors in so as to obtain a different perspective on the topics. The theoretical framework used three health behaviour models: the Health Belief Model, Leventhal‘s Common-Sense Model of self regulation and the Transtheoretical model. Results: The participants were between 27 and 49 years old and had been on HAART for between 9 months and 10 years. Six participants were support staff members from Rhodes University and eight from the Raphael Centre – a local NGO which assists PLWHA.In most of the participants HAART was associated with increased libido and improved sexual functioning (sexual activity and sexual enjoyment). The use of alcohol increased risky sexual behaviour. Issues of adherence were seemingly not directly affected by the effects of HAART on sexuality. PLWHA, especially women, face challenges related to their sexuality, some of which are not directly related to their illness and treatment. The fear of transmitting drug resistant HIV or getting re-infected, stigma, disclosure issues,difficulties negotiating for safe sex among women, HAART-related lipodystrophic changes that affect one‘s sense of self and unmet reproductive needs are some of the problems that were reported. The men‘s dislike for condoms was overt and blatant. Discussion: Being diagnosed with HIV and reaching a point where treatment is requiredare life-changing events. Making decisions about one‘s life (including adherence to HAART, alcohol use and knowingly partaking in risky sexual encounters) become all the more significant in the context of AIDS. Intentional non-adherence is informed by the individual‘s assessment of the costs and benefits of taking treatment. Cultural influences,gendered power relations and misconceptions strongly influence sexual behaviours. Conclusion: The general lack of attention among health care providers concerning issues related to PLWHA‘s sexuality and reproductive issues needs to be addressed. Insights fromthe theoretical models should be integrated with empirical findings in designing adherence interventions.
- Full Text:
- Date Issued: 2010
- Authors: Chizanga, Tongai Aldridge
- Date: 2010
- Subjects: AIDS (Disease) -- Treatment -- South Africa -- Grahamstown HIV infections -- Treatment -- South Africa -- Grahamstown Antiretroviral agents -- South Africa -- Grahamstown Patient compliance -- South Africa -- Grahamstown AIDS (Disease) -- Social aspects -- South Africa -- Grahamstown HIV infections -- Social aspects -- South Africa -- Grahamstown AIDS (Disease) -- Patients -- South Africa -- Grahamstown -- Sexual behavior HIV-positive persons -- South Africa -- Grahamstown -- Sexual behavior Patient education -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: vital:3750 , http://hdl.handle.net/10962/d1003228
- Description: Introduction: Adherence to Highly Active Antiretroviral Therapy (HAART) is critical for optimal therapeutic outcomes. A possible factor in adherence is the impact of HAART on sexual functioning. Methods: A mixed methods approach was used. A cohort of 14 people living with HIV/AIDS (PLWHA) in Grahamstown was identified. Two semi-structured interviews and two structured questionnaires were administered. In-depth interviews were conducted with two HIV counsellors in so as to obtain a different perspective on the topics. The theoretical framework used three health behaviour models: the Health Belief Model, Leventhal‘s Common-Sense Model of self regulation and the Transtheoretical model. Results: The participants were between 27 and 49 years old and had been on HAART for between 9 months and 10 years. Six participants were support staff members from Rhodes University and eight from the Raphael Centre – a local NGO which assists PLWHA.In most of the participants HAART was associated with increased libido and improved sexual functioning (sexual activity and sexual enjoyment). The use of alcohol increased risky sexual behaviour. Issues of adherence were seemingly not directly affected by the effects of HAART on sexuality. PLWHA, especially women, face challenges related to their sexuality, some of which are not directly related to their illness and treatment. The fear of transmitting drug resistant HIV or getting re-infected, stigma, disclosure issues,difficulties negotiating for safe sex among women, HAART-related lipodystrophic changes that affect one‘s sense of self and unmet reproductive needs are some of the problems that were reported. The men‘s dislike for condoms was overt and blatant. Discussion: Being diagnosed with HIV and reaching a point where treatment is requiredare life-changing events. Making decisions about one‘s life (including adherence to HAART, alcohol use and knowingly partaking in risky sexual encounters) become all the more significant in the context of AIDS. Intentional non-adherence is informed by the individual‘s assessment of the costs and benefits of taking treatment. Cultural influences,gendered power relations and misconceptions strongly influence sexual behaviours. Conclusion: The general lack of attention among health care providers concerning issues related to PLWHA‘s sexuality and reproductive issues needs to be addressed. Insights fromthe theoretical models should be integrated with empirical findings in designing adherence interventions.
- Full Text:
- Date Issued: 2010
Disjunctures within conventional knowledge of black male homosexual identity in contemporary South Africa
- Authors: Li, Xinling
- Date: 2010
- Subjects: Mead, George Herbert 1863-1931 , Foucault, Michel, 1926-1984 , Butler, Judith, 1956- , Gay men, Black -- South Africa , Lesbians -- South Africa , Gender identity -- South Africa , Homosexuality -- South Africa , Identity (Psychology) -- South Africa , Gender identity -- Social aspects
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3297 , http://hdl.handle.net/10962/d1003085 , Mead, George Herbert 1863-1931 , Foucault, Michel, 1926-1984 , Butler, Judith, 1956- , Gay men, Black -- South Africa , Lesbians -- South Africa , Gender identity -- South Africa , Homosexuality -- South Africa , Identity (Psychology) -- South Africa , Gender identity -- Social aspects
- Description: This thesis provides a sociological understanding of how conventional knowledge of sexuality negates the identity formation of black gay men in contemporary South Africa. It investigates the coming out experiences of six black gay men in order to reveal the disjunctures between being black and being gay. The theoretical formation of disjuncture is pursued through examining a number of sociological, historical, psychoanalytical, and feminist approaches to identity, sexuality, and society; featuring specifically the theories of George Herbert Mead, Michel Foucault, and Judith Butler. The chosen research paradigm is symbolic interactionism, postulating both „pragmatist‟ and „empiricist‟ trends that lead to both interactionist and structuralist forms of argumentation. The interactionist approach to sexuality is central to the deconstruction of sexual conventions. It involves conceptualising modern sexuality in the landscapes of African colonial history and the global gay and lesbian movement. The prescribed literature on homosexuality is thus reviewed in conjunction with the South African gay and lesbian struggle, so as to spawn themes and perspectives for conducting life story interviews. The use of the life story interview favours the participants‟ own view of the studied phenomenon, yet aims to depict the structural influence on homosexual identification. Following the qualitative research tradition, the data analysis is based on the interpretation of narratives. It illustrates interpersonal relationships and microscopic experiences that lead to the self-acceptance and self-actualisation of homosexuality. Within these processes, various disjunctures that exist between the cultural sanction of lifestyle and individual choice, between parents and children, between religious belief and personal desires, and between gender identity and sexual orientation are disclosed. The findings are associated with the historical transformation of masculinity in South Africa, sex role performance, and the heterosexualisation of desire. The solution to the proposed research problem is discussed through concepts of socialisation and gender conformity.
- Full Text:
- Date Issued: 2010
- Authors: Li, Xinling
- Date: 2010
- Subjects: Mead, George Herbert 1863-1931 , Foucault, Michel, 1926-1984 , Butler, Judith, 1956- , Gay men, Black -- South Africa , Lesbians -- South Africa , Gender identity -- South Africa , Homosexuality -- South Africa , Identity (Psychology) -- South Africa , Gender identity -- Social aspects
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3297 , http://hdl.handle.net/10962/d1003085 , Mead, George Herbert 1863-1931 , Foucault, Michel, 1926-1984 , Butler, Judith, 1956- , Gay men, Black -- South Africa , Lesbians -- South Africa , Gender identity -- South Africa , Homosexuality -- South Africa , Identity (Psychology) -- South Africa , Gender identity -- Social aspects
- Description: This thesis provides a sociological understanding of how conventional knowledge of sexuality negates the identity formation of black gay men in contemporary South Africa. It investigates the coming out experiences of six black gay men in order to reveal the disjunctures between being black and being gay. The theoretical formation of disjuncture is pursued through examining a number of sociological, historical, psychoanalytical, and feminist approaches to identity, sexuality, and society; featuring specifically the theories of George Herbert Mead, Michel Foucault, and Judith Butler. The chosen research paradigm is symbolic interactionism, postulating both „pragmatist‟ and „empiricist‟ trends that lead to both interactionist and structuralist forms of argumentation. The interactionist approach to sexuality is central to the deconstruction of sexual conventions. It involves conceptualising modern sexuality in the landscapes of African colonial history and the global gay and lesbian movement. The prescribed literature on homosexuality is thus reviewed in conjunction with the South African gay and lesbian struggle, so as to spawn themes and perspectives for conducting life story interviews. The use of the life story interview favours the participants‟ own view of the studied phenomenon, yet aims to depict the structural influence on homosexual identification. Following the qualitative research tradition, the data analysis is based on the interpretation of narratives. It illustrates interpersonal relationships and microscopic experiences that lead to the self-acceptance and self-actualisation of homosexuality. Within these processes, various disjunctures that exist between the cultural sanction of lifestyle and individual choice, between parents and children, between religious belief and personal desires, and between gender identity and sexual orientation are disclosed. The findings are associated with the historical transformation of masculinity in South Africa, sex role performance, and the heterosexualisation of desire. The solution to the proposed research problem is discussed through concepts of socialisation and gender conformity.
- Full Text:
- Date Issued: 2010
An investigation into perceptions of participative management in a Namibian secondary school
- Authors: Shilima, Christine
- Date: 2010
- Subjects: School management and organization -- Namibia -- Case studies Educational leadership -- Namibia -- Case studies Education, Secondary -- Namibia -- Case studies Education -- Parent participation -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1881 , http://hdl.handle.net/10962/d1005874
- Description: This study examines the perceptions and experiences of school stakeholders about the practices of participative management in a Namibian Secondary School. Data was collected by using interviews, observation and document analysis. The study revealed that participative management has some benefits for the school such as it promotes democracy in school management, school as an open system, sharing of ideas and skills, teamwork and that ownership and commitment enhance the chances for organization change. Participatory decision making and shared leadership are the practices of PM that emerged from this study. However the school does experience challenges such as lack of knowledge on the practice and potential of PM in school management and leadership, illiteracy among parents that prevent them from participation in management and autocratic management practices from some members in formal leadership. The study suggests that trust, relationships and openness are good interpersonal skills that can help enhance the practices of PM in the school. Other strategies were to sensitize stakeholders on the practices of PM.
- Full Text:
- Date Issued: 2010
- Authors: Shilima, Christine
- Date: 2010
- Subjects: School management and organization -- Namibia -- Case studies Educational leadership -- Namibia -- Case studies Education, Secondary -- Namibia -- Case studies Education -- Parent participation -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1881 , http://hdl.handle.net/10962/d1005874
- Description: This study examines the perceptions and experiences of school stakeholders about the practices of participative management in a Namibian Secondary School. Data was collected by using interviews, observation and document analysis. The study revealed that participative management has some benefits for the school such as it promotes democracy in school management, school as an open system, sharing of ideas and skills, teamwork and that ownership and commitment enhance the chances for organization change. Participatory decision making and shared leadership are the practices of PM that emerged from this study. However the school does experience challenges such as lack of knowledge on the practice and potential of PM in school management and leadership, illiteracy among parents that prevent them from participation in management and autocratic management practices from some members in formal leadership. The study suggests that trust, relationships and openness are good interpersonal skills that can help enhance the practices of PM in the school. Other strategies were to sensitize stakeholders on the practices of PM.
- Full Text:
- Date Issued: 2010
"Tell me how you read and I will tell you who you are": children's literature and moral development
- Authors: Van der Nest, Megan
- Date: 2010
- Subjects: Children's literature -- Philosophy Children's literature -- Moral and ethical aspects Children's literature -- History and criticism Literature and morals Ethics in literature Reader-response criticism Moral conditions in literature Literature -- Study and teaching
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2722 , http://hdl.handle.net/10962/d1002852
- Description: It is a common intuition that we can learn something of moral importance from literature, and one of the ways in which we teach our children about morality is through stories. In selecting books for children to read a primary concern is often the effect that the moral content of the story will have on the morality of the child reader. In this thesis I argue in order to take advantage of the contribution that literature can make to moral development, we need to teach children to read in a particular way. As a basis for this argument I use an account of moral agency that places emphasis on the development of moral skills - the ability to critically assess moral rules and systems, and the capacity to perceive and respond to the particulars of individual situations and to choose the right course of action in each - rather than on any particular kind of moral content. In order to make the most of the contribution that literature can make to the development of these skills, we need to teach children to immerse themselves in the story, rather than focusing on literary criticism. I argue that, contrary to the standard view of literary criticism as the only form of protection against possible negative effects, an immersed reading will help to prevent the child reader from taking any moral claims made in the story out of context, and so provide some measure of protection against possible negative moral effects of the story. Finally I argue that there are certain kinds of stories - recognisable by features that contribute to a high literary quality - that will enrich the experience of an immersed reading, and will therefore make a greater contribution to moral development than others.
- Full Text:
- Date Issued: 2010
- Authors: Van der Nest, Megan
- Date: 2010
- Subjects: Children's literature -- Philosophy Children's literature -- Moral and ethical aspects Children's literature -- History and criticism Literature and morals Ethics in literature Reader-response criticism Moral conditions in literature Literature -- Study and teaching
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2722 , http://hdl.handle.net/10962/d1002852
- Description: It is a common intuition that we can learn something of moral importance from literature, and one of the ways in which we teach our children about morality is through stories. In selecting books for children to read a primary concern is often the effect that the moral content of the story will have on the morality of the child reader. In this thesis I argue in order to take advantage of the contribution that literature can make to moral development, we need to teach children to read in a particular way. As a basis for this argument I use an account of moral agency that places emphasis on the development of moral skills - the ability to critically assess moral rules and systems, and the capacity to perceive and respond to the particulars of individual situations and to choose the right course of action in each - rather than on any particular kind of moral content. In order to make the most of the contribution that literature can make to the development of these skills, we need to teach children to immerse themselves in the story, rather than focusing on literary criticism. I argue that, contrary to the standard view of literary criticism as the only form of protection against possible negative effects, an immersed reading will help to prevent the child reader from taking any moral claims made in the story out of context, and so provide some measure of protection against possible negative moral effects of the story. Finally I argue that there are certain kinds of stories - recognisable by features that contribute to a high literary quality - that will enrich the experience of an immersed reading, and will therefore make a greater contribution to moral development than others.
- Full Text:
- Date Issued: 2010
Farm wages and working conditions in the Albany District, 1957-2008
- Authors: Roberts, Tamaryn Jean
- Date: 2010
- Subjects: Agricultural laborers -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa , Agricultural laborers -- Protection -- South Africa , Agricultural laws and legislation -- South Africa , Labour laws and legislation -- South Africa , Labour economics -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:978 , http://hdl.handle.net/10962/d1002712
- Description: Agriculture is a major employer of labour in South Africa with about 8.8% of the total labour force directly involved in agricultural production (StatsSA, 2007a). Farm wages and working conditions in the Albany district were researched in 1957 by Roberts (1958) and 1977 by Antrobus (1984). Research in 2008, involving face-to-face interviews of a sample survey of 40 Albany farmers, was undertaken to update the situation facing farm labourers and allowed for comparisons with the work previously done. Farm workers were governed by common law until 1994 when the government intervened with legislation. The introduction of the Basic Conditions of Employment Act (1997) for farm workers, amended in 2002 to include minimum wage legislation, and the Extension of Security of Tenure Act (ESTA) of 1997 impacted the supply and demand of farm workers. Other impacts have been due to the Albany district experiencing an increase in the establishment of Private Game Reserves and game-tourism with a simultaneous decline in conventional farming. It was concluded from the survey conducted that minimum wage legislation decreased the demand for regular and increased the demand for casual labour, which incur lower costs including transaction costs, than their regular counterparts. The ESTA of 1997 contributed to a decreased number of farm residents, which had spin-off affects on the supply of labour. Farmers experienced a simultaneous price-cost squeeze, which furthermore decreased the demand for labour. Studying the working and living conditions showed that farm workers had limited access to educational and recreational facilities which negatively impacted the supply of labour.
- Full Text:
- Date Issued: 2010
- Authors: Roberts, Tamaryn Jean
- Date: 2010
- Subjects: Agricultural laborers -- South Africa -- Eastern Cape , Agricultural wages -- South Africa -- Eastern Cape , Agricultural laborers -- Legal status, laws, etc. -- South Africa , Agricultural laborers -- Protection -- South Africa , Agricultural laws and legislation -- South Africa , Labour laws and legislation -- South Africa , Labour economics -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:978 , http://hdl.handle.net/10962/d1002712
- Description: Agriculture is a major employer of labour in South Africa with about 8.8% of the total labour force directly involved in agricultural production (StatsSA, 2007a). Farm wages and working conditions in the Albany district were researched in 1957 by Roberts (1958) and 1977 by Antrobus (1984). Research in 2008, involving face-to-face interviews of a sample survey of 40 Albany farmers, was undertaken to update the situation facing farm labourers and allowed for comparisons with the work previously done. Farm workers were governed by common law until 1994 when the government intervened with legislation. The introduction of the Basic Conditions of Employment Act (1997) for farm workers, amended in 2002 to include minimum wage legislation, and the Extension of Security of Tenure Act (ESTA) of 1997 impacted the supply and demand of farm workers. Other impacts have been due to the Albany district experiencing an increase in the establishment of Private Game Reserves and game-tourism with a simultaneous decline in conventional farming. It was concluded from the survey conducted that minimum wage legislation decreased the demand for regular and increased the demand for casual labour, which incur lower costs including transaction costs, than their regular counterparts. The ESTA of 1997 contributed to a decreased number of farm residents, which had spin-off affects on the supply of labour. Farmers experienced a simultaneous price-cost squeeze, which furthermore decreased the demand for labour. Studying the working and living conditions showed that farm workers had limited access to educational and recreational facilities which negatively impacted the supply of labour.
- Full Text:
- Date Issued: 2010
Sample preparation for pesticide analysis in water and sediments a case study of the Okavango Delta, Botswana
- Authors: Mmualefe, Lesego Cecilia
- Date: 2010
- Subjects: Water quality -- Botswana -- Okavango Delta Water -- Analysis Pesticides -- Environmental aspects -- Botswana -- Okavango Delta Water -- Pollution -- Botswana -- Okavango Delta DDT (Insecticide) -- Environmental aspects -- Botswana -- Okavango Delta
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4344 , http://hdl.handle.net/10962/d1005006
- Description: This thesis presents a first ever extensive analysis of pesticides in water and sediments from the Okavango Delta, Botswana, employing green sample preparation techniques that require small volumes of organic solvents hence generating negligible volumes of organic solvent waste. Pesticides were extracted and pre-concentrated from water by solid phase extraction (SPE) and headspace solid phase microextraction (HS-SPME) while supercritical fluid extraction (SFE) and pressurized fluid extraction (PFE) were employed for sediments. Subsequent analysis was carried out on a gas chromatograph with electron capture detection and analytes were unequivocally confirmed by high resolution mass spectrometric detection. Hexachlorobenzene (HCB), trans-chlordane, 4,4′-DDD and 4,4′-DDE were detected after optimized HS-SPME in several water samples from the lower Delta at concentrations ranging from 2.4 to 61.4 μg L-1 that are much higher than the 0.1 μg L-1 maximum limit of individual organochlorine pesticides in drinking water set by the European Community Directive. The same samples were cleaned with ISOLUTE C18 SPE sorbent with an optimal acetone/n-hexane (1:1 v/v) mixture for the elution of analytes. No pesticides were detected after SPE clean-up and pre-concentration. HCB, aldrin and 4, 4‟-DDT were identified in sediments after SFE at concentration ranges of 1.1 - 30.3, 0.5 – 15.2 and 1.4 – 55.4 μg/g, respectively. There was an increase of pesticides concentrations in the direction of water flow from the Panhandle (point of entry) to the lower delta. DDE, fatty acids and phthalates were detected after PFE with optimized extraction solvent and temperature. The presence of DDT metabolites in the water and sediments from the Okavango Delta confirm historical exposure to the pesticide. However their cumulative concentration increase in the water-flow direction calls for further investigation of point sources for the long-term preservation of the Delta. The green sample preparation techniques and low toxicity solvents employed in this thesis are thus recommended for routine environmental monitoring exercises.
- Full Text:
- Date Issued: 2010
- Authors: Mmualefe, Lesego Cecilia
- Date: 2010
- Subjects: Water quality -- Botswana -- Okavango Delta Water -- Analysis Pesticides -- Environmental aspects -- Botswana -- Okavango Delta Water -- Pollution -- Botswana -- Okavango Delta DDT (Insecticide) -- Environmental aspects -- Botswana -- Okavango Delta
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4344 , http://hdl.handle.net/10962/d1005006
- Description: This thesis presents a first ever extensive analysis of pesticides in water and sediments from the Okavango Delta, Botswana, employing green sample preparation techniques that require small volumes of organic solvents hence generating negligible volumes of organic solvent waste. Pesticides were extracted and pre-concentrated from water by solid phase extraction (SPE) and headspace solid phase microextraction (HS-SPME) while supercritical fluid extraction (SFE) and pressurized fluid extraction (PFE) were employed for sediments. Subsequent analysis was carried out on a gas chromatograph with electron capture detection and analytes were unequivocally confirmed by high resolution mass spectrometric detection. Hexachlorobenzene (HCB), trans-chlordane, 4,4′-DDD and 4,4′-DDE were detected after optimized HS-SPME in several water samples from the lower Delta at concentrations ranging from 2.4 to 61.4 μg L-1 that are much higher than the 0.1 μg L-1 maximum limit of individual organochlorine pesticides in drinking water set by the European Community Directive. The same samples were cleaned with ISOLUTE C18 SPE sorbent with an optimal acetone/n-hexane (1:1 v/v) mixture for the elution of analytes. No pesticides were detected after SPE clean-up and pre-concentration. HCB, aldrin and 4, 4‟-DDT were identified in sediments after SFE at concentration ranges of 1.1 - 30.3, 0.5 – 15.2 and 1.4 – 55.4 μg/g, respectively. There was an increase of pesticides concentrations in the direction of water flow from the Panhandle (point of entry) to the lower delta. DDE, fatty acids and phthalates were detected after PFE with optimized extraction solvent and temperature. The presence of DDT metabolites in the water and sediments from the Okavango Delta confirm historical exposure to the pesticide. However their cumulative concentration increase in the water-flow direction calls for further investigation of point sources for the long-term preservation of the Delta. The green sample preparation techniques and low toxicity solvents employed in this thesis are thus recommended for routine environmental monitoring exercises.
- Full Text:
- Date Issued: 2010
Structure and functioning of fish assemblages in two South African estuaries, with emphasis on the presence and absence of aquatic macrophyte beds
- Authors: Sheppard, Jill Nicole
- Date: 2010
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5321 , http://hdl.handle.net/10962/d1005166 , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: Temporarily open/closed estuaries (TOCEs) are the dominant estuary type in South Africa. These systems are often characterized by extensive beds of submerged macrophytes, which form important foraging and shelter habitats for fishes, especially for estuary-dependent fish species such as the Cape stumpnose Rhabdosargus holubi and Cape moony Monodactylus falciformis that are commonly associated with them. A loss of submerged macrophytes from an estuary has been shown to affect the fish community as well as reducing overall system productivity. The TOC East Kleinemonde Estuary, situated in the warm-temperate biogeographic region of South Africa has been subject to an ongoing long-term fish monitoring project since 1995. During the period 1995 to 2002, this estuary contained large beds of the submerged macrophytes Ruppia cirrhosa and Potamogeton pectinatus. However, subsequent to a major flood event in 2003 these macrophytes have been largely absent from this system. The effect of the loss of submerged macrophytes on the East Kleinemonde fish assemblage was investigated through an analysis of seine and gill net catch data. Seine net catches for a 12 year period, encompassing six years of macrophyte presence and six years of macrophyte senescence, revealed changes in the relative abundance of certain fish species. Vegetation-associated species such as R. holubi and M. falciformis decreased in abundance whereas sediment-associated species, especially members of the family Mugilidae, increased in abundance following loss of the macrophytes in this estuary. The critically endangered pipefish Syngnathus watermeyeri was only recorded in catches during years in which macrophyte beds were present. In addition to the analysis of catch data, the importance of macrophytes as a primary energy source for selected estuarine fishes was explored through the analysis of carbon and nitrogen stable isotopes. Prior to conducting these analyses, common methodological practices to address the presence of carbonates and lipids within isotope samples were evaluated. A subset of samples were either acid washed to remove carbonates, or lipids were removed according to the method of Bligh and Dyer (1959) as both of these compounds have been shown to affect stable carbon and nitrogen isotope ratios. The suitability of the lipid normalization models of Fry (2002) and Post et al. (2007) for samples of estuarine fish muscle were also tested. Based on this evaluation both models are suitable for use with estuarine fish muscle tissue, however since neither carbonate nor lipid content of any of the samples used in this study was high all samples were left untreated in the following analysis. Carbon isotope ratios from a wide range of fish species collected from the East Kleinemonde Estuary during the macrophyte-senescent phase were compared with individuals of the same species from the neighbouring West Kleinemonde Estuary (where extensive beds of R. cirrhosa and P. pectinatus were present) and revealed the influence of submerged macrophyte material in the diet of fishes in the latter system. However, it was apparent that these plants are not directly consumed but rather contribute to the detrital pool that forms a food source for most invertebrate and some fish species. The most significant source of carbon for East Kleinemonde fishes during the macrophyte senescent phase appeared to have a more depleted origin; probably from benthic or pelagic microalgae. In conclusion, while the importance of macrophyte beds as shelter and foraging habitats for estuarine fishes are well documented, their role in terms of the structuring and functioning of fish assemblages in TOCEs remains somewhat uncertain. The findings of this study were possibly masked by the resilience of vegetation-associated species to the loss of this habitat, as well as by life history characteristics of species such as R. holubi that allow their numerical dominance despite habitat change. Nonetheless, macrophyte senescence in the East Kleinemonde Estuary resulted in the loss of at least one species and the reduced abundance of vegetation-associated species, probably reflective of reduced food resources and/or increased vulnerability to predation. As a result, beds of submerged macrophytes are an important habitat within TOCEs.
- Full Text:
- Date Issued: 2010
- Authors: Sheppard, Jill Nicole
- Date: 2010
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5321 , http://hdl.handle.net/10962/d1005166 , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: Temporarily open/closed estuaries (TOCEs) are the dominant estuary type in South Africa. These systems are often characterized by extensive beds of submerged macrophytes, which form important foraging and shelter habitats for fishes, especially for estuary-dependent fish species such as the Cape stumpnose Rhabdosargus holubi and Cape moony Monodactylus falciformis that are commonly associated with them. A loss of submerged macrophytes from an estuary has been shown to affect the fish community as well as reducing overall system productivity. The TOC East Kleinemonde Estuary, situated in the warm-temperate biogeographic region of South Africa has been subject to an ongoing long-term fish monitoring project since 1995. During the period 1995 to 2002, this estuary contained large beds of the submerged macrophytes Ruppia cirrhosa and Potamogeton pectinatus. However, subsequent to a major flood event in 2003 these macrophytes have been largely absent from this system. The effect of the loss of submerged macrophytes on the East Kleinemonde fish assemblage was investigated through an analysis of seine and gill net catch data. Seine net catches for a 12 year period, encompassing six years of macrophyte presence and six years of macrophyte senescence, revealed changes in the relative abundance of certain fish species. Vegetation-associated species such as R. holubi and M. falciformis decreased in abundance whereas sediment-associated species, especially members of the family Mugilidae, increased in abundance following loss of the macrophytes in this estuary. The critically endangered pipefish Syngnathus watermeyeri was only recorded in catches during years in which macrophyte beds were present. In addition to the analysis of catch data, the importance of macrophytes as a primary energy source for selected estuarine fishes was explored through the analysis of carbon and nitrogen stable isotopes. Prior to conducting these analyses, common methodological practices to address the presence of carbonates and lipids within isotope samples were evaluated. A subset of samples were either acid washed to remove carbonates, or lipids were removed according to the method of Bligh and Dyer (1959) as both of these compounds have been shown to affect stable carbon and nitrogen isotope ratios. The suitability of the lipid normalization models of Fry (2002) and Post et al. (2007) for samples of estuarine fish muscle were also tested. Based on this evaluation both models are suitable for use with estuarine fish muscle tissue, however since neither carbonate nor lipid content of any of the samples used in this study was high all samples were left untreated in the following analysis. Carbon isotope ratios from a wide range of fish species collected from the East Kleinemonde Estuary during the macrophyte-senescent phase were compared with individuals of the same species from the neighbouring West Kleinemonde Estuary (where extensive beds of R. cirrhosa and P. pectinatus were present) and revealed the influence of submerged macrophyte material in the diet of fishes in the latter system. However, it was apparent that these plants are not directly consumed but rather contribute to the detrital pool that forms a food source for most invertebrate and some fish species. The most significant source of carbon for East Kleinemonde fishes during the macrophyte senescent phase appeared to have a more depleted origin; probably from benthic or pelagic microalgae. In conclusion, while the importance of macrophyte beds as shelter and foraging habitats for estuarine fishes are well documented, their role in terms of the structuring and functioning of fish assemblages in TOCEs remains somewhat uncertain. The findings of this study were possibly masked by the resilience of vegetation-associated species to the loss of this habitat, as well as by life history characteristics of species such as R. holubi that allow their numerical dominance despite habitat change. Nonetheless, macrophyte senescence in the East Kleinemonde Estuary resulted in the loss of at least one species and the reduced abundance of vegetation-associated species, probably reflective of reduced food resources and/or increased vulnerability to predation. As a result, beds of submerged macrophytes are an important habitat within TOCEs.
- Full Text:
- Date Issued: 2010
Participatory human development in post-apartheid South Africa: a discussion of the 2006/7 Tantyi Youth Empowerment Project
- Authors: Kulundu, Injairu M
- Date: 2010
- Subjects: Spirals Trust (South Africa) Community development -- South Africa -- Citizen participation Economic development projects -- South Africa -- Citizen participation Youth in development -- South Africa Non-governmental organizations -- South Africa Post-apartheid era -- South Africa South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2791 , http://hdl.handle.net/10962/d1003001
- Description: This thesis relates the work of a non-governmental organisation, The Spirals Trust, to discussions on human and participatory development. The focus of the study is one of The Spirals Trust’s projects, the 2006/7 Tantyi Youth Empowerment Project, which is discussed in relation to theoretical material on human development and participatory development. Collectively these perspectives are defined in this thesis as ‘participatory human development’. The 2006/7 Tantyi Youth Empowerment Project illustrates some of the challenges that face the practice of participatory human development. Workshops and focus group interviews were conducted with participants who were part of the 2006/7 Tantyi Youth Empowerment Project in order to draw out their experiences of the project. Questions were created from themes that emerged from the participants’ discussion of their experiences and these questions were then posed to members of staff of The Spirals Trust. The experiences of both the participants and the staff members are discussed in order to explore issues that emerge in the practice of participatory human development in the 2006/7 Tantyi Youth Empowerment Project. The results highlight the challenges of putting into action the tenets of participatory human development. Feedback showed that a focus on personal development can help cultivate the ethic of participation. The effort that this entailed on the part of facilitators is discussed. The importance of exposing and continually working with power dynamics that may emerge in projects of this nature is revealed and the eroding influence of bureaucratic compliance in projects like this one is explored. The study also suggests that there is a need to promote development initiatives that challenge the political status quo rather than just finding ways to incorporate the marginalised more effectively into current systems. New questions that the research poses to the practice of participatory human development are considered in conjunction with suggestions for further research.
- Full Text:
- Date Issued: 2010
- Authors: Kulundu, Injairu M
- Date: 2010
- Subjects: Spirals Trust (South Africa) Community development -- South Africa -- Citizen participation Economic development projects -- South Africa -- Citizen participation Youth in development -- South Africa Non-governmental organizations -- South Africa Post-apartheid era -- South Africa South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2791 , http://hdl.handle.net/10962/d1003001
- Description: This thesis relates the work of a non-governmental organisation, The Spirals Trust, to discussions on human and participatory development. The focus of the study is one of The Spirals Trust’s projects, the 2006/7 Tantyi Youth Empowerment Project, which is discussed in relation to theoretical material on human development and participatory development. Collectively these perspectives are defined in this thesis as ‘participatory human development’. The 2006/7 Tantyi Youth Empowerment Project illustrates some of the challenges that face the practice of participatory human development. Workshops and focus group interviews were conducted with participants who were part of the 2006/7 Tantyi Youth Empowerment Project in order to draw out their experiences of the project. Questions were created from themes that emerged from the participants’ discussion of their experiences and these questions were then posed to members of staff of The Spirals Trust. The experiences of both the participants and the staff members are discussed in order to explore issues that emerge in the practice of participatory human development in the 2006/7 Tantyi Youth Empowerment Project. The results highlight the challenges of putting into action the tenets of participatory human development. Feedback showed that a focus on personal development can help cultivate the ethic of participation. The effort that this entailed on the part of facilitators is discussed. The importance of exposing and continually working with power dynamics that may emerge in projects of this nature is revealed and the eroding influence of bureaucratic compliance in projects like this one is explored. The study also suggests that there is a need to promote development initiatives that challenge the political status quo rather than just finding ways to incorporate the marginalised more effectively into current systems. New questions that the research poses to the practice of participatory human development are considered in conjunction with suggestions for further research.
- Full Text:
- Date Issued: 2010
The isolation of muscle activity and ground reaction force patterns associated with postural control in four load manipulation tasks
- Authors: Pettengell, Clare Louise
- Date: 2010
- Subjects: Physical fitness , Exercise , Materials handling , Manual work , Lifting and carrying
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5125 , http://hdl.handle.net/10962/d1005203 , Physical fitness , Exercise , Materials handling , Manual work , Lifting and carrying
- Description: Although much effort has been placed into the reduction of risks associated with manual materials handling, risk of musculoskeletal disorder development remains high. This may be due to the additional muscle activity necessary for the maintenance of postural equilibrium during work tasks. This research proposes that postural control and subsequent additional muscle activity is influenced by the magnitude of the external load and the degree of body movement. The objective of this research was to identify whether performing tasks with increased external load and with a greater degree of trunk motion places additional strain on the musculoskeletal system in excess of that imposed by task demands. Twenty-four male and twenty-four female subjects performed four load manipulation tasks under three loading conditions (0.8kg, 1.6kg, and 4kg). Each task comprised of a static and dynamic condition. For the static condition, subjects maintained a stipulated posture for ten seconds. The dynamic condition required subjects to move and replace a box once every three seconds, such that a complete lift and lower cycle was performed in six seconds. Throughout task completion, muscle activity of six pairs of trunk muscles were analysed using surface electromyography. This was accompanied by data regarding ground reaction forces obtained through the use of a force platform. After the completion of each condition subjects were required to identify and rate body discomfort. Differential analysis was used to isolate the muscle activity and ground reaction forces attributed to increased external load and increased trunk movement. It was found that the heaviest loading conditions (4kg) resulted in significantly greater (p<0.05) muscle activation in the majority of muscles during all tasks investigated. The trend of muscle activity attributed to load was similar in all significantly altered muscles and activation was greatest in the heaviest loading condition. A degree of movement efficiency occurred in some muscles when manipulating loads of 0.8kg and 1.6kg. At greater loads, this did not occur suggesting that heavier loading conditions result in additional strain on the body in excess of that imposed by task demands. In manipulated data, trend of vertical ground reaction forces increased with increased load in all tasks. Sagittal movement of the centre of pressure attributed to load was significantly affected in manipulated data in the second movement phase of the “hip shoulder” task and the second movement phase of the “hip twist” task. The “hip reach” task was most affected by increased load magnitude as muscle activity attributed to load was significantly different (p<0.05) under increased loading conditions in both movement phases in all muscles. Further, a significant interactional effect (p<0.05) between condition and data point was found in all muscles with the exception of the right and left lumbar erector spinae during the second movement phase of the “hip reach” task. Muscle activity associated with increased trunk motion resulted in additional strain on the trunk muscles in the “hip shoulder” and “hip reach” tasks as muscle activity associated with the static component of each of the above tasks was greater than that of the dynamic tasks. Trend of ground reaction forces attributed to increased trunk motion generally increased under increased loading conditions. Additionally, a significant interactional effect (p<0.05) between load and muscle activity pattern was found in all muscles during all tasks, with the exception of the right rectus abdominis in the first movement phase of the “hip shoulder’ task, the left rectus abdominis in the second movement phase of the “hip knee” task and the right latissimus dorsi during the first movement phase of the “hip twist” task. This was accompanied by a significant interactional effect (p<0.05) between load and sagittal centre of pressure movement attributed to load, in both movement phases of all tasks investigated. From this research it can be proposed that guidelines may underestimate risk and subsequently under predict the strain in tasks performed with greater external loads as well as tasks which require a greater degree of trunk motion. Therefore, this study illustrates the importance of the consideration of the muscle activity necessary to maintain postural equilibrium in overall load analyses.
- Full Text:
- Date Issued: 2010
- Authors: Pettengell, Clare Louise
- Date: 2010
- Subjects: Physical fitness , Exercise , Materials handling , Manual work , Lifting and carrying
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5125 , http://hdl.handle.net/10962/d1005203 , Physical fitness , Exercise , Materials handling , Manual work , Lifting and carrying
- Description: Although much effort has been placed into the reduction of risks associated with manual materials handling, risk of musculoskeletal disorder development remains high. This may be due to the additional muscle activity necessary for the maintenance of postural equilibrium during work tasks. This research proposes that postural control and subsequent additional muscle activity is influenced by the magnitude of the external load and the degree of body movement. The objective of this research was to identify whether performing tasks with increased external load and with a greater degree of trunk motion places additional strain on the musculoskeletal system in excess of that imposed by task demands. Twenty-four male and twenty-four female subjects performed four load manipulation tasks under three loading conditions (0.8kg, 1.6kg, and 4kg). Each task comprised of a static and dynamic condition. For the static condition, subjects maintained a stipulated posture for ten seconds. The dynamic condition required subjects to move and replace a box once every three seconds, such that a complete lift and lower cycle was performed in six seconds. Throughout task completion, muscle activity of six pairs of trunk muscles were analysed using surface electromyography. This was accompanied by data regarding ground reaction forces obtained through the use of a force platform. After the completion of each condition subjects were required to identify and rate body discomfort. Differential analysis was used to isolate the muscle activity and ground reaction forces attributed to increased external load and increased trunk movement. It was found that the heaviest loading conditions (4kg) resulted in significantly greater (p<0.05) muscle activation in the majority of muscles during all tasks investigated. The trend of muscle activity attributed to load was similar in all significantly altered muscles and activation was greatest in the heaviest loading condition. A degree of movement efficiency occurred in some muscles when manipulating loads of 0.8kg and 1.6kg. At greater loads, this did not occur suggesting that heavier loading conditions result in additional strain on the body in excess of that imposed by task demands. In manipulated data, trend of vertical ground reaction forces increased with increased load in all tasks. Sagittal movement of the centre of pressure attributed to load was significantly affected in manipulated data in the second movement phase of the “hip shoulder” task and the second movement phase of the “hip twist” task. The “hip reach” task was most affected by increased load magnitude as muscle activity attributed to load was significantly different (p<0.05) under increased loading conditions in both movement phases in all muscles. Further, a significant interactional effect (p<0.05) between condition and data point was found in all muscles with the exception of the right and left lumbar erector spinae during the second movement phase of the “hip reach” task. Muscle activity associated with increased trunk motion resulted in additional strain on the trunk muscles in the “hip shoulder” and “hip reach” tasks as muscle activity associated with the static component of each of the above tasks was greater than that of the dynamic tasks. Trend of ground reaction forces attributed to increased trunk motion generally increased under increased loading conditions. Additionally, a significant interactional effect (p<0.05) between load and muscle activity pattern was found in all muscles during all tasks, with the exception of the right rectus abdominis in the first movement phase of the “hip shoulder’ task, the left rectus abdominis in the second movement phase of the “hip knee” task and the right latissimus dorsi during the first movement phase of the “hip twist” task. This was accompanied by a significant interactional effect (p<0.05) between load and sagittal centre of pressure movement attributed to load, in both movement phases of all tasks investigated. From this research it can be proposed that guidelines may underestimate risk and subsequently under predict the strain in tasks performed with greater external loads as well as tasks which require a greater degree of trunk motion. Therefore, this study illustrates the importance of the consideration of the muscle activity necessary to maintain postural equilibrium in overall load analyses.
- Full Text:
- Date Issued: 2010
An investigation of principals' perceptions and experiences of the implementation of the national standards and performance indicators (NSPI) for Namibian schools in the Ohangwena region
- Authors: Johannes, Thomas Kamusheefa
- Date: 2010
- Subjects: Professional education -- Namibia Educational change -- Namibia Education -- Namibia Education and state -- Namibia School management and organization -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1640 , http://hdl.handle.net/10962/d1003522
- Description: The post independence Namibian education system has been characterised by many reform initiatives, aimed at eradicating inequity, poor performance, and inferior education provision inherited from a pre-independence education system. This legacy posed a serious challenge to Namibia when it set out to achieve a national goal, Vision 2030. Vision 2030 inspires Namibia to be among the eveloped countries in 2030. In an attempt to achieve the goals outlined by the mission statement of Vision 2030, the Ministry of Education (MoE) introduced two national education initiatives: the Education and Training Sector Improvement Program (ETSIP), and the National Standards and Performance Indicators (NSPIs). These would be implemented in Namibian schools as, respectively, the Ministry’s strategic plan and its policy document. The NSPIs were introduced to address the fragmentation of standards and inequity in regions and schools in Namibia, as they aimed to standardise the provision of equal, quality education across the country (Namibia. MoE, 2005a, p. 1). The NSPI policy calls for schools to take quality assurance seriously, with particular emphasis on School Self-Evaluation (SSE), a process that encourages self-management (Namibia. MoE, 2007a, p. 3). Thus, the standards set out by the NSPIs became the yardstick by which internal and external school evaluators could assess whole school performance. The purpose of this present study was to investigate the perceptions and experiences of principals in the Ohangwena Region following the implementation of the NSPIs. It is a case study involving two Inspectors of Education (IoEs), twelve principals, and four Heads of Department (HODs). Interviews, document analysis, questionnaires, and a focus group interview were used to collect the data. The study found that principals acknowledge the importance of the NSPIs, and believe that they would succeed in improving the provision of quality education if they were fully implemented. The study found that schools implemented Performance Indicators 5.3 (School Administration) Aspect 5.3.2 (Storage and retrieval of information) in Key Area 5. However, the results of the study also showed that principals experienced many challenges in the implementation of the NSPIs. These included a lack of understanding among principals and teachers of the NSPIs, a lack of understanding of contemporary leadership theories (that would otherwise help principals to implement change effectively), and a lack of support in terms of skills and resources from both the Regional Office in Ohangwena and the MoE itself. The study found that the NSPIs have not yet improved school performance, and consequently that the pass rate remains the same as before the introduction of the NSPIs, four years ago. The SSE, which aims to help schools identify their strengths and weaknesses, and encourages them to establish and make use of a School Development Plan (SDP) to address weaknesses and sustain strengths, is characterised by a high degree of dishonesty. Thus, the information furnished by SSEs, SDPs, and Teachers Self-Evaluations (TSEs) is unreliable, lacks credibility, and has the further ill-effect of skewing schools’ performance targets. Therefore, this problem could be addressed when the rationale of completing the SSE is clearly explained to principals and teachers.
- Full Text:
- Date Issued: 2010
- Authors: Johannes, Thomas Kamusheefa
- Date: 2010
- Subjects: Professional education -- Namibia Educational change -- Namibia Education -- Namibia Education and state -- Namibia School management and organization -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1640 , http://hdl.handle.net/10962/d1003522
- Description: The post independence Namibian education system has been characterised by many reform initiatives, aimed at eradicating inequity, poor performance, and inferior education provision inherited from a pre-independence education system. This legacy posed a serious challenge to Namibia when it set out to achieve a national goal, Vision 2030. Vision 2030 inspires Namibia to be among the eveloped countries in 2030. In an attempt to achieve the goals outlined by the mission statement of Vision 2030, the Ministry of Education (MoE) introduced two national education initiatives: the Education and Training Sector Improvement Program (ETSIP), and the National Standards and Performance Indicators (NSPIs). These would be implemented in Namibian schools as, respectively, the Ministry’s strategic plan and its policy document. The NSPIs were introduced to address the fragmentation of standards and inequity in regions and schools in Namibia, as they aimed to standardise the provision of equal, quality education across the country (Namibia. MoE, 2005a, p. 1). The NSPI policy calls for schools to take quality assurance seriously, with particular emphasis on School Self-Evaluation (SSE), a process that encourages self-management (Namibia. MoE, 2007a, p. 3). Thus, the standards set out by the NSPIs became the yardstick by which internal and external school evaluators could assess whole school performance. The purpose of this present study was to investigate the perceptions and experiences of principals in the Ohangwena Region following the implementation of the NSPIs. It is a case study involving two Inspectors of Education (IoEs), twelve principals, and four Heads of Department (HODs). Interviews, document analysis, questionnaires, and a focus group interview were used to collect the data. The study found that principals acknowledge the importance of the NSPIs, and believe that they would succeed in improving the provision of quality education if they were fully implemented. The study found that schools implemented Performance Indicators 5.3 (School Administration) Aspect 5.3.2 (Storage and retrieval of information) in Key Area 5. However, the results of the study also showed that principals experienced many challenges in the implementation of the NSPIs. These included a lack of understanding among principals and teachers of the NSPIs, a lack of understanding of contemporary leadership theories (that would otherwise help principals to implement change effectively), and a lack of support in terms of skills and resources from both the Regional Office in Ohangwena and the MoE itself. The study found that the NSPIs have not yet improved school performance, and consequently that the pass rate remains the same as before the introduction of the NSPIs, four years ago. The SSE, which aims to help schools identify their strengths and weaknesses, and encourages them to establish and make use of a School Development Plan (SDP) to address weaknesses and sustain strengths, is characterised by a high degree of dishonesty. Thus, the information furnished by SSEs, SDPs, and Teachers Self-Evaluations (TSEs) is unreliable, lacks credibility, and has the further ill-effect of skewing schools’ performance targets. Therefore, this problem could be addressed when the rationale of completing the SSE is clearly explained to principals and teachers.
- Full Text:
- Date Issued: 2010
The ichthyofauna and piscivorous avifauna in a small temporarily open/closed Eastern Cape estuary, South Africa
- Authors: Blake, Justin David
- Date: 2010
- Subjects: Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5709 , http://hdl.handle.net/10962/d1005395 , Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Description: The spatial and temporal patterns in selected components of the ichthyofauna and piscivorous avifauna in the small temporarily open/closed Riet River Estuary located on the eastern seaboard of southern Africa was investigated monthly over the period August 2005 to July 2006. The ichthyofauna within the littoral zone of the estuary was sampled using a 5 m seine net (8 stations) while a 30 m seine net (4 stations) was employed to sample the fish in the channel. Bird counts were made along repeat transects along the length of the estuary. Total ichthyofaunal abundances and biomass ranged between 1.60 and 8.67 individuals m⁻² and 0.45 to 21.76 g wwt m⁻² within the littoral zone, and between 0.08 and 0.44 individuals m⁻² and 0.58 and 36.52 g wwt m⁻² in the channel of the estuary. The highest values were generally recorded during the summer months. Results of the numerical analysis indicated that the breaching events recorded over the study period did not lead to a common trend in the ichthyofaunal community. In the absence of a link to the marine environment, the ichthyofaunal community in the littoral zone was numerically dominated by the estuarine resident species, Gilchristella aestuaria and to a lesser extent by Glossogobius callidus, which collectively accounted for ca. 54% of the total ichthyofauna sampled. The establishment of a link to the marine environment coincided with increased numbers of marine breeding species including Atherina breviceps and Rhabdosargus holubi to total fish counts within the estuary. Hierarchical cluster analysis did not identify any spatial patterns in the community structure of the ichthyofauna in the littoral zone or channel zone of the estuary, which could likely be linked to the absence of any distinct horizontal patterns in salinity and temperature within the system. A total of thirteen piscivorous bird species was recorded over the study period. Of the recorded species, six species were wading piscivores, four species were aerial divers and the remaining three species were pursuit swimmers. There were no significant correlations between the estimates of the ichthyofaunal abundance and biomass and bird numbers evident during the study (P> 0.05 in both cases). The Reed Cormorant (Phalacrocorax africanus) was the dominant species throughout the study, with a mean of 8.25 (SD ± 7.90) individuals per count. Mean values of the Pied Kingfisher (Ceryle rudis) and Giant Kingfisher (Megaceryle maximus) were 3.42 (SD ± 1.20) and 1.17 (SD ± 0.60) individuals per count, respectively. The remaining species revealed mean values < 0.5 individuals per count. The highest bird numbers were recorded in winter reflecting the migration of large numbers of the Reed Cormorant into the system. Breaching events were associated with a decrease in total bird numbers, which was most likely due to loss of potential foraging habitat (littoral zone) for waders resulting from reduced water levels. Monthly food consumption by all piscivorous birds revealed large temporal variability, ranging from 26.35 to 140.58 kg per month. The observed variability could be linked to mouth phase and bird numbers.
- Full Text:
- Date Issued: 2010
- Authors: Blake, Justin David
- Date: 2010
- Subjects: Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5709 , http://hdl.handle.net/10962/d1005395 , Estuarine fishes -- South Africa -- Eastern Cape , Bird populations -- South Africa -- Riet River Estuary , Estuaries -- South Africa -- Eastern Cape , Fish populations -- South Africa -- Riet River Estuary , Estuarine animals -- South Africa -- Riet River Estuary , Birds -- South Africa -- Riet River Estuary , Riet River Estuary (South Africa)
- Description: The spatial and temporal patterns in selected components of the ichthyofauna and piscivorous avifauna in the small temporarily open/closed Riet River Estuary located on the eastern seaboard of southern Africa was investigated monthly over the period August 2005 to July 2006. The ichthyofauna within the littoral zone of the estuary was sampled using a 5 m seine net (8 stations) while a 30 m seine net (4 stations) was employed to sample the fish in the channel. Bird counts were made along repeat transects along the length of the estuary. Total ichthyofaunal abundances and biomass ranged between 1.60 and 8.67 individuals m⁻² and 0.45 to 21.76 g wwt m⁻² within the littoral zone, and between 0.08 and 0.44 individuals m⁻² and 0.58 and 36.52 g wwt m⁻² in the channel of the estuary. The highest values were generally recorded during the summer months. Results of the numerical analysis indicated that the breaching events recorded over the study period did not lead to a common trend in the ichthyofaunal community. In the absence of a link to the marine environment, the ichthyofaunal community in the littoral zone was numerically dominated by the estuarine resident species, Gilchristella aestuaria and to a lesser extent by Glossogobius callidus, which collectively accounted for ca. 54% of the total ichthyofauna sampled. The establishment of a link to the marine environment coincided with increased numbers of marine breeding species including Atherina breviceps and Rhabdosargus holubi to total fish counts within the estuary. Hierarchical cluster analysis did not identify any spatial patterns in the community structure of the ichthyofauna in the littoral zone or channel zone of the estuary, which could likely be linked to the absence of any distinct horizontal patterns in salinity and temperature within the system. A total of thirteen piscivorous bird species was recorded over the study period. Of the recorded species, six species were wading piscivores, four species were aerial divers and the remaining three species were pursuit swimmers. There were no significant correlations between the estimates of the ichthyofaunal abundance and biomass and bird numbers evident during the study (P> 0.05 in both cases). The Reed Cormorant (Phalacrocorax africanus) was the dominant species throughout the study, with a mean of 8.25 (SD ± 7.90) individuals per count. Mean values of the Pied Kingfisher (Ceryle rudis) and Giant Kingfisher (Megaceryle maximus) were 3.42 (SD ± 1.20) and 1.17 (SD ± 0.60) individuals per count, respectively. The remaining species revealed mean values < 0.5 individuals per count. The highest bird numbers were recorded in winter reflecting the migration of large numbers of the Reed Cormorant into the system. Breaching events were associated with a decrease in total bird numbers, which was most likely due to loss of potential foraging habitat (littoral zone) for waders resulting from reduced water levels. Monthly food consumption by all piscivorous birds revealed large temporal variability, ranging from 26.35 to 140.58 kg per month. The observed variability could be linked to mouth phase and bird numbers.
- Full Text:
- Date Issued: 2010
The development and implementation of computer literacy terminology in isiXhosa
- Authors: Sam, Msindisi Scara
- Date: 2010
- Subjects: Xhosa language -- Data processing Computer literacy -- South Africa -- Dwesa-Cwebe Computer literacy -- South Africa -- Grahamstown Information technology -- South Africa -- Dwesa-Cwebe Information technology -- South Africa -- Grahamstown Computational linguistics -- South Africa -- Dwesa-Cwebe Computational linguistics -- South Africa -- Grahamstown Information technology -- South Africa -- Dwesa-Cwebe -- Social aspects Information technology -- South Africa -- Grahamstown -- Social aspects Digital divide -- South Africa -- Dwesa-Cwebe Communication in economic development -- South Africa -- Dwesa-Cwebe Communication in economic development -- South Africa -- Grahamstown South Africa-Norway Tertiary Education Development Programme Rhodes University. Dept. of African Languages
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3580 , http://hdl.handle.net/10962/d1002155
- Full Text:
- Date Issued: 2010
- Authors: Sam, Msindisi Scara
- Date: 2010
- Subjects: Xhosa language -- Data processing Computer literacy -- South Africa -- Dwesa-Cwebe Computer literacy -- South Africa -- Grahamstown Information technology -- South Africa -- Dwesa-Cwebe Information technology -- South Africa -- Grahamstown Computational linguistics -- South Africa -- Dwesa-Cwebe Computational linguistics -- South Africa -- Grahamstown Information technology -- South Africa -- Dwesa-Cwebe -- Social aspects Information technology -- South Africa -- Grahamstown -- Social aspects Digital divide -- South Africa -- Dwesa-Cwebe Communication in economic development -- South Africa -- Dwesa-Cwebe Communication in economic development -- South Africa -- Grahamstown South Africa-Norway Tertiary Education Development Programme Rhodes University. Dept. of African Languages
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3580 , http://hdl.handle.net/10962/d1002155
- Full Text:
- Date Issued: 2010
Intertidal patterns and processes : tracking the effects of coastline topography and settlement choice across life stages of the mussels perna perna and mytilus galloprovincialis
- Von Der Meden, Charles Eric Otto
- Authors: Von Der Meden, Charles Eric Otto
- Date: 2010
- Subjects: Mexilhao mussel -- Behavior -- South Africa Mytilus galloprovincialis -- Behavior -- South Africa Perna -- Behavior -- South Africa Mussels -- Ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5721 , http://hdl.handle.net/10962/d1005407
- Description: Within landscapes, spatial heterogeneity is common and specific landscape features can influence propagule dispersal by wind or water, affecting population connectivity and dynamics. Coastline topographic features, such as bays and headlands, have a variety of biophysical effects on nearshore oceanography, larval transport, retention and supply, and the processes of larval settlement and recruitment. Although this has been demonstrated in several parts of the world, engendering a perception of a general ‘bay effect’, few studies have investigated this generality in a single experiment or region, by replicating at the level of ‘bay’. The Agulhas biogeographic region of the south coast of South Africa is a useful system within which to test for such generality. Using the intertidal mussels Mytilus galloprovincialis and Perna perna as model organisms, patterns of adult distribution were surveyed across four large ‘halfheart’ bays and intervening stretches of open coast, providing replication at the level of ‘bay’ and duplication of ecologically similar species. In support of a general, pervasive influence of bays on intertidal populations, mussel cover was found to be greater in bays than on the open coast for both species, although the effect was strongest for M. galloprovincialis. To explain this adult distribution, settlement, post-settlement mortality and recruitment were examined over 12mo at the same sites, with the prediction that rates of each would favour larger bay populations. Contrary to this, an interaction between month and bay-status was found, with greater settlement and recruitment on the open coast than in bays reflecting extreme settlement and recruitment events at 3 westerly open coast sites during summer. Re-analysis excluding these outliers, revealed the expected effect, of greater settlement and recruitment in bays. While this indicates the broad generality of the bay effect, it highlights exceptions and the need for replication in time and space when examining landscape effects. Measuring post-settlement mortality required testing small-scale settlement behaviour on established and newly deployed settler collectors. It was found that all settlers preferred collectors with biofilm, but that primary settlers avoided conspecific settlers, while secondary settlers were attracted to them. With discrepancies in settler attraction to new and established collectors accounted for, initial (over 2d) and longer-term (over 7d) post-settlement mortality rates were found to be substantial (ca 60 %) for both species. No topographic effect on p-s mortality was evident. Finally, recruit-settler, adult-recruit and interspecies correlations were examined at regional and local scales. Synergistic (or neutral) effects maintained the initial settlement pattern in recruit and adult populations regionally, but not at local scales; striking interspecies correlations suggested the influence of common regional transport processes. Ultimately, the results emphasize the importance of the direction of effects in different life stages and at different spatial scales, and the possibility that antagonistic effects may mask even strong patterns.
- Full Text:
- Date Issued: 2010
- Authors: Von Der Meden, Charles Eric Otto
- Date: 2010
- Subjects: Mexilhao mussel -- Behavior -- South Africa Mytilus galloprovincialis -- Behavior -- South Africa Perna -- Behavior -- South Africa Mussels -- Ecology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5721 , http://hdl.handle.net/10962/d1005407
- Description: Within landscapes, spatial heterogeneity is common and specific landscape features can influence propagule dispersal by wind or water, affecting population connectivity and dynamics. Coastline topographic features, such as bays and headlands, have a variety of biophysical effects on nearshore oceanography, larval transport, retention and supply, and the processes of larval settlement and recruitment. Although this has been demonstrated in several parts of the world, engendering a perception of a general ‘bay effect’, few studies have investigated this generality in a single experiment or region, by replicating at the level of ‘bay’. The Agulhas biogeographic region of the south coast of South Africa is a useful system within which to test for such generality. Using the intertidal mussels Mytilus galloprovincialis and Perna perna as model organisms, patterns of adult distribution were surveyed across four large ‘halfheart’ bays and intervening stretches of open coast, providing replication at the level of ‘bay’ and duplication of ecologically similar species. In support of a general, pervasive influence of bays on intertidal populations, mussel cover was found to be greater in bays than on the open coast for both species, although the effect was strongest for M. galloprovincialis. To explain this adult distribution, settlement, post-settlement mortality and recruitment were examined over 12mo at the same sites, with the prediction that rates of each would favour larger bay populations. Contrary to this, an interaction between month and bay-status was found, with greater settlement and recruitment on the open coast than in bays reflecting extreme settlement and recruitment events at 3 westerly open coast sites during summer. Re-analysis excluding these outliers, revealed the expected effect, of greater settlement and recruitment in bays. While this indicates the broad generality of the bay effect, it highlights exceptions and the need for replication in time and space when examining landscape effects. Measuring post-settlement mortality required testing small-scale settlement behaviour on established and newly deployed settler collectors. It was found that all settlers preferred collectors with biofilm, but that primary settlers avoided conspecific settlers, while secondary settlers were attracted to them. With discrepancies in settler attraction to new and established collectors accounted for, initial (over 2d) and longer-term (over 7d) post-settlement mortality rates were found to be substantial (ca 60 %) for both species. No topographic effect on p-s mortality was evident. Finally, recruit-settler, adult-recruit and interspecies correlations were examined at regional and local scales. Synergistic (or neutral) effects maintained the initial settlement pattern in recruit and adult populations regionally, but not at local scales; striking interspecies correlations suggested the influence of common regional transport processes. Ultimately, the results emphasize the importance of the direction of effects in different life stages and at different spatial scales, and the possibility that antagonistic effects may mask even strong patterns.
- Full Text:
- Date Issued: 2010
The role of strategic leadership in Coega Development Corporation: a case study
- Authors: Davids, Mogamad Sadiek
- Date: 2010
- Subjects: Coega Development Corporation Industrial development projects -- South Africa -- Eastern Cape -- Case studies Leadership -- South Africa -- Eastern Cape -- Case studies Strategic planning -- South Africa -- Eastern Cape -- Case studies Organizational behavior -- South Africa -- Eastern Cape -- Case studies
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:763 , http://hdl.handle.net/10962/d1003884
- Description: South Africa became a democracy after its election in April 1994. Thereafter, the country faced the daunting task of trying to fast-track economic growth and addressing social challenges. The Department of Trade and Industry was mandated by the newly elected government to spearhead economic development in order to address these challenges. Trade policy instruments such as industrial development zones formed part of government’s strategic economic instruments to achieve economic reform. The Coega Industrial Development Zone (CIDZ) near Port Elizabeth was one of many economic development zones created principally to promote export orientated manufacturing. The Coega Development Corporation (CDC) was registered as a company to develop, operate and manage the CIDZ. The literature suggests that strategic leadership is important for organizational success. Strategic leadership is described as the ability to influence others to make day-to-day voluntary decisions that enhance long-term viability while maintaining short term financial stability. Literature further suggests that strategic leaders deal with the evolution of organizations and their changing aims and transform them through their capabilities and strategic leadership roles such as being a figurehead, spokesperson, team builder, design school planner and so on. The aim of this research is to analyse the role of strategic leadership with the objectives to ascertain whether strategic leadership contributed to the success of the development of CDC, and identify possible challenges they are confronted with in the execution of their leadership duties. This research was conducted from an interpretivist perspective as the researcher attempted to develop insight into how the strategic leadership of CDC viewed and understood their role. The strategic leadership of CDC, who were the focus of this study, consisted of the executive management team of the organization, including the Chief Executive Officer (CEO). The research design was in the form of a case study of the CDC leadership, with data collected through semi-structured interviews and documents. The most prominent roles exercised by the leadership of CDC included creating a vision and strategy development and inculcating a teamwork corporate culture. Other roles identified include that of team builder, fostering innovation and developing human capital etc. A lack of stakeholder management as well as managing the culture of the organization as it expands and grows, remain critical challenges. Finally recommendations are made together with suggestions for future research.
- Full Text:
- Date Issued: 2010
- Authors: Davids, Mogamad Sadiek
- Date: 2010
- Subjects: Coega Development Corporation Industrial development projects -- South Africa -- Eastern Cape -- Case studies Leadership -- South Africa -- Eastern Cape -- Case studies Strategic planning -- South Africa -- Eastern Cape -- Case studies Organizational behavior -- South Africa -- Eastern Cape -- Case studies
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:763 , http://hdl.handle.net/10962/d1003884
- Description: South Africa became a democracy after its election in April 1994. Thereafter, the country faced the daunting task of trying to fast-track economic growth and addressing social challenges. The Department of Trade and Industry was mandated by the newly elected government to spearhead economic development in order to address these challenges. Trade policy instruments such as industrial development zones formed part of government’s strategic economic instruments to achieve economic reform. The Coega Industrial Development Zone (CIDZ) near Port Elizabeth was one of many economic development zones created principally to promote export orientated manufacturing. The Coega Development Corporation (CDC) was registered as a company to develop, operate and manage the CIDZ. The literature suggests that strategic leadership is important for organizational success. Strategic leadership is described as the ability to influence others to make day-to-day voluntary decisions that enhance long-term viability while maintaining short term financial stability. Literature further suggests that strategic leaders deal with the evolution of organizations and their changing aims and transform them through their capabilities and strategic leadership roles such as being a figurehead, spokesperson, team builder, design school planner and so on. The aim of this research is to analyse the role of strategic leadership with the objectives to ascertain whether strategic leadership contributed to the success of the development of CDC, and identify possible challenges they are confronted with in the execution of their leadership duties. This research was conducted from an interpretivist perspective as the researcher attempted to develop insight into how the strategic leadership of CDC viewed and understood their role. The strategic leadership of CDC, who were the focus of this study, consisted of the executive management team of the organization, including the Chief Executive Officer (CEO). The research design was in the form of a case study of the CDC leadership, with data collected through semi-structured interviews and documents. The most prominent roles exercised by the leadership of CDC included creating a vision and strategy development and inculcating a teamwork corporate culture. Other roles identified include that of team builder, fostering innovation and developing human capital etc. A lack of stakeholder management as well as managing the culture of the organization as it expands and grows, remain critical challenges. Finally recommendations are made together with suggestions for future research.
- Full Text:
- Date Issued: 2010
Ecology and degree of specialization of South African milkweeds with diverse pollination systems
- Authors: Coombs, Gareth
- Date: 2010
- Subjects: Milkweeds -- South Africa Milkweeds -- South Africa -- Ecology Milkweeds -- South Africa -- Pollination Allee effect Self-pollination Pollination by insects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4189 , http://hdl.handle.net/10962/d1003758
- Description: Like orchids, the complexity of flowers found in asclepiads (Asclepiadoideae, Apocynaceae) and the fact that pollen is presented as pollinaria, offers excellent opportunities to study various aspects of plant-pollinator interactions. In this thesis I investigated two broad themes: ecological aspects of the pollination biology of hymenopteran and fly-pollinated asclepiads as well as the degree of specialization to certain pollinators in these species. Colonizing plants often reproduce through self-pollination, or have highly generalized pollination systems, or both. These characteristics facilitate establishment in small founding populations and generates the prediction that reproductive success should be independent of population size in these species. Chapter one examines the pollination biology of Gomphocarpus physocarpus, an indigenous, weedy species and investigates the relationship between reproductive success and population size. In this species, there is no evidence of an Allee effect and reproductive success is not correlated with population size. In addition G. physocarpus is not capable of self-pollination, suggesting it is completely reliant on pollinators for seed set. The lack of a relationship between pollination success and population size is therefore likely explained by the generalized wasp pollination system of this species. Several milkweeds are invasive outside of their native ranges. Invasive species either need to co-opt native pollinators in order to reproduce or reduce their reliance on pollinators through having the ability to self-pollinate. Co-opting native pollinators is expected to be easier in species that have generalized pollination systems, alternatively species with specialized flower morphologies need to rely on similar functional groups of pollinators to be present within the invaded range. Chapter two investigates the pollination biology and pollination success of the invasive milkweed, Araujia sericifera, and finds that in South Africa, this species is visited mainly by native honeybees and nocturnal moths. Moths however contribute little to pollen removal, and deposition. Based on the apparent morphological mismatch between the flower of A. sericifera and native honeybees, I propose that the native pollinators of this species are likely to be larger Hymenoptera (e.g. Bumblebees). Data from a breeding system study, indicated that this species is not capable of automatic self-pollination, but could set fruit from geitonogamous self-pollinations pointing to the importance of native pollinators for successful reproduction. The pollinaria of milkweeds can accumulate on pollinators to form pollen masses large enough to physically interfere with the foraging behaviour of pollinating insects. In chapter three I describe the pollination biology of Cynanchum ellipticum and find that this species is mainly pollinated by honeybees although this species is visited by several other members of Hymenoptera, Lepidoptera and Diptera. Due to the structure of the pollinaria, these chain together relatively efficiently and frequently form large pollinarium loads on the mouthparts of honeybees. However there is little evidence that these pollinarium loads influence the foraging times of pollinators and only a few individual honeybees exhibited longer foraging times and most honeybees were unaffected by the presence of large pollinarium loads. Within the genus Cynanchum there is large variation in the gynostegium structure that may influence the pattern of pollinarium loading on pollinators as well as pollen reception as shown in chapter three. In Chapter four, the pollination biology of Cynanchum obtusifolium is examined, and like that of C. ellipticum, this species is visited by a wide diversity of pollinators but honeybees appear to be the primary pollinators. More importantly this species is shown to be andromonoecious and produces two morphologically different flower types, that may be distinguished based on differences in the gynostegium structure. These two types of flower could mainly be distinguished by the length of the anther wings. I found that flowers with short anther wings function as male flowers by only exporting- and rarely receiving pollinia. Flowers with longer anther wings function as hermaphrodite flowers and can both export and receive pollinia. The ratio of male to hermaphrodite flowers varied at different times during the flowering season, but preliminary data suggested that this was not related to levels of pollination success. The genera Stapelia and Ceropegia are well known for their intricate floral adaptations that mimic the brood and feeding substrates of pollinating flies. Despite several studies that have documented the various adaptations to fly pollination in different species, there is a lack of natural history studies documenting different flower visitors, pollen loads and long term levels of pollination success in these species. In Chapter six I document the pollination biology of Ceropegia ampliata by documenting different pollinators and quantifying average levels of pollination success and the nectar reward. I also experimentally manipulated the trapping hairs of this species to determine whether trapping hairs influence average levels of pollen export and receipt. I show that Ceropegia ampliata is pollinated by a generalist guild of flies (mainly Tachinidae, Sarcophagidae, Muscidae and Lauxaniidae) and produces minute quantities of relatively dilute nectar as a reward. Pollination success was generally low in this species and increases periodically suggesting that the abundance of pollinators is patchy. I found that flowers with trapping hairs that had already wilted had higher levels of pollinarium removal than flowers with erect hairs, however experimentally removing the hairs had no significant effect on pollen export and receipt. In Chapter seven, I document the pollinators, pollen loads and long term levels of pollination success in Stapelia hirsuta var. bayllissi, a rare sapromyiophilous stapeliad. I find that, in contrast to C. ampliata, this species was specialized to pollination by small flies of the family Anthomyiidae. Similar to the results from Chapter seven, I find that long term levels of pollination success were typically low but could increase periodically, although such increases were generally unpredictable. There are currently very few records documenting pollinator interactions in the Periplocoideae. Many species within this subfamily exhibit open-access flowers suggestive of pollination by short-tongued insects. I investigated the pollination biology of Chlorocyathus lobulata, a rare species with a highly localized distribution. I aimed to determine the pollinators, average levels of pollination success and demography of this species in order to determine whether this rare species is suffering from the collapse of a highly specialized pollinator mutualism. I also quantified the high incidence of flower herbivory caused by larvae of the moth, Bocchoris onychinalis. I find that C. lobulata has a highly generalized fly pollination system and average levels of pollination success suggested that a large proportion of flowers had pollen removed and deposited suggesting that this species is not experiencing pollination failure. The large numbers of juveniles present also indicated that recruitment is taking place.
- Full Text:
- Date Issued: 2010
- Authors: Coombs, Gareth
- Date: 2010
- Subjects: Milkweeds -- South Africa Milkweeds -- South Africa -- Ecology Milkweeds -- South Africa -- Pollination Allee effect Self-pollination Pollination by insects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4189 , http://hdl.handle.net/10962/d1003758
- Description: Like orchids, the complexity of flowers found in asclepiads (Asclepiadoideae, Apocynaceae) and the fact that pollen is presented as pollinaria, offers excellent opportunities to study various aspects of plant-pollinator interactions. In this thesis I investigated two broad themes: ecological aspects of the pollination biology of hymenopteran and fly-pollinated asclepiads as well as the degree of specialization to certain pollinators in these species. Colonizing plants often reproduce through self-pollination, or have highly generalized pollination systems, or both. These characteristics facilitate establishment in small founding populations and generates the prediction that reproductive success should be independent of population size in these species. Chapter one examines the pollination biology of Gomphocarpus physocarpus, an indigenous, weedy species and investigates the relationship between reproductive success and population size. In this species, there is no evidence of an Allee effect and reproductive success is not correlated with population size. In addition G. physocarpus is not capable of self-pollination, suggesting it is completely reliant on pollinators for seed set. The lack of a relationship between pollination success and population size is therefore likely explained by the generalized wasp pollination system of this species. Several milkweeds are invasive outside of their native ranges. Invasive species either need to co-opt native pollinators in order to reproduce or reduce their reliance on pollinators through having the ability to self-pollinate. Co-opting native pollinators is expected to be easier in species that have generalized pollination systems, alternatively species with specialized flower morphologies need to rely on similar functional groups of pollinators to be present within the invaded range. Chapter two investigates the pollination biology and pollination success of the invasive milkweed, Araujia sericifera, and finds that in South Africa, this species is visited mainly by native honeybees and nocturnal moths. Moths however contribute little to pollen removal, and deposition. Based on the apparent morphological mismatch between the flower of A. sericifera and native honeybees, I propose that the native pollinators of this species are likely to be larger Hymenoptera (e.g. Bumblebees). Data from a breeding system study, indicated that this species is not capable of automatic self-pollination, but could set fruit from geitonogamous self-pollinations pointing to the importance of native pollinators for successful reproduction. The pollinaria of milkweeds can accumulate on pollinators to form pollen masses large enough to physically interfere with the foraging behaviour of pollinating insects. In chapter three I describe the pollination biology of Cynanchum ellipticum and find that this species is mainly pollinated by honeybees although this species is visited by several other members of Hymenoptera, Lepidoptera and Diptera. Due to the structure of the pollinaria, these chain together relatively efficiently and frequently form large pollinarium loads on the mouthparts of honeybees. However there is little evidence that these pollinarium loads influence the foraging times of pollinators and only a few individual honeybees exhibited longer foraging times and most honeybees were unaffected by the presence of large pollinarium loads. Within the genus Cynanchum there is large variation in the gynostegium structure that may influence the pattern of pollinarium loading on pollinators as well as pollen reception as shown in chapter three. In Chapter four, the pollination biology of Cynanchum obtusifolium is examined, and like that of C. ellipticum, this species is visited by a wide diversity of pollinators but honeybees appear to be the primary pollinators. More importantly this species is shown to be andromonoecious and produces two morphologically different flower types, that may be distinguished based on differences in the gynostegium structure. These two types of flower could mainly be distinguished by the length of the anther wings. I found that flowers with short anther wings function as male flowers by only exporting- and rarely receiving pollinia. Flowers with longer anther wings function as hermaphrodite flowers and can both export and receive pollinia. The ratio of male to hermaphrodite flowers varied at different times during the flowering season, but preliminary data suggested that this was not related to levels of pollination success. The genera Stapelia and Ceropegia are well known for their intricate floral adaptations that mimic the brood and feeding substrates of pollinating flies. Despite several studies that have documented the various adaptations to fly pollination in different species, there is a lack of natural history studies documenting different flower visitors, pollen loads and long term levels of pollination success in these species. In Chapter six I document the pollination biology of Ceropegia ampliata by documenting different pollinators and quantifying average levels of pollination success and the nectar reward. I also experimentally manipulated the trapping hairs of this species to determine whether trapping hairs influence average levels of pollen export and receipt. I show that Ceropegia ampliata is pollinated by a generalist guild of flies (mainly Tachinidae, Sarcophagidae, Muscidae and Lauxaniidae) and produces minute quantities of relatively dilute nectar as a reward. Pollination success was generally low in this species and increases periodically suggesting that the abundance of pollinators is patchy. I found that flowers with trapping hairs that had already wilted had higher levels of pollinarium removal than flowers with erect hairs, however experimentally removing the hairs had no significant effect on pollen export and receipt. In Chapter seven, I document the pollinators, pollen loads and long term levels of pollination success in Stapelia hirsuta var. bayllissi, a rare sapromyiophilous stapeliad. I find that, in contrast to C. ampliata, this species was specialized to pollination by small flies of the family Anthomyiidae. Similar to the results from Chapter seven, I find that long term levels of pollination success were typically low but could increase periodically, although such increases were generally unpredictable. There are currently very few records documenting pollinator interactions in the Periplocoideae. Many species within this subfamily exhibit open-access flowers suggestive of pollination by short-tongued insects. I investigated the pollination biology of Chlorocyathus lobulata, a rare species with a highly localized distribution. I aimed to determine the pollinators, average levels of pollination success and demography of this species in order to determine whether this rare species is suffering from the collapse of a highly specialized pollinator mutualism. I also quantified the high incidence of flower herbivory caused by larvae of the moth, Bocchoris onychinalis. I find that C. lobulata has a highly generalized fly pollination system and average levels of pollination success suggested that a large proportion of flowers had pollen removed and deposited suggesting that this species is not experiencing pollination failure. The large numbers of juveniles present also indicated that recruitment is taking place.
- Full Text:
- Date Issued: 2010
Deliberating the Dialogues: a critical examination of the nature and purpose of a Daily Dispatch public journalism project
- Authors: Amner, Roderick John
- Date: 2010
- Subjects: Daily Dispatch (East London, South Africa) Journalism -- South Africa -- East London Citizen journalism -- South Africa -- East London
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3417 , http://hdl.handle.net/10962/d1002870
- Description: This thesis critically examines the nature and purpose of a series of four town-hall-like meetings, the Community Dialogues, held in the townships and suburbs of East London, South Africa, in 2009. They were undertaken by a mainstream, commercial newspaper, the Daily Dispatch, under the banner of the worldwide public journalism movement. Following Christians et al (2009), the thesis sets out a normative framework of media performance in a democracy, including a detailed and critical normative theory of the ‘facilitative role’ proposed and developed by Haas (2007), one of the public journalism movement’s key advocate-theorists. It also draws on a variety of theoretical frameworks and perspectives in the fields of Political Studies and Media Studies to provide an analytical overview of the complex matrix of political and media contexts – at the macro (global), meso (national) and micro (local) levels – that have helped give impetus to the Community Dialogues and also shaped their ongoing operation as a public journalism strategy in the South African context. Following a critical realist case study design, the thesis goes on to provide a narrative account of the Dialogues based on in-depth interviews exploring the motivations, self-understandings and perceptions of those journalists who originated, directed and participated in this project, as well as observation of a Community Dialogue, and an examination of some of the journalistic texts related to the Dialogues. This primary data is then critically evaluated against normative theories of press performance, especially Haas’s ‘public philosophy’ of public journalism. The thesis found that apart from their undoubted success in generating a more comprehensive and representative news agenda for the newspaper, the Dialogues often fell short of Habermas’s (1989) proceduralist-discursive notion of the ‘deliberating public’, which sees citizens share a commitment to engage in common deliberation and public problem solving. This can be attributed to a number of problems, including some important theoretical/conceptual weaknesses in the Community Dialogues’ project design, the relative immaturity of the project, the domination of civil society by political society in the South African political context, and a number of organisational constraints at the Daily Dispatch. On the other hand, the newspaper’s editorial leadership has shown clear commitment to the idea of expanding the project in the future, establishing a more a more structured programme of community engagement, and nurturing a more sustainable public sphere, including the building of a more dialectical relationship between the Dialogues and civil society.
- Full Text:
- Date Issued: 2010
- Authors: Amner, Roderick John
- Date: 2010
- Subjects: Daily Dispatch (East London, South Africa) Journalism -- South Africa -- East London Citizen journalism -- South Africa -- East London
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3417 , http://hdl.handle.net/10962/d1002870
- Description: This thesis critically examines the nature and purpose of a series of four town-hall-like meetings, the Community Dialogues, held in the townships and suburbs of East London, South Africa, in 2009. They were undertaken by a mainstream, commercial newspaper, the Daily Dispatch, under the banner of the worldwide public journalism movement. Following Christians et al (2009), the thesis sets out a normative framework of media performance in a democracy, including a detailed and critical normative theory of the ‘facilitative role’ proposed and developed by Haas (2007), one of the public journalism movement’s key advocate-theorists. It also draws on a variety of theoretical frameworks and perspectives in the fields of Political Studies and Media Studies to provide an analytical overview of the complex matrix of political and media contexts – at the macro (global), meso (national) and micro (local) levels – that have helped give impetus to the Community Dialogues and also shaped their ongoing operation as a public journalism strategy in the South African context. Following a critical realist case study design, the thesis goes on to provide a narrative account of the Dialogues based on in-depth interviews exploring the motivations, self-understandings and perceptions of those journalists who originated, directed and participated in this project, as well as observation of a Community Dialogue, and an examination of some of the journalistic texts related to the Dialogues. This primary data is then critically evaluated against normative theories of press performance, especially Haas’s ‘public philosophy’ of public journalism. The thesis found that apart from their undoubted success in generating a more comprehensive and representative news agenda for the newspaper, the Dialogues often fell short of Habermas’s (1989) proceduralist-discursive notion of the ‘deliberating public’, which sees citizens share a commitment to engage in common deliberation and public problem solving. This can be attributed to a number of problems, including some important theoretical/conceptual weaknesses in the Community Dialogues’ project design, the relative immaturity of the project, the domination of civil society by political society in the South African political context, and a number of organisational constraints at the Daily Dispatch. On the other hand, the newspaper’s editorial leadership has shown clear commitment to the idea of expanding the project in the future, establishing a more a more structured programme of community engagement, and nurturing a more sustainable public sphere, including the building of a more dialectical relationship between the Dialogues and civil society.
- Full Text:
- Date Issued: 2010
An investigation of the role of principals in promoting computer usage in selected Namibian schools
- Authors: Katulo, Mighty Masiku
- Date: 2010
- Subjects: Computers -- Study and teaching -- Namibia Educational technology -- Namibia Information technology -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1658 , http://hdl.handle.net/10962/d1003541
- Description: Globalisation and technology change have created a new global economy fuelled by information and driven by knowledge. Information and Communication Technologies (ICT) have been touted as potential powerful tools for enabling educational change and reform. Namibia is among those countries that have adopted the use of ICTs as a vehicle for change. This thesis explores the role of school principals in promoting and managing computer usage in selected schools in Namibia. The study was conducted at four schools in the Caprivi Region. The study employed a qualitative case study to collect and analyse data. A total of four school principals and four computer coordinators were interviewed, and responded to questions pertaining to the role of principals in the following areas: acquiring ICT equipment; providing access to the computer labs; promoting the use of computers; maintaining computers; capacity-building of teachers, and addressing challenges that could prevent computer usage. Two focus group interviews were also conducted at two schools, to find out what they perceived to be the role of school principals in supporting and ensuring the effective use of computers in schools. The findings on acquisition of computers reveal that principals were often the initiators of the acquisition process. Ministerial deployment is the most common form of acquisition, followed by the use of the school’s development fund to purchase administrative computers. Only one of the participating schools did not acquire its computers through Ministerial deployment. Some schools were more resourced than others. Availability and maintenance of equipment depended on the kind of school (advantaged or disadvantaged) and the way the computers were acquired rather than on the role of the principal. Schools that acquired their computers through the ministerial deployment received satisfactory technical support from the ministry while schools that acquired their computers through other sources had to rely more heavily on the principal to pro-actively seek support. School principals that demonstrated the qualities of transformational leadership promoted the usage of computers by taking part in training offered to teachers and encouraged teachers on different platforms to make use of computers. The study also found that schools in which principals actively supported and promoted the use of computers were successful in the usage of the computer labs, while in schools where principals left the running of the computer lab to an individual teacher, the usage was minimal. It was found that a number of challenges are hampering the usage. These include lack of internet connectivity, qualified personnel to cascade training, and minimum infrastructure. The study recommends that school principals should adopt trategies that encourage teachers to use computers in their daily routines. It also makes suggestions for further research on the impact of school culture on ICT integration.
- Full Text:
- Date Issued: 2010
- Authors: Katulo, Mighty Masiku
- Date: 2010
- Subjects: Computers -- Study and teaching -- Namibia Educational technology -- Namibia Information technology -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1658 , http://hdl.handle.net/10962/d1003541
- Description: Globalisation and technology change have created a new global economy fuelled by information and driven by knowledge. Information and Communication Technologies (ICT) have been touted as potential powerful tools for enabling educational change and reform. Namibia is among those countries that have adopted the use of ICTs as a vehicle for change. This thesis explores the role of school principals in promoting and managing computer usage in selected schools in Namibia. The study was conducted at four schools in the Caprivi Region. The study employed a qualitative case study to collect and analyse data. A total of four school principals and four computer coordinators were interviewed, and responded to questions pertaining to the role of principals in the following areas: acquiring ICT equipment; providing access to the computer labs; promoting the use of computers; maintaining computers; capacity-building of teachers, and addressing challenges that could prevent computer usage. Two focus group interviews were also conducted at two schools, to find out what they perceived to be the role of school principals in supporting and ensuring the effective use of computers in schools. The findings on acquisition of computers reveal that principals were often the initiators of the acquisition process. Ministerial deployment is the most common form of acquisition, followed by the use of the school’s development fund to purchase administrative computers. Only one of the participating schools did not acquire its computers through Ministerial deployment. Some schools were more resourced than others. Availability and maintenance of equipment depended on the kind of school (advantaged or disadvantaged) and the way the computers were acquired rather than on the role of the principal. Schools that acquired their computers through the ministerial deployment received satisfactory technical support from the ministry while schools that acquired their computers through other sources had to rely more heavily on the principal to pro-actively seek support. School principals that demonstrated the qualities of transformational leadership promoted the usage of computers by taking part in training offered to teachers and encouraged teachers on different platforms to make use of computers. The study also found that schools in which principals actively supported and promoted the use of computers were successful in the usage of the computer labs, while in schools where principals left the running of the computer lab to an individual teacher, the usage was minimal. It was found that a number of challenges are hampering the usage. These include lack of internet connectivity, qualified personnel to cascade training, and minimum infrastructure. The study recommends that school principals should adopt trategies that encourage teachers to use computers in their daily routines. It also makes suggestions for further research on the impact of school culture on ICT integration.
- Full Text:
- Date Issued: 2010
Take my word for it: a new approach to the problem of sincerity in the epistemology of testimony
- Authors: Dewhurst, Therese
- Date: 2010
- Subjects: Sincerity Philosophy Terminology Knowledge, Theory of Honesty
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2707 , http://hdl.handle.net/10962/d1002837
- Description: The epistemological problem of sincerity in testimony is often approached in the following way: We, as a matter of fact, accept utterances as sincere. We do so in the face of knowledge that people lie and deceive,and yet we still count these beliefs as good beliefs. Therefore there must be some reason or argument that we can cite in order to justify our acceptance of the sincerity of the speaker. In this thesis I will argue, contra this, that there is no reason, per se, that justifies our of a speakers sincerity: this is because recognition of the obligation to accept the sincerity is a necessary condition on the possibility of communication and interpretation. In the first three of the thesis I will argue against three of the main approaches to the problem by focusing on what I believe to be the strongest accounts of each: Elizabeth Fricker's reductionism, Tyler Burge's non-reductionism, and Paul Faulkner's trust account of testimony. In the final chapter I will put forward my positive account. I will argue that it is a constitutive rule of language that a speaker be sincere, and then make the further claim, that it is a constitutive rule of interpretation that the hearer take an utterance as sincere. On my account, successful communication does not just depend on a speaker making sincere utterances,but just as importantly,, on the hearer recognising an obligation to take those utterances as being sincere.
- Full Text:
- Date Issued: 2010
- Authors: Dewhurst, Therese
- Date: 2010
- Subjects: Sincerity Philosophy Terminology Knowledge, Theory of Honesty
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2707 , http://hdl.handle.net/10962/d1002837
- Description: The epistemological problem of sincerity in testimony is often approached in the following way: We, as a matter of fact, accept utterances as sincere. We do so in the face of knowledge that people lie and deceive,and yet we still count these beliefs as good beliefs. Therefore there must be some reason or argument that we can cite in order to justify our acceptance of the sincerity of the speaker. In this thesis I will argue, contra this, that there is no reason, per se, that justifies our of a speakers sincerity: this is because recognition of the obligation to accept the sincerity is a necessary condition on the possibility of communication and interpretation. In the first three of the thesis I will argue against three of the main approaches to the problem by focusing on what I believe to be the strongest accounts of each: Elizabeth Fricker's reductionism, Tyler Burge's non-reductionism, and Paul Faulkner's trust account of testimony. In the final chapter I will put forward my positive account. I will argue that it is a constitutive rule of language that a speaker be sincere, and then make the further claim, that it is a constitutive rule of interpretation that the hearer take an utterance as sincere. On my account, successful communication does not just depend on a speaker making sincere utterances,but just as importantly,, on the hearer recognising an obligation to take those utterances as being sincere.
- Full Text:
- Date Issued: 2010
Photophysiochemical studies of d¹⁰ metallophthalocyanines and their interaction with nanoparticles
- Chidawanyika, Wadzanai Janet Upenyu
- Authors: Chidawanyika, Wadzanai Janet Upenyu
- Date: 2010
- Subjects: Nanoparticles Phthalocyanines Photochemistry Electrochemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4335 , http://hdl.handle.net/10962/d1004996
- Description: The syntheses, extensive spectroscopic characterization, photophysical and photochemical studies have been conducted for a variation of d10 metallophthaloycanines (MPcs). Comparisons have been made taking into consideration the nfluence of the central metal ion, solvent properties, substituent type and position. Coordination to heavy central metals i.e. Hg gives enhanced triplet state properties. Low symmetry metallophthalocyanine complexes were similarly haracterized and the influence of nteractions with nanoparticles on their photophysical and photochemical properties determined. The MPcs have been linked and adsorbed or mixed with nanoparticles i.e. hemically functionalized single-walled carbon nanotubes SWCNT) and mercaptocarboxylic acid capped CdTe quantum dots (QDs) and changes in the spectra accounted for with respect to the proposed conjugate structures. Distinct differences ccur for linked and adsorbed or mixed conjugates in the bsorption, infrared (IR) and Raman spectra and for thermal ravimetric decay profiles, suggesting successful formation f covalent bonds (linked) and point to structurally ifferent materials. SWCNT quench MPc fluorescence by a photoinduced electron transfer mediated process to give low fluorescence quantum yields. The QDs were used as energy transfer donors and facilitate energy transfer, through Förster resonance energy transfer (FRET) from the QDs to the MPcs. Improved FRET efficiencies were found for linked MPc-QD conjugates relative to the mixed species. Photophysicochemical properties of MPcs were, in general, improved as a result of interactions with nanoparticles.
- Full Text:
- Date Issued: 2010
- Authors: Chidawanyika, Wadzanai Janet Upenyu
- Date: 2010
- Subjects: Nanoparticles Phthalocyanines Photochemistry Electrochemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4335 , http://hdl.handle.net/10962/d1004996
- Description: The syntheses, extensive spectroscopic characterization, photophysical and photochemical studies have been conducted for a variation of d10 metallophthaloycanines (MPcs). Comparisons have been made taking into consideration the nfluence of the central metal ion, solvent properties, substituent type and position. Coordination to heavy central metals i.e. Hg gives enhanced triplet state properties. Low symmetry metallophthalocyanine complexes were similarly haracterized and the influence of nteractions with nanoparticles on their photophysical and photochemical properties determined. The MPcs have been linked and adsorbed or mixed with nanoparticles i.e. hemically functionalized single-walled carbon nanotubes SWCNT) and mercaptocarboxylic acid capped CdTe quantum dots (QDs) and changes in the spectra accounted for with respect to the proposed conjugate structures. Distinct differences ccur for linked and adsorbed or mixed conjugates in the bsorption, infrared (IR) and Raman spectra and for thermal ravimetric decay profiles, suggesting successful formation f covalent bonds (linked) and point to structurally ifferent materials. SWCNT quench MPc fluorescence by a photoinduced electron transfer mediated process to give low fluorescence quantum yields. The QDs were used as energy transfer donors and facilitate energy transfer, through Förster resonance energy transfer (FRET) from the QDs to the MPcs. Improved FRET efficiencies were found for linked MPc-QD conjugates relative to the mixed species. Photophysicochemical properties of MPcs were, in general, improved as a result of interactions with nanoparticles.
- Full Text:
- Date Issued: 2010