Unitarity constraints on the ratio of shear viscosity to entropy density in higher derivative gravity
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6815 , http://hdl.handle.net/10962/d1004325
- Description: We discuss corrections to the ratio of shear viscosity to entropy density η/s in higher-derivative gravity theories. Generically, these theories contain ghost modes with Planck-scale masses. Motivated by general considerations about unitarity, we propose new boundary conditions for the equations of motion of the graviton perturbations that force the amplitude of the ghosts modes to vanish. We analyze explicitly four-derivative perturbative corrections to Einstein gravity which generically lead to four-derivative equations of motion, compare our choice of boundary conditions to previous proposals and show that, with our new prescription, the ratio η/s remains at the Einstein-gravity value of 1/4π to leading order in the corrections. It is argued that, when the new boundary conditions are imposed on six and higher-derivative equations of motion, η/s can only increase from the Einstein-gravity value. We also recall some general arguments that support the validity of our results to all orders in the strength of the corrections to Einstein gravity. We then discuss the particular case of Gauss-Bonnet gravity, for which the equations of motion are only of two-derivative order and the value of η/s can decrease below 1/4π when treated in a nonperturbative way. Our findings provide further evidence for the validity of the KSS bound for theories that can be viewed as perturbative corrections to Einstein gravity.
- Full Text:
- Date Issued: 2011
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6815 , http://hdl.handle.net/10962/d1004325
- Description: We discuss corrections to the ratio of shear viscosity to entropy density η/s in higher-derivative gravity theories. Generically, these theories contain ghost modes with Planck-scale masses. Motivated by general considerations about unitarity, we propose new boundary conditions for the equations of motion of the graviton perturbations that force the amplitude of the ghosts modes to vanish. We analyze explicitly four-derivative perturbative corrections to Einstein gravity which generically lead to four-derivative equations of motion, compare our choice of boundary conditions to previous proposals and show that, with our new prescription, the ratio η/s remains at the Einstein-gravity value of 1/4π to leading order in the corrections. It is argued that, when the new boundary conditions are imposed on six and higher-derivative equations of motion, η/s can only increase from the Einstein-gravity value. We also recall some general arguments that support the validity of our results to all orders in the strength of the corrections to Einstein gravity. We then discuss the particular case of Gauss-Bonnet gravity, for which the equations of motion are only of two-derivative order and the value of η/s can decrease below 1/4π when treated in a nonperturbative way. Our findings provide further evidence for the validity of the KSS bound for theories that can be viewed as perturbative corrections to Einstein gravity.
- Full Text:
- Date Issued: 2011
Does the growth of structure affect our dynamical models of the Universe? The averaging, backreaction, and fitting problems in cosmology
- Clarkson, C, Ellis, G, Larena, Julien, Umeh, O
- Authors: Clarkson, C , Ellis, G , Larena, Julien , Umeh, O
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6791 , http://hdl.handle.net/10962/d1006944
- Description: Structure occurs over a vast range of scales in the Universe. Our large-scale cosmological models are coarse-grained representations of what exists, which have much less structure than there really is. An important problem for cosmology is determining the influence the small-scale structure in the Universe has on its large-scale dynamics and observations. Is there a significant, general relativistic, backreaction effect from averaging over structure? One issue is whether the process of smoothing over structure can contribute to an acceleration term and so alter the apparent value of the cosmological constant. If this is not the case, are there other aspects of concordance cosmology that are affected by backreaction effects? Despite much progress, this 'averaging problem' is still unanswered, but it cannot be ignored in an era of precision cosmology, for instance it may affect aspects of baryon acoustic oscillation observations.
- Full Text:
- Date Issued: 2011
- Authors: Clarkson, C , Ellis, G , Larena, Julien , Umeh, O
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6791 , http://hdl.handle.net/10962/d1006944
- Description: Structure occurs over a vast range of scales in the Universe. Our large-scale cosmological models are coarse-grained representations of what exists, which have much less structure than there really is. An important problem for cosmology is determining the influence the small-scale structure in the Universe has on its large-scale dynamics and observations. Is there a significant, general relativistic, backreaction effect from averaging over structure? One issue is whether the process of smoothing over structure can contribute to an acceleration term and so alter the apparent value of the cosmological constant. If this is not the case, are there other aspects of concordance cosmology that are affected by backreaction effects? Despite much progress, this 'averaging problem' is still unanswered, but it cannot be ignored in an era of precision cosmology, for instance it may affect aspects of baryon acoustic oscillation observations.
- Full Text:
- Date Issued: 2011
Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone
- Idahosa, Kenudi C, Molefe, Duduzile M, Pakade, Vusumzi E, Brown, Michael E
- Authors: Idahosa, Kenudi C , Molefe, Duduzile M , Pakade, Vusumzi E , Brown, Michael E
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6574 , http://hdl.handle.net/10962/d1004137
- Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
- Full Text:
- Date Issued: 2011
- Authors: Idahosa, Kenudi C , Molefe, Duduzile M , Pakade, Vusumzi E , Brown, Michael E
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6574 , http://hdl.handle.net/10962/d1004137
- Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
- Full Text:
- Date Issued: 2011
Good Chemistry
- Authors: Grange, Helen
- Date: 2011
- Subjects: Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7185 , http://hdl.handle.net/10962/d1006276 , Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Description: Helen Grange profiles four women who've fearlessly taken on the complex predominantly male-dominated field of science.
- Full Text:
- Date Issued: 2011
- Authors: Grange, Helen
- Date: 2011
- Subjects: Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7185 , http://hdl.handle.net/10962/d1006276 , Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Description: Helen Grange profiles four women who've fearlessly taken on the complex predominantly male-dominated field of science.
- Full Text:
- Date Issued: 2011
Incorporation of Ni(II)-dimethylglyoxime ion-imprinted polymer into electrospun polysulphone nanofibre for the determination of Ni(II) ions from aqueous samples
- Rammika, M, Darko, G, Torto, N
- Authors: Rammika, M , Darko, G , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6589 , http://hdl.handle.net/10962/d1004172
- Description: Ni(II)-dimethylglyoxime ion-imprinted polymer (Ni(II)-DMG IIP) was encapsulated in polysulphone and electrospun into nanofibres with diameters ranging from 406 to 854 nm. The structures of the Ni(II)-DMG encapsulated-IIP nanofibre, non-imprinted encapsulated-polymer nanofibre and polysulphone nanofibre mats were observed by scanning electron microscopy and evaluated by infrared spectroscopy. Electrospinning increased the specific surface area of the Ni(II)-DMG encapsulated-IIP nanofibre mats, as was evidenced by the low masses of the Ni(II)-DMG encapsulated-IIP nanofibre mats used. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3); the concentration of Ni(II) obtained was close to the certified one. The limit of detection was found to be 4.0x10-4 μg∙mℓ−1 while the limit of quantification was found to be 1.2x10-3 μg∙mℓ−1. The recovery of Ni(II) achieved using the Ni(II)-DMG imprinted nanofibre mats in water samples was found to range from 83 to 89%, while that of non-imprinted nanofibre mats was found to range from 59 to 65%, and that of polysulphone from 55 to 62%.
- Full Text:
- Date Issued: 2011
- Authors: Rammika, M , Darko, G , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6589 , http://hdl.handle.net/10962/d1004172
- Description: Ni(II)-dimethylglyoxime ion-imprinted polymer (Ni(II)-DMG IIP) was encapsulated in polysulphone and electrospun into nanofibres with diameters ranging from 406 to 854 nm. The structures of the Ni(II)-DMG encapsulated-IIP nanofibre, non-imprinted encapsulated-polymer nanofibre and polysulphone nanofibre mats were observed by scanning electron microscopy and evaluated by infrared spectroscopy. Electrospinning increased the specific surface area of the Ni(II)-DMG encapsulated-IIP nanofibre mats, as was evidenced by the low masses of the Ni(II)-DMG encapsulated-IIP nanofibre mats used. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3); the concentration of Ni(II) obtained was close to the certified one. The limit of detection was found to be 4.0x10-4 μg∙mℓ−1 while the limit of quantification was found to be 1.2x10-3 μg∙mℓ−1. The recovery of Ni(II) achieved using the Ni(II)-DMG imprinted nanofibre mats in water samples was found to range from 83 to 89%, while that of non-imprinted nanofibre mats was found to range from 59 to 65%, and that of polysulphone from 55 to 62%.
- Full Text:
- Date Issued: 2011
Diverse pollination systems of the twin-spurred orchid genus Satyrium in African grasslands
- Johnson, S.D, Peter, C.I, Ellis, A.G, Boberg, E, Botes, C, Van der Niet, T
- Authors: Johnson, S.D , Peter, C.I , Ellis, A.G , Boberg, E , Botes, C , Van der Niet, T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6558 , http://hdl.handle.net/10962/d1006025 , http://dx.doi.org/10.1007/s00606-010-0411-1
- Description: The large terrestrial orchid genus Satyrium underwent evolutionary radiations in the Cape floral region and the grasslands of southern and eastern Africa. These radiations were accompanied by tremendous diversification of the unusual twin-spurred flowers that characterize the genus, but pollination data required to interpret these patterns of floral evolution have been lacking for grassland species in the genus. Here we document pollinators, nectar properties, and levels of pollination success for 11 grassland Satyrium species in southern and south-central Africa. Pollinators of these species include bees, beetles, butterflies, hawkmoths, noctuid moths, long-proboscid flies, and sunbirds. Most species appear to be specialized for pollination by one functional pollinator group. Long-proboscid fly pollination systems are reported for the first time in Satyrium (in S. macrophyllum and a high-altitude form of S. neglectum). Floral morphology, especially spur length and rostellum structure, differs markedly among plants with different pollinators, while nectar volume, concentration, and sugar composition are fairly uniform across species. Most taxa exhibited high levels of pollination success (>50% of flowers pollinated), a trend that can be attributed to the presence of nectar in the twin spurs.
- Full Text:
- Date Issued: 2011
- Authors: Johnson, S.D , Peter, C.I , Ellis, A.G , Boberg, E , Botes, C , Van der Niet, T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6558 , http://hdl.handle.net/10962/d1006025 , http://dx.doi.org/10.1007/s00606-010-0411-1
- Description: The large terrestrial orchid genus Satyrium underwent evolutionary radiations in the Cape floral region and the grasslands of southern and eastern Africa. These radiations were accompanied by tremendous diversification of the unusual twin-spurred flowers that characterize the genus, but pollination data required to interpret these patterns of floral evolution have been lacking for grassland species in the genus. Here we document pollinators, nectar properties, and levels of pollination success for 11 grassland Satyrium species in southern and south-central Africa. Pollinators of these species include bees, beetles, butterflies, hawkmoths, noctuid moths, long-proboscid flies, and sunbirds. Most species appear to be specialized for pollination by one functional pollinator group. Long-proboscid fly pollination systems are reported for the first time in Satyrium (in S. macrophyllum and a high-altitude form of S. neglectum). Floral morphology, especially spur length and rostellum structure, differs markedly among plants with different pollinators, while nectar volume, concentration, and sugar composition are fairly uniform across species. Most taxa exhibited high levels of pollination success (>50% of flowers pollinated), a trend that can be attributed to the presence of nectar in the twin spurs.
- Full Text:
- Date Issued: 2011
Dimethylglyoxime based ion-imprinted polymer for the determination of Ni(II) ions from aqueous samples
- Rammika, M, Darko, G, Tshentu, Z, Sewry, J D, Torto, N
- Authors: Rammika, M , Darko, G , Tshentu, Z , Sewry, J D , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6590 , http://hdl.handle.net/10962/d1004173
- Description: A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was synthesised by the bulk polymerisation method. The morphology of the Ni(II)-DMG IIP and non-imprinted polymer were observed by scanning electron microscopy and the chemical structures were evaluated by infrared spectroscopy. Selectivity of the Ni(II)-DMG IIP was studied by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. The studies revealed Ni(II) recoveries ranging from 93 to 100% in aqueous solutions with minimal interference from competing ions. Enrichment factors ranged from 2 to 18 with a binding capacity of 120 μg∙g−1. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). Selectivity studies confirmed that the Ni(II)-DMG IIP had very good selectivity, characterised by %RSD of less than 5%. The limits of detection and quantification were 3x10-4 μg∙mℓ−1 and 9x10-4 μg∙mℓ−1, respectively. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3) and the concentration of Ni(II) obtained was in close agreement with the certified one. The Ni(II)-DMG IIP was successfully employed to trap Ni(II) ions from a matrix of sea, river and sewage water. It is believed that the Ni(II)-DMG IIP has potential to be used as sorbent material for pre-concentration of Ni(II) ions from aqueous solutions by solid-phase extraction.
- Full Text:
- Date Issued: 2011
- Authors: Rammika, M , Darko, G , Tshentu, Z , Sewry, J D , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6590 , http://hdl.handle.net/10962/d1004173
- Description: A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was synthesised by the bulk polymerisation method. The morphology of the Ni(II)-DMG IIP and non-imprinted polymer were observed by scanning electron microscopy and the chemical structures were evaluated by infrared spectroscopy. Selectivity of the Ni(II)-DMG IIP was studied by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. The studies revealed Ni(II) recoveries ranging from 93 to 100% in aqueous solutions with minimal interference from competing ions. Enrichment factors ranged from 2 to 18 with a binding capacity of 120 μg∙g−1. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). Selectivity studies confirmed that the Ni(II)-DMG IIP had very good selectivity, characterised by %RSD of less than 5%. The limits of detection and quantification were 3x10-4 μg∙mℓ−1 and 9x10-4 μg∙mℓ−1, respectively. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3) and the concentration of Ni(II) obtained was in close agreement with the certified one. The Ni(II)-DMG IIP was successfully employed to trap Ni(II) ions from a matrix of sea, river and sewage water. It is believed that the Ni(II)-DMG IIP has potential to be used as sorbent material for pre-concentration of Ni(II) ions from aqueous solutions by solid-phase extraction.
- Full Text:
- Date Issued: 2011
Tebello Nyokong "As chemists, we are designers"
- Authors: Nolan, Cathy
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: vital:7201 , http://hdl.handle.net/10962/d1006385
- Description: What is the common thread running through denim jeans, cancer and pesticides? None springs to mind, yet when chemist Tebello Nyokong describes her fascinating research, a link begins to emerge: light. A specialist in nanochemistry, Nyokong is using laser in ways that could revolutionize not only the diagnosis and treatment of cancer but also water purification.
- Full Text:
- Date Issued: 2011
- Authors: Nolan, Cathy
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: vital:7201 , http://hdl.handle.net/10962/d1006385
- Description: What is the common thread running through denim jeans, cancer and pesticides? None springs to mind, yet when chemist Tebello Nyokong describes her fascinating research, a link begins to emerge: light. A specialist in nanochemistry, Nyokong is using laser in ways that could revolutionize not only the diagnosis and treatment of cancer but also water purification.
- Full Text:
- Date Issued: 2011
Late Quaternary environmental phases in the Eastern Cape and adjacent Plettenberg Bay-Knysna region and Little Karoo, South Africa
- Authors: Lewis, Colin A
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6712 , http://hdl.handle.net/10962/d1006749
- Description: Four major climato-environmental phases have been identified in the Eastern Cape, Plettenberg Bay-Knysna region and Little Karoo between somewhat before ~ 40 000 cal. a BP and the present: the Birnam Interstadial from before 40 000 cal. a BP until ~ 24 000 cal. a BP; the Bottelnek Stadial (apparently equating with the Last Glacial Maximum) from ~24 000 cal. a BP until before ~ 18 350 cal. a BP; the Aliwal North (apparently equating with the Late Glacial) from before ~ 18 350 cal. a BP until ~ 11 000 cal. a BP; the Dinorben (apparently equating with the Holocene) from ~ 11 000 cal. a BP until the present. The evidence for, and the characteristics of, these phases is briefly described.
- Full Text:
- Date Issued: 2011
- Authors: Lewis, Colin A
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6712 , http://hdl.handle.net/10962/d1006749
- Description: Four major climato-environmental phases have been identified in the Eastern Cape, Plettenberg Bay-Knysna region and Little Karoo between somewhat before ~ 40 000 cal. a BP and the present: the Birnam Interstadial from before 40 000 cal. a BP until ~ 24 000 cal. a BP; the Bottelnek Stadial (apparently equating with the Last Glacial Maximum) from ~24 000 cal. a BP until before ~ 18 350 cal. a BP; the Aliwal North (apparently equating with the Late Glacial) from before ~ 18 350 cal. a BP until ~ 11 000 cal. a BP; the Dinorben (apparently equating with the Holocene) from ~ 11 000 cal. a BP until the present. The evidence for, and the characteristics of, these phases is briefly described.
- Full Text:
- Date Issued: 2011
Selective removal of chromium (VI) from sulphates and other metal anions using an ion-imprinted polymer
- Pakade, V, Cukrowska, E, Darkwa, J, Torto, N, Chimuka, L
- Authors: Pakade, V , Cukrowska, E , Darkwa, J , Torto, N , Chimuka, L
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6588 , http://hdl.handle.net/10962/d1004171
- Description: A linear copolymer was prepared from 4-vinylpyridine and styrene. An ion-imprinted polymer (IIP) specific for Cr (VI) adsorption was prepared by copolymerisation of the quaternised linear copolymer (quaternised with 1,4-chlorobutane), 2-vinylpyridine functional monomer and ethylene glycol dimethacrylate (EGDMA), as the cross-linking monomer, in the presence of 1,1’-azobis(cyclohexanecarbonitrile) as initiator. Ammonium dichromate and aqueous methanol were used as a template and porogenic solvent, respectively. Leaching of the chromate template from the polymer particles was achieved with successive stirring of the ion-imprinted polymer (IIP) particles in 4 M HNO3 solutions to obtain leached materials, which were then used for selective rebinding of Cr (VI) ions from aqueous solutions. Similarly, the non-imprinted polymer/ control polymer (NIP/CP) material was also prepared under exactly the same conditions as the IIP but without the chromate anion template. Various parameters, such as solution pH, initial concentration, aqueous phase volume, sorbent dosage, contact time and leaching solution volumes, were investigated. Scanning electron microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy, BET surface area and pore size analysis were used for the characterisation of IIP (both unleached and leached) and CP materials. Optimal parameters were as follows: solution pH, 3; contact time, 120 min; eluent, 20 mℓ of 0.1 M NaOH; and sorbent amount, 125 mg. Maximum retention capacity of IIP and CP was 37.58 and 25.44 mg∙g-1, respectively. The extraction efficiencies of the IIP and CP were compared using a batch and SPE mode of extraction. In the absence of high concentrations of ions, especially sulphate ions, both CP and IIP demonstrated no differences in binding of Cr (VI), which was almost 100%. However, in the presence of high concentrations of sulphate ions, the selectivity on the CP completely collapsed. The study clearly demonstrates the suitably of the developed IIP for selective extraction of Cr (VI) in complex samples such as those from acid mine drainage. The selectivity was also compared by direct injection of the real-world sample, both spiked and non-spiked, into that obtained after IIP selective extraction. Despite the method’s very low detection limits for direct injection (below 1 μg∙ℓ-1), no Cr (VI) was obtained. However, after IIP selective extraction, spiked Cr (VI) was detected in the spiked sample.
- Full Text:
- Date Issued: 2011
- Authors: Pakade, V , Cukrowska, E , Darkwa, J , Torto, N , Chimuka, L
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6588 , http://hdl.handle.net/10962/d1004171
- Description: A linear copolymer was prepared from 4-vinylpyridine and styrene. An ion-imprinted polymer (IIP) specific for Cr (VI) adsorption was prepared by copolymerisation of the quaternised linear copolymer (quaternised with 1,4-chlorobutane), 2-vinylpyridine functional monomer and ethylene glycol dimethacrylate (EGDMA), as the cross-linking monomer, in the presence of 1,1’-azobis(cyclohexanecarbonitrile) as initiator. Ammonium dichromate and aqueous methanol were used as a template and porogenic solvent, respectively. Leaching of the chromate template from the polymer particles was achieved with successive stirring of the ion-imprinted polymer (IIP) particles in 4 M HNO3 solutions to obtain leached materials, which were then used for selective rebinding of Cr (VI) ions from aqueous solutions. Similarly, the non-imprinted polymer/ control polymer (NIP/CP) material was also prepared under exactly the same conditions as the IIP but without the chromate anion template. Various parameters, such as solution pH, initial concentration, aqueous phase volume, sorbent dosage, contact time and leaching solution volumes, were investigated. Scanning electron microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy, BET surface area and pore size analysis were used for the characterisation of IIP (both unleached and leached) and CP materials. Optimal parameters were as follows: solution pH, 3; contact time, 120 min; eluent, 20 mℓ of 0.1 M NaOH; and sorbent amount, 125 mg. Maximum retention capacity of IIP and CP was 37.58 and 25.44 mg∙g-1, respectively. The extraction efficiencies of the IIP and CP were compared using a batch and SPE mode of extraction. In the absence of high concentrations of ions, especially sulphate ions, both CP and IIP demonstrated no differences in binding of Cr (VI), which was almost 100%. However, in the presence of high concentrations of sulphate ions, the selectivity on the CP completely collapsed. The study clearly demonstrates the suitably of the developed IIP for selective extraction of Cr (VI) in complex samples such as those from acid mine drainage. The selectivity was also compared by direct injection of the real-world sample, both spiked and non-spiked, into that obtained after IIP selective extraction. Despite the method’s very low detection limits for direct injection (below 1 μg∙ℓ-1), no Cr (VI) was obtained. However, after IIP selective extraction, spiked Cr (VI) was detected in the spiked sample.
- Full Text:
- Date Issued: 2011
Ilam's Archival Revitalisation: the past five years at the International Library of African Music
- Authors: Still-Drewett, F
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6983 , http://hdl.handle.net/10962/d1006719
- Description: The International Library for African Music (ILAM) was begun in 1954 by ethnomusicologist Hugh Tracey (1903–1977). Since 2007, an active set of projects in preservation and digitisation of both sound and photographic archives have meant that this highly important archive of traditional African music has been stabilized and conserved. New outreach education projects are helping distribute the wealth of the collection back to the African people. ILAM now has a more secure future and makes seminal contributions in the fields of research, publication and education for African music. French Abstract La Bibliothèque Internationale pour la Musique Africaine (ILAM) a été établie en 1954 par l’ethnomusicologue Hugh Tracey (1903–1977). Depuis 2007, un ensemble de projets actifs dans la préservation et la numérisation des archives sonores et photographiques, a eu comme résultat que ces archives très importantes de la musique traditionnelle africaine ont été stabilisées et conservées. De nouveaux projets d’éducation et de sensibilisation aident à distribuer la richesse de cette collection à la population africaine. ILAM a maintenant un avenir plus sûr et apporte une contribution fondamentale dans les domaines de la recherche, la publication et l’enseignement de la musique africaine. German Abstract Die International Library for African Music (ILAM) wurde im Jahr 1954 durch den Musi kethnolo - gen Hugh Tracey (1903–1977) gegründet. Seit 2007 laufende Projekte zur Bestandssicherung und Digitalisierung des Schall- und Fotoarchivs helfen, dieses überaus wichtige Archiv für traditionelle afrikanische Musik zu erhalten und in seiner Existenz zu stabilisieren. Neue, nach außen wirkende Bildungsprojekte tragen dazu bei, den Reichtum der Sammlung an die afrikanische Bevölkerung zurückzugeben. Durch seine nun gesicherte Zukunft kann ILAM für die afrikanische Musik grundlegende Beiträge in Forschung, Veröffentlichung und Bildung leisten. Afrikaans Abstract Die International Library of African Music (ILAM) is in 1954 deur die etnomusikoloog, Hugh Tracey (1903–1977), gestig. Aktiewe preserverings- en digitaliseringsprojekte van beide klank- en foto-argiewe sedert 2007, het tot gevolg gehad dat hierdie hoogs belangrike argief van tradisionele Afrikamusiek gestabiliseer en bewaar kon word. Nuwe ontwikkelings-uitreikprojekte dra daartoe by dat die rykdom van hierdie versameling teruggeploeg word aan Afrika. ILAM het tans ‘n meer versekerde toekoms en lewer invloedryke bydraes op die gebied van navorsing, publikasie en opleiding in Afrikamusiek. IsiXhosa Abstract Ithala lehlabathi lomculo wase-Afrika, i- International Library for African Music (ILAM) laqalwa ngo- 1954 yingcali yomculo weentlanga ngeentlanga, uHugh Tracey (1903–1977). Ukususela ngo-2007 umsebenzi wokulondoloza nokugcina ngekhompyutha isandi seengoma kwakunye neefoto uthetha ukuba le mbali ibalulekileyo kumculo we-Afrika wemveli iqiniselwe kwaye igcinwe ngononophelo. Iiprojekti ezintsha zokolulela isandla kwabanye abantu ziyanceda ekusasazeni le ndyebo kwabo bantu isuka kubo, ama-Afrika. Ngoku i-ILAM inekamva elingagunqgiyo kwaye inegalelo elibonakalayo kuphando, upapasho nemfundo ngomculo wase-Afrika.
- Full Text:
- Date Issued: 2011
- Authors: Still-Drewett, F
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6983 , http://hdl.handle.net/10962/d1006719
- Description: The International Library for African Music (ILAM) was begun in 1954 by ethnomusicologist Hugh Tracey (1903–1977). Since 2007, an active set of projects in preservation and digitisation of both sound and photographic archives have meant that this highly important archive of traditional African music has been stabilized and conserved. New outreach education projects are helping distribute the wealth of the collection back to the African people. ILAM now has a more secure future and makes seminal contributions in the fields of research, publication and education for African music. French Abstract La Bibliothèque Internationale pour la Musique Africaine (ILAM) a été établie en 1954 par l’ethnomusicologue Hugh Tracey (1903–1977). Depuis 2007, un ensemble de projets actifs dans la préservation et la numérisation des archives sonores et photographiques, a eu comme résultat que ces archives très importantes de la musique traditionnelle africaine ont été stabilisées et conservées. De nouveaux projets d’éducation et de sensibilisation aident à distribuer la richesse de cette collection à la population africaine. ILAM a maintenant un avenir plus sûr et apporte une contribution fondamentale dans les domaines de la recherche, la publication et l’enseignement de la musique africaine. German Abstract Die International Library for African Music (ILAM) wurde im Jahr 1954 durch den Musi kethnolo - gen Hugh Tracey (1903–1977) gegründet. Seit 2007 laufende Projekte zur Bestandssicherung und Digitalisierung des Schall- und Fotoarchivs helfen, dieses überaus wichtige Archiv für traditionelle afrikanische Musik zu erhalten und in seiner Existenz zu stabilisieren. Neue, nach außen wirkende Bildungsprojekte tragen dazu bei, den Reichtum der Sammlung an die afrikanische Bevölkerung zurückzugeben. Durch seine nun gesicherte Zukunft kann ILAM für die afrikanische Musik grundlegende Beiträge in Forschung, Veröffentlichung und Bildung leisten. Afrikaans Abstract Die International Library of African Music (ILAM) is in 1954 deur die etnomusikoloog, Hugh Tracey (1903–1977), gestig. Aktiewe preserverings- en digitaliseringsprojekte van beide klank- en foto-argiewe sedert 2007, het tot gevolg gehad dat hierdie hoogs belangrike argief van tradisionele Afrikamusiek gestabiliseer en bewaar kon word. Nuwe ontwikkelings-uitreikprojekte dra daartoe by dat die rykdom van hierdie versameling teruggeploeg word aan Afrika. ILAM het tans ‘n meer versekerde toekoms en lewer invloedryke bydraes op die gebied van navorsing, publikasie en opleiding in Afrikamusiek. IsiXhosa Abstract Ithala lehlabathi lomculo wase-Afrika, i- International Library for African Music (ILAM) laqalwa ngo- 1954 yingcali yomculo weentlanga ngeentlanga, uHugh Tracey (1903–1977). Ukususela ngo-2007 umsebenzi wokulondoloza nokugcina ngekhompyutha isandi seengoma kwakunye neefoto uthetha ukuba le mbali ibalulekileyo kumculo we-Afrika wemveli iqiniselwe kwaye igcinwe ngononophelo. Iiprojekti ezintsha zokolulela isandla kwabanye abantu ziyanceda ekusasazeni le ndyebo kwabo bantu isuka kubo, ama-Afrika. Ngoku i-ILAM inekamva elingagunqgiyo kwaye inegalelo elibonakalayo kuphando, upapasho nemfundo ngomculo wase-Afrika.
- Full Text:
- Date Issued: 2011
Designer ligands : the search for metal ion selectivity
- Authors: Kaye, P T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6576 , http://hdl.handle.net/10962/d1004139
- Description: The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
- Full Text:
- Date Issued: 2011
- Authors: Kaye, P T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6576 , http://hdl.handle.net/10962/d1004139
- Description: The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
- Full Text:
- Date Issued: 2011
I love laser : it's my guiding light
- Authors: Nolan, Cathy
- Date: 2011
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7184 , http://hdl.handle.net/10962/d1006274 , http://unesdoc.unesco.org/images/0019/001906/190645e.pdf#190680 , Nyokong, Tebello
- Description: What is the common thread that could possibly link denim jeans, cancer and pesticides? None is evident. Yet when South African chemist Tebello Nyokong describes her fascinating research, the link that emerges is light. Nyokong, a specialist in nanochemistry, loves laser, and is using it in ways that could have a revolutionary impact on medicine and the environment.
- Full Text:
- Date Issued: 2011
- Authors: Nolan, Cathy
- Date: 2011
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7184 , http://hdl.handle.net/10962/d1006274 , http://unesdoc.unesco.org/images/0019/001906/190645e.pdf#190680 , Nyokong, Tebello
- Description: What is the common thread that could possibly link denim jeans, cancer and pesticides? None is evident. Yet when South African chemist Tebello Nyokong describes her fascinating research, the link that emerges is light. Nyokong, a specialist in nanochemistry, loves laser, and is using it in ways that could have a revolutionary impact on medicine and the environment.
- Full Text:
- Date Issued: 2011
Energy versus angular momentum in black hole binaries
- Damour, T, Nagar, A, Pollney, D, Reisswig, C
- Authors: Damour, T , Nagar, A , Pollney, D , Reisswig, C
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6792 , http://hdl.handle.net/10962/d1006946
- Description: Using accurate numerical-relativity simulations of (nonspinning) black-hole binaries with mass ratios 1∶1, 2∶1, and 3∶1, we compute the gauge-invariant relation between the (reduced) binding energy E and the (reduced) angular momentum j of the system. We show that the relation E(j) is an accurate diagnostic of the dynamics of a black-hole binary in a highly relativistic regime. By comparing the numerical-relativity ENR(j) curve with the predictions of several analytic approximation schemes, we find that, while the canonically defined, nonresummed post-Newtonian–expanded EPN(j) relation exhibits large and growing deviations from ENR(j), the prediction of the effective one body formalism, based purely on known analytical results (without any calibration to numerical relativity), agrees strikingly well with the numerical-relativity results.
- Full Text:
- Date Issued: 2011
- Authors: Damour, T , Nagar, A , Pollney, D , Reisswig, C
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6792 , http://hdl.handle.net/10962/d1006946
- Description: Using accurate numerical-relativity simulations of (nonspinning) black-hole binaries with mass ratios 1∶1, 2∶1, and 3∶1, we compute the gauge-invariant relation between the (reduced) binding energy E and the (reduced) angular momentum j of the system. We show that the relation E(j) is an accurate diagnostic of the dynamics of a black-hole binary in a highly relativistic regime. By comparing the numerical-relativity ENR(j) curve with the predictions of several analytic approximation schemes, we find that, while the canonically defined, nonresummed post-Newtonian–expanded EPN(j) relation exhibits large and growing deviations from ENR(j), the prediction of the effective one body formalism, based purely on known analytical results (without any calibration to numerical relativity), agrees strikingly well with the numerical-relativity results.
- Full Text:
- Date Issued: 2011
Tebello Nyokong 'As chemists, we are designers'
- Authors: Nolan, Cathy
- Date: 2011
- Subjects: Nyokong, Tebello , L’Oreal–UNESCO Awards for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7183 , http://hdl.handle.net/10962/d1006272 , Nyokong, Tebello , L’Oreal–UNESCO Awards for Women in Science
- Description: What is the common thread running through denim jeans, cancer and pesticides? None springs to mind, yet when chemist Tebello Nyokong describes her fascinating research, a link begins to emerge: light. A specialist in nanochemistry, Nyokong is using laser in ways that could revolutionize not only the diagnosis and treatment of cancer but also water purification. Born in Lesotho, Tebello Nyokong is Professor of Medicinal Chemistry and Nanotechnology at Rhodes University in South Africa and Director of the Nanotechnology Innovation Centre for Sensors (Mintek). In 2009, she was one of the five Laureates of the 2009 L’Oreal–UNESCO Awards for Women in Science.
- Full Text:
- Date Issued: 2011
- Authors: Nolan, Cathy
- Date: 2011
- Subjects: Nyokong, Tebello , L’Oreal–UNESCO Awards for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7183 , http://hdl.handle.net/10962/d1006272 , Nyokong, Tebello , L’Oreal–UNESCO Awards for Women in Science
- Description: What is the common thread running through denim jeans, cancer and pesticides? None springs to mind, yet when chemist Tebello Nyokong describes her fascinating research, a link begins to emerge: light. A specialist in nanochemistry, Nyokong is using laser in ways that could revolutionize not only the diagnosis and treatment of cancer but also water purification. Born in Lesotho, Tebello Nyokong is Professor of Medicinal Chemistry and Nanotechnology at Rhodes University in South Africa and Director of the Nanotechnology Innovation Centre for Sensors (Mintek). In 2009, she was one of the five Laureates of the 2009 L’Oreal–UNESCO Awards for Women in Science.
- Full Text:
- Date Issued: 2011
Evaluating the Wald entropy from two-derivative terms in quadratic actions
- Brustein, R, Gorbonos, D, Hadad, M, Medved, A J M
- Authors: Brustein, R , Gorbonos, D , Hadad, M , Medved, A J M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6816 , http://hdl.handle.net/10962/d1004326
- Description: We evaluate the Wald Noether charge entropy for a black hole in generalized theories of gravity. Expanding the Lagrangian to second order in gravitational perturbations, we show that contributions to the entropy density originate only from the coefficients of two-derivative terms. The same considerations are extended to include matter fields and to show that arbitrary powers of matter fields and their symmetrized covariant derivatives cannot contribute to the entropy density. We also explain how to use the linearized gravitational field equation rather than quadratic actions to obtain the same results. Several explicit examples are presented that allow us to clarify subtle points in the derivation and application of our method.
- Full Text:
- Date Issued: 2011
- Authors: Brustein, R , Gorbonos, D , Hadad, M , Medved, A J M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6816 , http://hdl.handle.net/10962/d1004326
- Description: We evaluate the Wald Noether charge entropy for a black hole in generalized theories of gravity. Expanding the Lagrangian to second order in gravitational perturbations, we show that contributions to the entropy density originate only from the coefficients of two-derivative terms. The same considerations are extended to include matter fields and to show that arbitrary powers of matter fields and their symmetrized covariant derivatives cannot contribute to the entropy density. We also explain how to use the linearized gravitational field equation rather than quadratic actions to obtain the same results. Several explicit examples are presented that allow us to clarify subtle points in the derivation and application of our method.
- Full Text:
- Date Issued: 2011
Prof Nyokong receives another Science award
- Authors: Matiwana, Zamuxolo
- Date: 2011
- Subjects: Nyokong, Tebello , International Conference on Frontiers of Polymers and Advanced Materiel (ICFPAM)
- Language: English
- Type: Article , text
- Identifier: vital:7182 , http://hdl.handle.net/10962/d1006267 , Nyokong, Tebello
- Description: The Rhodes University professor of Medicinal Chemistry and Nanotechnology, Tebello Nyokong, says the Award for her Scientific Achievements by the International Conference on Frontiers of Polymers and Advanced Materiel (ICFPAM) is an honour, especially since it is awarded in memory of the centenary of the first Nobel Prize in Chemistry awarded to a woman: Marie Curie.
- Full Text:
- Date Issued: 2011
- Authors: Matiwana, Zamuxolo
- Date: 2011
- Subjects: Nyokong, Tebello , International Conference on Frontiers of Polymers and Advanced Materiel (ICFPAM)
- Language: English
- Type: Article , text
- Identifier: vital:7182 , http://hdl.handle.net/10962/d1006267 , Nyokong, Tebello
- Description: The Rhodes University professor of Medicinal Chemistry and Nanotechnology, Tebello Nyokong, says the Award for her Scientific Achievements by the International Conference on Frontiers of Polymers and Advanced Materiel (ICFPAM) is an honour, especially since it is awarded in memory of the centenary of the first Nobel Prize in Chemistry awarded to a woman: Marie Curie.
- Full Text:
- Date Issued: 2011
Non-perturbative unitarity constraints on the ratio of shear viscosity to entropy density in ultraviolet-complete theories with a gravity dual
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6817 , http://hdl.handle.net/10962/d1004327
- Description: We reconsider, from a novel perspective, how unitarity constrains the corrections to the ratio of shear viscosity η to entropy density s. We start with higher-derivative extensions of Einstein gravity in asymptotically anti-de Sitter spacetimes. It is assumed that these theories are derived from string theory and thus have a unitary UV completion that is dual to a unitary, UV-complete boundary gauge theory. We then propose that the gravitational perturbations about a solution of the UV-complete theory are described by an effective theory whose linearized equations of motion have at most two time derivatives. Our proposal leads to a concrete prescription for the calculation of η/s for theories of gravity with arbitrary higher-derivative corrections. The resulting ratio can take on values above or below 1/4π and is consistent with all the previous calculations, even though our reasoning is substantially different. For the purpose of calculating η/s, our proposal also leads to only two possible candidates for the effective two-derivative theory: Einstein and Gauss-Bonnet gravity. The distinction between the two is that Einstein gravity satisfies the equivalence principle, and so its graviton correlation functions are polarization-independent, whereas the Gauss-Bonnet theory has polarization-dependent correlation functions. We discuss the graviton three-point functions in this context and explain how these can provide additional information on the value of η/s.
- Full Text:
- Date Issued: 2011
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6817 , http://hdl.handle.net/10962/d1004327
- Description: We reconsider, from a novel perspective, how unitarity constrains the corrections to the ratio of shear viscosity η to entropy density s. We start with higher-derivative extensions of Einstein gravity in asymptotically anti-de Sitter spacetimes. It is assumed that these theories are derived from string theory and thus have a unitary UV completion that is dual to a unitary, UV-complete boundary gauge theory. We then propose that the gravitational perturbations about a solution of the UV-complete theory are described by an effective theory whose linearized equations of motion have at most two time derivatives. Our proposal leads to a concrete prescription for the calculation of η/s for theories of gravity with arbitrary higher-derivative corrections. The resulting ratio can take on values above or below 1/4π and is consistent with all the previous calculations, even though our reasoning is substantially different. For the purpose of calculating η/s, our proposal also leads to only two possible candidates for the effective two-derivative theory: Einstein and Gauss-Bonnet gravity. The distinction between the two is that Einstein gravity satisfies the equivalence principle, and so its graviton correlation functions are polarization-independent, whereas the Gauss-Bonnet theory has polarization-dependent correlation functions. We discuss the graviton three-point functions in this context and explain how these can provide additional information on the value of η/s.
- Full Text:
- Date Issued: 2011
A South African response to ethics in legal education
- Authors: Kruuse, Helen
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54174 , vital:26399 , https://www.routledge.com/The-Ethics-Project-in-Legal-Education/Robertson-Corbin-Tranter-Bartlett/p/book/9780415546515
- Description: The contributions in this volume suggest that "the ethics project in legal education" is increasingly an international one. Even though the strength of commitment by both the profession and the legal academy to "ethics learning" within law schools varies, two fundamental questions confront all who work in this area. First, what is it that we want our students to learn (or, perhaps, in what manner do we want our students to develop) from the teaching of "legal ethics"? Second, how can we create a learning environment that will encourage the nature and quality of learning we think is important?.
- Full Text: false
- Date Issued: 2011
- Authors: Kruuse, Helen
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54174 , vital:26399 , https://www.routledge.com/The-Ethics-Project-in-Legal-Education/Robertson-Corbin-Tranter-Bartlett/p/book/9780415546515
- Description: The contributions in this volume suggest that "the ethics project in legal education" is increasingly an international one. Even though the strength of commitment by both the profession and the legal academy to "ethics learning" within law schools varies, two fundamental questions confront all who work in this area. First, what is it that we want our students to learn (or, perhaps, in what manner do we want our students to develop) from the teaching of "legal ethics"? Second, how can we create a learning environment that will encourage the nature and quality of learning we think is important?.
- Full Text: false
- Date Issued: 2011
Evaluation of the kinetics and mechanism of drug release from Econazole nitrate nanosponge loaded Carbapol Hydrogel
- Sharma, Renuka, Walker, Roderick B, Pathak, Kamla
- Authors: Sharma, Renuka , Walker, Roderick B , Pathak, Kamla
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6437 , http://hdl.handle.net/10962/d1006614
- Description: The objective of this study was to investigate the mechanism of release of econazole nitrate (EN) nanosponges loaded hydrogel and to compare it with EN hydrogel so as to develop an extended release topical drug delivery system of EN. Nanosponges of EN were prepared using ethyl cellulose and PVA by emulsion solvent evaporation method. On the basis of pharmacotechnical evaluation nanosponges with least particle size of 230.1 nm and good rheological properties were formulated as hydrogel (F1 – F7). In vitro drug release data of EN nanosponges loaded hydrogels in phosphate buffer pH 6.8 and 7.4 when analysed by GraphPad Prism software version 4.0 San Diego, USA best fitted the Makoid-2 Banakar model (R value greater than 0.98). The Korsmeyer-Peppas release exponent (n) ranged between 0.331 – 0.418, which confirmed diffusion as the principle mechanism of drug release. The release mechanism was further confirmed by calculating the ratio of exponents A/B ratio derived from the Kopcha model.
- Full Text:
- Date Issued: 2011
- Authors: Sharma, Renuka , Walker, Roderick B , Pathak, Kamla
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6437 , http://hdl.handle.net/10962/d1006614
- Description: The objective of this study was to investigate the mechanism of release of econazole nitrate (EN) nanosponges loaded hydrogel and to compare it with EN hydrogel so as to develop an extended release topical drug delivery system of EN. Nanosponges of EN were prepared using ethyl cellulose and PVA by emulsion solvent evaporation method. On the basis of pharmacotechnical evaluation nanosponges with least particle size of 230.1 nm and good rheological properties were formulated as hydrogel (F1 – F7). In vitro drug release data of EN nanosponges loaded hydrogels in phosphate buffer pH 6.8 and 7.4 when analysed by GraphPad Prism software version 4.0 San Diego, USA best fitted the Makoid-2 Banakar model (R value greater than 0.98). The Korsmeyer-Peppas release exponent (n) ranged between 0.331 – 0.418, which confirmed diffusion as the principle mechanism of drug release. The release mechanism was further confirmed by calculating the ratio of exponents A/B ratio derived from the Kopcha model.
- Full Text:
- Date Issued: 2011