Photophysical properties of newly synthesized fluorinated zinc phthalocyanines in the presence of CdTe quantum dots and the accompanying energy transfer processes
- Erdoğmuş, Ali, Moeno, Sharon, Litwinski, Christian, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Moeno, Sharon , Litwinski, Christian , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262671 , vital:53543 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.014"
- Description: The photophysical properties of two newly synthesized phthalocyanines (Pcs) were studied in the presence and the absence of 3-mercaptopropionic acid (MPA) capped quantum dots (QDs). Energy transfer processes resulting from the combination of QDs and the Pcs: 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato)zinc(II) (TtfmMPyZnPc, 3) and 4-(tetrakis-5-(trifluoromethyl)-2-pyridyloxyphthalocyaninato) zinc(II) (TtfmPyZnPc, 4) were also studied. The photophysical properties of the Pcs in the presence of QDs were enhanced and Förster resonance energy transfer (FRET) was observed with the phthalocyanines used. The efficiency of FRET between the QDs and TtfmMPyZnPc and TtfmPyZnPc was found to be 0.31% and 0.45% in DMSO and 0.24% and 0.32% in pyridine, respectively. The triplet state quantum yields for TtfmMPyZnPc and TtfmPyZnPc were found to be 0.86 and 0.74 in DMSO and 0.83 and 0.76 in pyridine.
- Full Text:
- Authors: Erdoğmuş, Ali , Moeno, Sharon , Litwinski, Christian , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262671 , vital:53543 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.12.014"
- Description: The photophysical properties of two newly synthesized phthalocyanines (Pcs) were studied in the presence and the absence of 3-mercaptopropionic acid (MPA) capped quantum dots (QDs). Energy transfer processes resulting from the combination of QDs and the Pcs: 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato)zinc(II) (TtfmMPyZnPc, 3) and 4-(tetrakis-5-(trifluoromethyl)-2-pyridyloxyphthalocyaninato) zinc(II) (TtfmPyZnPc, 4) were also studied. The photophysical properties of the Pcs in the presence of QDs were enhanced and Förster resonance energy transfer (FRET) was observed with the phthalocyanines used. The efficiency of FRET between the QDs and TtfmMPyZnPc and TtfmPyZnPc was found to be 0.31% and 0.45% in DMSO and 0.24% and 0.32% in pyridine, respectively. The triplet state quantum yields for TtfmMPyZnPc and TtfmPyZnPc were found to be 0.86 and 0.74 in DMSO and 0.83 and 0.76 in pyridine.
- Full Text:
A research tool for analysing and monitoring the Extent to which Environmental issues are integrated into teachers’ lessons
- Authors: Nsubuga, Yvonne
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386447 , vital:68142 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122246"
- Description: South Africa enjoys strong policy support for the integration of environmental issues into school curricula. However, much doubt exists over the extent to which this has been converted into appropriate classroom practice at the majority of under-resourced rural schools in the country. This article reports on a study which piloted a research tool which can be used to analyse teachers’ lessons, with the aim of gaining insight into the extent to which they integrate natural resource management issues. The research tool was based on Bernstein’s concept of classification and consisted of five indicators of natural resource management integration into Life Sciences lessons. The study contributes to the design of research tools that can be used to analyse and monitor the integration of environmental issues into teachers’ lessons. It also provides some insight into the environmental content of a sample of Grade 10 Life Sciences lessons at four rural underresourced schools in the Eastern Cape.
- Full Text:
- Authors: Nsubuga, Yvonne
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386447 , vital:68142 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122246"
- Description: South Africa enjoys strong policy support for the integration of environmental issues into school curricula. However, much doubt exists over the extent to which this has been converted into appropriate classroom practice at the majority of under-resourced rural schools in the country. This article reports on a study which piloted a research tool which can be used to analyse teachers’ lessons, with the aim of gaining insight into the extent to which they integrate natural resource management issues. The research tool was based on Bernstein’s concept of classification and consisted of five indicators of natural resource management integration into Life Sciences lessons. The study contributes to the design of research tools that can be used to analyse and monitor the integration of environmental issues into teachers’ lessons. It also provides some insight into the environmental content of a sample of Grade 10 Life Sciences lessons at four rural underresourced schools in the Eastern Cape.
- Full Text:
The photophysical studies of Pluronic F127/P123 micelle mixture system loaded with metal free and Zn 5, 10, 15, 20-tetrakis [4-(benzyloxy) phenyl] porphyrins
- Managa, Muthumuni, Ngoy, Bokolombe P, Nyokong, Tebello
- Authors: Managa, Muthumuni , Ngoy, Bokolombe P , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188932 , vital:44799 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.02.018"
- Description: Binary mixtures of Pluronics are studied as drug nanocarriers in this work. H2 and Zn 5,10,15,20-tetrakis[4-(benzyloxy) phenyl] porphyrin were encapsulated onto binary micelle mixture of Pluronic F127/P123. The fluorescence and singlet oxygen generating behaviour of the porphyrins were investigated following incorporation. The fluorescence quantum yield for H2TBnOPP (ΦF = 0.034) was higher than that of ZnTBnOPP (ΦF = 0.023) and decreased when ZnTBnOPP or H2TBnOPP when in the presence of Pluronic F127/P123 binary mixtures. The kq values were 2.8 × 108 and 3.7 × 108 M−1 s−1, for H2TBnOPP + Pluronic F127/P123 and ZnTBnOPP + Pluronic F127/P123 in water, respectively. The binding constants (Kb) were 1.58 × 105 M−1 and 1.02 × 105 M−1 for ZnTBnOPP + Pluronic F127/P123 and H2TBnOPP + Pluronic F127/P123, respectively.
- Full Text:
- Authors: Managa, Muthumuni , Ngoy, Bokolombe P , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188932 , vital:44799 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.02.018"
- Description: Binary mixtures of Pluronics are studied as drug nanocarriers in this work. H2 and Zn 5,10,15,20-tetrakis[4-(benzyloxy) phenyl] porphyrin were encapsulated onto binary micelle mixture of Pluronic F127/P123. The fluorescence and singlet oxygen generating behaviour of the porphyrins were investigated following incorporation. The fluorescence quantum yield for H2TBnOPP (ΦF = 0.034) was higher than that of ZnTBnOPP (ΦF = 0.023) and decreased when ZnTBnOPP or H2TBnOPP when in the presence of Pluronic F127/P123 binary mixtures. The kq values were 2.8 × 108 and 3.7 × 108 M−1 s−1, for H2TBnOPP + Pluronic F127/P123 and ZnTBnOPP + Pluronic F127/P123 in water, respectively. The binding constants (Kb) were 1.58 × 105 M−1 and 1.02 × 105 M−1 for ZnTBnOPP + Pluronic F127/P123 and H2TBnOPP + Pluronic F127/P123, respectively.
- Full Text:
Effect of adding a probiotic to an aquaponic system on plant and fish growth, water quality, and microbial diversity
- Authors: Kasozi, Nasser
- Date: 2022-04-08
- Subjects: To be added
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/294596 , vital:57236
- Description: Thesis embargoed. Release date April 2023. , Thesis (PhD) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
- Authors: Kasozi, Nasser
- Date: 2022-04-08
- Subjects: To be added
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/294596 , vital:57236
- Description: Thesis embargoed. Release date April 2023. , Thesis (PhD) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
Factors constraining and enabling the adoption of a disruptive technology by African small, micro, and medium enterprises for the Fourth Industrial Revolution: The case of mobile money
- Authors: Tarr, Dillon
- Date: 2022-10-14
- Subjects: Disruptive technologies , Mobile commerce , Industry 4.0 , Small business Africa, Sub-Saharan , Diffusion of innovations Africa, Sub-Saharan , Technological innovations Management
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/357709 , vital:64770
- Description: The Fourth Industrial Revolution (4IR) is set to disrupt existing economic and social structures through the use of cyber-physical systems that result from a fusion of the digital, biological, and physical spheres. The fifth and current long wave of innovation is going through such a digital revolution in the ongoing deployment period which is being driven by the generalpurpose technologies of Artificial Intelligence and the Internet of Things, among other cyberphysical systems. The impact of mobile money in the access of financial services has shown how disruptive incremental innovations in mobile and digital technologies can be. The transformational power of mobile money in financial access is due to its use as an accessible financial tool that utilizes mobile devices to send and/or receive money over great distances. With the 4IR looming, this thesis determines the factors that enable and constrain the adoption of a disruptive technology amongst Sub-Saharan African small, micro, and medium enterprises (SMMEs). Therefore, due to its impact on financial inclusion and the formalization of SMMEs, mobile money is used as an indicator for the adoption of 4IR disruptive digital technologies. The adoption of mobile money was evaluated using secondary data from a survey conducted by Research ICT Africa, which surveyed 4408 SMMEs in nine African countries. The Diffusion of Innovations (DOI) model and the Unified Theory of Acceptance and Use of Technology (UTAUT) model were used to identify the factors enabling and constraining the adoption of a disruptive technology, in this case mobile money. Factors included gender, vocational training, business skills training, tertiary education, services, performance expectancy, social media, location, and nine African countries (Kenya, Mozambique, Ghana, Nigeria, Rwanda, South Africa, Tanzania, Uganda, and Senegal). The factors were grouped into owner characteristics, firm attributes and country attributes. SMME owners with business skills (49%) showed the highest level of adoption in terms of owner characteristics, Kenyan SMMEs (21%) had the highest adoption between the countries surveyed, and social media (62%) showed the highest adoption in terms of firm attributes followed by the formal variable (47%). In general, only 29% of SMMEs surveyed adopted mobile money. The study found that women SMME owners were more likely to be affected by business formality when adopting a disruptive technology compared to male owned SMMEs. This is because informality often exacerbates other barriers/challenges women face such as lower access to finance, lower ability to exercise property, business, and labour rights, and lower visibility. The results also demonstrate that vocational training is more important than general tertiary education for the ii adoption of a disruptive technology such as mobile money. Furthermore, when using social media as a tool for business advice SMME owners were more likely to adopt the disruptive technology. The study suggests that to encourage African SMMEs to adequately adopt disruptive technologies of the 4IR, more women owned SMMEs need to enter the formal economy, and vocational training targeted at business skills must be promoted amongst all SMME owners. Eastern African SMMEs were found to be more likely to adopt mobile money compared to other African regions. The finding demonstrates the need for more African countries (particularly outside of the Eastern African region) to encourage innovation by addressing the four enablers of mobile connectivity (i.e. infrastructure, affordability, consumer readiness, and mobile services) which will in effect lead to economic growth and development. The study shows that to address country/regional differences, in addition to building the required infrastructure in terms of mobile internet connectivity, countries should increase the local relevancy of disruptive technologies between SMMEs. To achieve this the study suggests increasing mobile social media penetration rates. This is because when social media is used as a tool for business advice SMME owners are more likely to adopt a disruptive technology (as is the case with mobile money) due to the social influence of social media. , Thesis (MCom) -- Faculty of Commerce, Economics and Economic History, 2022
- Full Text:
- Authors: Tarr, Dillon
- Date: 2022-10-14
- Subjects: Disruptive technologies , Mobile commerce , Industry 4.0 , Small business Africa, Sub-Saharan , Diffusion of innovations Africa, Sub-Saharan , Technological innovations Management
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/357709 , vital:64770
- Description: The Fourth Industrial Revolution (4IR) is set to disrupt existing economic and social structures through the use of cyber-physical systems that result from a fusion of the digital, biological, and physical spheres. The fifth and current long wave of innovation is going through such a digital revolution in the ongoing deployment period which is being driven by the generalpurpose technologies of Artificial Intelligence and the Internet of Things, among other cyberphysical systems. The impact of mobile money in the access of financial services has shown how disruptive incremental innovations in mobile and digital technologies can be. The transformational power of mobile money in financial access is due to its use as an accessible financial tool that utilizes mobile devices to send and/or receive money over great distances. With the 4IR looming, this thesis determines the factors that enable and constrain the adoption of a disruptive technology amongst Sub-Saharan African small, micro, and medium enterprises (SMMEs). Therefore, due to its impact on financial inclusion and the formalization of SMMEs, mobile money is used as an indicator for the adoption of 4IR disruptive digital technologies. The adoption of mobile money was evaluated using secondary data from a survey conducted by Research ICT Africa, which surveyed 4408 SMMEs in nine African countries. The Diffusion of Innovations (DOI) model and the Unified Theory of Acceptance and Use of Technology (UTAUT) model were used to identify the factors enabling and constraining the adoption of a disruptive technology, in this case mobile money. Factors included gender, vocational training, business skills training, tertiary education, services, performance expectancy, social media, location, and nine African countries (Kenya, Mozambique, Ghana, Nigeria, Rwanda, South Africa, Tanzania, Uganda, and Senegal). The factors were grouped into owner characteristics, firm attributes and country attributes. SMME owners with business skills (49%) showed the highest level of adoption in terms of owner characteristics, Kenyan SMMEs (21%) had the highest adoption between the countries surveyed, and social media (62%) showed the highest adoption in terms of firm attributes followed by the formal variable (47%). In general, only 29% of SMMEs surveyed adopted mobile money. The study found that women SMME owners were more likely to be affected by business formality when adopting a disruptive technology compared to male owned SMMEs. This is because informality often exacerbates other barriers/challenges women face such as lower access to finance, lower ability to exercise property, business, and labour rights, and lower visibility. The results also demonstrate that vocational training is more important than general tertiary education for the ii adoption of a disruptive technology such as mobile money. Furthermore, when using social media as a tool for business advice SMME owners were more likely to adopt the disruptive technology. The study suggests that to encourage African SMMEs to adequately adopt disruptive technologies of the 4IR, more women owned SMMEs need to enter the formal economy, and vocational training targeted at business skills must be promoted amongst all SMME owners. Eastern African SMMEs were found to be more likely to adopt mobile money compared to other African regions. The finding demonstrates the need for more African countries (particularly outside of the Eastern African region) to encourage innovation by addressing the four enablers of mobile connectivity (i.e. infrastructure, affordability, consumer readiness, and mobile services) which will in effect lead to economic growth and development. The study shows that to address country/regional differences, in addition to building the required infrastructure in terms of mobile internet connectivity, countries should increase the local relevancy of disruptive technologies between SMMEs. To achieve this the study suggests increasing mobile social media penetration rates. This is because when social media is used as a tool for business advice SMME owners are more likely to adopt a disruptive technology (as is the case with mobile money) due to the social influence of social media. , Thesis (MCom) -- Faculty of Commerce, Economics and Economic History, 2022
- Full Text:
Social upgrading or dependency?: Investigating the implications of the inclusion of commercial wine farms within South African Fairtrade certification
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
Activated carbon-decorated polyacrylonitrile fibers and their porphyrin-immobilized composites for removal of methylene blue dye and Ciprofloxacin in water
- Oyim, James, Amuhaya, Edith, Nyokong, Tebello
- Authors: Oyim, James , Amuhaya, Edith , Nyokong, Tebello
- Date: 2023
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:65077 , xlink:href="https://doi.org/10.1080/10601325.2023.2183868"
- Description: Photocatalyst adsorbents are an appealing group of materials for environmental applications. Herein, we study a new simple, inexpensive, yet very effective adsorbent photocatalyst based on porphyrin immobilized activated carbon-decorated polyacrylonitrile, InP(PAN/AC), for removal of methylene blue dye and Ciprofloxacin in water under Xe-lamp and sunlight irradiation (the latter for Ciprofloxacin only). Our results shed light on developing the most effective and sustainable adsorbent photocatalysts that can easily be industrialized due to the ease of preparation through electrospinning coupled with the readily available preparation materials. After five cycles, the InP(PAN/AC) maintained high methylene dye removal efficiency and structural integrity. Significantly, we propose the coordinated contribution of singlet oxygen and hydroxyl radical in the photodegradation process and highlight the importance of such an integrated system with adsorption and photodegradation capabilities for water treatment.
- Full Text:
- Authors: Oyim, James , Amuhaya, Edith , Nyokong, Tebello
- Date: 2023
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:65077 , xlink:href="https://doi.org/10.1080/10601325.2023.2183868"
- Description: Photocatalyst adsorbents are an appealing group of materials for environmental applications. Herein, we study a new simple, inexpensive, yet very effective adsorbent photocatalyst based on porphyrin immobilized activated carbon-decorated polyacrylonitrile, InP(PAN/AC), for removal of methylene blue dye and Ciprofloxacin in water under Xe-lamp and sunlight irradiation (the latter for Ciprofloxacin only). Our results shed light on developing the most effective and sustainable adsorbent photocatalysts that can easily be industrialized due to the ease of preparation through electrospinning coupled with the readily available preparation materials. After five cycles, the InP(PAN/AC) maintained high methylene dye removal efficiency and structural integrity. Significantly, we propose the coordinated contribution of singlet oxygen and hydroxyl radical in the photodegradation process and highlight the importance of such an integrated system with adsorption and photodegradation capabilities for water treatment.
- Full Text:
10 Years of IEASA history
- International Education Association of South Africa (IEASA), Jooste, Nico
- Authors: International Education Association of South Africa (IEASA) , Jooste, Nico
- Date: 2007
- Subjects: International Education Association of South Africa -- History , Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65356 , vital:28752 , ISBN 1920176004
- Description: [Preface - Nico Jooste]: For more than ten years, we have been involved in implementing internationalisation of South African Higher Education. The we I am referring too, are those who are both visionaries and passionately dedicated to the process of internationalisation. A small group of South African Higher Education administrators, academics and senior managers involved themselves in the process of internationalisation of their institutions, and collectively the South African system. This process of internationalisation started as an uncoordinated response to the demands of a South African higher education system that was determined to break with the past, and re-connect with global higher education, it was left to a few dedicated visionaries to create the support structure that would not only assist the higher education institutions, but also the system. The other bodies that were supposed to pay attention to this very important aspect of Higher Education in the 21st century were too busy with other, equally important, matters. It became clear that the priorities of organisations like SAUVCA were not internationalisation, and IEASA was established as the vehicle to promote it. This story of IEASA needed to be told. This book is not aimed at IEASA members only, but also at the broader higher education public. This is the story of an organisation that touched all parts of South African Higher Education society as well as the broader society. It is partly the ‘corporate memory’ of Internationalisation, as well as a reflection on achievements. Ten years looked like a short period to reflect on an organisations history, I am however of the opinion that in a society that is changing so rapidly, we need to reflect more frequently on the past so that we can plan a better future. For any historian operating in the modem era of electronic communication, access to sources of information has become a major challenge. IEASA, Thilor Manikam in particular, needs to be commended for the accurate record keeping of events over the past ten years. Kirstin Nussgruber very diligently captured the efforts of the forces driving the establishment of IEASA for the first two years. This book was mainly based on evidence gathered from minutes, reports and letters that are in the possession of the IEASA Office. I also had the privilege, and advantage, to be a member of the Executive Committee for the past five years. This book cannot be the last word on IEASA, as it is only the view of a member. The bias is thus toward IEASA and focusses mainly on its achievements. Chapter 3 focusses mainly on the achievements of a voluntary organisation. The efforts over the ten years of three persons namely. Roshen Kishun as President, Derek Swemmer as Treasurer, and Thilor Manikam as the Administrator stood out, and was the stabilising factor during the foundation years. The role of Roshen Kishun in the publication of Study South African cannot be underestimated. Without his vision, drive and effort, this publication would not be preparing for the launch of the seventh edition. It is a unique source of information about South African Higher Education. Very few other systems, if any. produce such a publication. Although the author was requested by the IEASA Executive Committee to write this book, the views expressed in this publication is not the views of the Executive Committee, but that of the author.
- Full Text:
- Authors: International Education Association of South Africa (IEASA) , Jooste, Nico
- Date: 2007
- Subjects: International Education Association of South Africa -- History , Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65356 , vital:28752 , ISBN 1920176004
- Description: [Preface - Nico Jooste]: For more than ten years, we have been involved in implementing internationalisation of South African Higher Education. The we I am referring too, are those who are both visionaries and passionately dedicated to the process of internationalisation. A small group of South African Higher Education administrators, academics and senior managers involved themselves in the process of internationalisation of their institutions, and collectively the South African system. This process of internationalisation started as an uncoordinated response to the demands of a South African higher education system that was determined to break with the past, and re-connect with global higher education, it was left to a few dedicated visionaries to create the support structure that would not only assist the higher education institutions, but also the system. The other bodies that were supposed to pay attention to this very important aspect of Higher Education in the 21st century were too busy with other, equally important, matters. It became clear that the priorities of organisations like SAUVCA were not internationalisation, and IEASA was established as the vehicle to promote it. This story of IEASA needed to be told. This book is not aimed at IEASA members only, but also at the broader higher education public. This is the story of an organisation that touched all parts of South African Higher Education society as well as the broader society. It is partly the ‘corporate memory’ of Internationalisation, as well as a reflection on achievements. Ten years looked like a short period to reflect on an organisations history, I am however of the opinion that in a society that is changing so rapidly, we need to reflect more frequently on the past so that we can plan a better future. For any historian operating in the modem era of electronic communication, access to sources of information has become a major challenge. IEASA, Thilor Manikam in particular, needs to be commended for the accurate record keeping of events over the past ten years. Kirstin Nussgruber very diligently captured the efforts of the forces driving the establishment of IEASA for the first two years. This book was mainly based on evidence gathered from minutes, reports and letters that are in the possession of the IEASA Office. I also had the privilege, and advantage, to be a member of the Executive Committee for the past five years. This book cannot be the last word on IEASA, as it is only the view of a member. The bias is thus toward IEASA and focusses mainly on its achievements. Chapter 3 focusses mainly on the achievements of a voluntary organisation. The efforts over the ten years of three persons namely. Roshen Kishun as President, Derek Swemmer as Treasurer, and Thilor Manikam as the Administrator stood out, and was the stabilising factor during the foundation years. The role of Roshen Kishun in the publication of Study South African cannot be underestimated. Without his vision, drive and effort, this publication would not be preparing for the launch of the seventh edition. It is a unique source of information about South African Higher Education. Very few other systems, if any. produce such a publication. Although the author was requested by the IEASA Executive Committee to write this book, the views expressed in this publication is not the views of the Executive Committee, but that of the author.
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Violence and destruction as an important part of artistic action with reference to the two Great Wars
- Hallier, Michael Glen Thomas
- Authors: Hallier, Michael Glen Thomas
- Date: 1971-11
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190329 , vital:44984
- Description: A well known fact about any work of art of any significance is its power to upset current conventions and disturb certain of our normal emotional patterns. The artist frequently achieves this by deliberately expressing emotions that are violent. There is nothing, however, new about the existence of violence in the arts, a large number of works in the history of art being painted with blood. One has only to think of the many battles, rapes, murders, martyrdoms and catastrophes that have been the subjects of many great paintings. Since the beginning of this century, and especially since the work of the Impressionists, in which violence is entirely excluded, violence has taken on a role of great importance and has been used to a greater or lesser extent by artists and group movements. It would appear initially that there are two main reasons in this century for the use of violence: one as a means of using it as a weapon against the academic and avant-garde in the arts, which in turn reflects attitudes found in society, and secondly as a direct reflection of the corrupt society in which we live. This is not to say that the twentieth century is an age in which more violence and sadism is found than in any other era of history, but never has it received so much publicity. I do not believe that man has change so much over the years, but it is my view that the apparent increase in this century is due to the vast changes in communications, it is due to the publicity it receives that violence has in recent times become a focal point, with murders, assassinations and war part of our daily lives. , Thesis (MFA) -- Faculty of Humanities, Fine Art, 1971
- Full Text:
- Authors: Hallier, Michael Glen Thomas
- Date: 1971-11
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190329 , vital:44984
- Description: A well known fact about any work of art of any significance is its power to upset current conventions and disturb certain of our normal emotional patterns. The artist frequently achieves this by deliberately expressing emotions that are violent. There is nothing, however, new about the existence of violence in the arts, a large number of works in the history of art being painted with blood. One has only to think of the many battles, rapes, murders, martyrdoms and catastrophes that have been the subjects of many great paintings. Since the beginning of this century, and especially since the work of the Impressionists, in which violence is entirely excluded, violence has taken on a role of great importance and has been used to a greater or lesser extent by artists and group movements. It would appear initially that there are two main reasons in this century for the use of violence: one as a means of using it as a weapon against the academic and avant-garde in the arts, which in turn reflects attitudes found in society, and secondly as a direct reflection of the corrupt society in which we live. This is not to say that the twentieth century is an age in which more violence and sadism is found than in any other era of history, but never has it received so much publicity. I do not believe that man has change so much over the years, but it is my view that the apparent increase in this century is due to the vast changes in communications, it is due to the publicity it receives that violence has in recent times become a focal point, with murders, assassinations and war part of our daily lives. , Thesis (MFA) -- Faculty of Humanities, Fine Art, 1971
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Land expropriation without compensation: a study of constructions of the Parliamentary process in selected mainstream and “ground-up” media from 27 February – 12 August 2018
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
- Full Text:
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
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Needs assessment for gender-sensitive training in substance use disorder treatment for gender-nonconforming people
- Authors: Tao, Lane
- Date: 2022-04-07
- Subjects: Discrimination in mental health services , Substance abuse Psychological aspects , Substance abuse Social aspects , Substance abuse Treatment , LGBTQ+ people Psychology , LGBTQ+ people Mental health services , Gender mainstreaming , Psychiatric ethics
- Language: English
- Type: Master's thesis , text
- Identifier: http://hdl.handle.net/10962/234339 , vital:50187
- Description: Research suggests that queer people face both general discrimination and inadequate support in substance use disorder (SUD) treatment. One recommendation made by scholarship to address this is to improve the treatment capabilities of practitioners, thus improving practitioner readiness and reducing access barriers for a potentially at-risk population. The purpose of this study is to explore SUD treatment practitioners’ experiences of treating queer clients and identify their training needs. Semi-structured interviews were conducted with seven registered mental healthcare practitioners operating in Cape Town, South Africa. Data was analysed via thematic analysis, using a social constructionist approach to gender and practitioner knowledge. The findings reflect a strong interest in gender-sensitive training to better prepare practitioners for treating queer clients. Participants provided feedback on areas in need of improvement and made recommendations on how training should be conducted. Findings indicate that queer clients may enter treatment with a high burden of trauma due to discrimination, and that healthcare structures abiding by a binary approach to gender may not be able to address queer people’s diverse needs. Recommendations for future research are made, with particular emphasis on including queer people in surveillance data. Target areas for training programmes are described, with emphasis on terminological understanding and accessibility of training. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Authors: Tao, Lane
- Date: 2022-04-07
- Subjects: Discrimination in mental health services , Substance abuse Psychological aspects , Substance abuse Social aspects , Substance abuse Treatment , LGBTQ+ people Psychology , LGBTQ+ people Mental health services , Gender mainstreaming , Psychiatric ethics
- Language: English
- Type: Master's thesis , text
- Identifier: http://hdl.handle.net/10962/234339 , vital:50187
- Description: Research suggests that queer people face both general discrimination and inadequate support in substance use disorder (SUD) treatment. One recommendation made by scholarship to address this is to improve the treatment capabilities of practitioners, thus improving practitioner readiness and reducing access barriers for a potentially at-risk population. The purpose of this study is to explore SUD treatment practitioners’ experiences of treating queer clients and identify their training needs. Semi-structured interviews were conducted with seven registered mental healthcare practitioners operating in Cape Town, South Africa. Data was analysed via thematic analysis, using a social constructionist approach to gender and practitioner knowledge. The findings reflect a strong interest in gender-sensitive training to better prepare practitioners for treating queer clients. Participants provided feedback on areas in need of improvement and made recommendations on how training should be conducted. Findings indicate that queer clients may enter treatment with a high burden of trauma due to discrimination, and that healthcare structures abiding by a binary approach to gender may not be able to address queer people’s diverse needs. Recommendations for future research are made, with particular emphasis on including queer people in surveillance data. Target areas for training programmes are described, with emphasis on terminological understanding and accessibility of training. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
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Nonlinear optical properties of metal free thio alkyl and tert-butyl phenoxy phthalocyanine
- Authors: Joseph, Otto
- Date: 2021-10
- Subjects: Nonlinear optics , Phthalocyanines , Time-dependent density functional theory , Magnetic circular dichroism , Reverse saturable absorption (RSA) , Real Time Dependent Density Functional Theory (RT-TDDFT)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190712 , vital:45021
- Description: This work reports on the nonlinear optical properties of tetra - and octa substituted phthalocyanines (Pcs) utilising pentane thiol and 4-tertbutyl phenol as substituents. Their nonlinear absorption coefficient (𝛽) and absorption cross sections were determined using the Z-scan technique with a 10 ns pulse laser at 532 nm. The molecular second order hyperpolarizability Im[γ] was observed and the following Im[γ] trend was obtained for 𝛼-H2Pc(SC5H11)4 isomers, 5.93 ×10−31 (Cs) 2.24×10−32(D2h) > 1.21×10−32(C4h) > 1.05×10−32 (C2v) esu, respectively, in chloroform. Symmetry was seen to have an effect on the observed reverse saturable absorption (RSA) response. Based on the five level model rate equation nonlinear fit of the RSA response curves and Real Time Time Dependant Density Functional Theory (RT-TDDFT) results, the singlet excited state population dynamics was found to play a significant role in producing the observed Im[γ] trend. , Thesis (MSc) -- Faculty of Science, Chemistry, 2021
- Full Text:
- Authors: Joseph, Otto
- Date: 2021-10
- Subjects: Nonlinear optics , Phthalocyanines , Time-dependent density functional theory , Magnetic circular dichroism , Reverse saturable absorption (RSA) , Real Time Dependent Density Functional Theory (RT-TDDFT)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190712 , vital:45021
- Description: This work reports on the nonlinear optical properties of tetra - and octa substituted phthalocyanines (Pcs) utilising pentane thiol and 4-tertbutyl phenol as substituents. Their nonlinear absorption coefficient (𝛽) and absorption cross sections were determined using the Z-scan technique with a 10 ns pulse laser at 532 nm. The molecular second order hyperpolarizability Im[γ] was observed and the following Im[γ] trend was obtained for 𝛼-H2Pc(SC5H11)4 isomers, 5.93 ×10−31 (Cs) 2.24×10−32(D2h) > 1.21×10−32(C4h) > 1.05×10−32 (C2v) esu, respectively, in chloroform. Symmetry was seen to have an effect on the observed reverse saturable absorption (RSA) response. Based on the five level model rate equation nonlinear fit of the RSA response curves and Real Time Time Dependant Density Functional Theory (RT-TDDFT) results, the singlet excited state population dynamics was found to play a significant role in producing the observed Im[γ] trend. , Thesis (MSc) -- Faculty of Science, Chemistry, 2021
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A business model framework for mission-driven organisations
- Authors: Thackeray, Sean Robin
- Date: 2023-03-31
- Subjects: Nonprofit organizations South Africa Makhanda , Business model , Sustainable development South Africa Makhanda , Resource-based view , Social responsibility of business South Africa Makhanda
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419123 , vital:71618
- Description: Non-profit organisations (NPOs) contribute to our society by addressing needs through value-creation activities which are normally not addressed by normal for-profit organisations. These NPOs generate their income through donations, fundraising and market activities such as the sale of products or services. However, in the pursuit of organisational sustainability, these NPOs need to ensure that their income meets their expenditure needs over the long run, to allow continuous value creation and to pursue their mission. An organisation’s business model can be visualised through a business model framework (BMF), which have been illustrated to be useful tools for organisations to test new business models, plan and coordinate activities, and to communicate how an organisations business model works to stakeholders. The use of BMFs by NPOs may be useful for similar purposes. However, a key challenge for NPOs and their management is adapting for-profit tools to be more applicable to the NPO environment. Whilst there has been some progress within the literature on adapting these for-profit business model tools to NPOs, this area of research is relatively underrepresented in the literature. The single case study method, exploratory in nature, following a deductive approach with a theoretical framework was used to evaluate the NPO Business model framework for NPOs with multiple income streams (Sanderse, 2014) appropriateness for the Centre for Biological Control (CBC), a mission-driven research organisation located within Rhodes University. The study made use of an interpretivist paradigm through the lens of resource-based theory. The contextual environment of the CBC was similar to other NPOs in that their organisational sustainability was at risk due to uncertainty about the availability of long-term funding. The CBC is actively diversifying their income streams by establishing new partnerships, which increase the capacity and resource base of the organisation to improve its flexibility in meeting current and potential funders’ needs. The NPO Business model framework for NPOs with multiple income streams was found to be a suitable BMF to visualise the holistic operations of the CBC. However, the role of governance-related matters being represented in this BMF was found to be lacking. An amended framework including governance as part of the Business model framework for NPOs with multiple income streams was developed. This improved the BMF, by allowing for further contextual insight into the CBCs business model as governance played a major role in the key activities and income-generating strategies they participate in. The role a BMF has in assisting an organisation with resource management activities was also explored. A suitable BMF, which allows for a holistic and explicit display of an organisation’s business model, would assist in determining how resources could be better managed or orchestrated to pursue different potential income-generating strategies or improve the efficiency of how resources are used in the current business model. This study contributed to business model theory by further testing the Business model framework for NPOs with multiple income streams as a tool to visualise an NPOs business model and identifying that once the governance block was added, this BMF became more suitable within the CBCs context. A minor contribution to resource based theory was the exploration of the potential roles BMFs play in resource management, which should be further investigated in line with additional research questions proposed. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2023
- Full Text:
- Authors: Thackeray, Sean Robin
- Date: 2023-03-31
- Subjects: Nonprofit organizations South Africa Makhanda , Business model , Sustainable development South Africa Makhanda , Resource-based view , Social responsibility of business South Africa Makhanda
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419123 , vital:71618
- Description: Non-profit organisations (NPOs) contribute to our society by addressing needs through value-creation activities which are normally not addressed by normal for-profit organisations. These NPOs generate their income through donations, fundraising and market activities such as the sale of products or services. However, in the pursuit of organisational sustainability, these NPOs need to ensure that their income meets their expenditure needs over the long run, to allow continuous value creation and to pursue their mission. An organisation’s business model can be visualised through a business model framework (BMF), which have been illustrated to be useful tools for organisations to test new business models, plan and coordinate activities, and to communicate how an organisations business model works to stakeholders. The use of BMFs by NPOs may be useful for similar purposes. However, a key challenge for NPOs and their management is adapting for-profit tools to be more applicable to the NPO environment. Whilst there has been some progress within the literature on adapting these for-profit business model tools to NPOs, this area of research is relatively underrepresented in the literature. The single case study method, exploratory in nature, following a deductive approach with a theoretical framework was used to evaluate the NPO Business model framework for NPOs with multiple income streams (Sanderse, 2014) appropriateness for the Centre for Biological Control (CBC), a mission-driven research organisation located within Rhodes University. The study made use of an interpretivist paradigm through the lens of resource-based theory. The contextual environment of the CBC was similar to other NPOs in that their organisational sustainability was at risk due to uncertainty about the availability of long-term funding. The CBC is actively diversifying their income streams by establishing new partnerships, which increase the capacity and resource base of the organisation to improve its flexibility in meeting current and potential funders’ needs. The NPO Business model framework for NPOs with multiple income streams was found to be a suitable BMF to visualise the holistic operations of the CBC. However, the role of governance-related matters being represented in this BMF was found to be lacking. An amended framework including governance as part of the Business model framework for NPOs with multiple income streams was developed. This improved the BMF, by allowing for further contextual insight into the CBCs business model as governance played a major role in the key activities and income-generating strategies they participate in. The role a BMF has in assisting an organisation with resource management activities was also explored. A suitable BMF, which allows for a holistic and explicit display of an organisation’s business model, would assist in determining how resources could be better managed or orchestrated to pursue different potential income-generating strategies or improve the efficiency of how resources are used in the current business model. This study contributed to business model theory by further testing the Business model framework for NPOs with multiple income streams as a tool to visualise an NPOs business model and identifying that once the governance block was added, this BMF became more suitable within the CBCs context. A minor contribution to resource based theory was the exploration of the potential roles BMFs play in resource management, which should be further investigated in line with additional research questions proposed. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2023
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Creating the Ideal Push-Pull System for Electrocatalysis A Comparative Study on Symmetrical and Asymmetrical Cardanol-based Cobalt Phthalocyanines
- Nkhahle, Reitumetse, Nyokong, Tebello
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44452 , xlink:href="https://doi.org/10.1002/elan.202060019"
- Description: A symmetrical cardanol-based cobalt phthalocyanine (Pc) along with its asymmetrical acid-based derivatives were synthesized and applied in the electrocatalysis of hydrazine. Despite the inhibition of electron movement by the bulky cardanol-based substituent throughout the series of molecules, an ideal combination of substituents was established in GCE-3 (2,9,16-tris(3- pentadecylphenoxy)-23-mono propionic acid phthalocyanato cobalt (II)) where a limit of detection (LoD) value of 5.10 μM (signal to noise ratio=5) was recorded for the detection of hydrazine. The results obtained serve as an illustration that the combination of electron-donating and electron-withdrawing substituents has a significant influence on the complete functioning of the phthalocyanine molecule(s) being investigated.
- Full Text:
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44452 , xlink:href="https://doi.org/10.1002/elan.202060019"
- Description: A symmetrical cardanol-based cobalt phthalocyanine (Pc) along with its asymmetrical acid-based derivatives were synthesized and applied in the electrocatalysis of hydrazine. Despite the inhibition of electron movement by the bulky cardanol-based substituent throughout the series of molecules, an ideal combination of substituents was established in GCE-3 (2,9,16-tris(3- pentadecylphenoxy)-23-mono propionic acid phthalocyanato cobalt (II)) where a limit of detection (LoD) value of 5.10 μM (signal to noise ratio=5) was recorded for the detection of hydrazine. The results obtained serve as an illustration that the combination of electron-donating and electron-withdrawing substituents has a significant influence on the complete functioning of the phthalocyanine molecule(s) being investigated.
- Full Text:
Interaction of nitric oxide with cobalt (II) phthalocyanine
- Vilakazi, Sibulelo L, Nyokong, Tebello
- Authors: Vilakazi, Sibulelo L , Nyokong, Tebello
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293579 , vital:57100 , xlink:href="https://doi.org/10.1016/S0277-5387(98)00244-7"
- Description: The coordination of nitric oxide (NO) to cobalt(II) phthalocyanine (CoPc) in dimethyl sulphoxide (DMSO) has been studied. CoPc coordinates with NO in a 1:1 ratio, forming a CoPc(NO) species. The IR band observed at 1680 cm−1 is assigned to the coordinated NO. In the presence of excess NO, pseudo first order kinetics were followed. The observed rate constant, kf, was determined to be 15.0±0.3 dm−3 mol−1 s−1 and the equilibrium constant was K=5.4±0.4×104dm3 mol−1. Solution or adsorbed CoPc catalyses the reduction of NO. The products of reduction include NH3 and NH2OH.
- Full Text:
- Authors: Vilakazi, Sibulelo L , Nyokong, Tebello
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293579 , vital:57100 , xlink:href="https://doi.org/10.1016/S0277-5387(98)00244-7"
- Description: The coordination of nitric oxide (NO) to cobalt(II) phthalocyanine (CoPc) in dimethyl sulphoxide (DMSO) has been studied. CoPc coordinates with NO in a 1:1 ratio, forming a CoPc(NO) species. The IR band observed at 1680 cm−1 is assigned to the coordinated NO. In the presence of excess NO, pseudo first order kinetics were followed. The observed rate constant, kf, was determined to be 15.0±0.3 dm−3 mol−1 s−1 and the equilibrium constant was K=5.4±0.4×104dm3 mol−1. Solution or adsorbed CoPc catalyses the reduction of NO. The products of reduction include NH3 and NH2OH.
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Fluorescence “turn on” probe for bromide ion using nanoconjugates of glutathione-capped CdTe@ ZnS quantum dots with nickel tetraamino-phthalocyanine
- Adegoke, Oluwasesan, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190479 , vital:44998 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.05.013"
- Description: In this paper, three differently sized glutathione (GSH)-capped CdTe@ZnS quantum dots (QDs) have been successfully conjugated to nickel tetraamino-phthalocyanine (NiTAPc) to form different QDs-NiTAPc nanocomplexes. Several techniques such as TEM, FT-IR, time-resolved fluorescence measurement and electronic spectroscopy were employed to characterize the nanocomplex. Bromide ion was chosen as a model anion to test the efficacy of the nanoprobe. The fluorescence of the nanoconjugate was “turned off” upon binding but was progressively “turned on” upon interaction with varying concentrations of bromide ion. Experimental results showed that the quantum size effect of nanocrystal QD determined the overall sensitivity and selectivity of the nanoprobe and followed the order QD563-NiTAPc > QD605-NiTAPc > QD621-NiTAPc. The mechanism of reaction is proposed.
- Full Text:
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190479 , vital:44998 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.05.013"
- Description: In this paper, three differently sized glutathione (GSH)-capped CdTe@ZnS quantum dots (QDs) have been successfully conjugated to nickel tetraamino-phthalocyanine (NiTAPc) to form different QDs-NiTAPc nanocomplexes. Several techniques such as TEM, FT-IR, time-resolved fluorescence measurement and electronic spectroscopy were employed to characterize the nanocomplex. Bromide ion was chosen as a model anion to test the efficacy of the nanoprobe. The fluorescence of the nanoconjugate was “turned off” upon binding but was progressively “turned on” upon interaction with varying concentrations of bromide ion. Experimental results showed that the quantum size effect of nanocrystal QD determined the overall sensitivity and selectivity of the nanoprobe and followed the order QD563-NiTAPc > QD605-NiTAPc > QD621-NiTAPc. The mechanism of reaction is proposed.
- Full Text:
Sexual socialisation: young adult women storying how sexual activities were discussed in South African cultural contexts
- Authors: Ludidi, Zizipho
- Date: 2022-04-07
- Subjects: Socialization South Africa , Sex Social aspects South Africa , Young women Socialization South Africa , Young women Sexual behavior South Africa , Culture , Memory , Narrative inquiry (Research method)
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/292737 , vital:57011
- Description: Epidemics such as HIV/AIDS, unplanned pregnancy, gender-based violence and homophobia, in South Africa, have focused research on how young people learn about sex. This research has often focused on young girls from risk-saturated areas, and specific agents of socialisation, where they might learn about sex, such as parents, life orientation at schools, peers, media, and traditional cultural approaches. Using a narrative theoretical framework, through memory work, this study explored how black young adult women friends – who were university students – experienced forms of sexual socialisation, through various communication in South African cultural contexts. Findings from the thematic narrative analysis that was conducted demonstrated that sexual socialisation is a complex life-long process. This takes place through a collision of contradictory messages, from different agents of socialisation, in different cultural contexts. Themes were identified and organised to tell an overall sexual socialisation story that progressed through time, moving from a stage of perceived innocent oblivion, mixed messages in primary and high school, “liberal” university stories and the current stage of reauthoring stories. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Authors: Ludidi, Zizipho
- Date: 2022-04-07
- Subjects: Socialization South Africa , Sex Social aspects South Africa , Young women Socialization South Africa , Young women Sexual behavior South Africa , Culture , Memory , Narrative inquiry (Research method)
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/292737 , vital:57011
- Description: Epidemics such as HIV/AIDS, unplanned pregnancy, gender-based violence and homophobia, in South Africa, have focused research on how young people learn about sex. This research has often focused on young girls from risk-saturated areas, and specific agents of socialisation, where they might learn about sex, such as parents, life orientation at schools, peers, media, and traditional cultural approaches. Using a narrative theoretical framework, through memory work, this study explored how black young adult women friends – who were university students – experienced forms of sexual socialisation, through various communication in South African cultural contexts. Findings from the thematic narrative analysis that was conducted demonstrated that sexual socialisation is a complex life-long process. This takes place through a collision of contradictory messages, from different agents of socialisation, in different cultural contexts. Themes were identified and organised to tell an overall sexual socialisation story that progressed through time, moving from a stage of perceived innocent oblivion, mixed messages in primary and high school, “liberal” university stories and the current stage of reauthoring stories. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
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Sustainability assessment using a unit-based sustainability assessment tool: The case of three teaching departments at Rhodes University, South Africa
- Authors: Togo, Muchaiteyi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386863 , vital:68182 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122776"
- Description: A sustainability assessment study was performed with three teaching departments at Rhodes University – Ichthyology and Fisheries Science, Anthropology, and Accounting. The assessment used a Unit-based Sustainability Assessment Tool (USAT) and was guided by systems thinking and the ontological framework provided by critical realism. Results of the study showed that the Department of Ichthyology and Fisheries Science had a higher integration of sustainability issues in its activities than the other departments sampled, with Accounting having the lowest integration. Interviews conducted with departmental heads and content analyses of documents revealed differences in sustainability issues addressed and in approaches used in tackling them among these departments. The study is intended to inform the Mainstreaming of Environment and Sustainability in African (MESA) Universities Partnership, which promotes mainstreaming environment and sustainability in universities during the United Nations Decade of Education for Sustainable Development. The study does not provide answers to mainstreaming activities, but opens up space to debate and deliberate how to deal with the mainstreaming of sustainability in universities. It identified some of the challenges to be addressed in university-wide mainstreaming work, and affirmed the need for systems thinking in bringing about change at institutional level to extend changes taking place in individual teaching contexts.
- Full Text:
- Authors: Togo, Muchaiteyi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386863 , vital:68182 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122776"
- Description: A sustainability assessment study was performed with three teaching departments at Rhodes University – Ichthyology and Fisheries Science, Anthropology, and Accounting. The assessment used a Unit-based Sustainability Assessment Tool (USAT) and was guided by systems thinking and the ontological framework provided by critical realism. Results of the study showed that the Department of Ichthyology and Fisheries Science had a higher integration of sustainability issues in its activities than the other departments sampled, with Accounting having the lowest integration. Interviews conducted with departmental heads and content analyses of documents revealed differences in sustainability issues addressed and in approaches used in tackling them among these departments. The study is intended to inform the Mainstreaming of Environment and Sustainability in African (MESA) Universities Partnership, which promotes mainstreaming environment and sustainability in universities during the United Nations Decade of Education for Sustainable Development. The study does not provide answers to mainstreaming activities, but opens up space to debate and deliberate how to deal with the mainstreaming of sustainability in universities. It identified some of the challenges to be addressed in university-wide mainstreaming work, and affirmed the need for systems thinking in bringing about change at institutional level to extend changes taking place in individual teaching contexts.
- Full Text:
Délices et négation: une approche de l’écriture féminine à travers quelques romans Africains Francophones
- Authors: Anjugu, Taimako Ajigo
- Date: 2023-03-30
- Subjects: African fiction (French) History and criticism , Literature Women authors , Women authors, African , Reader-response criticism , Womanism in literature
- Language: French
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/409779 , vital:70629 , DOI 10.21504/10962/409779
- Description: From the onset, it is worthy to note that, nowadays, just as after the independence of most African countries, several writers from the African continent have been preoccupied with the fate of women. This is because, the African continent was since ancient times characterized by certain traditions and cultures which mainly have contributed to the plight of the women. This goes to emphasise that women in most cases are the victims of misdeeds such as early marriage, forced marriage, prejudices, violence, marginalisation, exploitation, discrimination; in short, vices that lead to devalorisation of African women in Africa. Over time, some contemporary French-speaking African writers have responded to the devaluation and valuation of women in their novels using 21st century objective view. With regard to the theme that we decided to address in this research, it is worth knowing that the preponderant task is based on the socio-critical theory, postulated by Claude Duchet. Meanwhile, recourse is also made to the comparative method by Rens, Bod et al. However, since the author’s message could be understood by the reader through the use of some expressions or terms that speak directly to the themes of the research, and that a reader’s role in reading experience cannot be overemphasised, we have been able to also lean on the Reader-response theory of Louise Michelle Rosenblatt. The three methods were used concurrently especially that the analysis of each text is based on how characters are being depicted leading us to realizing that our findings on how the African woman is devalued in the first part of the research, while in the second part of the thesis, our findings demonstrate that a lot of tributes are showered on the African woman due to her numerous outstanding qualities. In effect, our findings also reinforce a significant shift in the narrative that concerns the contemporary view on womanhood. Hence, moving from a dogmatic overconcentration on her lot to the new era woman whose lot is now redefined via the new wave feminist perspective on the negation of the African woman. This could be said to be in line with Amadiume Ifi’s contributions and pioneering work in feminist discourse towards new ways of thinking about sex and gender, the question of power, and women’s place in history and culture. , Pour commencer, il est nécessaire de se souvenir qu’à l’époque actuelle, comme juste après les indépendances de la plupart des pays africains, bon nombre des écrivains venant du continent africain décident de se préoccuper des méfaits sociaux tels que le mariage précoce et/ou forcé, les préjugés, la violence, la marginalisation, l’exploitation, la discrimination, entre autres. Tous ces vices sont issus de la négation de la femme africaine. Ceci se justifie par le fait que le continent africain était depuis l’antiquité caractérisé par certaines traditions et cultures qui ont contribué principalement aux dégâts ci-dessus soulignés subis par les femmes. En effet, nous estimons que beaucoup de femmes sont victimes de ces méfaits qui sont encore pratiqués dans certaines parties de l’Afrique. Avec le temps, certains écrivains africains francophones contemporains représentent la dévalorisation et la valorisation de la femme dans leurs romans en se servant d’une vision contemporaine, celle du XXIe siècle. En ce qui concerne le thème que nous avons décidé d'aborder dans cette recherche, il faut savoir que la tâche prépondérante repose sur la théorie sociocritique, postulée par Claude Duchet. Parallèlement, on a également recours à la méthode comparative de Bod Rens Et ses coauteurs. Cependant, puisque le message de l’auteur pourrait être compris aussi par le lecteur à travers l’usage de certaines expressions ou termes qui sont directement liés aux thèmes de la recherche, le rôle du lecteur dans l’expérience de lecture ne peut pas être surestimé, nous avons également pu nous appuyer sur la théorie de la réponse du lecteur de Louise Michelle Rosenblatt. Les trois méthodes ont été utilisées simultanément d'autant plus que l'analyse de chaque texte est basée sur la façon dont les personnages sont représentés ; ceci nous a amené à tirer nos conclusions sur la façon dont la femme africaine est dévalorisée dans la première partie de la recherche, tandis que dans la deuxième partie de la thèse, nos résultats démontrent que de nombreux hommages sont rendus à la femme africaine grâce à ses nombreuses qualités exceptionnelles. En effet, nos résultats renforcent également un changement important dans le récit qui concerne la vision contemporaine de la féminité. Par conséquent, passer d’une surconcentration dogmatique sur son sort à la femme de la nouvelle ère dont le sort est maintenant redéfini via la perspective féministe par rapport à la négation de la femme africaine telle a été la démarche. On pourrait dire que cela est au diapason avec les contributions d’Amadiume Ifi et avec son travail dans le discours féministe vers de nouvelles façons de penser le sexe et le genre, la question du pouvoir et la place de la femme dans l’histoire et la culture. , Thesis (PhD) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Authors: Anjugu, Taimako Ajigo
- Date: 2023-03-30
- Subjects: African fiction (French) History and criticism , Literature Women authors , Women authors, African , Reader-response criticism , Womanism in literature
- Language: French
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/409779 , vital:70629 , DOI 10.21504/10962/409779
- Description: From the onset, it is worthy to note that, nowadays, just as after the independence of most African countries, several writers from the African continent have been preoccupied with the fate of women. This is because, the African continent was since ancient times characterized by certain traditions and cultures which mainly have contributed to the plight of the women. This goes to emphasise that women in most cases are the victims of misdeeds such as early marriage, forced marriage, prejudices, violence, marginalisation, exploitation, discrimination; in short, vices that lead to devalorisation of African women in Africa. Over time, some contemporary French-speaking African writers have responded to the devaluation and valuation of women in their novels using 21st century objective view. With regard to the theme that we decided to address in this research, it is worth knowing that the preponderant task is based on the socio-critical theory, postulated by Claude Duchet. Meanwhile, recourse is also made to the comparative method by Rens, Bod et al. However, since the author’s message could be understood by the reader through the use of some expressions or terms that speak directly to the themes of the research, and that a reader’s role in reading experience cannot be overemphasised, we have been able to also lean on the Reader-response theory of Louise Michelle Rosenblatt. The three methods were used concurrently especially that the analysis of each text is based on how characters are being depicted leading us to realizing that our findings on how the African woman is devalued in the first part of the research, while in the second part of the thesis, our findings demonstrate that a lot of tributes are showered on the African woman due to her numerous outstanding qualities. In effect, our findings also reinforce a significant shift in the narrative that concerns the contemporary view on womanhood. Hence, moving from a dogmatic overconcentration on her lot to the new era woman whose lot is now redefined via the new wave feminist perspective on the negation of the African woman. This could be said to be in line with Amadiume Ifi’s contributions and pioneering work in feminist discourse towards new ways of thinking about sex and gender, the question of power, and women’s place in history and culture. , Pour commencer, il est nécessaire de se souvenir qu’à l’époque actuelle, comme juste après les indépendances de la plupart des pays africains, bon nombre des écrivains venant du continent africain décident de se préoccuper des méfaits sociaux tels que le mariage précoce et/ou forcé, les préjugés, la violence, la marginalisation, l’exploitation, la discrimination, entre autres. Tous ces vices sont issus de la négation de la femme africaine. Ceci se justifie par le fait que le continent africain était depuis l’antiquité caractérisé par certaines traditions et cultures qui ont contribué principalement aux dégâts ci-dessus soulignés subis par les femmes. En effet, nous estimons que beaucoup de femmes sont victimes de ces méfaits qui sont encore pratiqués dans certaines parties de l’Afrique. Avec le temps, certains écrivains africains francophones contemporains représentent la dévalorisation et la valorisation de la femme dans leurs romans en se servant d’une vision contemporaine, celle du XXIe siècle. En ce qui concerne le thème que nous avons décidé d'aborder dans cette recherche, il faut savoir que la tâche prépondérante repose sur la théorie sociocritique, postulée par Claude Duchet. Parallèlement, on a également recours à la méthode comparative de Bod Rens Et ses coauteurs. Cependant, puisque le message de l’auteur pourrait être compris aussi par le lecteur à travers l’usage de certaines expressions ou termes qui sont directement liés aux thèmes de la recherche, le rôle du lecteur dans l’expérience de lecture ne peut pas être surestimé, nous avons également pu nous appuyer sur la théorie de la réponse du lecteur de Louise Michelle Rosenblatt. Les trois méthodes ont été utilisées simultanément d'autant plus que l'analyse de chaque texte est basée sur la façon dont les personnages sont représentés ; ceci nous a amené à tirer nos conclusions sur la façon dont la femme africaine est dévalorisée dans la première partie de la recherche, tandis que dans la deuxième partie de la thèse, nos résultats démontrent que de nombreux hommages sont rendus à la femme africaine grâce à ses nombreuses qualités exceptionnelles. En effet, nos résultats renforcent également un changement important dans le récit qui concerne la vision contemporaine de la féminité. Par conséquent, passer d’une surconcentration dogmatique sur son sort à la femme de la nouvelle ère dont le sort est maintenant redéfini via la perspective féministe par rapport à la négation de la femme africaine telle a été la démarche. On pourrait dire que cela est au diapason avec les contributions d’Amadiume Ifi et avec son travail dans le discours féministe vers de nouvelles façons de penser le sexe et le genre, la question du pouvoir et la place de la femme dans l’histoire et la culture. , Thesis (PhD) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
Students as Agents of Social Change-Student Initiatives at Rhodes University, South Africa
- Authors: Togo, Muchaiteyi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386561 , vital:68151 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122830"
- Description: Rhodes University has a diversity of sustainable development initiatives meant for students and in a range of cases activities are initiated by students themselves with the support of the university. Results of a sustainability assessment revealed the involvement of students in environmental societies, environmental awareness campaigns, campus sustainability initiatives and community sustainability projects. Though most of the projects are still in their infancy and some challenges are yet to be overcome, the sustainability initiatives are gaining momentum and have contributed to improving the overall picture of sustainability at the university. Based on the results of the Rhodes University case study, the underpinning viewpoint in this paper is that university students are not merely recipients of Education for Sustainable Development but have the capacity to become agents for social change.
- Full Text:
- Authors: Togo, Muchaiteyi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386561 , vital:68151 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122830"
- Description: Rhodes University has a diversity of sustainable development initiatives meant for students and in a range of cases activities are initiated by students themselves with the support of the university. Results of a sustainability assessment revealed the involvement of students in environmental societies, environmental awareness campaigns, campus sustainability initiatives and community sustainability projects. Though most of the projects are still in their infancy and some challenges are yet to be overcome, the sustainability initiatives are gaining momentum and have contributed to improving the overall picture of sustainability at the university. Based on the results of the Rhodes University case study, the underpinning viewpoint in this paper is that university students are not merely recipients of Education for Sustainable Development but have the capacity to become agents for social change.
- Full Text: