List of Titles

Ecological assessment of a temperate river system using biomonitoring techniques: a case study of the Bloukrans River system, South Africa

- Magadze, Tinotenda

Authors: Magadze, Tinotenda
Date: 2020
Subjects: Bloukrans River , Ecological assessment (Biology) -- South Africa , Stream ecology -- South Africa , Rivers -- Environmental aspects -- South Africa , Benthic animals -- Effect of human beings on -- South Africa , Water quality biological assessment -- South Africa , Diatoms -- South Africa -- Data processing
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/142933 , vital:38177
Description: Escalating pressures from growing human populations and environmental impacts increasingly imperil freshwater ecosystems. The Bloukrans River, which drains an urbanised and agricultural catchment in the Eastern Cape province of South Africa, is no exception. Detailed knowledge of the structure and function of the aquatic ecosystems is required in order to create models and matrices that predict, guide assessment and direct intervention on ecological integrity and water quality management in these systems. The main objectives of this research were to: examine the effects of urbanization on the benthic macroinvertebrate functional feeding guild structure among different stream orders; determine if benthic diatoms can be used as effective and reliable indicators of ionic composition and conductivity in different stream order categories and finally; to evaluate the applicability of the South African Diatom Index (SADI) and other indices in the Eastern Cape region of South Africa. Field studies were carried out to explore temporal patterns in community structure (macroinvertebrates and diatoms) and ecosystem function related to land-use patterns, instream habitat availability, and water quality parameters in the Bloukrans River system across four study periods: February (summer) and July (winter) 2016 and February (summer) and May/July (winter) 2018. The study was conducted along a gradient of impacts from less impacted agricultural headwaters to highly impacted urban sites located immediately downstream of the city of Makhanda. Macroinvertebrates were separated into functional feeding groups (FFGs) (i.e. collector-gatherer, collector-filterer, scraper, shredder, and predator) which were then used to assess the effects of selected physico-chemical variables and riparian zone condition on FFG organization. Collector-gatherers were the most abundant in the Bloukrans River and represented 71.3 % of the macroinvertebrate assemblages. Stream order 1species such as Nitzschia palea, Gomphonema parvulum, Tryblionella apiculata, Diploneis vulgaris and Staurosira elliptica. Multivariate analysis (Canonical correspondence analysis (CCA)) indicated that differences in diatom community assemblages were best explained by calcium, magnesium, pH, phosphate, nitrate, dissolved oxygen, sediment nitrate, conductivity and salinity. These results indicate that diatoms can be used as bioindicators for monitoring highly impacted river systems and to also further examine pollution gradients and impacts of specific/point pollution sources. In order to further test the application of diatom indices, nine sites with contrasting water quality were sampled along the length river system in February, May and July 2018. Diatom-based indices incorporated in OMNIDIA software were applied to assess the integrity of the water quality as indicated by diatom communities. For comparative purposes, several foreign indices (e.g. the trophic diatom index (TDI), the percentage pollution-tolerant valves (%PTV), biological diatom index (BDI)) and the South African Diatom Index (SADI) were used in the study. From the results, the Percentage Pollution-Tolerant Valves (%PTV) of most urban sites in the Bloukrans River was above the 20% limit indicating the presence of organic pollutants. Although the foreign diatom indices were applicable in the study, the SADI had significant correlations with most water quality variables (p < 0.05) compared to other indices such as Watanabe Index (WAT), Biological Index of Water Quality Trophic Index (BIWQ) and Trophic Index (TI)). These results support wider use of the SADI as an indicator of water quality conditions in South African river systems. Finally, the observed variations in diatom community structure and composition as a result of changes in water quality were broadly in agreement with the results of macroinvertebrate FFG structure indicating that the two biological indicators can, and should, be used as complementary techniques in the biomonitoring of rivers and streams in South Africa.
Full Text:
Date Issued: 2020

Quick View

Aspects Allocentristes de l’Humanisme dans l’Univers Romanesque de Williams Sassine

- Dami, Emmanuel Naancin

Authors: Dami, Emmanuel Naancin
Date: 2018
Subjects: Sassine, Williams, 1944-1997 -- Criticism and interpretation , Guinean fiction (French) -- 20th century -- History and criticism , Humanism in literature , Human beings in literature , Postcolonialism in literature , Existentialism in literature
Language: French , English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/61957 , vital:28089
Description: The human being, his behaviour and more importantly, his very essence have, for time immemorial, proven to be enigmatic to many a man and to researchers in particular. Consequently, the need for a thorough and more profound understanding of man has made him the epicentre of epistemic investigations across many academic disciplines. This, unfortunately, does not seem to have shaded bright lights on the grey areas bordering on his nature to his behavior. This, in turn, opens up other windows requiring further probes. For instance, proponents of the Neo-classical economic school contend that the human being is homo oeconomicus. This implies that man is intrinsically egocentric and a rational being whose decisions are based on informed choices driven by his urge for maximal utility geared towards his personal satisfaction (O’Boyle 2009; Caruso 2012). This stance invalidates man’s ability to do ‘disinterested good’ in any form. African francophone literature is replete with different and diverse images of man, his behaviour and existential conditions: sufferings and struggles. It, therefore, constitutes, inter alia, a laboratory in which researchers undertake investigative endeavours. This thesis beams its floodlights on the allocentric aspects of humanism in the novels of Williams Sassine. Thus, using the phenomenological and ‘clavieniste’ lenses as overarching operational theories, the thesis investigates Sassine’s novels with the view to shading a ray of light on the ‘humanistic man’ especially the allocentric dimensions of his nature and comportment. Emphasis is laid on the motives and motivations underlying the individual and the in-group struggle of the sassinien heroes in the emancipation of their society from the shackles of colonial and postcolonial domination, exploitation and subjugation resulting in self-determination and the subsequent disenchantment. Furthermore, the thesis examines the nature and character of human charity, generosity and sacrifices among the characters in the novels. In conclusion, the thesis establishes, through an x-ray of the nature of actions and decisions of certain characters in the novels, the examination of the conscious and subconscious intentions underlying these same actions and decisions which, on a face value, are apparently altruistic, that the sassinien heroes’ efforts and sacrifices are geared towards the common and greater good. This invariably means that man is, indeed, capable of posing disinterested acts of charity and bringing succour, devoid of any ulterior motives for personal gain, to his fellow humans. The position of the Neo-classical economists is consequently over-assuming, sweeping and tad generalizing. The sassinien characters have demonstrated beyond reasonable doubt that they are humanists. Their nature, the remote and immediate causes of their fights, the goals and objectives of their struggles and their spirit of abnegation have indeed proven that “human beings have the right and the responsibility to give meaning and shape to their own lives. [They have stood] for the building of a more humane society through an ethics based on the human and other natural values in a spirit of reason and free inquiry through human capabilities” (AHA 2017 : 3).
Full Text:
Date Issued: 2018

Quick View

Understanding climate change and rural livelihoods in Zimbabwe: adaptation by communal farmers in Ngundu, Chivi District

- Nciizah, Elinah

Authors: Nciizah, Elinah
Date: 2020
Subjects: Agriculture -- Zimbabwe , Agriculture -- Climatic factors -- Chivi District (Zimbabwe) , Chivi District (Zimbabwe) -- Rural conditions
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/118765 , vital:34666
Description: Climate change and variability is a global phenomenon which has deeply localised patterns, dynamics and effects. Amongst those people who are particularly vulnerable to climate change effects are small-scale farmers who are dependent in large part on rain-fed agriculture in pursuing their livelihoods. This is true of small-scale farmers in contemporary Zimbabwe and, more specifically, farmers in communal areas. At the same time, at international and national levels, there are attempts currently to minimise the effects of, and to adapt to, climate change. However, adaptation measures also exist at local levels amongst small-scale farmers, such as communal farmers in Zimbabwe. In this context, as its main objective, this thesis examines climate change and small-scale farmer livelihood adaptation to climate change with specific reference to communal farmers in Chivi District in Zimbabwe and, in particular, in Ward 25 which is popularly known as Ngundu. In pursuing this main objective, a number of subsidiary objectives are addressed, including a focus on the established livelihoods of Ngundu farmers, the perceptions and concerns of Ngundu farmers about climate change, the coping and adaptation measures of Ngundu farmers, and the enablements and constraints which affect attempts by Ngundu farmers to adopt such measures. The fieldwork for the thesis involved a diverse array of research methods, such as a questionnaire survey, life-history interviews, key informant interviews, focus group discussions and transect walks. In terms of theoretical framing, the thesis makes use of both middle-level theory (the Sustainable Livelihoods Framework) and macro-theory in the form of the sociological work of Margaret Archer. Combined, these two theories allow for a focus on both structure and agency when seeking to understand livelihood adaptations to climate change by communal farmers in Ngundu. The thesis concludes that there are massive constraints inhibiting adaptation measures by Ngundu farmers, but that this should not distract from the deep, often historically-embedded, concerns of Ngundu farmers about climate change and the multiple ways in which they express agency in and through adaptation and coping activities. It also highlights the need for more specifically sociological investigations of climate change and small-scale farmer adaptation, as well as the need for localised studies which are able to identify and analyse the specificities of adaptation.
Full Text:
Date Issued: 2020

Quick View

The remote sensing of fires and their effects on soil properties in the uKhahlamba Drakensberg Park

- Moore, Natasha Jade

Authors: Moore, Natasha Jade
Date: 2019
Subjects: Remote sensing -- South Africa -- KwaZulu-Natal , Soil ecology -- South Africa -- KwaZulu-Natal , Grassland fires -- South Africa -- KwaZulu-Natal , Grassland fires -- Remote sensing -- South Africa -- KwaZulu-Natal , Soils -- Effect of fires on -- South Africa -- KwaZulu-Natal , uKhalamba Drakensberg Park (South Africa)
Language: English
Type: text , Thesis , Masters , MSc
Identifier: http://hdl.handle.net/10962/94400 , vital:31042
Description: Fires are a common and natural occurrence globally and specifically on the African continent. The Drakensberg Mountains are home to southern Africa’s high-altitude fire-climax grasslands, where fire is the dominant management tool. Fire is used to maintain the grasslands in the uKhahlamba Drakensberg Park (UDP) World Heritage Site, located on the eastern escarpment of the KwaZulu-Natal Drakensberg. This study aimed to investigate the spatial and temporal frequency of fires using remote sensing, and to investigate the effect of fire frequency on soil properties in the UDP. Remote sensing offers a set of supportive tools for the management of this sensitive vegetation and specifically to assess the frequency and spatial extent of fires. Field assessments can then be used to assess the impact of fires. Remotely sensed data were used to determine fire frequency and the spatial extent of fires in the UDP. The Moderate Resolution Imaging Spectroradiometer (MODIS) and Visible Infrared Imaging Radiometer Suite (VIIRS) active fire detection point data were processed to investigate the temporal resolution of fires. Landsat 5 and 8 imagery were utilised for conducting Normalised Burn Ratios (NBR) to determine the spatial extent of the burn scars of fires. The results from the remotely sensed data were used to select study sites for accessing the effects of fire frequency on soil properties. The remote sensing results showed the main fire season in the UDP was from May to October, and annual burn scars from the available Landsat data for 1998 to 2017 ranged from 22.5% to 57.67% of the UDP. Remote sensing was shown to be an effective tool for monitoring fires in the UDP, with a combination of satellite data producing the best results. Soil properties were highly varied across the UDP. Environmental factors were shown to have a more significant influence on soil properties than fire frequency. This study highlighted the complex nature and diversity of fires and soils across the UDP.
Full Text:
Date Issued: 2019

Quick View

A metabletic study of the male/female process in psychology

- O'Brien, Keith Stanley Edward Michael

Authors: O'Brien, Keith Stanley Edward Michael
Date: 1989
Subjects: Psychology -- Philosophy , Sex difference (Psychology) , Psychotherapy
Language: English
Type: text , Thesis , Masters , MA
Identifier: vital:2908 , http://hdl.handle.net/10962/d1002073
Description: The motivation to explore the subject matter of this thesis arises from two interlinked processes: (1) the experience of the power and pervasiveness of a "basic split" experienced in therapy in the unity of the individual, (2) the tendency in the unitary discipline psychology for theorists to adopt views which are polar opposites. In trying to understand these phenomena one has to explore the basic paradox of being which has fascinated thinkers and mystics down through the ages, the paradox of the One and the many, and thus the phenomenon of change. This paradox is explored in mythology, in the "philosophia perennis" and as encountered in high-energy sub-atomic physics. Out of this emerges the awareness of Being as One but as embodying a dynamic polar process, the first of whose manifestations is the male and the female process (or Yin/Yang in Chinese). The male/female process is defined and explored and it is shown that the female process has been progressively ignored and largely repressed in the West. I demonstrate this process in a metabletic (hermeneutical phenomenological) study of Greek sacred architecture. Metabletics as defined by its originator, J.H. van den Berg, is "the theory of change" or a psychology of history. It is thus a particularly suitable method of analysing the cultural-historical process of the repression of the female process in Western society. The emergence of the male process as predominant in the West is explored hermeneutically through the emergence of the individual and the suppression of the old unity centred in the Mother Goddess, and the receding of the Father God to the heavens. The choice by the great Greek philosophers of the male process is particularly important because of their emphasis on the Logico-Mathematical Sequential (L.M.S.) mode of knowing and perception at the expense of the female process, Intuitive-Creative Holistic (I.C.H.) mode.The dominance of the male process in the West is traced from the aboriginal female-process state through neolithic village culture to the rise of the first cities. Processes studied are the rise of kingship, war, private property and the splitting of labour. The roots of anomie and alienation are described. The emergence of god as powerful ruler and lawgiver is shown. The splitting of the male/female process leads to the splitting of the individual from him/herself, from others, from the world and from the divine. This is traced in the mystery religions, in religious dualism, in the rise of the Judaeo-Christian tradition and Gnosticism. The split and its effects are demonstrated in Western science and psychology. The necessity and possibility of integration in science and in psychology is demonstrated through the integration of our process of knowing and perceiving which is used as a model for the integration of psychology. The effects of the male/female split on the individual in Western society are shown. The split in our society leads to anomie and alienation, which produce "socioses". These affect the child born into the society and lead to a "Parent/Child" split. The possibility of healing the split in the individual, between people, between humankind and the world and in re-establishing our unity in the One is illustrated. The unity of the One is experienced through the dynamic polar interaction of the male/female process.
Full Text:
Date Issued: 1989

Quick View

History after apartheid

- Maylam, Paul

Authors: Maylam, Paul
Date: 1993-03-24
Language: English
Type: text
Identifier: http://hdl.handle.net/10962/54290 , vital:26451 , ISBN 0-86810-256-3
Description: [From introduction] The purpose of my lecture tonight is to consider some possible future trends and issues in the discipline of South African history in the post-apartheid era. Before doing that I need to say something about two influences or traditions that have left a troublesome legacy and require critical examination. I am referring to the two ‘E’s’: empiricism and eurocentrism. Now it is true that both of these have wilted under serious assaults from scholars in the past 25 years. But both remain present in many sorts of texts; both remain embedded in what we might call ‘the everyday commonsense view of the world’ - so that they continue to constitute a problem.
Full Text:
Date Issued: 1993-03-24

Quick View

An exploration of social media as a key site for the expression of post-racial politics

- Bell, Joshua

Authors: Bell, Joshua
Date: 2019
Subjects: Social media -- Political aspects -- South Africa , South Africa -- Politics and government -- 1994- , South Africa -- In mass media
Language: English
Type: text , Thesis , Masters , MA
Identifier: http://hdl.handle.net/10962/94049 , vital:30995
Description: This research sets out to examine colourblind racism in contemporary South Africa, specifically, as expressed on social media networks. In South Africa, a nation lauded for its transition from Apartheid to liberal democracy, racism still continues to exist. In the new democracy, racism continues in old, familiar forms but it has been suggested that racism also assumes new and emergent forms such as ‘colourblind’ racism. This is evident in recent controversies involving local public figures and their expressions of ‘soft’, ‘colourblind’ racism on Facebook. It is the new platforms and modes of racism unique to democratic South Africa which this thesis attempts to explore. Specifically, this study is framed by ‘post-racialism’, a concept developed by scholars globally to capture the suggestion that in liberal democratic societies across the world, racism continues with racial inequality now underpinned by an ideology of colourblindness as opposed to overt policies of segregation. Colourblindness denies the relevance of race as a collective issue, proposing instead that other social factors such as class are more pertinent in considerations of social inequality. The purpose of colourblind narratives may be identified as the reduction of racism to mere individual action, denying systemic white privilege and historical responsibility for reparation as well as preventing racially subjugated groups from critically interrogating racial power and privilege (Goldberg, 2015: 28-30). Post-racial theorists agree that the projection of colourblind politics which claims to no longer ‘see race’ has instead served to secure the normalisation of white privilege and black subjugation (Bonilla-Silva et al, 2004: 559-560). The purported existence of colourblind /post-racial racism and its impact requires exploration in the context of South Africa today. In expanding on the definition of racism, we are able to see that racism is an adaptive system of power that is able to reproduce and reconceptualise itself to changes within society. As modalities of racism have evolved, so have the platforms for its propagation. This research offers social media as a site of exploration for post-racial narratives. The case studies of Penny Sparrow, Helen Zille and Mabel Jansen are presented in this study as exemplars of post-racial liberalism, denial and exclusion. This research calls for the expansion of racial understanding so as to contest racial power structures as a continuing systemic issue in contemporary South Africa.
Full Text:
Date Issued: 2019

Quick View

An access control model for a South African National Electronic Health Record System

- Tsegaye, Tamir Asrat

Authors: Tsegaye, Tamir Asrat
Date: 2019
Subjects: Medical records -- Data processing , Medical records -- Data processing -- Safety measures , Medical records -- Data processing -- South Africa , Medical records -- Data processing -- Access control , Medical informatics , Medical records -- Management -- South Africa , Health services administration -- South Africa
Language: English
Type: text , Thesis , Masters , MCom
Identifier: http://hdl.handle.net/10962/97046 , vital:31390
Description: Countries such as South Africa have attempted to leverage eHealth by digitising patients’ medical records with the ultimate goal of improving the delivery of healthcare. This involves the use of the Electronic Health Record (EHR) which is a longitudinal electronic record of a patient’s information. The EHR is comprised of all of the encounters that have been made at different health facilities. In the national context, the EHR is also known as a national EHR which enables the sharing of patient information between points of care. Despite this, the realisation of a national EHR system puts patients' EHRs at risk. This is because patients’ information, which was once only available at local health facilities in the form of paper-based records, can be accessed anywhere within the country as a national EHR. This results in security and privacy issues since patients’ EHRs are shared with an increasing number of parties who are geographically distributed. This study proposes an access control model that will address the security and privacy issues by providing the right level of secure access to authorised clinicians. The proposed model is based on a combination of Role-Based Access Control (RBAC) and Attribute-Based Access Control (ABAC). The study found that RBAC is the most common access control model that is used within the healthcare domain where users’ job functions are based on roles. While RBAC is not able to handle dynamic events such as emergencies, the proposed model’s use of ABAC addresses this limitation. The development of the proposed model followed the design science research paradigm and was informed by the results of the content analysis plus an expert review. The content analysis sample was retrieved by conducting a systematic literature review and the analysis of this sample resulted in 6743 tags. The proposed model was evaluated using an evaluation framework via an expert review.
Full Text:
Date Issued: 2019

Quick View

Creating a new declaration of rights : a critical reconstruction of earth jurisprudence's global legislative framework

- Lenferna, Georges Alexandre

Authors: Lenferna, Georges Alexandre
Date: 2013
Subjects: Universal Declaration , Rights , Earth , Environment , Ethics , Environmental law, International -- Research , Environmental law, International -- Philosophy , Environmental ethics -- Research , Nature conservation -- Law and legislation -- Research , Jurisprudence -- Research , Law -- Philosophy
Language: English
Type: text , Thesis , Masters , MA
Identifier: vital:2704 , http://hdl.handle.net/10962/d1001979
Description: This thesis aims to critique the Universal Declaration of the Rights of Mother Earth and its underlying moral justification in order to provide a stronger and improved version of both. In Chapter 1 I explore what sort of moral justification is necessary to establish the Universal Declaration on firm grounds and explore its relation to environmental ethics and rights discourse. I argue that a non-anthropocentric perspective is necessary to justify the Universal Declaration’s rights. In Chapter 2 I explore the underlying justification of the Universal Declaration as discovered in the works of Cormac Cullinan and Father Thomas Berry. I argue that their ethical framework is indeterminate, has many ambiguities and uncertainties, and, among other problems, it does not provide a clear action-guiding framework. In Chapter 3 I develop an alternative justification for the Universal Declaration. I argue against many predominant moral theories, that in light of our best scientific and moral understanding we should expand the realm of moral concern to include all living beings, a moral theory I call Life’s Imperative. In Chapter 4 I illustrate that Life’s Imperative is a much stronger, more coherent justification for the Universal Declaration, one that coheres with both our best understanding of the natural world and our relation to it, and to an environmental ethic reflective of that relationship. Unfortunately many of the weaknesses in the current implicit justification of the Universal Declaration have also led to it enshrining rights that are themselves problematic. In order to address these issues, I revise its rights to accord with the stronger justification that I established in Chapter 3. The end result of doing so is a revised version of the Universal Declaration
Full Text:
Date Issued: 2013

Quick View

A formative intervention for developing Learner Representative Council (LRC) voice and leadership in a newly established school in Namibia

- Amadhila, Linda

Authors: Amadhila, Linda
Date: 2018
Subjects: School management and organization -- Namibia , Educational leadership -- Namibia , Education, Secondary -- Namibia , Student government -- Namibia , Student participation in administration -- Namibia
Language: English
Type: text , Thesis , Masters , MEd
Identifier: http://hdl.handle.net/10962/61744 , vital:28054
Description: In Namibian schools, learner voice and leadership are being promoted through the policy document entitled the Education Act 16 of2001 which provides an opportunity to establish Learner Representative Councils (LRCs) in secondary schools. However, recent studies have found that this body of learner leaders do not function all that effectively and sometimes exist for the sake of adhering to the policy. This prompted me to conduct an activity theoretical interventionist case- study within the critical paradigm, to develop LRC voice and leadership in a newly established Namibian school. Framed by Cultural Historical Activity Theory, the study was divided into two phases to answer the over-arching question: How can LRC voice and leadership be developed in a school? Phase one was largely interpretive, the contextual profiling phase, where document analysis, individual interviews, questionnaires and observations were used to generate data to answer the following research sub-questions: How is learner leadership understood in the school? What leadership development opportunities for the LRC currently exist in the school? What underlying factors constrain the development of LRC voice and leadership in the newly established school? Phase two of the study was the expansive learning phase, which consisted of three intervention workshops. The Change Laboratory method and a focus group interview were used to generate data in response to the last research sub-question: In what ways can LRC participation in a Change Laboratory process contribute to their leadership development? Data generated were inductively and deductively analysed, using the activity theoretical principles of contradictions and double stimulation. Data revealed that learner leadership was largely understood as managerial roles carried out by the LRC in the school. Unlike many schools in Namibia, this case-study school offered numerous leadership development opportunities for the LRC. The community networking events such as: School Exchange Programmes, Town Council breakfast and Junior Regional Council, were opportunities offered to the LRC to solicit information, exchange ideas and discuss matters of common interest with the LRCs of the fully established schools. However, there were a number of challenges that constrained LRC voice and leadership development, the major one being the fact that this was a newly established school. Of significance was that LRC participation in the Change Laboratory process contributed positively to the development of voice and leadership in learners. During this Change Laboratory process, the LRC developed a new artefact - the vision and mission statement of the school - this signified that the learners expansively transformed the object of their activity. Recommendations emerging out of the study included that the School Management Team see the ‘newly established’ status of the school as an opportunity for development, rather than a limitation, and therefore invite the LRC to participate in the different leadership practices as the school becomes established. A significant recommendation for school leadership research is to use the third generation of CHAT to expand the unit of analysis, in order to understand the leadership relations and power dynamics between multiple activity systems in schools as complex organisations.
Full Text:
Date Issued: 2018

Quick View

A gender based analysis of the Amalima Programme in empowering married women within households in rural Gwanda, Zimbabwe

- Sibanda, Patience

Authors: Sibanda, Patience
Date: 2018
Subjects: Non-governmental organizations Zimbabwe Matabeleland South Province , Power (Social sciences) Zimbabwe Matabeleland South Province , Women Zimbabwe Social conditions , Women's rights Zimbabwe , Patriarchy Zimbabwe Matabeleland South Province
Language: English
Type: text , Thesis , Masters , MA
Identifier: http://hdl.handle.net/10962/63682 , vital:28470
Description: Non-Governmental Organisations (NGOs) have occupied a prominent role in the socio-economic development of rural areas of Zimbabwe since the time of the country’s independence in 1980, including a focus on improving the conditions and status of women in communal areas. These NGOs adopt a participatory methodology in their development programmes and projects, as they try to ensure that the active participation of women in rural development facilitates women’s access to resources and the realisation of their rights. These initiatives are important given the pronounced system of patriarchy which exists in communal areas. In the context of local patriarchies, NGOs also often claim that they empower women. This thesis focuses on the work of one particular NGO programme, namely the Amalima programme, with a particular focus on three wards in the communal areas in Gwanda, Zimbabwe. From a gendered perspective concerned with questions of women’s empowerment, the main objective of the thesis is to provide a critical analysis of the Amalima programme with particular reference to married women in Gwanda. Based on original fieldwork (including interviews with men, women and NGO practitioners), the thesis concludes that the outcomes of the Amalima programme in empowering married women in Gwanda are uneven and that, overall, the local system of patriarchy (including at household level) remains largely intact.
Full Text:
Date Issued: 2018

Quick View

Electrocatalytic activity of symmetric and asymmetric Co(II) and Mn(III) porphyrins in the presence of graphene quantum dots towards the oxidation of hydrazine

- Jokazi, Mbulelo

Authors: Jokazi, Mbulelo
Date: 2022-10-14
Subjects: Electrocatalysis , Hydrazine , Quantum dots , Graphene , Porphyrins
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/362894 , vital:65372
Description: The influence of metal porphyrins in electro-oxidation of hydrazine is explored. A series of symmetric and asymmetric porphyrins alone and in the presence of graphene quantum dots (GQDs) are employed in this work. Tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin--GQDs, and manganese tetra 4-aminophenyl porphyrin@GQDs are the symmetric porphyrins. The asymmetric porphyrin and composites are 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs, and cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs. These complexes were synthesized and characterized accordingly and applied for electrocatalysis. The electrocatalytic experiments were carried out using glassy carbon electrode and the modification was through drop-dry method. The porphyrin and GQDs synthesized were characterized using UV-Vis spectroscopy, Mass spectrometry, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy. The modified electrodes were characterized using cyclic voltammetry and electrochemical Impedance spectroscopy. The introduction of metal ion in the center of the porphyrin improved electrocatalysis. The presence of push-pull substituents in the porphyrin lowered the oxidation potential and improved the catalysis. The presence of GQDs improved catalysis in both symmetric and asymmetric porphyrin compared to individual components. Cobalt porphyrins showed better activity than manganese porphyrin. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
Full Text:
Date Issued: 2022-10-14

Quick View

Chemical composition of leaf essential oils of Lantana camara varieties in South Africa and their effect on the behavioural preference of Falconia intermedia

- Ngxande-Koza, Samella W

Authors: Ngxande-Koza, Samella W
Date: 2017
Language: English
Type: text , Thesis , Masters , MSc
Identifier: http://hdl.handle.net/10962/4877 , vital:20739
Description: Lantana camara L. (Verbenaceae) is one the most problematic invaders in South Africa invading forest edges, sand dunes, and shorelines by forming impenetrable thickets. Lantana camara invasions degrade natural biodiversity, reduce the value of land and consequently it has been a target for biological control, over the last 50 years in South Africa. Studies that have reported on chemical profile of Lantana camara have been conducted around the world but not in South Africa. Hence, the first aim of the current study was to identify the chemical baseline of L. camara varieties in the Eastern Cape, South Africa. Recent studies have shown that feeding by one of the agents released against L. camara, Falconia intermedia (Distant) (Hemiptera: Miridae), induces anti-herbivory response through increased leaf toughness and trichome density. A preliminary study conducted also reported the production of volatile chemicals by one variety, Whitney Farm, due to feeding by the mirids. Therefore, the second aim was to determine the induced changes in chemical compounds of L. camara varieties after feeding by F. intermedia. A third aim was to determine the effect these chemical compounds have on the behaviour of F. intermedia. To identify the chemical baseline of L. camara varieties, the essential oils of four L. camara varieties (East London, Port Alfred, Whitney Farm and Heather Glen) were analysed using gas chromatography mass spectrometry (GC-MS) and that resulted to the identification of 163 constitutive and 75 induced chemicals across the varieties tested. Lantana camara varieties showed different chemical classes but were highly dominated by terpenes. A great variation in the number of constitutive chemical compounds was found in all the varieties. There were 56 constitutive chemical compounds in the Whitney Farm variety, 41 in the East London variety, 36 in the Heather Glen variety and 30 in the Port Alfred variety. The Whitney Farm variety had the highest number (22) of unique constitutive chemicals identified when compared with other varieties. This indicates the chemical distinctiveness of the Whitney Farm variety from the other varieties. In the varieties tested, there were common chemical compounds identified in constitutive and induced (discussed below) states of the plants such as caryophyllene, hexane, naphthalene, copaene and a-caryophyllene. Besides naphthalene, the majority of chemical compounds in South African L. camara varieties were similar to compounds that have been identified across the world, suggesting that they are closely related. The expression of naphthalene in these varieties may be due to changes in the chemicals expressed over evolutionary time as predicted by the Novel Weapons Hypothesis. Amongst the varieties, a great variation in chemical compounds and their concentrations was shown in the induced states of the plants. The concentration of constitutive caryophyllene ranged from (3.13 - 15.7) %, to (4.02 - 11.10) % after feeding. The concentration of constitutive hexane ranged from (6.13 - 71.19) %, to (33.3 - 75.8) % after feeding. The concentration of constitutive naphthalene ranged from (0.21 - 4.79) %, to (0.92 - 2.11) % after feeding. The concentration of constitutive copaene ranged from (0.57 - 1.57) %, to (1.20 - 2.72) %. Lastly, the concentration of constitutive a-caryophyllene ranged from (1.18 - 9.03) %, to (0.78 - 5.48) % after feeding. The changes in chemical concentrations in lantana varieties indicated that feeding by the mirid on L. camara varieties causes an induction by either reducing or increasing the chemical concentrations. To determine the effect of the identified compounds on the behaviour of F. intermedia adults, olfactometer bioassays were conducted using a Y-tube technique. A significantly higher proportion of F. intermedia were attracted to undamaged leaves over damaged leaves and purified air. Undamaged leaves attracted 52 % of F. intermedia from the East London variety, 62.5 % from the Port Alfred variety, 56 % from the Whitney Farm variety, 58 % from the Lyndhurst variety and 54.5 % from the Heather Glen variety in dual choice trials versus damaged leaves. Furthermore, a significantly higher proportion of F. intermedia were attracted to damaged leaves over purified air. Damaged leaves attracted 67 % of F. intermedia from the East London variety, 67 % from the Port Alfred variety, 65.9 % from the Whitney Farm variety, 65.3 % from the Heather Glen variety and 64.5 % from the Lyndhurst variety. Olfactometer bioassays were also conducted using purified standard compounds of four chemical compounds identified from essential oils, hexane was used as a positive control as it is reported to be an insect attractant in literature. Hexane was highly attractive to the mirids compared to three standard compounds caryophyllene, caryophyllene oxide and naphthalene at the rate of 80 %, 73 % and 80 %, respectively. The standard compounds tested against F. intermedia are major compounds contained by L. camara varieties and they have proven to have a repellent effect. This may indicate that after feeding by F. intermedia, the major compounds expressed by the plant varieties repel F. intermedia contributing to the invasiveness of this weed. The increased expression of hexane and caryophyllene after feeding may also indicate increased attraction to some insects, opening up the potential for third trophic level interactions in varieties where this is the case. This is the first study on the chemical composition of essential oils of L. camara in South Africa. Therefore, we recommend that where appropriate chemical profile studies of the invasive alien plants should be considered during host specificity testing, and the vital role of chemical compounds on agent-weed interactions must be taken into consideration with other factors before and after the biological control agents are released.
Full Text:
Date Issued: 2017

Quick View

A Systematic Visualisation Framework for Radio-Imaging Pipelines

- Andati, Lexy Acherwa Livoyi

Authors: Andati, Lexy Acherwa Livoyi
Date: 2021-04
Subjects: Radio interferometers , Radio astronomy -- Data processing , Radio astronomy -- Data processing -- Software , Jupyter
Language: English
Type: thesis , text , Masters , MSc
Identifier: http://hdl.handle.net/10962/177338 , vital:42812
Description: Pipelines for calibration and imaging of radio interferometric data produce many intermediate images and other data products (gain tables, etc.) These often contain valuable information about the quality of the data and the calibration, and can provide the user with valuable insights, if only visualised in the right way. However, the deluge of data that we’re experiencing with modern instruments means that most of these products are never looked at, and only the final images and data products are examined. Furthermore, the variety of imaging algorithms currently available, and the range of their options, means that very different results can be produced from the same set of original data. Proper understanding of this requires a systematic comparison that can be carried out both by individual users locally, and by the community globally. We address both problems by developing a systematic visualisation framework based around Jupyter notebooks, enriched with interactive plots based on the Bokeh and Datashader visualisation libraries. , Thesis (MSc) -- Faculty of Science, Department of Physics and Electronics, 2021
Full Text:
Date Issued: 2021-04

Quick View

Design of pH Sensitive Electrochemical Sensor for Catecholamine Neurotransmitters Detection and the Screening Off of Ascorbic Acid

- Tshenkeng, Keamogetse Tebogo Charlotte

Authors: Tshenkeng, Keamogetse Tebogo Charlotte
Date: 2021-10-29
Subjects: Catecholamines , Electrochemical sensors , Neurotransmitters , Vitamin C , Cobalt , Phthalocyanines , Cobalt (II) tetra-(3-carboxyphenoxy) phthalocyanine (CoTCPhOPc)
Language: English
Type: thesis , text
Identifier: http://hdl.handle.net/10962/176921 , vital:42772
Description: This study presents the synthesis of cobalt (II) tetra-(3-carboxyphenoxy) phthalocyanine (CoTCPhOPc) through the cyclotetramerization of 4-(3-carboxyphe-noxy)phthalonitrile and its full characterization using Fourier transform infrared (FT-IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy, magnetic circular dichroism (MCD) spectroscopy, elemental analysis and mass spectrometry. The CoTCPhOPc was then immobilized onto phenylethylamino (PEA) pre-grafted gold electrode surface, Au-PEA using amide coupling reaction through a reaction with NHS and DCC to obtain Au-PEA-CoTCPhOPc. This yielded pH sensitive thin films due to the terminal carboxylic acid (–COOH) functional groups. Electrochemical and surface characterization was conducted to confirm the modification of the bare Au with PEA thin film (Au-PEA) and amide coupling of CoTCPhOPc (Au-PEA-CoTCPhOPc). The Au-PEA-CoTCPhOPc electrode was shown to possess pH selective properties towards negatively charged [Fe(CN)6]3-/4- and positively charged [Ru(NH3)6]2+/3+ redox probes. Au-PEA-CoTCPhOPc electrode surface enabled the detection of catecholamine neurotransmitters (dopamine, norepinephrine and epinephrine) and the screening off of ascorbic acid by means of pH sensitive functional groups. Bare Au and Au-PEA electrodes exhibited electro-oxidation and electroreduction of catecholamine neuro-transmitters and ascorbic acid at higher potentials compared to Au-PEA-CoTCPhOPc. There was no electro-oxidation or electroreduction of ascorbic acid at Au-PEA-CoTCPhOPc. For Au-PEA-CoTCPhOPc, excellent electrocatalytic oxidation with the limit of detection (LoD) determined using 3σ was found to be 1.32 (0.95), 2.11 (1.78) and 3.08 μM for electro-oxidation and electroreduction (in brackets) of dopamine, norepinephrine and epinephrine respectively. The limit of quantification (LoQ) was determined using 10σ and found to be 4.41 (3.17), 7.02 (5.93) and 10.3 μM electro-oxidation and electroreduction (in brackets) for dopamine, norepinephrine and epinephrine respectively. The Au-PEA-CoTCPhOPc thin film was shown to screen off ascorbic acid as no electrocatalytic oxidation was observed for up to 100.0 μM concentration. , Thesis (MSc) -- Faculty of Science, Department of Chemistry, 2021
Full Text:
Date Issued: 2021-10-29

Quick View

Biton’s Lost Siege Engine: Experimental archaeology in Classical Studies

- Rademan, David John

Authors: Rademan, David John
Date: 2021-10-29
Subjects: Pergamum (Extinct city) , Dimensional analysis , Engineering History To 168 B.C. , Fluid mechanics History To 168 B.C. , Byzantine literature History and criticism , Siege warfare History To 168 B.C. , Biton of Pergamon , Isidorus of Abydos , Poliorcetics
Language: English
Type: Master's theses , text
Identifier: http://hdl.handle.net/10962/192330 , vital:45216
Description: This thesis entails an examination of several problems inherent in placing a technical treatise by the Hellenistic Greek engineer, Biton of Pergamon, at a siege of 156-154BCE, with a view to galvanising the existing case of previous scholarship through a combined approach of literary, textual, geographical, and technical analysis. Particular focus is given to the following problems: technical errors in current translations of the treatise of Biton; technical considerations in scholars’ reproductions of a particular engine in the treatise; an assessment of the practical implications of the treatise in situ at the physical site of the ancient city of Pergamon in the second century BCE, as evidenced by archaeological findings and surveys; assessment of those implications by way of historical records of similar conflicts from the Hellenistic period; and suggesting a procedure of dimensional analysis for testing a hypothesis regarding the feasibility of the ancient engineer’s recommended engines as a stand-in for the city’s original defenses, in a manner that harmonises the methodologies of historicism and experimental archaeology with sound and appropriate modern engineering practice from the field of Fluid Mechanics. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2021
Full Text:
Date Issued: 2021-10-29

Showing items 101 - 120 of 2169