Perceived success of skills-development readiness within 4IR in RSA
- Authors: Hunt, Norman William
- Date: 2021-04
- Subjects: Technological innovations -- Economic aspects , Labor demand -- Research -- South Africa , Labor supply -- Research -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/51567 , vital:43310
- Description: The purpose of this study was to develop four scenarios for South Africa over the next forty years. The Positive Seed scenario portrays a positive image of hope and determination, with positive institutional innovations, as well as positive innovative learning methodologies. While the Shankar scenario also portrays positive institutional innovations, it is lacking in terms of innovation learning methodologies. The Negative Seed is lacking in both innovation learning methodologies, as well as institutional innovations. Finally, the fourth scenario, that of the ‘What If’ scenario, portrays a scenario whether good innovative learning methodologies exist, or not, but lacks institutional innovativeness. The goal of this thesis was not only to affirm the known and knowable about the skills-development environment, but it is also aimed at exploring its future within the 4IR towards 2060. This was achieved by scenario planning and the Causal Layered Analyses (CLA) methodology, which is designed to help navigate through this creative process. This thesis starts off by identifying the forces of change, which it then combines in various ways to create the set of scenarios about how the future of the skills-development sector could evolve towards 2060. This thesis provides useful insight into drivers for change for the South African skills-development sector and how to anticipate skills-readiness in South Africa within the 4IR towards 2060 in accordance with the CLA and scenario planning methods. This thesis looks at the future of skills-development in South Africa over the next forty years from a decision makers point of view. , Thesis (DBA) -- Faculty of Business and Economic Sciences, Business Administration, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Hunt, Norman William
- Date: 2021-04
- Subjects: Technological innovations -- Economic aspects , Labor demand -- Research -- South Africa , Labor supply -- Research -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/51567 , vital:43310
- Description: The purpose of this study was to develop four scenarios for South Africa over the next forty years. The Positive Seed scenario portrays a positive image of hope and determination, with positive institutional innovations, as well as positive innovative learning methodologies. While the Shankar scenario also portrays positive institutional innovations, it is lacking in terms of innovation learning methodologies. The Negative Seed is lacking in both innovation learning methodologies, as well as institutional innovations. Finally, the fourth scenario, that of the ‘What If’ scenario, portrays a scenario whether good innovative learning methodologies exist, or not, but lacks institutional innovativeness. The goal of this thesis was not only to affirm the known and knowable about the skills-development environment, but it is also aimed at exploring its future within the 4IR towards 2060. This was achieved by scenario planning and the Causal Layered Analyses (CLA) methodology, which is designed to help navigate through this creative process. This thesis starts off by identifying the forces of change, which it then combines in various ways to create the set of scenarios about how the future of the skills-development sector could evolve towards 2060. This thesis provides useful insight into drivers for change for the South African skills-development sector and how to anticipate skills-readiness in South Africa within the 4IR towards 2060 in accordance with the CLA and scenario planning methods. This thesis looks at the future of skills-development in South Africa over the next forty years from a decision makers point of view. , Thesis (DBA) -- Faculty of Business and Economic Sciences, Business Administration, 2021
- Full Text:
- Date Issued: 2021-04
Assessing service delivery protests in the Nelson Mandela Bay Municipality: the case of Walmer Township
- Authors: Mdanyana, Esethu
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54492 , vital:46609
- Description: In many South Africa’s areas, citizen’s frustration with poor or slow service delivery has resulted in a surge of service delivery protests. Some of these service delivery protests are violent in nature, resulting in the damage of public and private property. Therefore, it is imperative to scrutinize service delivery protests. The South African constitution states that municipalities have the responsibility to make sure that all citizens are provided with services to satisfy their basic needs. These services include water supply, sewage collection and disposal electricity, gas supply health services, roads, storm water drainage, street lighting, municipal parks and recreation. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text: false
- Date Issued: 2021-12
- Authors: Mdanyana, Esethu
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54492 , vital:46609
- Description: In many South Africa’s areas, citizen’s frustration with poor or slow service delivery has resulted in a surge of service delivery protests. Some of these service delivery protests are violent in nature, resulting in the damage of public and private property. Therefore, it is imperative to scrutinize service delivery protests. The South African constitution states that municipalities have the responsibility to make sure that all citizens are provided with services to satisfy their basic needs. These services include water supply, sewage collection and disposal electricity, gas supply health services, roads, storm water drainage, street lighting, municipal parks and recreation. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text: false
- Date Issued: 2021-12
Modifcations to gravitational waves due to matter shells
- Authors: Naidoo, Monogaran
- Date: 2021-10-29
- Subjects: Gravitational waves , General relativity (Physics) , Einstein field equations , Cosmology , Matter shells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191118 , vital:45062 , 10.21504/10962/191119
- Description: As detections of gravitational waves (GWs) mount, the need to investigate various effects on the propagation of these waves from the time of emission until detection also grows. We investigate how a thin low density dust shell surrounding a gravitational wave source affects the propagation of GWs. The Bondi-Sachs (BS) formalism for the Einstein equations is used for the problem of a gravitational wave (GW) source surrounded by a spherical dust shell. Using linearised perturbation theory, we and the geometry of the regions exterior to, interior to and within the shell. We and that the dust shell causes the gravitational wave to be modified both in magnitude and phase, but without any energy being transferred to or from the dust. This finding is novel. In the context of cosmology, apart from the gravitational redshift, the effects are too small to be measurable; but the effect would be measurable if a GW event were to occur with a source surrounded by a massive shell and with the radius of the shell and the wavelength of the GWs of the same order. We extended our investigation to astrophysical scenarios such as binary black hole (BBH) mergers, binary neutron star (BNS) mergers, and core collapse supernovae (CCSNe). In these scenarios, instead of a monochromatic GW source, as we used in our initial investigation, we consider burst-like GW sources. The thin density shell approach is modified to include thick shells by considering concentric thin shells and integrating. Solutions are then found for these burst-like GW sources using Fourier transforms. We show that GW echoes that are claimed to be present in the Laser Interferometer Gravitational-Wave Observatory (LIGO) data of certain events, could not have been caused by a matter shell. We do and, however, that matter shells surrounding BBH mergers, BNS mergers, and CCSNe could make modifications of order a few percent to a GW signal. These modifications are expected to be measurable in GW data with current detectors if the event is close enough and at a detectable frequency; or in future detectors with increased frequency range and amplitude sensitivity. Substantial use is made of computer algebra in these investigations. In setting the scene for our investigations, we trace the evolution of general relativity (GR) from Einstein's postulation in 1915 to vindication of his theory with the confirmation of the existence of GWs a century later. We discuss the implications of our results to current and future considerations. Calculations of GWs, both analytical and numerical, have normally assumed their propagation from source to a detector on Earth in a vacuum spacetime, and so discounted the effect of intervening matter. As we enter an era of precision GW measurements, it becomes important to quantify any effects due to propagation of GWs through a non-vacuum spacetime Observational confirmation of the modification effect that we and in astrophysical scenarios involving black holes (BHs), neutron stars (NSs) and CCSNe, would also enhance our understanding of the details of the physics of these bodies. , Thesis (PhD) -- Faculty of Science, Mathematics (Pure and Applied), 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Naidoo, Monogaran
- Date: 2021-10-29
- Subjects: Gravitational waves , General relativity (Physics) , Einstein field equations , Cosmology , Matter shells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/191118 , vital:45062 , 10.21504/10962/191119
- Description: As detections of gravitational waves (GWs) mount, the need to investigate various effects on the propagation of these waves from the time of emission until detection also grows. We investigate how a thin low density dust shell surrounding a gravitational wave source affects the propagation of GWs. The Bondi-Sachs (BS) formalism for the Einstein equations is used for the problem of a gravitational wave (GW) source surrounded by a spherical dust shell. Using linearised perturbation theory, we and the geometry of the regions exterior to, interior to and within the shell. We and that the dust shell causes the gravitational wave to be modified both in magnitude and phase, but without any energy being transferred to or from the dust. This finding is novel. In the context of cosmology, apart from the gravitational redshift, the effects are too small to be measurable; but the effect would be measurable if a GW event were to occur with a source surrounded by a massive shell and with the radius of the shell and the wavelength of the GWs of the same order. We extended our investigation to astrophysical scenarios such as binary black hole (BBH) mergers, binary neutron star (BNS) mergers, and core collapse supernovae (CCSNe). In these scenarios, instead of a monochromatic GW source, as we used in our initial investigation, we consider burst-like GW sources. The thin density shell approach is modified to include thick shells by considering concentric thin shells and integrating. Solutions are then found for these burst-like GW sources using Fourier transforms. We show that GW echoes that are claimed to be present in the Laser Interferometer Gravitational-Wave Observatory (LIGO) data of certain events, could not have been caused by a matter shell. We do and, however, that matter shells surrounding BBH mergers, BNS mergers, and CCSNe could make modifications of order a few percent to a GW signal. These modifications are expected to be measurable in GW data with current detectors if the event is close enough and at a detectable frequency; or in future detectors with increased frequency range and amplitude sensitivity. Substantial use is made of computer algebra in these investigations. In setting the scene for our investigations, we trace the evolution of general relativity (GR) from Einstein's postulation in 1915 to vindication of his theory with the confirmation of the existence of GWs a century later. We discuss the implications of our results to current and future considerations. Calculations of GWs, both analytical and numerical, have normally assumed their propagation from source to a detector on Earth in a vacuum spacetime, and so discounted the effect of intervening matter. As we enter an era of precision GW measurements, it becomes important to quantify any effects due to propagation of GWs through a non-vacuum spacetime Observational confirmation of the modification effect that we and in astrophysical scenarios involving black holes (BHs), neutron stars (NSs) and CCSNe, would also enhance our understanding of the details of the physics of these bodies. , Thesis (PhD) -- Faculty of Science, Mathematics (Pure and Applied), 2021
- Full Text:
- Date Issued: 2021-10-29
Photodegradation of tetracycline by asymmetrical zinc (II) phthalocyanines conjugated to cobalt tungstate nanoparticles
- Mgidlana, Sithi, Sen, Pinar, Nyokong, Tebello
- Authors: Mgidlana, Sithi , Sen, Pinar , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300233 , vital:57908 , xlink:href="https://doi.org/10.1016/j.molstruc.2022.132938"
- Description: This work focused on syntheses of novel asymmetrically tetra substituted Zn phthalocyanines (ZnPc) each containing a single carboxyl group, with the other substituents bearing alkynyl (complex 1) and fluorine containing groups (complexes 2 and 3). The complexes were conjugated to cobalt tungstate nanoparticles and employed as efficient photocatalysts for degradation of tetracycline in water. ZnPc complexes and their conjugates showed good photophysical and photochemical properties behaviour with complex 1 giving higher triplet and singlet oxygen quantum yields compared to 2 and 3. Complex 1 showed higher activity towards the photodegradation of tetracycline compared to complexes 2 and 3, with higher kobs and initial rates for the former. The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model.
- Full Text:
- Date Issued: 2022
- Authors: Mgidlana, Sithi , Sen, Pinar , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300233 , vital:57908 , xlink:href="https://doi.org/10.1016/j.molstruc.2022.132938"
- Description: This work focused on syntheses of novel asymmetrically tetra substituted Zn phthalocyanines (ZnPc) each containing a single carboxyl group, with the other substituents bearing alkynyl (complex 1) and fluorine containing groups (complexes 2 and 3). The complexes were conjugated to cobalt tungstate nanoparticles and employed as efficient photocatalysts for degradation of tetracycline in water. ZnPc complexes and their conjugates showed good photophysical and photochemical properties behaviour with complex 1 giving higher triplet and singlet oxygen quantum yields compared to 2 and 3. Complex 1 showed higher activity towards the photodegradation of tetracycline compared to complexes 2 and 3, with higher kobs and initial rates for the former. The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model.
- Full Text:
- Date Issued: 2022
Profiling Rhodes University students’ substance use during the Covid-19 pandemic lockdown: comparing the AUDIT and CCAPS-62 substance abuse sub-scale
- Authors: Goosen, Jeslyn Chrismaré
- Date: 2022-10-14
- Subjects: College students Substance use South Africa Makhanda , College students Alcohol use South Africa Makhanda , College students Mental health South Africa Makhanda , College students Attitudes , College students Economic conditions , COVID-19 (Disease) , Rhodes University
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405974 , vital:70224
- Description: Students are vulnerable to academic distress and mental health concerns. Many struggle to effectively cope with the many demands placed on them from various factions; included but not limited to institutional demands, financial concerns, and parental expectations. With the most recent outbreak of the SARS-Co V-2 (better known as the COVID-19 pandemic) many students have struggled to effectively cope with the changes relating to the nationwide lockdown. Universities had to change the way in which they provide students with the necessary academic material, and many had to return to their familial homes. This had a deleterious effect on the way students performed their daily activities and coping. A rise in impaired mental health was noted. Many students used alcohol as a means of coping during this tumultuous and unprecedented time. Undergraduate students at Rhodes University were asked to complete a survey questionnaire via SurveyMonkey, an online survey service. Data was collected over a ten-day period during July 2020. The AUDIT and the CCAPS-62 Substance Use subscale were used to measure their alcohol intake during lockdown and results was compared. Results indicated a significant positive correlation between the CCAPS-62 substance use subscale and the AUDIT (r = 0.80, n = 930, p < 0.01). Outcomes identified that men tend to drink more than females, and white students tend to drink more than black students. Findings suggests that the CCAPS-62 a multidimensional instrument measuring general distress among students could positively contribute to the reliability and validity of the measure used in a multicultural and multilingual society such as South Africa. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Goosen, Jeslyn Chrismaré
- Date: 2022-10-14
- Subjects: College students Substance use South Africa Makhanda , College students Alcohol use South Africa Makhanda , College students Mental health South Africa Makhanda , College students Attitudes , College students Economic conditions , COVID-19 (Disease) , Rhodes University
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405974 , vital:70224
- Description: Students are vulnerable to academic distress and mental health concerns. Many struggle to effectively cope with the many demands placed on them from various factions; included but not limited to institutional demands, financial concerns, and parental expectations. With the most recent outbreak of the SARS-Co V-2 (better known as the COVID-19 pandemic) many students have struggled to effectively cope with the changes relating to the nationwide lockdown. Universities had to change the way in which they provide students with the necessary academic material, and many had to return to their familial homes. This had a deleterious effect on the way students performed their daily activities and coping. A rise in impaired mental health was noted. Many students used alcohol as a means of coping during this tumultuous and unprecedented time. Undergraduate students at Rhodes University were asked to complete a survey questionnaire via SurveyMonkey, an online survey service. Data was collected over a ten-day period during July 2020. The AUDIT and the CCAPS-62 Substance Use subscale were used to measure their alcohol intake during lockdown and results was compared. Results indicated a significant positive correlation between the CCAPS-62 substance use subscale and the AUDIT (r = 0.80, n = 930, p < 0.01). Outcomes identified that men tend to drink more than females, and white students tend to drink more than black students. Findings suggests that the CCAPS-62 a multidimensional instrument measuring general distress among students could positively contribute to the reliability and validity of the measure used in a multicultural and multilingual society such as South Africa. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-14
Assessment of the implementation of performance management system at Mnquma Local municipality of the Eastern Cape Province
- Authors: Mbiko, Khanyiso Livingstone
- Date: 2008-12
- Subjects: Performance -- Management , Personnel management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24165 , vital:62439
- Description: The intention of this study was to assess the implementation of performance management system at the Mnquma local municipality. The municipality of Mnquma has in the past been plagued by service delivery challenges and thus the study sought to ascertain whether the challenges could be attributed to the failures of the performance management system within the municipality. It became apparent from the literature review that for any local municipality to play a meaningful role in ensuring that South Africa achieves the goal of becoming a developmental state, capable of confronting service delivery challenges, there needs to be a proper implementation of the performance management system. The study was also aimed at identifying the factors that support or hinder the implementation of the performance management system within the Mnquma local municipality. In order to achieve this objective, scheduled interviews were conducted with various respondents in the municipality. The respondents included the councilors from the four political parties comprising the municipality council, municipal manager and the rest of the Section 57 managers. The key findings that emerged from the data collected, was that the implementation of the performance management system has not been successful. It is also became apparent that there are brewing political tensions that are likely to affect the political stability of the municipality. In addition, it was also evident that there was a minimal or lack of involvement of the local communities in the municipal affairs such as the development of the Municipal Key Performance Indicators. It would therefore be critical important for the management of the Mnquma local municipality to take into account the results of this study and its recommendations so as to ensure that there is a proper implementation of the performance management system within the municipality. , Thesis (MPA) -- Faculty of Management and Commerce, 2008
- Full Text:
- Date Issued: 2008-12
- Authors: Mbiko, Khanyiso Livingstone
- Date: 2008-12
- Subjects: Performance -- Management , Personnel management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24165 , vital:62439
- Description: The intention of this study was to assess the implementation of performance management system at the Mnquma local municipality. The municipality of Mnquma has in the past been plagued by service delivery challenges and thus the study sought to ascertain whether the challenges could be attributed to the failures of the performance management system within the municipality. It became apparent from the literature review that for any local municipality to play a meaningful role in ensuring that South Africa achieves the goal of becoming a developmental state, capable of confronting service delivery challenges, there needs to be a proper implementation of the performance management system. The study was also aimed at identifying the factors that support or hinder the implementation of the performance management system within the Mnquma local municipality. In order to achieve this objective, scheduled interviews were conducted with various respondents in the municipality. The respondents included the councilors from the four political parties comprising the municipality council, municipal manager and the rest of the Section 57 managers. The key findings that emerged from the data collected, was that the implementation of the performance management system has not been successful. It is also became apparent that there are brewing political tensions that are likely to affect the political stability of the municipality. In addition, it was also evident that there was a minimal or lack of involvement of the local communities in the municipal affairs such as the development of the Municipal Key Performance Indicators. It would therefore be critical important for the management of the Mnquma local municipality to take into account the results of this study and its recommendations so as to ensure that there is a proper implementation of the performance management system within the municipality. , Thesis (MPA) -- Faculty of Management and Commerce, 2008
- Full Text:
- Date Issued: 2008-12
Livelihood implications of a possible Ramsar declaration of the Swartkops estuary, Eastern Cape, South Africa
- Authors: Vembo, Glen Muchengeti
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164715 , vital:41157
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Environmental Science, 2020
- Full Text:
- Date Issued: 2020
- Authors: Vembo, Glen Muchengeti
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164715 , vital:41157
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Environmental Science, 2020
- Full Text:
- Date Issued: 2020
Re-imagining Afrikaner masculinity through conceptual fashion design
- Authors: Smit, Dalton
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54563 , vital:46708
- Description: Traditional Afrikaner culture has often been associated with conservative beliefs, giving patriarchal figures such as the husband and father superior status. Although South Africa has undergone social progression, large numbers in Afrikaner communities still live according to old, patriarchal norms. My perceptions of Afrikaner masculinity, informed by my cultural background, enforce patriarchy's functioning in some Afrikaner homes, allowing the development of rigid expectations of a male's self-expression. These mind-sets of what masculinity is do not align with my values, beliefs, and the visual presentation of my identity. With the application of autoethnographic inquiry in this practice-based study, I was able to analyse and interpret the nuanced discrimination against the performance of my male identity in an Afrikaner cultural context. I implemented autoethnographic and practice-based methods to respond to and challenge outdated and conservative views regarding the prevalence of Afrikaner masculine ideals and their negative implications. The contribution of the research practice is FYN BOI, a fictive persona constructed and performed by me. He represents a liberated facet of my identity whose reaction is rejection against the Afrikaner cultural opinions of me, and in turn, is fuelled by the criticism to provoke further and challenge these views. The conceptual garments created are considered his wardrobe, which he uses in his self-expression online. With this unconventional approach to a fashion study, disseminating the research practice online instead of a physical exhibition allows for the study to be accessed to audiences beyond academia's domain. This undertaking intends to contribute to the existing discourse of masculinity and prejudice against individuals' self-expression of their identity. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Smit, Dalton
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54563 , vital:46708
- Description: Traditional Afrikaner culture has often been associated with conservative beliefs, giving patriarchal figures such as the husband and father superior status. Although South Africa has undergone social progression, large numbers in Afrikaner communities still live according to old, patriarchal norms. My perceptions of Afrikaner masculinity, informed by my cultural background, enforce patriarchy's functioning in some Afrikaner homes, allowing the development of rigid expectations of a male's self-expression. These mind-sets of what masculinity is do not align with my values, beliefs, and the visual presentation of my identity. With the application of autoethnographic inquiry in this practice-based study, I was able to analyse and interpret the nuanced discrimination against the performance of my male identity in an Afrikaner cultural context. I implemented autoethnographic and practice-based methods to respond to and challenge outdated and conservative views regarding the prevalence of Afrikaner masculine ideals and their negative implications. The contribution of the research practice is FYN BOI, a fictive persona constructed and performed by me. He represents a liberated facet of my identity whose reaction is rejection against the Afrikaner cultural opinions of me, and in turn, is fuelled by the criticism to provoke further and challenge these views. The conceptual garments created are considered his wardrobe, which he uses in his self-expression online. With this unconventional approach to a fashion study, disseminating the research practice online instead of a physical exhibition allows for the study to be accessed to audiences beyond academia's domain. This undertaking intends to contribute to the existing discourse of masculinity and prejudice against individuals' self-expression of their identity. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
Fluorescence behaviour of supramolecular hybrids containing graphene quantum dots and pyrene-derivatized phthalocyanines and porphyrins
- Achadu, Ojodomo John, Managa, Muthumuni, Nyokong, Tebello
- Authors: Achadu, Ojodomo John , Managa, Muthumuni , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188953 , vital:44801 , xlink:href="https://doi.org/10.1016/j.jphotochem.2016.10.029"
- Description: Novel pyrene-derivatized zinc and cobalt phthalocyanines (Pcs) and porphyrins (Ps) were immobilized on graphene quantum dots (GQDs) to form GQDs-Pcs and GQDs-Ps supramolecular hybrids via the π–π stacking interaction method. Spectroscopic evidence shows that the resultant hybrids were stable owing to the strong π–π stacking interaction between the GQDs and the respective Pcs and Ps, thus leading to the fabrication of interesting and functional supramolecular hybrids by taking advantage of the delocalized π electron systems of GQDs and the macrocycles. The conjugates showed increased fluorescence quantum yields for the Pcs/Ps, but decreased values for the GQDs in the conjugates. These novel hybrid materials could potentially be deployed for studies in both fundamental and applied perspectives due to the synergistic contributions resulting from the combination of their excellent electronic and optical properties.
- Full Text:
- Date Issued: 2017
- Authors: Achadu, Ojodomo John , Managa, Muthumuni , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188953 , vital:44801 , xlink:href="https://doi.org/10.1016/j.jphotochem.2016.10.029"
- Description: Novel pyrene-derivatized zinc and cobalt phthalocyanines (Pcs) and porphyrins (Ps) were immobilized on graphene quantum dots (GQDs) to form GQDs-Pcs and GQDs-Ps supramolecular hybrids via the π–π stacking interaction method. Spectroscopic evidence shows that the resultant hybrids were stable owing to the strong π–π stacking interaction between the GQDs and the respective Pcs and Ps, thus leading to the fabrication of interesting and functional supramolecular hybrids by taking advantage of the delocalized π electron systems of GQDs and the macrocycles. The conjugates showed increased fluorescence quantum yields for the Pcs/Ps, but decreased values for the GQDs in the conjugates. These novel hybrid materials could potentially be deployed for studies in both fundamental and applied perspectives due to the synergistic contributions resulting from the combination of their excellent electronic and optical properties.
- Full Text:
- Date Issued: 2017
Perceptions of parents on their involvement in the implementation of the prevention and management of learner pregnancy : a case study of three secondary schools in Amathole West District
- Authors: Mxothwa, Smileth Ncumisa
- Date: 2020-06
- Subjects: Pregnant teenagers , Sex instruction for teenagers
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19991 , vital:44923
- Description: There is quite a number of researches dealing with perceptions of parents on the prevention and management of learner pregnancy. However, less has been said about how these perceptions of parents on the prevention and management are being implemented to fulfil their purpose. Discovering how these perceptions are being implemented is necessary, bearing in mind that a large number of Schools are having high learner pregnancy and are lacking parental involvement in South Africa, particularly in terms of prevention and management. This is a qualitative study that seeks to explore the perceptions of parents on their implementation of the prevention and management of the learner pregnancy policy in the three secondary school in the Amathole West Education District. The interpretivism paradigm was used by the researcher for this study. A case study design was further used to detect the participants’ lived experiences, thoughts and outlooks about the implementation of the prevention and management of learner pregnancy policy in the secondary school. The data was collected through the use of interviews and focus group. The participants were purposefully selected in the sampling of this study. The participants included School Governing Body Chairpersons. In total, the study consisted of 18 participants. The data were analysed by reducing data into themes through the process of coding. It was further shortened and organised based on evolving themes, overall ideas, and related features. The study discovered that parents are not made aware of their importance by being involved at school level and also are not involved in the implementation of the prevention and management of learner pregnancy policy in the secondary schools in the Amathole West Education District. This research revealed that there need for parental involvement be practised by all schools in the implementation of the prevention and management of learner pregnancy policy as this would help in reducing learner pregnancy in secondary schools of Amathole West Education District. Findings also showed that though parents used different strategies to prevent learner pregnancy, these were not in line with pregnancy policy. The study also discovered that there is a lack of support and monitoring from the district officials to schools. , Thesis (MEd) -- Faculty of Education, 2020
- Full Text:
- Date Issued: 2020-06
- Authors: Mxothwa, Smileth Ncumisa
- Date: 2020-06
- Subjects: Pregnant teenagers , Sex instruction for teenagers
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19991 , vital:44923
- Description: There is quite a number of researches dealing with perceptions of parents on the prevention and management of learner pregnancy. However, less has been said about how these perceptions of parents on the prevention and management are being implemented to fulfil their purpose. Discovering how these perceptions are being implemented is necessary, bearing in mind that a large number of Schools are having high learner pregnancy and are lacking parental involvement in South Africa, particularly in terms of prevention and management. This is a qualitative study that seeks to explore the perceptions of parents on their implementation of the prevention and management of the learner pregnancy policy in the three secondary school in the Amathole West Education District. The interpretivism paradigm was used by the researcher for this study. A case study design was further used to detect the participants’ lived experiences, thoughts and outlooks about the implementation of the prevention and management of learner pregnancy policy in the secondary school. The data was collected through the use of interviews and focus group. The participants were purposefully selected in the sampling of this study. The participants included School Governing Body Chairpersons. In total, the study consisted of 18 participants. The data were analysed by reducing data into themes through the process of coding. It was further shortened and organised based on evolving themes, overall ideas, and related features. The study discovered that parents are not made aware of their importance by being involved at school level and also are not involved in the implementation of the prevention and management of learner pregnancy policy in the secondary schools in the Amathole West Education District. This research revealed that there need for parental involvement be practised by all schools in the implementation of the prevention and management of learner pregnancy policy as this would help in reducing learner pregnancy in secondary schools of Amathole West Education District. Findings also showed that though parents used different strategies to prevent learner pregnancy, these were not in line with pregnancy policy. The study also discovered that there is a lack of support and monitoring from the district officials to schools. , Thesis (MEd) -- Faculty of Education, 2020
- Full Text:
- Date Issued: 2020-06
A reflective multiple case study approach to understanding partner relationships within the context of community engagement at Rhodes University
- Authors: Bobo, Azola Benita Dorothea
- Date: 2021-05-06
- Subjects: Community development South Africa Makhanda , Community and college South Africa Makhanda , Community psychology South Africa Makhanda , Decolonization South Africa , Social action South Africa Makhanda , Transformative learning South Africa Makhanda , Rhodes University , Rhodes University Community Engagement (RUCE)
- Language: English
- Type: Doctoral thesis , text
- Identifier: http://hdl.handle.net/10962/253854 , vital:52406 , DOI 10.21504/10962/253854
- Description: Using a social constructivist approach, within the social action model of community psychology, this research interrogates the features of successful community engagement partnerships that exist within the context of higher education. It draws on the co-management model that the Rhodes University Community Engagement (RUCE) division proposes, where partnerships are seen to be mutually beneficial. This research further interrogates whether the principles of community engagement that RUCE propose play out in reality, and whether systems of power are deconstructed, in working towards more equitable engagements. Drawing on the Early Childhood Development (ECD) Residence Programme for case studies, this research used a reflective multiple case study design in attempting to answer the research question. Four partner groups (i.e., 4 community partners and 4 community engagement representatives) were selected for this research. Each participant was interviewed twice (with a 6-month time gap) and also participated in two focus group discussions. Thematic analysis was used to analyse the findings. In taking a social justice approach, it can be argued that RUCE has made strides towards forming collaborative partnerships based on the ethics of ubuntu and aspects of transformative learning, which may lead to the decolonisation of higher education. However, critical engagement with the research findings suggests that in many cases the principles that RUCE propose are aspirational. More work needs to be done with both students and community partners to develop the kinds of partnerships that RUCE aspires to. This research provides valuable insight into how carefully managed community engagement partnerships in higher education have the potential to contribute to the transformation agenda of higher education institutions, while promoting equitable societies. , Thesis (PhD) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2021-05-06
- Authors: Bobo, Azola Benita Dorothea
- Date: 2021-05-06
- Subjects: Community development South Africa Makhanda , Community and college South Africa Makhanda , Community psychology South Africa Makhanda , Decolonization South Africa , Social action South Africa Makhanda , Transformative learning South Africa Makhanda , Rhodes University , Rhodes University Community Engagement (RUCE)
- Language: English
- Type: Doctoral thesis , text
- Identifier: http://hdl.handle.net/10962/253854 , vital:52406 , DOI 10.21504/10962/253854
- Description: Using a social constructivist approach, within the social action model of community psychology, this research interrogates the features of successful community engagement partnerships that exist within the context of higher education. It draws on the co-management model that the Rhodes University Community Engagement (RUCE) division proposes, where partnerships are seen to be mutually beneficial. This research further interrogates whether the principles of community engagement that RUCE propose play out in reality, and whether systems of power are deconstructed, in working towards more equitable engagements. Drawing on the Early Childhood Development (ECD) Residence Programme for case studies, this research used a reflective multiple case study design in attempting to answer the research question. Four partner groups (i.e., 4 community partners and 4 community engagement representatives) were selected for this research. Each participant was interviewed twice (with a 6-month time gap) and also participated in two focus group discussions. Thematic analysis was used to analyse the findings. In taking a social justice approach, it can be argued that RUCE has made strides towards forming collaborative partnerships based on the ethics of ubuntu and aspects of transformative learning, which may lead to the decolonisation of higher education. However, critical engagement with the research findings suggests that in many cases the principles that RUCE propose are aspirational. More work needs to be done with both students and community partners to develop the kinds of partnerships that RUCE aspires to. This research provides valuable insight into how carefully managed community engagement partnerships in higher education have the potential to contribute to the transformation agenda of higher education institutions, while promoting equitable societies. , Thesis (PhD) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2021-05-06
Electrocatalytic properties of vitamin B12 towards oxidation and reduction of nitric oxide
- Vilakazi, Sibulelo Lea, Nyokong, Tebello
- Authors: Vilakazi, Sibulelo Lea , Nyokong, Tebello
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293196 , vital:57064 , xlink:href="https://doi.org/10.1016/S0013-4686(00)00628-9"
- Description: This paper reports on the catalytic behaviour of cyanocobalamin (VB12) towards the reduction and oxidation of nitric oxide. When VB12 is adsorbed on glassy carbon electrodes, it catalyses the reduction of nitric oxide (NO) in pH 4 and 9 buffers. In the absence of NO, cyclic voltammetry shows that VB12 is reduced by a one-step two-electron reduction from CoIII to the CoI species. Addition of NO at pH 9 to solutions of VB12 resulted in the splitting of the cyclic voltammetry peaks as a result of a consecutive one-electron reduction of the central CoIII metal in VB12 to CoII and finally to CoI. The catalytic peak for oxidation of NO on a glassy carbon electrode modified with VB12 was observed at 1.21 V versus Ag∣AgCl, at pH 9. The products of the catalytic reduction of nitric oxide include ammonia and hydroxylamine.
- Full Text:
- Date Issued: 2000
- Authors: Vilakazi, Sibulelo Lea , Nyokong, Tebello
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293196 , vital:57064 , xlink:href="https://doi.org/10.1016/S0013-4686(00)00628-9"
- Description: This paper reports on the catalytic behaviour of cyanocobalamin (VB12) towards the reduction and oxidation of nitric oxide. When VB12 is adsorbed on glassy carbon electrodes, it catalyses the reduction of nitric oxide (NO) in pH 4 and 9 buffers. In the absence of NO, cyclic voltammetry shows that VB12 is reduced by a one-step two-electron reduction from CoIII to the CoI species. Addition of NO at pH 9 to solutions of VB12 resulted in the splitting of the cyclic voltammetry peaks as a result of a consecutive one-electron reduction of the central CoIII metal in VB12 to CoII and finally to CoI. The catalytic peak for oxidation of NO on a glassy carbon electrode modified with VB12 was observed at 1.21 V versus Ag∣AgCl, at pH 9. The products of the catalytic reduction of nitric oxide include ammonia and hydroxylamine.
- Full Text:
- Date Issued: 2000
Effects of pyrene on the photophysical and two-photon absorption-based nonlinear optical properties of indium (III) phthalocyanines
- Sanusi, Kayode, Nyokong, Tebello
- Authors: Sanusi, Kayode , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189957 , vital:44951 , xlink:href="https://doi.org/10.1080/00958972.2014.959509"
- Description: Photophysical and two-photon-dependent nonlinear absorption properties of two chloroindium(III) phthalocyanines bearing pyrene units have been investigated. The tetra- (3) and the tri- (4) pyrene-substituted phthalocyanines exhibit strong triplet absorption with high triplet yields ( ) of 0.79 and 0.83, respectively. The measured nonlinear optical data, such as the two photon absorption cross-sections, the third- and second-order nonlinearities were found to be comparable with those of literature, thus, making the compounds promising candidates for a broad range of nonlinear optical applications.
- Full Text:
- Date Issued: 2014
- Authors: Sanusi, Kayode , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189957 , vital:44951 , xlink:href="https://doi.org/10.1080/00958972.2014.959509"
- Description: Photophysical and two-photon-dependent nonlinear absorption properties of two chloroindium(III) phthalocyanines bearing pyrene units have been investigated. The tetra- (3) and the tri- (4) pyrene-substituted phthalocyanines exhibit strong triplet absorption with high triplet yields ( ) of 0.79 and 0.83, respectively. The measured nonlinear optical data, such as the two photon absorption cross-sections, the third- and second-order nonlinearities were found to be comparable with those of literature, thus, making the compounds promising candidates for a broad range of nonlinear optical applications.
- Full Text:
- Date Issued: 2014
Comparative phototransformation of environmental pollutants using metallophthalocyanines supported on electrospun polymer fibers
- Zugle, Ruphino, Nyokong, Tebello
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190509 , vital:45001 , xlink:href="https://doi.org/10.1002/app.38381"
- Description: The fluorescence and photoactivity of a series of Zn and Lu phthalocyanine complexes incorporated in various polymer fibers were investigated for the phototransformation of 4-chlorophenol, 4-nitrophenol, and methyl orange. The phthalocyanine complexes functionalized on polystyrene and polysulfone polymer fibers could be applied in the degradation of 4-chlorophenol, 4-nitrophenol, and methyl orange with 4-chlorophenol being much more susceptible to degradation while methyl orange was the least. Also polymer fibers of polystyrene were found to be reusable.
- Full Text:
- Date Issued: 2013
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190509 , vital:45001 , xlink:href="https://doi.org/10.1002/app.38381"
- Description: The fluorescence and photoactivity of a series of Zn and Lu phthalocyanine complexes incorporated in various polymer fibers were investigated for the phototransformation of 4-chlorophenol, 4-nitrophenol, and methyl orange. The phthalocyanine complexes functionalized on polystyrene and polysulfone polymer fibers could be applied in the degradation of 4-chlorophenol, 4-nitrophenol, and methyl orange with 4-chlorophenol being much more susceptible to degradation while methyl orange was the least. Also polymer fibers of polystyrene were found to be reusable.
- Full Text:
- Date Issued: 2013
Malnutrition in children under the age of 5 years in a primary health care setting
- Kaswa, Ramprakash, Govender, Indiran, Rangiah, Selvandran, Nzaumvila, Doudou
- Authors: Kaswa, Ramprakash , Govender, Indiran , Rangiah, Selvandran , Nzaumvila, Doudou
- Date: 2021
- Subjects: Obesity Malnutrition Dietary supplements Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7260 , vital:53106 , xlink:href="https://doi.org/10.4102/safp.v63i1.5337"
- Description: In this study, we outlined the types of malnutrition amongst children, the causes of malnutrition intervention at the primary health care level and some recommendations to alleviate childhood malnutrition in South Africa. Keywords: obesity; severe acute malnutrition; individual factors; community level factors; dietary intervention.
- Full Text:
- Date Issued: 2021
- Authors: Kaswa, Ramprakash , Govender, Indiran , Rangiah, Selvandran , Nzaumvila, Doudou
- Date: 2021
- Subjects: Obesity Malnutrition Dietary supplements Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7260 , vital:53106 , xlink:href="https://doi.org/10.4102/safp.v63i1.5337"
- Description: In this study, we outlined the types of malnutrition amongst children, the causes of malnutrition intervention at the primary health care level and some recommendations to alleviate childhood malnutrition in South Africa. Keywords: obesity; severe acute malnutrition; individual factors; community level factors; dietary intervention.
- Full Text:
- Date Issued: 2021
The implementation of a mobile application to decrease occupational sitting through goal setting and social comparison
- Authors: Tsaoane, Moipone Lipalesa
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365544 , vital:65758
- Description: Background: Feedback proves to be a valuable tool in behaviour change as it is said to increase compliance and improve the effectiveness of interventions. Interventions that focus on decreasing sedentary behaviour as an independent factor from physical activity are necessary, especially for office workers who spend most of their day seated. There is insufficient knowledge regarding the effectiveness of feedback as a tool to decrease sedentary behaviour. This project implemented a tool that can be used to determine this. To take advantage of the cost-effectiveness and scalability of digital technologies, a mobile application was selected as the mode of delivery. Method: The application was designed as an intervention, using the Theoretical Domains Framework. It was then implemented into a fully functioning application through an agile development process, using Xam- arin.Forms framework. Due to challenges with this framework, a second application was developed using the React Native framework. Pilot studies were used for testing, with the final one consisting of Rhodes University employees. Results: The Xamarin.Forms application proved to be unfeasible; some users experienced fatal errors and crashes. The React Native application worked as desired and produced accurate and consistent step count readings, proving feasible from a functionality standpoint. The agile methodology enabled the developer to focus on implementing and testing one component at a time, which made the development process more manageable. Conclusion: Future work must conduct empirical studies to determine if feedback is an effective tool compared to a control group and which type of feedback (between goal-setting and social comparison) is most effective. , Thesis (MSc) -- Faculty of Science, Computer Science, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Tsaoane, Moipone Lipalesa
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365544 , vital:65758
- Description: Background: Feedback proves to be a valuable tool in behaviour change as it is said to increase compliance and improve the effectiveness of interventions. Interventions that focus on decreasing sedentary behaviour as an independent factor from physical activity are necessary, especially for office workers who spend most of their day seated. There is insufficient knowledge regarding the effectiveness of feedback as a tool to decrease sedentary behaviour. This project implemented a tool that can be used to determine this. To take advantage of the cost-effectiveness and scalability of digital technologies, a mobile application was selected as the mode of delivery. Method: The application was designed as an intervention, using the Theoretical Domains Framework. It was then implemented into a fully functioning application through an agile development process, using Xam- arin.Forms framework. Due to challenges with this framework, a second application was developed using the React Native framework. Pilot studies were used for testing, with the final one consisting of Rhodes University employees. Results: The Xamarin.Forms application proved to be unfeasible; some users experienced fatal errors and crashes. The React Native application worked as desired and produced accurate and consistent step count readings, proving feasible from a functionality standpoint. The agile methodology enabled the developer to focus on implementing and testing one component at a time, which made the development process more manageable. Conclusion: Future work must conduct empirical studies to determine if feedback is an effective tool compared to a control group and which type of feedback (between goal-setting and social comparison) is most effective. , Thesis (MSc) -- Faculty of Science, Computer Science, 2022
- Full Text:
- Date Issued: 2022-10-14
Beyond benefit sharing: Place attachment and the importance of access to protected areas for surrounding communities
- Cundill, Georgina, Bezerra, Joana C, de Vos, Alta, Ntingana, Nokuthula
- Authors: Cundill, Georgina , Bezerra, Joana C , de Vos, Alta , Ntingana, Nokuthula
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416265 , vital:71334 , xlink:href="https://doi.org/10.1016/j.ecoser.2017.03.011"
- Description: The concept of place attachment can assist to integrate relational values into ecosystem service research, and assist us to rethink the notion of benefits in contemporary protected area thinking. We present a case study from South Africa, where the concept of two-dimensional place attachment was used to understand the relationship between a protected area and a land claimant community that now owns part of this protected area but does not have physical access to the land. A place attachment lens helps refocus access to protected areas as cornerstone to long term sustainability of such areas. Such access must be considered in the context of spatially and economically differentiated users, including a focus on trade-offs between such users. Our findings highlight that when communities previously displaced from protected areas respond to offers of ‘benefit sharing’ with demands for access and recognition as land owners, they are asking for a recognition of relational values, and identity, based on close interaction with nature. A place attachment and relational values perspective raises questions about the extent to which traditional conservation practice can accommodate such values, and therefore meet local people’s expectations and remain viable in the long term.
- Full Text:
- Date Issued: 2017
- Authors: Cundill, Georgina , Bezerra, Joana C , de Vos, Alta , Ntingana, Nokuthula
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416265 , vital:71334 , xlink:href="https://doi.org/10.1016/j.ecoser.2017.03.011"
- Description: The concept of place attachment can assist to integrate relational values into ecosystem service research, and assist us to rethink the notion of benefits in contemporary protected area thinking. We present a case study from South Africa, where the concept of two-dimensional place attachment was used to understand the relationship between a protected area and a land claimant community that now owns part of this protected area but does not have physical access to the land. A place attachment lens helps refocus access to protected areas as cornerstone to long term sustainability of such areas. Such access must be considered in the context of spatially and economically differentiated users, including a focus on trade-offs between such users. Our findings highlight that when communities previously displaced from protected areas respond to offers of ‘benefit sharing’ with demands for access and recognition as land owners, they are asking for a recognition of relational values, and identity, based on close interaction with nature. A place attachment and relational values perspective raises questions about the extent to which traditional conservation practice can accommodate such values, and therefore meet local people’s expectations and remain viable in the long term.
- Full Text:
- Date Issued: 2017
Exploring the effect of the indigenous technology of oil extraction on Grade 10 Biology learners’ perspectives and sense making of enzymes
- Authors: Nyamakuti, Martha Ndeyatila
- Date: 2021-10-29
- Subjects: Biology Study and teaching (Secondary) , Enzymes , Traditional ecological knowledge Namibia , Culturally relevant pedagogy Namibia , Reasoning , Contiguity Argumentation Theory (CAT) , Namibian National Curriculum for Basic Education(NCBE) , Socio-cultural theory
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/192019 , vital:45188
- Description: The current status quo is that African learners’ local indigenous knowledge (IK) and experiences from home (cultural heritage) are not considered in science classrooms. In the context of Namibia, it seems that the Namibian curriculum policies do little or nothing to decolonise and address the issues of equity and social injustice in Namibian schools. For instance, although the Namibian National Curriculum for Basic Education (NCBE) claims that it “embraces traditional knowledge”, it does not specify how this should be done in schools. As a result, little or no integration of IK is enacted in many of our schools in Namibia. Resultantly, learners seem to find science inaccessible and irrelevant to their everyday lives. It is against this background that in this study I sought to explore how the mobilisation of the indigenous technology of oil extraction (okuyenga) from marula nuts and melon seeds influences (or not) Grade 10 Biology learners’ conceptions, dispositions and sense making of the topic of enzymes. The study was located within the interpretive and indigenous research paradigms. Central to the interpretive paradigm is the development of a greater understanding of how people make sense of the contexts in which they live and work. On the other hand, central to indigenous research paradigms are belief systems based on the lived experiences, values, and histories of the participants. The Ubuntu perspective or approach in which respect and humble togetherness is emphasised is critical in indigenous research paradigms especially when researchers are working with and in communities as I did in this study. The study was conducted in an under resourced school in Walvis Bay, Namibia. A qualitative case study approach was used and data were derived from a focus group interview, participatory classroom observations, learners’ reflections, and a stimulated recall interview. Vygotsky’s socio-cultural theory was employed as a theoretical framework. Within the socio-cultural theory, mediation of learning, social interactions, and the zone of proximal development (ZPD) were used as analytical lenses. The conceptual framework comprised of perspectives (conceptions, dispositions) and sense making of enzymes by the learners. Criteria were also adapted from Atallah, Bryant, and Dada to analyse learners’ perspectives. A thematic approach to analysis was employed to come up with categories and sub-themes and thereafter, common sub-themes were combined to form themes. The findings of the study revealed that the presentations on the indigenous technology of oil extraction by the expert community members influenced learners’ conceptions, dispositions, and sense making of enzymes and other associated science concepts. This was noticed when learners extracted emerging science concepts from the indigenous technology of oil extraction. The implication of this study is that there is a need for science teachers to consider learners’ cultural heritage and integrate local IK in their Biology classrooms in order to make science accessible and relevant to learners. Moreover, the integration of local IK is critical for learners to embrace and respect their cultural heritage. This study thus recommends that teachers should make efforts to collaborate with expert community members who are the custodians of local IK and tap into their cultural heritage and wisdom to enrich teaching in their science classrooms. , Thesis (MEd) -- Faculty of Education, Education, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Nyamakuti, Martha Ndeyatila
- Date: 2021-10-29
- Subjects: Biology Study and teaching (Secondary) , Enzymes , Traditional ecological knowledge Namibia , Culturally relevant pedagogy Namibia , Reasoning , Contiguity Argumentation Theory (CAT) , Namibian National Curriculum for Basic Education(NCBE) , Socio-cultural theory
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/192019 , vital:45188
- Description: The current status quo is that African learners’ local indigenous knowledge (IK) and experiences from home (cultural heritage) are not considered in science classrooms. In the context of Namibia, it seems that the Namibian curriculum policies do little or nothing to decolonise and address the issues of equity and social injustice in Namibian schools. For instance, although the Namibian National Curriculum for Basic Education (NCBE) claims that it “embraces traditional knowledge”, it does not specify how this should be done in schools. As a result, little or no integration of IK is enacted in many of our schools in Namibia. Resultantly, learners seem to find science inaccessible and irrelevant to their everyday lives. It is against this background that in this study I sought to explore how the mobilisation of the indigenous technology of oil extraction (okuyenga) from marula nuts and melon seeds influences (or not) Grade 10 Biology learners’ conceptions, dispositions and sense making of the topic of enzymes. The study was located within the interpretive and indigenous research paradigms. Central to the interpretive paradigm is the development of a greater understanding of how people make sense of the contexts in which they live and work. On the other hand, central to indigenous research paradigms are belief systems based on the lived experiences, values, and histories of the participants. The Ubuntu perspective or approach in which respect and humble togetherness is emphasised is critical in indigenous research paradigms especially when researchers are working with and in communities as I did in this study. The study was conducted in an under resourced school in Walvis Bay, Namibia. A qualitative case study approach was used and data were derived from a focus group interview, participatory classroom observations, learners’ reflections, and a stimulated recall interview. Vygotsky’s socio-cultural theory was employed as a theoretical framework. Within the socio-cultural theory, mediation of learning, social interactions, and the zone of proximal development (ZPD) were used as analytical lenses. The conceptual framework comprised of perspectives (conceptions, dispositions) and sense making of enzymes by the learners. Criteria were also adapted from Atallah, Bryant, and Dada to analyse learners’ perspectives. A thematic approach to analysis was employed to come up with categories and sub-themes and thereafter, common sub-themes were combined to form themes. The findings of the study revealed that the presentations on the indigenous technology of oil extraction by the expert community members influenced learners’ conceptions, dispositions, and sense making of enzymes and other associated science concepts. This was noticed when learners extracted emerging science concepts from the indigenous technology of oil extraction. The implication of this study is that there is a need for science teachers to consider learners’ cultural heritage and integrate local IK in their Biology classrooms in order to make science accessible and relevant to learners. Moreover, the integration of local IK is critical for learners to embrace and respect their cultural heritage. This study thus recommends that teachers should make efforts to collaborate with expert community members who are the custodians of local IK and tap into their cultural heritage and wisdom to enrich teaching in their science classrooms. , Thesis (MEd) -- Faculty of Education, Education, 2021
- Full Text:
- Date Issued: 2021-10-29
A decision-making model to guide securing blockchain deployments
- Authors: Cronje, Gerhard Roets
- Date: 2021-10-29
- Subjects: Blockchains (Databases) , Bitcoin , Cryptocurrencies , Distributed databases , Computer networks Security measures , Computer networks Security measures Decision making , Ethereum
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/10962/188865 , vital:44793
- Description: Satoshi Nakamoto, the pseudo-identity accredit with the paper that sparked the implementation of Bitcoin, is famously quoted as remarking, electronically of course, that “If you don’t believe it or don’t get it, I don’t have time to try and convince you, sorry” (Tsapis, 2019, p. 1). What is noticeable, 12 years after the famed Satoshi paper that initiated Bitcoin (Nakamoto, 2008), is that blockchain at the very least has staying power and potentially wide application. A lesser known figure Marc Kenisberg, founder of Bitcoin Chaser which is one of the many companies formed around the Bitcoin ecosystem, summarised it well saying “…Blockchain is the tech - Bitcoin is merely the first mainstream manifestation of its potential” (Tsapis, 2019, p. 1). With blockchain still trying to reach its potential and still maturing on its way towards a mainstream technology the main question that arises for security professionals is how do I ensure we do it securely? This research seeks to address that question by proposing a decision-making model that can be used by a security professional to guide them through ensuring appropriate security for blockchain deployments. This research is certainly not the first attempt at discussing the security of the blockchain and will not be the last, as the technology around blockchain and distributed ledger technology is still rapidly evolving. What this research does try to achieve is not to delve into extremely specific areas of blockchain security, or get bogged down in technical details, but to provide a reference framework that aims to cover all the major areas to be considered. The approach followed was to review the literature regarding blockchain and to identify the main security areas to be addressed. It then proposes a decision-making model and tests the model against a fictitious but relevant real-world example. It concludes with learnings from this research. The reader can be the judge, but the model aims to be a practical valuable resource to be used by any security professional, to navigate the security aspects logically and understandably when being involved in a blockchain deployment. In contrast to the Satoshi quote, this research tries to convince the reader and assist him/her in understanding the security choices related to every blockchain deployment. , Thesis (MSc) -- Faculty of Science, Computer Science, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Cronje, Gerhard Roets
- Date: 2021-10-29
- Subjects: Blockchains (Databases) , Bitcoin , Cryptocurrencies , Distributed databases , Computer networks Security measures , Computer networks Security measures Decision making , Ethereum
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/10962/188865 , vital:44793
- Description: Satoshi Nakamoto, the pseudo-identity accredit with the paper that sparked the implementation of Bitcoin, is famously quoted as remarking, electronically of course, that “If you don’t believe it or don’t get it, I don’t have time to try and convince you, sorry” (Tsapis, 2019, p. 1). What is noticeable, 12 years after the famed Satoshi paper that initiated Bitcoin (Nakamoto, 2008), is that blockchain at the very least has staying power and potentially wide application. A lesser known figure Marc Kenisberg, founder of Bitcoin Chaser which is one of the many companies formed around the Bitcoin ecosystem, summarised it well saying “…Blockchain is the tech - Bitcoin is merely the first mainstream manifestation of its potential” (Tsapis, 2019, p. 1). With blockchain still trying to reach its potential and still maturing on its way towards a mainstream technology the main question that arises for security professionals is how do I ensure we do it securely? This research seeks to address that question by proposing a decision-making model that can be used by a security professional to guide them through ensuring appropriate security for blockchain deployments. This research is certainly not the first attempt at discussing the security of the blockchain and will not be the last, as the technology around blockchain and distributed ledger technology is still rapidly evolving. What this research does try to achieve is not to delve into extremely specific areas of blockchain security, or get bogged down in technical details, but to provide a reference framework that aims to cover all the major areas to be considered. The approach followed was to review the literature regarding blockchain and to identify the main security areas to be addressed. It then proposes a decision-making model and tests the model against a fictitious but relevant real-world example. It concludes with learnings from this research. The reader can be the judge, but the model aims to be a practical valuable resource to be used by any security professional, to navigate the security aspects logically and understandably when being involved in a blockchain deployment. In contrast to the Satoshi quote, this research tries to convince the reader and assist him/her in understanding the security choices related to every blockchain deployment. , Thesis (MSc) -- Faculty of Science, Computer Science, 2021
- Full Text:
- Date Issued: 2021-10-29
Photodynamic therapy activity of zinc phthalocyanine linked to folic acid and magnetic nanoparticles
- Matlou, Gauta G, Oluwole, David O, Prinsloo, Earl, Nyokong, Tebello
- Authors: Matlou, Gauta G , Oluwole, David O , Prinsloo, Earl , Nyokong, Tebello
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/234429 , vital:50195 , xlink:href="https://doi.org/10.1016/j.jphotobiol.2018.07.025"
- Description: In this work, the photodynamic therapy (PDT) activities (using human carcinoma adherent MCF-7 cells) of zinc phthalocyanine derivatives: complexes 1 (Zn mono cinnamic acid phthalocyanine) and 2 (zinc mono carboxyphenoxy phthalocyanine) when covalently linked to folic acid (FA) and amine functionalized magnetic nanoparticles (AMNPs) are reported. The covalent linkage of asymmetric zinc cinnamic acid Pc (1) to FA (1-FA) through an amide bond is reported for the first time. Complex 1 is insoluble in water, but upon linkage to FA, (to form 1-FA) the molecule become water soluble, hence the UV–Vis spectrum and singlet oxygen quantum yield for 1-FA were also done in water since water solubility is essential for biological applications. The reported 2-FA is also water soluble. Linking complexes 1 and 2 to FA and AMNPs decreased the dark toxicity of 1 and 2 on MCF-7 cells. Pc-FA (1-FA and 2-FA) conjugates had better singlet oxygen quantum yields (Φ∆) in DMSO as compared to Pc-AMNPs (1-AMNPs and 2-AMNPs). The water- soluble 1-FA and 2-FA also achieved a better photodynamic therapy (PDT) activity as compared to 1-AMNPs and 2-AMNPs. Folic acid targeting on the tumor cells may have also facilitated better bioavailability of 1-FA and 2-FA and improved PDT activity on MCF-7 cells over AMNPs carriers.
- Full Text:
- Date Issued: 2018
Photodynamic therapy activity of zinc phthalocyanine linked to folic acid and magnetic nanoparticles
- Authors: Matlou, Gauta G , Oluwole, David O , Prinsloo, Earl , Nyokong, Tebello
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/234429 , vital:50195 , xlink:href="https://doi.org/10.1016/j.jphotobiol.2018.07.025"
- Description: In this work, the photodynamic therapy (PDT) activities (using human carcinoma adherent MCF-7 cells) of zinc phthalocyanine derivatives: complexes 1 (Zn mono cinnamic acid phthalocyanine) and 2 (zinc mono carboxyphenoxy phthalocyanine) when covalently linked to folic acid (FA) and amine functionalized magnetic nanoparticles (AMNPs) are reported. The covalent linkage of asymmetric zinc cinnamic acid Pc (1) to FA (1-FA) through an amide bond is reported for the first time. Complex 1 is insoluble in water, but upon linkage to FA, (to form 1-FA) the molecule become water soluble, hence the UV–Vis spectrum and singlet oxygen quantum yield for 1-FA were also done in water since water solubility is essential for biological applications. The reported 2-FA is also water soluble. Linking complexes 1 and 2 to FA and AMNPs decreased the dark toxicity of 1 and 2 on MCF-7 cells. Pc-FA (1-FA and 2-FA) conjugates had better singlet oxygen quantum yields (Φ∆) in DMSO as compared to Pc-AMNPs (1-AMNPs and 2-AMNPs). The water- soluble 1-FA and 2-FA also achieved a better photodynamic therapy (PDT) activity as compared to 1-AMNPs and 2-AMNPs. Folic acid targeting on the tumor cells may have also facilitated better bioavailability of 1-FA and 2-FA and improved PDT activity on MCF-7 cells over AMNPs carriers.
- Full Text:
- Date Issued: 2018