Synthesis of indium phthalocyanines for photodynamic antimicrobial chemotherapy and photo-oxidation of pollutants
- Authors: Sindelo, Azole
- Date: 2019
- Subjects: Phthalocyanines , Azo dyes , Indium compounds , Photochemotherapy , Nanoparticles , Photodegradation , Pollutants , Water -- Purification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/67581 , vital:29116
- Description: Indium (III) octacarboxyl phthalocyanine (ClInOCPc) alone and when conjugated to magnetic nanoparticles (MNP-ClInOCPc), 2(3),9(10),16(17),23(24)-octapyridylsulfanyl phthalocyaninato chloroindium (III) (ClInOPyPc) and its quaternized derivative 2(3),9(10),16(17),23(24)-octamethylpyridylsulfanyl phthalocyaninato chloroindium (III) (ClInOMePyPc) were synthesized. All Pcs were tested for both photodynamic antimicrobial chemotherapy (PACT) of an unknown water sample and photo-degradation of methyl red (MR). The singlet quantum yield (ΦΔ) for the ClInOCPc and MNP-ClInOCPc in PAN polymer fibers were 0.36 and 0.20 respectively using ADMA as a quencher in water. The photo-inactivation of bacteria in a water sample with unknown microbes was tested, with the MNP-ClInOCPc inactivating 90.6 % of the microbes and the ClInOCPc with 84.8 %. When embedded to the polymer, there was 48% bacterial clearance for ClInOCPc and 64% clearance for the MNP-ClInOCPc. The rate of degradation of MR increased with decrease of the MR concentration, with the MNP-ClInOCPc having the fastest rate. For ClInOPyPc and ClInOMePyPc, the singlet quantum yields were 0.46 and 0.33 in dimethylformamide (DMF), respectively. The PACT activity of ClInOMePyPc (containing 8 positive charges) was compared to those of 9(10),16(17),23(24)-tri-N-methyl-4-pyridylsulfanyl-2(3)-(4-aminophenoxy) phthalocyaninato chloro indium (III) triiodide (1) (containing 3 positive charges) and 2-[4-(N-methylpyridyloxy) phthalocyaninato] chloroindium (III) iodide (2) (containing 4 positive charges). When comparing ClInOMePyPc, 1 and 2, the largest log reduction for E. coli were obtained for complex 2 containing four positive charges hence showing it is not always the charge that determines the PACT activity, but the bridging atom in the phthalocyanine plays a role.
- Full Text:
- Date Issued: 2019
- Authors: Sindelo, Azole
- Date: 2019
- Subjects: Phthalocyanines , Azo dyes , Indium compounds , Photochemotherapy , Nanoparticles , Photodegradation , Pollutants , Water -- Purification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/67581 , vital:29116
- Description: Indium (III) octacarboxyl phthalocyanine (ClInOCPc) alone and when conjugated to magnetic nanoparticles (MNP-ClInOCPc), 2(3),9(10),16(17),23(24)-octapyridylsulfanyl phthalocyaninato chloroindium (III) (ClInOPyPc) and its quaternized derivative 2(3),9(10),16(17),23(24)-octamethylpyridylsulfanyl phthalocyaninato chloroindium (III) (ClInOMePyPc) were synthesized. All Pcs were tested for both photodynamic antimicrobial chemotherapy (PACT) of an unknown water sample and photo-degradation of methyl red (MR). The singlet quantum yield (ΦΔ) for the ClInOCPc and MNP-ClInOCPc in PAN polymer fibers were 0.36 and 0.20 respectively using ADMA as a quencher in water. The photo-inactivation of bacteria in a water sample with unknown microbes was tested, with the MNP-ClInOCPc inactivating 90.6 % of the microbes and the ClInOCPc with 84.8 %. When embedded to the polymer, there was 48% bacterial clearance for ClInOCPc and 64% clearance for the MNP-ClInOCPc. The rate of degradation of MR increased with decrease of the MR concentration, with the MNP-ClInOCPc having the fastest rate. For ClInOPyPc and ClInOMePyPc, the singlet quantum yields were 0.46 and 0.33 in dimethylformamide (DMF), respectively. The PACT activity of ClInOMePyPc (containing 8 positive charges) was compared to those of 9(10),16(17),23(24)-tri-N-methyl-4-pyridylsulfanyl-2(3)-(4-aminophenoxy) phthalocyaninato chloro indium (III) triiodide (1) (containing 3 positive charges) and 2-[4-(N-methylpyridyloxy) phthalocyaninato] chloroindium (III) iodide (2) (containing 4 positive charges). When comparing ClInOMePyPc, 1 and 2, the largest log reduction for E. coli were obtained for complex 2 containing four positive charges hence showing it is not always the charge that determines the PACT activity, but the bridging atom in the phthalocyanine plays a role.
- Full Text:
- Date Issued: 2019
Does the Transkei population of Haliotis Midae at the eastern edge of its distributional range have a higher thermal tolerance than those in more temperate waters?
- Authors: Mathebula, Surprise
- Date: 2021-04
- Subjects: Haliotis midae -- South Africa -- Indian Coast , Abalones -- South Africa -- Indian Coast , Haliotis midae -- Effect of temperature on -- South Africa -- Indian Coast , Haliotis midae -- Physiology -- South Africa -- Indian Coast , Haliotis midae -- Adaptation -- South Africa -- Indian Coast , Haliotis midae -- Growth -- South Africa -- Indian Coast
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/177360 , vital:42814
- Description: The South African perlemoen abalone (Haliotis midae) may be vulnerable to rising temperatures on the East coast of South Africa due to climate change. H. midae is South Africa’s most valuable aquaculture species, and it is thus important to understand its physiological ability to adapt to the expected changes and to identify possible management measures to mitigate the impacts of rising temperatures. This project aimed to understand thermal tolerance and growth rates of offspring from two H. midae populations originating from the warm-temperate Central region (Port Elizabeth) and warmer Eastern edge of the species’ distribution in the Transkei region. To determine the effects of temperature on the physiological performance of the two abalone populations, growth rates, oxygen consumption rates and critical thermal maxima (CTM) were compared. A laboratory growth trial was conducted at three controlled temperatures, visibly, the ‘optimal’ temperature for H. midae growth (18 - 20℃), ‘pejus’ (stressful) temperature (21 - 22℃) and ‘critical’ temperature (23 - 24℃). Oxygen consumption rates were recorded at optimum (20℃), pejus (22℃) and critical (24℃) temperature using a respirometer. In addition, a farm growth trial with simultaneously spawned cohorts of abalone from the two populations was conducted at ambient temperature (19.5 and 20.0℃). The laboratory growth trial revealed no significant differences in growth rate between the two populations at the three temperature treatments (ANOVA, P > 0.05; df = 2). However, mortalities were high and growth rates low, indicating that the rearing conditions were sub-optimal, possibly masking genetic differences. No significant differences were observed in oxygen consumption rates (ANOVA, P = 0.18; df = 2), and CTM (t-Test, P = 0.31; df = 3) between the two populations. The CTM for both populations was between 29 - 30℃. The farm trial yielded no significant differences in growth rate during the Nursery phase (t-Test, P = 0.25; df = 2), however significant differences in growth rate were observed during the grow out phase with the Central region abalone offspring growing faster than the Eastern edge population (t-Test, P = 0.04; df = 4) indicating the possibility of a genetic difference between the two populations. Further experiments will be required to determine whether the differences observed in the growth trial were genetically or environmentally induced. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Mathebula, Surprise
- Date: 2021-04
- Subjects: Haliotis midae -- South Africa -- Indian Coast , Abalones -- South Africa -- Indian Coast , Haliotis midae -- Effect of temperature on -- South Africa -- Indian Coast , Haliotis midae -- Physiology -- South Africa -- Indian Coast , Haliotis midae -- Adaptation -- South Africa -- Indian Coast , Haliotis midae -- Growth -- South Africa -- Indian Coast
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/177360 , vital:42814
- Description: The South African perlemoen abalone (Haliotis midae) may be vulnerable to rising temperatures on the East coast of South Africa due to climate change. H. midae is South Africa’s most valuable aquaculture species, and it is thus important to understand its physiological ability to adapt to the expected changes and to identify possible management measures to mitigate the impacts of rising temperatures. This project aimed to understand thermal tolerance and growth rates of offspring from two H. midae populations originating from the warm-temperate Central region (Port Elizabeth) and warmer Eastern edge of the species’ distribution in the Transkei region. To determine the effects of temperature on the physiological performance of the two abalone populations, growth rates, oxygen consumption rates and critical thermal maxima (CTM) were compared. A laboratory growth trial was conducted at three controlled temperatures, visibly, the ‘optimal’ temperature for H. midae growth (18 - 20℃), ‘pejus’ (stressful) temperature (21 - 22℃) and ‘critical’ temperature (23 - 24℃). Oxygen consumption rates were recorded at optimum (20℃), pejus (22℃) and critical (24℃) temperature using a respirometer. In addition, a farm growth trial with simultaneously spawned cohorts of abalone from the two populations was conducted at ambient temperature (19.5 and 20.0℃). The laboratory growth trial revealed no significant differences in growth rate between the two populations at the three temperature treatments (ANOVA, P > 0.05; df = 2). However, mortalities were high and growth rates low, indicating that the rearing conditions were sub-optimal, possibly masking genetic differences. No significant differences were observed in oxygen consumption rates (ANOVA, P = 0.18; df = 2), and CTM (t-Test, P = 0.31; df = 3) between the two populations. The CTM for both populations was between 29 - 30℃. The farm trial yielded no significant differences in growth rate during the Nursery phase (t-Test, P = 0.25; df = 2), however significant differences in growth rate were observed during the grow out phase with the Central region abalone offspring growing faster than the Eastern edge population (t-Test, P = 0.04; df = 4) indicating the possibility of a genetic difference between the two populations. Further experiments will be required to determine whether the differences observed in the growth trial were genetically or environmentally induced. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2021
- Full Text:
- Date Issued: 2021-04
Development and validation of an In Vitro Release Test (IVRT) to investigate the release of miconazole nitrate from topical cream formulations
- Authors: Purazi, Potiwa
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65223 , vital:28711
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
- Authors: Purazi, Potiwa
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65223 , vital:28711
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
Characterization and application of phthalocyanine-magnetic nanoparticle conjugates anchored to electrospun polyamide nanofibers
- Authors: Ledwaba, Mpho
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54610 , vital:26593
- Description: This work presents the syntheses, photophysical and photochemical characterization of zinc tetracarboxyphenoxy phthalocyanine (ZnTCPPc, 3) and its gadolinium oxide nanoparticle conjugate (4). By means of spectroscopic and microscopic characterization, the conjugation of the ZnTCPPc to the silica coated gadolinium oxide nanoparticles (Si-Gd2O3 NPs, 2) through an amide bond was confirmed. The thermal stability, morphology, nanoparticle sizes and their conjugates with the Pc were studied using ThermoGravimetric Analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and powder X-ray diffractometry (XRD). Conjugation of ZnTCPPc to the magnetic nanoparticles, proved to have a negligible effect on the photophysical parameters of the phthalocyanine, where a slight decrease in fluorescence and triplet quantum yields and lifetimes was observed. The singlet oxygen quantum yield, however, increased slightly upon conjugation, suggesting that the overall efficiency of the ZnTCPPc as a photosensitizer had improved. Physical mixing of the ZnTCPPc and the silica-coated gadolinium nanoparticles also showed an improvement in the singlet oxygen quantum yield and triplet lifetime, also showing an enhanced efficiency for the photosensitizer and therefore photocatalysis. ZnTCPPc (3) alone and the Pc-gadolinium oxide nanoparticle conjugate (4) were therefore electrospun into nanofibers to create a solid support. The fibers were characterized and their diameter sizes and composition was studied confirming the incorporation of the phthalocyanine and gadolinium oxide nanoparticle. Increased singlet oxygen generation resulted in increased Photodegradation of the environmental pollutant Orange G and the fibers were found to be more efficient as photocatalysts compared to the photosensitizer in solution. The nanomaterial may therefore be applied to the photodegradation of Orange G.
- Full Text:
- Date Issued: 2014
- Authors: Ledwaba, Mpho
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54610 , vital:26593
- Description: This work presents the syntheses, photophysical and photochemical characterization of zinc tetracarboxyphenoxy phthalocyanine (ZnTCPPc, 3) and its gadolinium oxide nanoparticle conjugate (4). By means of spectroscopic and microscopic characterization, the conjugation of the ZnTCPPc to the silica coated gadolinium oxide nanoparticles (Si-Gd2O3 NPs, 2) through an amide bond was confirmed. The thermal stability, morphology, nanoparticle sizes and their conjugates with the Pc were studied using ThermoGravimetric Analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and powder X-ray diffractometry (XRD). Conjugation of ZnTCPPc to the magnetic nanoparticles, proved to have a negligible effect on the photophysical parameters of the phthalocyanine, where a slight decrease in fluorescence and triplet quantum yields and lifetimes was observed. The singlet oxygen quantum yield, however, increased slightly upon conjugation, suggesting that the overall efficiency of the ZnTCPPc as a photosensitizer had improved. Physical mixing of the ZnTCPPc and the silica-coated gadolinium nanoparticles also showed an improvement in the singlet oxygen quantum yield and triplet lifetime, also showing an enhanced efficiency for the photosensitizer and therefore photocatalysis. ZnTCPPc (3) alone and the Pc-gadolinium oxide nanoparticle conjugate (4) were therefore electrospun into nanofibers to create a solid support. The fibers were characterized and their diameter sizes and composition was studied confirming the incorporation of the phthalocyanine and gadolinium oxide nanoparticle. Increased singlet oxygen generation resulted in increased Photodegradation of the environmental pollutant Orange G and the fibers were found to be more efficient as photocatalysts compared to the photosensitizer in solution. The nanomaterial may therefore be applied to the photodegradation of Orange G.
- Full Text:
- Date Issued: 2014
Development and assessment of a smart thermosetting intranasal hydrogel for lamotrigine
- Authors: Melamane, Siyabonga
- Date: 2018
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62975 , vital:28349
- Description: Expected release date-April 2020
- Full Text:
- Date Issued: 2018
- Authors: Melamane, Siyabonga
- Date: 2018
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62975 , vital:28349
- Description: Expected release date-April 2020
- Full Text:
- Date Issued: 2018
Towards defining the tipping point of tolerance to CO2-induced ocean acidification for the growth, development and metabolism of larval dusky kob Argyrosomus japonicus (Pisces: Sciaenidae)
- Authors: Mpopetsi, Pule Peter
- Date: 2019
- Subjects: Argyrosomus japonicus , Argyrosomus , Argyrosomus japonicus -- Larvae , Argyrosomus -- Larvae -- Effect of water acidification on , Argyrosomus japonicus -- Larvae -- Nutrition , Argyrosomus -- Larvae -- Nutrition , Ocean acidification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/71602 , vital:29924
- Description: Increased CO2 production and the consequent ocean acidification (OA) have been identified as one of the greatest threats to both calcifying and non-calcifying marine organisms. Traditionally, marine fishes, as non-calcifying organisms, were considered to have a higher tolerance to near-future OA conditions owing to their well-developed ion regulatory mechanisms. However, recent studies provide evidence to suggest that they may not be as resilient to near-future OA conditions as previously thought. In addition, earlier life stages of marine fishes are thought to be less tolerant than juveniles and adults of the same species as they lack well-developed ion regulatory mechanisms for maintaining homeostasis. This study follows up on previous studies examining the effects of near-future OA on larval Argyrosomus japonicus, an estuarine-dependent marine fish species, in order to identify the tipping point of tolerance for the larvae of this species. These previous studies showed that elevated pCO2, predicted for the year 2100, had negative effects on growth, development and metabolism and ultimately, survival of larval A. japonicus from post-flexion stage. Larval A. japonicus in the present study were reared from egg up to 22 DAH (days after hatching) under three treatments. The three treatments, (pCO2 353 μatm; pH 8.03), (pCO2 451 μatm; pH 7.93) and (pCO2 602 μatm; pH 7.83) corresponded to levels predicted to occur in year 2050, 2068 and 2090 respectively under the Intergovernmental Panel on Climate Change (IPCC) Representative Concentration Pathways (IPCC RCP) 8.5 model. Size-at-hatch, growth, development and metabolic responses (standard and active metabolic rates and metabolic scope) were assessed and compared between the three treatments throughout the rearing period. Five earlier larval life stages (hatchling – flexion/post-flexion) were identified by the end of the experiment. There were no significant differences in size-at-hatch (P > 0.05), development or the active metabolic (P > 0.05) or metabolic scope (P > 0.05) of fish in the three treatments throughout the study. However, the standard metabolic rate was significantly higher in the year 2068 treatment but only at the flexion/post-flexion stage which could be attributed to differences in developmental rates (including the development of the gills) between the 2068 and the other two treatments. Overall, the metabolic scope was narrowest in the 2090 treatment, but varied according to life stage. Although not significantly different, metabolic scope in the 2090 treatment was noticeably lower at the flexion stage compared to the other two treatments, and the development appeared slower, suggesting that this could be the stage most prone to OA. The study concluded that, in isolation, OA levels predicted to occur between 2050 and 2090 will not negatively affect size-at-hatch, growth, development, and metabolic responses of larval A. japonicus up to 22 DAH (flexion/post-flexion stage). Taken together with the previous studies of the same species, the tipping point of tolerance (where negative impacts will begin) in larvae of the species appears to be between the years 2090 and 2100.
- Full Text:
- Date Issued: 2019
- Authors: Mpopetsi, Pule Peter
- Date: 2019
- Subjects: Argyrosomus japonicus , Argyrosomus , Argyrosomus japonicus -- Larvae , Argyrosomus -- Larvae -- Effect of water acidification on , Argyrosomus japonicus -- Larvae -- Nutrition , Argyrosomus -- Larvae -- Nutrition , Ocean acidification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/71602 , vital:29924
- Description: Increased CO2 production and the consequent ocean acidification (OA) have been identified as one of the greatest threats to both calcifying and non-calcifying marine organisms. Traditionally, marine fishes, as non-calcifying organisms, were considered to have a higher tolerance to near-future OA conditions owing to their well-developed ion regulatory mechanisms. However, recent studies provide evidence to suggest that they may not be as resilient to near-future OA conditions as previously thought. In addition, earlier life stages of marine fishes are thought to be less tolerant than juveniles and adults of the same species as they lack well-developed ion regulatory mechanisms for maintaining homeostasis. This study follows up on previous studies examining the effects of near-future OA on larval Argyrosomus japonicus, an estuarine-dependent marine fish species, in order to identify the tipping point of tolerance for the larvae of this species. These previous studies showed that elevated pCO2, predicted for the year 2100, had negative effects on growth, development and metabolism and ultimately, survival of larval A. japonicus from post-flexion stage. Larval A. japonicus in the present study were reared from egg up to 22 DAH (days after hatching) under three treatments. The three treatments, (pCO2 353 μatm; pH 8.03), (pCO2 451 μatm; pH 7.93) and (pCO2 602 μatm; pH 7.83) corresponded to levels predicted to occur in year 2050, 2068 and 2090 respectively under the Intergovernmental Panel on Climate Change (IPCC) Representative Concentration Pathways (IPCC RCP) 8.5 model. Size-at-hatch, growth, development and metabolic responses (standard and active metabolic rates and metabolic scope) were assessed and compared between the three treatments throughout the rearing period. Five earlier larval life stages (hatchling – flexion/post-flexion) were identified by the end of the experiment. There were no significant differences in size-at-hatch (P > 0.05), development or the active metabolic (P > 0.05) or metabolic scope (P > 0.05) of fish in the three treatments throughout the study. However, the standard metabolic rate was significantly higher in the year 2068 treatment but only at the flexion/post-flexion stage which could be attributed to differences in developmental rates (including the development of the gills) between the 2068 and the other two treatments. Overall, the metabolic scope was narrowest in the 2090 treatment, but varied according to life stage. Although not significantly different, metabolic scope in the 2090 treatment was noticeably lower at the flexion stage compared to the other two treatments, and the development appeared slower, suggesting that this could be the stage most prone to OA. The study concluded that, in isolation, OA levels predicted to occur between 2050 and 2090 will not negatively affect size-at-hatch, growth, development, and metabolic responses of larval A. japonicus up to 22 DAH (flexion/post-flexion stage). Taken together with the previous studies of the same species, the tipping point of tolerance (where negative impacts will begin) in larvae of the species appears to be between the years 2090 and 2100.
- Full Text:
- Date Issued: 2019
Gold mineralization in a high grade metamorphic terrane in the Handeni District, Eastern Tanzania
- Bitesigirwe, Godfrey Stephen
- Authors: Bitesigirwe, Godfrey Stephen
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54756 , vital:26609
- Description: Most orogenic type gold deposits are formed under low greenschist facies to mid amphibolite facies metamorphic conditions and deposition is either structurally or lithologically controlled. A few known gold deposits found in high grade metamorphic terranes include those in the Yilgarn craton in Australia, Renco in Zimbabwe, Hemlo in Canada and the recently discovered Handeni deposit in Tanzania. Within Tanzania, gold deposits are mainly hosted in Archaean low grade metamorphic rocks commonly known as the Lake Victoria greenstone belt. The greenstone belts of Tanzania are of Nyanzian age (> 2.5Ga) and are located to the south and east of Lake Victoria on the Tanzania craton. The Tanzania Craton is surrounded by Usagaran 1.9 Ga rocks (the east African orogenic belt (EAO) better known as the Mozambique belt) to the east and the Ubendian belt to the south and west. Published reports show that the eastern part of the Tanzania Craton is dominated by the fragments of Archaean rocks. Metamorphism along East Africa and the Tanzania Craton is due to several geological events. These geological events include the intrusion of granites in the Archaean Tanzania Craton (3 Ga), subduction of ocean plate resulted to the formation of Usagaran belt (1.9 Ga), opening and closure of Mozambique Ocean, which resulted in the formation of the Mozambique belt between 700 – 800 Ma and the Pan African orogeny at 640 – 620 Ma, which is associated with the formation of Gondwana. It is believed that fragments from the Archaean Tanzania craton were re - metamorphosed during these events. The Handeni project (the focus of this thesis) is located in the northern portion of the eastern part of the Usagaran belt (1.9 Ga) comprising the eastern part of Archaean Tanzania Craton. The area is characterized by Proterozic rocks of basaltic composition. The documented 2.7 Ga rocks at the Kilindi Handeni Superterrane at the northern part of the Usagaran belt correlate well with 2.7 Ga of Nyanzian rocks of Archaean Tanzania craton. The Handeni project area is geologically dominated by metamorphosed and deformed units of quartzofeldspathic gneisses, migmatitic gneiss, garnet silicified rock, garnetiferous amphibolite, garnetiferous granulite, graphitic schist and hornblende pyroxenite. Intensive deformation features that were developed include folds (sheath folds, micro and macro scales), faults, shears and regional thrusts. This thesis focuses on identifying the protolith of the rocks, alteration minerals, and metamorphic assemblages in the project area in order to understand the timing of gold mineralization. Geological investigation of core, ore petrology and mineralogy, mineral composition by using JEOL microprobe analysis and XRF analysis of bulk rocks were utilized. All the analytical work was done at the Geology laboratory, Rhodes University. Petrographic analysis shows that the rocks sampled in the study area are characterized by alteration minerals such as calcite, dolomite and sericite. Sulphide minerals including chalcopyrite, pyrrhotite, pyrite, pentlandite and gersdorffite were identified. Gold mineralization is associated with disseminated sulphides in association with trace amounts of base metals. Four rock types were proposed as host rocks for the mineralization, namely garnet silicified rock with superimposed quartz veins, garnetiferous amphibolite, garnetiferous granulite and hornblende pyroxenite. Fold troughs, filled fractures associated with episodes of folding, quartz veins and shear zones are suggested as gold precipitation sites. The presence of high grade metamorphic rocks containing gold, intermediate to low grade assemblages with sulphides and associated hydrothermal alteration as well as a complex deformation history suggests that the Handeni mineralization took place over an extended time period stretching from a ductile to a brittle environment.
- Full Text:
- Date Issued: 2014
- Authors: Bitesigirwe, Godfrey Stephen
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54756 , vital:26609
- Description: Most orogenic type gold deposits are formed under low greenschist facies to mid amphibolite facies metamorphic conditions and deposition is either structurally or lithologically controlled. A few known gold deposits found in high grade metamorphic terranes include those in the Yilgarn craton in Australia, Renco in Zimbabwe, Hemlo in Canada and the recently discovered Handeni deposit in Tanzania. Within Tanzania, gold deposits are mainly hosted in Archaean low grade metamorphic rocks commonly known as the Lake Victoria greenstone belt. The greenstone belts of Tanzania are of Nyanzian age (> 2.5Ga) and are located to the south and east of Lake Victoria on the Tanzania craton. The Tanzania Craton is surrounded by Usagaran 1.9 Ga rocks (the east African orogenic belt (EAO) better known as the Mozambique belt) to the east and the Ubendian belt to the south and west. Published reports show that the eastern part of the Tanzania Craton is dominated by the fragments of Archaean rocks. Metamorphism along East Africa and the Tanzania Craton is due to several geological events. These geological events include the intrusion of granites in the Archaean Tanzania Craton (3 Ga), subduction of ocean plate resulted to the formation of Usagaran belt (1.9 Ga), opening and closure of Mozambique Ocean, which resulted in the formation of the Mozambique belt between 700 – 800 Ma and the Pan African orogeny at 640 – 620 Ma, which is associated with the formation of Gondwana. It is believed that fragments from the Archaean Tanzania craton were re - metamorphosed during these events. The Handeni project (the focus of this thesis) is located in the northern portion of the eastern part of the Usagaran belt (1.9 Ga) comprising the eastern part of Archaean Tanzania Craton. The area is characterized by Proterozic rocks of basaltic composition. The documented 2.7 Ga rocks at the Kilindi Handeni Superterrane at the northern part of the Usagaran belt correlate well with 2.7 Ga of Nyanzian rocks of Archaean Tanzania craton. The Handeni project area is geologically dominated by metamorphosed and deformed units of quartzofeldspathic gneisses, migmatitic gneiss, garnet silicified rock, garnetiferous amphibolite, garnetiferous granulite, graphitic schist and hornblende pyroxenite. Intensive deformation features that were developed include folds (sheath folds, micro and macro scales), faults, shears and regional thrusts. This thesis focuses on identifying the protolith of the rocks, alteration minerals, and metamorphic assemblages in the project area in order to understand the timing of gold mineralization. Geological investigation of core, ore petrology and mineralogy, mineral composition by using JEOL microprobe analysis and XRF analysis of bulk rocks were utilized. All the analytical work was done at the Geology laboratory, Rhodes University. Petrographic analysis shows that the rocks sampled in the study area are characterized by alteration minerals such as calcite, dolomite and sericite. Sulphide minerals including chalcopyrite, pyrrhotite, pyrite, pentlandite and gersdorffite were identified. Gold mineralization is associated with disseminated sulphides in association with trace amounts of base metals. Four rock types were proposed as host rocks for the mineralization, namely garnet silicified rock with superimposed quartz veins, garnetiferous amphibolite, garnetiferous granulite and hornblende pyroxenite. Fold troughs, filled fractures associated with episodes of folding, quartz veins and shear zones are suggested as gold precipitation sites. The presence of high grade metamorphic rocks containing gold, intermediate to low grade assemblages with sulphides and associated hydrothermal alteration as well as a complex deformation history suggests that the Handeni mineralization took place over an extended time period stretching from a ductile to a brittle environment.
- Full Text:
- Date Issued: 2014
TiRiFiG, a graphical 3D kinematic modelling tool
- Authors: Twum, Samuel Nyarko
- Date: 2019
- Subjects: Tilted Ring Fitting GUI , Astronomy -- Observations , Galaxies -- Observations , Galaxies -- Measurement , Galaxies -- Measurement -- Data processing , Kinematics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76409 , vital:30558
- Description: Galaxy kinematics is of crucial importance to understanding the structure, formation and evolution of galaxies. The studies of mass distributions giving rise to the missing mass problem, first raised by Zwicky (1933), give us an insight into dark matter distributions which are tightly linked to cosmology. Neutral hydrogen (H i) has been widely used as a tracer in the kinematic studies of galaxies. The Square Kilometre Array (SKA) and its precursors will produce large Hi datasets which will require kinematic modelling tools to extract kinematic parameters such as rotation curves. TiRiFiC (Józsa et al., 2007) is an example of such a tool for 3D kinematic modelling of resolved spectroscopic observations of rotating disks in terms of the tilted-ring model with varying complexities. TiRiFiC can be used to model a large number (20+) of parameters which are set in a configuration file (.def) for its execution. However, manually editing these parameters in a text editor is uncomfortable. In this work, we present TiRiFiG, Tilted Ring Fitting GUI, which is the graphical user interface that provides an easy way for parameter inputs to be modified in an interactive manner.
- Full Text:
- Date Issued: 2019
- Authors: Twum, Samuel Nyarko
- Date: 2019
- Subjects: Tilted Ring Fitting GUI , Astronomy -- Observations , Galaxies -- Observations , Galaxies -- Measurement , Galaxies -- Measurement -- Data processing , Kinematics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76409 , vital:30558
- Description: Galaxy kinematics is of crucial importance to understanding the structure, formation and evolution of galaxies. The studies of mass distributions giving rise to the missing mass problem, first raised by Zwicky (1933), give us an insight into dark matter distributions which are tightly linked to cosmology. Neutral hydrogen (H i) has been widely used as a tracer in the kinematic studies of galaxies. The Square Kilometre Array (SKA) and its precursors will produce large Hi datasets which will require kinematic modelling tools to extract kinematic parameters such as rotation curves. TiRiFiC (Józsa et al., 2007) is an example of such a tool for 3D kinematic modelling of resolved spectroscopic observations of rotating disks in terms of the tilted-ring model with varying complexities. TiRiFiC can be used to model a large number (20+) of parameters which are set in a configuration file (.def) for its execution. However, manually editing these parameters in a text editor is uncomfortable. In this work, we present TiRiFiG, Tilted Ring Fitting GUI, which is the graphical user interface that provides an easy way for parameter inputs to be modified in an interactive manner.
- Full Text:
- Date Issued: 2019
Effect of substituents on the photophysical properties and nonlinear optical properties of asymmetrical zinc(II) phthalocyanine when conjugated to semiconductor quantum dots
- Authors: Mgidlana, Sithi
- Date: 2019
- Subjects: Nonlinear optics , Quantum dots , Phthalocyanines , Zinc
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97152 , vital:31404
- Description: Various characterization techniques have been used to characterize the synthesized asymmetrical zinc phthalocyanines (ZnPc) derivatives. Techniques include Ultraviolet-visible (UV-vis) spectrophotometry, matrix assisted laser desorption time of flight mass spectrometry (MALD-TOF MS), proton nuclear magnetic resonance (1H-NMR), elemental analysis and Fourier-transform infra-red spectroscopy (FT-IR). The complexes are covalently linked to core/shell and core/shell/shell semiconductor quantum dots (SQDs) via amide bond formation. Photophysical properties of complexes improved in the presence of semiconductor quantum dots (SQDs). SQDs contain cadmium/telluride (CdTe) as core, coated in the first shell with zinc selenide (ZnSe) or zinc sulfide (ZnS) and with zinc oxide (ZnO) in second shell. The photophysical properties of the phthalocyanine (Pc) complexes and their conjugates with SQDs are investigated in solution. Triplet quantum yields of complexes improved in the presence of semiconductor quantum dots. The optical limiting behaviour of the Pc complexes and conjugates are assessed using the open aperture Z–scan technique at laser excitation wavelength of 532 nm with 10 ns pulse. Pcs complexes showed good nonlinear optical response with higher nonlinear absorption coefficient. The conjugates afforded higher nonlinear absorption coefficient than Pc complexes alone.
- Full Text:
- Date Issued: 2019
- Authors: Mgidlana, Sithi
- Date: 2019
- Subjects: Nonlinear optics , Quantum dots , Phthalocyanines , Zinc
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97152 , vital:31404
- Description: Various characterization techniques have been used to characterize the synthesized asymmetrical zinc phthalocyanines (ZnPc) derivatives. Techniques include Ultraviolet-visible (UV-vis) spectrophotometry, matrix assisted laser desorption time of flight mass spectrometry (MALD-TOF MS), proton nuclear magnetic resonance (1H-NMR), elemental analysis and Fourier-transform infra-red spectroscopy (FT-IR). The complexes are covalently linked to core/shell and core/shell/shell semiconductor quantum dots (SQDs) via amide bond formation. Photophysical properties of complexes improved in the presence of semiconductor quantum dots (SQDs). SQDs contain cadmium/telluride (CdTe) as core, coated in the first shell with zinc selenide (ZnSe) or zinc sulfide (ZnS) and with zinc oxide (ZnO) in second shell. The photophysical properties of the phthalocyanine (Pc) complexes and their conjugates with SQDs are investigated in solution. Triplet quantum yields of complexes improved in the presence of semiconductor quantum dots. The optical limiting behaviour of the Pc complexes and conjugates are assessed using the open aperture Z–scan technique at laser excitation wavelength of 532 nm with 10 ns pulse. Pcs complexes showed good nonlinear optical response with higher nonlinear absorption coefficient. The conjugates afforded higher nonlinear absorption coefficient than Pc complexes alone.
- Full Text:
- Date Issued: 2019
Demographic change in the Upper Tsitsa Catchment: the integration of census and land cover data for 2001 and 2011
- Authors: Hodgson, Danuta Lorina
- Date: 2018
- Subjects: Land use -- South Africa -- Eastern Cape , Watersheds -- South Africa -- Eastern Cape , Thematic maps -- South Africa -- Eastern Cape , Population density -- South Africa -- Eastern Cape , Mzimvubu River Watershed (South Africa) -- Census , Upper Tsitsa Catchment (South Africa)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57296 , vital:26870
- Description: The purpose of this research was to determine if the integration of census and land cover data could provide evidence of spatial patterns and temporal change for the Upper Tsitsa Catchment. This thesis contributed to academic literature with regards to dasymetric mapping and provided a database for the Ntabelanga and Laleni Ecological Infrastructure Project. The study took place in the Upper Tsitsa Catchment which is located in the north-eastern region of the Eastern Cape and falls within the uMzimvubu Catchment. South Africa National Population Censuses for 2001 and 2011 and the National Land Cover data sets for 2000 and 2013/14 were used to create dasymetric maps depicting demographic changes over time for the catchment area. Spatial statistics were performed on the dasymetric and choropleth map to determine the accuracy of the data that was created. From the results, it was found that although the statistics were skewed, the method was more accurate in displaying the population densities, which was noted during the sampling process of the spatial analysis. It was found that there had been a decrease in the population density within the catchment. This affected the density of several other variables such as population race group, language and employment status statistics as decreases in these values could be due to individuals migrating out of the catchment as well as socio-economic upliftment, such as having better access to services. The use of dasymetric mapping allowed an accurate representation of the population density from the census data to be created. The results of the dasymetric mapping were more accurate as they depicted where the population within the enumeration areas were located, and recognised that some areas were populated while some areas were not. To conclude, it was found that using dasymetric mapping provided reliable and useful data about population density and enables comparison over time.
- Full Text:
- Date Issued: 2018
- Authors: Hodgson, Danuta Lorina
- Date: 2018
- Subjects: Land use -- South Africa -- Eastern Cape , Watersheds -- South Africa -- Eastern Cape , Thematic maps -- South Africa -- Eastern Cape , Population density -- South Africa -- Eastern Cape , Mzimvubu River Watershed (South Africa) -- Census , Upper Tsitsa Catchment (South Africa)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57296 , vital:26870
- Description: The purpose of this research was to determine if the integration of census and land cover data could provide evidence of spatial patterns and temporal change for the Upper Tsitsa Catchment. This thesis contributed to academic literature with regards to dasymetric mapping and provided a database for the Ntabelanga and Laleni Ecological Infrastructure Project. The study took place in the Upper Tsitsa Catchment which is located in the north-eastern region of the Eastern Cape and falls within the uMzimvubu Catchment. South Africa National Population Censuses for 2001 and 2011 and the National Land Cover data sets for 2000 and 2013/14 were used to create dasymetric maps depicting demographic changes over time for the catchment area. Spatial statistics were performed on the dasymetric and choropleth map to determine the accuracy of the data that was created. From the results, it was found that although the statistics were skewed, the method was more accurate in displaying the population densities, which was noted during the sampling process of the spatial analysis. It was found that there had been a decrease in the population density within the catchment. This affected the density of several other variables such as population race group, language and employment status statistics as decreases in these values could be due to individuals migrating out of the catchment as well as socio-economic upliftment, such as having better access to services. The use of dasymetric mapping allowed an accurate representation of the population density from the census data to be created. The results of the dasymetric mapping were more accurate as they depicted where the population within the enumeration areas were located, and recognised that some areas were populated while some areas were not. To conclude, it was found that using dasymetric mapping provided reliable and useful data about population density and enables comparison over time.
- Full Text:
- Date Issued: 2018
The potential significance of refugia in safeguarding Non-Timber Forest products under Harvesting
- Authors: Mjoli, Nwabisa
- Date: 2018
- Subjects: Non-timber forest products -- South Africa -- Eastern Cape , Nature conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/60596 , vital:27801
- Description: Many rural households living in and adjacent to forests in South Africa harvest a variety of NonTimber Forest Products (NTFPs) such as wild fruits, fibre, fuelwood, seeds, medicine and bush meat for domestic use, sale and maintaining cultural values. To promote the continued availability of these NTFPs it is important that NTFPs are well maintained and that harvest offtake is sustainable, because if it is not, then the important livelihood function that they fulfil will be jeopardized over time. The role of refugia in conserving pockets of threatened species from overharvesting has rarely been considered. Building on Shackleton et al. (2015), six applications of the concept are considered: size refugia, spatial refugia, cultural/spiritual refugia and physical/habitat refugia. I examined the prevalence and type of refugia for NTFPs at three coastal sites in the Eastern Cape province of South Africa. This was done via several community focus group discussions at each site. Here I report on the role of refugia in offering some safeguard to NTFPs by assessing harvested and non-harvested sites of refugia as well as individual plant species by measuring population density, harvest damage and size class profile. Respondents from the focus group discussions perceived a general decline in the abundance of common, widely used species over the past five decades. Decreasing rainfall and distant farming activities was reported consistently by the majority of the respondents. The most common form of refugia was spatial refugia, followed by cultural/spiritual refugia and physical/habitat refugia. Only six species were identified to be in refugia, namely Cyperus congestus, Cyperus textillis, Millettia grandis, Olea europaea subsp. africana, Phoenix reclinata, and Ptaeroxylon obliquum. Population inventories revealed that regeneration and population densities of some NTFP species in the non-refuge site were adversely affected by harvesting. Populations in refuge sites generally had the largest size classes indicating a regeneration potential but likely to impact regeneration over time if pressures are maintained. Therefore, if refuge sites keep larger individuals, NTFP populations can be maintained. Few studies have critically analyzed the concept of refugia in relation to how NTFPs can be safeguarded and the practical implication of the refuge concept needs to be considered in conservation and strategies and population models.
- Full Text:
- Date Issued: 2018
- Authors: Mjoli, Nwabisa
- Date: 2018
- Subjects: Non-timber forest products -- South Africa -- Eastern Cape , Nature conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/60596 , vital:27801
- Description: Many rural households living in and adjacent to forests in South Africa harvest a variety of NonTimber Forest Products (NTFPs) such as wild fruits, fibre, fuelwood, seeds, medicine and bush meat for domestic use, sale and maintaining cultural values. To promote the continued availability of these NTFPs it is important that NTFPs are well maintained and that harvest offtake is sustainable, because if it is not, then the important livelihood function that they fulfil will be jeopardized over time. The role of refugia in conserving pockets of threatened species from overharvesting has rarely been considered. Building on Shackleton et al. (2015), six applications of the concept are considered: size refugia, spatial refugia, cultural/spiritual refugia and physical/habitat refugia. I examined the prevalence and type of refugia for NTFPs at three coastal sites in the Eastern Cape province of South Africa. This was done via several community focus group discussions at each site. Here I report on the role of refugia in offering some safeguard to NTFPs by assessing harvested and non-harvested sites of refugia as well as individual plant species by measuring population density, harvest damage and size class profile. Respondents from the focus group discussions perceived a general decline in the abundance of common, widely used species over the past five decades. Decreasing rainfall and distant farming activities was reported consistently by the majority of the respondents. The most common form of refugia was spatial refugia, followed by cultural/spiritual refugia and physical/habitat refugia. Only six species were identified to be in refugia, namely Cyperus congestus, Cyperus textillis, Millettia grandis, Olea europaea subsp. africana, Phoenix reclinata, and Ptaeroxylon obliquum. Population inventories revealed that regeneration and population densities of some NTFP species in the non-refuge site were adversely affected by harvesting. Populations in refuge sites generally had the largest size classes indicating a regeneration potential but likely to impact regeneration over time if pressures are maintained. Therefore, if refuge sites keep larger individuals, NTFP populations can be maintained. Few studies have critically analyzed the concept of refugia in relation to how NTFPs can be safeguarded and the practical implication of the refuge concept needs to be considered in conservation and strategies and population models.
- Full Text:
- Date Issued: 2018
Production, purification and characterization of a multifunctional, thermostable and acido/alkaline stable putative xylanase from the psychrotrophic bacterium, Sphingomonas aerolata
- Authors: Mathibe, Brian Nkanyiso
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164478 , vital:41122
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Biochemistry and Microbiology, 2020
- Full Text:
- Date Issued: 2020
- Authors: Mathibe, Brian Nkanyiso
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164478 , vital:41122
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Biochemistry and Microbiology, 2020
- Full Text:
- Date Issued: 2020
Mapping and predicting potential distribution patterns of free-range livestock in the rural communal rangelands of Mgwalana, Eastern Cape, South Africa
- Authors: Mkabile, Qawekazi
- Date: 2019
- Subjects: Range management -- South Africa , Grazing -- South Africa , Livestock -- South Africa , Livestock -- Monitoring -- South Africa , Livestock -- Remote sensing -- South Africa , Communal rangelands -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/96000 , vital:31223
- Description: Communal rangelands provide habitat to many plants and animals. However, there is evidence that livestock cause range degradation. Range degradation occurs because livestock select grazing based on the availability of resources such as water and forage material, their use of the landscape is non-uniform, consequently causing resource deterioration. Range management is thus necessary because communities depend on range condition for livestock productivity. However, precise quantification of livestock distribution within communal rangelands is lacking. In developed countries, Global Positioning Systems (GPS) collars have been used to monitor wildlife and domestic livestock in pastures and seem to have worked efficiently. However, in a developing country like South Africa, GPS technology to monitor animal behaviour has been used only for wildlife on privately owned land. The high costs of monitoring livestock herds in large open areas such as communal rangelands have resulted in little or no monitoring of domestic livestock using GPS technology. This study links monitored livestock distribution to physical landscape variables in Mgwalana, and uses the modelled relationship to predict livestock distribution in quaternary catchments, T12A and T35A-E. The research addresses the questions (1) where do livestock spend time in the wet and dry seasons? And (2) how can areas of potential livestock distribution be identified in other catchments where actual distribution is unknown? Livestock were tracked during the wet and dry seasons using GPS collars. The resulting distribution data is combined with selected physical landscape variables to identify selectivity. The GPS location data and the physical landscape variables are used to predict potential livestock distribution where distribution is unknown in quaternary catchments (T12A and T35A-E). The ArcGIS Predictive Analysis Tool (PAT) was used to extract the selected landscape variable ranges based on the GPS location data and identify areas with the same conditions in the quaternary catchments were subsequently selected. The key findings are that livestock prefer accessible areas with gentle terrain near water sources, avoiding south-facing slopes which receive less solar radiation and tend to be cooler. Livestock are attracted to vegetation in riparian zones. Rural communal lands are dominated by poverty, and land-based livelihood strategies can potentially contribute to the well-being of the community. Therefore, understanding livestock distribution can contribute to a rangeland management strategy aimed at improving range condition which could increase livestock productivity and contribute to the livelihoods of local people.
- Full Text:
- Date Issued: 2019
- Authors: Mkabile, Qawekazi
- Date: 2019
- Subjects: Range management -- South Africa , Grazing -- South Africa , Livestock -- South Africa , Livestock -- Monitoring -- South Africa , Livestock -- Remote sensing -- South Africa , Communal rangelands -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/96000 , vital:31223
- Description: Communal rangelands provide habitat to many plants and animals. However, there is evidence that livestock cause range degradation. Range degradation occurs because livestock select grazing based on the availability of resources such as water and forage material, their use of the landscape is non-uniform, consequently causing resource deterioration. Range management is thus necessary because communities depend on range condition for livestock productivity. However, precise quantification of livestock distribution within communal rangelands is lacking. In developed countries, Global Positioning Systems (GPS) collars have been used to monitor wildlife and domestic livestock in pastures and seem to have worked efficiently. However, in a developing country like South Africa, GPS technology to monitor animal behaviour has been used only for wildlife on privately owned land. The high costs of monitoring livestock herds in large open areas such as communal rangelands have resulted in little or no monitoring of domestic livestock using GPS technology. This study links monitored livestock distribution to physical landscape variables in Mgwalana, and uses the modelled relationship to predict livestock distribution in quaternary catchments, T12A and T35A-E. The research addresses the questions (1) where do livestock spend time in the wet and dry seasons? And (2) how can areas of potential livestock distribution be identified in other catchments where actual distribution is unknown? Livestock were tracked during the wet and dry seasons using GPS collars. The resulting distribution data is combined with selected physical landscape variables to identify selectivity. The GPS location data and the physical landscape variables are used to predict potential livestock distribution where distribution is unknown in quaternary catchments (T12A and T35A-E). The ArcGIS Predictive Analysis Tool (PAT) was used to extract the selected landscape variable ranges based on the GPS location data and identify areas with the same conditions in the quaternary catchments were subsequently selected. The key findings are that livestock prefer accessible areas with gentle terrain near water sources, avoiding south-facing slopes which receive less solar radiation and tend to be cooler. Livestock are attracted to vegetation in riparian zones. Rural communal lands are dominated by poverty, and land-based livelihood strategies can potentially contribute to the well-being of the community. Therefore, understanding livestock distribution can contribute to a rangeland management strategy aimed at improving range condition which could increase livestock productivity and contribute to the livelihoods of local people.
- Full Text:
- Date Issued: 2019
A comparative study of CERBER, MAKTUB and LOCKY Ransomware using a Hybridised-Malware analysis
- Authors: Schmitt, Veronica
- Date: 2019
- Subjects: Microsoft Windows (Computer file) , Data protection , Computer crimes -- Prevention , Computer security , Computer networks -- Security measures , Computers -- Access control , Malware (Computer software)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/92313 , vital:30702
- Description: There has been a significant increase in the prevalence of Ransomware attacks in the preceding four years to date. This indicates that the battle has not yet been won defending against this class of malware. This research proposes that by identifying the similarities within the operational framework of Ransomware strains, a better overall understanding of their operation and function can be achieved. This, in turn, will aid in a quicker response to future attacks. With the average Ransomware attack taking two hours to be identified, it shows that there is not yet a clear understanding as to why these attacks are so successful. Research into Ransomware is limited by what is currently known on the topic. Due to the limitations of the research the decision was taken to only examined three samples of Ransomware from different families. This was decided due to the complexities and comprehensive nature of the research. The in depth nature of the research and the time constraints associated with it did not allow for proof of concept of this framework to be tested on more than three families, but the exploratory work was promising and should be further explored in future research. The aim of the research is to follow the Hybrid-Malware analysis framework which consists of both static and the dynamic analysis phases, in addition to the digital forensic examination of the infected system. This allows for signature-based findings, along with behavioural and forensic findings all in one. This information allows for a better understanding of how this malware is designed and how it infects and remains persistent on a system. The operating system which has been chosen is the Microsoft Window 7 operating system which is still utilised by a significant proportion of Windows users especially in the corporate environment. The experiment process was designed to enable the researcher the ability to collect information regarding the Ransomware and every aspect of its behaviour and communication on a target system. The results can be compared across the three strains to identify the commonalities. The initial hypothesis was that Ransomware variants are all much like an instant cake box consists of specific building blocks which remain the same with the flavouring of the cake mix being the unique feature.
- Full Text:
- Date Issued: 2019
- Authors: Schmitt, Veronica
- Date: 2019
- Subjects: Microsoft Windows (Computer file) , Data protection , Computer crimes -- Prevention , Computer security , Computer networks -- Security measures , Computers -- Access control , Malware (Computer software)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/92313 , vital:30702
- Description: There has been a significant increase in the prevalence of Ransomware attacks in the preceding four years to date. This indicates that the battle has not yet been won defending against this class of malware. This research proposes that by identifying the similarities within the operational framework of Ransomware strains, a better overall understanding of their operation and function can be achieved. This, in turn, will aid in a quicker response to future attacks. With the average Ransomware attack taking two hours to be identified, it shows that there is not yet a clear understanding as to why these attacks are so successful. Research into Ransomware is limited by what is currently known on the topic. Due to the limitations of the research the decision was taken to only examined three samples of Ransomware from different families. This was decided due to the complexities and comprehensive nature of the research. The in depth nature of the research and the time constraints associated with it did not allow for proof of concept of this framework to be tested on more than three families, but the exploratory work was promising and should be further explored in future research. The aim of the research is to follow the Hybrid-Malware analysis framework which consists of both static and the dynamic analysis phases, in addition to the digital forensic examination of the infected system. This allows for signature-based findings, along with behavioural and forensic findings all in one. This information allows for a better understanding of how this malware is designed and how it infects and remains persistent on a system. The operating system which has been chosen is the Microsoft Window 7 operating system which is still utilised by a significant proportion of Windows users especially in the corporate environment. The experiment process was designed to enable the researcher the ability to collect information regarding the Ransomware and every aspect of its behaviour and communication on a target system. The results can be compared across the three strains to identify the commonalities. The initial hypothesis was that Ransomware variants are all much like an instant cake box consists of specific building blocks which remain the same with the flavouring of the cake mix being the unique feature.
- Full Text:
- Date Issued: 2019
The effect of bait on fine-scale habitat associations of reef fish investigated with remote underwater video systems
- Authors: Schmidt, Nicholas C
- Date: 2019
- Subjects: Baited remote underwater stereo-video systems (stereo-BRUVs) , Remote underwater stereo-video systems , Underwater videography in wildlife monitoring -- South Africa -- Tsitsikamma , Fish stock assessment -- South Africa -- Tsitsikamma , Fish populations -- Monitoring -- South Africa -- Tsitsikamma , Fishes -- Habitat -- South Africa -- Tsitsikamma
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68380 , vital:29249
- Description: Establishing the associations between fish and their habitats can aid in the monitoring of fish stocks and the design of effective marine protected areas (MPAs). Baited remote underwater stereo-video systems (stereo-BRUVs) are now commonly used to asses fish populations. The habitats seen in the video footage of stereo-BRUVs can be used to link fish fauna to preferred habitat types. However, the application of bait potentially attracts fish from surrounding habitats, and might result in a biased understanding of fish–habitat associations. A field study was conducted in the Tsitsikamma National Park MPA to determine the effect of bait on fine-scale fish–habitat associations, using remote photographic and video methods. The study was conducted over the summer season of 2015 and 2016. Data were collected within a 1x1 km shallow (9–44 m) reef complex. Within the sampling area, 944 photo-quadrats of the macrobenthos were taken 30 m apart by means of a drop camera. By separating the macrobenthos into broad taxonomic groups, five habitat types were identified, namely Shallow Sand, Shallow Reef, Deep Reef, Deep Sand and Patch Reef. The results show that even on a fine scale, depth is an important predictor of macrobenthic distribution and assemblage structure. Baited (stereo-BRUVs) and unbaited (stereo-RUVs) surveys were then conducted to sample the fish community in the same area during the period under study. Higher abundances of fish were observed in reef than in sandy habitats, and bait was seen to have a positive effect on species richness and fish abundance. When comparing habitats, fish abundance and composition on reef habitats were significantly different from sand habitats. This was observed in both the stereo-RUVs and stereo-BRUVs methods. High counts of roman (Chrysoblephus laticeps), fransmadam (Boopsoidea inornata) and steentjie (Spondyliosoma emarginatum) in reef habitats were contrasted by high counts of white sea catfish (Galeichthys feliceps), evil-eye puffer (Amblyrhynchotes honckenii) and lesser guitarfish (Rhinecanthus annulatus) in sandy habitats. Overall, the underlying patterns in fish diversity recorded with the two video methods were generally comparable. However, stereo-RUVs appeared to be unable to detect species that were present in sand habitats, while stereo-BRUVs increased the number and abundance of species recorded in all habitat types. In the stereo-RUVs footage, differences between reef habitats were dampened by the presence of highly abundant fish species. In the stereo-BRUVs footage, although bait appeared to have an effect on the observed fish assemblage, this manifested in an increase in species richness, higher fish abundances and a better overall ability to detect fish–habitat relationships. As such, stereo-BRUVs are considered a robust, effective and recommended method for detecting fish–habitat relationships, even over a fine scale.
- Full Text:
- Date Issued: 2019
- Authors: Schmidt, Nicholas C
- Date: 2019
- Subjects: Baited remote underwater stereo-video systems (stereo-BRUVs) , Remote underwater stereo-video systems , Underwater videography in wildlife monitoring -- South Africa -- Tsitsikamma , Fish stock assessment -- South Africa -- Tsitsikamma , Fish populations -- Monitoring -- South Africa -- Tsitsikamma , Fishes -- Habitat -- South Africa -- Tsitsikamma
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68380 , vital:29249
- Description: Establishing the associations between fish and their habitats can aid in the monitoring of fish stocks and the design of effective marine protected areas (MPAs). Baited remote underwater stereo-video systems (stereo-BRUVs) are now commonly used to asses fish populations. The habitats seen in the video footage of stereo-BRUVs can be used to link fish fauna to preferred habitat types. However, the application of bait potentially attracts fish from surrounding habitats, and might result in a biased understanding of fish–habitat associations. A field study was conducted in the Tsitsikamma National Park MPA to determine the effect of bait on fine-scale fish–habitat associations, using remote photographic and video methods. The study was conducted over the summer season of 2015 and 2016. Data were collected within a 1x1 km shallow (9–44 m) reef complex. Within the sampling area, 944 photo-quadrats of the macrobenthos were taken 30 m apart by means of a drop camera. By separating the macrobenthos into broad taxonomic groups, five habitat types were identified, namely Shallow Sand, Shallow Reef, Deep Reef, Deep Sand and Patch Reef. The results show that even on a fine scale, depth is an important predictor of macrobenthic distribution and assemblage structure. Baited (stereo-BRUVs) and unbaited (stereo-RUVs) surveys were then conducted to sample the fish community in the same area during the period under study. Higher abundances of fish were observed in reef than in sandy habitats, and bait was seen to have a positive effect on species richness and fish abundance. When comparing habitats, fish abundance and composition on reef habitats were significantly different from sand habitats. This was observed in both the stereo-RUVs and stereo-BRUVs methods. High counts of roman (Chrysoblephus laticeps), fransmadam (Boopsoidea inornata) and steentjie (Spondyliosoma emarginatum) in reef habitats were contrasted by high counts of white sea catfish (Galeichthys feliceps), evil-eye puffer (Amblyrhynchotes honckenii) and lesser guitarfish (Rhinecanthus annulatus) in sandy habitats. Overall, the underlying patterns in fish diversity recorded with the two video methods were generally comparable. However, stereo-RUVs appeared to be unable to detect species that were present in sand habitats, while stereo-BRUVs increased the number and abundance of species recorded in all habitat types. In the stereo-RUVs footage, differences between reef habitats were dampened by the presence of highly abundant fish species. In the stereo-BRUVs footage, although bait appeared to have an effect on the observed fish assemblage, this manifested in an increase in species richness, higher fish abundances and a better overall ability to detect fish–habitat relationships. As such, stereo-BRUVs are considered a robust, effective and recommended method for detecting fish–habitat relationships, even over a fine scale.
- Full Text:
- Date Issued: 2019
Observations of diffuse radio emission in the Abell 773 galaxy cluster
- Authors: Sichone, Gift L
- Date: 2020
- Subjects: Galaxies -- Clusters -- Observations , Radio astronomy -- Observations , Astrophysics -- South Africa , Westerbork Radio Telescope , A773 galaxy cluster , Astronomy -- Observations , Radio sources (Astronomy
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/144945 , vital:38394
- Description: In this thesis, we present 18 and 21 cm observations of the A773 galaxy cluster observed with the Westerbork radio telescope. The final 18 and 21 cm images achieve a noise level of 0.018 mJy beam‾ 1 and 0.025 mJy beam-1 respectively. After subtracting the compact sources, the low resolution images show evidence of a radio halo at 18 cm, whereas its presence is more uncertain in the low resolution 21 cm images due the presence of residual sidelobes from bright sources. In the joint analysis of both frequencies, the radio halo has a 5.37 arcmin2 area with a 6.76 mJy flux density. Further observations and analysis are, however, required to fully characterize its properties.
- Full Text:
- Date Issued: 2020
- Authors: Sichone, Gift L
- Date: 2020
- Subjects: Galaxies -- Clusters -- Observations , Radio astronomy -- Observations , Astrophysics -- South Africa , Westerbork Radio Telescope , A773 galaxy cluster , Astronomy -- Observations , Radio sources (Astronomy
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/144945 , vital:38394
- Description: In this thesis, we present 18 and 21 cm observations of the A773 galaxy cluster observed with the Westerbork radio telescope. The final 18 and 21 cm images achieve a noise level of 0.018 mJy beam‾ 1 and 0.025 mJy beam-1 respectively. After subtracting the compact sources, the low resolution images show evidence of a radio halo at 18 cm, whereas its presence is more uncertain in the low resolution 21 cm images due the presence of residual sidelobes from bright sources. In the joint analysis of both frequencies, the radio halo has a 5.37 arcmin2 area with a 6.76 mJy flux density. Further observations and analysis are, however, required to fully characterize its properties.
- Full Text:
- Date Issued: 2020
Using four different methods to reach a taxonomic conclusion in dung beetles (Scarabaeinae)
- Authors: Deschodt, Christian Michel
- Date: 2019
- Subjects: Dung beetles -- Classification , Scarabaeidae -- Classification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/67845 , vital:29156
- Description: Four different techniques to make taxonomic decisions concerning different species in Scarabaeinae are being investigated. Firstly, I made measurements of the body dimensions which are plotted on a two dimensional graph. This method is successfully used to erect one new species, Copris crassus Deschodt and Davis, 2015, and to establish the synonymy of Copris bihamatus Balthasar, 1965 with Copris fidius (Olivier, 1789). Thereafter the classical or traditional comparative method is used to propose seven new species Scarabaeolus soutpansbergensis (Deschodt and Davis 2015), Scarabaeolus megaparvulus (Davis and Deschodt 2015), Scarabaeolus niemandi (Deschodt and Davis 2015), Scarabaeolus carniphilus (Davis and Deschodt 2015), Scarabaeolus ermienae (Deschodt and Davis 2015), Scarabaeolus planipennis (Davis and Deschodt 2015) and Scarabaeolus afronitidus (Davis and Deschodt 2015) and formally synonymise Scarabaeolus vansoni (Ferreira, 1958) with Scarabaeolus lucidulus (Boheman, 1860) and Scarabaeolus xavieri (Ferreira, 1968) with Scarabaeolus andreaei (zur Strassen, 1963). Morphometric measurements of external structures of a group of flightless relict beetles in the tribe Canthonini are used to compile a nexus file which is analysed with computer software. The interpretation of these results is used here to support the erection of a new genus Drogo Deschodt, Davis & Scholtz 2016, Lastly I analysed the DNA sequences of specimens from different species belonging to a species complex in the genus Epirinus Reiche, 1841 occurring over a wide geographic range. These sequences are used together with external morphological characters to propose the synonymy of Epirinus hluhluwensis Medina & Scholtz 2005 and Epirinus ngomae Medina & Scholtz 2005 with Epirinus davisi Scholtz & Howden 1987.
- Full Text:
- Date Issued: 2019
- Authors: Deschodt, Christian Michel
- Date: 2019
- Subjects: Dung beetles -- Classification , Scarabaeidae -- Classification
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/67845 , vital:29156
- Description: Four different techniques to make taxonomic decisions concerning different species in Scarabaeinae are being investigated. Firstly, I made measurements of the body dimensions which are plotted on a two dimensional graph. This method is successfully used to erect one new species, Copris crassus Deschodt and Davis, 2015, and to establish the synonymy of Copris bihamatus Balthasar, 1965 with Copris fidius (Olivier, 1789). Thereafter the classical or traditional comparative method is used to propose seven new species Scarabaeolus soutpansbergensis (Deschodt and Davis 2015), Scarabaeolus megaparvulus (Davis and Deschodt 2015), Scarabaeolus niemandi (Deschodt and Davis 2015), Scarabaeolus carniphilus (Davis and Deschodt 2015), Scarabaeolus ermienae (Deschodt and Davis 2015), Scarabaeolus planipennis (Davis and Deschodt 2015) and Scarabaeolus afronitidus (Davis and Deschodt 2015) and formally synonymise Scarabaeolus vansoni (Ferreira, 1958) with Scarabaeolus lucidulus (Boheman, 1860) and Scarabaeolus xavieri (Ferreira, 1968) with Scarabaeolus andreaei (zur Strassen, 1963). Morphometric measurements of external structures of a group of flightless relict beetles in the tribe Canthonini are used to compile a nexus file which is analysed with computer software. The interpretation of these results is used here to support the erection of a new genus Drogo Deschodt, Davis & Scholtz 2016, Lastly I analysed the DNA sequences of specimens from different species belonging to a species complex in the genus Epirinus Reiche, 1841 occurring over a wide geographic range. These sequences are used together with external morphological characters to propose the synonymy of Epirinus hluhluwensis Medina & Scholtz 2005 and Epirinus ngomae Medina & Scholtz 2005 with Epirinus davisi Scholtz & Howden 1987.
- Full Text:
- Date Issued: 2019
A study of the catalysis of the Diels-Alder and Aldol Condensation Reactions
- Authors: Ndagano, Urbain Nshokano
- Date: 2021-04
- Subjects: To be added
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/178525 , vital:42947
- Description: Access restricted until April 2022. , Thesis (MSc) -- Faculty of Science, Chemistry, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Ndagano, Urbain Nshokano
- Date: 2021-04
- Subjects: To be added
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/178525 , vital:42947
- Description: Access restricted until April 2022. , Thesis (MSc) -- Faculty of Science, Chemistry, 2021
- Full Text:
- Date Issued: 2021-04
Taste masking of clarithromycin with ion exchange resins
- Authors: Ntemi, Pascal Vitalis
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65178 , vital:28701
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
- Authors: Ntemi, Pascal Vitalis
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65178 , vital:28701
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
Macroinvertebrate and diatom assemblage responses to pollution, with emphasis on salinity, in the Kat River, Eastern Cape South Africa
- Authors: Mgaba, Ntombekhaya
- Date: 2018
- Subjects: Water -- Pollution -- South Africa -- Kat River , Stream salinity -- South Africa -- Kat River , Sewage disposal plants -- South Africa , Environmental monitoring -- South Africa -- Kat River , Water quality -- South Africa -- Kat River , South African Scoring System version 5 (SASS5) , Macroinvertebrate Response Assessment Index (MIRAI)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63279 , vital:28389
- Description: Salinity has been implicated as one of the major contributors to deteriorating water quality of freshwater ecosystems around the globe. In South Africa, anthropogenic activities such as mining, agriculture, industry and wastewater treatment works (WWTWs) are the major sources of increasing salinity levels of freshwater resources. The main focus of this study was to assess the impact of salinity on water quality of the Kat River using macroinvertebrates and diatoms as bioindicators. Biomonitoring using macroinvertebrates and diatom communities and concurrent sampling of water physicochemical variables were conducted bi-monthly from December 2015 to November 2016.This period covered summer and winter, and the study was conducted at five selected sites (Sites 1, 2, 3, 4 and 5) along the length of the Kat River. For macroinvertebrates biomonitoring, the South African Scoring System version 5 (SASS5) and Macroinvertebrate Response Assessment Index (MIRAI) were applied to collect and analyse data, while the Taylor et al (2006) protocol for collecting and analysing diatom assemblages was modified and used for diatom collection and analysis. Water physicochemical variables, including hydrogen ion concentration (pH), electrical conductivity (EC), dissolved oxygen (DO), temperature, turbidity and stream flow were determined in situ using appropriate multiprobe meter and/or techniques. Nutrients (NO3-N, NO2-N, NH4-N and PO4-P) were analysed in the laboratory using appropriate analytical methods. All data were subjected to appropriate statistical analyses and statistical decisions were made at an alpha value of 0.05. Particularly, multivariate analyses of both macroinvertebrates and diatoms assemblages were conducted using canonical correspondence analysis and Bray-Curtis similarity analysis, while indicator species analysis was used to determine which species is/are more significant with respect to biomonitoring in the Kat River. Biotic diversity indices were also measured and used to discriminate between least and most impacted sites. The Kat River water quality was found to have experienced a varying degree of modification compared to Generic Resources Water Quality Objectives limits. Change in DO, stream flow, EC, nutrients and turbidity exerted the greatest influenced on the macroinvertebrates assemblage structure, with organisms at Sites 4 and 5 (downstream sites) showing more significant negative impact compared to organisms at Sites 1, 2 and 3 (upstream sites). Analysis of the diatom biomonitoring showed more negative impact at Sites 2, 4 and 5 compared to Sites 1 and 3. Fort Beaufort Wastewater Treatment Works and small-scale farming activities, as well as leaking of pipes carrying sewage, were found to be the likely major sources of anthropogenic activities responsible for the observed increased salinity and other pollutants in the Kat River. Overall, this study found macroinvertebrates (identified up to the family level) as good for biomonitoring to assess or predict water quality of the Kat River, while diatoms were found to be most suitable for biomonitoring to assess salinity in the Kat River.
- Full Text:
- Date Issued: 2018
- Authors: Mgaba, Ntombekhaya
- Date: 2018
- Subjects: Water -- Pollution -- South Africa -- Kat River , Stream salinity -- South Africa -- Kat River , Sewage disposal plants -- South Africa , Environmental monitoring -- South Africa -- Kat River , Water quality -- South Africa -- Kat River , South African Scoring System version 5 (SASS5) , Macroinvertebrate Response Assessment Index (MIRAI)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63279 , vital:28389
- Description: Salinity has been implicated as one of the major contributors to deteriorating water quality of freshwater ecosystems around the globe. In South Africa, anthropogenic activities such as mining, agriculture, industry and wastewater treatment works (WWTWs) are the major sources of increasing salinity levels of freshwater resources. The main focus of this study was to assess the impact of salinity on water quality of the Kat River using macroinvertebrates and diatoms as bioindicators. Biomonitoring using macroinvertebrates and diatom communities and concurrent sampling of water physicochemical variables were conducted bi-monthly from December 2015 to November 2016.This period covered summer and winter, and the study was conducted at five selected sites (Sites 1, 2, 3, 4 and 5) along the length of the Kat River. For macroinvertebrates biomonitoring, the South African Scoring System version 5 (SASS5) and Macroinvertebrate Response Assessment Index (MIRAI) were applied to collect and analyse data, while the Taylor et al (2006) protocol for collecting and analysing diatom assemblages was modified and used for diatom collection and analysis. Water physicochemical variables, including hydrogen ion concentration (pH), electrical conductivity (EC), dissolved oxygen (DO), temperature, turbidity and stream flow were determined in situ using appropriate multiprobe meter and/or techniques. Nutrients (NO3-N, NO2-N, NH4-N and PO4-P) were analysed in the laboratory using appropriate analytical methods. All data were subjected to appropriate statistical analyses and statistical decisions were made at an alpha value of 0.05. Particularly, multivariate analyses of both macroinvertebrates and diatoms assemblages were conducted using canonical correspondence analysis and Bray-Curtis similarity analysis, while indicator species analysis was used to determine which species is/are more significant with respect to biomonitoring in the Kat River. Biotic diversity indices were also measured and used to discriminate between least and most impacted sites. The Kat River water quality was found to have experienced a varying degree of modification compared to Generic Resources Water Quality Objectives limits. Change in DO, stream flow, EC, nutrients and turbidity exerted the greatest influenced on the macroinvertebrates assemblage structure, with organisms at Sites 4 and 5 (downstream sites) showing more significant negative impact compared to organisms at Sites 1, 2 and 3 (upstream sites). Analysis of the diatom biomonitoring showed more negative impact at Sites 2, 4 and 5 compared to Sites 1 and 3. Fort Beaufort Wastewater Treatment Works and small-scale farming activities, as well as leaking of pipes carrying sewage, were found to be the likely major sources of anthropogenic activities responsible for the observed increased salinity and other pollutants in the Kat River. Overall, this study found macroinvertebrates (identified up to the family level) as good for biomonitoring to assess or predict water quality of the Kat River, while diatoms were found to be most suitable for biomonitoring to assess salinity in the Kat River.
- Full Text:
- Date Issued: 2018