A study of a class of invariant optimal control problems on the Euclidean group SE(2)
- Authors: Adams, Ross Montague
- Date: 2011
- Subjects: Matrix groups Lie groups Extremal problems (Mathematics) Maximum principles (Mathematics) Hamilton-Jacobi equations Lyapunov stability
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5420 , http://hdl.handle.net/10962/d1006060
- Description: The aim of this thesis is to study a class of left-invariant optimal control problems on the matrix Lie group SE(2). We classify, under detached feedback equivalence, all controllable (left-invariant) control affine systems on SE(2). This result produces six types of control affine systems on SE(2). Hence, we study six associated left-invariant optimal control problems on SE(2). A left-invariant optimal control problem consists of minimizing a cost functional over the trajectory-control pairs of a left-invariant control system subject to appropriate boundary conditions. Each control problem is lifted from SE(2) to T*SE(2) ≅ SE(2) x se (2)*and then reduced to a problem on se (2)*. The maximum principle is used to obtain the optimal control and Hamiltonian corresponding to the normal extremals. Then we derive the (reduced) extremal equations on se (2)*. These equations are explicitly integrated by trigonometric and Jacobi elliptic functions. Finally, we fully classify, under Lyapunov stability, the equilibrium states of the normal extremal equations for each of the six types under consideration.
- Full Text:
- Authors: Adams, Ross Montague
- Date: 2011
- Subjects: Matrix groups Lie groups Extremal problems (Mathematics) Maximum principles (Mathematics) Hamilton-Jacobi equations Lyapunov stability
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5420 , http://hdl.handle.net/10962/d1006060
- Description: The aim of this thesis is to study a class of left-invariant optimal control problems on the matrix Lie group SE(2). We classify, under detached feedback equivalence, all controllable (left-invariant) control affine systems on SE(2). This result produces six types of control affine systems on SE(2). Hence, we study six associated left-invariant optimal control problems on SE(2). A left-invariant optimal control problem consists of minimizing a cost functional over the trajectory-control pairs of a left-invariant control system subject to appropriate boundary conditions. Each control problem is lifted from SE(2) to T*SE(2) ≅ SE(2) x se (2)*and then reduced to a problem on se (2)*. The maximum principle is used to obtain the optimal control and Hamiltonian corresponding to the normal extremals. Then we derive the (reduced) extremal equations on se (2)*. These equations are explicitly integrated by trigonometric and Jacobi elliptic functions. Finally, we fully classify, under Lyapunov stability, the equilibrium states of the normal extremal equations for each of the six types under consideration.
- Full Text:
A study of atmospheric oscillations in the meteor region above Grahamstown
- Authors: Malinga, Sandile B
- Date: 1995
- Subjects: Mesosphere , Thermosphere , Atmosphere, Upper -- South Africa -- Grahamstown , Meteorology -- Methodology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5490 , http://hdl.handle.net/10962/d1005276 , Mesosphere , Thermosphere , Atmosphere, Upper -- South Africa -- Grahamstown , Meteorology -- Methodology
- Description: The dynamics of the atmospheric meteor region have been studied using the data obtained with - - the Grahamstown (33°16'S, 26<>:30'E) meteor radar between the years 1987 and 1993 inclusive. Harmonic analysis and the maximum entropy method (MEM) , were used for the spectral characterization ofthe wind above Grahamstown. The prevailing wind, tidal (periods 12- and 24- h) and other (periods 8- and 6-h) oscillations were extracted from the data using the guidelines agreed upon by the A TMAP community. Above Grahamstown the zonal and meridional prevailing winds were found to be predominantly eastward and equatorward respectively. Tidal amplitudes are comparable to the magnitude of the prevailing wind vector, with the diurnal tide being stronger than the semidiurnal tide. The phase differences between ,the zonal and meridional components of the semidiurnal and diurnal tides are - 2 hand - 5 h respectively, which is in reasonable agreement with the corresponding expected values of3 hand 6 h. The tidal wind vectors are on average elliptically polarized with anticlockwise rotation. Longitudinal and day-to-day tidal variations were studied. From the longitudinal study, the semidiurnal tide was found to be dominated by migrating modes, while the diurnal tidal behaviour suggests the presence of nonmigrating modes with zonal wavenumber s = 4. Tides were found to be variable from day to day with little apparent correlation between the zonal and meridional components of the respective tides.
- Full Text:
- Authors: Malinga, Sandile B
- Date: 1995
- Subjects: Mesosphere , Thermosphere , Atmosphere, Upper -- South Africa -- Grahamstown , Meteorology -- Methodology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5490 , http://hdl.handle.net/10962/d1005276 , Mesosphere , Thermosphere , Atmosphere, Upper -- South Africa -- Grahamstown , Meteorology -- Methodology
- Description: The dynamics of the atmospheric meteor region have been studied using the data obtained with - - the Grahamstown (33°16'S, 26<>:30'E) meteor radar between the years 1987 and 1993 inclusive. Harmonic analysis and the maximum entropy method (MEM) , were used for the spectral characterization ofthe wind above Grahamstown. The prevailing wind, tidal (periods 12- and 24- h) and other (periods 8- and 6-h) oscillations were extracted from the data using the guidelines agreed upon by the A TMAP community. Above Grahamstown the zonal and meridional prevailing winds were found to be predominantly eastward and equatorward respectively. Tidal amplitudes are comparable to the magnitude of the prevailing wind vector, with the diurnal tide being stronger than the semidiurnal tide. The phase differences between ,the zonal and meridional components of the semidiurnal and diurnal tides are - 2 hand - 5 h respectively, which is in reasonable agreement with the corresponding expected values of3 hand 6 h. The tidal wind vectors are on average elliptically polarized with anticlockwise rotation. Longitudinal and day-to-day tidal variations were studied. From the longitudinal study, the semidiurnal tide was found to be dominated by migrating modes, while the diurnal tidal behaviour suggests the presence of nonmigrating modes with zonal wavenumber s = 4. Tides were found to be variable from day to day with little apparent correlation between the zonal and meridional components of the respective tides.
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A study of barred preferential arrangements with applications to numerical approximation in electric circuits
- Authors: Nkonkobe, Sithembele
- Date: 2015
- Subjects: Electric circuits , Numerical calculations , Sequences (Mathematics)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5433 , http://hdl.handle.net/10962/d1020394
- Description: In 1854 Cayley proposed an interesting sequence 1,1,3,13,75,541,... in connection with analytical forms called trees. Since then there has been various combinatorial interpretations of the sequence. The sequence has been interpreted as the number of preferential arrangements of members of a set with n elements. Alternatively the sequence has been interpreted as the number of ordered partitions; the outcomes in races in which ties are allowed or geometrically the number of vertices, edges and faces of simplicial objects. An interesting application of the sequence is found in combination locks. The idea of a preferential arrangement has been extended to a wider combinatorial object called barred preferential arrangement with multiple bars. In this thesis we study barred preferential arrangements combinatorially with application to resistance of certain electrical circuits. In the process we derive some results on cyclic properties of the last digit of the number of barred preferential arrangements. An algorithm in python has been developed to find the number of barred preferential arrangements.
- Full Text:
- Authors: Nkonkobe, Sithembele
- Date: 2015
- Subjects: Electric circuits , Numerical calculations , Sequences (Mathematics)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5433 , http://hdl.handle.net/10962/d1020394
- Description: In 1854 Cayley proposed an interesting sequence 1,1,3,13,75,541,... in connection with analytical forms called trees. Since then there has been various combinatorial interpretations of the sequence. The sequence has been interpreted as the number of preferential arrangements of members of a set with n elements. Alternatively the sequence has been interpreted as the number of ordered partitions; the outcomes in races in which ties are allowed or geometrically the number of vertices, edges and faces of simplicial objects. An interesting application of the sequence is found in combination locks. The idea of a preferential arrangement has been extended to a wider combinatorial object called barred preferential arrangement with multiple bars. In this thesis we study barred preferential arrangements combinatorially with application to resistance of certain electrical circuits. In the process we derive some results on cyclic properties of the last digit of the number of barred preferential arrangements. An algorithm in python has been developed to find the number of barred preferential arrangements.
- Full Text:
A study of carbonate-rich brines from Sua Pan to characterize organic contaminants in the soda ash process
- Authors: Joseph, Manjusha
- Date: 2001
- Subjects: Sua Pan Soda Ash Project -- Botswana , Sodium carbonate -- Research , Biotic communities , Organic compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4031 , http://hdl.handle.net/10962/d1004091 , Sua Pan Soda Ash Project -- Botswana , Sodium carbonate -- Research , Biotic communities , Organic compounds
- Description: Botswana Ash (Pty) Ltd which is situated in Sua Pan, north east Bostwana, is one of Africa's largest suppliers of salt and soda ash. For a number of years, the company has been experiencing problems which have resulted in the final soda ash product being contaminated and discoloured. The problems experienced at Sua Pan have been reported also to occur in other salt works all over the world. It has been suggested that contamination in many salt works could be possibly be due to the microbial activity by halophilic algae and bacteria that grow in the solar ponds. This study was undertaken to investigate the nature of the contaminating organic compounds present in the brine, to identify the compounds, and to establish how these components vary during the various stages of the soda ash processing. For this study, two sets of brine samples were used; the first set was collected before the summer rains and the second set was collected after the summer rains. Solid bicarbonate and soda ash samples were also used. Extractions, desalting, UV and HPLC analysis and oxidative biotransformations using four enzymes, were used for developing profiles and characterizing the brine components. From these studies, we were able to confirm that the components of the brine are organic in nature. A thorough study of one of the compounds isolated,from solid bicarbonate and soda ash was conducted using UV, HPLC, IR, NMR, HPLC-MS, GC-MS and TLC. The results of these analyses, show that the. isolated compound was benzyl butyl phthalate which is generally regarded to be humic in nature. This compound was found to be present in all the brine samples collected after the summer rains including the well brine, suggesting this compound occurs naturally and is not formed during the processing.
- Full Text:
- Authors: Joseph, Manjusha
- Date: 2001
- Subjects: Sua Pan Soda Ash Project -- Botswana , Sodium carbonate -- Research , Biotic communities , Organic compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4031 , http://hdl.handle.net/10962/d1004091 , Sua Pan Soda Ash Project -- Botswana , Sodium carbonate -- Research , Biotic communities , Organic compounds
- Description: Botswana Ash (Pty) Ltd which is situated in Sua Pan, north east Bostwana, is one of Africa's largest suppliers of salt and soda ash. For a number of years, the company has been experiencing problems which have resulted in the final soda ash product being contaminated and discoloured. The problems experienced at Sua Pan have been reported also to occur in other salt works all over the world. It has been suggested that contamination in many salt works could be possibly be due to the microbial activity by halophilic algae and bacteria that grow in the solar ponds. This study was undertaken to investigate the nature of the contaminating organic compounds present in the brine, to identify the compounds, and to establish how these components vary during the various stages of the soda ash processing. For this study, two sets of brine samples were used; the first set was collected before the summer rains and the second set was collected after the summer rains. Solid bicarbonate and soda ash samples were also used. Extractions, desalting, UV and HPLC analysis and oxidative biotransformations using four enzymes, were used for developing profiles and characterizing the brine components. From these studies, we were able to confirm that the components of the brine are organic in nature. A thorough study of one of the compounds isolated,from solid bicarbonate and soda ash was conducted using UV, HPLC, IR, NMR, HPLC-MS, GC-MS and TLC. The results of these analyses, show that the. isolated compound was benzyl butyl phthalate which is generally regarded to be humic in nature. This compound was found to be present in all the brine samples collected after the summer rains including the well brine, suggesting this compound occurs naturally and is not formed during the processing.
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A study of cation exchange in South African soils
- Authors: Du Toit, A A
- Date: 1952
- Subjects: Soil chemistry , Ion exchange
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4462 , http://hdl.handle.net/10962/d1011506 , Soil chemistry , Ion exchange
- Description: The colloidal fraction is the vital part of a soil. These extremely minute particles determine the nature of the soil and are mainly responsible for its many and varied functions. The most important of these functions is perhaps the ability of the colloids to adsorb and exchange cations, the elements so essential to all organisms as building materials. When pure water is passed through a non-saline. soil, the leachate will contain very few dissolved cations. If, on the other hand, an electrolyte such as a weak solution of sodiun chloride, is passed through the same soil, the leachate will contain considerable quantities of calcium, magnesium and potassiun chlorides as well as much of the original sodium chloride. The number of equivalents of the cations collected will be approximately the same as the number of equivalents of sodium ions added. Sodium ions have displaced some of the calcian, magnesium and potassium ions from the soil. This phenomenon is known as cation exchange. Intro., p. 1.
- Full Text:
- Authors: Du Toit, A A
- Date: 1952
- Subjects: Soil chemistry , Ion exchange
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4462 , http://hdl.handle.net/10962/d1011506 , Soil chemistry , Ion exchange
- Description: The colloidal fraction is the vital part of a soil. These extremely minute particles determine the nature of the soil and are mainly responsible for its many and varied functions. The most important of these functions is perhaps the ability of the colloids to adsorb and exchange cations, the elements so essential to all organisms as building materials. When pure water is passed through a non-saline. soil, the leachate will contain very few dissolved cations. If, on the other hand, an electrolyte such as a weak solution of sodiun chloride, is passed through the same soil, the leachate will contain considerable quantities of calcium, magnesium and potassiun chlorides as well as much of the original sodium chloride. The number of equivalents of the cations collected will be approximately the same as the number of equivalents of sodium ions added. Sodium ions have displaced some of the calcian, magnesium and potassium ions from the soil. This phenomenon is known as cation exchange. Intro., p. 1.
- Full Text:
A study of certain members of the South African xylariaceae, with reference to the use of cultural characters in classification
- Martin, Philip Michael Dunlop
- Authors: Martin, Philip Michael Dunlop
- Date: 1961
- Subjects: Xylariaceae -- South Africa , Hypoxylon , Fungi -- South Africa -- Morphology , Fungi -- South Africa -- Anatomy , Fungi -- Classification , Mycelium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4265 , http://hdl.handle.net/10962/d1013505
- Description: [Summary] Sixty-three species, drawn from the genera Rosellinia Hypoxylon, Nummularia, Daldinia, Penzigia and Xylaria, are studied in order to determine whether any correlation exists between various characters of the perfect stage and characters connected with the mycelium in artificial culture that might be used to supplement the existing classification of the Xylariaceae. An examination is made of the morphological and anatomical characters of several stromal types and a statistical method of evaluating differences in ascospore dimension between samples of closely related species is described. Cultural work shows that :- a) Each species group, based primarily on similarity of stromal form, has a characteristic set of cultural characters. b) Members within a Species group can usually be distinguished clearly in culture. The use of cultural characters as an additional criterion in classification is therefore recommended.
- Full Text:
- Authors: Martin, Philip Michael Dunlop
- Date: 1961
- Subjects: Xylariaceae -- South Africa , Hypoxylon , Fungi -- South Africa -- Morphology , Fungi -- South Africa -- Anatomy , Fungi -- Classification , Mycelium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4265 , http://hdl.handle.net/10962/d1013505
- Description: [Summary] Sixty-three species, drawn from the genera Rosellinia Hypoxylon, Nummularia, Daldinia, Penzigia and Xylaria, are studied in order to determine whether any correlation exists between various characters of the perfect stage and characters connected with the mycelium in artificial culture that might be used to supplement the existing classification of the Xylariaceae. An examination is made of the morphological and anatomical characters of several stromal types and a statistical method of evaluating differences in ascospore dimension between samples of closely related species is described. Cultural work shows that :- a) Each species group, based primarily on similarity of stromal form, has a characteristic set of cultural characters. b) Members within a Species group can usually be distinguished clearly in culture. The use of cultural characters as an additional criterion in classification is therefore recommended.
- Full Text:
A study of coeval sibling cannibalism in larval and juvenile fishes and its control under culture conditions
- Authors: Pienaar, Anthony Graham
- Date: 1990
- Subjects: Fishes -- Behavior , Fishes -- Larvae , Fish culture
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5781 , http://hdl.handle.net/10962/d1005469 , Fishes -- Behavior , Fishes -- Larvae , Fish culture
- Description: The primary objective of this study was to examine environmental parameters thought to affect cannibalism in certain fish species. It was found that environmental, behavioural, genetic and physiological factors all affect cannibalism in the species exhibiting the phenomenon. The diversity of factors nfluencing cannibalism served to illustrate the complexity of this behaviour pattern. Feeding to satiation was found to suppress cannibalism in catfish, trout and koi carp. High population densities were found to increase the rate of cannibalism, thereby acting as a population regulation mechanism for catfish, trout and the common and koi carps. Live food, as compared with dry pelletized feed was found to significantly suppress cannibalistic aggression. Catfish grown in total darkness, provided with refuges and living in turbid conditions were found to exhibit lowered cannibalistic and territorial aggression. Various lines of evidence suggested that cannibalism has a genetic basis, as was shown by the differences in cannibalistic behaviour of the two strains of Cyprinus carpio, viz. common and koi carp, with cannibalism being higher in the latter. This finding substantiates the hypothesis that cannibalism is genetically controlled and therefore open to evolutionary change. It is concluded that cannibalism is adaptive in times of food limitation, but that it is merely a by-product of normal feeding behaviour when food is abundant. Since cannibalism is advantageous and thus adaptive, the question arises ai to whether selection is occurring at the individual or the population level (or both). It was concluded that it is acting at the individual level, and that any benefits accruing at the population level iv were simply the effect of the initial cause, viz. individual selection. One of the aims of this study was to determine whether cannibalistic tendencies in fish are influenced by differing life history style trajectories. Based on the results of this study it is hypothesized that cannibalism is an r-selected trait. wi th the understanding gained from the knowl edge of the fundamental principles governing cannibalism, certain recommendations for its control in fish culture could be made. It is, however, imperative that further intensive studies be carried out to understand more fully this complex subject. General "rules" for regulating cannibalism could be helpful for any given cannibalistic species. However, in considering the differing life-history styles of each species, it becomes evident that species-specific guidelines need to be worked out. Until then, any suggestions for cannibalistic control offered to the aquaculturist can only serve as unrefined tools.
- Full Text:
- Authors: Pienaar, Anthony Graham
- Date: 1990
- Subjects: Fishes -- Behavior , Fishes -- Larvae , Fish culture
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5781 , http://hdl.handle.net/10962/d1005469 , Fishes -- Behavior , Fishes -- Larvae , Fish culture
- Description: The primary objective of this study was to examine environmental parameters thought to affect cannibalism in certain fish species. It was found that environmental, behavioural, genetic and physiological factors all affect cannibalism in the species exhibiting the phenomenon. The diversity of factors nfluencing cannibalism served to illustrate the complexity of this behaviour pattern. Feeding to satiation was found to suppress cannibalism in catfish, trout and koi carp. High population densities were found to increase the rate of cannibalism, thereby acting as a population regulation mechanism for catfish, trout and the common and koi carps. Live food, as compared with dry pelletized feed was found to significantly suppress cannibalistic aggression. Catfish grown in total darkness, provided with refuges and living in turbid conditions were found to exhibit lowered cannibalistic and territorial aggression. Various lines of evidence suggested that cannibalism has a genetic basis, as was shown by the differences in cannibalistic behaviour of the two strains of Cyprinus carpio, viz. common and koi carp, with cannibalism being higher in the latter. This finding substantiates the hypothesis that cannibalism is genetically controlled and therefore open to evolutionary change. It is concluded that cannibalism is adaptive in times of food limitation, but that it is merely a by-product of normal feeding behaviour when food is abundant. Since cannibalism is advantageous and thus adaptive, the question arises ai to whether selection is occurring at the individual or the population level (or both). It was concluded that it is acting at the individual level, and that any benefits accruing at the population level iv were simply the effect of the initial cause, viz. individual selection. One of the aims of this study was to determine whether cannibalistic tendencies in fish are influenced by differing life history style trajectories. Based on the results of this study it is hypothesized that cannibalism is an r-selected trait. wi th the understanding gained from the knowl edge of the fundamental principles governing cannibalism, certain recommendations for its control in fish culture could be made. It is, however, imperative that further intensive studies be carried out to understand more fully this complex subject. General "rules" for regulating cannibalism could be helpful for any given cannibalistic species. However, in considering the differing life-history styles of each species, it becomes evident that species-specific guidelines need to be worked out. Until then, any suggestions for cannibalistic control offered to the aquaculturist can only serve as unrefined tools.
- Full Text:
A study of electrospun nanofibers and diatomaceous earth materials for the extraction of alkaloids, flavonoids and aromatic amines in various matrices
- Mothibedi, Kediemetse (Kedimetse)
- Authors: Mothibedi, Kediemetse (Kedimetse)
- Date: 2013 , 2013-04-07
- Subjects: Nanofibers , Electrospinning , Sorbents , Extraction (Chemistry) , Alkaloids , Flavonoids , Amines , Matrices , Goldenseal , Ginkgo , Dyes and dyeing -- Chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4288 , http://hdl.handle.net/10962/d1003052 , Nanofibers , Electrospinning , Sorbents , Extraction (Chemistry) , Alkaloids , Flavonoids , Amines , Matrices , Goldenseal , Ginkgo , Dyes and dyeing -- Chemistry
- Description: The thesis explored the use of different sorbent materials in solid phase extraction method development. The methods included the use of the polymeric Agilent Bond Elut Plexa solid phase extraction and electrospun polymer-silica composite sorbents for clean-up and preconcentration. Sample clean-up for alkaloids (hydrastine and berberine) in goldenseal, Hydrastis canadensis and flavonoids (quercetin, kaempferol and isorhamnetin) in Ginkgo biloba was achieved using Bond Elut Plexa SPE sorbent. Clean-up of flavonoids in Ginkgo biloba was also achieved using electrospun polymer-silica composite (polystyrene-silica, polyacrylonitrile-silica and nylon 6-silica) sorbents. All analysis of flavonoids and alkaloids was carried out using an Agilent 1200 Series HPLC coupled with a diode array detector. Good peak separation was achieved in less than 6 min employing an Agilent ZORBAX Eclipse Plus C18 column (4.6 x 75 mm, 3.5 μm) at 35⁰C. The mobile phases employed were 0.1% phosphoric acid/methanol gradient and 0.5% phosphoric acid/methanol (40:60) for alkaloids and flavonoids respectively. The calibration curves exhibited linearity up to 120 μg mL⁻¹ with correlation coefficients of more than 0.9980. The recoveries ranged from 73-109% with relative standard deviation of less than 5% for all analytes. Agilent Chem Elut supported liquid extraction was employed for the development of a sample preparation method for the determination of 24 banned aromatic amines from azo dyes in textile following the EU standard method EN 14362-1:2003 (E) and the Chinese standard method GB/T 17592-2006. The supported liquid extraction was effective in the extraction of the aromatic amines from textile (cotton, wool and polyester/cotton [80%:20%]). Most of the recoveries obtained were conforming to the minimum requirements set in the EN 14362-1:2003 (E) standard method and the relative standard deviations were less than 15%. Good peak separation was obtained within 70 min run time using the Agilent Zorbax SB-Phenyl column (4.6 mm x 250 mm, 5-micron) or the Agilent DB-35 MS (J & W) (30 m x 0.25 mm, 0.25 μm film thickness. It was demonstrated that the polymeric Agilent Bond Elut Plexa, electrospun nanofibers and diatomaceous earth were effective in extraction of alkaloids, flavonoids and aromatic amines in different matrices. The developed methods were simple, rapid and reproducible.
- Full Text:
- Authors: Mothibedi, Kediemetse (Kedimetse)
- Date: 2013 , 2013-04-07
- Subjects: Nanofibers , Electrospinning , Sorbents , Extraction (Chemistry) , Alkaloids , Flavonoids , Amines , Matrices , Goldenseal , Ginkgo , Dyes and dyeing -- Chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4288 , http://hdl.handle.net/10962/d1003052 , Nanofibers , Electrospinning , Sorbents , Extraction (Chemistry) , Alkaloids , Flavonoids , Amines , Matrices , Goldenseal , Ginkgo , Dyes and dyeing -- Chemistry
- Description: The thesis explored the use of different sorbent materials in solid phase extraction method development. The methods included the use of the polymeric Agilent Bond Elut Plexa solid phase extraction and electrospun polymer-silica composite sorbents for clean-up and preconcentration. Sample clean-up for alkaloids (hydrastine and berberine) in goldenseal, Hydrastis canadensis and flavonoids (quercetin, kaempferol and isorhamnetin) in Ginkgo biloba was achieved using Bond Elut Plexa SPE sorbent. Clean-up of flavonoids in Ginkgo biloba was also achieved using electrospun polymer-silica composite (polystyrene-silica, polyacrylonitrile-silica and nylon 6-silica) sorbents. All analysis of flavonoids and alkaloids was carried out using an Agilent 1200 Series HPLC coupled with a diode array detector. Good peak separation was achieved in less than 6 min employing an Agilent ZORBAX Eclipse Plus C18 column (4.6 x 75 mm, 3.5 μm) at 35⁰C. The mobile phases employed were 0.1% phosphoric acid/methanol gradient and 0.5% phosphoric acid/methanol (40:60) for alkaloids and flavonoids respectively. The calibration curves exhibited linearity up to 120 μg mL⁻¹ with correlation coefficients of more than 0.9980. The recoveries ranged from 73-109% with relative standard deviation of less than 5% for all analytes. Agilent Chem Elut supported liquid extraction was employed for the development of a sample preparation method for the determination of 24 banned aromatic amines from azo dyes in textile following the EU standard method EN 14362-1:2003 (E) and the Chinese standard method GB/T 17592-2006. The supported liquid extraction was effective in the extraction of the aromatic amines from textile (cotton, wool and polyester/cotton [80%:20%]). Most of the recoveries obtained were conforming to the minimum requirements set in the EN 14362-1:2003 (E) standard method and the relative standard deviations were less than 15%. Good peak separation was obtained within 70 min run time using the Agilent Zorbax SB-Phenyl column (4.6 mm x 250 mm, 5-micron) or the Agilent DB-35 MS (J & W) (30 m x 0.25 mm, 0.25 μm film thickness. It was demonstrated that the polymeric Agilent Bond Elut Plexa, electrospun nanofibers and diatomaceous earth were effective in extraction of alkaloids, flavonoids and aromatic amines in different matrices. The developed methods were simple, rapid and reproducible.
- Full Text:
A study of four-dimensional oscillator groups and the associated left-invariant control affine systems
- Authors: Biggs, Rory
- Date: 2012
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164941 , vital:41186
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Department of Mathematics, 2012
- Full Text:
- Authors: Biggs, Rory
- Date: 2012
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164941 , vital:41186
- Description: Thesis (MSc)--Rhodes University, Faculty of Science, Department of Mathematics, 2012
- Full Text:
A study of fuzzy sets and systems with applications to group theory and decision making
- Authors: Gideon, Frednard
- Date: 2006
- Subjects: Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5417 , http://hdl.handle.net/10962/d1005231 , Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Description: In this study we apply the knowledge of fuzzy sets to group structures and also to decision-making implications. We study fuzzy subgroups of finite abelian groups. We set G = Z[subscript p[superscript n]] + Z[subscript q[superscript m]]. The classification of fuzzy subgroups of G using equivalence classes is introduced. First, we present equivalence relations on fuzzy subsets of X, and then extend it to the study of equivalence relations of fuzzy subgroups of a group G. This is then followed by the notion of flags and keychains projected as tools for enumerating fuzzy subgroups of G. In addition to this, we use linear ordering of the lattice of subgroups to characterize the maximal chains of G. Then we narrow the gap between group theory and decision-making using relations. Finally, a theory of the decision-making process in a fuzzy environment leads to a fuzzy version of capital budgeting. We define the goal, constraints and decision and show how they conflict with each other using membership function implications. We establish sets of intervals for projecting decision boundaries in general. We use the knowledge of triangular fuzzy numbers which are restricted field of fuzzy logic to evaluate investment projections.
- Full Text:
- Authors: Gideon, Frednard
- Date: 2006
- Subjects: Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5417 , http://hdl.handle.net/10962/d1005231 , Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Description: In this study we apply the knowledge of fuzzy sets to group structures and also to decision-making implications. We study fuzzy subgroups of finite abelian groups. We set G = Z[subscript p[superscript n]] + Z[subscript q[superscript m]]. The classification of fuzzy subgroups of G using equivalence classes is introduced. First, we present equivalence relations on fuzzy subsets of X, and then extend it to the study of equivalence relations of fuzzy subgroups of a group G. This is then followed by the notion of flags and keychains projected as tools for enumerating fuzzy subgroups of G. In addition to this, we use linear ordering of the lattice of subgroups to characterize the maximal chains of G. Then we narrow the gap between group theory and decision-making using relations. Finally, a theory of the decision-making process in a fuzzy environment leads to a fuzzy version of capital budgeting. We define the goal, constraints and decision and show how they conflict with each other using membership function implications. We establish sets of intervals for projecting decision boundaries in general. We use the knowledge of triangular fuzzy numbers which are restricted field of fuzzy logic to evaluate investment projections.
- Full Text:
A study of germination and flowering in Cichorium intybus. L
- Authors: Minnaar, Hugo Roelof
- Date: 1985
- Subjects: Chicory -- South Africa Germination Seeds -- Development Plants -- Flowering of
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4178 , http://hdl.handle.net/10962/d1002027
- Description: Chicory (Cichorium intybus L) is a deep rooted biennial (or weakly perennial) composite that is grown as an annual in South Africa for its parsnip-like root. In its wild state the plant is a perennial with thin fibrous roots, but, through selection and propagation, cultivars with large, fleshy roots have been developed. From a purely horticultural standpoint, chicory is of interest as a pot-herb, a salad plant and as a root (Bailey, 1942) . As a root, the chicory plant represents an important article of commerce. In South Africa, the plants are grown virtually exclusively for their roots which, after drying, roasting and grinding, are used as an additive to, or substitute for, coffee (Introduction p. 11)
- Full Text:
- Authors: Minnaar, Hugo Roelof
- Date: 1985
- Subjects: Chicory -- South Africa Germination Seeds -- Development Plants -- Flowering of
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4178 , http://hdl.handle.net/10962/d1002027
- Description: Chicory (Cichorium intybus L) is a deep rooted biennial (or weakly perennial) composite that is grown as an annual in South Africa for its parsnip-like root. In its wild state the plant is a perennial with thin fibrous roots, but, through selection and propagation, cultivars with large, fleshy roots have been developed. From a purely horticultural standpoint, chicory is of interest as a pot-herb, a salad plant and as a root (Bailey, 1942) . As a root, the chicory plant represents an important article of commerce. In South Africa, the plants are grown virtually exclusively for their roots which, after drying, roasting and grinding, are used as an additive to, or substitute for, coffee (Introduction p. 11)
- Full Text:
A study of malicious software on the macOS operating system
- Authors: Regensberg, Mark Alan
- Date: 2019
- Subjects: Malware (Computer software) , Computer security , Computer viruses , Mac OS
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/92302 , vital:30701
- Description: Much of the published malware research begins with a common refrain: the cost, quantum and complexity of threats are increasing, and research and practice should prioritise efforts to automate and reduce times to detect and prevent malware, while improving the consistency of categories and taxonomies applied to modern malware. Existing work related to malware targeting Apple's macOS platform has not been spared this approach, although limited research has been conducted on the true nature of threats faced by users of the operating system. While macOS focused research available consistently notes an increase in macOS users, devices and ultimately in threats, an opportunity exists to understand the real nature of threats faced by macOS users and suggest potential avenues for future work. This research provides a view of the current state of macOS malware by analysing and exploring a dataset of malware detections on macOS endpoints captured over a period of eleven months by an anti-malware software vendor. The dataset is augmented with malware information provided by the widely used Virus. Total service, as well as the application of prior automated malware categorisation work, AVClass to categorise and SSDeep to cluster and report on observed data. With Windows and Android platforms frequently in the spotlight as targets for highly disruptive malware like botnets, ransomware and cryptominers, research and intuition seem to suggest the threat of malware on this increasingly popular platform should be growing and evolving accordingly. Findings suggests that the direction and nature of growth and evolution may not be entirely as clear as industry reports suggest. Adware and Potentially Unwanted Applications (PUAs) make up the vast majority of the detected threats, with remote access trojans (RATs), ransomware and cryptocurrency miners comprising a relatively small proportion of the detected malware. This provides a number of avenues for potential future work to compare and contrast with research on other platforms, as well as identification of key factors that may influence its growth in the future.
- Full Text:
- Authors: Regensberg, Mark Alan
- Date: 2019
- Subjects: Malware (Computer software) , Computer security , Computer viruses , Mac OS
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/92302 , vital:30701
- Description: Much of the published malware research begins with a common refrain: the cost, quantum and complexity of threats are increasing, and research and practice should prioritise efforts to automate and reduce times to detect and prevent malware, while improving the consistency of categories and taxonomies applied to modern malware. Existing work related to malware targeting Apple's macOS platform has not been spared this approach, although limited research has been conducted on the true nature of threats faced by users of the operating system. While macOS focused research available consistently notes an increase in macOS users, devices and ultimately in threats, an opportunity exists to understand the real nature of threats faced by macOS users and suggest potential avenues for future work. This research provides a view of the current state of macOS malware by analysing and exploring a dataset of malware detections on macOS endpoints captured over a period of eleven months by an anti-malware software vendor. The dataset is augmented with malware information provided by the widely used Virus. Total service, as well as the application of prior automated malware categorisation work, AVClass to categorise and SSDeep to cluster and report on observed data. With Windows and Android platforms frequently in the spotlight as targets for highly disruptive malware like botnets, ransomware and cryptominers, research and intuition seem to suggest the threat of malware on this increasingly popular platform should be growing and evolving accordingly. Findings suggests that the direction and nature of growth and evolution may not be entirely as clear as industry reports suggest. Adware and Potentially Unwanted Applications (PUAs) make up the vast majority of the detected threats, with remote access trojans (RATs), ransomware and cryptocurrency miners comprising a relatively small proportion of the detected malware. This provides a number of avenues for potential future work to compare and contrast with research on other platforms, as well as identification of key factors that may influence its growth in the future.
- Full Text:
A study of petrol and diesel fuel blends with special reference to their thermodynamic properties and phase equilibria
- Authors: Heyward, Caroline
- Date: 1986
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21167 , http://hdl.handle.net/10962/6695
- Description: The ternary phase behaviour of the n-heptane-l-propanol-water system was studied and compared with the theoretical prediction based on the UNIQUAC model for non-electrolyte solutions. The results showed that this model adequately approximated experimental studies. The excess enthalpies and excess volumes for several binary mixtures were determined. The excess enthalpies were measured using a LKB flow microcalorimeter and the excess -volumes determined using a PAAR densitometer. The study showed that no significant enthalpy or volume changes occurred when petrol/n-heptane were mixed with alcohols. Ternary phase diagrams, including tie lines have been determined for a number of petrol-alcohol-water systems (including the Sasol blend of alcohols). The tie line results show that the concentration of water in the water-rich layer is strongly dependent on the type of alcohol used. The Sasol alcohol blended with petrol resulted in a high water concentration in the water-rich layer which forms on phase separation. This is believed to contribute significantly to the corrosion problems experienced by motorists using the Sasol blended fuel on the Witwatersrand. The effect of temperature on several of these blends was included in the study. Diesel-alcohol blends and the co-solvent properties of ethyl acetate investigated. Ethyl acetate ensures miscibility at low concentrations for diesel-ethanol blends. Octyl nitrate and two cetane improvers from AECI were assessed in terms of their ability to restore cetane rating of blended diesel fuel to that of pure diesel fuel. The results indicated that all three samples were successful in this application.
- Full Text:
- Authors: Heyward, Caroline
- Date: 1986
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21167 , http://hdl.handle.net/10962/6695
- Description: The ternary phase behaviour of the n-heptane-l-propanol-water system was studied and compared with the theoretical prediction based on the UNIQUAC model for non-electrolyte solutions. The results showed that this model adequately approximated experimental studies. The excess enthalpies and excess volumes for several binary mixtures were determined. The excess enthalpies were measured using a LKB flow microcalorimeter and the excess -volumes determined using a PAAR densitometer. The study showed that no significant enthalpy or volume changes occurred when petrol/n-heptane were mixed with alcohols. Ternary phase diagrams, including tie lines have been determined for a number of petrol-alcohol-water systems (including the Sasol blend of alcohols). The tie line results show that the concentration of water in the water-rich layer is strongly dependent on the type of alcohol used. The Sasol alcohol blended with petrol resulted in a high water concentration in the water-rich layer which forms on phase separation. This is believed to contribute significantly to the corrosion problems experienced by motorists using the Sasol blended fuel on the Witwatersrand. The effect of temperature on several of these blends was included in the study. Diesel-alcohol blends and the co-solvent properties of ethyl acetate investigated. Ethyl acetate ensures miscibility at low concentrations for diesel-ethanol blends. Octyl nitrate and two cetane improvers from AECI were assessed in terms of their ability to restore cetane rating of blended diesel fuel to that of pure diesel fuel. The results indicated that all three samples were successful in this application.
- Full Text:
A study of petrol and diesel fuel blends with special reference to their thermodynamic propeties and phase equilibria
- Authors: Hayward, Caroline
- Date: 1986
- Subjects: Gasoline , Diesel fuels , Thermodynamics , Liquid-liquid equilibrium , Alcohol as fuel
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4065 , http://hdl.handle.net/10962/d1004902 , Gasoline , Diesel fuels , Thermodynamics , Liquid-liquid equilibrium , Alcohol as fuel
- Description: The ternary phase behaviour of the n-heptane-l-propanol-water system was studied and compared with the theoretical prediction based on the UNIQUAC model for non-electrolyte solutions. The results showed that this model adequately approximated experimental studies. The excess enthalpies and excess volumes for several binary mixtures were determined. The excess enthalpies were measured using a LKB flow microcalorimeter and the excess -volumes determined using a PAAR densitometer. The study showed that no significant enthalpy or volume changes occurred when petrol/n-heptane were mixed with alcohols . Ternary phase diagrams, including tie lines have been determined for a number of petrol-alcohol-water systems (including the Sasol blend of alcohols). The tie line results show that the concentration of water in the water-rich layer is strongly dependent on the type of alcohol used. The Sasol alcohol blended with petrol resulted in a high water concentration in the water-rich layer which forms on phase separation. This is believed to contribute significantly to the corrosion problems experienced by motorists using the Sasol blended fuel on the Witwatersrand. The effect of temperature on several of these blends was included in the study. Diesel-alcohol blends and the co-solvent properties of ethyl acetate investigated. Ethyl acetate ensures miscibility at low concentrations for diesel-ethanol blends. Octyl nitrate and two cetane improvers from AECI were assessed in terms of their ability to restore cetane rating of blended diesel fuel to that of pure diesel fuel. The results indicated that all three samples were successful in this application. , KMBT_363
- Full Text:
- Authors: Hayward, Caroline
- Date: 1986
- Subjects: Gasoline , Diesel fuels , Thermodynamics , Liquid-liquid equilibrium , Alcohol as fuel
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4065 , http://hdl.handle.net/10962/d1004902 , Gasoline , Diesel fuels , Thermodynamics , Liquid-liquid equilibrium , Alcohol as fuel
- Description: The ternary phase behaviour of the n-heptane-l-propanol-water system was studied and compared with the theoretical prediction based on the UNIQUAC model for non-electrolyte solutions. The results showed that this model adequately approximated experimental studies. The excess enthalpies and excess volumes for several binary mixtures were determined. The excess enthalpies were measured using a LKB flow microcalorimeter and the excess -volumes determined using a PAAR densitometer. The study showed that no significant enthalpy or volume changes occurred when petrol/n-heptane were mixed with alcohols . Ternary phase diagrams, including tie lines have been determined for a number of petrol-alcohol-water systems (including the Sasol blend of alcohols). The tie line results show that the concentration of water in the water-rich layer is strongly dependent on the type of alcohol used. The Sasol alcohol blended with petrol resulted in a high water concentration in the water-rich layer which forms on phase separation. This is believed to contribute significantly to the corrosion problems experienced by motorists using the Sasol blended fuel on the Witwatersrand. The effect of temperature on several of these blends was included in the study. Diesel-alcohol blends and the co-solvent properties of ethyl acetate investigated. Ethyl acetate ensures miscibility at low concentrations for diesel-ethanol blends. Octyl nitrate and two cetane improvers from AECI were assessed in terms of their ability to restore cetane rating of blended diesel fuel to that of pure diesel fuel. The results indicated that all three samples were successful in this application. , KMBT_363
- Full Text:
A study of phosphorus dynamics in the main basin of Swartvlei, September - December 1980
- Authors: Silberbauer, M J
- Date: 1981
- Subjects: Phosphorus -- Environmental aspects -- South Africa -- Swartvlei Lakes -- South Africa -- Swartvlei Limnology -- South Africa -- Swartvlei Aquatic ecology -- South Africa -- Swartvlei
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5016 , http://hdl.handle.net/10962/d1006146
- Description: Introduction: Phosphorus is an especially scarce element in the aquatic environment, yet it is of vital importance to living organisms: the pyrophosphate bond is the basis of biochemical energy transfer, and phosphate groups make up the backbone of the nucleic acids (Wetzel, 1975). An understanding of phosphorus movements and transformations is thus essential to a study of the biological functioning of a lake. The present report describes a study of phosphorus dynamics inSwartvlei, a lake with an extremely low pelagic primary production rate, in the order of 0,15 gC.m⁻².d⁻¹ (Robarts, 1973; Howard-Williams and Allanson, 1978). The littoral phosphorus dynamics of Swartvlei have been discussed in some detail (Howard-Williams, 1977; Howard-Williams and Allanson, 1978), and what follows is an attempt to quantify the changes in phosphorus concentration occurring in the deeper parts of the lake, which comprise some 57% of the total area.
- Full Text:
- Authors: Silberbauer, M J
- Date: 1981
- Subjects: Phosphorus -- Environmental aspects -- South Africa -- Swartvlei Lakes -- South Africa -- Swartvlei Limnology -- South Africa -- Swartvlei Aquatic ecology -- South Africa -- Swartvlei
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5016 , http://hdl.handle.net/10962/d1006146
- Description: Introduction: Phosphorus is an especially scarce element in the aquatic environment, yet it is of vital importance to living organisms: the pyrophosphate bond is the basis of biochemical energy transfer, and phosphate groups make up the backbone of the nucleic acids (Wetzel, 1975). An understanding of phosphorus movements and transformations is thus essential to a study of the biological functioning of a lake. The present report describes a study of phosphorus dynamics inSwartvlei, a lake with an extremely low pelagic primary production rate, in the order of 0,15 gC.m⁻².d⁻¹ (Robarts, 1973; Howard-Williams and Allanson, 1978). The littoral phosphorus dynamics of Swartvlei have been discussed in some detail (Howard-Williams, 1977; Howard-Williams and Allanson, 1978), and what follows is an attempt to quantify the changes in phosphorus concentration occurring in the deeper parts of the lake, which comprise some 57% of the total area.
- Full Text:
A study of plocamium corallorhiza secondary metabolites and their biological activity
- Authors: Mkwananzi, Henry Bayanda
- Date: 2005
- Subjects: Natural products -- Therapeutic use , Marine metabolites -- Therapeutic use , Marine pharmacology , Marine algae , Monoterpenes
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3841 , http://hdl.handle.net/10962/d1007666 , Natural products -- Therapeutic use , Marine metabolites -- Therapeutic use , Marine pharmacology , Marine algae , Monoterpenes
- Description: Seaweeds of the genus Plocamium are known to produce a variety of halogenated monoterpenes. In addition to their ecological role as feeding deterrents, biological activities reported for these compounds include antibacterial, antialgal, antifungal and anticancer activities. An investigation of the non-polar extracts of the seaweed Plocamium corallorhiza resulted in the isolation of six known halogenated monoterpene compounds, 4-bromo-5-bromomethyl-1-chlorovinyl-2, 5-dichloro-methylcyclohexane (2.68), 1,4,8-tribromo-3 ,7-dichloro-3, 7-dimethyl-1,5-octadiene (2.67), 8-bromo-1 ,3,4,7-tetrachloro-3, 7-dimethyl-1,5-octadiene (2.66), 4,6-dibromo-1,1-dichloro-3,7-dimethyl-2,7-octadiene (2.64), 4,8-dibromo-1,1,7-trichloro-3,7-dimethyl-2,5-octadiene (2.65) and 3,4 ,6,7-tetrachloro-3, 7-dimethyl-1-octene (2.63) as well as eight new compounds, including five halogenated monoterpene aldehydes. The new compounds were identified by 1D and 2D NMR spectroscopic techniques as: 8-Bromo-6,7-dichloro-3,7-dimethyl-octa-2,4-dienal (2.72), 8-Bromo-1,1,2,7-tetrachloro-3,7-dimethyl-octa-3,5-diene (2.70), 4,8-Dichloro-3,7-dimethyl-octa-2,4,6-trienal (2.74), 4-Bromo-8-chloro-3, 7-di methyl-octa-2, 6-dienal (2 76), 8-Bromo-4-chloro-3, 7-dimethyl-octa-2,4 ,6-trienaI (2.75), 4-Bromo-1,3,6,7-tetrachloro-3 ,7-dimethyl-octa-1,4-diene (2.71), 8-Bromo-1,3,4,7-tetrachloro-3,7-dimethyl-octa-1,5-diene (2.69), 4,6-Dibromo-3,7 -dimethyl-octa-2,7-dienal (2.73). All compounds were screened for antimicrobial activity, brine shrimp lethality and cytotoxicity towards oesophageal cancer cells. Compound 2.68 was toxic to brine shrimp larvae at a concentration of 50 μ/mL. It also showed promising activity towards oesophageal cancer cells with an IC₅₀, of 2 μg/mL.
- Full Text:
- Authors: Mkwananzi, Henry Bayanda
- Date: 2005
- Subjects: Natural products -- Therapeutic use , Marine metabolites -- Therapeutic use , Marine pharmacology , Marine algae , Monoterpenes
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3841 , http://hdl.handle.net/10962/d1007666 , Natural products -- Therapeutic use , Marine metabolites -- Therapeutic use , Marine pharmacology , Marine algae , Monoterpenes
- Description: Seaweeds of the genus Plocamium are known to produce a variety of halogenated monoterpenes. In addition to their ecological role as feeding deterrents, biological activities reported for these compounds include antibacterial, antialgal, antifungal and anticancer activities. An investigation of the non-polar extracts of the seaweed Plocamium corallorhiza resulted in the isolation of six known halogenated monoterpene compounds, 4-bromo-5-bromomethyl-1-chlorovinyl-2, 5-dichloro-methylcyclohexane (2.68), 1,4,8-tribromo-3 ,7-dichloro-3, 7-dimethyl-1,5-octadiene (2.67), 8-bromo-1 ,3,4,7-tetrachloro-3, 7-dimethyl-1,5-octadiene (2.66), 4,6-dibromo-1,1-dichloro-3,7-dimethyl-2,7-octadiene (2.64), 4,8-dibromo-1,1,7-trichloro-3,7-dimethyl-2,5-octadiene (2.65) and 3,4 ,6,7-tetrachloro-3, 7-dimethyl-1-octene (2.63) as well as eight new compounds, including five halogenated monoterpene aldehydes. The new compounds were identified by 1D and 2D NMR spectroscopic techniques as: 8-Bromo-6,7-dichloro-3,7-dimethyl-octa-2,4-dienal (2.72), 8-Bromo-1,1,2,7-tetrachloro-3,7-dimethyl-octa-3,5-diene (2.70), 4,8-Dichloro-3,7-dimethyl-octa-2,4,6-trienal (2.74), 4-Bromo-8-chloro-3, 7-di methyl-octa-2, 6-dienal (2 76), 8-Bromo-4-chloro-3, 7-dimethyl-octa-2,4 ,6-trienaI (2.75), 4-Bromo-1,3,6,7-tetrachloro-3 ,7-dimethyl-octa-1,4-diene (2.71), 8-Bromo-1,3,4,7-tetrachloro-3,7-dimethyl-octa-1,5-diene (2.69), 4,6-Dibromo-3,7 -dimethyl-octa-2,7-dienal (2.73). All compounds were screened for antimicrobial activity, brine shrimp lethality and cytotoxicity towards oesophageal cancer cells. Compound 2.68 was toxic to brine shrimp larvae at a concentration of 50 μ/mL. It also showed promising activity towards oesophageal cancer cells with an IC₅₀, of 2 μg/mL.
- Full Text:
A study of possible interactions between the pineal gland and the opioidergic system
- Authors: Khan, Razeeya B
- Date: 1990
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3729 , http://hdl.handle.net/10962/d1001468
- Description: Recent observations suggest a link between the pineal gland and the opioid system. Possible areas of interaction between the pineal gland and the opioidergic system in Wistar rats were investigated. The effect of opioids on the pineal gland in organ culture was monitored. Neither morphine, methadone nor the opioid antagonist naloxone was found to affect [¹⁴C]-serotonin metabolism by the pineal gland in vitro. Both the pineal gland and the opioid system are influenced by exposure to stressful stimuli. Morphine and melatonin had protective effects on stress-induced gastric lesions. The ability of melatonin to inhibit lesion formation was found not to be exerted via an opioidergic mechanism. Evidence has been obtained for a possible modulation of the stress response by the pineal gland . The opioid drugs are the most potent analgesic agents available. A possible interaction between the opioid system and the pineal gland in the modulation of the response to noxious stimuli was investigated. An intact pineal gland was found to be necessary for the manifestation of the nocturnally increased response of rats to noxious stimuli
- Full Text:
- Authors: Khan, Razeeya B
- Date: 1990
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3729 , http://hdl.handle.net/10962/d1001468
- Description: Recent observations suggest a link between the pineal gland and the opioid system. Possible areas of interaction between the pineal gland and the opioidergic system in Wistar rats were investigated. The effect of opioids on the pineal gland in organ culture was monitored. Neither morphine, methadone nor the opioid antagonist naloxone was found to affect [¹⁴C]-serotonin metabolism by the pineal gland in vitro. Both the pineal gland and the opioid system are influenced by exposure to stressful stimuli. Morphine and melatonin had protective effects on stress-induced gastric lesions. The ability of melatonin to inhibit lesion formation was found not to be exerted via an opioidergic mechanism. Evidence has been obtained for a possible modulation of the stress response by the pineal gland . The opioid drugs are the most potent analgesic agents available. A possible interaction between the opioid system and the pineal gland in the modulation of the response to noxious stimuli was investigated. An intact pineal gland was found to be necessary for the manifestation of the nocturnally increased response of rats to noxious stimuli
- Full Text:
A study of real-time operating systems for microcomputers
- Authors: Wells, George Clifford
- Date: 1990
- Subjects: Operating systems (Computers) , Microcomputers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4611 , http://hdl.handle.net/10962/d1004896 , Operating systems (Computers) , Microcomputers
- Description: This thesis describes the evaluation of four operating systems for microcomputers. The emphasis of the study is on the suitability of the operating systems for use in real-time applications, such as process control. The evaluation was performed in two sections. The first section was a quantitative assessment of the performance of the real-time features of the operating system. This was performed using benchmarks. The criteria for the benchmarks and their design are discussed. The second section was a qualitative assessment of the suitability of the operating systems for the development and implementation of real-time systems. This was assessed through the implementation of a small simulation of a manufacturing process and its associated control system. The simulation was designed using the Ward and Mellor real-time design method which was extended to handle the special case of a real-time simulation. The operating systems which were selected for the study covered a spectrum from general purpose operating systems to small, specialised real-time operating systems. From the quantitative assessment it emerged that QNX (from Quantum Software Systems) had the best overall performance. Qualitatively, UNIX was found to offer the best system development environment, but it does not have the performance and the characteristics required for real-time applications. This suggests that versions of UNIX that are adapted for real-time applications are worth careful consideration for use both as development systems and implementation systems.
- Full Text:
- Authors: Wells, George Clifford
- Date: 1990
- Subjects: Operating systems (Computers) , Microcomputers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4611 , http://hdl.handle.net/10962/d1004896 , Operating systems (Computers) , Microcomputers
- Description: This thesis describes the evaluation of four operating systems for microcomputers. The emphasis of the study is on the suitability of the operating systems for use in real-time applications, such as process control. The evaluation was performed in two sections. The first section was a quantitative assessment of the performance of the real-time features of the operating system. This was performed using benchmarks. The criteria for the benchmarks and their design are discussed. The second section was a qualitative assessment of the suitability of the operating systems for the development and implementation of real-time systems. This was assessed through the implementation of a small simulation of a manufacturing process and its associated control system. The simulation was designed using the Ward and Mellor real-time design method which was extended to handle the special case of a real-time simulation. The operating systems which were selected for the study covered a spectrum from general purpose operating systems to small, specialised real-time operating systems. From the quantitative assessment it emerged that QNX (from Quantum Software Systems) had the best overall performance. Qualitatively, UNIX was found to offer the best system development environment, but it does not have the performance and the characteristics required for real-time applications. This suggests that versions of UNIX that are adapted for real-time applications are worth careful consideration for use both as development systems and implementation systems.
- Full Text:
A study of South African aquatic Hyphomycetes
- Authors: Greathead, Sarah Kathleen
- Date: 1962
- Subjects: Hyphomycetes -- South Africa , Aquatic fungi -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4269 , http://hdl.handle.net/10962/d1014992
- Description: 1, Eighteen species of aquatic Hyphomycetes are recorded from South Africa for the first time. All except two of these can be assigned to described species. The other two are new species of Articulospora and Anguillospora and are described in this thesis. Three unidentified spore types, an "Articulospora" type and "Anguillospora" type and a Y-shaped spore are also described. 2. Spore development in ten species is described. 3. A key to the fungi described in this thesis is given. 4. General notes on the ecology of these fungi and a table recording the fungi found in the Eastern Cape Province of South Africa, their distribution within the localities and the nature of the material on which they are growing are given. 5. The gross characteristics of plate cultures of six species, five growing on malt agar, Czapek agar, plain agar and maize agar and one on malt agar only are described. 6. Growth of four species in liquid culture using the Czapek-Dox medium is reported. 7. The results of an investigation into the effect of variations in temperature and medium on the growth of plate cultures of five species are analysed, discussed and conclusions are drawn. 8. Growth of certain isolates of four species on twigs is described.
- Full Text:
- Authors: Greathead, Sarah Kathleen
- Date: 1962
- Subjects: Hyphomycetes -- South Africa , Aquatic fungi -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4269 , http://hdl.handle.net/10962/d1014992
- Description: 1, Eighteen species of aquatic Hyphomycetes are recorded from South Africa for the first time. All except two of these can be assigned to described species. The other two are new species of Articulospora and Anguillospora and are described in this thesis. Three unidentified spore types, an "Articulospora" type and "Anguillospora" type and a Y-shaped spore are also described. 2. Spore development in ten species is described. 3. A key to the fungi described in this thesis is given. 4. General notes on the ecology of these fungi and a table recording the fungi found in the Eastern Cape Province of South Africa, their distribution within the localities and the nature of the material on which they are growing are given. 5. The gross characteristics of plate cultures of six species, five growing on malt agar, Czapek agar, plain agar and maize agar and one on malt agar only are described. 6. Growth of four species in liquid culture using the Czapek-Dox medium is reported. 7. The results of an investigation into the effect of variations in temperature and medium on the growth of plate cultures of five species are analysed, discussed and conclusions are drawn. 8. Growth of certain isolates of four species on twigs is described.
- Full Text:
A study of South African computer users' password usage habits and attitude towards password security
- Authors: Friendman, Brandon
- Date: 2014
- Subjects: Computers -- Access control -- Passwords , Computer users -- Attitudes , Internet -- Access control , Internet -- Security measures , Internet -- Management , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4700
- Description: The challenge of having to create and remember a secure password for each user account has become a problem for many computer users and can lead to bad password management practices. Simpler and less secure passwords are often selected and are regularly reused across multiple user accounts. Computer users within corporations and institutions are subject to password policies, policies which require users to create passwords of a specified length and composition and change passwords regularly. These policies often prevent users from reusing previous selected passwords. Security vendors and professionals have sought to improve or even replace password authentication. Technologies such as multi-factor authentication and single sign-on have been developed to complement or even replace password authentication. The objective of the study was to investigate the password habits of South African computer and internet users. The aim was to assess their attitudes toward password security, to determine whether password policies a↵ect the manner in which they manage their passwords and to investigate their exposure to alternate authentication technologies. The results from the online survey demonstrated that password practices of the participants across their professional and personal contexts were generally insecure. Participants often used shorter, simpler and ultimately less secure passwords. Participants would try to memorise all of their passwords or reuse the same password on most of their accounts. Many participants had not received any security awareness training, and additional security technologies (such as multi-factor authentication or password managers) were seldom used or provided to them. The password policies encountered by the participants in their organisations did little towards encouraging the users to apply more secure password practices. Users lack the knowledge and understanding about password security as they had received little or no training pertaining to it.
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- Authors: Friendman, Brandon
- Date: 2014
- Subjects: Computers -- Access control -- Passwords , Computer users -- Attitudes , Internet -- Access control , Internet -- Security measures , Internet -- Management , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4700
- Description: The challenge of having to create and remember a secure password for each user account has become a problem for many computer users and can lead to bad password management practices. Simpler and less secure passwords are often selected and are regularly reused across multiple user accounts. Computer users within corporations and institutions are subject to password policies, policies which require users to create passwords of a specified length and composition and change passwords regularly. These policies often prevent users from reusing previous selected passwords. Security vendors and professionals have sought to improve or even replace password authentication. Technologies such as multi-factor authentication and single sign-on have been developed to complement or even replace password authentication. The objective of the study was to investigate the password habits of South African computer and internet users. The aim was to assess their attitudes toward password security, to determine whether password policies a↵ect the manner in which they manage their passwords and to investigate their exposure to alternate authentication technologies. The results from the online survey demonstrated that password practices of the participants across their professional and personal contexts were generally insecure. Participants often used shorter, simpler and ultimately less secure passwords. Participants would try to memorise all of their passwords or reuse the same password on most of their accounts. Many participants had not received any security awareness training, and additional security technologies (such as multi-factor authentication or password managers) were seldom used or provided to them. The password policies encountered by the participants in their organisations did little towards encouraging the users to apply more secure password practices. Users lack the knowledge and understanding about password security as they had received little or no training pertaining to it.
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