Plasmodium falciparum Hop (PfHop) interacts with the Hsp70 chaperone in a nucleotide-dependent fashion and exhibits ligand selectivity
- Zininga, Tawanda, Makumire, Stanley, Gitau, Grace W, Njunge, James M, Pooe, Ofentse J, Klimek, Hanna, Scheurr, Robina, Raifer, Hartmann, Prinsloo, Earl, Przyborski, Jude M, Hoppe, Heinrich C, Shonhai, Addmore
- Authors: Zininga, Tawanda , Makumire, Stanley , Gitau, Grace W , Njunge, James M , Pooe, Ofentse J , Klimek, Hanna , Scheurr, Robina , Raifer, Hartmann , Prinsloo, Earl , Przyborski, Jude M , Hoppe, Heinrich C , Shonhai, Addmore
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431752 , vital:72801 , xlink:href=" https://doi.org/10.1371/journal.pone.0135326"
- Description: Heat shock proteins (Hsps) play an important role in the development and pathogenicity of malaria parasites. One of the most prominent functions of Hsps is to facilitate the folding of other proteins. Hsps are thought to play a crucial role when malaria parasites invade their host cells and during their subsequent development in hepatocytes and red blood cells. It is thought that Hsps maintain proteostasis under the unfavourable conditions that malaria parasites encounter in the host environment. Although heat shock protein 70 (Hsp70) is capable of independent folding of some proteins, its functional cooperation with heat shock protein 90 (Hsp90) facilitates folding of some proteins such as kinases and steroid hormone receptors into their fully functional forms. The cooperation of Hsp70 and Hsp90 occurs through an adaptor protein called Hsp70-Hsp90 organising protein (Hop). We previously characterised the Hop protein from Plasmodium falciparum (PfHop). We observed that the protein co-localised with the cytosol-localised chaperones, PfHsp70-1 and PfHsp90 at the blood stages of the malaria parasite. In the current study, we demonstrated that PfHop is a stress-inducible protein. We further explored the direct interaction between PfHop and PfHsp70-1 using far Western and surface plasmon resonance (SPR) analyses.
- Full Text:
- Authors: Zininga, Tawanda , Makumire, Stanley , Gitau, Grace W , Njunge, James M , Pooe, Ofentse J , Klimek, Hanna , Scheurr, Robina , Raifer, Hartmann , Prinsloo, Earl , Przyborski, Jude M , Hoppe, Heinrich C , Shonhai, Addmore
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431752 , vital:72801 , xlink:href=" https://doi.org/10.1371/journal.pone.0135326"
- Description: Heat shock proteins (Hsps) play an important role in the development and pathogenicity of malaria parasites. One of the most prominent functions of Hsps is to facilitate the folding of other proteins. Hsps are thought to play a crucial role when malaria parasites invade their host cells and during their subsequent development in hepatocytes and red blood cells. It is thought that Hsps maintain proteostasis under the unfavourable conditions that malaria parasites encounter in the host environment. Although heat shock protein 70 (Hsp70) is capable of independent folding of some proteins, its functional cooperation with heat shock protein 90 (Hsp90) facilitates folding of some proteins such as kinases and steroid hormone receptors into their fully functional forms. The cooperation of Hsp70 and Hsp90 occurs through an adaptor protein called Hsp70-Hsp90 organising protein (Hop). We previously characterised the Hop protein from Plasmodium falciparum (PfHop). We observed that the protein co-localised with the cytosol-localised chaperones, PfHsp70-1 and PfHsp90 at the blood stages of the malaria parasite. In the current study, we demonstrated that PfHop is a stress-inducible protein. We further explored the direct interaction between PfHop and PfHsp70-1 using far Western and surface plasmon resonance (SPR) analyses.
- Full Text:
Overexpression, Purification and Characterisation of the Plasmodium falciparum Hsp70-z (PfHsp70-z) Protein
- Zininga, Tawanda, Achilonu, Ikechukwu, Hoppe, Heinrich C, Prinsloo, Earl, Dirr, Heinrich W, Shonhai, Addmore
- Authors: Zininga, Tawanda , Achilonu, Ikechukwu , Hoppe, Heinrich C , Prinsloo, Earl , Dirr, Heinrich W , Shonhai, Addmore
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431719 , vital:72799 , xlink:href="https://doi.org/10.1371/journal.pone.0129445"
- Description: Six Hsp70-like genes are represented on the genome of Plasmodium falciparum. Of these two occur in the cytosol: P. falciparum Hsp70-z (PfHsp70-z) and PfHsp70-1. PfHsp70-1 is a well characterised canonical Hsp70 that facilitates protein quality control and is crucial for the development of malaria parasites. There is very little known about PfHsp70-z. However, PfHsp70-z is known to be essential and is implicated in suppressing aggregation of asparagine-rich proteins of P. falciparum. In addition, its expression at the clinical stage of malaria correlates with disease prognosis. Based on structural evidence PfHsp70-z belongs to the Hsp110 family of proteins. Since Hsp110 proteins have been described as nucleotide exchange factors (NEFs) of their canonical Hsp70 counterparts, it has been speculated that PfHsp70-z may serve as a NEF of PfHsp70-1. In the current study, P. falciparum cells cultured in vitro were subjected to heat stress, triggering the enhanced expression of PfHsp70-z. Biochemical assays conducted using recombinant PfHsp70-z protein demonstrated that the protein is heat stable and possesses ATPase activity. Furthermore, we observed that PfHsp70-z is capable of self-association. The structural-functional features of PfHsp70-z provide further evidence for its role as a chaperone and possible nucleotide exchange factor of PfHsp70-1.
- Full Text:
- Authors: Zininga, Tawanda , Achilonu, Ikechukwu , Hoppe, Heinrich C , Prinsloo, Earl , Dirr, Heinrich W , Shonhai, Addmore
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431719 , vital:72799 , xlink:href="https://doi.org/10.1371/journal.pone.0129445"
- Description: Six Hsp70-like genes are represented on the genome of Plasmodium falciparum. Of these two occur in the cytosol: P. falciparum Hsp70-z (PfHsp70-z) and PfHsp70-1. PfHsp70-1 is a well characterised canonical Hsp70 that facilitates protein quality control and is crucial for the development of malaria parasites. There is very little known about PfHsp70-z. However, PfHsp70-z is known to be essential and is implicated in suppressing aggregation of asparagine-rich proteins of P. falciparum. In addition, its expression at the clinical stage of malaria correlates with disease prognosis. Based on structural evidence PfHsp70-z belongs to the Hsp110 family of proteins. Since Hsp110 proteins have been described as nucleotide exchange factors (NEFs) of their canonical Hsp70 counterparts, it has been speculated that PfHsp70-z may serve as a NEF of PfHsp70-1. In the current study, P. falciparum cells cultured in vitro were subjected to heat stress, triggering the enhanced expression of PfHsp70-z. Biochemical assays conducted using recombinant PfHsp70-z protein demonstrated that the protein is heat stable and possesses ATPase activity. Furthermore, we observed that PfHsp70-z is capable of self-association. The structural-functional features of PfHsp70-z provide further evidence for its role as a chaperone and possible nucleotide exchange factor of PfHsp70-1.
- Full Text:
An interpretive analysis of the experiences of adults working as university support staff
- Authors: Zini, Thembela Nomonde
- Date: 2021-10-29
- Subjects: Universities and colleges South Africa , Universities and colleges Employees , Universities and colleges Sociological aspects , Identity (Psychology) , Identity (Psychology) Social aspects , Work Psychological aspects , Work Social aspects , Interpretive Phenomenological Analysis (IPA)
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/10962/188888 , vital:44795
- Description: Work means different things to different people and the different meanings they make of their work has the unique ability of contributing to a sense of identity. Support staff have to negotiate their personal identities and social identities to develop a work identity in the complex South African context that has its unique challenges. Exploring how support staff make sense of their experiences, when it comes to their identities, reveals what identity work strategies they use. An interpretative phenomenological method of inquiry was employed as an initial research method to explore the aspects that impact on the identity formation of support staff at Rhodes University. The study aims to investigate how support staff have constructed a work identity through their constructions of their experiences. Six participants were recruited through a purposive sampling method and data were collected using semi-structured interviews. The study revealed that support staff use the following identity work strategies to negotiate their identities: Financial, Personality, Career mobility, Roles, Status and Esteem, Subjective wellbeing. These themes were derived from the narratives of the participants, using the emphases in the data and suggest that support staff use identity work strategies both outside and within the workplace, when constructing their work identities. The study illustrates that as people ascribe different meanings to work, they will define and negotiate their identities in the workplace based upon those meanings. Identity work is indeed challenging for support staff because they need to use identity strategies that are enhancing to their self-esteem. Identity work is a challenging task because of the many tensions and demands of modern society, as adults negotiate their needs to provide for families and to find ways to construct their job status in positive ways. , Thesis (MA) -- Faculty of Humanities, Psychology, 2021
- Full Text:
- Authors: Zini, Thembela Nomonde
- Date: 2021-10-29
- Subjects: Universities and colleges South Africa , Universities and colleges Employees , Universities and colleges Sociological aspects , Identity (Psychology) , Identity (Psychology) Social aspects , Work Psychological aspects , Work Social aspects , Interpretive Phenomenological Analysis (IPA)
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/10962/188888 , vital:44795
- Description: Work means different things to different people and the different meanings they make of their work has the unique ability of contributing to a sense of identity. Support staff have to negotiate their personal identities and social identities to develop a work identity in the complex South African context that has its unique challenges. Exploring how support staff make sense of their experiences, when it comes to their identities, reveals what identity work strategies they use. An interpretative phenomenological method of inquiry was employed as an initial research method to explore the aspects that impact on the identity formation of support staff at Rhodes University. The study aims to investigate how support staff have constructed a work identity through their constructions of their experiences. Six participants were recruited through a purposive sampling method and data were collected using semi-structured interviews. The study revealed that support staff use the following identity work strategies to negotiate their identities: Financial, Personality, Career mobility, Roles, Status and Esteem, Subjective wellbeing. These themes were derived from the narratives of the participants, using the emphases in the data and suggest that support staff use identity work strategies both outside and within the workplace, when constructing their work identities. The study illustrates that as people ascribe different meanings to work, they will define and negotiate their identities in the workplace based upon those meanings. Identity work is indeed challenging for support staff because they need to use identity strategies that are enhancing to their self-esteem. Identity work is a challenging task because of the many tensions and demands of modern society, as adults negotiate their needs to provide for families and to find ways to construct their job status in positive ways. , Thesis (MA) -- Faculty of Humanities, Psychology, 2021
- Full Text:
The relationship between student satisfaction and online learning interaction at a South African Institution of Higher Learning (IHL)
- Authors: Zindove, Problem
- Date: 2025-04-04
- Subjects: Education, Higher South Africa , Web-based instruction South Africa , E-learning , Interaction analysis in education , Student satisfaction
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/479517 , vital:78320
- Description: Institutions of Higher Learning (IHLs) are key providers of skilled labour that drive economic growth. Therefore, it is crucial to ensure that students are satisfied with their interaction in the learning environment, including interaction with peers, instructors, and course content. This satisfaction is vital for positive learning outcomes. The COVID-19 pandemic prompted a shift from traditional face-to-face to online learning, significantly affecting student interaction. This research aimed to explore the relationship between online learning interaction and student satisfaction at a selected South African IHL. A comprehensive review of the South African higher education landscape, online learning interaction, and student satisfaction literature was conducted. Based on this review, a hypothesised model was proposed, identifying the independent variable (and its constructs namely, learner-to-learner interaction, learner-to-instructor interaction, and learner-to-content interaction) that may influence the dependent variable- student satisfaction (encompassing both expectations and experience). The research employed a positivistic approach using a deductive reasoning and quantitative methodology. A survey strategy, consisting of self-administered online and paper-based questionnaires, was used to gather data from a convenience sample of students registered at an IHL in South Africa. A total of 268 usable responses were analysed statistically. The validity and reliability of the measurement instrument were confirmed. Descriptive and inferential statistics, including standard deviation, Pearson`s correlation coefficients, regression analysis, and Analysis of Variance (ANOVA) were applied in the data analysis. The results revealed a statistically significant relationship between online learning interaction (independent variable) and student satisfaction (dependent variable), leading to the acceptance of the hypotheses. No modifications were necessary, as the hypothesised model provided a good fit. This research contributes to the body of knowledge on student satisfaction in online learning interaction within South African IHLs. Its use of the Community of Inquiry (CoI) framework has provided a comprehensive perspective of the online learning interaction variable. Also, this research is among the few that juxtaposed student expectations and student experience in student satisfaction discourse. Furthermore, it was found that the constructs of learner-to-learner interaction and learner-to-instructor interaction have an equally strong and statistically significant relationship with student satisfaction, compared to the learner-to-content interaction construct. It also offers practical, methodological recommendations for IHLs to adopt and implement online learning courses effectively. Among others, the adoption of online learning at IHLs should be encouraged as it leads to student satisfaction. Tangent to this is the need for instructor training programmes on online pedagogy. Future research should also consider qualitative research design to get rich insight into Why and How the relationship between online learning interaction and student satisfaction exists. , Thesis (MCom) -- Faculty of Commerce, Management, 2025
- Full Text:
- Authors: Zindove, Problem
- Date: 2025-04-04
- Subjects: Education, Higher South Africa , Web-based instruction South Africa , E-learning , Interaction analysis in education , Student satisfaction
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/479517 , vital:78320
- Description: Institutions of Higher Learning (IHLs) are key providers of skilled labour that drive economic growth. Therefore, it is crucial to ensure that students are satisfied with their interaction in the learning environment, including interaction with peers, instructors, and course content. This satisfaction is vital for positive learning outcomes. The COVID-19 pandemic prompted a shift from traditional face-to-face to online learning, significantly affecting student interaction. This research aimed to explore the relationship between online learning interaction and student satisfaction at a selected South African IHL. A comprehensive review of the South African higher education landscape, online learning interaction, and student satisfaction literature was conducted. Based on this review, a hypothesised model was proposed, identifying the independent variable (and its constructs namely, learner-to-learner interaction, learner-to-instructor interaction, and learner-to-content interaction) that may influence the dependent variable- student satisfaction (encompassing both expectations and experience). The research employed a positivistic approach using a deductive reasoning and quantitative methodology. A survey strategy, consisting of self-administered online and paper-based questionnaires, was used to gather data from a convenience sample of students registered at an IHL in South Africa. A total of 268 usable responses were analysed statistically. The validity and reliability of the measurement instrument were confirmed. Descriptive and inferential statistics, including standard deviation, Pearson`s correlation coefficients, regression analysis, and Analysis of Variance (ANOVA) were applied in the data analysis. The results revealed a statistically significant relationship between online learning interaction (independent variable) and student satisfaction (dependent variable), leading to the acceptance of the hypotheses. No modifications were necessary, as the hypothesised model provided a good fit. This research contributes to the body of knowledge on student satisfaction in online learning interaction within South African IHLs. Its use of the Community of Inquiry (CoI) framework has provided a comprehensive perspective of the online learning interaction variable. Also, this research is among the few that juxtaposed student expectations and student experience in student satisfaction discourse. Furthermore, it was found that the constructs of learner-to-learner interaction and learner-to-instructor interaction have an equally strong and statistically significant relationship with student satisfaction, compared to the learner-to-content interaction construct. It also offers practical, methodological recommendations for IHLs to adopt and implement online learning courses effectively. Among others, the adoption of online learning at IHLs should be encouraged as it leads to student satisfaction. Tangent to this is the need for instructor training programmes on online pedagogy. Future research should also consider qualitative research design to get rich insight into Why and How the relationship between online learning interaction and student satisfaction exists. , Thesis (MCom) -- Faculty of Commerce, Management, 2025
- Full Text:
The physical activity status and the impact of lifestyle behaviours on workplace productivity and absenteeism of Transnet employees
- Authors: Zimmermann, Sharnae Vanessa
- Date: 2021-10
- Subjects: Transnet (Firm : South Africa) Employees , Absenteeism (Labor) South Africa Durban , Labor productivity South Africa Durban , Exercise , Sedentary behavior , Lifestyles
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190077 , vital:44961
- Description: Increased sitting time, insufficient physical activity and sub-optimal body composition are all contributing to the global disease burden. This is made evident by increases in obesity, type II diabetes, cardiovascular diseases (i.e. hypertension and strokes), cancer and other non-communicable diseases resulting in absenteeism and reduced productivity in the workplace. The global rise in sitting time and physical inactivity is caused, in part, by changes in transport convenience, work roles and technological advancements. Employees working in office environments or driving trains sit for prolonged periods; something which is evident in the industry that Transnet operates in. Sitting time and physical inactivity are independent risk factors for non-communicable diseases with poor nutrition, smoking, alcohol consumption and psychological wellbeing, being separate constructs. The purpose of the study is to determine the levels of sedentary behaviour, physical inactivity, obesity, nutrition, alcohol consumption, smoking, non-communicable disease risk, mental wellbeing and their association with productivity and absenteeism in office workers and train drivers at Transnet Freight Rail, Durban. A cross-sectional study was done with 40 participants, 20 office workers and 20 train drivers. Stature (175.80 ± 9.43 ±cm) and body mass (83.85 ± 20.31 kg) were measured; and body mass index calculated (26.98 ± 5.37 kg.m2). Physical activity levels, sedentary behaviour, body mass index and other lifestyle factors were explored using an amended version of The Health and Wellbeing survey, a self-report measure. The results revealed that there was a high prevalence of sedentary behaviour (train drivers = 7.85 ± 2.21 and office workers = 8.3 ± 1.03), particularly among office workers. Most of the participants had a relatively high body mass index, placing in the overweight and obese category, particularly among train drivers. The prevalence of physical inactivity was marginally higher for office workers compared to train drivers. There were significantly (p<0.05) higher levels of physical activity within train drivers with a moderate effect size. There were limited associations found between lifestyle factors and sickness absenteeism and worker productivity. Obesity had the most prominent relationship with noncommunicable diseases, followed by high levels of sedentary behaviour, not meeting physical activity guidelines, obesity, overweight, and prolonged sitting time at work. A significant and moderate correlation was found between obesity and absenteeism (train drivers: r = 0.32 and office workers: r= 0.46), however, no associations were found between sedentary behaviour, physical activity and fruit and vegetable intake and absenteeism. Lastly, the association between physical activity and productivity among the train drivers was low negative (r=-0.15) which was not significant (p>0.05). The associations between physical activity and productivity among office workers, however, was both significant (p<0.05) and moderate positive (r=0.39). The vegetable intake among the office workers showed a significant (p<0.05) moderate positive association with productivity (r=0.49). The association between vegetable intake and productivity among the train drivers was not significant (p>0.05) and low positive (r=0.16). There was a significant (p<0.05) and moderate positive association between fruit intake and productivity among both train drivers (r=0.43) and office workers (r=0.47). No significant associations between sedentary behaviour and obesity and productivity were found. The current study provided new insight into the risks associated with lifestyle factors of office workers and train drivers in the transportation sector. The poor lifestyle factors, together with the high prevalence of sedentary behaviour and physical inactivity, provide ideal opportunities for future interventions to focus on workers productivity and overall wellbeing. The job design of train drivers and office workers does not place significant importance on employee health and wellness. Essentially they are not “healthy” but they work productively, giving reason as to why employee wellness is not a priority for employers. The current findings of the study suggest that adopting regular physical activity, healthy dietary patterns and reduced sitting time should be promoted as key components of lifestyle interventions for the prevention of non-communicable diseases in office workers and train drivers. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2021
- Full Text:
- Authors: Zimmermann, Sharnae Vanessa
- Date: 2021-10
- Subjects: Transnet (Firm : South Africa) Employees , Absenteeism (Labor) South Africa Durban , Labor productivity South Africa Durban , Exercise , Sedentary behavior , Lifestyles
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190077 , vital:44961
- Description: Increased sitting time, insufficient physical activity and sub-optimal body composition are all contributing to the global disease burden. This is made evident by increases in obesity, type II diabetes, cardiovascular diseases (i.e. hypertension and strokes), cancer and other non-communicable diseases resulting in absenteeism and reduced productivity in the workplace. The global rise in sitting time and physical inactivity is caused, in part, by changes in transport convenience, work roles and technological advancements. Employees working in office environments or driving trains sit for prolonged periods; something which is evident in the industry that Transnet operates in. Sitting time and physical inactivity are independent risk factors for non-communicable diseases with poor nutrition, smoking, alcohol consumption and psychological wellbeing, being separate constructs. The purpose of the study is to determine the levels of sedentary behaviour, physical inactivity, obesity, nutrition, alcohol consumption, smoking, non-communicable disease risk, mental wellbeing and their association with productivity and absenteeism in office workers and train drivers at Transnet Freight Rail, Durban. A cross-sectional study was done with 40 participants, 20 office workers and 20 train drivers. Stature (175.80 ± 9.43 ±cm) and body mass (83.85 ± 20.31 kg) were measured; and body mass index calculated (26.98 ± 5.37 kg.m2). Physical activity levels, sedentary behaviour, body mass index and other lifestyle factors were explored using an amended version of The Health and Wellbeing survey, a self-report measure. The results revealed that there was a high prevalence of sedentary behaviour (train drivers = 7.85 ± 2.21 and office workers = 8.3 ± 1.03), particularly among office workers. Most of the participants had a relatively high body mass index, placing in the overweight and obese category, particularly among train drivers. The prevalence of physical inactivity was marginally higher for office workers compared to train drivers. There were significantly (p<0.05) higher levels of physical activity within train drivers with a moderate effect size. There were limited associations found between lifestyle factors and sickness absenteeism and worker productivity. Obesity had the most prominent relationship with noncommunicable diseases, followed by high levels of sedentary behaviour, not meeting physical activity guidelines, obesity, overweight, and prolonged sitting time at work. A significant and moderate correlation was found between obesity and absenteeism (train drivers: r = 0.32 and office workers: r= 0.46), however, no associations were found between sedentary behaviour, physical activity and fruit and vegetable intake and absenteeism. Lastly, the association between physical activity and productivity among the train drivers was low negative (r=-0.15) which was not significant (p>0.05). The associations between physical activity and productivity among office workers, however, was both significant (p<0.05) and moderate positive (r=0.39). The vegetable intake among the office workers showed a significant (p<0.05) moderate positive association with productivity (r=0.49). The association between vegetable intake and productivity among the train drivers was not significant (p>0.05) and low positive (r=0.16). There was a significant (p<0.05) and moderate positive association between fruit intake and productivity among both train drivers (r=0.43) and office workers (r=0.47). No significant associations between sedentary behaviour and obesity and productivity were found. The current study provided new insight into the risks associated with lifestyle factors of office workers and train drivers in the transportation sector. The poor lifestyle factors, together with the high prevalence of sedentary behaviour and physical inactivity, provide ideal opportunities for future interventions to focus on workers productivity and overall wellbeing. The job design of train drivers and office workers does not place significant importance on employee health and wellness. Essentially they are not “healthy” but they work productively, giving reason as to why employee wellness is not a priority for employers. The current findings of the study suggest that adopting regular physical activity, healthy dietary patterns and reduced sitting time should be promoted as key components of lifestyle interventions for the prevention of non-communicable diseases in office workers and train drivers. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2021
- Full Text:
Grand challenges in urban agriculture: ecological and social approaches to transformative sustainability
- Zimmerer, Karl S, Bell, Martha G, Chirisa, Innocent, Duvall, Chris S, Egerer, Monika, Hung, Po-Yi, Lerner, Amy M, Shackleton, Charlie M, Ward, James D, Ochoa, Carolina Y
- Authors: Zimmerer, Karl S , Bell, Martha G , Chirisa, Innocent , Duvall, Chris S , Egerer, Monika , Hung, Po-Yi , Lerner, Amy M , Shackleton, Charlie M , Ward, James D , Ochoa, Carolina Y
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/402287 , vital:69838 , xlink:href="https://doi.org/10.3389/fsufs.2021.668561"
- Description: This synopsis of the Grand Challenges of Urban Agriculture (UA) is framed by the urgent need to understand and strengthen the expanding yet highly diverse roles of UA amid rapid global urbanization, failures of predominant food systems, and crises in systems of physical and mental health. More than half of humanity lives in cities today and by 2030 this is projected to grow to 60.4 percent, ∼5 billion people (UN Habitat, 2020). More than 90 percent of urban demographic increase is anticipated to take place in the developing world. Ecological and social dimensions of UA are situated in these expanding spaces of cities, towns, and villages (along with their urban fringe or peri-urban areas), and among their diverse populations. UA is further situated in the powerful, far-reaching influences of urbanization processes that occur within and beyond these spaces. UA is thus integral to the prospect of Urban Sustainability as SDG 11 (“Make cities and human settlements inclusive, safe, resilient and sustainable”) of the U.N.’s 2030 Agenda for Sustainable Development.
- Full Text:
- Authors: Zimmerer, Karl S , Bell, Martha G , Chirisa, Innocent , Duvall, Chris S , Egerer, Monika , Hung, Po-Yi , Lerner, Amy M , Shackleton, Charlie M , Ward, James D , Ochoa, Carolina Y
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/402287 , vital:69838 , xlink:href="https://doi.org/10.3389/fsufs.2021.668561"
- Description: This synopsis of the Grand Challenges of Urban Agriculture (UA) is framed by the urgent need to understand and strengthen the expanding yet highly diverse roles of UA amid rapid global urbanization, failures of predominant food systems, and crises in systems of physical and mental health. More than half of humanity lives in cities today and by 2030 this is projected to grow to 60.4 percent, ∼5 billion people (UN Habitat, 2020). More than 90 percent of urban demographic increase is anticipated to take place in the developing world. Ecological and social dimensions of UA are situated in these expanding spaces of cities, towns, and villages (along with their urban fringe or peri-urban areas), and among their diverse populations. UA is further situated in the powerful, far-reaching influences of urbanization processes that occur within and beyond these spaces. UA is thus integral to the prospect of Urban Sustainability as SDG 11 (“Make cities and human settlements inclusive, safe, resilient and sustainable”) of the U.N.’s 2030 Agenda for Sustainable Development.
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Host searching and oviposition behaviour of Agathis bishopi (Hymenoptera: Braconidae), a larval parasitoid of false codling moth, Thaumatotibia leucotreta (Lepidoptera: Tortricidae): a potential proxy indicator for fruit infestation
- Zimba, Kennedy J, Heshula, Lelethu U P, Moore, Sean D, Hill, Martin P
- Authors: Zimba, Kennedy J , Heshula, Lelethu U P , Moore, Sean D , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/407019 , vital:70330 , xlink:href="https://hdl.handle.net/10520/EJC195073"
- Description: Agathis bishopi (Nixon) (Hymenoptera: Braconidae)is an arrhenotokous larval endoparasitoid of Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae) (Gendall 2007; Hofmeyr et al. 2015) commonly known as false codling moth (FCM), a major pest of citrus in South Africa (Moore et al. 2004; Malan et al. 2011). Under field conditions, A. bishopi was identified attacking more than 34% of FCM larvae in fruit, showing good biocontrol potential (Gendall 2007). Preference by A. bishopi for parasitising the early instars of its concealed host suggests that the parasitoid has strong natural host location ability (Sishuba 2003; Gendall 2007).
- Full Text:
- Authors: Zimba, Kennedy J , Heshula, Lelethu U P , Moore, Sean D , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/407019 , vital:70330 , xlink:href="https://hdl.handle.net/10520/EJC195073"
- Description: Agathis bishopi (Nixon) (Hymenoptera: Braconidae)is an arrhenotokous larval endoparasitoid of Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae) (Gendall 2007; Hofmeyr et al. 2015) commonly known as false codling moth (FCM), a major pest of citrus in South Africa (Moore et al. 2004; Malan et al. 2011). Under field conditions, A. bishopi was identified attacking more than 34% of FCM larvae in fruit, showing good biocontrol potential (Gendall 2007). Preference by A. bishopi for parasitising the early instars of its concealed host suggests that the parasitoid has strong natural host location ability (Sishuba 2003; Gendall 2007).
- Full Text:
Agathis bishopi, a larval parasitoid of false codling moth Thaumatotibia leucotreta: laboratory rearing and effect of adult food on parasitism and longevity
- Zimba, Kennedy J, Moore, Sean D, Heshula, Lelethu U P, Hill, Martin P
- Authors: Zimba, Kennedy J , Moore, Sean D , Heshula, Lelethu U P , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406985 , vital:70328 , xlink:href="https://hdl.handle.net/10520/EJC185849"
- Description: Agathis bishopi (Nixon) (Hymenoptera: Braconidae) is a koinobiont larval endoparasitoid of false codling moth (FCM), Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), a pest of economic importance on citrus in South Africa. In the field Agathis bishopi was found to parasitise up to 34 % of FCM larvae in fruit, reflecting reasonable biocontrol potential. Improving the rearing of A. bishopi would therefore complement the existing biocontrol strategies for FCM. In several parasitic wasps, sugar concentration and feeding duration has been shown to influence parasitism and longevity. However, their effect on parasitism and longevity of A. bishopi is unknown. In the present study a rearing protocol for A. bishopi is described, including evaluation of the effects of honey concentration on parasitoid longevity. On average, 18.2%of FCM larvae in rearing containers were parasitised under the rearing protocol described. Cotton wool, instead of paper towelling, as honey carrier for feeding parasitoids in rearing containers significantly increased parasitism and yield of offspring. Furthermore, longevity significantly increased with higher concentrations of honey. Maximum lifespan duration for male and female parasitoids was achieved when parasitoids were fed on 36 % (w/v) honey. Results from this study indicate that A. bishopi requires a sufficient concentration of sugar, coupled with frequent and prolonged feeding on a cotton wool substrate, in order to achieve maximum parasitism and longevity. Such information provides a basis for optimising mass-rearing and longevity of A. bishopi and parasitism of FCM in orchards.
- Full Text:
- Authors: Zimba, Kennedy J , Moore, Sean D , Heshula, Lelethu U P , Hill, Martin P
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406985 , vital:70328 , xlink:href="https://hdl.handle.net/10520/EJC185849"
- Description: Agathis bishopi (Nixon) (Hymenoptera: Braconidae) is a koinobiont larval endoparasitoid of false codling moth (FCM), Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), a pest of economic importance on citrus in South Africa. In the field Agathis bishopi was found to parasitise up to 34 % of FCM larvae in fruit, reflecting reasonable biocontrol potential. Improving the rearing of A. bishopi would therefore complement the existing biocontrol strategies for FCM. In several parasitic wasps, sugar concentration and feeding duration has been shown to influence parasitism and longevity. However, their effect on parasitism and longevity of A. bishopi is unknown. In the present study a rearing protocol for A. bishopi is described, including evaluation of the effects of honey concentration on parasitoid longevity. On average, 18.2%of FCM larvae in rearing containers were parasitised under the rearing protocol described. Cotton wool, instead of paper towelling, as honey carrier for feeding parasitoids in rearing containers significantly increased parasitism and yield of offspring. Furthermore, longevity significantly increased with higher concentrations of honey. Maximum lifespan duration for male and female parasitoids was achieved when parasitoids were fed on 36 % (w/v) honey. Results from this study indicate that A. bishopi requires a sufficient concentration of sugar, coupled with frequent and prolonged feeding on a cotton wool substrate, in order to achieve maximum parasitism and longevity. Such information provides a basis for optimising mass-rearing and longevity of A. bishopi and parasitism of FCM in orchards.
- Full Text:
Agathis bishopi (Hymenoptera: Braconidae) as a potential tool for detecting oranges infested with Thaumatotibia leucotreta (Lepidoptera: Tortricidae)
- Zimba, Kennedy J, Hill, Martin P, Moore, Sean D, Heshula, Unathi
- Authors: Zimba, Kennedy J , Hill, Martin P , Moore, Sean D , Heshula, Unathi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423955 , vital:72108 , xlink:href="https://doi.org/10.1007/s10905-015-9526-0"
- Description: In South Africa, Thaumatotibia leucotreta is a key pest of citrus impacting its production and trade. Detection of newly infested fruit by visual inspection is challenging and poses a risk of packing infested with healthy fruit for export. Agathis bishopi is a larval endoparasitoid of T. leucotreta, attacking early larval instars. Understanding how A. bishopi parasitoids locate fruit infested with their host is of interest for developing an efficient detector for T. leucotreta infested fruit. The response of female adult A. bishopi parasitoids to olfactory and visual cues associated with T. leucotreta infested fruit were evaluated using a Y-tube olfactometer and flight tunnel. Agathis bishopi parasitoids were strongly attracted to infested fruit over healthy fruit, either when only olfactory or combinations of visual and olfactory cues were offered. Among the four synthetic compounds tested, D-limonene and ocimene elicited a strong attraction to parasitoids with response rates of 92 % and 72 % respectively. A blend of four synthetic compounds simulating T. leucotreta infested fruit odour equally elicited strong attraction to parasitoids (84 % response rate). Attraction of parasitoids to infested fruit cues was heightened by prior experience, suggesting the occurrence of associative learning. Results from this study indicate that A. bishopi parasitoids mainly rely on olfactory cues in host habitat location and that D-limonene and ocimene are the major attractants in infested fruit volatiles. These findings and the potential for manipulating A. bishopi for detection of infested fruit in the packhouse are discussed.
- Full Text:
- Authors: Zimba, Kennedy J , Hill, Martin P , Moore, Sean D , Heshula, Unathi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423955 , vital:72108 , xlink:href="https://doi.org/10.1007/s10905-015-9526-0"
- Description: In South Africa, Thaumatotibia leucotreta is a key pest of citrus impacting its production and trade. Detection of newly infested fruit by visual inspection is challenging and poses a risk of packing infested with healthy fruit for export. Agathis bishopi is a larval endoparasitoid of T. leucotreta, attacking early larval instars. Understanding how A. bishopi parasitoids locate fruit infested with their host is of interest for developing an efficient detector for T. leucotreta infested fruit. The response of female adult A. bishopi parasitoids to olfactory and visual cues associated with T. leucotreta infested fruit were evaluated using a Y-tube olfactometer and flight tunnel. Agathis bishopi parasitoids were strongly attracted to infested fruit over healthy fruit, either when only olfactory or combinations of visual and olfactory cues were offered. Among the four synthetic compounds tested, D-limonene and ocimene elicited a strong attraction to parasitoids with response rates of 92 % and 72 % respectively. A blend of four synthetic compounds simulating T. leucotreta infested fruit odour equally elicited strong attraction to parasitoids (84 % response rate). Attraction of parasitoids to infested fruit cues was heightened by prior experience, suggesting the occurrence of associative learning. Results from this study indicate that A. bishopi parasitoids mainly rely on olfactory cues in host habitat location and that D-limonene and ocimene are the major attractants in infested fruit volatiles. These findings and the potential for manipulating A. bishopi for detection of infested fruit in the packhouse are discussed.
- Full Text:
Structural modification of RhIIItriarylcorroles for enhanced electrocatalyzed hydrogen evolution reactions
- Zhu, Weihua, Li, Lihua, Wang, Yu, Mack, John, Dingiswayo, Somila, Nyokong, Tebello, Liang, Xu
- Authors: Zhu, Weihua , Li, Lihua , Wang, Yu , Mack, John , Dingiswayo, Somila , Nyokong, Tebello , Liang, Xu
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229933 , vital:49724 , xlink:href="https://doi.org/10.1016/j.dyepig.2021.110046"
- Description: A series of A3 type RhIIItriarylcorroles 2a-c with different meso-substituents with differing electron-donating and withdrawing properties and two A2B type RhIIItriarylcorroles 4a-b with meso-methylthiophenyls at the B position have been prepared and characterized. An analysis of structure-property relationships of 2a-c and 4a-b has been carried out by comparing the optical spectroscopy and electrochemistry of the dyes to trends predicted in DFT and TD-DFT calculations. Rational structural modification strategies that enhance the suitability of 2a-c for use as highly efficient catalysts for hydrogen evolution reactions on glassy carbon electrodes coated with 2a-c/reduced graphene oxide composites and of 4a-b in surface-modified Au electrodes are explored.
- Full Text:
- Authors: Zhu, Weihua , Li, Lihua , Wang, Yu , Mack, John , Dingiswayo, Somila , Nyokong, Tebello , Liang, Xu
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229933 , vital:49724 , xlink:href="https://doi.org/10.1016/j.dyepig.2021.110046"
- Description: A series of A3 type RhIIItriarylcorroles 2a-c with different meso-substituents with differing electron-donating and withdrawing properties and two A2B type RhIIItriarylcorroles 4a-b with meso-methylthiophenyls at the B position have been prepared and characterized. An analysis of structure-property relationships of 2a-c and 4a-b has been carried out by comparing the optical spectroscopy and electrochemistry of the dyes to trends predicted in DFT and TD-DFT calculations. Rational structural modification strategies that enhance the suitability of 2a-c for use as highly efficient catalysts for hydrogen evolution reactions on glassy carbon electrodes coated with 2a-c/reduced graphene oxide composites and of 4a-b in surface-modified Au electrodes are explored.
- Full Text:
Synthesis and properties of chiral amide-bonded porphyrin dimers with various functional bridging blocks
- Zhu, Weihua, Haider, Syed Najeeb-uz-Zaman, Zhang, Honglin, Attatsi, Isaac K, Mack, John, Dingiswayo, Somila, Nyokong, Tebello, Song, Yuting, Xu, Haijun, Liang, Xu
- Authors: Zhu, Weihua , Haider, Syed Najeeb-uz-Zaman , Zhang, Honglin , Attatsi, Isaac K , Mack, John , Dingiswayo, Somila , Nyokong, Tebello , Song, Yuting , Xu, Haijun , Liang, Xu
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186791 , vital:44534 , xlink:href="https://doi.org/10.1016/j.dyepig.2019.107740"
- Description: Eight porphyrin dimers with various functional bridging blocks and chiral amide-bonds were synthesized and characterized. An analysis of the spectroscopy and electrochemistry has been carried out to demonstrate that the chiral properties can be modified by changing the interchromophoric through-space coupling distance between the two porphyrin chromophores by introducing various bonding and bridging blocks.
- Full Text:
- Authors: Zhu, Weihua , Haider, Syed Najeeb-uz-Zaman , Zhang, Honglin , Attatsi, Isaac K , Mack, John , Dingiswayo, Somila , Nyokong, Tebello , Song, Yuting , Xu, Haijun , Liang, Xu
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186791 , vital:44534 , xlink:href="https://doi.org/10.1016/j.dyepig.2019.107740"
- Description: Eight porphyrin dimers with various functional bridging blocks and chiral amide-bonds were synthesized and characterized. An analysis of the spectroscopy and electrochemistry has been carried out to demonstrate that the chiral properties can be modified by changing the interchromophoric through-space coupling distance between the two porphyrin chromophores by introducing various bonding and bridging blocks.
- Full Text:
Diversification of the African legless skinks in the subfamily Acontinae (Family Scincidae)
- Zhao, Zhongning, Conradie, Werner C, Pietersen, Darren W, Jordaan, Adriaan, Nicolau, Gary K, Edwards, Shelley, Riekert, Stephanus, Heideman, Neil
- Authors: Zhao, Zhongning , Conradie, Werner C , Pietersen, Darren W , Jordaan, Adriaan , Nicolau, Gary K , Edwards, Shelley , Riekert, Stephanus , Heideman, Neil
- Date: 2023
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/461495 , vital:76207 , xlink:href="https://doi.org/10.1016/j.ympev.2023.107747"
- Description: Cladogenic diversification is often explained by referring to climatic oscillations and geomorphic shifts that cause allopatric speciation. In this regard, southern Africa retains a high level of landscape heterogeneity in vegetation, geology, and rainfall patterns. The legless skink subfamily Acontinae occurs broadly across the southern African subcontinent and therefore provides an ideal model group for investigating biogeographic patterns associated with the region. A robust phylogenetic study of the Acontinae with comprehensive coverage and adequate sampling of each taxon has been lacking up until now, resulting in unresolved questions regarding the subfamily’s biogeography and evolution. In this study, we used multi-locus genetic markers (three mitochondrial and two nuclear) with comprehensive taxon coverage (all currently recognized Acontinae species) and adequate sampling (multiple specimens for most taxa) of each taxon to infer a phylogeny for the subfamily.
- Full Text:
- Authors: Zhao, Zhongning , Conradie, Werner C , Pietersen, Darren W , Jordaan, Adriaan , Nicolau, Gary K , Edwards, Shelley , Riekert, Stephanus , Heideman, Neil
- Date: 2023
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/461495 , vital:76207 , xlink:href="https://doi.org/10.1016/j.ympev.2023.107747"
- Description: Cladogenic diversification is often explained by referring to climatic oscillations and geomorphic shifts that cause allopatric speciation. In this regard, southern Africa retains a high level of landscape heterogeneity in vegetation, geology, and rainfall patterns. The legless skink subfamily Acontinae occurs broadly across the southern African subcontinent and therefore provides an ideal model group for investigating biogeographic patterns associated with the region. A robust phylogenetic study of the Acontinae with comprehensive coverage and adequate sampling of each taxon has been lacking up until now, resulting in unresolved questions regarding the subfamily’s biogeography and evolution. In this study, we used multi-locus genetic markers (three mitochondrial and two nuclear) with comprehensive taxon coverage (all currently recognized Acontinae species) and adequate sampling (multiple specimens for most taxa) of each taxon to infer a phylogeny for the subfamily.
- Full Text:
Synthesis and photophysical properties of a covalently linked porphyrin-phthalocyanine conjugate
- Zhao, Zhixin, Ogunsipe, Abimbola O, Maree, M David, Nyokong, Tebello
- Authors: Zhao, Zhixin , Ogunsipe, Abimbola O , Maree, M David , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300358 , vital:57922 , xlink:href="https://doi.org/10.1142/S1088424605000253"
- Description: The synthesis of a phthalocyanine-porphyrin heteropentamer (zinc(II) tetra(5-phenoxy-10,15,20-triphenylporphyrin)) zinc(II) phthalocyanine, (ZnPc-(ZnTPP)4), containing four units of zinc tetraphenylporphyrin linked to a central zinc phthalocyanine macrocycle via an ether linkage is reported. The photophysical parameters of the pentamer are reported in toluene and dimethyl sulfoxide (DMSO). The observed differences in the fluorescence behavior of the pentamer in the two solvents is explained in terms of emission from different states; charge transfer state in DMSO and locally excited state in toluene. The rate constants for fluorescence, intersystem crossing, internal conversion, and of charge and energy transfer are reported for the pentamer. Quantum yields for fluorescence, internal conversion, triplet state and of charge and energy transfer are also reported for the pentamer, ZnPc-(ZnTPP)4 and the mixture of ZnPc and ZnTPP. The latter two parameters are higher in the pentamer compared to a mixture containing ZnPc and ZnTPP.
- Full Text:
- Authors: Zhao, Zhixin , Ogunsipe, Abimbola O , Maree, M David , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300358 , vital:57922 , xlink:href="https://doi.org/10.1142/S1088424605000253"
- Description: The synthesis of a phthalocyanine-porphyrin heteropentamer (zinc(II) tetra(5-phenoxy-10,15,20-triphenylporphyrin)) zinc(II) phthalocyanine, (ZnPc-(ZnTPP)4), containing four units of zinc tetraphenylporphyrin linked to a central zinc phthalocyanine macrocycle via an ether linkage is reported. The photophysical parameters of the pentamer are reported in toluene and dimethyl sulfoxide (DMSO). The observed differences in the fluorescence behavior of the pentamer in the two solvents is explained in terms of emission from different states; charge transfer state in DMSO and locally excited state in toluene. The rate constants for fluorescence, intersystem crossing, internal conversion, and of charge and energy transfer are reported for the pentamer. Quantum yields for fluorescence, internal conversion, triplet state and of charge and energy transfer are also reported for the pentamer, ZnPc-(ZnTPP)4 and the mixture of ZnPc and ZnTPP. The latter two parameters are higher in the pentamer compared to a mixture containing ZnPc and ZnTPP.
- Full Text:
Meso-and axially-modified IrIIItriarylcorroles with tunable electrocatalytic properties
- Zhang, Xifeng, Wang, Yu, Zhu, Weihua, Mack, John, Soy, Rodah C, Nyokong, Tebello, Liang, Xu
- Authors: Zhang, Xifeng , Wang, Yu , Zhu, Weihua , Mack, John , Soy, Rodah C , Nyokong, Tebello , Liang, Xu
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190851 , vital:45034 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.02.040"
- Description: The synthesis of three A2B type Ir(III)triarylcorroles with meso-aryl substituents that provide electron donating (push) and withdrawing (pull) properties and three A3 type IrIIItriphenylcorroles with differing pyridine axial ligands is reported, along with their structural characterization. An analysis of the structure-property relationships in the optical and redox properties has been carried out by comparing their optical spectroscopy and electrochemistry to trends predicted in DFT and TD-DFT calculations. The results demonstrate that A2B type IrIIItriarylcorroles are highly efficient electrocatalyzed oxygen reduction reactions (ORRs) and that their reactivity can be modulated by modulating the electronic structure by changing the nature of the meso-substituent at the B-positions, and even axial pyridine ligands.
- Full Text:
- Authors: Zhang, Xifeng , Wang, Yu , Zhu, Weihua , Mack, John , Soy, Rodah C , Nyokong, Tebello , Liang, Xu
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190851 , vital:45034 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.02.040"
- Description: The synthesis of three A2B type Ir(III)triarylcorroles with meso-aryl substituents that provide electron donating (push) and withdrawing (pull) properties and three A3 type IrIIItriphenylcorroles with differing pyridine axial ligands is reported, along with their structural characterization. An analysis of the structure-property relationships in the optical and redox properties has been carried out by comparing their optical spectroscopy and electrochemistry to trends predicted in DFT and TD-DFT calculations. The results demonstrate that A2B type IrIIItriarylcorroles are highly efficient electrocatalyzed oxygen reduction reactions (ORRs) and that their reactivity can be modulated by modulating the electronic structure by changing the nature of the meso-substituent at the B-positions, and even axial pyridine ligands.
- Full Text:
Restless imagination: material, urban space and contemporary art practices in postcolonial Harare
- Authors: Zhang, Lifang
- Date: 2024-10-11
- Subjects: African art , Art, Modern 21st century , Materiality , Zimbabwean art , Public spaces in art Zimbabwe Harare , Found objects (Art)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/467061 , vital:76811 , DOI htps://doi.org/10.21504/10962/467061
- Description: The use of everyday objects as art materials has evolved into a contemporary phenomenon in Africa, deeply rooted in specific contexts and possessing global relevance. Despite limited scholarly attention, existing discussions tend to revolve around individual artists or particular mediums. Many discourses are associated with either the prevailing universalist perspective that views the trend as Western avant-garde derivation or the reductionist narrative that attributes it merely to local material scarcity. There exists a critical need to investigate historical genealogies and explore the theoretical frameworks essential for comprehending this phenomenon. Through a combination of visual analysis, fieldwork and interviews, this thesis conducts an in-depth examination of the use of found materials in Zimbabwe, exploring its historiography, mechanism, impact, and visual achievements. This thesis situates the investigation in postcolonial Harare, the city that profoundly shaped the evolution of the phenomenon of using found materials. Regarding timeframe, this thesis examines contemporary Zimbabwean artists’ practices, with a special emphasis on the period following the Redefinitions movement in the early 2000s. However, it also explores the pioneering material innovations of Tapfuma Gutsa and Keston Beaton, as well as analyses the importance of the Pachipamwe workshop between the 1980s and 1990s. Among the artists, it highlights those who consistently engage with found materials and delve into their interactions with urban spaces in their practices. With the city as the analytical framework, this thesis draws on debates centring on contemporary African art and theories about materiality and urban studies. Approaching found materials as the materiality of both art and the city, it reveals a convergence of various interrelated artistic practices in Harare. The multidimensional relationships are manifested in the artistic processes, where the collection of materials, the creation of artworks, and collaboration with diverse urban groups, are intricately linked to urban spaces in Harare. By unfolding this process and emphasising the labour of artists, this thesis transcends conventional perceptions of artworks as mere visual objects, revealing the societal and spatial interactions inherent in artistic practices involving found materials. This thesis also explores the visual and semantical interactions between art and the city, centring on a curated array of artworks which is not merely a visual representation or reflection of the city but also provides critical thoughts on and dialogues with the city, as well as (re)imaginations and aspirations of the urban landscape. The relationship between art and the city is further deepened through iii artistic practices, extending beyond the creation of artworks and involving art infrastructure building in Harare. This thesis conceptualises artists’ practices of working with found material as restless imagination, a term drawn from the name of the city, which refers to “no one sleeps” in the Shona language. The restlessness embedded in its naming has characterised the city in various dimensions and across time, with the haunting colonial legacy, ongoing urban crises, ubiquitous movements and the ordinary people’s unwavering efforts for liberation and survival. Artists residing in postcolonial Harare also adopt and cultivate restlessness as a working strategy not only to cope with but also to transgress such conditions. The evolution of found materials has been unfolded through a continuous process of restless imagination and innovative manoeuvres, which are embodied in the continual re-imagination of the convention of art materials, the expressive capacities of specific materials, and a commitment to labour throughout the transformative process. This open-ended though productive process of exploration perpetuates and extends to the re-imagination and reclaiming of urban spaces, transforming them into artistic spaces that foster artistic creation and the reproduction of artists and imaginations. This thesis argues the potential framing and comprehension of Harare city as the site of restless imagination pursued, embodied and materialised by artists through their artwork and engagement with urban spaces. Contemporary Zimbabwean artists have redefined their artistic practices, interacting with the materiality of everyday urban life, urban matters, urban spaces, and urban communities, and, concurrently, the relationship between art and city, art and society. By doing so, they open up space for possibilities to refashion the restless city, negotiate urban citizenship, and recreate themselves as agentive subjects in postcolonial Harare. It could be argued that artists, as urban citizens, akin to other residents grappling with everyday life in the city, also exercise their arts of citizenship through their creative innovations in artistic expression and practices. Therefore, this thesis not only delves into the contextualisation of artistic practices in Harare but also contributes to broader discussions on everyday practices in African cities through the lens of art. , Thesis (PhD) -- Faculty of Humanities, Fine Art, 2024
- Full Text:
- Authors: Zhang, Lifang
- Date: 2024-10-11
- Subjects: African art , Art, Modern 21st century , Materiality , Zimbabwean art , Public spaces in art Zimbabwe Harare , Found objects (Art)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/467061 , vital:76811 , DOI htps://doi.org/10.21504/10962/467061
- Description: The use of everyday objects as art materials has evolved into a contemporary phenomenon in Africa, deeply rooted in specific contexts and possessing global relevance. Despite limited scholarly attention, existing discussions tend to revolve around individual artists or particular mediums. Many discourses are associated with either the prevailing universalist perspective that views the trend as Western avant-garde derivation or the reductionist narrative that attributes it merely to local material scarcity. There exists a critical need to investigate historical genealogies and explore the theoretical frameworks essential for comprehending this phenomenon. Through a combination of visual analysis, fieldwork and interviews, this thesis conducts an in-depth examination of the use of found materials in Zimbabwe, exploring its historiography, mechanism, impact, and visual achievements. This thesis situates the investigation in postcolonial Harare, the city that profoundly shaped the evolution of the phenomenon of using found materials. Regarding timeframe, this thesis examines contemporary Zimbabwean artists’ practices, with a special emphasis on the period following the Redefinitions movement in the early 2000s. However, it also explores the pioneering material innovations of Tapfuma Gutsa and Keston Beaton, as well as analyses the importance of the Pachipamwe workshop between the 1980s and 1990s. Among the artists, it highlights those who consistently engage with found materials and delve into their interactions with urban spaces in their practices. With the city as the analytical framework, this thesis draws on debates centring on contemporary African art and theories about materiality and urban studies. Approaching found materials as the materiality of both art and the city, it reveals a convergence of various interrelated artistic practices in Harare. The multidimensional relationships are manifested in the artistic processes, where the collection of materials, the creation of artworks, and collaboration with diverse urban groups, are intricately linked to urban spaces in Harare. By unfolding this process and emphasising the labour of artists, this thesis transcends conventional perceptions of artworks as mere visual objects, revealing the societal and spatial interactions inherent in artistic practices involving found materials. This thesis also explores the visual and semantical interactions between art and the city, centring on a curated array of artworks which is not merely a visual representation or reflection of the city but also provides critical thoughts on and dialogues with the city, as well as (re)imaginations and aspirations of the urban landscape. The relationship between art and the city is further deepened through iii artistic practices, extending beyond the creation of artworks and involving art infrastructure building in Harare. This thesis conceptualises artists’ practices of working with found material as restless imagination, a term drawn from the name of the city, which refers to “no one sleeps” in the Shona language. The restlessness embedded in its naming has characterised the city in various dimensions and across time, with the haunting colonial legacy, ongoing urban crises, ubiquitous movements and the ordinary people’s unwavering efforts for liberation and survival. Artists residing in postcolonial Harare also adopt and cultivate restlessness as a working strategy not only to cope with but also to transgress such conditions. The evolution of found materials has been unfolded through a continuous process of restless imagination and innovative manoeuvres, which are embodied in the continual re-imagination of the convention of art materials, the expressive capacities of specific materials, and a commitment to labour throughout the transformative process. This open-ended though productive process of exploration perpetuates and extends to the re-imagination and reclaiming of urban spaces, transforming them into artistic spaces that foster artistic creation and the reproduction of artists and imaginations. This thesis argues the potential framing and comprehension of Harare city as the site of restless imagination pursued, embodied and materialised by artists through their artwork and engagement with urban spaces. Contemporary Zimbabwean artists have redefined their artistic practices, interacting with the materiality of everyday urban life, urban matters, urban spaces, and urban communities, and, concurrently, the relationship between art and city, art and society. By doing so, they open up space for possibilities to refashion the restless city, negotiate urban citizenship, and recreate themselves as agentive subjects in postcolonial Harare. It could be argued that artists, as urban citizens, akin to other residents grappling with everyday life in the city, also exercise their arts of citizenship through their creative innovations in artistic expression and practices. Therefore, this thesis not only delves into the contextualisation of artistic practices in Harare but also contributes to broader discussions on everyday practices in African cities through the lens of art. , Thesis (PhD) -- Faculty of Humanities, Fine Art, 2024
- Full Text:
Aza boron-pyridyl-isoindoline analogues
- Zhang, Hui, Wu, Yanping, Fan, Minhui, Xiao, Xuqiong, Mack, John, Kubheka, Gugu, Nyokong, Tebello, Lu, Hua
- Authors: Zhang, Hui , Wu, Yanping , Fan, Minhui , Xiao, Xuqiong , Mack, John , Kubheka, Gugu , Nyokong, Tebello , Lu, Hua
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232912 , vital:50037 , xlink:href="https://doi.org/10.1039/C7NJ00707H"
- Description: Several aza boron-pyridyl-isoindoline analogues are synthesized through a facile and scale-up two step reaction using 1,2-naphthalenedicarbonitrile as a starting material. These analogues show broad envelopes of intense vibrational bands in the absorption spectra with moderate fluorescence quantum yields in solution and the solid-state. An analysis of the structure–property relationships is described based on X-ray crystallography, optical spectroscopy, and theoretical calculations.
- Full Text:
- Authors: Zhang, Hui , Wu, Yanping , Fan, Minhui , Xiao, Xuqiong , Mack, John , Kubheka, Gugu , Nyokong, Tebello , Lu, Hua
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232912 , vital:50037 , xlink:href="https://doi.org/10.1039/C7NJ00707H"
- Description: Several aza boron-pyridyl-isoindoline analogues are synthesized through a facile and scale-up two step reaction using 1,2-naphthalenedicarbonitrile as a starting material. These analogues show broad envelopes of intense vibrational bands in the absorption spectra with moderate fluorescence quantum yields in solution and the solid-state. An analysis of the structure–property relationships is described based on X-ray crystallography, optical spectroscopy, and theoretical calculations.
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Cordidepsine is A Potential New Anti-HIV Depsidone from Cordia millenii
- Zeukang, Rostanie D, Siwe-Noundou, Xavier, Fotsing, Maurice T, Mbafor, Joseph T, Krause, Rui W M, Choudhary, Muhammad I, Atchade, Alex de Theodore
- Authors: Zeukang, Rostanie D , Siwe-Noundou, Xavier , Fotsing, Maurice T , Mbafor, Joseph T , Krause, Rui W M , Choudhary, Muhammad I , Atchade, Alex de Theodore
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193988 , vital:45413 , xlink:href="https://doi.org/10.3390/molecules24173202"
- Description: Chemical investigation of Cordia millenii, Baker resulted in the isolation of a new depsidone, cordidepsine (1), along with twelve known compounds including cyclooctasulfur (2), lup-20(29)-en-3-triacontanoate (3), 1-(26-hydroxyhexacosanoyl)glycerol (4), glyceryl-1-hexacosanoate (5) betulinic acid (6), lupenone (7), β-amyrone (8), lupeol (9), β-amyrin (10), allantoin (11), 2′-(4-hydroxyphenyl)ethylpropanoate (12) and stigmasterol glycoside (13). Hemi-synthetic reactions were carried out on two isolated compounds (5 and 6) to afford two new derivatives, that is, cordicerol A (14) and cordicerol B (15), respectively. The chemical structures of all the compounds were established based on analysis and interpretation of spectroscopic data such as electron ionization mass spectrometry (EI–MS), high resolution electrospray ionization mass spectrometry (HR-ESI–MS), fast atom bombardment mass spectrometry (FAB–MS), one dimension and two dimension nuclear magnetic resonance (1D and 2D-NMR) spectral data as well as X-ray crystallography (XRC). Lupeol ester derivatives [Lup-20(29)-en-3-triacontanoate (3)], monoglycerol derivatives [1-(26-hydroxyhexacosanoyl)glycerol (4) and glyceryl-1 hexacosanoate (5)] were isolated for the first time from Cordia genus while sulfur allotrope [cyclooctasulfur (2)] was isolated for the first time from plant origin. Biological assays cordidepsine (1) exhibited significant anti-HIV integrase activity with IC50 = 4.65 μM; EtOAc extract of stem barks, EtOAc fraction of roots and leaves were not toxic against 3T3 cells.
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- Authors: Zeukang, Rostanie D , Siwe-Noundou, Xavier , Fotsing, Maurice T , Mbafor, Joseph T , Krause, Rui W M , Choudhary, Muhammad I , Atchade, Alex de Theodore
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193988 , vital:45413 , xlink:href="https://doi.org/10.3390/molecules24173202"
- Description: Chemical investigation of Cordia millenii, Baker resulted in the isolation of a new depsidone, cordidepsine (1), along with twelve known compounds including cyclooctasulfur (2), lup-20(29)-en-3-triacontanoate (3), 1-(26-hydroxyhexacosanoyl)glycerol (4), glyceryl-1-hexacosanoate (5) betulinic acid (6), lupenone (7), β-amyrone (8), lupeol (9), β-amyrin (10), allantoin (11), 2′-(4-hydroxyphenyl)ethylpropanoate (12) and stigmasterol glycoside (13). Hemi-synthetic reactions were carried out on two isolated compounds (5 and 6) to afford two new derivatives, that is, cordicerol A (14) and cordicerol B (15), respectively. The chemical structures of all the compounds were established based on analysis and interpretation of spectroscopic data such as electron ionization mass spectrometry (EI–MS), high resolution electrospray ionization mass spectrometry (HR-ESI–MS), fast atom bombardment mass spectrometry (FAB–MS), one dimension and two dimension nuclear magnetic resonance (1D and 2D-NMR) spectral data as well as X-ray crystallography (XRC). Lupeol ester derivatives [Lup-20(29)-en-3-triacontanoate (3)], monoglycerol derivatives [1-(26-hydroxyhexacosanoyl)glycerol (4) and glyceryl-1 hexacosanoate (5)] were isolated for the first time from Cordia genus while sulfur allotrope [cyclooctasulfur (2)] was isolated for the first time from plant origin. Biological assays cordidepsine (1) exhibited significant anti-HIV integrase activity with IC50 = 4.65 μM; EtOAc extract of stem barks, EtOAc fraction of roots and leaves were not toxic against 3T3 cells.
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Aspects of the water use of Cannabis sativa L. under dryland cultivation in the Eastern Cape
- Authors: Zenani, Kamva Trevor Songo
- Date: 2024-10-11
- Subjects: Cannabis , Water consumption , Large aperture scintillometer , Cannabis Water requirements , Dry farming South Africa Eastern Cape , Evapotranspiration
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465035 , vital:76567
- Description: Cannabis spp is one of the oldest cultivated plants, with its origin in Asia. It has two species, namely C. indica and C. sativa. This research focuses on C. sativa, which is widely cultivated locally and globally. C. sativa has a wide range of uses, including industrial, medicinal, religious, and recreational. This study will be focusing on the water use of medicinal and recreational C. sativa grown under dryland conditions. In recent years, there has been a growing interest in increasing its cultivation, but there are reports of it having high water usage. The global interest has led many governments to review the laws governing this plant as it is a controlled substance in many countries. Due to its legal status, there is a dearth of knowledge about its growth and water use. It is against this backdrop that the Water Research Commission (WRC) commissioned this study into the water use of this plant. This will provide evidence-based support for the issuing of water use licenses by the Department of Water and Sanitation. The Eastern Cape and KwaZulu Natal have many small-scale legacy farmers who have been growing C. sativa illegally for decades. The findings of this research will seek to fill some of these knowledge gaps and assist legacy farmers in the cultivation of this plant. This research had four approaches, which include 1) planting the crop in a dryland location that will mimic the conditions experienced by legacy growers, 2) the collection of plant biophysical variables in the study site in order to gain a better understanding of the plant’s health, growth, progress, and to use these variables to parameterize a mechanistic eco-physiological model, 3) the installing of a large aperture scintillometer (LAS) together with a micro-meteorological station to measure the evapotranspiration (ET) and meteorological parameters over a crop cycle, 4) to use MEDRUSH evapotranspiration model to predict the ET and compare these results against that of the LAS. The results show that water provision had a significant impact on plant biophysical variables and water use. The plants received 154 mm (2 mm day-1) of rain during the crop cycle. The large aperture scintillometer recorded a total ET of 126.8 mm (1.76 mm day-1) during the same period. The MEDRUSH model (2.5 mm day-1) overestimated the LAS ET (1.79 mm day-1), and the results from the daily ET revealed that C. sativa had higher daily ET when compared to the local grass Eragrostis plana. These results confirm that at this location in the Eastern Cape, C. sativa requires regular irrigation during the growing season to grow and secure a crop. , Thesis (MSc) -- Faculty of Science, Institute for Water Research, 2024
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- Authors: Zenani, Kamva Trevor Songo
- Date: 2024-10-11
- Subjects: Cannabis , Water consumption , Large aperture scintillometer , Cannabis Water requirements , Dry farming South Africa Eastern Cape , Evapotranspiration
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465035 , vital:76567
- Description: Cannabis spp is one of the oldest cultivated plants, with its origin in Asia. It has two species, namely C. indica and C. sativa. This research focuses on C. sativa, which is widely cultivated locally and globally. C. sativa has a wide range of uses, including industrial, medicinal, religious, and recreational. This study will be focusing on the water use of medicinal and recreational C. sativa grown under dryland conditions. In recent years, there has been a growing interest in increasing its cultivation, but there are reports of it having high water usage. The global interest has led many governments to review the laws governing this plant as it is a controlled substance in many countries. Due to its legal status, there is a dearth of knowledge about its growth and water use. It is against this backdrop that the Water Research Commission (WRC) commissioned this study into the water use of this plant. This will provide evidence-based support for the issuing of water use licenses by the Department of Water and Sanitation. The Eastern Cape and KwaZulu Natal have many small-scale legacy farmers who have been growing C. sativa illegally for decades. The findings of this research will seek to fill some of these knowledge gaps and assist legacy farmers in the cultivation of this plant. This research had four approaches, which include 1) planting the crop in a dryland location that will mimic the conditions experienced by legacy growers, 2) the collection of plant biophysical variables in the study site in order to gain a better understanding of the plant’s health, growth, progress, and to use these variables to parameterize a mechanistic eco-physiological model, 3) the installing of a large aperture scintillometer (LAS) together with a micro-meteorological station to measure the evapotranspiration (ET) and meteorological parameters over a crop cycle, 4) to use MEDRUSH evapotranspiration model to predict the ET and compare these results against that of the LAS. The results show that water provision had a significant impact on plant biophysical variables and water use. The plants received 154 mm (2 mm day-1) of rain during the crop cycle. The large aperture scintillometer recorded a total ET of 126.8 mm (1.76 mm day-1) during the same period. The MEDRUSH model (2.5 mm day-1) overestimated the LAS ET (1.79 mm day-1), and the results from the daily ET revealed that C. sativa had higher daily ET when compared to the local grass Eragrostis plana. These results confirm that at this location in the Eastern Cape, C. sativa requires regular irrigation during the growing season to grow and secure a crop. , Thesis (MSc) -- Faculty of Science, Institute for Water Research, 2024
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Heritage–A conceptually evolving and dissonant phenomenon: Implications for heritage management and education practices in post-colonial Southern Africa
- Authors: Zazu, Clayton
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387208 , vital:68215 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122250"
- Description: This conceptual paper is based on experiences and insights which have emerged from my quest to develop a conceptual framework for working with the term ‘heritage’ within an education for sustainable development study that I am currently conducting. Of specific interest to me, and having potential to improve the relevance and quality of heritage education in southern Africa, given the region’s inherent cultural diversity and colonial history, is the need for ‘heritage construct inclusivity’ within the processes constituting heritage education practices. Working around this broad research goal, I therefore needed to be clear about what I mean or refer to as heritage. I realised, however, how elusive and conceptually problematic the term ‘heritage’ is. I therefore, drawing from literature and experiences gained during field observations and focus group interviews, came up with the idea of working with three viewpoints of heritage. Drawing on real life cases I argue that current heritage management and education practices’ failure to recognise and respect the evolving, interconnectedness and multi layered nature of heritage, partly explain the same practices’ lack of relevance and agency to enhance the sustainable management of local heritage resources. I also suggest a few ideas which heritage educators in the context of post-colonial southern Africa may need to consider in their everyday heritage education practices. I also introduce the notion of conceptualising heritage as ‘cultural landscapes’, within which the evolving, dissonant and interconnected nature of heritage, and associated heritage constructs, may be reconciled.
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- Authors: Zazu, Clayton
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387208 , vital:68215 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122250"
- Description: This conceptual paper is based on experiences and insights which have emerged from my quest to develop a conceptual framework for working with the term ‘heritage’ within an education for sustainable development study that I am currently conducting. Of specific interest to me, and having potential to improve the relevance and quality of heritage education in southern Africa, given the region’s inherent cultural diversity and colonial history, is the need for ‘heritage construct inclusivity’ within the processes constituting heritage education practices. Working around this broad research goal, I therefore needed to be clear about what I mean or refer to as heritage. I realised, however, how elusive and conceptually problematic the term ‘heritage’ is. I therefore, drawing from literature and experiences gained during field observations and focus group interviews, came up with the idea of working with three viewpoints of heritage. Drawing on real life cases I argue that current heritage management and education practices’ failure to recognise and respect the evolving, interconnectedness and multi layered nature of heritage, partly explain the same practices’ lack of relevance and agency to enhance the sustainable management of local heritage resources. I also suggest a few ideas which heritage educators in the context of post-colonial southern Africa may need to consider in their everyday heritage education practices. I also introduce the notion of conceptualising heritage as ‘cultural landscapes’, within which the evolving, dissonant and interconnected nature of heritage, and associated heritage constructs, may be reconciled.
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Analysis of saprolite-hosted Rutile-Graphite deposit: a case study of Malingunde saprolite-hosted Rutile-Graphite project in Central Malawi
- Authors: Zabula, Ansel Aliko
- Date: 2024-10-11
- Subjects: Rutile , Graphite , Saprolites , Geophysical surveys Malawi , Vanadium pentoxide , Geophysical surveys Economic aspects
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464970 , vital:76562
- Description: The Malingunde graphite project, owned by Sovereign Metals Ltd (SML), has revealed significant potential for rutile and high-grade graphite in saprolite. This study addresses the complexity of mineral assemblages in the Malingunde area, emphasizing the coexistence of graphite and rutile. SML's exploration activities, including extensive drilling and soil sampling, have uncovered variations in associated minerals, such as muscovite, kyanite, garnets, and ilmenite. Rutile, initially discovered incidentally, has prompted further investigation, impacting the financial model of the project. This research aims to analyse the Malingunde deposit, focusing on understanding its mineralogy, formation, and potential for elements like vanadium. Geological surveys reveal the distribution of graphite in the Precambrian to lower Palaeozoic age basement complex, hosted in saprolite resulting from tropical weathering of graphitic gneisses. Exploration techniques, including remote sensing, and geophysics, are crucial in targeting graphite and rutile deposits. Ground electromagnetic surveys, airborne electromagnetic data, and GIS applications aid in identifying and quantifying mineralised areas. Geochemical analysis and metallurgical tests further contribute to understanding the ore body and processing methods. Results indicate an inverse relationship between graphite and rutile concentrations, influencing the economic viability of different regions within the project area. Correlation matrices and regression analyses reveal distinct geological conditions influencing the association of vanadium and graphite in Lifidzi and Malingunde. The study concludes with exploration potential outside the Malingunde project, highlighting regional prospects and potential byproducts like vanadium pentoxide. The ongoing metallurgical tests and pilot plant design signify the project's evolution toward production. Additionally, neighbouring licenses show potential, emphasizing the need for comprehensive research to define and quantify resources in the region. This research provides valuable insights for the mining industry, informing strategies for exploration, resource assessment, and potential byproduct utilization in similar geological settings. , Thesis (MSc) -- Faculty of Science, Geology, 2024
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- Authors: Zabula, Ansel Aliko
- Date: 2024-10-11
- Subjects: Rutile , Graphite , Saprolites , Geophysical surveys Malawi , Vanadium pentoxide , Geophysical surveys Economic aspects
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464970 , vital:76562
- Description: The Malingunde graphite project, owned by Sovereign Metals Ltd (SML), has revealed significant potential for rutile and high-grade graphite in saprolite. This study addresses the complexity of mineral assemblages in the Malingunde area, emphasizing the coexistence of graphite and rutile. SML's exploration activities, including extensive drilling and soil sampling, have uncovered variations in associated minerals, such as muscovite, kyanite, garnets, and ilmenite. Rutile, initially discovered incidentally, has prompted further investigation, impacting the financial model of the project. This research aims to analyse the Malingunde deposit, focusing on understanding its mineralogy, formation, and potential for elements like vanadium. Geological surveys reveal the distribution of graphite in the Precambrian to lower Palaeozoic age basement complex, hosted in saprolite resulting from tropical weathering of graphitic gneisses. Exploration techniques, including remote sensing, and geophysics, are crucial in targeting graphite and rutile deposits. Ground electromagnetic surveys, airborne electromagnetic data, and GIS applications aid in identifying and quantifying mineralised areas. Geochemical analysis and metallurgical tests further contribute to understanding the ore body and processing methods. Results indicate an inverse relationship between graphite and rutile concentrations, influencing the economic viability of different regions within the project area. Correlation matrices and regression analyses reveal distinct geological conditions influencing the association of vanadium and graphite in Lifidzi and Malingunde. The study concludes with exploration potential outside the Malingunde project, highlighting regional prospects and potential byproducts like vanadium pentoxide. The ongoing metallurgical tests and pilot plant design signify the project's evolution toward production. Additionally, neighbouring licenses show potential, emphasizing the need for comprehensive research to define and quantify resources in the region. This research provides valuable insights for the mining industry, informing strategies for exploration, resource assessment, and potential byproduct utilization in similar geological settings. , Thesis (MSc) -- Faculty of Science, Geology, 2024
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