Nathaniel Merriman’s lecture: “Shakspeare, as Bearing on English History”
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
A preliminary survey of the estuaries on the south coast of South Africa, Robberg Peninsula - Cape St Francis, with particular reference to the fish fauna : ecological overview article
- James, Nicola Caroline, Harrison, T D
- Authors: James, Nicola Caroline , Harrison, T D
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:7144 , http://hdl.handle.net/10962/d1011842
- Description: A basic ichthyofaunal and physico-chemical survey of the coastal outlets on the south coast of South Africa (Robberg Peninsula to Cape St Francis) was undertaken during November 1994 and September 1995. Some 27 systems were identified along this stretch of coast and of these, 48% (Brak, Helpmekaars, Klip, Witels, Geelhoutbos, Kleinbos, Bruglaagte, Langbos, Sanddrif, Eerste, Boskloof, Kaapsedrif and Klipdrif [Wes]) comprised the inlets of coastal streams that offer little habitat for fishes, 26% (Sout, Bloukrans, Lottering, Elandsbos, Storms, Elands and Groot [Oos]) are located within deeply incised valleys within the Tsitsikamma region and provide limited littoral habitat for estuary-associated fishes; 26% of the systems (Piesang, Keurbooms, Matjies, Groot [Wes], Tsitsikamma, Klipdrif [Oos], Slang) appear to serve some estuarine function for both marine migrant and resident species although some of these may also be limited due to their small size and infrequent connection with the sea. This study serves to emphasize the ecological importance of these latter estuaries within this coastal sector.
- Full Text:
- Authors: James, Nicola Caroline , Harrison, T D
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:7144 , http://hdl.handle.net/10962/d1011842
- Description: A basic ichthyofaunal and physico-chemical survey of the coastal outlets on the south coast of South Africa (Robberg Peninsula to Cape St Francis) was undertaken during November 1994 and September 1995. Some 27 systems were identified along this stretch of coast and of these, 48% (Brak, Helpmekaars, Klip, Witels, Geelhoutbos, Kleinbos, Bruglaagte, Langbos, Sanddrif, Eerste, Boskloof, Kaapsedrif and Klipdrif [Wes]) comprised the inlets of coastal streams that offer little habitat for fishes, 26% (Sout, Bloukrans, Lottering, Elandsbos, Storms, Elands and Groot [Oos]) are located within deeply incised valleys within the Tsitsikamma region and provide limited littoral habitat for estuary-associated fishes; 26% of the systems (Piesang, Keurbooms, Matjies, Groot [Wes], Tsitsikamma, Klipdrif [Oos], Slang) appear to serve some estuarine function for both marine migrant and resident species although some of these may also be limited due to their small size and infrequent connection with the sea. This study serves to emphasize the ecological importance of these latter estuaries within this coastal sector.
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The synthesis, cyclic voltammetry and spectroelectrochemical studies of Co (II) phthalocyanines tetra-substituted at the α and β positions with phenylthio groups
- Nombona, Nolwazi, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264529 , vital:53742 , xlink:href="https://doi.org/10.1016/j.dyepig.2008.06.002"
- Description: Non-peripherally substituted cobalt 1,(4)-(tetraphenylthiophthalocyaninato) and peripherally substituted cobalt 2,(3)-(tetraphenylthiophthalocyaninato) complexes were synthesized. Redox processes were observed at E1/2 = −1.44 V (I), −0.39 V (II), +0.37 V (III), +0.78 V (IV) and 1.15 V (V) for the non-peripherally substituted and at E1/2 = −1.42 V (I), −0.57, −0.39 V (II), +0.27 V (III), +0.79 V (IV) and +1.10 V (V) for the peripherally substituted complexes, respectively. The couples were assigned to CoIPc−2/CoIPc−3 (I), CoIIPc−2/CoIPc−2 (II), CoIIIPc−2/CoIIPc−2 (III), and CoIIIPc−1/CoIIIPc−2 (IV) using spectroelectrochemistry. The last process (V) could not be ascertained by spectroelectrochemistry but is associated with ring oxidation. Upon reduction or oxidation, the Q band of the non-peripherally substituted complex became less red shifted compared to that of its peripherally substituted counterpart.
- Full Text:
- Authors: Nombona, Nolwazi , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264529 , vital:53742 , xlink:href="https://doi.org/10.1016/j.dyepig.2008.06.002"
- Description: Non-peripherally substituted cobalt 1,(4)-(tetraphenylthiophthalocyaninato) and peripherally substituted cobalt 2,(3)-(tetraphenylthiophthalocyaninato) complexes were synthesized. Redox processes were observed at E1/2 = −1.44 V (I), −0.39 V (II), +0.37 V (III), +0.78 V (IV) and 1.15 V (V) for the non-peripherally substituted and at E1/2 = −1.42 V (I), −0.57, −0.39 V (II), +0.27 V (III), +0.79 V (IV) and +1.10 V (V) for the peripherally substituted complexes, respectively. The couples were assigned to CoIPc−2/CoIPc−3 (I), CoIIPc−2/CoIPc−2 (II), CoIIIPc−2/CoIIPc−2 (III), and CoIIIPc−1/CoIIIPc−2 (IV) using spectroelectrochemistry. The last process (V) could not be ascertained by spectroelectrochemistry but is associated with ring oxidation. Upon reduction or oxidation, the Q band of the non-peripherally substituted complex became less red shifted compared to that of its peripherally substituted counterpart.
- Full Text:
White Guys Can't Beg
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229796 , vital:49711 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229796 , vital:49711 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
What's wrong with Walden Two?
- Authors: Tabensky, Pedro
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/305791 , vital:58612 , xlink:href="https://hdl.handle.net/10520/EJC96066"
- Description: Despite being eminently forgettable from the literary point of view, B. F. Skinner's novel, Walden Two, provides us with an excellent opportunity, not so much to show what is wrong with mainstream accounts of free will, as Robert Kane thinks, but rather to explore another key and importantly neglected condition for genuine agency; namely, that properly lived human lives are those that are and must continue to be vulnerable to unforseable reversals, as Aldous Huxley speculates in his Brave New World. In short, I argue, perhaps scandalously, that one of the central conditions for genuine agency is that our lives are and must continue to be, to a large extent, out of our personal control. The promise of too much personal control, not too little (as Kane thinks), is what is wrong with Skinner's social utopia.
- Full Text:
- Authors: Tabensky, Pedro
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/305791 , vital:58612 , xlink:href="https://hdl.handle.net/10520/EJC96066"
- Description: Despite being eminently forgettable from the literary point of view, B. F. Skinner's novel, Walden Two, provides us with an excellent opportunity, not so much to show what is wrong with mainstream accounts of free will, as Robert Kane thinks, but rather to explore another key and importantly neglected condition for genuine agency; namely, that properly lived human lives are those that are and must continue to be vulnerable to unforseable reversals, as Aldous Huxley speculates in his Brave New World. In short, I argue, perhaps scandalously, that one of the central conditions for genuine agency is that our lives are and must continue to be, to a large extent, out of our personal control. The promise of too much personal control, not too little (as Kane thinks), is what is wrong with Skinner's social utopia.
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Site of struggle: the Freedom Park fracas and the divisive legacy of South Africa’s Border War/Liberation Struggle
- Authors: Baines, Gary F
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126954 , vital:35938 , https://doi.10.1080/02533950903076428
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
- Full Text:
- Authors: Baines, Gary F
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126954 , vital:35938 , https://doi.10.1080/02533950903076428
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
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Fanon’s Curse: re-imagining Marxism in South Africa’s age of retreat
- Helliker, Kirk D, Vale, Peter C J
- Authors: Helliker, Kirk D , Vale, Peter C J
- Date: 2009
- Language: English
- Type: conference paper , text
- Identifier: http://hdl.handle.net/10962/61029 , vital:27924 , http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.587.740&rep=rep1&type=pdf
- Description: Given its growing, even dark, reputation for xenophobia, it seems extraordinary that South Africa remains open to ideas from the outside. Fifteen years after apartheid in South Africa ended, the country’s great cities are branded with the same imported images that clutter glittering malls in New York, London or Sydney. The rapidity of this makeover from apartheid’s grey conformity is held to be testimony to the success of neo-liberal globalisation which was enthusiastically embraced with apartheid’s ending.
- Full Text:
- Authors: Helliker, Kirk D , Vale, Peter C J
- Date: 2009
- Language: English
- Type: conference paper , text
- Identifier: http://hdl.handle.net/10962/61029 , vital:27924 , http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.587.740&rep=rep1&type=pdf
- Description: Given its growing, even dark, reputation for xenophobia, it seems extraordinary that South Africa remains open to ideas from the outside. Fifteen years after apartheid in South Africa ended, the country’s great cities are branded with the same imported images that clutter glittering malls in New York, London or Sydney. The rapidity of this makeover from apartheid’s grey conformity is held to be testimony to the success of neo-liberal globalisation which was enthusiastically embraced with apartheid’s ending.
- Full Text:
Rhodes University Library Annual Report 2009: Library Director’s Review
- Authors: Thomas, G M E
- Date: 2009
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/59941 , vital:27713
- Description: [From the Introduction] As you read through this annual overview of the work carried out by the staff of the Rhodes University Library Services Division, I am sure you will be impressed by their achievements during a year marked by major building construction and a demanding institutional review of our services and staffing structures.
- Full Text:
- Authors: Thomas, G M E
- Date: 2009
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/59941 , vital:27713
- Description: [From the Introduction] As you read through this annual overview of the work carried out by the staff of the Rhodes University Library Services Division, I am sure you will be impressed by their achievements during a year marked by major building construction and a demanding institutional review of our services and staffing structures.
- Full Text:
Film Review: Hollywood on Safari
- Authors: Amner, Roderick J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142680 , vital:38101 , https://doi.org/10.1386/jams.1.2.335_4
- Description: Film Review: Hollywood on Safari.
- Full Text:
- Authors: Amner, Roderick J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142680 , vital:38101 , https://doi.org/10.1386/jams.1.2.335_4
- Description: Film Review: Hollywood on Safari.
- Full Text:
The synthesis and photophysicochemical behaviour of novel water-soluble cationic indium (III) phthalocyanine
- Durmus, Mahmut, Erdoğmuş, Ali, Ogunsipe, Abimbola, Nyokong, Tebello
- Authors: Durmus, Mahmut , Erdoğmuş, Ali , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263419 , vital:53626 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.01.008"
- Description: The syntheses and characterization of 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) and quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) are described. The ground state electronic absorption spectra, photophysics and photochemistry of both dyes in DMSO as well as that of the quaternized compound in aqueous solution are also presented. A comparison of the photophysical and photochemical parameters of the two dyes revealed that quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) was a better photosensitizer than its unquaternized counterpart. The quantum yield values of fluorescence (ΦF), triplet state formation (ΦT) and singlet oxygen formation (ΦΔ) for the cationic dye were found to be 0.03, 0.68 and 0.66 respectively in DMSO; these values were higher than those for 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III), which exhibited values of 0.02, 0.66 and 0.63, respectively in DMSO. The values for the cationic dye in aq. solution were 0.02, 0.59 and 0.56 respectively, suggesting that the water-soluble quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) offers potential as a photosensitizer in photodynamic therapy treatment.
- Full Text:
- Authors: Durmus, Mahmut , Erdoğmuş, Ali , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263419 , vital:53626 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.01.008"
- Description: The syntheses and characterization of 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) and quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) are described. The ground state electronic absorption spectra, photophysics and photochemistry of both dyes in DMSO as well as that of the quaternized compound in aqueous solution are also presented. A comparison of the photophysical and photochemical parameters of the two dyes revealed that quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) was a better photosensitizer than its unquaternized counterpart. The quantum yield values of fluorescence (ΦF), triplet state formation (ΦT) and singlet oxygen formation (ΦΔ) for the cationic dye were found to be 0.03, 0.68 and 0.66 respectively in DMSO; these values were higher than those for 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III), which exhibited values of 0.02, 0.66 and 0.63, respectively in DMSO. The values for the cationic dye in aq. solution were 0.02, 0.59 and 0.56 respectively, suggesting that the water-soluble quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) offers potential as a photosensitizer in photodynamic therapy treatment.
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Steps by steps: the making of the Steps for the Future documentary series, likka Vehkalathi and Don Edkins: book review
- Authors: Schoon, Alette
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159348 , vital:40290 , https://hdl.handle.net/10520/EJC139902
- Description: In a frank, offbeat memoir, Finnish filmmaker Iikka Vehkalahti and his South African partner Don Edkins, tell their story of how they developed an infectious concept, charmed big broadcasters - and nearly didn't get the films made. Alette Schoon gets taken along for the ride.
- Full Text:
- Authors: Schoon, Alette
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159348 , vital:40290 , https://hdl.handle.net/10520/EJC139902
- Description: In a frank, offbeat memoir, Finnish filmmaker Iikka Vehkalahti and his South African partner Don Edkins, tell their story of how they developed an infectious concept, charmed big broadcasters - and nearly didn't get the films made. Alette Schoon gets taken along for the ride.
- Full Text:
'Here's to you, Mrs Robinson' : peculiarities and paragraph 29 in determining the treatment of domestic partnerships
- Authors: Kruuse, Helen
- Date: 2009
- Language: English
- Type: Article , text
- Identifier: vital:26388 , http://hdl.handle.net/10962/54083
- Description: There is always need of persons not only to discover new truths, and point out when what were once truths are true no longer, but also to commence new practices, and set the example of more enlightened conduct. The law is one of the important architects of social norms. At times, it can be a tool to solve problems, eradicate inequalities, and advance the rights of the disadvantaged. At other times, the law is an anchor and a constraint upon social and ideological advances. With regards to equality and non-traditional partnerships, it seems that law falls into this latter category.
- Full Text:
- Authors: Kruuse, Helen
- Date: 2009
- Language: English
- Type: Article , text
- Identifier: vital:26388 , http://hdl.handle.net/10962/54083
- Description: There is always need of persons not only to discover new truths, and point out when what were once truths are true no longer, but also to commence new practices, and set the example of more enlightened conduct. The law is one of the important architects of social norms. At times, it can be a tool to solve problems, eradicate inequalities, and advance the rights of the disadvantaged. At other times, the law is an anchor and a constraint upon social and ideological advances. With regards to equality and non-traditional partnerships, it seems that law falls into this latter category.
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The syntheses, characterization and fluorescence spectra of novel, octakis (alkylthiophthalocyanato) nickel (II) and palladium (II) complexes
- Ogunbayo, Taofeek Babatunde, Ogunsipe, Abimbola, Nyokong, Tebello
- Authors: Ogunbayo, Taofeek Babatunde , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263386 , vital:53623 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.03.009"
- Description: The syntheses, characterization and fluorescence studies of several {octakis(alkylthio)phthalocyanato} palladium(II) and nickel(II) complexes are presented. The absorption spectra of some of the complexes showed extra peaks which are attributable to non-planar distortion, the extent of which, was found to dependent on alkyl chain length. The fluorescence excitation spectra of the nickel(II) derivatives were not in agreement with their absorption spectra, owing to structural changes upon excitation. Fluorescence quantum yields were very low (more than 1%) for all complexes as a consequence of the open-shell electronic structures of nickel(II) and palladium(II).
- Full Text:
- Authors: Ogunbayo, Taofeek Babatunde , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263386 , vital:53623 , xlink:href="https://doi.org/10.1016/j.dyepig.2009.03.009"
- Description: The syntheses, characterization and fluorescence studies of several {octakis(alkylthio)phthalocyanato} palladium(II) and nickel(II) complexes are presented. The absorption spectra of some of the complexes showed extra peaks which are attributable to non-planar distortion, the extent of which, was found to dependent on alkyl chain length. The fluorescence excitation spectra of the nickel(II) derivatives were not in agreement with their absorption spectra, owing to structural changes upon excitation. Fluorescence quantum yields were very low (more than 1%) for all complexes as a consequence of the open-shell electronic structures of nickel(II) and palladium(II).
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Synthesis, photophysical and photochemical properties of octa-substituted antimony phthalocyanines
- Modibane, Desmond Kwena, Nyokong, Tebello
- Authors: Modibane, Desmond Kwena , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264226 , vital:53711 , xlink:href="https://doi.org/10.1016/j.poly.2008.11.052"
- Description: This work reports on the synthesis and photophysicochemical parameters of unsubstituted [SbIIIPc]+I3- and octa-phenoxy ([SbIIIOPPc]+I3-) and -4-t-butylphenoxy ([SbIIIOTBPPc]+I3-) substituted antimony phthalocyanines. Photophysical and photochemical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide and toluene. The excitation spectra of oxidized antimony (Sb(V)Pc) derivates were similar to absorption spectra. Low fluorescence quantum yields, high triplet quantum yields and low triplet lifetimes were observed as the result of heavy atom (antimony ion).
- Full Text:
- Authors: Modibane, Desmond Kwena , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264226 , vital:53711 , xlink:href="https://doi.org/10.1016/j.poly.2008.11.052"
- Description: This work reports on the synthesis and photophysicochemical parameters of unsubstituted [SbIIIPc]+I3- and octa-phenoxy ([SbIIIOPPc]+I3-) and -4-t-butylphenoxy ([SbIIIOTBPPc]+I3-) substituted antimony phthalocyanines. Photophysical and photochemical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide and toluene. The excitation spectra of oxidized antimony (Sb(V)Pc) derivates were similar to absorption spectra. Low fluorescence quantum yields, high triplet quantum yields and low triplet lifetimes were observed as the result of heavy atom (antimony ion).
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The both-and edition:
- Authors: Garman, Anthea
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158817 , vital:40231 , https://hdl.handle.net/10520/EJC139955
- Description: I was driving down the N2 from Cape Town towards the airport recently and scanning the turn-offs for Vanguard Drive, when suddenly I noticed among the shacks that line the road some really interesting buildings. These were not the pale pink matchboxes that periodically spring up in rows alongside the derelict housing that millions of South Africans call home. They were multi-levelled, had large windows and looked like an architect might have had something to do with them. I was heartened at the sight of housing – at last – with humanity in mind. But as I reread the 2010 pieces in this edition, I’m reminded by Jane Duncan in particular (“Whose World Cup?” page 23) that prettifying the ghastly spaces in our world cup cities that will be visible to those international tourists is high on the agenda for our government. But then, I reason, at least someone will benefit from living along the noisy and congested airport route!.
- Full Text:
- Authors: Garman, Anthea
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158817 , vital:40231 , https://hdl.handle.net/10520/EJC139955
- Description: I was driving down the N2 from Cape Town towards the airport recently and scanning the turn-offs for Vanguard Drive, when suddenly I noticed among the shacks that line the road some really interesting buildings. These were not the pale pink matchboxes that periodically spring up in rows alongside the derelict housing that millions of South Africans call home. They were multi-levelled, had large windows and looked like an architect might have had something to do with them. I was heartened at the sight of housing – at last – with humanity in mind. But as I reread the 2010 pieces in this edition, I’m reminded by Jane Duncan in particular (“Whose World Cup?” page 23) that prettifying the ghastly spaces in our world cup cities that will be visible to those international tourists is high on the agenda for our government. But then, I reason, at least someone will benefit from living along the noisy and congested airport route!.
- Full Text:
Solvent and central metal effects on the photophysical and photochemical properties of peripherally tetra mercaptopyridine substituted metallophthalocyanines
- Moeno, Sharon, Nyokong, Tebello
- Authors: Moeno, Sharon , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263522 , vital:53635 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.01.021"
- Description: The synthesis of peripherally tetra 2-mercaptopyridine substituted phthalocyanines containing Si, Ga, Sn and In as central metal ions is reported for the first time in this study. Photophysical and photochemical studies were carried out on these compounds in order to determine the potential of the complexes as photosensitizers for use in photodynamic therapy. Fluorescence quantum yields (ΦF) ranged from 0.012 to 0.2 and triplet quantum yields (ΦT) from 0.54 to 0.89 in dimethylformamide (DMF) and from 0.65 to 0.93 in dimethylsulfoxide (DMSO). The triplet lifetimes ranged from 20 to 130 μs, the low values are due to the heavy atom effects of the central metal. The triplet lifetimes were larger in DMSO when compared with DMF.
- Full Text:
- Authors: Moeno, Sharon , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263522 , vital:53635 , xlink:href="https://doi.org/10.1016/j.jphotochem.2009.01.021"
- Description: The synthesis of peripherally tetra 2-mercaptopyridine substituted phthalocyanines containing Si, Ga, Sn and In as central metal ions is reported for the first time in this study. Photophysical and photochemical studies were carried out on these compounds in order to determine the potential of the complexes as photosensitizers for use in photodynamic therapy. Fluorescence quantum yields (ΦF) ranged from 0.012 to 0.2 and triplet quantum yields (ΦT) from 0.54 to 0.89 in dimethylformamide (DMF) and from 0.65 to 0.93 in dimethylsulfoxide (DMSO). The triplet lifetimes ranged from 20 to 130 μs, the low values are due to the heavy atom effects of the central metal. The triplet lifetimes were larger in DMSO when compared with DMF.
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Professor Emeritus Denis William Ewer MBE FRSSAf 1913 - 2009: biographical memoir
- Authors: Hodgson, Alan N
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:6884 , http://hdl.handle.net/10962/d1011643
- Description: Denis Ewer went to University College School in London. In 1931 he entered Trinity College, Cambridge (his father had studied mathematics at Trinity) where he read for the Natural Science Tripos, obtaining a B.A. in 1934. In his second year at Cambridge he gained the nickname of 'Jakes' via a literary route (his father's nickname also had literary origins). The word 'ewer' can mean a jug, chamber pot, or jerry, and hence the progress to 'jakes', Elizabethan English for an outside lavatory. It was at Cambridge that he also met the future communist spy, Kim Philby. After graduating, Jakes Ewer moved to the University of Birmingham where he undertook his doctoral studies (graduating PhD in 1940) under H. Munro Fox. World War II, however, temporarily halted any further academic career, and during the war years he was an Experimental Officer for the Army Operational Research Group (Ministry of Supply) achieving the rank of Major. For his work, which included being a Scientific Advisor to the Chief, Air Defence Division, Supreme Headquarters Allied Expeditionary Force, he was awarded the M.B.E. (Member of the British Empire).
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- Authors: Hodgson, Alan N
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:6884 , http://hdl.handle.net/10962/d1011643
- Description: Denis Ewer went to University College School in London. In 1931 he entered Trinity College, Cambridge (his father had studied mathematics at Trinity) where he read for the Natural Science Tripos, obtaining a B.A. in 1934. In his second year at Cambridge he gained the nickname of 'Jakes' via a literary route (his father's nickname also had literary origins). The word 'ewer' can mean a jug, chamber pot, or jerry, and hence the progress to 'jakes', Elizabethan English for an outside lavatory. It was at Cambridge that he also met the future communist spy, Kim Philby. After graduating, Jakes Ewer moved to the University of Birmingham where he undertook his doctoral studies (graduating PhD in 1940) under H. Munro Fox. World War II, however, temporarily halted any further academic career, and during the war years he was an Experimental Officer for the Army Operational Research Group (Ministry of Supply) achieving the rank of Major. For his work, which included being a Scientific Advisor to the Chief, Air Defence Division, Supreme Headquarters Allied Expeditionary Force, he was awarded the M.B.E. (Member of the British Empire).
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Exploring job search and the causes of endogenous unemployment: evidence from Duncan Village, South Africa
- Authors: Duff, Patrick Alexander
- Date: 2009
- Subjects: Unemployment , Unemployment -- Social aspects -- South Africa -- East London -- Duncan Village , Job hunting -- South Africa -- East London -- Duncan Village , Labor market -- South Africa
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: vital:1026
- Description: Despite high rates of unemployment in South Africa, there is little consensus about its origins and solutions to the problem. Job search (how and when people search for work)is one aspect of the unemployment problem. Job search is shown to be a complex process strongly linked to the endogenous structure of the labour market. The flaws in traditional methods (theoretical and measurement) highlight this. Using data from a tailor-made survey in Duncan Village (a peri-urban area in Buffalo City, South Africa) the research examines factors that influence the effectiveness of job search. The results show that mode of search (how people look for work) is used as a signal by employers. Degrees of success are stratified amongst searchers using either ‘word of mouth’, place-to-place or formal modes of search. The thesis provides a method-test to reveal a complex body of evidence that has yet to be fully explored by practitioners in this field.
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- Authors: Duff, Patrick Alexander
- Date: 2009
- Subjects: Unemployment , Unemployment -- Social aspects -- South Africa -- East London -- Duncan Village , Job hunting -- South Africa -- East London -- Duncan Village , Labor market -- South Africa
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: vital:1026
- Description: Despite high rates of unemployment in South Africa, there is little consensus about its origins and solutions to the problem. Job search (how and when people search for work)is one aspect of the unemployment problem. Job search is shown to be a complex process strongly linked to the endogenous structure of the labour market. The flaws in traditional methods (theoretical and measurement) highlight this. Using data from a tailor-made survey in Duncan Village (a peri-urban area in Buffalo City, South Africa) the research examines factors that influence the effectiveness of job search. The results show that mode of search (how people look for work) is used as a signal by employers. Degrees of success are stratified amongst searchers using either ‘word of mouth’, place-to-place or formal modes of search. The thesis provides a method-test to reveal a complex body of evidence that has yet to be fully explored by practitioners in this field.
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NGOs and rural movements in contemporary South Africa
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
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- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
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A far from passive record Anton van Wouw: The smaller works, AE Duffey: book review
- Authors: de Jager, Maureen
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147402 , vital:38633 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC38334
- Description: Anton van Wouw : the smaller works is, as its title implies, concerned with the generally lesser-known smaller works of Dutch-born sculptor, Anton van Wouw. Using the measure of "half life-size and smaller" as a guideline, author Alexander Duffey provides a comprehensive and well-illustrated overview of the many full-length small sculptures, busts, relief panels and maquettes produced by Van Wouw between 1881 (nine years prior to his arrival in South Africa at the age of 28) and 1940. Naturalistically sculpted and generally cast in bronze, these smaller works are wide-ranging in their subject matter, depicting innocuous, commonplace scenes alongside aspects of Afrikaner history, representations of Boer and British leaders, and so-called "native studies" (p 11).
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- Authors: de Jager, Maureen
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147402 , vital:38633 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC38334
- Description: Anton van Wouw : the smaller works is, as its title implies, concerned with the generally lesser-known smaller works of Dutch-born sculptor, Anton van Wouw. Using the measure of "half life-size and smaller" as a guideline, author Alexander Duffey provides a comprehensive and well-illustrated overview of the many full-length small sculptures, busts, relief panels and maquettes produced by Van Wouw between 1881 (nine years prior to his arrival in South Africa at the age of 28) and 1940. Naturalistically sculpted and generally cast in bronze, these smaller works are wide-ranging in their subject matter, depicting innocuous, commonplace scenes alongside aspects of Afrikaner history, representations of Boer and British leaders, and so-called "native studies" (p 11).
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