Toughened wood plastic composites for low technology and advanced manufacturing applications
- Authors: Mabutho, Briswell
- Date: 2024-12
- Subjects: Plastic-impregnated wood , Polymeric composites
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69360 , vital:77225
- Description: The utilization of wood plastic composites (WPCs) has increasingly emerged as an appealing alternative for products where traditional wood and conventional composites would typically be used. This is primarily due to their cost-effectiveness, mouldability, recyclability, renewability, and potential biodegradability. However, the incorporation of wood flour (WF) in thermoplastics to produce WPCs presents several challenges, two of which are addressed in the current study: the WF-thermoplastic matrix adhesion, and the resulting brittleness of the WPC. The hydrophilic nature of WF filler and the hydrophobic polypropylene matrix, which typically lead to poor mixing due to their differing surface energies. Consequently, the current research focuses on enhancing WF-matrix (i.e. polypropylene, PP) adhesion and dispersion through compatibilization using maleic anhydride grafted polypropylene (MAPP). Additionally, the brittleness of WPC, exacerbated by the WF content, is addressed through the incorporation of crumb rubber (CR), a process commonly referred to as "toughening" the WPC. Prior to the use of CR in WPCs, optimization of the CR amount and compatibility within the PP-matrix were conducted to establish a toughening system that would achieve the highest impact strength without significantly affecting the tensile strength. The CR was compatibilized by employing dynamic vulcanization of varying amounts of ethylene propylene diene monomer rubber (EPDM) in the CR/PP blends using both sulphur and dicumyl peroxide cure systems. The results indicated that the sulphur dynamic cure system exhibited higher crosslinking efficiency, as reflected by the highest impact strength. Furthermore, to enhance WPC processability and adhesion, WF alkalization was conducted following a central composite design to optimize treatment temperature, time, and alkali concentration. This optimization resulted in improved WPC processability and mechanical properties at mild alkalization conditions. Subsequently, the optimum CR/EPDM dynamic cure system was employed to toughen both untreated and alkalized WPCs, resulting in toughened WPCs with improved thermal stability, impact strength, and elongation at break, while the tensile strength was only slightly compromised. , Thesis (PhD) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Mabutho, Briswell
- Date: 2024-12
- Subjects: Plastic-impregnated wood , Polymeric composites
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69360 , vital:77225
- Description: The utilization of wood plastic composites (WPCs) has increasingly emerged as an appealing alternative for products where traditional wood and conventional composites would typically be used. This is primarily due to their cost-effectiveness, mouldability, recyclability, renewability, and potential biodegradability. However, the incorporation of wood flour (WF) in thermoplastics to produce WPCs presents several challenges, two of which are addressed in the current study: the WF-thermoplastic matrix adhesion, and the resulting brittleness of the WPC. The hydrophilic nature of WF filler and the hydrophobic polypropylene matrix, which typically lead to poor mixing due to their differing surface energies. Consequently, the current research focuses on enhancing WF-matrix (i.e. polypropylene, PP) adhesion and dispersion through compatibilization using maleic anhydride grafted polypropylene (MAPP). Additionally, the brittleness of WPC, exacerbated by the WF content, is addressed through the incorporation of crumb rubber (CR), a process commonly referred to as "toughening" the WPC. Prior to the use of CR in WPCs, optimization of the CR amount and compatibility within the PP-matrix were conducted to establish a toughening system that would achieve the highest impact strength without significantly affecting the tensile strength. The CR was compatibilized by employing dynamic vulcanization of varying amounts of ethylene propylene diene monomer rubber (EPDM) in the CR/PP blends using both sulphur and dicumyl peroxide cure systems. The results indicated that the sulphur dynamic cure system exhibited higher crosslinking efficiency, as reflected by the highest impact strength. Furthermore, to enhance WPC processability and adhesion, WF alkalization was conducted following a central composite design to optimize treatment temperature, time, and alkali concentration. This optimization resulted in improved WPC processability and mechanical properties at mild alkalization conditions. Subsequently, the optimum CR/EPDM dynamic cure system was employed to toughen both untreated and alkalized WPCs, resulting in toughened WPCs with improved thermal stability, impact strength, and elongation at break, while the tensile strength was only slightly compromised. , Thesis (PhD) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
Supramolecular chemistry considerations of fluorenyl-derived host compounds
- Authors: McFarlane, Duncan William
- Date: 2024-12
- Subjects: Supramolecular chemistry , Organic compounds , Chemistry, Organic
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69371 , vital:77227
- Description: This work examined various supramolecular aspects of 9-fluorenone-derived host compounds, namely 4,4’-(9-fluorenylidene)diphenol (H1), 9,9-(1,4-phenylene)bis(fluoren-9-ol) (H2), 9,9- (ethyne-1,2-diyl)bis(fluoren-9-ol) (H3) and 9,9-(biphenyl-4,4-diyl)bis(fluoren-9-ol) (H4). These compounds were successfully synthesized and then screened for their host ability for, and host behaviour in, various organic compounds. At the outset, molecular modelling calculations were carried out on each of the four host compounds. Various structural parameters and the geometries of the low energy conformers that were calculated were then compared with these aspects of the guest-free host molecules obtained from single crystal X-ray diffraction (SCXRD) analysis. The host behaviour of H1 was, furthermore, assessed in the presence of four alkylnitriles, namely acetonitrile (ACE), acrylonitrile (ACRY), propionitrile (PROP) and butyronitrile (BUT). All four guests complexed with H1 with 1:1 host:guest (H:G) ratios. From SCXRD analyses, each of the complexes crystallized in the monoclinic crystal system and the centrosymmetric space group P21/n, and the host packing was isostructural in each instance. The complexes were stabilized by a plethora of short inter- and intramolecular contacts. The thermal stabilities of the four complexes were also examined together with Hirshfeld surface considerations. Finally, lattice energy calculations were carried out and the results of these compared with the relative thermal stabilities of the four complexes. The compounds H2 and H3 were examined for their selectivity behaviour in mixtures of aniline, N-methylaniline and N,N’-dimethylaniline (ANI, NMA and DMA). Both host compounds were able to form complexes with ANI and DMA with various H:G ratios, while only H3 possessed enclathration ability for NMA (H:G 1:1). SCXRD analyses showed that all of the complexes were stabilized by means of classical (host)O‒H···N(guest) hydrogen bonds in addition to other short contacts. Equimolar binary guest competition experiments with H2 revealed an extremely high host selectivity for DMA (ANI/DMA and DMA/NMA experiments furnished crystals with > 91% DMA), while the experiment with all three anilines present also resulted in a complex with an , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: McFarlane, Duncan William
- Date: 2024-12
- Subjects: Supramolecular chemistry , Organic compounds , Chemistry, Organic
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69371 , vital:77227
- Description: This work examined various supramolecular aspects of 9-fluorenone-derived host compounds, namely 4,4’-(9-fluorenylidene)diphenol (H1), 9,9-(1,4-phenylene)bis(fluoren-9-ol) (H2), 9,9- (ethyne-1,2-diyl)bis(fluoren-9-ol) (H3) and 9,9-(biphenyl-4,4-diyl)bis(fluoren-9-ol) (H4). These compounds were successfully synthesized and then screened for their host ability for, and host behaviour in, various organic compounds. At the outset, molecular modelling calculations were carried out on each of the four host compounds. Various structural parameters and the geometries of the low energy conformers that were calculated were then compared with these aspects of the guest-free host molecules obtained from single crystal X-ray diffraction (SCXRD) analysis. The host behaviour of H1 was, furthermore, assessed in the presence of four alkylnitriles, namely acetonitrile (ACE), acrylonitrile (ACRY), propionitrile (PROP) and butyronitrile (BUT). All four guests complexed with H1 with 1:1 host:guest (H:G) ratios. From SCXRD analyses, each of the complexes crystallized in the monoclinic crystal system and the centrosymmetric space group P21/n, and the host packing was isostructural in each instance. The complexes were stabilized by a plethora of short inter- and intramolecular contacts. The thermal stabilities of the four complexes were also examined together with Hirshfeld surface considerations. Finally, lattice energy calculations were carried out and the results of these compared with the relative thermal stabilities of the four complexes. The compounds H2 and H3 were examined for their selectivity behaviour in mixtures of aniline, N-methylaniline and N,N’-dimethylaniline (ANI, NMA and DMA). Both host compounds were able to form complexes with ANI and DMA with various H:G ratios, while only H3 possessed enclathration ability for NMA (H:G 1:1). SCXRD analyses showed that all of the complexes were stabilized by means of classical (host)O‒H···N(guest) hydrogen bonds in addition to other short contacts. Equimolar binary guest competition experiments with H2 revealed an extremely high host selectivity for DMA (ANI/DMA and DMA/NMA experiments furnished crystals with > 91% DMA), while the experiment with all three anilines present also resulted in a complex with an , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
Associations between patterns of wild ungulate patch use, soil carbon and albedo in montane grasslands
- Authors: Mc Gregor, Steven
- Date: 2024-12
- Subjects: Grassland ecology , Global environmental change , Climatic changes
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69382 , vital:77250
- Description: Grassy ecosystems are essential for human survival, providing key services including food production, water provisioning and moderating climate. Yet, grassy ecosystems remain undervalued due to misconceptions that they are remnants of degraded states of forest – a view that continues to influence climate change policies. This thesis explores the links between wild, free-roaming ungulate grazers and climate drivers, including carbon storage and surface albedo (i.e., reflectance of solar radiation), through their impacts on vegetation and soils. Using black wildebeest (Connochaetes gnou) as a model wild species, I compared their grazing patterns in an Afromontane grassland in the eastern Karoo, South Africa, to those of short-duration cattle grazing systems in similar nearby grasslands (Chapter 2). While short-duration grazing aims to mimic spatiotemporal wild ungulate grazing patterns to supposedly enhance ecosystem functioning and soil carbon stocks, I found that wildebeest had ~50% shorter grazing durations and much shorter rest intervals (1-5 days versus 60-365 days), revealing key differences in grazing patterns that may affect vegetation and climate feedbacks. Next, I examined spatial variations in soil organic carbon (SOC) stocks between grass growth forms that differ in grazing tolerance (Chapter 3). Red grass (Themeda triandra) tussock patches, sensitive to frequent grazing, had higher SOC to a soil depth of 20 cm (61.45 ± 1.59 Mg C·ha-1)than intensively grazed, prostrate-growing Cynodon dactylon grazing lawns (55.43 ± 3.40Mg C·ha-1), likely due to greater shading and soil moisture beneath tussocks which drives microbial decomposition. Seasonal albedo variations were then assessed across distinct grassland patch types among seasons to determine whether albedo varies seasonally at fine patch-scales between grass patches, between shrub and grass patches, and with grazing (Chapter 4). Albedo was lower during the growing season compared to dormancy, and was consistently lower in dwarf shrub (Pentzia incana) encroached patches compared to grass patches. No albedo differences between grazed and less-grazed tussock grass patches of the same species were found, although intensively grazed grazing lawns had consistently higher albedo than most patch types. Finally, I evaluated trade-offs between plant carbon, albedo, and their impacts on radiative forcing (i.e., atmospheric warming/cooling) resulting from patch type changes commonly found in grassy ecosystems (Chapter 5). The loss of perennial grass cover resulted in the highest net positive (warming) effect, mostly due to reduced root biomass. Additionally, shrub encroachment into all patches lowered albedo, but led to negative (cooling) effects from shrub encroachment into bare ground patches due to biomass gains. This thesis challenges current views of grassy landscapes and short-duration grazing systems, emphasizing the need to rethink climate change mitigation strategies to prioritize maintaining heterogeneity, while enhancing carbon sequestration and albedo in grassy ecosystems. , Thesis (PhD) -- Faculty of Science, School of Environmental Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Mc Gregor, Steven
- Date: 2024-12
- Subjects: Grassland ecology , Global environmental change , Climatic changes
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69382 , vital:77250
- Description: Grassy ecosystems are essential for human survival, providing key services including food production, water provisioning and moderating climate. Yet, grassy ecosystems remain undervalued due to misconceptions that they are remnants of degraded states of forest – a view that continues to influence climate change policies. This thesis explores the links between wild, free-roaming ungulate grazers and climate drivers, including carbon storage and surface albedo (i.e., reflectance of solar radiation), through their impacts on vegetation and soils. Using black wildebeest (Connochaetes gnou) as a model wild species, I compared their grazing patterns in an Afromontane grassland in the eastern Karoo, South Africa, to those of short-duration cattle grazing systems in similar nearby grasslands (Chapter 2). While short-duration grazing aims to mimic spatiotemporal wild ungulate grazing patterns to supposedly enhance ecosystem functioning and soil carbon stocks, I found that wildebeest had ~50% shorter grazing durations and much shorter rest intervals (1-5 days versus 60-365 days), revealing key differences in grazing patterns that may affect vegetation and climate feedbacks. Next, I examined spatial variations in soil organic carbon (SOC) stocks between grass growth forms that differ in grazing tolerance (Chapter 3). Red grass (Themeda triandra) tussock patches, sensitive to frequent grazing, had higher SOC to a soil depth of 20 cm (61.45 ± 1.59 Mg C·ha-1)than intensively grazed, prostrate-growing Cynodon dactylon grazing lawns (55.43 ± 3.40Mg C·ha-1), likely due to greater shading and soil moisture beneath tussocks which drives microbial decomposition. Seasonal albedo variations were then assessed across distinct grassland patch types among seasons to determine whether albedo varies seasonally at fine patch-scales between grass patches, between shrub and grass patches, and with grazing (Chapter 4). Albedo was lower during the growing season compared to dormancy, and was consistently lower in dwarf shrub (Pentzia incana) encroached patches compared to grass patches. No albedo differences between grazed and less-grazed tussock grass patches of the same species were found, although intensively grazed grazing lawns had consistently higher albedo than most patch types. Finally, I evaluated trade-offs between plant carbon, albedo, and their impacts on radiative forcing (i.e., atmospheric warming/cooling) resulting from patch type changes commonly found in grassy ecosystems (Chapter 5). The loss of perennial grass cover resulted in the highest net positive (warming) effect, mostly due to reduced root biomass. Additionally, shrub encroachment into all patches lowered albedo, but led to negative (cooling) effects from shrub encroachment into bare ground patches due to biomass gains. This thesis challenges current views of grassy landscapes and short-duration grazing systems, emphasizing the need to rethink climate change mitigation strategies to prioritize maintaining heterogeneity, while enhancing carbon sequestration and albedo in grassy ecosystems. , Thesis (PhD) -- Faculty of Science, School of Environmental Sciences, 2024
- Full Text:
- Date Issued: 2024-12
The ontological reality of spirit and its ways of knowing as a form of embodied intangible cultural heritage: a case of the oGobela teaching approaches and techniques within Ubungoma practice
- Authors: Jacobs, Venetia Rose
- Date: 2024-10-11
- Subjects: Spiritual teacher , Cultural property South Africa , Ubuntu (Philosophy) , Learning , Teaching , Traditional knowledge
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/463570 , vital:76421
- Description: This study uses an ethnographic lens to explore the lived experiences, learning processes and experiential knowledge of oGobela (spiritual teachers). The study explores oGobela teaching approaches, techniques, and ways of knowing in Ubungoma1 practice which is known as Ukuthwasa2, which is understood as a modality or expression of Isintu. Furthermore, Isintu is defined as Indigenous knowledge systems and ancestral wisdom traditions which include Indigenous expressions of African peoples’ interactions with the cosmos, nature, earth and knowledge systems. The study reveals how esoteric knowledge (knowledge from ancestors and divinities) is translated into attainable knowledge in the form of healing techniques. This study aims to dismantle a largely European pedagogy when it pertains to the understanding of religious practices. An ethnographic lens layered with a decolonial intent worked together as a counter-hegemonic practice in the recentralisation of marginal voices, in this case, the voices of Izangoma narrating their lived experiences. Izangoma refer to people who have graduated as healers from initiation school. The theoretical framework used to guide the study was the sociocultural theory and decolonial theory. The decolonial theory was useful in my study to re-examine imperial histories through the harmful lens of colonialism. Sociocultural theory is geared towards looking at how learners actually learn as opposed to the way learners are expected to learn. This Vygotskian school of thought believes that human development is not isolated from historical, cultural and social contexts. My methodology made use of the case study, narrative analysis and criticalethnographic approaches involving semi-structured interviews with approximately seven Izangoma. This included radical embodied participation and reflexive journalling. I also drew on emerging studies on Indigenous knowledge systems such as the “anthropology of dreaming” (Tedlock, 1987, p. 1) and the “institution of drumming and dreaming in Ngoma” (Janzen, 1991, p. 291) to reflect on my experience as an initiate (Gogo Ukukhanya KweMhlaba) and my observations of my Gobela and other oGobela learning processes. The study draws a sample pool of both Izangoma and oGobela, to provide a holistic view of the role of oGobela from a teacher and learner perspective. It is important to note that not everyone who is a Sangoma is a Gobela. Becoming a Gobela is an additional calling based on specific instructions from your ancestors. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Jacobs, Venetia Rose
- Date: 2024-10-11
- Subjects: Spiritual teacher , Cultural property South Africa , Ubuntu (Philosophy) , Learning , Teaching , Traditional knowledge
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/463570 , vital:76421
- Description: This study uses an ethnographic lens to explore the lived experiences, learning processes and experiential knowledge of oGobela (spiritual teachers). The study explores oGobela teaching approaches, techniques, and ways of knowing in Ubungoma1 practice which is known as Ukuthwasa2, which is understood as a modality or expression of Isintu. Furthermore, Isintu is defined as Indigenous knowledge systems and ancestral wisdom traditions which include Indigenous expressions of African peoples’ interactions with the cosmos, nature, earth and knowledge systems. The study reveals how esoteric knowledge (knowledge from ancestors and divinities) is translated into attainable knowledge in the form of healing techniques. This study aims to dismantle a largely European pedagogy when it pertains to the understanding of religious practices. An ethnographic lens layered with a decolonial intent worked together as a counter-hegemonic practice in the recentralisation of marginal voices, in this case, the voices of Izangoma narrating their lived experiences. Izangoma refer to people who have graduated as healers from initiation school. The theoretical framework used to guide the study was the sociocultural theory and decolonial theory. The decolonial theory was useful in my study to re-examine imperial histories through the harmful lens of colonialism. Sociocultural theory is geared towards looking at how learners actually learn as opposed to the way learners are expected to learn. This Vygotskian school of thought believes that human development is not isolated from historical, cultural and social contexts. My methodology made use of the case study, narrative analysis and criticalethnographic approaches involving semi-structured interviews with approximately seven Izangoma. This included radical embodied participation and reflexive journalling. I also drew on emerging studies on Indigenous knowledge systems such as the “anthropology of dreaming” (Tedlock, 1987, p. 1) and the “institution of drumming and dreaming in Ngoma” (Janzen, 1991, p. 291) to reflect on my experience as an initiate (Gogo Ukukhanya KweMhlaba) and my observations of my Gobela and other oGobela learning processes. The study draws a sample pool of both Izangoma and oGobela, to provide a holistic view of the role of oGobela from a teacher and learner perspective. It is important to note that not everyone who is a Sangoma is a Gobela. Becoming a Gobela is an additional calling based on specific instructions from your ancestors. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2024
- Full Text:
- Date Issued: 2024-10-11
Synthesis, X-Ray characterization, spectroscopic and Hirshfeld surface analysis of dimeric metal centers featuring phenacyl-esters
- Authors: Qomfo, Vuyiseka
- Date: 2024-12
- Subjects: Spectrum analysis , Spectroscopic imaging , Diagnostic imaging -- Digital techniques
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69426 , vital:77254
- Description: In this study, the synthesis and characterization of carboxylate paddlewheel copper complexes were investigated and reported. The complexes consist of O-, and N- donor ligands which coordinated in the apical positions of the copper (II) paddlewheel complexes. The primary focus was the investigation of the influence of the incoming substituents on the structure; more especially with regards to the spectral properties and thermal properties of the synthesized compounds. Synthesized complexes ranged from simple mononuclear complexes and dinuclear dimers to supramolecular 1D networks and a tetranuclear copper (II) compound. Characterization of complexes was done using analytical, and spectroscopic techniques such as single crystal diffraction studies, FT-IR spectroscopy, thermal analysis and Hirshfeld surface analysis. Structural analysis of the mononuclear complex obtained in the reaction of the Cu2(o-CH3-PhCO2)4(THF)2 with the ligand ,2-oxo-phenylethylnicotinate, revealed a square-planar geometry. The series of dinuclear paddlewheel complexes obtained with ligands (L = THF (1), C4H8O (2), C14H11NO3 (3)) revealed a square pyramidal geometry with the methyl-substituted phenyl carboxylate groups bridging the two copper atoms in the syn-syn coordination mode. Extended supramolecular complexes were synthesized via the reaction of three synthesized structurally bifunctional organic ligands and the tetrakis(μ-carboxylato-O,O)dicopper(II) core. Two of the six reactions synthesized successfully to form paddlewheel cage type structures; resulting in dinuclear paddlewheel complexes with four carboxylate ligands occupying the equatorial positions and the bifunctional ligands coordinating in the apical positions. Four of the nine reactions produced mononuclear copper complexes. Due to the inconsistent power supply because of load-shedding, the other three crystals synthesized could not be confirmed by single-crystal diffraction before the submission of this thesis. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Qomfo, Vuyiseka
- Date: 2024-12
- Subjects: Spectrum analysis , Spectroscopic imaging , Diagnostic imaging -- Digital techniques
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69426 , vital:77254
- Description: In this study, the synthesis and characterization of carboxylate paddlewheel copper complexes were investigated and reported. The complexes consist of O-, and N- donor ligands which coordinated in the apical positions of the copper (II) paddlewheel complexes. The primary focus was the investigation of the influence of the incoming substituents on the structure; more especially with regards to the spectral properties and thermal properties of the synthesized compounds. Synthesized complexes ranged from simple mononuclear complexes and dinuclear dimers to supramolecular 1D networks and a tetranuclear copper (II) compound. Characterization of complexes was done using analytical, and spectroscopic techniques such as single crystal diffraction studies, FT-IR spectroscopy, thermal analysis and Hirshfeld surface analysis. Structural analysis of the mononuclear complex obtained in the reaction of the Cu2(o-CH3-PhCO2)4(THF)2 with the ligand ,2-oxo-phenylethylnicotinate, revealed a square-planar geometry. The series of dinuclear paddlewheel complexes obtained with ligands (L = THF (1), C4H8O (2), C14H11NO3 (3)) revealed a square pyramidal geometry with the methyl-substituted phenyl carboxylate groups bridging the two copper atoms in the syn-syn coordination mode. Extended supramolecular complexes were synthesized via the reaction of three synthesized structurally bifunctional organic ligands and the tetrakis(μ-carboxylato-O,O)dicopper(II) core. Two of the six reactions synthesized successfully to form paddlewheel cage type structures; resulting in dinuclear paddlewheel complexes with four carboxylate ligands occupying the equatorial positions and the bifunctional ligands coordinating in the apical positions. Four of the nine reactions produced mononuclear copper complexes. Due to the inconsistent power supply because of load-shedding, the other three crystals synthesized could not be confirmed by single-crystal diffraction before the submission of this thesis. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
Ground- and marine water inputs into supratidal microbialite systems along the Nelson Mandela Bay coastline
- Authors: O’Connell, Tristin Wade
- Date: 2024-12
- Subjects: Groundwater -- South Africa -- Nelson Mandela Bay , Earth sciences , Geology
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69415 , vital:77253
- Description: Extant supratidal microbialite systems are especially numerous and well-developed along the rocky coastline of Nelson Mandela Bay (NMB), South Africa. Precipitating in a hydrological environment formed by the input of constant, fresh groundwater discharge and periodic marine water intrusion these systems form part of the longest uninterrupted geological record of life on Earth (~3.4 billion years ago). Microbialites are layered organosedimentary deposits which potentially provide a window into historical environmental conditions. This study focusses on the fresh groundwater and saline marine water inputs of these microbialite pools, and the corresponding microbialite accretion rates. Severe regional drought in the NMB area resulted in rapid anthropogenic groundwater abstraction of the coastal aquifers on which the microbialite systems rely for groundwater inflow. This study provides insight into the current state of the coastal aquifers of NMB through the quantification of groundwater discharge via microbialite systems in terms of volume and flow rate. This is paired with in situ hourly microbialite pool water temperature and conductivity data to determine the effect of marine intrusion and the role of tidal flushing in these pools. A spatial assessment of groundwater discharge conducted using quantitative and semi-quantitative measurement techniques indicated that the total discharge of the study area is ~45.8 L/s or 3.8 ML/d. Over 1,500 freshwater seeps were identified, of which 78% showed microbialite deposits. Topography of the coast indicated that this might influence the flowrate. Calcareous sediment of sandy beaches within the study area supported lower discharge, while rocky shores with lithified rock had higher discharge. Seasonal differences in the volume discharged were evident, with winter having higher flowrates. Flow paths and discharge rates are affected by inland lithological differences and indicate variability linked to rainfall events that show lag effects depending on aquifer origins. This study is the first spatial analysis of the volume of groundwater discharging through microbialite-fed seeps. Marine intrusion and the corresponding pool flushing dynamics identified three types of microbailite systems: groundwater-dominant, dynamic input, and fast-reacting sites. A novel measurement technique for microbialite accretion determined accretion rates for systems under varying pool conditions. Although the average accretion rates of the Nelson Mandela Bay microbialites were in the order of erosion of 0.35 mm per year, there was significant variability in these measurements likely linked to differential localised vulnerability to storm events or responses to groundwater ix flow variability. It remains to be determined whether these factors are definitive risks to the sensitive supratidal microbialite systems. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: O’Connell, Tristin Wade
- Date: 2024-12
- Subjects: Groundwater -- South Africa -- Nelson Mandela Bay , Earth sciences , Geology
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69415 , vital:77253
- Description: Extant supratidal microbialite systems are especially numerous and well-developed along the rocky coastline of Nelson Mandela Bay (NMB), South Africa. Precipitating in a hydrological environment formed by the input of constant, fresh groundwater discharge and periodic marine water intrusion these systems form part of the longest uninterrupted geological record of life on Earth (~3.4 billion years ago). Microbialites are layered organosedimentary deposits which potentially provide a window into historical environmental conditions. This study focusses on the fresh groundwater and saline marine water inputs of these microbialite pools, and the corresponding microbialite accretion rates. Severe regional drought in the NMB area resulted in rapid anthropogenic groundwater abstraction of the coastal aquifers on which the microbialite systems rely for groundwater inflow. This study provides insight into the current state of the coastal aquifers of NMB through the quantification of groundwater discharge via microbialite systems in terms of volume and flow rate. This is paired with in situ hourly microbialite pool water temperature and conductivity data to determine the effect of marine intrusion and the role of tidal flushing in these pools. A spatial assessment of groundwater discharge conducted using quantitative and semi-quantitative measurement techniques indicated that the total discharge of the study area is ~45.8 L/s or 3.8 ML/d. Over 1,500 freshwater seeps were identified, of which 78% showed microbialite deposits. Topography of the coast indicated that this might influence the flowrate. Calcareous sediment of sandy beaches within the study area supported lower discharge, while rocky shores with lithified rock had higher discharge. Seasonal differences in the volume discharged were evident, with winter having higher flowrates. Flow paths and discharge rates are affected by inland lithological differences and indicate variability linked to rainfall events that show lag effects depending on aquifer origins. This study is the first spatial analysis of the volume of groundwater discharging through microbialite-fed seeps. Marine intrusion and the corresponding pool flushing dynamics identified three types of microbailite systems: groundwater-dominant, dynamic input, and fast-reacting sites. A novel measurement technique for microbialite accretion determined accretion rates for systems under varying pool conditions. Although the average accretion rates of the Nelson Mandela Bay microbialites were in the order of erosion of 0.35 mm per year, there was significant variability in these measurements likely linked to differential localised vulnerability to storm events or responses to groundwater ix flow variability. It remains to be determined whether these factors are definitive risks to the sensitive supratidal microbialite systems. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2024
- Full Text:
- Date Issued: 2024-12
A multistep synthesis of zidovudine in continuous flow systems
- Authors: Kwakhanya, Mkwakwi
- Date: 2024-12
- Subjects: HIV -- South Africa , HIV infections -- Diagnosis , Antiretroviral agents -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69393 , vital:77251
- Description: Universal access to antiretroviral drugs is still a challenge in developing nations. This promoted an investigation into an efficient process towards the synthesis of zidovudine (AZT), a nucleoside reverse transcriptase inhibitor (NRTI) that is used to treat HIV/AIDS. It was the first antiretroviral drug approved by the FDA and it is still widely used today. AZT works by blocking the enzyme reverse transcriptase, which is used by HIV to copy its genetic material. This prevents HIV from replicating and spreading throughout the body. AZT is usually taken in combination with other antiretroviral drugs. AZT was originally used as a single-drug therapy, but it is no longer recommended for this purpose as HIV can become resistant to AZT if it is used alone. Consequently, AZT is most commonly used as part of a combination therapy; this means that it is taken with other antiretroviral drugs. This helps to prevent HIV from becoming resistant to AZT. AZT can be used to prevent mother-to-child transmission of HIV; it is usually given to HIV-positive women during pregnancy and childbirth. AZT can also be used to treat post-exposure prophylaxis (PEP); this is a course of antiretroviral drugs that is taken after a possible exposure to HIV. The application of continuous flow microreactors to reaction chemistries, such as this, could provide a potentially practical solution that could be used to meet the rising needs for antiretroviral drugs in Africa and to give new opportunities for efficient local drug manufacture. Consequently, the focus of this research was to develop safe and efficient processes towards AZT by taking advantage of micro reactor technology. Furthermore, since there is no literature on continuous flow synthesis of this drug, this research extensively unearthed interesting continuous flow processes towards zidovudine. , Thesis (PhD) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Kwakhanya, Mkwakwi
- Date: 2024-12
- Subjects: HIV -- South Africa , HIV infections -- Diagnosis , Antiretroviral agents -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69393 , vital:77251
- Description: Universal access to antiretroviral drugs is still a challenge in developing nations. This promoted an investigation into an efficient process towards the synthesis of zidovudine (AZT), a nucleoside reverse transcriptase inhibitor (NRTI) that is used to treat HIV/AIDS. It was the first antiretroviral drug approved by the FDA and it is still widely used today. AZT works by blocking the enzyme reverse transcriptase, which is used by HIV to copy its genetic material. This prevents HIV from replicating and spreading throughout the body. AZT is usually taken in combination with other antiretroviral drugs. AZT was originally used as a single-drug therapy, but it is no longer recommended for this purpose as HIV can become resistant to AZT if it is used alone. Consequently, AZT is most commonly used as part of a combination therapy; this means that it is taken with other antiretroviral drugs. This helps to prevent HIV from becoming resistant to AZT. AZT can be used to prevent mother-to-child transmission of HIV; it is usually given to HIV-positive women during pregnancy and childbirth. AZT can also be used to treat post-exposure prophylaxis (PEP); this is a course of antiretroviral drugs that is taken after a possible exposure to HIV. The application of continuous flow microreactors to reaction chemistries, such as this, could provide a potentially practical solution that could be used to meet the rising needs for antiretroviral drugs in Africa and to give new opportunities for efficient local drug manufacture. Consequently, the focus of this research was to develop safe and efficient processes towards AZT by taking advantage of micro reactor technology. Furthermore, since there is no literature on continuous flow synthesis of this drug, this research extensively unearthed interesting continuous flow processes towards zidovudine. , Thesis (PhD) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
Graphene@microalgae-based nanohybrid structures as adsorbents for removal of Cr(VI) ions in aqueous solutions
- Authors: Mulovhedzi, Rolivhuwa
- Date: 2024-12
- Subjects: Nanoscience , Nanotechnology , Nonaqueous solvents
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69404 , vital:77252
- Description: iv ABSTRACT The efficient removal of heavy metals using carbon-based nanoadsorbents poses a substantial challenge in the domain of water purification. Graphene-based materials have been extensively utilised in the treatment of water and wastewater due to their tremendous surface areas, porosity, turntable nature to different functional groups, and photo-catalytic properties. In this project, graphene oxide (GO) was synthesised via the modified Hummers method. A similar method was used to produce nitrogen-doped graphene oxide (NGO), with urea as the nitrogen precursor. Utilising biomass materials to dope graphene-based nanocomposites can effectively enhance their application in water treatment. In this work, graphene oxide-microalgae (GO@Algae) and N-doped graphene oxide-microalgae (NGO@Algae) nanocomposites were synthesised by combining GO or NGO with green Scenedesmus microalgae. This was done through a solution self-assembly mixing method using ultrasonication. The resulting nanocomposites were used to remove Cr(VI) from water solutions. The influence of microalgae content deposited on GO and NGO nanosheets at different weight ratios (1:1, 3:1, and 1:3) on the chemical, structural, morphological, and thermal characteristics of nanoadsorbents was evaluated using various techniques such as Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The flat nanosheet-like morphology of GO@Algae and NGO@Algae nanostructured materials was observed through SEM, confirming microalgae's incorporation within the GO and NGO matrices. The thermal stability and surface area properties of GO and NGO nanocomposite materials decreased with the incorporation of microalgae content. The incorporation of microalgae into GO nanosheets showed enhancements in chemical and structural properties due to the presence of the strong covalent interaction (oxygen and nitrogen-containing groups) between the interfaces of nanocomposites. XPS and FT-IR analyses revealed the existence of amides, carboxylic acids, and phosphates, which exhibited positive charges below the pH 2.03 point-of-zero charge. The second phase of the study involved assessing the adsorption capabilities of the GO, NGO nanosheets, and GO@Algae and NGO@Algae nanocomposites in removing Cr(VI)from the water solution. Adsorption parameters such as the effect of solution pH, contact time, adsorbent dosage and metal ion concentrations were evaluated for Cr(VI) removal. When comparing GO, NGO, GO@Algae, and NGO@Algae, it was found that GO@Algae and NGO@Algae exhibited superior adsorption performance due to the available functional groups and well-developed pores. Additionally, a mixed ratio of GO or NGO and algae at a ratio of 1:3 was found to be the most suitable for GO@Algae and NGO@Algae. The adsorption efficiency of nanostructured materials for Cr(VI) is significantly influenced by their surface charge, porosity and specific surface area. The results revealed that the adsorption capabilities of GO@Algae (1:3) and NGO@Algae (1:3) were 2.24 and 2.01 times higher than GO and NGO which were 1.64 and 1.89, respectively, at a solution of pH 2 where HCrO4− species are predominant compared to a solution of pH 5 which predominate a mix of Cr2O72− and CrO42- species. The enhanced performance of the GO@Algae and NGO@Algae nanocomposites is attributed due to their increased surface functionalities and porosity. The adsorption of Cr(VI) ions by the GO/NGO@Algae nanocomposites declined with increasing initial concentration of Cr(VI) species in the water medium. The adsorption kinetics data for GO, NGO, GO@Algae (1:3), and NGO@Algae (1:3) exhibited a good fit with the pseudo-second-order model (R2 > 0.995) suggesting that chemisorption governed the adsorption process. Similarly, the isotherm adsorption findings showed a good fit with the Freundlich model (R2 > 0.961). The findings indicated that the adsorption mechanism process was characterised by monolayer adsorption onto a heterogeneous adsorbent surface. Furthermore, the GO@Algae (1:3) was found to have the maximum adsorption capacity of 10.85 mg/g surpassing the capacities of both unmodified and NGO@Algae counterparts. The application of GO@Algae and NGO@Algae has the potential to promote the green reuse of graphene-based nanomaterials. In summary, GO@Algae and NGO@Algae show great potential as eco-friendly adsorbents for the feasible treatment of heavy metal-contaminated water. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Mulovhedzi, Rolivhuwa
- Date: 2024-12
- Subjects: Nanoscience , Nanotechnology , Nonaqueous solvents
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69404 , vital:77252
- Description: iv ABSTRACT The efficient removal of heavy metals using carbon-based nanoadsorbents poses a substantial challenge in the domain of water purification. Graphene-based materials have been extensively utilised in the treatment of water and wastewater due to their tremendous surface areas, porosity, turntable nature to different functional groups, and photo-catalytic properties. In this project, graphene oxide (GO) was synthesised via the modified Hummers method. A similar method was used to produce nitrogen-doped graphene oxide (NGO), with urea as the nitrogen precursor. Utilising biomass materials to dope graphene-based nanocomposites can effectively enhance their application in water treatment. In this work, graphene oxide-microalgae (GO@Algae) and N-doped graphene oxide-microalgae (NGO@Algae) nanocomposites were synthesised by combining GO or NGO with green Scenedesmus microalgae. This was done through a solution self-assembly mixing method using ultrasonication. The resulting nanocomposites were used to remove Cr(VI) from water solutions. The influence of microalgae content deposited on GO and NGO nanosheets at different weight ratios (1:1, 3:1, and 1:3) on the chemical, structural, morphological, and thermal characteristics of nanoadsorbents was evaluated using various techniques such as Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The flat nanosheet-like morphology of GO@Algae and NGO@Algae nanostructured materials was observed through SEM, confirming microalgae's incorporation within the GO and NGO matrices. The thermal stability and surface area properties of GO and NGO nanocomposite materials decreased with the incorporation of microalgae content. The incorporation of microalgae into GO nanosheets showed enhancements in chemical and structural properties due to the presence of the strong covalent interaction (oxygen and nitrogen-containing groups) between the interfaces of nanocomposites. XPS and FT-IR analyses revealed the existence of amides, carboxylic acids, and phosphates, which exhibited positive charges below the pH 2.03 point-of-zero charge. The second phase of the study involved assessing the adsorption capabilities of the GO, NGO nanosheets, and GO@Algae and NGO@Algae nanocomposites in removing Cr(VI)from the water solution. Adsorption parameters such as the effect of solution pH, contact time, adsorbent dosage and metal ion concentrations were evaluated for Cr(VI) removal. When comparing GO, NGO, GO@Algae, and NGO@Algae, it was found that GO@Algae and NGO@Algae exhibited superior adsorption performance due to the available functional groups and well-developed pores. Additionally, a mixed ratio of GO or NGO and algae at a ratio of 1:3 was found to be the most suitable for GO@Algae and NGO@Algae. The adsorption efficiency of nanostructured materials for Cr(VI) is significantly influenced by their surface charge, porosity and specific surface area. The results revealed that the adsorption capabilities of GO@Algae (1:3) and NGO@Algae (1:3) were 2.24 and 2.01 times higher than GO and NGO which were 1.64 and 1.89, respectively, at a solution of pH 2 where HCrO4− species are predominant compared to a solution of pH 5 which predominate a mix of Cr2O72− and CrO42- species. The enhanced performance of the GO@Algae and NGO@Algae nanocomposites is attributed due to their increased surface functionalities and porosity. The adsorption of Cr(VI) ions by the GO/NGO@Algae nanocomposites declined with increasing initial concentration of Cr(VI) species in the water medium. The adsorption kinetics data for GO, NGO, GO@Algae (1:3), and NGO@Algae (1:3) exhibited a good fit with the pseudo-second-order model (R2 > 0.995) suggesting that chemisorption governed the adsorption process. Similarly, the isotherm adsorption findings showed a good fit with the Freundlich model (R2 > 0.961). The findings indicated that the adsorption mechanism process was characterised by monolayer adsorption onto a heterogeneous adsorbent surface. Furthermore, the GO@Algae (1:3) was found to have the maximum adsorption capacity of 10.85 mg/g surpassing the capacities of both unmodified and NGO@Algae counterparts. The application of GO@Algae and NGO@Algae has the potential to promote the green reuse of graphene-based nanomaterials. In summary, GO@Algae and NGO@Algae show great potential as eco-friendly adsorbents for the feasible treatment of heavy metal-contaminated water. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
Gold mineralization at the Blue Rock Deposit, Gadzema Greenstone Belt: Implications on genesis and exploration for orogenic gold mineralization within Archaean Greenstone Belts of Zimbabwe
- Authors: Mavuwa, Tavashavira
- Date: 2024-10-11
- Subjects: Felsite , Quartz porphyry , Orogenic gold deposit , Shear zones (Geology) , Prospecting
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464944 , vital:76559
- Description: The Blue Rock gold deposit was re-discovered by African Consolidated Resources (ACR) in 2007, over a defunct historical gold mine at Blue Rock, during a regional geochemical soil sampling program, within the Gadzema Greenstone Belt (GGB), in Central Zimbabwe. Most significant orogenic gold deposits within this belt occur as BIF- and quartz vein hosted orebodies. But unlike them, gold mineralization at Blue Rock is associated with felsite and quartz porphyry rocks. The GGB is a northern extension of the Midlands Greenstone Belt (MGB), where the common occurrence of mineralized felsites, in close association with major gold reefs within numerous gold mines is well documented. But no significant effort was directed towards their understanding or exploration in the past. They were never considered viable exploration targets for significant economic gold deposits, until recently. More attention was instead focused on high-grade BIF and quartz vein hosted gold, that dominate most orebodies exploited by numerous mines within the belt. At Blue Rock, ACR defined a significant JORC compliant felsite-hosted gold resource of close to a million ounces, which represents a brand new attractive open-pit mining opportunity. But the successful exploration for such type of mineralization, whose footprint is so different from the common ones previously mined within the GGB, no doubt, calls for a good understanding of this type of mineralization. Which makes felsite-hosted gold mineralization a prime candidate for research, based on a deposit whose discovery and development, I was fortunate to be part of during the past few years. In this contribution, the genesis, localization and economic significance of felsite-hosted gold mineralization is investigated, using the gold deposit at Blue Rock as a case study. The deposit could be understood best through the Mineral Systems Approach, used in this study to interrogate alternative ideas about its genesis using published information and deposit-scale exploratory data. Results from the synthesis of published information on the evolution of Archaean Greenstone Belts and genesis of their host orogenic gold deposits, are consistent with models that view orogenic terrains as having formed through horizontal accretion in modern-day like subduction-accretion systems, at continental margins, where orogenic gold deposition occurred via processes that could be explained quite simply, through a universal orogenic gold mineral systems model. According to this model, orogenic gold deposits are believed to have formed from near neutral fluids containing dissolved gold, generated directly from the devolatilization of a subducted oceanic slab together with its overlying gold-bearing sulphide-rich sedimentary package, or indirectly through fluid released from a mantle lithosphere that was originally metasomatized and fertilized during an earlier subduction event. The fluid migrated up-dip from the mantle to crustal levels, through advection or seismic pumping along lithosphere- to crustal-scale fault zones, to form orogenic gold deposits within lower order structures. If these models are all accurate, then the GGB formed through subduction-related east-directed horizontal accretion at the continental margins of the Sebakwe Proto-Craton (SPC), and the genesis of felsite-hosted gold mineralization at Blue Rock could be explained eloquently through a universal orogenic gold model, in which mantle derived auriferous fluids were localised within lower order structures associated with felsites during the late stages of terrain accretion. Evidence from surface mapping and 3D modelling of exploratory drilling data, conducted during this research, strongly support the argument that the felsite hosted gold mineralization at Blue Rock, is neither unique nor accidental. It is just but, a simple product of the conjunction of favourable geological factors, no different to those that birthed typical GGB orogenic gold mineralization hosted within sheared sulphidic BIFs and quartz vein reefs. They all share the same geodynamic setting, fertility, preservation and regional architectural factors reminiscent of accretionary orogenic settings, albeit with differences in local architecture, variably controlled by geochemical and rheological properties of the different local host rocks. At deposit scale, the felsites occur as small dykes and sills emplaced along pre-existing structural zones of weakness. Gold mineralization is structurally controlled and associated mostly with brittle-ductile shears. During deformation, rheological contrast played a significant role in the selective failure of the more competent felsite rocks, resulting in the creation of permeability channels that allowed fluid migration. The more brittle and competent felsites acted as rigid bodies, that localised strain along their contacts with the surrounding less competent ductile mafic schists which acted as a relatively less permeable fluid cap rock. The irregular felsite contact zones with surrounding mafic schist caused a significant variation in the orientation of local principal maximum stress relative to the internally imposed regional stress, causing anomalously low minimum stress zones at deposit scale. Gold deposition occurred within low minimum stress structural traps dominated by sheared felsite contacts and their fractured interiors as well as triple junctions formed by complex structural geometries created by multiple felsite intrusions. The felsite hosted gold at Blue Rock can therefore be recognized as an orogenic gold mineral system archetype, for which an occurrence model is proposed. Understanding this type of mineralization is key for developing a robust exploration strategy - one that could be applied in a predictive capacity in exploration, to locate new economic gold deposits especially within well-endowed mature orogenic terrains, where exploration risk could be minimized by leveraging on new forward-thinking initiatives like Artificial Intelligence (AI) to re-analyze data from previous mining and exploration, allowing for a faster route to a return on investment. In a world of diminishing natural resources, the potential for previously ignored gold mineralization like the one at Blue Rock, becomes very significant. The prophetic words of Foster (1984), writing in Gold ‘82, therefore remain true and relevant to our time, that; “…. the way ahead for successful gold exploration is to search for new deposits not commonly recognized – in auriferous muds, disseminations in carbonate rocks, porphyries, and in felsic intrusive and extrusive volcanics…”. , Thesis (MSc) -- Faculty of Science, Geology, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Mavuwa, Tavashavira
- Date: 2024-10-11
- Subjects: Felsite , Quartz porphyry , Orogenic gold deposit , Shear zones (Geology) , Prospecting
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464944 , vital:76559
- Description: The Blue Rock gold deposit was re-discovered by African Consolidated Resources (ACR) in 2007, over a defunct historical gold mine at Blue Rock, during a regional geochemical soil sampling program, within the Gadzema Greenstone Belt (GGB), in Central Zimbabwe. Most significant orogenic gold deposits within this belt occur as BIF- and quartz vein hosted orebodies. But unlike them, gold mineralization at Blue Rock is associated with felsite and quartz porphyry rocks. The GGB is a northern extension of the Midlands Greenstone Belt (MGB), where the common occurrence of mineralized felsites, in close association with major gold reefs within numerous gold mines is well documented. But no significant effort was directed towards their understanding or exploration in the past. They were never considered viable exploration targets for significant economic gold deposits, until recently. More attention was instead focused on high-grade BIF and quartz vein hosted gold, that dominate most orebodies exploited by numerous mines within the belt. At Blue Rock, ACR defined a significant JORC compliant felsite-hosted gold resource of close to a million ounces, which represents a brand new attractive open-pit mining opportunity. But the successful exploration for such type of mineralization, whose footprint is so different from the common ones previously mined within the GGB, no doubt, calls for a good understanding of this type of mineralization. Which makes felsite-hosted gold mineralization a prime candidate for research, based on a deposit whose discovery and development, I was fortunate to be part of during the past few years. In this contribution, the genesis, localization and economic significance of felsite-hosted gold mineralization is investigated, using the gold deposit at Blue Rock as a case study. The deposit could be understood best through the Mineral Systems Approach, used in this study to interrogate alternative ideas about its genesis using published information and deposit-scale exploratory data. Results from the synthesis of published information on the evolution of Archaean Greenstone Belts and genesis of their host orogenic gold deposits, are consistent with models that view orogenic terrains as having formed through horizontal accretion in modern-day like subduction-accretion systems, at continental margins, where orogenic gold deposition occurred via processes that could be explained quite simply, through a universal orogenic gold mineral systems model. According to this model, orogenic gold deposits are believed to have formed from near neutral fluids containing dissolved gold, generated directly from the devolatilization of a subducted oceanic slab together with its overlying gold-bearing sulphide-rich sedimentary package, or indirectly through fluid released from a mantle lithosphere that was originally metasomatized and fertilized during an earlier subduction event. The fluid migrated up-dip from the mantle to crustal levels, through advection or seismic pumping along lithosphere- to crustal-scale fault zones, to form orogenic gold deposits within lower order structures. If these models are all accurate, then the GGB formed through subduction-related east-directed horizontal accretion at the continental margins of the Sebakwe Proto-Craton (SPC), and the genesis of felsite-hosted gold mineralization at Blue Rock could be explained eloquently through a universal orogenic gold model, in which mantle derived auriferous fluids were localised within lower order structures associated with felsites during the late stages of terrain accretion. Evidence from surface mapping and 3D modelling of exploratory drilling data, conducted during this research, strongly support the argument that the felsite hosted gold mineralization at Blue Rock, is neither unique nor accidental. It is just but, a simple product of the conjunction of favourable geological factors, no different to those that birthed typical GGB orogenic gold mineralization hosted within sheared sulphidic BIFs and quartz vein reefs. They all share the same geodynamic setting, fertility, preservation and regional architectural factors reminiscent of accretionary orogenic settings, albeit with differences in local architecture, variably controlled by geochemical and rheological properties of the different local host rocks. At deposit scale, the felsites occur as small dykes and sills emplaced along pre-existing structural zones of weakness. Gold mineralization is structurally controlled and associated mostly with brittle-ductile shears. During deformation, rheological contrast played a significant role in the selective failure of the more competent felsite rocks, resulting in the creation of permeability channels that allowed fluid migration. The more brittle and competent felsites acted as rigid bodies, that localised strain along their contacts with the surrounding less competent ductile mafic schists which acted as a relatively less permeable fluid cap rock. The irregular felsite contact zones with surrounding mafic schist caused a significant variation in the orientation of local principal maximum stress relative to the internally imposed regional stress, causing anomalously low minimum stress zones at deposit scale. Gold deposition occurred within low minimum stress structural traps dominated by sheared felsite contacts and their fractured interiors as well as triple junctions formed by complex structural geometries created by multiple felsite intrusions. The felsite hosted gold at Blue Rock can therefore be recognized as an orogenic gold mineral system archetype, for which an occurrence model is proposed. Understanding this type of mineralization is key for developing a robust exploration strategy - one that could be applied in a predictive capacity in exploration, to locate new economic gold deposits especially within well-endowed mature orogenic terrains, where exploration risk could be minimized by leveraging on new forward-thinking initiatives like Artificial Intelligence (AI) to re-analyze data from previous mining and exploration, allowing for a faster route to a return on investment. In a world of diminishing natural resources, the potential for previously ignored gold mineralization like the one at Blue Rock, becomes very significant. The prophetic words of Foster (1984), writing in Gold ‘82, therefore remain true and relevant to our time, that; “…. the way ahead for successful gold exploration is to search for new deposits not commonly recognized – in auriferous muds, disseminations in carbonate rocks, porphyries, and in felsic intrusive and extrusive volcanics…”. , Thesis (MSc) -- Faculty of Science, Geology, 2024
- Full Text:
- Date Issued: 2024-10-11
Church music as pedagogy: An investigation through digital storytelling into the role that Southern African Christian Church music praxis played in the musical development of five professional musicians
- Authors: Mathebula, Praise Ntsako
- Date: 2024-10-11
- Subjects: Church music Africa, Southern , Indigenous music , Digital storytelling , Music of Southern Africa , Musicians Africa, Southern , Western education
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465975 , vital:76673
- Description: Using an ethnographic and autoethnographic approach, this study investigated how the church has influenced the development and practice of five professional musicians practicing in South Africa. This research resulted from discussions with numerous musicians who had their music genesis at church, some of them well-known professionals in the country. Reflecting on the history of church music education that can be traced back to the arrival of the missionaries on the African continent and the different types of music education settings that can be found in South Africa, this thesis analyses the approach and delivery of music pedagogy that exists in the South African church setting. Discussing the introduction of Western musical tools such as tonic-solfa, choral music and four-part singing, this research contextualises the historical effect of mission education of several South African composers, including Tiyo Soga, Enoch Sontonga and John Knox Bokwe. Thereafter, using Digital Storytelling (DS) as a methodology for data collection and Ethnographic Content Analysis (ECA) as an analytic tool, co-researchers were given the opportunity to create data or share their stories in a novel manner, which has proven to develop powerful, honest and self-reflexive results. Important pedagogic themes that emerged as being part of a shared church-led approach to music teaching and learning include practice and consistent performance; collaboration; imitation; embodied and experiential learning, rote learning, and memorisation. Central to using DS as a methodology, this study found that musical identity and early pedagogical approaches to learning music play an important factor in further musical development and education. , Thesis (MA) -- Faculty of Humanities, Music and Musicology, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Mathebula, Praise Ntsako
- Date: 2024-10-11
- Subjects: Church music Africa, Southern , Indigenous music , Digital storytelling , Music of Southern Africa , Musicians Africa, Southern , Western education
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465975 , vital:76673
- Description: Using an ethnographic and autoethnographic approach, this study investigated how the church has influenced the development and practice of five professional musicians practicing in South Africa. This research resulted from discussions with numerous musicians who had their music genesis at church, some of them well-known professionals in the country. Reflecting on the history of church music education that can be traced back to the arrival of the missionaries on the African continent and the different types of music education settings that can be found in South Africa, this thesis analyses the approach and delivery of music pedagogy that exists in the South African church setting. Discussing the introduction of Western musical tools such as tonic-solfa, choral music and four-part singing, this research contextualises the historical effect of mission education of several South African composers, including Tiyo Soga, Enoch Sontonga and John Knox Bokwe. Thereafter, using Digital Storytelling (DS) as a methodology for data collection and Ethnographic Content Analysis (ECA) as an analytic tool, co-researchers were given the opportunity to create data or share their stories in a novel manner, which has proven to develop powerful, honest and self-reflexive results. Important pedagogic themes that emerged as being part of a shared church-led approach to music teaching and learning include practice and consistent performance; collaboration; imitation; embodied and experiential learning, rote learning, and memorisation. Central to using DS as a methodology, this study found that musical identity and early pedagogical approaches to learning music play an important factor in further musical development and education. , Thesis (MA) -- Faculty of Humanities, Music and Musicology, 2024
- Full Text:
- Date Issued: 2024-10-11
Extreme value theory with applications in finance
- Authors: Matshaya, Aphelele
- Date: 2024-10-11
- Subjects: Bitcoin , Bivariate analysis , Correlation (Statistics) , Extreme value theory , Generalized Pareto distribution , High frequency data , Tail risk
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465047 , vital:76568
- Description: The development and implementation of extreme value theory models has been very significant as they demonstrate an application of statistics that is very much needed in the analysis of extreme events in a wide range of industries, and more recently the cryptocurrency industry. The crypto industry is booming as the phenomenon of cryptocurrencies is spreading worldwide and constantly drawing the attention of investors, the media, as well as financial institutions. Cryptocurrencies are highly volatile assets whose price fluctuations continually lead to the loss of millions in a variety of currencies in the market. In this thesis, the extreme behaviour in the tail of the distribution of returns of Bitcoin will be examined. High-frequency Bitcoin data spanning periods before as well as after the COVID-19 pandemic will be utilised. The Peaks-over-Threshold method will be used to build models based on the generalised Pareto distribution, and both positive returns and negative returns will be modelled. Several techniques to select appropriate thresholds for the models are explored and the goodness-offit of the models assessed to determine the extent to which extreme value theory can model Bitcoin returns sufficiently. The analysis is extended and performed on Bitcoin data from a different crypto exchange to ensure model robustness is achieved. Using Bivariate extreme value theory, a Gumbel copula is fitted by the method of maximum likelihood with censored data to model the dynamic relationship between Bitcoin returns and trading volumes at the extreme tails. The extreme dependence and correlation structures will be analysed using tail dependence coefficients and the related extreme correlation coefficients. All computations are executed in R and the results are recorded in tabular and graphical formats. Tail-related measures of risk, namely Value-at-Risk and Expected Shortfall, are estimated from the extreme value models. Backtesting procedures are performed on the results from the risk models. A comparison between the negative returns of Bitcoin and those of Gold is carried out to determine which is the less risky asset to invest in during extreme market conditions. Extreme risk is calculated using the same extreme value approach and the results show that Bitcoin is riskier than Gold. , Thesis (MSc) -- Faculty of Science, Statistics, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Matshaya, Aphelele
- Date: 2024-10-11
- Subjects: Bitcoin , Bivariate analysis , Correlation (Statistics) , Extreme value theory , Generalized Pareto distribution , High frequency data , Tail risk
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/465047 , vital:76568
- Description: The development and implementation of extreme value theory models has been very significant as they demonstrate an application of statistics that is very much needed in the analysis of extreme events in a wide range of industries, and more recently the cryptocurrency industry. The crypto industry is booming as the phenomenon of cryptocurrencies is spreading worldwide and constantly drawing the attention of investors, the media, as well as financial institutions. Cryptocurrencies are highly volatile assets whose price fluctuations continually lead to the loss of millions in a variety of currencies in the market. In this thesis, the extreme behaviour in the tail of the distribution of returns of Bitcoin will be examined. High-frequency Bitcoin data spanning periods before as well as after the COVID-19 pandemic will be utilised. The Peaks-over-Threshold method will be used to build models based on the generalised Pareto distribution, and both positive returns and negative returns will be modelled. Several techniques to select appropriate thresholds for the models are explored and the goodness-offit of the models assessed to determine the extent to which extreme value theory can model Bitcoin returns sufficiently. The analysis is extended and performed on Bitcoin data from a different crypto exchange to ensure model robustness is achieved. Using Bivariate extreme value theory, a Gumbel copula is fitted by the method of maximum likelihood with censored data to model the dynamic relationship between Bitcoin returns and trading volumes at the extreme tails. The extreme dependence and correlation structures will be analysed using tail dependence coefficients and the related extreme correlation coefficients. All computations are executed in R and the results are recorded in tabular and graphical formats. Tail-related measures of risk, namely Value-at-Risk and Expected Shortfall, are estimated from the extreme value models. Backtesting procedures are performed on the results from the risk models. A comparison between the negative returns of Bitcoin and those of Gold is carried out to determine which is the less risky asset to invest in during extreme market conditions. Extreme risk is calculated using the same extreme value approach and the results show that Bitcoin is riskier than Gold. , Thesis (MSc) -- Faculty of Science, Statistics, 2024
- Full Text:
- Date Issued: 2024-10-11
Cocrystals, salts and eutectics of anti-tuberculosis medicines
- Authors: Matlapeng, Tsebang Alice
- Date: 2024-10-11
- Subjects: Cocrystal , Tuberculosis , 4-aminosalicylic acid , Isoniazid , Pyrazinamide , Pyrazinoic acid
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464521 , vital:76518
- Description: Tuberculosis remains as a prominent cause of death worldwide. This infectious disease is treated with first and second line drugs. However, challenges of multi drug resistant tuberculosis and adverse side effects such as depletion of essential B group vitamins in the body by first line drugs, as well as poor physicochemical properties of second line drugs persist. Cocrystallisation of anti-tubercular drugs with various coformers has therefore been used as an alternative method to improve the physicochemical properties of active pharmaceutical ingredients (API) while maintaining their efficacy. The main objective of this study was to carry out cocrystal screening of anti-tubercular API and vitamin B coformers to make drug-drug or drug-vitamin multicomponent complexes. Preparation of the multicomponent complexes was carried out by mechanochemical grinding (neat grinding (NG), liquid assisted grinding (LAG) and slow evaporation. All complexes were characterised using Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and crystal structures were elucidated using single-crystal X-ray diffraction (SCXRD). The cocrystal screening resulted in the formation of various solid forms, which included cocrystals, salts and eutectic products. Two cocrystals of 4-aminosalicylic acid (PAS) were isolated and characterised. The cocrystal of PAS with isoniazid (INH) demonstrated similar characteristics for both the bulk crystalline material and milled materials. The cocrystal of PAS and pyrazinamide (PYR) prepared using mechanochemical synthesis was met with challenges, while difficulties were also encountered in obtaining suitable crystals for SCXRD analysis. The ground and recrystallised samples of the PAS and pyrazinecarboxylic acid (PCBA) showed distinct differences in their thermal behaviour, with SCXRD revealing the decomposition product phenolammonium-pyrazinecarboxylate salt ‘sans’ the CO2 moiety. Salt formation involving pyridoxine (PN) yielded a salt hydrate with PAS (PN-PAS) and an anhydrous salt with PCBA (PN-PCBA). Both salts exhibited very complex packing arrangements with equally complex thermal behaviour depending on the solvent used during preparation, and the method of preparation. Three eutectic systems involving INH with PYR, PN and pyridoxine hydrochloride (PNꞏHCl) were identified, and their phase diagrams were constructed from DSC data. The eutectic compositions obtained were 1:1 for INH:PYR, 1:1 for INH:PN and 6:4 for INH:PNꞏHCl. Finally, a total of eight multicomponent complexes were prepared using selected API and vitamin B6 components. The results presented here provide motivation for further investigation and evaluation of the pharmacochemical properties of these API. , Thesis (MSc) -- Faculty of Science, Chemistry, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Matlapeng, Tsebang Alice
- Date: 2024-10-11
- Subjects: Cocrystal , Tuberculosis , 4-aminosalicylic acid , Isoniazid , Pyrazinamide , Pyrazinoic acid
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464521 , vital:76518
- Description: Tuberculosis remains as a prominent cause of death worldwide. This infectious disease is treated with first and second line drugs. However, challenges of multi drug resistant tuberculosis and adverse side effects such as depletion of essential B group vitamins in the body by first line drugs, as well as poor physicochemical properties of second line drugs persist. Cocrystallisation of anti-tubercular drugs with various coformers has therefore been used as an alternative method to improve the physicochemical properties of active pharmaceutical ingredients (API) while maintaining their efficacy. The main objective of this study was to carry out cocrystal screening of anti-tubercular API and vitamin B coformers to make drug-drug or drug-vitamin multicomponent complexes. Preparation of the multicomponent complexes was carried out by mechanochemical grinding (neat grinding (NG), liquid assisted grinding (LAG) and slow evaporation. All complexes were characterised using Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and crystal structures were elucidated using single-crystal X-ray diffraction (SCXRD). The cocrystal screening resulted in the formation of various solid forms, which included cocrystals, salts and eutectic products. Two cocrystals of 4-aminosalicylic acid (PAS) were isolated and characterised. The cocrystal of PAS with isoniazid (INH) demonstrated similar characteristics for both the bulk crystalline material and milled materials. The cocrystal of PAS and pyrazinamide (PYR) prepared using mechanochemical synthesis was met with challenges, while difficulties were also encountered in obtaining suitable crystals for SCXRD analysis. The ground and recrystallised samples of the PAS and pyrazinecarboxylic acid (PCBA) showed distinct differences in their thermal behaviour, with SCXRD revealing the decomposition product phenolammonium-pyrazinecarboxylate salt ‘sans’ the CO2 moiety. Salt formation involving pyridoxine (PN) yielded a salt hydrate with PAS (PN-PAS) and an anhydrous salt with PCBA (PN-PCBA). Both salts exhibited very complex packing arrangements with equally complex thermal behaviour depending on the solvent used during preparation, and the method of preparation. Three eutectic systems involving INH with PYR, PN and pyridoxine hydrochloride (PNꞏHCl) were identified, and their phase diagrams were constructed from DSC data. The eutectic compositions obtained were 1:1 for INH:PYR, 1:1 for INH:PN and 6:4 for INH:PNꞏHCl. Finally, a total of eight multicomponent complexes were prepared using selected API and vitamin B6 components. The results presented here provide motivation for further investigation and evaluation of the pharmacochemical properties of these API. , Thesis (MSc) -- Faculty of Science, Chemistry, 2024
- Full Text:
- Date Issued: 2024-10-11
Teaching problem solving: the "Ten Commandments" approach
- Authors: Matiwane, Noluvuyo
- Date: 2024-10-11
- Subjects: Problem solving Study and teaching , Physics Study and teaching , Curriculum change , Rhodes University , College students Attitudes
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464897 , vital:76555
- Description: The evident need for an intervention to help physics students, especially incoming university students, develop their problem-solving skills led to exploring possible curriculum structures to achieve the goal. A modified curriculum structure of the first-year physics course, including explicit teaching of physics problem solving, was developed and implemented at Rhodes University, South Africa, in 2017. First-year physics students learn to solve problems by implementing the "Ten Commandments" of physics problem solving in their solutions, following a three-stage problem-solving framework. Additionally, students attend whiteboard tutorial sessions where they actively practise using the problem-solving framework in their solutions to physics problems with peers in an environment where help is available. Students are explicitly prompted to use the \Ten Commandments" during the whiteboard tutorials and not prompted for other assessment tasks. Students' solutions to formative physics assessment tasks (problem sets and tests) in the first semester were examined, problem-solving scores were determined using a problem-solving rubric developed in the department, shifts in attitudes and beliefs about physics and solving problems in physics were measured, and relationships between their problem-solving scores and task performance were evaluated to investigate how students adopted the framework and its implications over one semester. The problems issued to students differed in context and difficulty level; as a result, not all of the "Ten Commandments" were applicable to solve all problems, and different combinations of the commandments were applied to different problems. The explicit use of the problem-solving rubric to mark student problem sets was an indirect prompt for students to use commandments when doing their problem sets. As a result, students attempted to implement more applicable "commandments" (mostly partially correct) in their solutions to problem sets than in tests. Moreover, students' solutions to problems show that they used more of the "commandments" they were familiar with from school and less of the new ones, such as drawing diagrams without being prompted, producing algebraic solutions before substituting numbers, and doing dimensional analysis. Problem sets are often assumed to help prepare students for tests; however, correlations between students' problem-solving scores and performance between the two assessments did not give clear indications of whether problem sets were helping to prepare students to solve problems. Lastly, students' attitudes and beliefs also show a negative shift in students' perceptions of problem-solving by the end of the first semester. Problem-solving is a skill that develops in stages and over time; therefore, a timeframe longer than one semester is needed to report on significant changes in students' problem-solving habits and perspectives about problem-solving in physics. The study results are also important in giving insights into the initial developments of problem-solving skills and teaching problem solving. , Thesis (MSc) -- Faculty of Science, Physics and Electronics, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Matiwane, Noluvuyo
- Date: 2024-10-11
- Subjects: Problem solving Study and teaching , Physics Study and teaching , Curriculum change , Rhodes University , College students Attitudes
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464897 , vital:76555
- Description: The evident need for an intervention to help physics students, especially incoming university students, develop their problem-solving skills led to exploring possible curriculum structures to achieve the goal. A modified curriculum structure of the first-year physics course, including explicit teaching of physics problem solving, was developed and implemented at Rhodes University, South Africa, in 2017. First-year physics students learn to solve problems by implementing the "Ten Commandments" of physics problem solving in their solutions, following a three-stage problem-solving framework. Additionally, students attend whiteboard tutorial sessions where they actively practise using the problem-solving framework in their solutions to physics problems with peers in an environment where help is available. Students are explicitly prompted to use the \Ten Commandments" during the whiteboard tutorials and not prompted for other assessment tasks. Students' solutions to formative physics assessment tasks (problem sets and tests) in the first semester were examined, problem-solving scores were determined using a problem-solving rubric developed in the department, shifts in attitudes and beliefs about physics and solving problems in physics were measured, and relationships between their problem-solving scores and task performance were evaluated to investigate how students adopted the framework and its implications over one semester. The problems issued to students differed in context and difficulty level; as a result, not all of the "Ten Commandments" were applicable to solve all problems, and different combinations of the commandments were applied to different problems. The explicit use of the problem-solving rubric to mark student problem sets was an indirect prompt for students to use commandments when doing their problem sets. As a result, students attempted to implement more applicable "commandments" (mostly partially correct) in their solutions to problem sets than in tests. Moreover, students' solutions to problems show that they used more of the "commandments" they were familiar with from school and less of the new ones, such as drawing diagrams without being prompted, producing algebraic solutions before substituting numbers, and doing dimensional analysis. Problem sets are often assumed to help prepare students for tests; however, correlations between students' problem-solving scores and performance between the two assessments did not give clear indications of whether problem sets were helping to prepare students to solve problems. Lastly, students' attitudes and beliefs also show a negative shift in students' perceptions of problem-solving by the end of the first semester. Problem-solving is a skill that develops in stages and over time; therefore, a timeframe longer than one semester is needed to report on significant changes in students' problem-solving habits and perspectives about problem-solving in physics. The study results are also important in giving insights into the initial developments of problem-solving skills and teaching problem solving. , Thesis (MSc) -- Faculty of Science, Physics and Electronics, 2024
- Full Text:
- Date Issued: 2024-10-11
Interlingual and intercultural communication discordances as impediments to the provision of quality public healthcare services: cases of Cecilia Makiwane Hospital, Nkqubela Chest Hospital and Frere Hospital
- Authors: Hlitane, Nkosekaya
- Date: 2024-04-04
- Subjects: Language, Universal , Intercultural communication , Communication in public health , Communication Social aspects , Communication and culture South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/435501 , vital:73163
- Description: This study seeks to explore interlingual and intercultural discordances between clinicians and patients during treatment processes in selected public hospitals in the Eastern Cape. The two languages under investigation are English and isiXhosa. Intercultural communication refers to a phenomenon in which people who speak different native languages are engaged in a conversation (Gudykunst 1993). , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2024
- Full Text:
- Date Issued: 2024-04-04
- Authors: Hlitane, Nkosekaya
- Date: 2024-04-04
- Subjects: Language, Universal , Intercultural communication , Communication in public health , Communication Social aspects , Communication and culture South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/435501 , vital:73163
- Description: This study seeks to explore interlingual and intercultural discordances between clinicians and patients during treatment processes in selected public hospitals in the Eastern Cape. The two languages under investigation are English and isiXhosa. Intercultural communication refers to a phenomenon in which people who speak different native languages are engaged in a conversation (Gudykunst 1993). , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2024
- Full Text:
- Date Issued: 2024-04-04
Formulation of Fish Feed for Aquaculture using Olive Pomace Extract as an Antioxidant
- Authors: Koza, Nondumiso Norma
- Date: 2024-12
- Subjects: Fishes -- Feeding and feeds , Fishes -- Ecology , Sustainable aquaculture
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69318 , vital:77205
- Description: Olive pomace is a significant by-product of the olive oil extraction process and is an environmental issue in olive-producing countries. This project aimed to add extracts from olive pomace as an antioxidant to a fish feed formulation without compromising growth performance and meat quality, thereby contributing to the aquaculture industry. To produce the olive pomace extracts, Coratina cultivar olives were collected from a farm near Oudtshoorn, and the fresh pomace was immediately frozen at -22oC for preservation. The extracts were obtained using a large-scale extraction method using a solvent blend of n-heptane, ethanol, and water. A pressure filtration and centrifuge method were then applied to separate any residue from the extracts. An HPLC method was developed to characterise the extracts' content, identifying various bioactive compounds such as squalene, α-tocopherol, and water-soluble polyphenols like oleuropein, hydroxytyrosol, and tyrosol. In a fish feeding trial it was concluded that the fish fed with the feed without olive pomace gained more weight than those fed the feed with the added pomace extract. Overall, the results indicate that fish sustained on the feed without the olive pomace extract ate more food, consuming more energy to support weight gain but that this did not necessarily translate to an improved feed conversion ratio. The morphometric variables suggest that fish used in the trial remained healthy, implying that there may be a taste or palatability difference between feeds that could explain why less of the feed with olive pomace extract was eaten. Overall, the observed feed conversion ratio values were somewhat lower than the expected values for tilapia (FCR: 1.5-2.0). The peroxide value of fish feed with an addition of 0.3% olive pomace extract was lower than that of the feed without olive pomace extract after 12 weeks of stability testing at room temperature. The results showed a value of 1.48 MeqO2/kg for the feed containing olive pomace extract compared to the peroxide value for the fish feed without olive pomace extract, which was 2.75 MeqO2/kg. This indicates that the nutritional content of the feed was preserved. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Koza, Nondumiso Norma
- Date: 2024-12
- Subjects: Fishes -- Feeding and feeds , Fishes -- Ecology , Sustainable aquaculture
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/69318 , vital:77205
- Description: Olive pomace is a significant by-product of the olive oil extraction process and is an environmental issue in olive-producing countries. This project aimed to add extracts from olive pomace as an antioxidant to a fish feed formulation without compromising growth performance and meat quality, thereby contributing to the aquaculture industry. To produce the olive pomace extracts, Coratina cultivar olives were collected from a farm near Oudtshoorn, and the fresh pomace was immediately frozen at -22oC for preservation. The extracts were obtained using a large-scale extraction method using a solvent blend of n-heptane, ethanol, and water. A pressure filtration and centrifuge method were then applied to separate any residue from the extracts. An HPLC method was developed to characterise the extracts' content, identifying various bioactive compounds such as squalene, α-tocopherol, and water-soluble polyphenols like oleuropein, hydroxytyrosol, and tyrosol. In a fish feeding trial it was concluded that the fish fed with the feed without olive pomace gained more weight than those fed the feed with the added pomace extract. Overall, the results indicate that fish sustained on the feed without the olive pomace extract ate more food, consuming more energy to support weight gain but that this did not necessarily translate to an improved feed conversion ratio. The morphometric variables suggest that fish used in the trial remained healthy, implying that there may be a taste or palatability difference between feeds that could explain why less of the feed with olive pomace extract was eaten. Overall, the observed feed conversion ratio values were somewhat lower than the expected values for tilapia (FCR: 1.5-2.0). The peroxide value of fish feed with an addition of 0.3% olive pomace extract was lower than that of the feed without olive pomace extract after 12 weeks of stability testing at room temperature. The results showed a value of 1.48 MeqO2/kg for the feed containing olive pomace extract compared to the peroxide value for the fish feed without olive pomace extract, which was 2.75 MeqO2/kg. This indicates that the nutritional content of the feed was preserved. , Thesis (MSc) -- Faculty of Science, School of Biomolecular & Chemical Sciences, 2024
- Full Text:
- Date Issued: 2024-12
A framework for designing a gamified system that promotes knowledge of water sustainability
- Authors: Kunjuzwa, Dumani Tau
- Date: 2024-12
- Subjects: Computer science , User interfaces (Computer systems) , Water-supply -- Management
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69349 , vital:77216
- Description: Water shortages are becoming increasingly common and raising awareness thereof has been proposed as a key strategy for empowering citizens with knowledge relevant to promoting water sustainability. This knowledge should incorporate indigenous knowledge, which is unique and confined to a particular culture. Indigenous knowledge has been recognised as the key to sustainable social and economic development. Knowledge incorporated within appropriate technologies can be a transformative solution to promote sustainable consumption of natural resources. This study aimed to develop a framework with strong theoretical connections that can be used as a guide for designing and developing technological solutions for promoting knowledge, attitude, and practices (KAP) of water sustainability. Gamification, serious games, and community social networks were identified as appropriate technologies for implementing these solutions. Design Science Research (DSR) was an appropriate research methodology for this research. As the requirement of the DSR methodology, a framework was designed that considered relevant theories. The two theories (Self-Determination Theory and Social Capital Theory) were incorporated into the framework. The framework can guide other researchers in developing gamified systems that promote the KAPs of water sustainability. This framework was the theoretical artefact of the study. The research context was the Eastern Cape Province of South Africa where the data was collected from two municipalities namely, the Nelson Mandela Bay and Buffalo City Metro, which have both experienced water shortages in recent years. Quantitative and qualitative data collection methods were used. Qualitative data was collected from brainstorming sessions and expert reviews that were conducted with various stakeholders that assisted with designing and evaluating the prototype designs of the gamified solution. For the design of the study’s artefacts, a participatory research approach was adopted. Participants were recruited to complete an online survey, which ran for three months. The findings revealed that citizens’ knowledge is closely correlated to the attitudes and practices of citizens regarding water sustainability. In addition, the findings showed that the knowledge of the citizens in the Eastern Cape Province was relatively low on water practices such as conservation and filtering methods. These results were considered in the design of the practical artefact and the instantiation findings. One limitation of this study was the limited number of indigenous participants in the survey. Other limitations were the lack of experts with indigenous knowledge and the lack of indigenous knowledge documentation. The promotion of water sustainability knowledge in communities would be more effective with the use of gamification and social community networks. In principle, the enhancement in water sustainability knowledge would promote the citizens’ good practices and attitudes (behavioural) related to water sustainability. Since 2015, a significant portion of South Africa's Eastern Cape Province has been suffering from a severe drought. This province is one of the regions of the country where weather patterns have changed dramatically, and as a result, most households were left vulnerable to the water shortage problem. While the broad topic of water sustainability is widely discussed in the literature, the role of appropriate technologies in promoting knowledge of water sustainability is still under-researched. This gap provided a significant potential for investigation by sustainability to design a technological and theoretical solution for promoting knowledge of water sustainability. This study contributes to the body of knowledge by delivering three DSR artefacts namely, a Framework for Designing a Gamified System that Promotes Knowledge of Water Sustainability; the design guidelines that supplement the framework, and a practical instantiation of the framework. , Thesis (DPhil) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2024
- Full Text:
- Date Issued: 2024-12
- Authors: Kunjuzwa, Dumani Tau
- Date: 2024-12
- Subjects: Computer science , User interfaces (Computer systems) , Water-supply -- Management
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/69349 , vital:77216
- Description: Water shortages are becoming increasingly common and raising awareness thereof has been proposed as a key strategy for empowering citizens with knowledge relevant to promoting water sustainability. This knowledge should incorporate indigenous knowledge, which is unique and confined to a particular culture. Indigenous knowledge has been recognised as the key to sustainable social and economic development. Knowledge incorporated within appropriate technologies can be a transformative solution to promote sustainable consumption of natural resources. This study aimed to develop a framework with strong theoretical connections that can be used as a guide for designing and developing technological solutions for promoting knowledge, attitude, and practices (KAP) of water sustainability. Gamification, serious games, and community social networks were identified as appropriate technologies for implementing these solutions. Design Science Research (DSR) was an appropriate research methodology for this research. As the requirement of the DSR methodology, a framework was designed that considered relevant theories. The two theories (Self-Determination Theory and Social Capital Theory) were incorporated into the framework. The framework can guide other researchers in developing gamified systems that promote the KAPs of water sustainability. This framework was the theoretical artefact of the study. The research context was the Eastern Cape Province of South Africa where the data was collected from two municipalities namely, the Nelson Mandela Bay and Buffalo City Metro, which have both experienced water shortages in recent years. Quantitative and qualitative data collection methods were used. Qualitative data was collected from brainstorming sessions and expert reviews that were conducted with various stakeholders that assisted with designing and evaluating the prototype designs of the gamified solution. For the design of the study’s artefacts, a participatory research approach was adopted. Participants were recruited to complete an online survey, which ran for three months. The findings revealed that citizens’ knowledge is closely correlated to the attitudes and practices of citizens regarding water sustainability. In addition, the findings showed that the knowledge of the citizens in the Eastern Cape Province was relatively low on water practices such as conservation and filtering methods. These results were considered in the design of the practical artefact and the instantiation findings. One limitation of this study was the limited number of indigenous participants in the survey. Other limitations were the lack of experts with indigenous knowledge and the lack of indigenous knowledge documentation. The promotion of water sustainability knowledge in communities would be more effective with the use of gamification and social community networks. In principle, the enhancement in water sustainability knowledge would promote the citizens’ good practices and attitudes (behavioural) related to water sustainability. Since 2015, a significant portion of South Africa's Eastern Cape Province has been suffering from a severe drought. This province is one of the regions of the country where weather patterns have changed dramatically, and as a result, most households were left vulnerable to the water shortage problem. While the broad topic of water sustainability is widely discussed in the literature, the role of appropriate technologies in promoting knowledge of water sustainability is still under-researched. This gap provided a significant potential for investigation by sustainability to design a technological and theoretical solution for promoting knowledge of water sustainability. This study contributes to the body of knowledge by delivering three DSR artefacts namely, a Framework for Designing a Gamified System that Promotes Knowledge of Water Sustainability; the design guidelines that supplement the framework, and a practical instantiation of the framework. , Thesis (DPhil) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2024
- Full Text:
- Date Issued: 2024-12
Marine plastic pollution impacts on ecosystem services and livelihoods in South Africa: a review and stakeholder perceptions
- Authors: Yose, Papama
- Date: 2023-10-13
- Subjects: Marine ecology South Africa , Marine plastic pollution , Ecosystem services , Multi-stakeholder process , Marine biodiversity conservation
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424743 , vital:72180
- Description: Marine plastic pollution is one of the major environmental problems globally, with adverse impacts on marine ecosystem services, functions and benefits and people. Yet, compared to plastic pollution impacts on terrestrial ecosystems, the impacts of plastic waste on marine ecosystems are little studied and poorly understood in South Africa. In response, research interest on the ecological and economic impacts of marine plastic pollution has grown rapidly but socio-cultural impacts remain poorly conceptualized and little understudied. This trend is arguably driven by the dominance of a quantitative paradigm which is arguably inadequate to respond to dynamic socio-cultural issues and contexts. Further, in South Africa, marine ecosystems are used by diverse groups of people ranging from subsistence users, tourism operators, commercial fishers and recreational users, meaning that addressing marine plastic pollution requires a multi-stakeholder approach. However, few studies explore the perceptions of diverse stakeholders regarding marine plastic pollution, its impacts and potential interventions. Against this background, the objective of the thesis are twofold: (a) to argue for a more nuanced understanding of marine plastic pollution impacts on human well-being in order to strengthen conceptualization of impacts that goes beyond direct and quantitatively measured impacts (ecological, health and economic) but considers the socio-cultural dimensions of impacts (lifestyle disruptions, mental health costs and cultural and heritage impacts), and (b) examine stakeholders’ perceptions of marine plastic pollution, its impacts and potential interventions in South Africa. Drawing on case studies, this study provides a working definition of the socio-cultural impacts of marine plastic pollution and a conceptual framework for categorizing the impacts. It highlights three dimensions of the socio-cultural impacts of marine plastic pollution (lifestyle, mental health, and cultural and heritage impacts). It also illustrates connections between marine ecosystems and marine-based livelihood activities with the social and cultural dimensions of human wellbeing to show the links between marine environments and socio-cultural contexts. Concerning stakeholder perceptions, the study showed a tendency to associate marine plastic pollution with immediate, noticeable and easily quantifiable ecological impacts such as entanglement and ingestion of marine organisms, economic impacts and social impacts (e.g., loss of aesthetic appeal). However, secondary impacts such as loss of marine biodiversity and social impacts such as human health, were largely unknown. Moreover, there was heterogeneity in perceptions of marine plastic pollution impacts among the stakeholder groups. Prospective studies researching marine plastic pollution impacts should consider divergent and diverse perceptions of different stakeholders to capture the real costs of marine plastic pollution. , Thesis (MSc) -- Faculty of Science, Environmental Science, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Yose, Papama
- Date: 2023-10-13
- Subjects: Marine ecology South Africa , Marine plastic pollution , Ecosystem services , Multi-stakeholder process , Marine biodiversity conservation
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424743 , vital:72180
- Description: Marine plastic pollution is one of the major environmental problems globally, with adverse impacts on marine ecosystem services, functions and benefits and people. Yet, compared to plastic pollution impacts on terrestrial ecosystems, the impacts of plastic waste on marine ecosystems are little studied and poorly understood in South Africa. In response, research interest on the ecological and economic impacts of marine plastic pollution has grown rapidly but socio-cultural impacts remain poorly conceptualized and little understudied. This trend is arguably driven by the dominance of a quantitative paradigm which is arguably inadequate to respond to dynamic socio-cultural issues and contexts. Further, in South Africa, marine ecosystems are used by diverse groups of people ranging from subsistence users, tourism operators, commercial fishers and recreational users, meaning that addressing marine plastic pollution requires a multi-stakeholder approach. However, few studies explore the perceptions of diverse stakeholders regarding marine plastic pollution, its impacts and potential interventions. Against this background, the objective of the thesis are twofold: (a) to argue for a more nuanced understanding of marine plastic pollution impacts on human well-being in order to strengthen conceptualization of impacts that goes beyond direct and quantitatively measured impacts (ecological, health and economic) but considers the socio-cultural dimensions of impacts (lifestyle disruptions, mental health costs and cultural and heritage impacts), and (b) examine stakeholders’ perceptions of marine plastic pollution, its impacts and potential interventions in South Africa. Drawing on case studies, this study provides a working definition of the socio-cultural impacts of marine plastic pollution and a conceptual framework for categorizing the impacts. It highlights three dimensions of the socio-cultural impacts of marine plastic pollution (lifestyle, mental health, and cultural and heritage impacts). It also illustrates connections between marine ecosystems and marine-based livelihood activities with the social and cultural dimensions of human wellbeing to show the links between marine environments and socio-cultural contexts. Concerning stakeholder perceptions, the study showed a tendency to associate marine plastic pollution with immediate, noticeable and easily quantifiable ecological impacts such as entanglement and ingestion of marine organisms, economic impacts and social impacts (e.g., loss of aesthetic appeal). However, secondary impacts such as loss of marine biodiversity and social impacts such as human health, were largely unknown. Moreover, there was heterogeneity in perceptions of marine plastic pollution impacts among the stakeholder groups. Prospective studies researching marine plastic pollution impacts should consider divergent and diverse perceptions of different stakeholders to capture the real costs of marine plastic pollution. , Thesis (MSc) -- Faculty of Science, Environmental Science, 2023
- Full Text:
- Date Issued: 2023-10-13
Native-range studies on insect herbivores associated with African Lovegrass (Eragrostis curvula) in South Africa: prospects for biological control in Australia
- Authors: Yell, Liam Dougal
- Date: 2023-10-13
- Subjects: Weeping lovegrass Biological control Australia , Tetramesa , Biological pest control agents , Efficacy , Host specificity , Environmental risk assessment
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424446 , vital:72154
- Description: Eragrostis curvula (Schrad.) Nees. (African Lovegrass) is an African native species of grass that was intentionally introduced for pasture in Australia. It has since escaped cultivation and has become widespread and highly invasive. Eragrostis curvula has been recorded in every state and territory in Australia where it has altered fire regimes, disrupted nutrient cycles and can reduce livestock carrying capacity by up to 50%. The Centre for Biological Control at Rhodes University and the New South Wales Department of Primary Industries have been working in collaboration to identify and screen herbivorous insects as biological control agents for E. curvula in Australia. Native-range surveys were conducted between 2021 and 2022 on E. curvula at twenty-two sites across South Africa to identify herbivorous natural enemies associated with it. Species accumulation curves were generated to ensure adequate sampling was performed to identify all the insects associated with E. curvula. Twenty-nine non-target grass species were surveyed simultaneously to determine the field-host range of the natural enemies associated with the target weed. Herbivorous natural enemies were prioritised as possible biological control agents against E. curvula in Australia based on field-host range, predicted efficacy and climatic suitability. Four insect species were consistently found on E. curvula, two of which were herbivorous, as well as a parasitoid and a detritivore. Species accumulation curves show that the insect community was adequately sampled in South Africa. The two herbivorous insects were identified to the lowest taxonomic level using COI barcoding. Both species are undescribed phytophagous wasps in the genus Tetramesa (Hymenoptera: Eurytomidae). Because Tetramesa species have been shown to be host specific and highly damaging in previous biological control programs for other invasive grass weeds, we assessed their suitability as candidate biological control agents for use on E. curvula in Australia. Both Tetramesa species (“sp. 4” and “sp. 5”) were found on several native congeners under field conditions in South Africa. Congeneric South African-native non-target grass species were used as phylogenetic proxies to assess the risk posed to Australian native Eragrostis species. This highlighted three non-target Australian native Eragrostis species, namely: E. parviflora (R. Br.) Trin., E. leptocarpa Benth. fl., and E. trachycarpa Benth., that are at risk of being attacked by the two candidate agents based on their phylogenetic proximity to E. curvula. Predicted efficacy trials were conducted at five long-term repeat survey sites and revealed that Tetramesa sp. 4 does not reduce the probability of E. curvula tiller survival or reproduction, while Tetramesa sp. 5 does not reduce the probability of tiller reproduction but does increase the probability of tiller survival. This result was unexpected and may be a plant compensatory response to herbivory. The sites where both Tetramesa species were collected in South Africa are climatically similar to the invaded range of E. curvula in Australia, and as such, the Tetramesa spp. are likely to be suitably adapted to the climate where they would be released in Australia. These results suggest that both Tetramesa species associated with E. curvula may have too broad a host range to be used as biological control agents in Australia. However, further quarantine-based host-range assessments on Australian native Eragrostis species are recommended to confirm this. The field-based methods used in this study have reduced the number of insect and plant species that host-range assessments will be required to be performed on, thus preventing wasted resources. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Yell, Liam Dougal
- Date: 2023-10-13
- Subjects: Weeping lovegrass Biological control Australia , Tetramesa , Biological pest control agents , Efficacy , Host specificity , Environmental risk assessment
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424446 , vital:72154
- Description: Eragrostis curvula (Schrad.) Nees. (African Lovegrass) is an African native species of grass that was intentionally introduced for pasture in Australia. It has since escaped cultivation and has become widespread and highly invasive. Eragrostis curvula has been recorded in every state and territory in Australia where it has altered fire regimes, disrupted nutrient cycles and can reduce livestock carrying capacity by up to 50%. The Centre for Biological Control at Rhodes University and the New South Wales Department of Primary Industries have been working in collaboration to identify and screen herbivorous insects as biological control agents for E. curvula in Australia. Native-range surveys were conducted between 2021 and 2022 on E. curvula at twenty-two sites across South Africa to identify herbivorous natural enemies associated with it. Species accumulation curves were generated to ensure adequate sampling was performed to identify all the insects associated with E. curvula. Twenty-nine non-target grass species were surveyed simultaneously to determine the field-host range of the natural enemies associated with the target weed. Herbivorous natural enemies were prioritised as possible biological control agents against E. curvula in Australia based on field-host range, predicted efficacy and climatic suitability. Four insect species were consistently found on E. curvula, two of which were herbivorous, as well as a parasitoid and a detritivore. Species accumulation curves show that the insect community was adequately sampled in South Africa. The two herbivorous insects were identified to the lowest taxonomic level using COI barcoding. Both species are undescribed phytophagous wasps in the genus Tetramesa (Hymenoptera: Eurytomidae). Because Tetramesa species have been shown to be host specific and highly damaging in previous biological control programs for other invasive grass weeds, we assessed their suitability as candidate biological control agents for use on E. curvula in Australia. Both Tetramesa species (“sp. 4” and “sp. 5”) were found on several native congeners under field conditions in South Africa. Congeneric South African-native non-target grass species were used as phylogenetic proxies to assess the risk posed to Australian native Eragrostis species. This highlighted three non-target Australian native Eragrostis species, namely: E. parviflora (R. Br.) Trin., E. leptocarpa Benth. fl., and E. trachycarpa Benth., that are at risk of being attacked by the two candidate agents based on their phylogenetic proximity to E. curvula. Predicted efficacy trials were conducted at five long-term repeat survey sites and revealed that Tetramesa sp. 4 does not reduce the probability of E. curvula tiller survival or reproduction, while Tetramesa sp. 5 does not reduce the probability of tiller reproduction but does increase the probability of tiller survival. This result was unexpected and may be a plant compensatory response to herbivory. The sites where both Tetramesa species were collected in South Africa are climatically similar to the invaded range of E. curvula in Australia, and as such, the Tetramesa spp. are likely to be suitably adapted to the climate where they would be released in Australia. These results suggest that both Tetramesa species associated with E. curvula may have too broad a host range to be used as biological control agents in Australia. However, further quarantine-based host-range assessments on Australian native Eragrostis species are recommended to confirm this. The field-based methods used in this study have reduced the number of insect and plant species that host-range assessments will be required to be performed on, thus preventing wasted resources. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring grade 11 learners’ mathematical problem-solving skills using Polka’s model during the learning of Euclidean geometry
- Authors: Hlupeni, Ratham
- Date: 2024-04-05
- Subjects: Mathematics Study and teaching (Secondary) South Africa , Euclidean geometry , Problem solving , Pólya, George, 1887-1985 , Mathematics Problems, exercises, etc.
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/436465 , vital:73274
- Description: The skill of Problem-solving in Mathematics is very imperative. Poor performance by most South African learners in schools and international tests such as the Trends in International Mathematics and Science, calls for emphasis to be placed on problem-solving in the teaching and learning of Mathematics. Euclidean Geometry is perceived, especially by learners, to be one of the difficult components of Mathematics. Thus, the aim of this study was to explore and develop the mathematical problem-solving and geometric skills of Grade 11 learners in Euclidean Geometry. Polya’s model of problem-solving was employed in geometric skills development as a tool for intervention. The concepts Geometry and problem-solving formed the conceptual framework of the study, while the social cognitive theory constituted the theoretical framework. A case study was used as the main research method following a mixed method approach within an interpretivist paradigm. Purposive and convenience sampling methods were used in the selection of both the Mathematics class and the six learners whose work was further observed and analysed. Data about the geometric skills displayed by the learners was gathered using a moderated pre-intervention test; observations; document analysis; a moderated post-intervention test; and focus group interviews. Data was analysed quantitatively using descriptive statistics and qualitatively using thematic analysis. In the pre-intervention test, learners did not bring with them expected geometric skills to the classroom before they were introduced to grade11 Geometry content and when doing problem-solving during intervention, the four stages of model used were not necessarily following each other in a linear sequence with most of the learners not applying the fourth stage “look back”. In the post intervention test, the frequency of use and application of most geometric skills improved in comparison to the pre-intervention test; the frequency of correct and inappropriate application of the skills increased at the expense of incorrect application. Learners appreciated the four stages model and gave their views related to the challenged faced during the use of the four stages model and the challenges revealed include: practice related challenges, challenges specific to certain learners, concept related challenges, curriculum-related challenges, model application challenge, and context related challenges. The study concludes that the effective use of Polyas’ four stages model can yield great results in developing learners’ geometric and problem-solving skills. The study recommends that teachers give more attention to prior geometric knowledge, teaching of geometric theorems, teaching of geometric problem-solving, and the learning environment. , Thesis (MEd) -- Faculty of Education, Secondary and Post School Education, 2024
- Full Text:
- Date Issued: 2024-04-05
- Authors: Hlupeni, Ratham
- Date: 2024-04-05
- Subjects: Mathematics Study and teaching (Secondary) South Africa , Euclidean geometry , Problem solving , Pólya, George, 1887-1985 , Mathematics Problems, exercises, etc.
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/436465 , vital:73274
- Description: The skill of Problem-solving in Mathematics is very imperative. Poor performance by most South African learners in schools and international tests such as the Trends in International Mathematics and Science, calls for emphasis to be placed on problem-solving in the teaching and learning of Mathematics. Euclidean Geometry is perceived, especially by learners, to be one of the difficult components of Mathematics. Thus, the aim of this study was to explore and develop the mathematical problem-solving and geometric skills of Grade 11 learners in Euclidean Geometry. Polya’s model of problem-solving was employed in geometric skills development as a tool for intervention. The concepts Geometry and problem-solving formed the conceptual framework of the study, while the social cognitive theory constituted the theoretical framework. A case study was used as the main research method following a mixed method approach within an interpretivist paradigm. Purposive and convenience sampling methods were used in the selection of both the Mathematics class and the six learners whose work was further observed and analysed. Data about the geometric skills displayed by the learners was gathered using a moderated pre-intervention test; observations; document analysis; a moderated post-intervention test; and focus group interviews. Data was analysed quantitatively using descriptive statistics and qualitatively using thematic analysis. In the pre-intervention test, learners did not bring with them expected geometric skills to the classroom before they were introduced to grade11 Geometry content and when doing problem-solving during intervention, the four stages of model used were not necessarily following each other in a linear sequence with most of the learners not applying the fourth stage “look back”. In the post intervention test, the frequency of use and application of most geometric skills improved in comparison to the pre-intervention test; the frequency of correct and inappropriate application of the skills increased at the expense of incorrect application. Learners appreciated the four stages model and gave their views related to the challenged faced during the use of the four stages model and the challenges revealed include: practice related challenges, challenges specific to certain learners, concept related challenges, curriculum-related challenges, model application challenge, and context related challenges. The study concludes that the effective use of Polyas’ four stages model can yield great results in developing learners’ geometric and problem-solving skills. The study recommends that teachers give more attention to prior geometric knowledge, teaching of geometric theorems, teaching of geometric problem-solving, and the learning environment. , Thesis (MEd) -- Faculty of Education, Secondary and Post School Education, 2024
- Full Text:
- Date Issued: 2024-04-05
“Ha! Relationships? I only shout at them!”: Strategic management of discordant rapport in an African small business context
- Lauriks, Sanne, Siebörger, Ian, De Vos, Mark A
- Authors: Lauriks, Sanne , Siebörger, Ian , De Vos, Mark A
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385338 , vital:68009 , xlink:href="https://doi.org/10.1515/pr-2015-0002"
- Description: This study demonstrates how and why interactants at a tyre fitment centre in Grahamstown, South Africa, manage discordant interpersonal relationships in strategic ways. Individuals in a post-apartheid small business respond to their social and economic context and exercise agency to their advantage in doing so. This study draws on linguistic ethnography (Rampton 2007) and the Rapport Management Framework (RMF, Spencer-Oatey 2000b, 2011), itself a development of politeness theory (Brown and Levinson 1987). An initial RMF analysis ran into difficulties around interactions that at first glance appeared to be oriented toward Rapport Challenge and Neglect. Upon closer examination, it appeared that discordant rapport was being actively maintained in this business. This led us to address underdeveloped areas of RMF that were not responsive enough to describe naturally occurring small business interactions, and propose an Enhanced Rapport Management Framework to overcome its inadequacies. We conclude that people may deliberately maintain discordant relationships when it is in their best interests to do so. Thus, contrary to a common-sense belief that harmonious social relations are an intrinsic good, we found that promoting discordant social relations can be understood as a rational response to individuals’ social and economic contexts, particularly in conditions such as those in many postcolonial African societies.
- Full Text:
- Date Issued: 2015
- Authors: Lauriks, Sanne , Siebörger, Ian , De Vos, Mark A
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385338 , vital:68009 , xlink:href="https://doi.org/10.1515/pr-2015-0002"
- Description: This study demonstrates how and why interactants at a tyre fitment centre in Grahamstown, South Africa, manage discordant interpersonal relationships in strategic ways. Individuals in a post-apartheid small business respond to their social and economic context and exercise agency to their advantage in doing so. This study draws on linguistic ethnography (Rampton 2007) and the Rapport Management Framework (RMF, Spencer-Oatey 2000b, 2011), itself a development of politeness theory (Brown and Levinson 1987). An initial RMF analysis ran into difficulties around interactions that at first glance appeared to be oriented toward Rapport Challenge and Neglect. Upon closer examination, it appeared that discordant rapport was being actively maintained in this business. This led us to address underdeveloped areas of RMF that were not responsive enough to describe naturally occurring small business interactions, and propose an Enhanced Rapport Management Framework to overcome its inadequacies. We conclude that people may deliberately maintain discordant relationships when it is in their best interests to do so. Thus, contrary to a common-sense belief that harmonious social relations are an intrinsic good, we found that promoting discordant social relations can be understood as a rational response to individuals’ social and economic contexts, particularly in conditions such as those in many postcolonial African societies.
- Full Text:
- Date Issued: 2015