https://commons.ru.ac.za/vital/access/manager/Index ${session.getAttribute("locale")} 5 https://commons.ru.ac.za/vital/access/manager/Repository/vital:4330 Wed 12 May 2021 23:40:38 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2356 Wed 12 May 2021 23:36:21 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3925 Wed 12 May 2021 23:30:20 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1881 Wed 12 May 2021 23:29:46 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3293 Wed 12 May 2021 23:13:23 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2981 Wed 12 May 2021 23:12:04 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3421 Wed 12 May 2021 23:11:48 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5553 Wed 12 May 2021 23:11:12 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:740 Wed 12 May 2021 23:06:16 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3417 Tue 31 Aug 2021 09:51:03 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5324 Thu 29 Sep 2022 14:19:13 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1658 Thu 13 May 2021 16:20:09 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4643 Thu 13 May 2021 14:53:46 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4187 Thu 13 May 2021 13:32:45 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2129 Thu 13 May 2021 09:55:09 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4652 Thu 13 May 2021 08:52:16 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4217 Thu 13 May 2021 08:49:26 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3295 Thu 13 May 2021 08:49:02 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2820 Thu 13 May 2021 08:23:15 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2207 Thu 13 May 2021 08:22:28 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3472 Thu 13 May 2021 08:22:21 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3845 Thu 13 May 2021 08:22:13 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:942 Thu 13 May 2021 08:21:55 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1463 Thu 13 May 2021 08:07:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5578 Thu 13 May 2021 08:05:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1573 Thu 13 May 2021 07:40:59 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2427 Thu 13 May 2021 07:36:02 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3494 Thu 13 May 2021 07:35:37 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2762 Thu 13 May 2021 07:35:13 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:769 Thu 13 May 2021 07:26:17 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2347 Thu 13 May 2021 07:24:59 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5370 0.001) and A. gilli between Rondegat and Noordhoeks rivers (x₂ = 34.74, d.f. = 4, p > 0.001). The Spearman's rank correlation test showed no shifts in the diet of A. barnardi from Noordhoeks River and A. gilli from Rondegat River with a change in size and season (p>O.OS). However, there was a shift in the diet of A. gilli from the Noordhoeks River which could suggest a distinct patchiness of benthic macroinvertebrates between the riffle feeding areas used by juveniles and other biotopes used by adults. The occurrence, in stomach contents, of other prey items from a wide variety of taxa and the presence of allochthonous material from the terrestrial environment could suggest an opportunistic feeding guild for both Austroglanis species. The life-history traits of A. gilli and A. barnardi, which are charaterized by slow growth, long life span and low relative fecundity, indicate that both species are relatively precocial and K-selected. The population of a precocial species is relatively stable and if population numbers were to be greatly reduced, they would require a long time to rebuild. An urgent conservation intervention is therefore recommended for Austroglanis spp. so as to maintain the diversity of populations within these species. The creation of protected river reserves and raising public conservation awareness may minimise activities that result in altered river hydrology and the destruction of complex benthic habitats.]]> Thu 13 May 2021 07:20:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4413 [M(2-OH-oVANPN)Xn] + HnX MX₂ + 2-OH-oVANPN (2:1) -> [Mn(2-OH-oVANPN)OH] + H₂X₂ MX₂ + (o-vanillin : diaminopropanol) (1:1) -> [M(1:1)X₂] MX₂ + (o-vanillin : diaminopropanol) (1:1) -> [M₃(1:1)X₄] M = Cu(II), Co(II) or Co(III); X = Cl; n = 1, 2. Their structural features have been deduced from their elemental analytical data, IR spectral data, and electronic spectral data. With the exception of {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆}(A4), the Cu(II) complexes were monomeric with 2-OH-oVANPN acting as a tetradentate ligand. A binuclear Co(II) complex, [Co₂(C₁₉H₁₉N₂O₅)(OH)] (B1), was synthesised and the rest of the Co(II) and Co(III) complexes were monomeric with chloride ions coordinating to the metal centre in some cases. Electronic data suggest that the cobalt(II) complexes have octahedral geometries and the copper(II) complexes have square planar structures – Co(III) is likely to be octahedral. Thermal analyses, which included the copper-block-method for determining sublimation temperatures, revealed that some copper(II) and cobalt(II) complexes are hygroscopic and sublime at 200 °C and below. DSC analyses of the Cu(II) complexes gave exotherms around 300 °C for complexes K[Cu(C₁₉H₂₀N₂O₅)(OH)]·2H₂O (A1) and [Cu(C₁₁H15N₂O₃)(Cl)₂]·2H₂O (A2) and above 400 °C for [Cu(C₁₁H₁₆N₂O₃)(Cl)₂] (A3) and {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆} (A4). Antioxidant studies were carried out against the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH·). The cobalt(II) complex, [Co₂(C₁₉H₁₉N₂O₅)(OH)] (B1), which was synthesized in the presence of KOH, had no antioxidant activity, whilst the other cobalt(II) complexes, [Co(C₁₇H₁₇N₂O₅(Cl))]·1½H₂O (B2), [Co(C₁₉H₂₂N₂O₅) (Cl)₂]·5½H₂O (B3) and [Co(C₁₉H₂₂N₂O₅)(Cl)₂]·5½H₂O (B4), which were synthesised in the absence of KOH, demonstrated antioxidant activity. The latter complexes are candidates for cancer cell line testing, while [Cu(C₁₁H₁₆N₂O₃)(Cl)₂] (A3), {Cu₃(C₁₁H₁₄N₂O₃)(Cl)₄(H₂O)₆} (A4), [Co(C₁₉H₂₁N₂O₅)(Cl)₂ ]·5H₂O (C2) and [Co(C₁₉H₂₀N₂O₅)(Cl)]·3H₂O (C3) may show anticancer activity through possible hydrolysis products. Most of the complexes synthesized displayed antimicrobial activity against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans. The results indicated that complexes [Cu(C₁₁H₁₆N₂O₃)(Cl)₂](A3), [Co(C₁₉H₂₂N₂O₅)(Cl)₂]·5½H₂O (B3) and [Co(C₁₉H₂₁N₂O₅)(Cl)₂ ]·5H₂O (C2) are active against the Gram-negative Ps. aeruginosa and that the ligand, 2-OH-oVANPN, did not have any activity. The same trend was observed with 2-OH-oVANPN, {Cu₃(C₁₁H₁₄N₂O₃)(Cl)4(H₂O)₆} (A4) and [Co(C₁₉H₂₀N₂O₅)(Cl)]·3H₂O (C3) against the Gram-positive S. aureus. As for activity against E. coli and C. albicans, some complexes showed more activity than the ligand. There is an observed trend here that the metal complexes are more active (toxic) than the corresponding ligand, which is in agreement with Tweedy’s chelation theory.]]> Thu 13 May 2021 07:08:10 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2000 Thu 13 May 2021 07:08:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:763 Thu 13 May 2021 07:04:36 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3959 Thu 13 May 2021 07:01:49 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5793 Thu 13 May 2021 06:54:20 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1641 Thu 13 May 2021 06:45:39 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3506 Thu 13 May 2021 06:44:19 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5677 Thu 13 May 2021 06:30:18 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2951 Thu 13 May 2021 06:27:42 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:3470 Thu 13 May 2021 06:26:10 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5723 Thu 13 May 2021 06:19:17 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1640 Thu 13 May 2021 06:16:40 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:963 Thu 13 May 2021 05:59:51 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:5768 500 μm) was investigated in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa. Spatial and seasonal patterns in the hyperbenthic community structure were assessed monthly at six stations along the length of the estuary over a period of twelve months. Data were collected using a modified hyperbenthic sledge, comprising two super-imposed nets. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentrations were evident. Total average hyperbenthic densities ranged between 0.04 and 166 ind.m-3 in the lower net and between 0.12 and 225 ind.m-3 in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m-3 in the lower net and between 0.02 and 17.4 mg.dry weight.m-3 in the upper net. A spatial and temporal pattern in total densities was detected with an increase in abundance over the period of September to October 2008 particularly in the middle reaches (Stations 3 and 4). Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoeae) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, making up 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis. Diel variability in the hyperbenthic community structure was assessed during March 2009. Samples were collected during the day and night (n = 6 for each period) using sampling gear described above. Total average hyperbenthic densities during the day (497.9 ± 254.1 ind.m-3) were significantly higher than night-time estimates (129.9 ± 38.5 ind.m-3; p<0.05). There were no significant differences in the average dayand night-time estimates of hyperbenthic biomass (p>0.05). A hierarchical cluster analysis identified two significantly distinct groupings, designated the day and night samples. Results from the SIMPER procedure indicated that the high densities of crab zoeae recorded during the day-time accounted for the majority of the dissimilarity between the day and night groupings (44.7%). In addition, it is apparent that several benthic species, especially from the cumacean and isopod orders, were absent from the hyperbenthos during the day-time and emerged into the water column at night.]]> Thu 13 May 2021 05:37:41 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1168 Thu 13 May 2021 05:20:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4325 Thu 13 May 2021 04:49:41 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:2415 Thu 13 May 2021 04:43:19 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1166 Thu 13 May 2021 04:36:28 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1619 Thu 13 May 2021 04:19:17 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:1489 Thu 13 May 2021 04:18:05 SAST ]]> https://commons.ru.ac.za/vital/access/manager/Repository/vital:4294 Thu 13 May 2021 04:10:37 SAST ]]> 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