https://commons.ru.ac.za/vital/access/manager/Index en-us 5 Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety https://commons.ru.ac.za/vital/access/manager/Repository/vital:50935 Wed 08 May 2024 15:24:11 SAST ]]> Spectroscopic investigations and theoretical calculations of DABCO induced xanthene bridged self-assembled zinc (II) porphyrin dimer https://commons.ru.ac.za/vital/access/manager/Repository/vital:50866 Wed 08 May 2024 15:19:59 SAST ]]> Push–pull type manganese (III) corroles https://commons.ru.ac.za/vital/access/manager/Repository/vital:44826 Wed 08 May 2024 15:14:51 SAST ]]> Highly efficient CCl bond cleavage and unprecedented CC bond cleavage of environmentally toxic DDT through molecular electrochemical catalysis https://commons.ru.ac.za/vital/access/manager/Repository/vital:44798 Wed 08 May 2024 15:10:59 SAST ]]> Halogen substituted A2B type Co (III) triarylcorroles https://commons.ru.ac.za/vital/access/manager/Repository/vital:50051 Wed 08 May 2024 15:10:29 SAST ]]> Flexible Metal–Porphyrin Dimers (M= MnIIICl, CoII, NiII, CuII) https://commons.ru.ac.za/vital/access/manager/Repository/vital:50754 Wed 08 May 2024 15:10:04 SAST ]]> Enantioselective electrochemical carbon-chloride bond cleavage of hexachlorocyclohexanes (HCHs) catalyzed by Mn (III) Cl-phthalocyanine https://commons.ru.ac.za/vital/access/manager/Repository/vital:44831 Wed 08 May 2024 15:09:36 SAST ]]> Cu (III) triarylcorroles with asymmetric push–pull meso-substitutions https://commons.ru.ac.za/vital/access/manager/Repository/vital:50040 Wed 08 May 2024 15:08:26 SAST ]]> A2B type copper (III) corroles containing zero-to-five fluorine atoms https://commons.ru.ac.za/vital/access/manager/Repository/vital:50604 Wed 08 May 2024 15:07:33 SAST ]]> Porphyrin dimers with a bridging chiral amide-bonded benzo-moiety https://commons.ru.ac.za/vital/access/manager/Repository/vital:50090 Wed 08 May 2024 15:03:38 SAST ]]> Core-modified rubyrins with phenanthrene-fused pyrrole rings https://commons.ru.ac.za/vital/access/manager/Repository/vital:50209 Wed 08 May 2024 14:56:10 SAST ]]> Co (ii) Tetraphenyltetraphenanthroporphyrin@ MWCNTs https://commons.ru.ac.za/vital/access/manager/Repository/vital:50210 Wed 08 May 2024 14:51:18 SAST ]]> Iron (iii) porphyrin electrocatalyzed enantioselective carbon-chloride bond cleavage of hexachlorocyclohexanes (HCHs): combined experimental investigation and theoretical calculations https://commons.ru.ac.za/vital/access/manager/Repository/vital:74688 α-HCH > δ-HCH > β-HCH. Steric considerations and a molecular orbital theory approach can be used to rationalize the enantioselective nature of the catalysis based on the ease of approach of each Cl atom to the central Fe(I) ion and a consideration of the nodes on the C–Cl bonds that weaken these bonds in a manner that results in bond cleavage and the formation of an Fe–Cl bond.]]> Wed 07 Aug 2024 15:48:18 SAST ]]>